JP2607712Y2 - Delivery slip - Google Patents

Description

[Detailed description of the invention]

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a delivery slip used for parcel delivery parcels or postal parcels.

[0002]

2. Description of the Related Art A delivery slip is used for transportation and delivery of packages and parcels. This delivery slip is to be sent to the client when the package is received, a copy of the client, a copy of the shipping company, a copy at each transit point to the delivery destination, a delivery confirmation letter to get a confirmation stamp of the recipient of the delivery destination, affixed to the package When stacking several slips such as a luggage affixed slip with an adhesive layer, fix each side of the slips with an adhesive etc. to prevent these slips from falling apart, and also remove the slips one by one. Therefore, a perforation is provided as a separation line in the slip. This delivery slip is a package that retains a copy of the copy of the client and the copy of the shipping company, a copy of the copy at each transit point to the destination, and a delivery confirmation for receiving the confirmation of the recipient at the destination. Attach the attached slips to luggage or parcels, etc., and separate and store the slips one by one at each transit point, or separate and store the delivery confirmation certificate to get the recipient's confirmation seal for use. However, when separating the slip from the perforation, the slip may be torn if the slip is too thin, or if the slip is thick, or if the number of slips is large, the slipping slip with other luggage during delivery There is a problem of falling off. The paper thickness of the delivery slip usually used is 400 to 500 μm. Therefore, recently, in order to prevent slips from falling off, an envelope format that inserts and fixes a slip longer than the envelope in an open envelope, pulls the slip off the envelope, and separates the slip from the perforation in the envelope Delivery slips are also used. However, such a delivery slip has a problem that it is bulky and it takes time to separate the slip.

[0003] As a method of writing necessary information such as a delivery destination on a slip, pressure-sensitive recording paper such as carbonless paper is used for each slip, and the client is required to keep a copy of the top client. When characters such as required information such as delivery destination are written on the slip, the characters often move to the bottom slip, and if the number is large, if the pen pressure is weak, it will reach the bottom slip. Characters and information may not be transmitted. Also, when sending a lot of packages or parcels to the same destination, the printer may print necessary information such as the destination, but the letter or information may not be transferred to the bottom slip. There is also.

[0004]

[Problem to be Solved by the Invention] The present invention does not require the trouble of separating by hand from the perforation line of the separation line as in the past, and the slip due to the bulk of the slip even when pasted to luggage or parcels. The present invention is to provide a delivery slip in which characters and information do not move to the bottom slip due to handwriting or writing pressure when writing necessary information on a slip by a printer.

[0005]

According to the delivery slip of the present invention, a pressure-sensitive adhesive layer and a release sheet are sequentially laminated on one side of a base sheet, and a first synthetic resin layer and a second synthetic resin are formed on the other side. A delivery slip provided by sequentially laminating a layer and a surface substrate,
One of three interfaces among the four interfaces of the base material sheet, the first synthetic resin layer, the second synthetic resin layer and the surface substrate forms a peelable interface, which is a peelable interface. Has an adhesive force of 5 to 500 g / 25 mm, and has a surface substrate
A punching line is formed, and the punching line forms a surface base material.
A plurality of slips are formed separately in a plane.
The line is applied from the surface substrate side to the peeling interface, and the slip is peeled
A delivery slip that can be separated from an interface .

Since the interface between the surface substrate and the second synthetic resin layer forms a peeling interface, the first synthetic resin layer is a polyethylene resin layer serving as an adhesive synthetic resin layer, and the second synthetic resin layer is used as an adhesive synthetic resin layer. A polyolefin resin layer containing a silicone resin to be a release synthetic resin layer, wherein the adhesive force at the release interface is 5
It is good to set it to 500 g / 25 mm. Since the interface between the first synthetic resin layer and the second synthetic resin layer forms a peeling interface, the first synthetic resin layer is a polyethylene resin layer serving as an adhesive synthetic resin layer, and the second synthetic resin layer is A silicone resin layer or a polypropylene resin layer serving as a peelable synthetic resin layer, and the adhesive force at the peeling interface is preferably 5 to 500 g / 25 mm.

[0007] Since the interface between the base sheet and the first synthetic resin layer forms a peeling interface, the first synthetic resin layer is a polyolefin resin layer containing a silicone resin to be a peelable synthetic resin layer, It is preferable that the second synthetic resin layer is a polyethylene resin layer serving as an adhesive synthetic resin layer, and the adhesive force at the peeling interface be 5 to 500 g / 25 mm. Further, a polyethylene resin layer serving as an adhesive synthetic resin layer may be laminated by an extrusion lamination method. The first
It is preferable that at least one of the synthetic resin layer and the second synthetic resin layer is laminated by an extrusion lamination method. The slip on the surface substrate may be formed by printing general information and then printing necessary information such as a delivery destination by a printer or a copying machine.

[0008]

[Effect] In the delivery slip of the present invention, each piece of the surface base material with the punched line is a copy of the client, a copy of the shipping company, a copy at each transit point to the delivery destination, confirmation of the recipient of the delivery destination. This is a conventional single slip such as a delivery confirmation letter for receiving a seal. The materials of the surface base material and the base sheet used as the slip include papers, films, metal foils,
Laminates and the like are targets, but from the viewpoint of suitability for punching delivery slips, economics, and application purposes, both the surface base material and the base material sheet are often paper. However, other than papers are used for special applications.

[0009] The surface base material is used in accordance with the purpose of, for example, the material, thickness, surface properties and the like, and is preferably processed for printing or information recording. In particular, printing and recording are used for applications requiring precision, such as barcodes, and therefore must have sufficient suitability. The suitability includes, for example, whiteness, smoothness, gloss, strength, stiffness, coefficient of friction, curl stability, printability, recordability, storage stability, and the like.

[0010] The surface of the surface substrate or substrate sheet which is in contact with the releasable synthetic resin layer may be subjected to a treatment for reinforcing the strength or improving the releasability from the interface according to the purpose.
Further, the surface of the surface base material and the base material sheet which is in contact with the adhesive synthetic resin layer may be adjusted by coating treatment or printing treatment or the like so as to obtain the desired adhesive strength.

In order to selectively peel off from the interface between the surface base material and the second synthetic resin layer, when both the surface base material and the base sheet are made of paper, a polyethylene resin layer and a first synthetic resin layer are used as the first synthetic resin layer. A polyolefin resin layer containing a silicone resin is used as the synthetic resin layer of No. 2. With this configuration, the polyethylene resin layer becomes an adhesive synthetic resin layer to show adhesiveness to the base sheet and the polyolefin resin layer containing the silicone resin, and the polyolefin resin layer containing the silicone resin is Since it exhibits adhesiveness to the polyethylene resin layer but exhibits releasability to the surface substrate, it becomes a releasable synthetic resin layer, and the above-described selective peeling is possible.

In order to selectively peel off from the interface between the first synthetic resin layer and the second synthetic resin layer, a polyethylene resin layer is used as the first synthetic resin layer, and a polypropylene resin is used as the second synthetic resin layer. Layer or silicone resin layer. With this configuration, the polyethylene resin layer becomes an adhesive synthetic resin layer because it shows adhesiveness to the base sheet, and the polypropylene resin layer or the silicone resin layer shows adhesiveness to the surface base material. Since the polyethylene resin layer exhibits releasability, it becomes a releasable synthetic resin layer. Therefore, the above-described selective peeling is enabled.

In order to selectively peel off from the interface between the base sheet and the first synthetic resin layer, a polyolefin resin layer containing a silicone resin as the first synthetic resin layer;
A polyethylene resin layer is used as the second synthetic resin layer. With this configuration, the polyolefin resin layer containing the silicone resin exhibits adhesiveness to the polyethylene resin layer, but exhibits releasability to the base sheet, so that it becomes a peelable synthetic resin layer. The layer becomes an adhesive synthetic resin layer because it exhibits adhesiveness to the surface substrate and the polyolefin resin layer containing the silicone resin. Therefore, the above-described selective peeling is enabled.

[0014] The base sheet is desirably the minimum necessary from the economical point of view.
Workability of printing and recording is required.

Examples of the silicone resin include silicone oil, polyether-modified silicone, epoxy-modified silicone, amino-modified silicone, carboxyl-modified silicone, carbinol-modified silicone, mercapto-modified silicone, higher fatty acid ester-modified silicone,
Further, a reaction product of polymethyl hydrogen siloxane with a polyolefin resin having a double bond may be used.

As the polyolefin resin, polyethylene resin and polypropylene resin are used. Examples of the polyethylene resin include low-density polyethylene, linear low-density polyethylene, medium-density polyethylene, and high-density polyethylene. Of these, low-density polyethylene and linear low-density polyethylene resin are preferably used.

The delivery slip of the present invention is composed of one of the three interfaces among the four layers of the base material sheet, the first synthetic resin layer, the second synthetic resin layer, and the surface base material. Has an adhesive force of 5 to 500 g / 25 mm, more preferably 10 g / 25 mm.
４００400 g / 25 mm. This adhesive strength is 5g / 25
If it is less than mm, it becomes difficult to fix the surface substrate on the substrate sheet due to insufficient adhesive function, and slips of the surface substrate fall off from the base sheet in various processes for handling delivery slips, for example, However, there is a problem that accurate printing and recording cannot be performed, and a slip of the surface base material falls off during delivery after being attached to a baggage or the like. Conversely, 500g / 25m
If it exceeds m, the releasability will be poor, and the surface substrate will be damaged, making it difficult to use for slips and the like. The surface substrate side referred to here means only the surface substrate if it can be peeled from the interface between the surface substrate and the second synthetic resin layer, from the interface between the substrate sheet and the first synthetic resin layer. If it is peelable,
When it can be peeled off from the interface between the synthetic resin layer and the second synthetic resin layer, it refers to the surface substrate and the synthetic resin layer adhered thereto.

The adhesive force in the present invention is 25 mm.
The force applied when the surface base material side of the width delivery slip is peeled from the base material sheet side at an angle of 180 ° and a peeling speed of 300 mm / min is expressed in units of g / 25 mm.

The method of laminating the first synthetic resin layer and the second synthetic resin layer of the present invention includes, for example, a wet lamination method, a dry lamination method, a solvent lamination method, a hot melt lamination method, and an extrusion lamination method. Is mentioned. In particular, the extrusion lamination method is preferable. Temperature is 250 ° C ~
At 350 ° C., the speed is suitably adjusted within the range of 10 to 300 m / min, and the pressure is suitably adjusted within the range of ^{2 to 20} kg / cm ² .

The kind of the adhesive used in the delivery slip of the present invention is not particularly limited, and may be a solvent type, an emulsion type, a hot melt type, such as a rubber type, an acrylic type, and a silicone type. Etc. are used. In that case, a roll coater, a knife coater, a bar coater, a slot die coater or the like is used as a method of coating the release sheet, and the coating amount is adjusted in a range of about 5 to 50 g / m ² by dry weight. It is necessary to provide an adhesive force between the base sheet and the adherend that does not peel off when attached to an adherend such as luggage or parcel.

The release sheet is not particularly limited, and may be a high-density base paper such as glassine paper, a clay-coated paper, a kraft paper or a high-quality paper, a film-laminated paper such as polyethylene, a fluorine resin or a silicone. A resin or the like which is applied so as to have a dry weight of about 0.1 to 3 g / m ² and a release layer is provided by heat curing or ionizing radiation curing is appropriately used. As a coating apparatus in this case, a bar coater, an air knife coater, a direct gravure coater, an offset gravure coater, a multi-stage roll coater, or the like is appropriately used.

Examples of the apparatus for punching out the surface substrate to the peeling interface of the present invention and performing die cutting include a Victorian type of flat pressure type, a Thomson type, a Bobst type, a Heidel type of circular pressure type, and a Chambon type of rotary type. . Therefore, the delivery slip of the present invention is handled in the form of winding or plain paper.

The method of printing general information on the surface base material in advance can be performed before or after the punching step. As the printing method, for example, printing of specific characters, copy-forgery-inhibited patterns, ruled lines, patterns, numbering, barcodes, and the like include printing methods and printing methods such as offset printing, gravure printing, letterpress printing, screen printing, and flexographic printing. Various methods can be used for the printing ink and its drying, but UV printing using UV ink and drying by UV irradiation is preferred.

Further, as a method for displaying necessary information such as a delivery destination, a printing method as described above, or printing or recording and display using a recording device can be used. Among recording devices, there are various methods that can individually set information such as characters, numbers, figures, barcodes, and the like, for example, an ink jet method, an ink ribbon method, a thermal transfer method,
Printers and copiers of an electrophotographic system, a pressure-sensitive recording system, a heat-sensitive recording system, and the like are exemplified.

[0025]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described more specifically with reference to the following embodiments, but it is needless to say that the present invention is not limited thereto.

Example 1 First, as a release sheet, an adhesive (trade name “Nicazole L-14”) was put on a commercially available polyethylene laminated release paper.
5 ", Nippon Carbide Industrial Co., Ltd.) was applied so as to 20g / m ² in a reverse roll coater, dried, stuck a high-quality paper of basis weight 36g / m ² as the substrate sheet, high-quality paper While applying corona discharge treatment to
As the first synthetic resin layer, low-density polyethylene (trade name: "SHOLEX L182", manufactured by Showa Denko KK) was formed by extrusion lamination at a lamination temperature of 320 ° C to a thickness of 20 µm.

Next, on the back surface of a high quality paper (trade name: "high quality <55>", manufactured by Kanzaki Paper Co., Ltd.) of 64 g / m ² of U.S.P. A resin obtained by mixing a silicone resin obtained by reacting di-tert-butyl peroxide with gensiloxane and a vinyl group-containing polydimethylsiloxane as a catalyst and low-density polyethylene (trade name: "SHOLEX L182", manufactured by Showa Denko KK) Was formed at a lamination temperature of 295 ° C. to a thickness of 20 μm by an extrusion lamination method, and bonded to the above-mentioned structure to obtain a structure of a delivery slip.

With respect to the constituents of the delivery slip obtained in the first embodiment, a delivery slip was prepared as follows. Using a Thomson-type punching machine, a punching line was made only on the surface substrate of the delivery slip. Next, using a flexographic printing machine, UV printing is used on the surface of the delivery slip with a punched line, using a flexo printing machine, a package sticker , a copy for the client, a copy for the shipping company, a copy for the arrival at the store, and a delivery confirmation certificate. The information was printed and a delivery slip was obtained. FIG. 1 shows a sectional view of a part of the delivery slip of the first embodiment obtained in this way. FIG. 2 shows a plan view thereof.

Next, a method of using the delivery slip will be described with reference to FIGS.
This will be described with reference to FIG. First, the delivery slip obtained by the above method is passed through a printer, and the delivery destination, client,
Necessary information of the contents of the package, punched line on the surface base material, package affixing slip 21, customer copy 22, transportation company copy 23,
Printed on each slip of the store receipt 24 and delivery confirmation 25. Then, one piece of the surface base material to be the slip 22 for the client was peeled off from the first synthetic resin layer and passed to the client. Also, when carrying the cargo, peel off a piece of the surface base material that becomes the slip 23 of the shipping company's copy in the same manner as the copy of the client, store it as a copy of the shipping company, peel off the peeling sheet of the delivery slip, It was attached to the luggage using the adhesive layer. After that, the slip 24 of the store receipt is peeled off and stored at the waypoint where the package was delivered, and finally the recipient's confirmation mark is obtained on the delivery confirmation certificate 25,
Peeled off like other slips, stored and used. The baggage affixing slip 21 for clarifying the sender of the baggage is not peeled off,
It was kept affixed to the baggage.

The total paper thickness of the delivery slip obtained in Example 1 was 220 μm, and after the delivery slip was attached to the package, the surface base material, the first synthetic resin layer, the second synthetic resin layer,
Since the thickness of the base sheet was only used, the base sheet was not bulky, and the slip was not dropped because the front base material was fixed on the base sheet by the first synthetic resin layer and the second synthetic resin layer. . Further, by using the same polyethylene resin as the first synthetic resin layer for the second synthetic resin layer, the adhesive force between the two layers of polyethylene resin is strengthened, and the first synthetic resin layer and the second synthetic resin layer are used. It is strongly adhered to the layer, and the layer is torn if it is forcibly peeled off. In addition, the first synthetic resin layer and the base sheet are similarly strongly adhered to each other, and if the layer is forcibly peeled off, the layer is broken. Surface substrate and 2nd
Was adjusted to 200 g / 25 mm. Therefore, the interface between the surface substrate and the second synthetic resin layer becomes the peeling interface. With this level of adhesive strength, the surface base material does not float from the second synthetic resin layer when passing the paper through the printer. It could be printed.
Also, the slips of the client's copy, the shipping company copy, the store receipt copy, and the delivery confirmation certificate can be peeled off from the second synthetic resin layer without damaging the back of each slip, and the source of the package is clarified. The baggage affixed slip was stored on the baggage without falling off, so it could be used like a general slip.

Example 2 As a second synthetic resin layer, a silicone resin obtained by reacting polymethyl hydrogen siloxane with di-tert-butyl peroxide as a vinyl group-containing polydimethylsiloxane catalyst and polypropylene (trade name: "SHOW ALLOMER LS620") , Manufactured by Showa Denko KK), and a delivery slip was obtained and used in the same manner as in Example 1 except that a resin mixed with the resin was used.

At this time, the adhesive force between the surface substrate and the second synthetic resin layer is 100 g / 25 mm, and the adhesive force between the second synthetic resin layer and the first synthetic resin layer is 250 g / 25 mm.
However, since the adhesive force between the surface base material and the second synthetic resin layer is lower than the adhesive force between the first synthetic resin layer and the second synthetic resin layer, The interface with the synthetic resin layer of No. 2 serves as a peeling interface, and can be peeled off without damaging the back surface of each slip on the front surface substrate. Also, the first synthetic resin layer and the base sheet are strongly adhered to each other, and if they are forcibly peeled off, they will be broken. In addition, it could be used in the same manner as a general slip, similar to the first embodiment, in which there was no problem such as the slip of the slip. The paper thickness of the delivery slip was 220 μm. The sectional view of a part of the delivery slip of the second embodiment obtained in this way is the same as that of the first embodiment, and its plan view is also the same as FIG.

Example 3 As a first synthetic resin layer, low density polyethylene (trade name;
"Showrex L182", manufactured by Showa Denko KK
And using a polypropylene resin (trade name: "SHOW ALLOMER LS620" manufactured by Showa Denko KK) as the second synthetic resin layer, and punching a wire to the interface between the second synthetic resin layer and the first synthetic resin layer. A delivery slip was obtained and used in the same manner as in Example 1 except that the mark was put.

The polyethylene resin of the first synthetic resin layer is strongly adhered to the base sheet, and the polyethylene resin is torn if it is forcibly peeled off. Also, since the polypropylene resin of the second synthetic resin layer is adhered to the surface base material, the second synthetic resin layer and the surface base material are similarly strongly adhered to each other. Then, the substrate is broken. The adhesive force at the interface between the polyethylene resin layer and the polypropylene resin layer, which is a different type of resin, becomes the weakest. Therefore, the interface between the first synthetic resin layer and the second synthetic resin layer becomes a peeling interface, and peels off therefrom. did. At this time, the adhesive force between the first synthetic resin layer and the second synthetic resin layer was 250 g / 25 mm, which was the same as that of Example 1, and could be used like a general slip. The paper thickness of the delivery slip was 220 μm. FIG. 3 shows a cross-sectional view of a part of the delivery slip of the third embodiment thus obtained. The plan view is the same as FIG. 2 of the first embodiment.

Example 4 As the first synthetic resin layer, a silicone resin obtained by reacting di-tert-butyl peroxide with polymethyl hydrogen siloxane and vinyl group-containing polymethyl siloxane as a catalyst and low density polyethylene (trade name; Using a resin mixed with "SHOLEX L182" (manufactured by Showa Denko KK) and using a low density polyethylene (trade name: "SHOLEX L182", manufactured by Showa Denko KK) as the second synthetic resin layer, Example 1 except that a perforated line was formed up to the interface between the first synthetic resin layer and the base material sheet.
A delivery slip was obtained and used in the same manner as in.

At this time, the first synthetic resin layer and the second synthetic resin layer use the same polyethylene resin to increase the adhesive strength between the two layers of polyethylene resin, and the first synthetic resin layer and the second synthetic resin layer If it is forcibly peeled off from the second synthetic resin layer, the layer will be broken. In addition, since the second synthetic resin layer was completely adhered to the surface substrate, the interface between the first synthetic resin layer and the base sheet became a peel interface, and the second synthetic resin layer was peeled therefrom.
At this time, the adhesive force between the first synthetic resin layer and the base sheet is 20.
It was 0 g / 25 mm, and could be used in the same manner as in Example 1, like a general slip. The paper thickness of the delivery slip is 220μ.
m. FIG. 4 shows a cross-sectional view of a part of the delivery slip of the fourth embodiment obtained in this way. The plan view is the same as FIG. 2 of the first embodiment.

Comparative Example 1 A delivery slip was obtained and used in the same manner as in Example 1 except that the laminating temperature of the second synthetic resin layer was 300 ° C. At this time, each slip on the front substrate was tried to be peeled from the second synthetic resin layer, but the back face of the slip was damaged and could not be used as a slip. Also,
The adhesive strength between the surface substrate and the second synthetic resin layer is 750 g /
It was 25 mm.

Comparative Example 2 A delivery slip was obtained in the same manner as in Example 1 except that linear low-density polyethylene (trade name: "Moortec 0628D", manufactured by Idemitsu Petrochemical Co., Ltd.) was used as the second synthetic resin layer. ,used. At this time, each slip on the front substrate was tried to be peeled from the second synthetic resin layer, but the back face of the slip was damaged and could not be used as a slip. Further, the adhesive strength between the surface base material and the second synthetic resin layer could not be measured because the surface base material was broken.

Comparative Example 3 A low-density polyethylene (trade name;
"Showrex L182", manufactured by Showa Denko KK
Was produced and used in the same manner as in Example 3 except that the film was formed to a thickness of 20 μm by an extrusion lamination method while performing corona discharge on the back surface of the front substrate. At this time, each slip of the surface base material was tried to be peeled from the first synthetic resin layer, but the first synthetic resin layer and the second synthetic resin layer did not peel off in close contact and could be used as a slip. Did not. Further, the adhesive force between the first synthetic resin layer and the second synthetic resin layer could not be measured because they could not be separated because they were in close contact with each other.

When the front base material is peeled off as a slip as in Examples 1 and 2, there is no synthetic resin layer on the back surface as in the other examples, so that the touch by hand is good. There is.

[0041]

[Effects of the Invention] As is clear from the results of the embodiment, the delivery slip of the present invention does not have the problem that characters and information are not transferred to the bottom slip due to pen pressure even when printed by a printer or the like. Also, since the paper thickness of the delivery slip was 220 μm, which was about half the thickness of a normal delivery slip, there was no problem of slipping out of the slip due to bulkiness even when pasted on luggage or parcels. Since it was used after peeling from the layer, there was no need to separate the voucher from the perforation as in the past, and the back of the voucher after peeling was not damaged, so it could be used as a general voucher .

[0042]

[Brief description of the drawings]

FIG. 1 is a sectional view of a part of a delivery slip according to a first embodiment of the present invention.

FIG. 2 is a plan view of a delivery slip according to the first embodiment of the present invention.

FIG. 3 is a sectional view of a part of a delivery slip according to a third embodiment of the present invention;

FIG. 4 is a sectional view of a part of a delivery slip according to a fourth embodiment of the present invention.

[Explanation of symbols]

 1: Surface substrate 2: Second synthetic resin layer 3: First synthetic resin layer 4: Base sheet 5: Adhesive layer 6: Release sheet 7: Release interface 8: Punching line

──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-3-32893 (JP, A) JP-A-5-346676 (JP, A) JP-A-5-169595 (JP, A) 95682 (JP, U) (58) Field surveyed (Int. Cl. ⁷ , DB name) B42D 11/00

Claims (7)

(57) [Scope of request for utility model registration] 1. A pressure-sensitive adhesive layer and a release sheet are sequentially laminated on one side of a substrate sheet, and a first synthetic resin layer, a second synthetic resin layer and a surface substrate are sequentially laminated on the other side. A delivery slip, wherein one of three interfaces between the base material sheet, the first synthetic resin layer, the second synthetic resin layer, and the four layers of the surface base material is peelable. The peeling interface has an adhesive force of 5 to 500 g / 25 mm, and a punching line is formed on the surface substrate , and the punching line divides a plurality of slips on the surface substrate in a plane.
The delivery slip , wherein the punching line is formed from the surface base material side to the peeling interface, and the slip can be separated from the peeling interface . 2. The method according to claim 1, wherein the first synthetic resin layer is a polyethylene resin layer serving as an adhesive synthetic resin layer such that an interface between the surface substrate and the second synthetic resin layer forms a peeling interface. 2. The synthetic resin layer of No. 2 is a polyolefin resin layer containing a silicone resin to be a peelable synthetic resin layer, and the adhesive force at the peeling interface is 5 to 500 g / 25 mm.
Delivery slip described. 3. A polyethylene resin layer, wherein said first synthetic resin layer is an adhesive synthetic resin layer such that an interface between said first synthetic resin layer and said second synthetic resin layer forms a peeling interface. A silicone resin layer or a polypropylene resin layer, wherein the second synthetic resin layer is a peelable synthetic resin layer,
The delivery slip according to claim 1, wherein the peeling interface has an adhesive force of 5 to 500 g / 25 mm. 4. A polyolefin resin containing a silicone resin, wherein the first synthetic resin layer becomes a peelable synthetic resin layer so that an interface between the base sheet and the first synthetic resin layer forms a peeling interface. 2. The delivery slip according to claim 1, wherein the second synthetic resin layer is a polyethylene resin layer serving as an adhesive synthetic resin layer, and the adhesive force at the peeling interface is 5 to 500 g / 25 mm. 5. The delivery slip according to claim 2, wherein at least a polyethylene resin layer serving as an adhesive synthetic resin layer is laminated by an extrusion lamination method. 6. The delivery slip according to claim 1, wherein at least one of the first synthetic resin layer and the second synthetic resin layer is laminated by an extrusion lamination method. 7. The slip of the surface base material is formed by printing general information and then printing necessary information such as a delivery destination by a printer or a copying machine. Delivery slip described in.