JP2616352B2 - Morning paint - Google Patents
Morning paintInfo
- Publication number
- JP2616352B2 JP2616352B2 JP4234313A JP23431392A JP2616352B2 JP 2616352 B2 JP2616352 B2 JP 2616352B2 JP 4234313 A JP4234313 A JP 4234313A JP 23431392 A JP23431392 A JP 23431392A JP 2616352 B2 JP2616352 B2 JP 2616352B2
- Authority
- JP
- Japan
- Prior art keywords
- noble metal
- metal layer
- paint
- color
- zircon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は，盛りが高く，耐久性，
耐摩耗性に優れた，盛貴金属彩の盛部分を形成すること
ができる盛絵具に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a heap paint which is excellent in abrasion resistance and can form a heap part of a noble metal color.
【０００２】[0002]
【従来技術】ホテル，レストラン等で使われる食器，装
飾品等の陶磁器は，豪華な色彩装飾が施されているもの
が好まれる。中でも，金を含む盛貴金属彩は，貴金属色
の光沢が美しく，特に珍重される。盛貴金属彩とは，盛
を高く形成するための盛部分と，該盛部分を被覆した貴
金属層とからなるものである。上記盛貴金属彩は，盛部
分の厚みにより，貴金属層が高く盛られたように見え，
豪華性，装飾性共に優れている。2. Description of the Related Art Ceramics used in hotels, restaurants, etc., such as tableware and ornaments, are preferably those with luxurious color decoration. Among them, Sori noble metal colors including gold have a beautiful noble metal color luster and are especially prized. The precious noble metal color comprises a protruding portion for forming the prominence high and a noble metal layer covering the protruding portion. The above noble metal color looks like the noble metal layer was piled high by the thickness of the high part,
Superior luxury and decoration.
【０００３】盛貴金属彩を陶磁器に形成する方法として
は，まず第１に，盛絵具を陶磁器の上に厚く塗布して焼
成し盛部分を形成したのち，該盛部分の表面に薄層の貴
金属層を被覆し，再度焼成する方法がある。また第２
に，盛絵具を印刷後，乾燥する前に貴金属粉を蒔き，一
度の焼成で盛貴金属層を形成する方法（特公昭４９−２
８０１０号公報）がある。さらに第３の方法として，盛
絵具と貴金属層とを重ねて印刷し，貴金属層がマット状
であったり盛り上がったりしたように見せる方法（特開
昭６２−２３５２３４号公報）がある。[0003] As a method for forming a noble metal porcelain on ceramics, first, a thick paint is applied on the porcelain and fired to form a swelled part, and then a thin layer of noble metal is formed on the surface of the swelled part. There is a method of coating the layer and firing again. Also the second
In addition, a method of printing a noble metal powder before printing and then sowing noble metal powder and forming a noble metal layer in a single firing (Japanese Patent Publication No. 49-2)
No. 8010). Further, as a third method, there is a method of superimposing a noble metal layer on a stencil paint and printing the same so that the noble metal layer looks like a mat or is raised (Japanese Patent Application Laid-Open No. 62-235234).
【０００４】[0004]
【解決しようとする課題】しかしながら，上記第１の盛
貴金属彩は，予め盛部分を焼成しておくことが必要であ
り，二度の焼成を行なう必要がある。またその製造工程
は人手に頼る部分が多いため手間と労力がかかり，製品
のコストアップにつながるものである。第２の盛貴金属
彩は，高価な貴金属粉を用いる。貴金属粉は飛び散りや
すいため回収の手間がかかる。よって第１の盛貴金属彩
と同様，手間と労力がかかり，製品のコストアップにつ
ながるものである。However, the first metal precious metal must be fired in advance, and must be fired twice. In addition, the manufacturing process has many parts that depend on human labor, which requires labor and labor, which leads to an increase in product cost. The second precious metal color uses expensive precious metal powder. Precious metal powder is easy to scatter and takes time to recover. Therefore, as in the case of the first precious precious metal color, labor and labor are required, which leads to an increase in product cost.
【０００５】第３の盛貴金属彩は，盛部分をマット状に
してエッチング効果を得るとともに，焼成時の貴金属層
の割れを防止するために，盛部分に相互に熔融しにくい
盛絵具を利用する必要がある。しかし，この場合には，
盛部分と貴金属層との接合性が悪く，接合面に空隙が形
成され，陶磁器の取扱時において，盛貴金属彩にチッピ
ングが生じてしまうという問題がある。[0005] In the third precious metal color, a protruding portion is matted to obtain an etching effect, and in order to prevent cracking of the precious metal layer during firing, a prosthetic color which is hardly melted is used in the protruding portion. There is a need. However, in this case,
There is a problem that the bonding property between the protruding portion and the noble metal layer is poor, voids are formed in the bonding surface, and chipping occurs in the precious metal color when handling ceramics.
【０００６】また，第３の盛貴金属彩の盛厚は１０〜２
０μｍ程度である。これ以上の盛厚も可能だが，盛貴金
属彩にさらに多くのチッピングが生じてしまう。そこ
で，実用強度の高い盛貴金属彩を得ようとすると，盛部
分に相互に熔融しやすい盛絵具を利用する必要がある。
しかし，この場合にはガラスフラックスは焼成時に熔融
状態となり，その表面に貴金属層を設けるとガラス層が
流動して不安定なため，貴金属層に割れが生じてしまう
という問題がある。本発明はかかる問題点に鑑み，盛り
が高く，耐久性，耐摩耗性に優れた，盛貴金属彩の盛部
分を形成することができる盛絵具を提供しようとするも
のである。[0006] The thickness of the third precious metal color is 10-2.
It is about 0 μm. Although thicker than this is possible, more chipping occurs on the precious metal motif. Therefore, in order to obtain a high-grade precious metal color with high practical strength, it is necessary to use a high-melting paint which easily melts in the high-rise portion.
However, in this case, the glass flux is in a molten state at the time of firing, and if a noble metal layer is provided on its surface, the glass layer flows and becomes unstable, so that there is a problem that the noble metal layer is cracked. The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a heaping paint having a high heap, excellent durability and abrasion resistance, and capable of forming a heap portion of a noble metal color.
【０００７】[0007]
【課題の解決手段】本発明は，陶磁器と貴金属層との間
に配置され該貴金属層を盛り上げるための盛絵具であっ
て，該盛絵具は，６０〜８０重量％のガラスフラックス
と２０〜４０重量％のジルコンとよりなることを特徴と
する盛絵具にある。本発明において上記盛絵具は，６０
〜８０重量％（以下％という。）のガラスフラックスと
２０〜４０％のジルコンとよりなる。SUMMARY OF THE INVENTION The present invention relates to a heap paint arranged between a ceramic and a noble metal layer for raising the noble metal layer, wherein the heap paint has a glass flux of 60 to 80% by weight and a glass flux of 20 to 40% by weight. A weight paint comprising zircon by weight. In the present invention, the heaping paint is 60
It consists of 80% by weight (hereinafter referred to as%) of glass flux and 20-40% of zircon.
【０００８】上記ガラスフラックスは，下記の組成より
なることが好ましい。即ち， 二酸化珪素 ４０〜５５重量％ 酸化ホウ素 ３〜１５重量％ 酸化アルミニウム ３〜１５重量％ 酸化鉛 ０〜３０重量％It is preferable that the glass flux has the following composition. That is, silicon dioxide 40 to 55% by weight Boron oxide 3 to 15% by weight Aluminum oxide 3 to 15% by weight Lead oxide 0 to 30% by weight
【０００９】Ｋ2 Ｏ，Ｎａ2 Ｏ，Ｌｉ2 Ｏのいずれか１
又は２種以上からなるＲ2 Ｏ １５重量％以下 酸化鉛（ＰｂＯ）を除く，ＣａＯ，ＢａＯ，ＭｇＯ，Ｚ
ｎＯのいずれか１又は２種以上からなるＲＯ １５重量％以下 ＳｎＯ2 ，ＴｉＯ2 ，ＺｒＯ2 のいずれか１又は２種以
上からなるＲＯ2 ２０重量％以下Any one of K 2 O, Na 2 O and Li 2 O
Or excluding comprising two or more R 2 O 15% by weight of lead oxide (PbO), CaO, BaO, MgO, Z
RO 15 wt% or less SnO 2 consisting of either one or two or more nO, TiO 2, consists of ZrO 2 of any one or two or more RO 2 20 wt% or less
【００１０】上記ジルコンは，ジルコン顔料を含有して
いることが好ましい。ジルコン顔料は，ＺｒＳｉＯ4 に
Ｐｒ（プラセオジウム），Ｖ（バナジウム），Ｆｅ
（鉄），Ｃｏ（コバルト），Ｃｒ（クロム）のいずれか
を固溶したものである。これにより，盛部分が貴金属色
を呈する。そのため，貴金属層が剥離したときにも，視
覚上剥離部分を目立たなくすることができる。上記盛絵
具を陶磁器の上に塗布することにより，盛部分が形成さ
れ，該盛部分は貴金属層により被覆されるため，上記盛
部分及び貴金属層は，盛貴金属彩を形成する。It is preferable that the zircon contains a zircon pigment. Zircon pigments to ZrSiO 4 Pr (praseodymium), V (vanadium), Fe
(Iron), Co (cobalt), or Cr (chromium) as a solid solution. As a result, the protruding portion exhibits a noble metal color. Therefore, even when the noble metal layer is peeled, the peeled portion can be made visually inconspicuous. A swelling portion is formed by applying the swelling paint on the porcelain, and the swelling portion is covered with a noble metal layer, so that the swelling portion and the noble metal layer form a noble metal color.
【００１１】上記盛貴金属彩を製造するに当たっては，
上記盛絵具と，貴金属層形成用の貴金属ペースト或いは
貴金属粉とを準備する。貴金属としては，金，プラチ
ナ，パラジウム等がある。その後，上記両者を陶磁器の
上に塗布し，焼成し，盛貴金属彩を形成する。該塗布方
法としては，転写紙使用法，直接描写法等がある。[0011] In producing the Sori noble metal color,
The above-mentioned paint and noble metal paste or noble metal powder for forming a noble metal layer are prepared. Noble metals include gold, platinum, palladium and the like. After that, both of the above are applied on porcelain and baked to form a noble metal color. Examples of the coating method include a method using a transfer paper and a direct drawing method.
【００１２】上記転写紙使用法とは，両者を転写紙の上
に塗布し，該転写紙を陶磁器の上に貼着し，焼き付け
て，盛貴金属彩を形成する方法である。一方，直接描写
法とは，スクリーン印刷或いは筆，刷毛等により，直接
陶磁器の上に上記両者を塗布して，盛貴金属彩を形成す
る方法である。上記焼成温度は，７５０〜９００℃が好
ましい。７５０℃未満では，盛絵具及び貴金属層が焼結
しないおそれがある。９００℃を越える場合には，貴金
属層に割れが生ずるとともに，光沢が悪くなるという問
題がある。The above-mentioned method of using transfer paper is a method in which both are coated on transfer paper, and the transfer paper is pasted on ceramics and baked to form a precious metal color. On the other hand, the direct depiction method is a method in which both of the above are applied directly on a ceramic by screen printing or a brush, a brush, or the like, thereby forming a precious metal color. The firing temperature is preferably 750 to 900 ° C. If the temperature is lower than 750 ° C., there is a possibility that the stencil and the noble metal layer do not sinter. If the temperature exceeds 900 ° C., there is a problem that cracks occur in the noble metal layer and gloss deteriorates.
【００１３】[0013]
【作用及び効果】本発明において，上記盛絵具は，上記
組成よりなる。従って，該盛絵具よりなる盛部分は，焼
成の際に流動せず安定している。そのため，盛部分の表
面に貴金属層を設けたときには，貴金属層の表面にひび
割れが生じない。また，ジルコンとガラスフラックスと
の熔融性がよいので，緻密な構造を有する盛部分を形成
することができる。さらに，ガラスフラックスの熔けが
よいため盛部分と貴金属層との接着が密となり，盛部分
と貴金属層とが優れた接合性を有するものとなる。よっ
て，陶磁器の取扱に際して盛貴金属彩にチッピングを生
じない。In the present invention, the above-mentioned heap paint has the above composition. Therefore, the swelling portion made of the sham paint does not flow during firing and is stable. Therefore, when the noble metal layer is provided on the surface of the embossed portion, no crack occurs on the surface of the noble metal layer. In addition, since zircon and the glass flux have good melting properties, a protruding portion having a dense structure can be formed. Further, since the glass flux is well melted, the adhesion between the protruding portion and the noble metal layer becomes dense, and the protruding portion and the noble metal layer have excellent bonding properties. Therefore, chipping does not occur in the precious metal colors when handling ceramics.
【００１４】また，上記盛絵具は，上記組成よりなるた
め，焼成時に盛部分が流動せず安定し，ジルコンとガラ
スフラックスとの熔融性がよく，３０μ〜６０μｍの盛
高の盛部分を形成することができる。従って，本発明に
よれば，盛りが高く，耐久性，耐摩耗性に優れた，盛貴
金属彩の盛部分を形成することができる盛絵具を提供す
ることができる。Further, since the above-mentioned paint has the above-mentioned composition, the protruding portion does not flow during firing and is stable, the meltability of zircon and glass flux is good, and a protruding portion having a protuberance of 30 μm to 60 μm is formed. be able to. Therefore, according to the present invention, it is possible to provide a heaping paint capable of forming a heaping portion of a noble metal color, which has a high embossment and is excellent in durability and abrasion resistance.
【００１５】[0015]
実施例１ 本発明にかかる実施例につき，図１を用いて説明する。
本例の盛絵具１０は，陶磁器９と貴金属層２との間に配
置されて，貴金属層２を盛り上げる。盛絵具１０は，７
８重量％のガラスフラックス１１と２２重量％のジルコ
ン１２とを有する。Embodiment 1 An embodiment according to the present invention will be described with reference to FIG.
The stencil 10 of the present example is arranged between the porcelain 9 and the noble metal layer 2 to excite the noble metal layer 2. Morning paint 10 is 7
It has 8% by weight of glass flux 11 and 22% by weight of zircon 12.
【００１６】盛絵具には，ペースト状にするためのオイ
ルが添加されている。オイルは，ガラスフラックス及び
ジルコンの合計重量１００重量部に対して４０重量部添
加される。ジルコン１２は，粒径２〜５μｍの粉体であ
る。上記ガラスフラックス１１は，表１に示す組成より
なる。[0016] An oil for making a paste is added to the heaping paint. The oil is added in an amount of 40 parts by weight based on 100 parts by weight of the total weight of the glass flux and the zircon. The zircon 12 is a powder having a particle size of 2 to 5 μm. The glass flux 11 has the composition shown in Table 1.
【００１７】盛部分１の盛高は，３０〜６０μｍであ
る。貴金属層２の厚みは，１〜５μｍである。上記盛絵
具１０を陶磁器９の上に塗布することにより，盛部分１
が形成される。該盛部分１は貴金属層２により被覆され
る。盛部分１及び貴金属層２は，盛貴金属彩１００を形
成する。The height of the embossed portion 1 is 30 to 60 μm. The thickness of the noble metal layer 2 is 1 to 5 μm. By applying the above-mentioned color paint 10 on the ceramic 9,
Is formed. The raised portion 1 is covered with a noble metal layer 2. The embossed portion 1 and the noble metal layer 2 form an embossed noble metal color 100.
【００１８】上記盛貴金属彩１００を製造するに当たっ
ては，まず，上記盛絵具１０と，貴金属層形成用の金ペ
ーストとを作製する。次に，上記両者を転写紙使用法に
より陶磁器９の上に塗布する。上記転写紙使用法とは，
両者を転写紙の上に厚み４５〜９０μｍに塗布し，その
後該転写紙を陶磁器９の上に貼着し，焼成して，盛貴金
属彩１００を形成する方法である。焼成温度は，８００
〜８５０℃である。In manufacturing the noble metal color 100, first, the high color paint 10 and a gold paste for forming a noble metal layer are prepared. Next, both of the above are applied onto the porcelain 9 by using a transfer paper. The above transfer paper usage is
Both are coated on a transfer paper to a thickness of 45 to 90 μm, and then the transfer paper is pasted on a porcelain 9 and fired to form a metal precious metal color 100. The firing temperature is 800
８850 ° C.
【００１９】次に，本例の作用効果について説明する。
本発明においては，上記盛絵具１０は，上記組成よりな
る。従って，該盛絵具１０よりなる盛部分１は，焼成の
際に流動せず安定している。そのため，盛部分１の表面
に貴金属層２を設けても，貴金属層２の表面のひび割れ
を防ぐことができる。また，ジルコン１２とガラスフラ
ックス１１との熔融性がよいので，緻密な構造を有する
盛部分１を形成することができる。それ故，盛部分１と
貴金属層２との接着が密となり，盛部分１と貴金属層２
とが優れた接合性を有するものとなる。よって，陶磁器
９の取扱に際して盛貴金属彩１００にチッピングを生じ
ない。Next, the operation and effect of this embodiment will be described.
In the present invention, the heaping paint 10 has the above composition. Therefore, the protruding portion 1 made of the prosthetic paint 10 is stable without flowing during firing. Therefore, even if the noble metal layer 2 is provided on the surface of the embossed portion 1, it is possible to prevent the surface of the noble metal layer 2 from cracking. In addition, since the zircon 12 and the glass flux 11 have good melting properties, the protruding portion 1 having a dense structure can be formed. Therefore, the adhesion between the embossed portion 1 and the noble metal layer 2 becomes dense, and the embossed portion 1 and the noble metal layer 2
Have excellent bonding properties. Therefore, chipping does not occur in the metal precious metal color 100 when the ceramics 9 is handled.
【００２０】また，上記盛絵具１０は，上記組成よりな
るため，焼成時に盛部分１が流動せず安定し，ジルコン
１２とガラスフラックス１１との熔融性がよく，３０μ
〜６０μｍの盛高の盛部分１を形成することができる。
従って，耐久性，耐摩耗性に優れた，立体的な盛貴金属
彩１００を形成することができる。上記ジルコン１２
は，ジルコン顔料（プラセオジム・イエロー）を含有し
ている。そのため，盛部分１が金色を呈する。それ故，
貴金属層２が剥離したときにも，視覚上剥離部分を目立
たなくすることができる。Further, since the above-mentioned paint 10 is composed of the above-mentioned composition, the protruding portion 1 does not flow during firing and is stable, the zircon 12 and the glass flux 11 have good melting properties, and
A protruding portion 1 having a protruding height of ６０60 μm can be formed.
Therefore, a three-dimensional metal precious metal color 100 excellent in durability and abrasion resistance can be formed. Zircon 12 above
Contains a zircon pigment (praseodymium yellow). Therefore, the protruding portion 1 has a golden color. Therefore,
Even when the noble metal layer 2 is peeled, the peeled portion can be made visually inconspicuous.
【００２１】実施例２ 本例の盛絵具は，７０％のガラスフラックスと２０％の
ジルコンと１０％のジルコン顔料（プラセオジム・イエ
ロー）とを有する。また，上記盛絵具により形成された
盛部分の盛高は，４０μｍである。その他は，実施例１
と同様である。Example 2 The heap paint of this example has 70% glass flux, 20% zircon and 10% zircon pigment (praseodymium yellow). The height of the protruding portion formed by the above-mentioned protruding paint is 40 μm. Others are described in Example 1.
Is the same as
【００２２】本例の盛部分と貴金属層とよりなる盛貴金
属彩の耐摩耗性評価を行った。該評価方法は，同一人物
がジルコンサンドペーパーを用いて盛貴金属彩を１０回
強く擦り，その後の盛貴金属彩の表面を観察するという
ものである。尚，比較のために，本例の盛絵具と類似し
た材料により形成された盛貴金属彩（比較例１），及び
金蒔き技法により形成された盛貴金属彩（比較例２）に
ついても，上記と同様の評価を行った。尚，両盛貴金属
彩は，本例と同様に形成されたものである。The abrasion resistance of the noble metal iris composed of the noble metal layer and the swelled portion of this example was evaluated. In this evaluation method, the same person rubs the noble metal color vigorously ten times using zircon sandpaper, and then observes the surface of the noble metal color. For comparison, the noble metal motif formed by a material similar to the lacquer paint of the present example (Comparative Example 1) and the noble metal motif formed by the gold plating technique (Comparative Example 2) are also described above. The same evaluation was performed. The Ryomori noble metal color was formed in the same manner as in this example.
【００２３】その結果を表３に示す。同表において，
「ＯＫ」とは，盛貴金属彩が無傷であることを示す。
「金摩耗」とは，貴金属層が薄くなった状態であること
を示す。「金剥離」とは，貴金属層が剥離し，下地が見
えてしまった状態であることを示す。「盛剥離」とは，
貴金属層だけでなく盛部分も剥離したことを示す。Table 3 shows the results. In the table,
"OK" indicates that Sori noble metal color is intact.
"Gold abrasion" indicates that the noble metal layer is thin. "Gold peeling" indicates a state in which the noble metal layer has peeled off and the underlayer has been visible. "Sheet peeling"
This shows that not only the noble metal layer but also the protruding portion was peeled off.
【００２４】表３より知られるように，本例の盛貴金属
彩は，擦り回数５０回までは，貴金属層が盛部分から剥
がれなかった。１００回目で，やや貴金属層の摩耗が生
じた。一方，比較例は，擦り回数１０回で貴金属層に剥
離が生じた。比較例１では，２０回で，盛貴金属彩の内
部の盛部分に剥離が発生した。これからも，本例の盛絵
具は，貴金属層との接合性に優れ，耐摩耗性に優れた，
盛部分を形成することが分かる。As is known from Table 3, the noble metal layer of the present example did not peel off the noble metal layer from the embossed portion up to 50 times of rubbing. At the 100th time, the abrasion of the noble metal layer occurred slightly. On the other hand, in the comparative example, the noble metal layer peeled off after rubbing 10 times. In Comparative Example 1, peeling occurred in the protruding portion inside the precious metal color after 20 times. From now on, the lacquer paint of this example has excellent bonding with the precious metal layer and excellent wear resistance.
It can be seen that a protruding portion is formed.
【００２５】[0025]
【表１】 [Table 1]
【００２６】[0026]
【表２】 [Table 2]
【図１】実施例にかかる，盛貴金属彩の断面図。FIG. 1 is a cross-sectional view of a precious metal color according to an embodiment.
１．．．盛部分， １０．．．盛絵具， １００．．．盛貴金属彩， １１．．．ガラスフラックス， １２．．．ジルコン， ２．．．貴金属層， ９．．．陶磁器， 1. . . Ascending part, 10. . . Morning paint, 100. . . Sori Noble Metal Aya, 11． . . Glass flux, 12. . . Zircon, 2. . . 8. noble metal layer, . . Porcelain,
Claims (2)
金属層を盛り上げるための盛絵具であって，該盛絵具
は，６０〜８０重量％のガラスフラックスと２０〜４０
重量％のジルコンとよりなることを特徴とする盛絵具。An embossing paint disposed between a ceramic and a noble metal layer for raising the noble metal layer, wherein the embossing paint has a glass flux of 60 to 80% by weight and a glass flux of 20 to 40% by weight.
Morite paint characterized by comprising zircon by weight.
ｉＯ4 ，あるいはＺｒＳｉＯ4 にＰｒ，Ｖ，Ｆｅ，Ｃ
ｏ，Ｃｒのいずれかを固溶させたジルコン顔料の，１種
または２種以上の混合物であることを特徴とする盛絵
具。2. The method according to claim 1, wherein the zircon is ZrS.
Pr, V, Fe, C on iO 4 or ZrSiO 4
A heap paint characterized by being one or a mixture of two or more zircon pigments in which either o or Cr is dissolved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4234313A JP2616352B2 (en) | 1992-08-10 | 1992-08-10 | Morning paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4234313A JP2616352B2 (en) | 1992-08-10 | 1992-08-10 | Morning paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0656558A JPH0656558A (en) | 1994-03-01 |
| JP2616352B2 true JP2616352B2 (en) | 1997-06-04 |
Family
ID=16969054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4234313A Expired - Fee Related JP2616352B2 (en) | 1992-08-10 | 1992-08-10 | Morning paint |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2616352B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011121849A (en) * | 2009-12-14 | 2011-06-23 | Noritake Co Ltd | Thickly decorated inorganic material corresponding to white porcelain |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3986321B2 (en) | 2002-02-19 | 2007-10-03 | 株式会社ノリタケカンパニーリミテド | Lead-free glass flux and painting material containing the flux |
| JP4014468B2 (en) | 2002-08-07 | 2007-11-28 | 株式会社ノリタケカンパニーリミテド | Lead-free glass flux and painting material containing the flux |
| DE102006002373B4 (en) | 2006-01-17 | 2009-06-18 | Duravit Ag | A method of making a ceramic or porcelain article coated with a layer of noble metal and a ceramic or porcelain article coated with such a layer |
| JPWO2023032532A1 (en) * | 2021-08-30 | 2023-03-09 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03126686A (en) * | 1989-09-28 | 1991-05-29 | Degussa Ag | Preparation of relief-like decoration on surface of ceramic and preparation therefor |
-
1992
- 1992-08-10 JP JP4234313A patent/JP2616352B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03126686A (en) * | 1989-09-28 | 1991-05-29 | Degussa Ag | Preparation of relief-like decoration on surface of ceramic and preparation therefor |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011121849A (en) * | 2009-12-14 | 2011-06-23 | Noritake Co Ltd | Thickly decorated inorganic material corresponding to white porcelain |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0656558A (en) | 1994-03-01 |
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