JP2510067B2 - Disassembly method of waste rubber tires - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for disassembling a rubber tire. More specifically, it relates to a method for disassembling a rubber tire for disposal.

[0002]

2. Description of the Related Art Conventionally, used or discarded rubber tires have been crushed and recycled to be recycled as rubber products at a limited rate. Further, the regenerated rubber tire powder assists processing characteristics such as extrusion and rolling in the process of processing rubber products, but the ratio of additives is extremely small, and in the United States, it is only about 10% in new rubber raw materials. The actual situation is that% of the recycled rubber is exhausted.

However, environmental protection problems are increasing more and more, and it is a reality that old rubber tires must be treated.

[0004] As a cracking process of a waste rubber tire that has been applied so far, a method of generating fuel oil and a gas, and other 1000 ° C
As mentioned above, there is a method of advancing the reaction under high temperature and high pressure of 3 to 30 Kg / cm ² .

However, the following problems are found in the method of decomposing rubber at high temperature and high pressure. 1. A cracking reactor (crac) for generating high temperature and high pressure.
King reactor) manufacturing investment is enormous.

2. In the decomposition process, a large amount of combustible gas such as hydrogen; a low hydrocarbon compound gas containing methane, ethane, propane, butane, isobutane, butylene, etc. is generated. Combustible gas generated from a high temperature and high pressure reactor is a very dangerous substitute from the viewpoint of industrial safety. For example, the ignition point of hydrogen is 585 ° C, methane is 537 ° C, and ethane is 51 ° C.
5 ℃, etc. is lower than about 1000 ℃, and the reaction temperature is 10
Leakage of these gases from a reactor that exceeds 00 ° C easily causes spontaneous accidents such as fires and explosions, which is a detriment to the workplace environment. Therefore, not only must careful attention be paid to the operation of the reactor, but also the operation becomes more difficult and costly.

3. Wastes valuable energy because the decomposition reaction occurs at high temperatures.

From the above viewpoint, the appearance of a method of decomposing rubber under low temperature and low pressure is awaited.

An object of the present invention is to provide a novel method for disassembling a waste rubber tire.

Still another object of the present invention is to use mica (mica) as a catalyst at a temperature of 230 to 400 ° C. and 1 to 2.5.
A method of decomposing rubber tires or rubber products under atmospheric pressure to obtain oil, carbon, black, gas, and other residues, and decomposing waste rubber tires or other rubber products safely and economically. To provide.

[0011]

According to the present invention, a) washed and crushed waste rubber tires are crushed into rubber, and b) the crushed rubber, sericite and muscovite (MU).
210 at least one mica catalyst selected from the group consisting of SCOVITE) and biotite (BIOTITE).
Heat to ℃ to mix, c) Heat for 1 hour, 1-2.5
A gas phase product (Vapo-phas) containing a gas product and a mixed oil while maintaining a temperature of 230 to 400 ° C. at atmospheric pressure (Atm).
e-product) and the mica having a catalytic amount of 2 to 3% with respect to the total amount (100%) of a waste rubber tire supplied to a decomposition reaction so as to obtain a decomposed product containing a carbon black and a solid product containing a residue. The present invention relates to a method for decomposing a waste rubber tire, which comprises dry-distilling the rubber pulverized product in the presence of a catalyst to decompose it, and further d) separating the decomposed product into a gas product, a mixed oil, carbon black and a residue. In the present invention, the mica catalyst is preferably sericite powder.

The attached drawings are a flow chart showing the manufacturing process of the present invention. The contents of the present invention will be described below with reference to the accompanying drawings.

A) Cleaning of waste rubber tires 1: Rubber tires including various tubes and other rubber products are washed with water or the like.

B) Grind the washed rubber tire 2: Or cut or grind the tire to about 5 cm x 5 cm.

C) The decomposed rubber particles are thoroughly mixed with powdered mica catalyst in a mixer 3: Preheated to 210 ° C.

D) The resulting mixture is sent to a closed reactor and decomposed by destructive distillation. 4: Rubber particles mixed with a mica catalyst are heated and kept at a temperature of 230 to 400 ° C.
The decomposition reaction is performed at 2.5 atmospheric pressure (Atm). The decomposition reaction is 2
It starts at 30 ° C and is most intense at 350 ° C with a maximum temperature of 400 ° C being sufficient. Since the reaction pressure is 1 to 2.5 atm, the gas generated by the decomposition reaction does not inhale other inert gas (Inert) such as nitrogen.

E) Gas phase products (Va
Po-phase-product 5 is a gas product 51
And the mixed oil 52 is decomposed into the mixed oil 52.
It is decomposed into light oil (Light oil) and gasoline 71, petroleum (Kerosene) 72, diesel oil 73 and heavy oil 74 by means of the actionable distribution 7.

F) After the decomposition reaction 4, the solid product 6 is placed in the reaction vessel.
Left behind, carbon black 61, steel wire (steel)
(wire) 62 and other residues 63.

The catalyst used in the present invention is muscovite (MU).
SCOVITE), sericite (SERICITE), and at least one selected from biotite (BIOTITE)
Among them, sericite is the most preferable. The chemical formula of sericite is KA
1 ₂ (AlSiO ₃ O ₁₀ ) (OH) ₂ with the following component weight ratio (%).

SiO ₂ ----- 47.65% Al ₂ O ₃ --- 37.03% K ₂ O --- 9.02% TiO ₂ --- 0.10% Fe ₂ O _{3 --- 0.01% MgO ----- 0.04% Na} 2 O ---- 0.76% H 2 O ----- 0.73~4.97% P 2 O 5 - --0.02% FeO, MnO and CaO-- Traces The amount of catalyst used is 2-3% of the total weight of the waste rubber.

The mixed oil is light oil,
It is used as a fuel oil which is a mixed oil as it is without having to re-separate into gasoline, petroleum (Kerosene), diesel oil and heavy oil, and is separated into various oils through fractional distillation if necessary.

Gas products are hydrogen; low hydrocarbon compounds including methane, propane, butane, butylene, carbon monoxide,
Contains carbon dioxide and other trace gas products such as sulfur.

Sulfur is included due to the addition of sulfur during the vulcanization process of rubber during the production of tires. Gaseous products are also used as fuels, but with large amounts of isobutylene and butylene contained therein, the re-separation makes them useful materials, eg for butyl rubber.

The waste rubber tires that can be treated in the present invention are mainly tires having a steel wire (Sreeel wire),
Other included tires, tubes or natural or synthetic rubber products may be included. A rubber tire containing a steel wire has a steel wire left as a solid component by fracture carbonization.

[0025]

EXAMPLES Next, the present invention will be described in detail based on the following examples.

Example 1 6680 g of a tire tube crushed to a size of about 5 × 5 cm was placed in a 32 liter autoclave equipped with an intermittent stirrer, 150 g of sericite was added as a catalyst, and the autoclave was gradually heated to 230 ° C. for decomposition reaction. Let it be done.
The temperature of the decomposition reaction was between 230 and 400 ° C., the pressure was kept at an absolute pressure of 1 to 2.5 pressure (Atm), and the reaction was performed for 1 hour. The products listed in Table 1 were obtained when the reaction was complete.

[0027]

Table 1 Product Weight (g) Weight (%) Gas product 1400 21 Mixed oil 2280 34 Carbon black and residue 2850 43 Moisture 150 2 The mixed oil was further fractionated to obtain the product shown in Table 2.

[0028]

[Table 2] Oil (distillation temperature range) Weight (g) Weight (%) Light oil, 50 to 186 ° C 370 16 (normal pressure fractionation) Gasoline 376 16.6 (500 mmHg, under vacuum) Petroleum (Kerosene) 310 14 ( 500 mmHg, Vac) Diesel oil 810 36 (500 mmHg, Vac) Heavy oil 385 17.4 The gas product was analyzed and the results in Table 3 were obtained.

[0029]

Table 3 Gas Volume (%) Hydrogen 12 Methane 20.59 Ethane 4.42 Ethylene 1.07 Propane 2.85 Propylene 1.66 Isobutane 5.13 Isobutylene and Butylene-1 45.3 Butylene-2 0.04 n -Pentane 0.15 Pentylene 0.49 CO ₂ 4.54 CO 1.65 Among the gaseous products of Table 3, the volume of isobutylene and butylene-2 account for 45.3% of the total, which is also a useful industrial product. Can be separated into

Example 2 In the same manner as in Example 1, a tire containing steel wire instead of the tire tube was put into a pressure cooker. The composition of the product is shown in Table 4. In Table 4, Example 1
Data is also shown and used for comparison.

[0031]

[Table 4] Product Example 2 Example 1 Gas product 12% 21% Mixed oil 50% 34% Carbon black 32% 43% and residual moisture 2% 2% Steel wire 4% -Steel wire as shown in Table 4 It can be seen that the product decomposed from the rubber tire containing (Steel wire) contained more oil and contained less gas product than the product decomposed from the tire tube containing no steel wire.

After fractionating the mixed oil regardless of Example 1 or Example 2, the composition (weight) ratio is almost the same as shown in Table 5.

[0033]

Oils Example 1 Example 2 Light oil / gasoline 32.6 33 Petroleum 14 15.5 Diesel oil 36 35 Heavy oil 17.4 16.5 Produced by the process of the invention as can be seen from the data in Table 5. The product is a useful and safe fuel, which prevents waste tires from being abandoned and wasted, and can convert waste products into valuable oils, gases and carbon black, which can be used to recycle resources. Available.

[0034]

As described above, the present invention decomposes rubber tires to be discarded by a new treatment method and converts them into useful and valuable products. effective.

1. Since the decomposition reaction is carried out at low temperature and low pressure,
The reaction is safer (note: only 4 according to the invention
At 00 ° C, it is safer than conventional methods because it is lower than the ignition point of hydrogen, methane and ethane mentioned above).

2. Since the reaction conditions are low temperature and low pressure, the cost of manufacturing, operation, operation, maintenance, etc. are low, and the consumption of resources is small.

3. Preventing or reducing air pollution by reducing the possibility of gas leaking from the reactor or manufacturing system due to the low reaction pressure.

It should be noted that the present invention does not limit appropriate modification or alteration unless it contradicts the scope of the claims.

Further, other polymers and fusion products can be decomposed by the method of the present invention.

[Brief description of drawings]

FIG. 1 is a flowchart showing an example of a manufacturing method of the present invention.

[Explanation of symbols]

1 --- Washing process of waste rubber tire, 2 --- Process of crushing washed rubber tire, 3-- Process of mixing decomposed rubber with mica catalyst, preheating, and 4-decomposing rubber Process.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification code Internal reference number FI technical display location C10J 3/00 B09B 3/00 302B 302A

Claims (2)

(57) [Claims] 1. A) washing and crushing a waste rubber tire to obtain a crushed rubber, and b) the crushed rubber and at least one mica catalyst selected from the group consisting of sericite, muscovite and biotite. 210
Heat to ℃ to mix, c) Heat for 1 hour, 230-400 at 1-2.5 atm.
The total amount of the waste rubber tires supplied to the decomposition reaction so as to obtain the gas phase product containing the gas product and the mixed oil and the decomposed product containing the carbon black and the solid product containing the residue while maintaining the temperature of 100 ° C. (100 %) To dry decompose the rubber pulverized product in the presence of the catalyst having a catalytic amount of 2 to 3%, and d) separate the decomposed product into a gas product, a mixed oil, carbon black and a residue. A method for disassembling a waste rubber tire, which comprises: 2. The mica catalyst is sericite powder.
The method described in.