JP2024011405A - Resin composition, and molded product of the resin composition - Google Patents
Resin composition, and molded product of the resin composition Download PDFInfo
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- JP2024011405A JP2024011405A JP2022113352A JP2022113352A JP2024011405A JP 2024011405 A JP2024011405 A JP 2024011405A JP 2022113352 A JP2022113352 A JP 2022113352A JP 2022113352 A JP2022113352 A JP 2022113352A JP 2024011405 A JP2024011405 A JP 2024011405A
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- Prior art keywords
- acid
- resin composition
- weight
- resin
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011342 resin composition Substances 0.000 title claims abstract description 63
- 239000003063 flame retardant Substances 0.000 claims abstract description 53
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 52
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 52
- 229920005989 resin Polymers 0.000 claims abstract description 44
- 239000011347 resin Substances 0.000 claims abstract description 44
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 41
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 41
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract 5
- 239000000463 material Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 229920005992 thermoplastic resin Polymers 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- PWZFXELTLAQOKC-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O PWZFXELTLAQOKC-UHFFFAOYSA-A 0.000 description 47
- 150000003839 salts Chemical class 0.000 description 24
- 229910052751 metal Inorganic materials 0.000 description 23
- 239000002184 metal Substances 0.000 description 23
- -1 polypropylene, ethylene-vinyl chloride copolymer Polymers 0.000 description 20
- 239000003381 stabilizer Substances 0.000 description 18
- 239000011701 zinc Substances 0.000 description 16
- 239000011777 magnesium Substances 0.000 description 14
- 150000007524 organic acids Chemical class 0.000 description 12
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 10
- 239000001993 wax Substances 0.000 description 10
- 239000011575 calcium Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 8
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 7
- 239000000654 additive Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- 239000004014 plasticizer Substances 0.000 description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 235000021314 Palmitic acid Nutrition 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 229940071120 dehydroacetate Drugs 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- 239000004808 2-ethylhexylester Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- MNUOZFHYBCRUOD-UHFFFAOYSA-N hydroxyphthalic acid Natural products OC(=O)C1=CC=CC(O)=C1C(O)=O MNUOZFHYBCRUOD-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- CKMXAIVXVKGGFM-UHFFFAOYSA-N p-cumic acid Chemical compound CC(C)C1=CC=C(C(O)=O)C=C1 CKMXAIVXVKGGFM-UHFFFAOYSA-N 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- RVHSTXJKKZWWDQ-UHFFFAOYSA-N 1,1,1,2-tetrabromoethane Chemical compound BrCC(Br)(Br)Br RVHSTXJKKZWWDQ-UHFFFAOYSA-N 0.000 description 1
- AHBGXHAWSHTPOM-UHFFFAOYSA-N 1,3,2$l^{4},4$l^{4}-dioxadistibetane 2,4-dioxide Chemical compound O=[Sb]O[Sb](=O)=O AHBGXHAWSHTPOM-UHFFFAOYSA-N 0.000 description 1
- DYAWZSJFAXDKFJ-UHFFFAOYSA-N 1,3-bis(4-octylphenyl)propane-1,3-dione Chemical compound C1=CC(CCCCCCCC)=CC=C1C(=O)CC(=O)C1=CC=C(CCCCCCCC)C=C1 DYAWZSJFAXDKFJ-UHFFFAOYSA-N 0.000 description 1
- CWWFKNYDPAANEP-UHFFFAOYSA-N 1-(4-methoxyphenyl)-3-phenylpropane-1,3-dione Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=CC=C1 CWWFKNYDPAANEP-UHFFFAOYSA-N 0.000 description 1
- LRQGFQDEQPZDQC-UHFFFAOYSA-N 1-Phenyl-1,3-eicosanedione Chemical compound CCCCCCCCCCCCCCCCCC(=O)CC(=O)C1=CC=CC=C1 LRQGFQDEQPZDQC-UHFFFAOYSA-N 0.000 description 1
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- RIZUCYSQUWMQLX-UHFFFAOYSA-N 2,3-dimethylbenzoic acid Chemical compound CC1=CC=CC(C(O)=O)=C1C RIZUCYSQUWMQLX-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- DVVXXHVHGGWWPE-UHFFFAOYSA-N 2-(dimethylamino)benzoic acid Chemical compound CN(C)C1=CC=CC=C1C(O)=O DVVXXHVHGGWWPE-UHFFFAOYSA-N 0.000 description 1
- FUVXVCHHAJCSSO-UHFFFAOYSA-N 2-[4-[3-[4-(carboxymethyl)phenyl]-3-oxopropanoyl]phenyl]acetic acid Chemical compound C1=CC(CC(=O)O)=CC=C1C(=O)CC(=O)C1=CC=C(CC(O)=O)C=C1 FUVXVCHHAJCSSO-UHFFFAOYSA-N 0.000 description 1
- CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical compound CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 description 1
- YSJWNEDBIWZWOI-UHFFFAOYSA-N 2-hydroxy-3,4-dimethylbenzoic acid Chemical compound CC1=CC=C(C(O)=O)C(O)=C1C YSJWNEDBIWZWOI-UHFFFAOYSA-N 0.000 description 1
- GADSJKKDLMALGL-UHFFFAOYSA-N 2-propylbenzoic acid Chemical compound CCCC1=CC=CC=C1C(O)=O GADSJKKDLMALGL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 1
- YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 1
- WGLQHUKCXBXUDV-UHFFFAOYSA-N 3-aminophthalic acid Chemical compound NC1=CC=CC(C(O)=O)=C1C(O)=O WGLQHUKCXBXUDV-UHFFFAOYSA-N 0.000 description 1
- BKFXSOCDAQACQM-UHFFFAOYSA-N 3-chlorophthalic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1C(O)=O BKFXSOCDAQACQM-UHFFFAOYSA-N 0.000 description 1
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- QHZLMUACJMDIAE-UHFFFAOYSA-N Palmitic acid monoglyceride Natural products CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000003490 Thiodipropionic acid Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229920001895 acrylonitrile-acrylic-styrene Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910000411 antimony tetroxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
- 239000004842 bisphenol F epoxy resin Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- ZNFNDZCXTPWRLQ-UHFFFAOYSA-N butane-1,1,1-tricarboxylic acid Chemical compound CCCC(C(O)=O)(C(O)=O)C(O)=O ZNFNDZCXTPWRLQ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- BMFYCFSWWDXEPB-UHFFFAOYSA-N cyclohexyl(phenyl)methanone Chemical compound C=1C=CC=CC=1C(=O)C1CCCCC1 BMFYCFSWWDXEPB-UHFFFAOYSA-N 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007706 flame test Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- ZBRRLVWJAPULGW-UHFFFAOYSA-N henicosane-2,4-dione Chemical compound CCCCCCCCCCCCCCCCCC(=O)CC(C)=O ZBRRLVWJAPULGW-UHFFFAOYSA-N 0.000 description 1
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910001853 inorganic hydroxide Inorganic materials 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000019303 thiodipropionic acid Nutrition 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
本発明は樹脂組成物、および、該樹脂組成物を用いた成形体に関する。 The present invention relates to a resin composition and a molded article using the resin composition.
電線、ケーブル等の被覆材には、塩化ビニル樹脂等の合成樹脂を含む樹脂組成物が用いられている。これらの用途には、耐熱性、および、難燃性が要求される。そのため、例えば、塩化ビニル樹脂に、安定剤、および、難燃剤を添加した組成物が用いられている。難燃剤としては、三酸化アンチモン、五酸化アンチモン等のアンチモン系難燃剤、水酸化アルミニウム、水酸化マグネシウム等の金属水和物、ホウ酸亜鉛等が用いられる。これらの難燃剤を、多量に添加することで、高難燃化された組成物とすることができることが知られている。なかでもアンチモン系難燃剤は難燃性に優れており、例えば高い難燃性が要求される電線の外皮材(被覆材)等にも好適に用いられている(特許文献1)。アンチモンは重金属であるため環境汚染等が懸念され、規制が進められている。そのため、アンチモン系難燃剤の使用量を低減し、かつ、高い難燃性を有する樹脂組成物が求められている。 Resin compositions containing synthetic resins such as vinyl chloride resin are used for covering materials such as electric wires and cables. These uses require heat resistance and flame retardancy. Therefore, for example, a composition in which a stabilizer and a flame retardant are added to vinyl chloride resin is used. As the flame retardant, antimony-based flame retardants such as antimony trioxide and antimony pentoxide, metal hydrates such as aluminum hydroxide and magnesium hydroxide, zinc borate, and the like are used. It is known that by adding a large amount of these flame retardants, a highly flame retardant composition can be obtained. Among these, antimony-based flame retardants have excellent flame retardancy, and are suitably used, for example, in outer covering materials (coating materials) for electric wires that require high flame retardancy (Patent Document 1). Since antimony is a heavy metal, there are concerns about environmental pollution, and regulations are being implemented. Therefore, there is a need for a resin composition that reduces the amount of antimony-based flame retardant used and has high flame retardancy.
本発明は上記課題を解決するためになされたものであり、その主たる目的は、アンチモン系難燃剤の添加量を低減し、かつ、高い難燃性を有する樹脂組成物を提供することにある。 The present invention has been made to solve the above problems, and its main purpose is to reduce the amount of antimony-based flame retardant added and to provide a resin composition that has high flame retardancy.
1.本発明の実施形態の樹脂組成物は、樹脂を100重量部と、該樹脂100重量部に対して、式(1)で表されるハイドロタルサイトを3重量部以上と、アンチモン系難燃剤を5重量部以下と、を含む:
MgxAl2(OH)yCO3・nH2O (1)
(式中、xは4.3以上の数であり、yは12.6以上の数であり、nは3.0以上の数である)。
2.上記1.に記載の樹脂組成物において、上記式(1)で表されるハイドロタルサイトは、Mg4.5Al2(OH)13CO3・3.5H2O、または、Mg6.0Al2(OH)16CO3・4H2Oであってもよい。
3.上記1.または2.に記載の樹脂組成物において、上記式(1)で表されるハイドロタルサイトは、Mg4.5Al2(OH)13CO3・3.5H2Oであってもよい。
4.上記1.から3.のいずれかに記載の樹脂組成物において、樹脂組成物は、上記式(1)で表されるハイドロタルサイトを3重量部~60重量部含んでいてもよい。
5.上記1.から4.のいずれかに記載の樹脂組成物において、上記樹脂は、熱可塑性樹脂であってもよい。
6.1つの実施形態において、成形体が提供される。この成形体は上記1.から5.のいずれかに記載の樹脂組成物からなる。
7.1つの実施形態において、被覆材が提供される。この被覆材は上記1.から5.のいずれかに記載の樹脂組成物を用いてなる。
8.1つの実施形態において、電線が提供される。この電線は上記7.に記載の被覆材で被覆されている。
1. The resin composition of the embodiment of the present invention contains 100 parts by weight of a resin, 3 parts by weight or more of hydrotalcite represented by formula (1), and an antimony-based flame retardant based on 100 parts by weight of the resin. 5 parts by weight or less:
Mg x Al 2 (OH) y CO 3・nH 2 O (1)
(In the formula, x is a number of 4.3 or more, y is a number of 12.6 or more, and n is a number of 3.0 or more).
2. Above 1. In the resin composition described in , the hydrotalcite represented by the above formula (1) is Mg 4.5 Al 2 (OH) 13 CO 3 ·3.5H 2 O, or Mg 6.0 Al 2 ( OH) 16 CO 3 .4H 2 O may be used.
3. Above 1. or 2. In the resin composition described in , the hydrotalcite represented by the above formula (1) may be Mg 4.5 Al 2 (OH) 13 CO 3 ·3.5H 2 O.
4. Above 1. From 3. In the resin composition according to any one of the above, the resin composition may contain 3 parts by weight to 60 parts by weight of hydrotalcite represented by the above formula (1).
5. Above 1. From 4. In the resin composition according to any one of the above, the resin may be a thermoplastic resin.
6. In one embodiment, a shaped body is provided. This molded body is the same as described in 1. From 5. It consists of a resin composition according to any one of the above.
7. In one embodiment, a dressing is provided. This covering material is the same as described in 1. From 5. The resin composition according to any one of the above is used.
8. In one embodiment, an electrical wire is provided. This electric wire is the same as described in 7. Covered with the coating material described in .
本発明の実施形態の樹脂組成物によれば、アンチモン系難燃剤の添加量を低減し、かつ、高い難燃性を有する樹脂組成物を提供することができる。また、アンチモン系難燃剤の添加量を低減させることができるため、重金属による環境汚染も抑制し得る。 According to the resin composition of the embodiment of the present invention, it is possible to reduce the amount of antimony-based flame retardant added and to provide a resin composition having high flame retardancy. Furthermore, since the amount of antimony-based flame retardant added can be reduced, environmental pollution caused by heavy metals can also be suppressed.
以下、本発明の実施形態について説明するが、本発明はこれらの実施形態には限定されない。 Embodiments of the present invention will be described below, but the present invention is not limited to these embodiments.
A.樹脂組成物
本発明の樹脂組成物は、樹脂を100重量部と、該樹脂100重量部に対して、式(1)で表されるハイドロタルサイトを3重量部以上と、アンチモン系難燃剤を5重量部以下と、を含む。本発明の実施形態の樹脂組成物は、式(1)で表されるハイドロタルサイトを含む。このハイドロタルサイトを含む樹脂組成物は、アンチモン系難燃剤の添加量が低減され、かつ、高い難燃性を有し得る。
MgxAl2(OH)yCO3・nH2O (1)
(式中、xは4.3以上の数であり、yは12.6以上の数であり、nは3.0以上の数である)。
A. Resin Composition The resin composition of the present invention contains 100 parts by weight of a resin, 3 parts by weight or more of hydrotalcite represented by formula (1), and an antimony flame retardant based on 100 parts by weight of the resin. 5 parts by weight or less. The resin composition of the embodiment of the present invention contains hydrotalcite represented by formula (1). The resin composition containing this hydrotalcite has a reduced amount of antimony-based flame retardant added and can have high flame retardancy.
Mg x Al 2 (OH) y CO 3・nH 2 O (1)
(In the formula, x is a number of 4.3 or more, y is a number of 12.6 or more, and n is a number of 3.0 or more).
B.樹脂
樹脂としては、任意の適切な樹脂を用いることができる。例えば、熱可塑性樹脂、および、熱硬化性樹脂が挙げられる。好ましくは熱可塑性樹脂が用いられる。熱可塑性樹脂としては、任意の適切な樹脂を用いることができる。例えば、ポリ塩化ビニル、ポリ塩化ビニリデン、塩素化ポリエチレン、塩素化ポリプロピレン、エチレン-塩化ビニル共重合体、エチレン-塩化ビニル-酢酸ビニルグラフト共重合体、塩化ビニル-プロピレン共重合体等の塩化ビニル系樹脂、ポリエチレン、ポリプロピレン、エチレン-プロピレン共重合体、ポリブテン、ポリ(4-メチルペンテン-1)等のC2~C8(炭素数2~8の)オレフィン(α-オレフィン)重合体またはこれらの共重合体、これらC2~C8オレフィンとジエンとの共重合体等のポリオレフィン系樹脂、ポリスチレン、ABS樹脂、AAS樹脂、AS樹脂、MBS樹脂等のスチレン系樹脂、ウレタン系樹脂等が挙げられる。好ましくは塩化ビニル系樹脂が用いられる。熱可塑性樹脂は1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。
B. Resin Any suitable resin can be used as the resin. Examples include thermoplastic resins and thermosetting resins. Preferably, thermoplastic resin is used. Any suitable resin can be used as the thermoplastic resin. For example, vinyl chloride systems such as polyvinyl chloride, polyvinylidene chloride, chlorinated polyethylene, chlorinated polypropylene, ethylene-vinyl chloride copolymer, ethylene-vinyl chloride-vinyl acetate graft copolymer, vinyl chloride-propylene copolymer, etc. C2 to C8 (having 2 to 8 carbon atoms) olefin (α-olefin) polymers such as resin, polyethylene, polypropylene, ethylene-propylene copolymer, polybutene, poly(4-methylpentene-1), or copolymers thereof Examples include polyolefin resins such as copolymers of these C2 to C8 olefins and dienes, styrene resins such as polystyrene, ABS resins, AAS resins, AS resins, and MBS resins, and urethane resins. Preferably, vinyl chloride resin is used. Only one type of thermoplastic resin may be used, or two or more types may be used in combination.
熱硬化性樹脂としては、任意の適切な樹脂を用いることができる。例えば、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂等のエポキシ樹脂、ノボラックフェノール樹脂、ポリオキシスチレン等のフェノール樹脂、ブチル化メラミン樹脂等のメラミン樹脂、尿素樹脂、不飽和ポリエステル樹脂、ビスマレイミド樹脂、ウレタン系樹脂等が挙げられる。熱硬化性樹脂は1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。 Any suitable resin can be used as the thermosetting resin. For example, epoxy resins such as bisphenol A epoxy resin and bisphenol F epoxy resin, phenolic resins such as novolak phenol resin and polyoxystyrene, melamine resins such as butylated melamine resin, urea resin, unsaturated polyester resin, and bismaleimide resin. , urethane resins, etc. Only one type of thermosetting resin may be used, or two or more types may be used in combination.
C.アンチモン系難燃剤
アンチモン系難燃剤としては任意の適切なアンチモン系難燃剤を用いることができる。例えば、三酸化アンチモン、四酸化アンチモン、五酸化アンチモン、アンチモン酸ナトリウム等が挙げられる。好ましくは、三酸化アンチモンを用いることができる。アンチモン系難燃剤は1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。
C. Antimony-based flame retardant Any suitable antimony-based flame retardant can be used as the antimony-based flame retardant. Examples include antimony trioxide, antimony tetroxide, antimony pentoxide, and sodium antimonate. Preferably, antimony trioxide can be used. Only one kind of antimony-based flame retardant may be used, or two or more kinds may be used in combination.
アンチモン系難燃剤の含有量は樹脂100重量部に対し5重量部以下であり、好ましくは3重量部以下、より好ましくは1重量部以下、さらに好ましくは0.5重量部以下である。式(1)で表されるハイドロタルサイトと組み合わせて用いる場合、アンチモン系難燃剤の添加量を低減し、かつ、高い難燃性を有する樹脂組成物を提供することができる。1つの実施形態において、樹脂組成物はアンチモン系難燃剤を含んでいなくてもよい(すなわち、アンチモン系難燃剤の含有量が0重量部である)。本発明の実施形態の樹脂組成物によれば、アンチモン系難燃剤を含んでいない場合であっても、高い難燃性を有し得る。また、アンチモン系難燃剤を使用することによる環境汚染も抑制し得る。 The content of the antimony-based flame retardant is 5 parts by weight or less, preferably 3 parts by weight or less, more preferably 1 part by weight or less, and even more preferably 0.5 parts by weight or less, based on 100 parts by weight of the resin. When used in combination with hydrotalcite represented by formula (1), it is possible to reduce the amount of antimony-based flame retardant added and provide a resin composition having high flame retardancy. In one embodiment, the resin composition may not contain an antimony-based flame retardant (that is, the content of the antimony-based flame retardant is 0 parts by weight). According to the resin composition of the embodiment of the present invention, even when it does not contain an antimony-based flame retardant, it can have high flame retardancy. Furthermore, environmental pollution caused by the use of antimony-based flame retardants can also be suppressed.
D.ハイドロタルサイト
本発明の実施形態の樹脂組成物は、式(1)で表されるハイドロタルサイトを3重量部以上含む。式(1)で表されるハイドロタルサイトを含む樹脂組成物は、アンチモン系難燃剤の添加量が低減され、かつ、高い難燃性を有し得る。1つの実施形態において、本発明の樹脂組成物はアンチモン系難燃剤を含まない。式(1)で表されるハイドロタルサイトを8重量部以上用いることにより、アンチモン系難燃剤を含まない場合であっても、高い難燃性(例えば、UL-94V燃焼試験によるV-0評価)を発揮し得る。ハイドロタルサイトは、一般的に耐熱性を付与する安定剤として樹脂組成物に用いられている。本発明の実施形態の樹脂組成物は、式(1)で表されるハイドロタルサイトを含む場合、アンチモン系難燃剤等の他の難燃剤を用いることなく高い難燃性を有し得る。式(1)で表されるハイドロタルサイトは1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。
MgxAl2(OH)yCO3・nH2O (1)
(式中、xは4.3以上の数であり、yは12.6以上の数であり、nは3.0以上の数である)。
D. Hydrotalcite The resin composition of the embodiment of the present invention contains 3 parts by weight or more of hydrotalcite represented by formula (1). A resin composition containing hydrotalcite represented by formula (1) can have a reduced amount of an antimony-based flame retardant and can have high flame retardancy. In one embodiment, the resin composition of the present invention does not contain an antimony-based flame retardant. By using 8 parts by weight or more of hydrotalcite represented by formula (1), high flame retardance (for example, V-0 rating by UL-94V flame test) is achieved even when antimony-based flame retardants are not included. ). Hydrotalcite is generally used in resin compositions as a stabilizer that imparts heat resistance. When the resin composition of the embodiment of the present invention contains hydrotalcite represented by formula (1), it can have high flame retardancy without using other flame retardants such as antimony-based flame retardants. Only one type of hydrotalcite represented by formula (1) may be used, or two or more types may be used in combination.
Mg x Al 2 (OH) y CO 3・nH 2 O (1)
(In the formula, x is a number of 4.3 or more, y is a number of 12.6 or more, and n is a number of 3.0 or more).
式(1)において、xは4.3以上の数であり、好ましくは4.5~8.0の数であり、より好ましくは4.5~7.0の数であり、さらに好ましくは4.5~6.0の数である。式(1)において、yは12.6以上の数であり、好ましくは13~18の数であり、より好ましくは13~17の数であり、さらに好ましくは13~16の数である。式(1)において、nは3.0以上の数であり、好ましくは3.5~7.0の数であり、より好ましくは3.5~6.0の数であり、さらに好ましくは3.5~4.0の数である。 In formula (1), x is a number of 4.3 or more, preferably a number of 4.5 to 8.0, more preferably a number of 4.5 to 7.0, and even more preferably 4 It is a number between .5 and 6.0. In formula (1), y is a number of 12.6 or more, preferably a number of 13 to 18, more preferably a number of 13 to 17, and still more preferably a number of 13 to 16. In formula (1), n is a number of 3.0 or more, preferably a number of 3.5 to 7.0, more preferably a number of 3.5 to 6.0, and even more preferably 3 It is a number between .5 and 4.0.
式(1)で表されるハイドロタルサイトとしては、好ましくはMg4.5Al2(OH)13CO3・3.5H2O、または、Mg6.0Al2(OH)16CO3・4H2Oを用いることができ、より好ましくはMg4.5Al2(OH)13CO3・3.5H2Oを用いることができる。これらのハイドロタルサイトを用いることにより、アンチモン系難燃剤の添加量を低減し、かつ、高い難燃性を有する樹脂組成物を提供することができる。 The hydrotalcite represented by formula (1) is preferably Mg 4.5 Al 2 (OH) 13 CO 3 .3.5H 2 O or Mg 6.0 Al 2 (OH) 16 CO 3 . 4H 2 O can be used, and more preferably Mg 4.5 Al 2 (OH) 13 CO 3 .3.5H 2 O can be used. By using these hydrotalcites, it is possible to reduce the amount of antimony-based flame retardant added and to provide a resin composition having high flame retardancy.
式(1)で表されるハイドロタルサイトとしては、市販品を用いてもよい。例えば、堺化学工業社製の商品名:HT-88F、および、HT-6が挙げられる。 As the hydrotalcite represented by formula (1), a commercially available product may be used. Examples include HT-88F and HT-6 manufactured by Sakai Chemical Industry Co., Ltd.
式(1)で表されるハイドロタルサイトのBET比表面積は、好ましくは5m2/g~20m2/gである。式(1)で表されるハイドロタルサイトのBET比表面積が5m2/g未満であると、樹脂との接触面積が減少し、期待される難燃効果が得られ難くなる場合がある。一方、式(1)で表されるハイドロタルサイトのBET比表面積が20m2/gを超えると、ハイドロタルサイトが凝集し、樹脂への分散性が低下し、樹脂物性が低下するおそれがある。式(1)で表されるハイドロタルサイトのBET比表面積は、より好ましくは6m2/g~19m2/gであり、さらに好ましくは、7m2/g~18m2/gである。 The BET specific surface area of the hydrotalcite represented by formula (1) is preferably 5 m 2 /g to 20 m 2 /g. If the BET specific surface area of the hydrotalcite represented by formula (1) is less than 5 m 2 /g, the contact area with the resin may decrease, making it difficult to obtain the expected flame retardant effect. On the other hand, if the BET specific surface area of the hydrotalcite expressed by formula (1) exceeds 20 m 2 /g, the hydrotalcite may aggregate, resulting in a decrease in dispersibility in the resin and a decrease in resin physical properties. . The BET specific surface area of the hydrotalcite represented by formula (1) is more preferably 6 m 2 /g to 19 m 2 /g, and even more preferably 7 m 2 /g to 18 m 2 /g.
式(1)で表されるハイドロタルサイトは任意の適切な形状を有する。例えば、板状、球状、円盤状等が挙げられる。なお、粒子形状は、走査型電子顕微鏡等によって観察することができる。 The hydrotalcite represented by formula (1) has any suitable shape. For example, it may be plate-shaped, spherical, disc-shaped, etc. Note that the particle shape can be observed using a scanning electron microscope or the like.
式(1)で表されるハイドロタルサイトは任意の適切な表面処理をされていてもよい。表面処理剤としては、任意の適切な表面処理剤を用いることができる。例えば、ステアリン酸、パルミチン酸等の高級脂肪酸、ステアリン酸ナトリウム等の高級脂肪酸金属塩、アニオン界面活性剤、リン酸エステル、シランカップリング剤、チタンカップリング剤、アルミニウムカップリング剤等のカップリング剤が挙げられる。表面処理剤は1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。表面処理剤の使用量は、任意の適切な値に設定することができる。好ましくは、表面処理されていないハイドロタルサイト100重量部に対して1重量部~10重量部であり、より好ましくは1重量部~6重量部である。 The hydrotalcite represented by formula (1) may be subjected to any appropriate surface treatment. Any suitable surface treating agent can be used as the surface treating agent. For example, higher fatty acids such as stearic acid and palmitic acid, higher fatty acid metal salts such as sodium stearate, anionic surfactants, phosphoric acid esters, coupling agents such as silane coupling agents, titanium coupling agents, and aluminum coupling agents. can be mentioned. Only one type of surface treatment agent may be used, or two or more types may be used in combination. The amount of surface treatment agent used can be set to any appropriate value. Preferably, the amount is from 1 part by weight to 10 parts by weight, more preferably from 1 part by weight to 6 parts by weight, based on 100 parts by weight of unsurface-treated hydrotalcite.
式(1)で表されるハイドロタルサイトの含有量は、樹脂100重量部に対し、3重量部以上であり、好ましくは3.5重量部以上であり、より好ましくは4重量部以上である。式(1)で表されるハイドロタルサイトが3重量部以上であればアンチモン系難燃剤の添加量を低減し、かつ、難燃性に優れた樹脂組成物を提供することができる。式(1)で表されるハイドロタルサイトの含有量は、例えば、樹脂100重量部に対し、60重量部以下であり、好ましくは55重量部以下である。式(1)で表されるハイドロタルサイトの含有量が60重量部を超える場合、物性が低下し、樹脂組成物の加工性、および、ハンドリング性が低下し得る。 The content of hydrotalcite represented by formula (1) is 3 parts by weight or more, preferably 3.5 parts by weight or more, and more preferably 4 parts by weight or more based on 100 parts by weight of the resin. . If the hydrotalcite represented by formula (1) is 3 parts by weight or more, the amount of antimony-based flame retardant added can be reduced and a resin composition with excellent flame retardancy can be provided. The content of hydrotalcite represented by formula (1) is, for example, 60 parts by weight or less, preferably 55 parts by weight or less, based on 100 parts by weight of the resin. When the content of hydrotalcite represented by formula (1) exceeds 60 parts by weight, the physical properties may deteriorate, and the processability and handleability of the resin composition may deteriorate.
1つの実施形態において、式(1)で表されるハイドロタルサイトの含有量は、樹脂100重量部に対し、好ましくは8重量部以上であり、より好ましくは15重量部以上であり、さらに好ましくは20重量部以上であり、特に好ましくは30重量部以上である。式(1)で表されるハイドロタルサイトの含有量が上記範囲である場合、アンチモン系難燃剤を含まない場合であってもアンチモン系難燃剤含有樹脂組成物と同等の高い難燃性を有する樹脂組成物を提供することができる。この実施形態において、式(1)で表されるハイドロタルサイトの含有量は、例えば、樹脂100重量部に対し、60重量部以下であり、好ましくは55重量部以下である。式(1)で表されるハイドロタルサイトの含有量が60重量部を超える場合、物性が低下し、樹脂組成物の加工性、および、ハンドリング性が低下し得る。この実施形態において、樹脂組成物は、アンチモン系難燃剤の含有量が0重量部(すなわち、アンチモン系難燃剤を含まない)であってもよい。 In one embodiment, the content of hydrotalcite represented by formula (1) is preferably 8 parts by weight or more, more preferably 15 parts by weight or more, and even more preferably is 20 parts by weight or more, particularly preferably 30 parts by weight or more. When the content of hydrotalcite represented by formula (1) is within the above range, it has high flame retardancy equivalent to that of a resin composition containing an antimony flame retardant even if it does not contain an antimony flame retardant. A resin composition can be provided. In this embodiment, the content of hydrotalcite represented by formula (1) is, for example, 60 parts by weight or less, preferably 55 parts by weight or less, based on 100 parts by weight of the resin. When the content of hydrotalcite represented by formula (1) exceeds 60 parts by weight, the physical properties may deteriorate, and the processability and handleability of the resin composition may deteriorate. In this embodiment, the content of the antimony-based flame retardant in the resin composition may be 0 parts by weight (that is, the resin composition does not contain the antimony-based flame retardant).
E.その他の添加剤
樹脂組成物は、アンチモン系難燃剤、および、式(1)で表されるハイドロタルサイト以外の任意の適切な他の添加剤を含んでいてもよい。他の添加剤としては、例えば、可塑剤、有機酸金属塩等の安定剤、β-ジケトン化合物、充填剤、ワックス、耐熱助剤、紫外線吸収剤、酸化防止剤、架橋助剤、アンチモン系難燃剤以外の難燃剤等が挙げられる。これらの添加剤は1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。
E. Other Additives The resin composition may contain any other appropriate additives other than the antimony-based flame retardant and the hydrotalcite represented by formula (1). Other additives include, for example, plasticizers, stabilizers such as organic acid metal salts, β-diketone compounds, fillers, waxes, heat resistance aids, ultraviolet absorbers, antioxidants, crosslinking aids, and antimony-based additives. Examples include flame retardants other than flame retardants. These additives may be used alone or in combination of two or more.
可塑剤としては、任意の適切な可塑剤を用いることができる。例えば、フタル酸エステル化合物、アジピン酸エステル化合物、リン酸エステル化合物、トリメリット酸エステル化合物などが挙げられる。より具体的には、フタル酸エステル化合物としてジオクチルフタレート(DOP)、ジイソノニルフタレート(DINP)およびジイソデシルフタレート(DIDP)が、アジピン酸エステル化合物としてジオクチルアジペート(DOA)が、トリメリット酸エステル化合物としてトリオクチルトリメリテート(TOTM)等がそれぞれ挙げられる。可塑剤としては、好ましくはトリメリット酸エステル化合物が用いられる。 Any suitable plasticizer can be used as the plasticizer. Examples include phthalic acid ester compounds, adipic acid ester compounds, phosphoric acid ester compounds, and trimellitic acid ester compounds. More specifically, dioctyl phthalate (DOP), diisononyl phthalate (DINP) and diisodecyl phthalate (DIDP) are used as phthalate ester compounds, dioctyl adipate (DOA) is used as an adipic acid ester compound, and trioctyl is used as a trimellitic acid ester compound. Examples include trimellitate (TOTM) and the like. As the plasticizer, preferably a trimellitic acid ester compound is used.
可塑剤の含有量は、任意の適切な量とすることができる。例えば、樹脂100重量部に対し、30重量部~100重量部であり、好ましくは40重量部~80重量部であり、より好ましくは45重量部~60重量部である。可塑剤の含有量が上記範囲であれば、樹脂組成物の柔軟性が向上し得る。 The content of plasticizer can be any suitable amount. For example, the amount is from 30 parts by weight to 100 parts by weight, preferably from 40 parts by weight to 80 parts by weight, and more preferably from 45 parts by weight to 60 parts by weight, based on 100 parts by weight of the resin. When the content of the plasticizer is within the above range, the flexibility of the resin composition can be improved.
有機金属塩としては任意の適切な有機金属塩を用いることができる。有機酸金属塩を含むことで、例えば、塩化ビニル系樹脂を用いる場合には、塩化ビニル系樹脂の塩素が安定化され、加工時、または、使用時に変色が抑制され得る。そのため、外観を低下させることなく成形体を得ることができる。 Any suitable organic metal salt can be used as the organic metal salt. By including an organic acid metal salt, for example, when a vinyl chloride resin is used, chlorine in the vinyl chloride resin is stabilized, and discoloration can be suppressed during processing or use. Therefore, a molded article can be obtained without deteriorating its appearance.
有機酸金属塩における有機酸としては任意の適切な有機酸を用いることができる。例えば、酢酸、プロピオン酸、酪酸、吉草酸、カプロン酸、エナント酸、カプリル酸、ペラルゴン酸、2-エチルヘキシル酸、ネオデカン酸、カプリン酸、ウンデカン酸、ラウリン酸、トリデカン酸、ミリスチン酸、パルミチン酸、イソステアリン酸、ステアリン酸、12-ヒドロキシステアリン酸、ベヘニン酸、モンタン酸、安息香酸、モノクロル安息香酸、p-t-ブチル安息香酸、ジメチルヒドロキシ安息香酸、3,5-ジ-t-ブチル-4-ヒドロキシ安息香酸、トルイル酸、ジメチル安息香酸、エチル安息香酸、クミン酸、n-プロピル安息香酸、アミノ安息香酸、N,N-ジメチルアミノ安息香酸、アセトキシ安息香酸、サリチル酸、p-t-オクチルサリチル酸、エライジン酸、オレイン酸、リノール酸、リノレイン酸、チオグリコール酸、メルカプトプロピオン酸、オクチルメルカプトプロピオン酸等の1価有機カルボン酸;シュウ酸、マロン酸、コハク酸、グルタル酸、アジピン酸、ピメリン酸、スベリン酸、アゼライン酸、セバシン酸、フタル酸、イソフタル酸、テレフタル酸、ヒドロキシフタル酸、クロルフタル酸、アミノフタル酸、マレイン酸、フマール酸、シトラコン酸、メタコン酸、イタコン酸、アコニット酸、チオジプロピオン酸等の2価有機カルボン酸;2価有機カルボン酸のモノエステル又はモノアミド化合物、ブタントリカルボン酸、ブタンテトラカルボン酸、ヘミメリット酸、トリメリット酸、メロファン酸、ピロメリット酸等の3価又は4価の有機カルボン酸のジ又はトリエステル;等が挙げられる。またこれらの有機酸を構成する水素原子の一部が水酸基等により置換されていてもよい。好ましくは炭素数12~20の高級脂肪酸が用いられる。具体的には、好ましくはミリスチン酸、パルミチン酸、イソステアリン酸、ステアリン酸の金属塩等を用いることができる。安価で入手しやすいことから、より好ましくはパルミチン酸の金属塩やステアリン酸の金属塩が用いられる。なお、後述するデヒドロ酢酸亜鉛のように、有機酸金属塩にもβ-ジケトン化合物にも該当する化合物は、本明細書ではβ-ジケトン化合物とする。すなわち、上記有機酸金属塩は、有機酸の金属塩であって、β-ジケトン化合物に該当する化合物以外のものである。 Any suitable organic acid can be used as the organic acid in the organic acid metal salt. For example, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, 2-ethylhexylic acid, neodecanoic acid, capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, palmitic acid, Isostearic acid, stearic acid, 12-hydroxystearic acid, behenic acid, montanic acid, benzoic acid, monochlorobenzoic acid, pt-butylbenzoic acid, dimethylhydroxybenzoic acid, 3,5-di-t-butyl-4- Hydroxybenzoic acid, toluic acid, dimethylbenzoic acid, ethylbenzoic acid, cumic acid, n-propylbenzoic acid, aminobenzoic acid, N,N-dimethylaminobenzoic acid, acetoxybenzoic acid, salicylic acid, pt-octylsalicylic acid, Monovalent organic carboxylic acids such as elaidic acid, oleic acid, linoleic acid, linoleic acid, thioglycolic acid, mercaptopropionic acid, octylmercaptopropionic acid; oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, Suberic acid, azelaic acid, sebacic acid, phthalic acid, isophthalic acid, terephthalic acid, hydroxyphthalic acid, chlorophthalic acid, aminophthalic acid, maleic acid, fumaric acid, citraconic acid, methaconic acid, itaconic acid, aconitic acid, thiodipropionic acid Divalent organic carboxylic acids such as monoesters or monoamide compounds of divalent organic carboxylic acids, trivalent or tetravalent such as butanetricarboxylic acid, butanetetracarboxylic acid, hemimellitic acid, trimellitic acid, merophanic acid, pyromellitic acid, etc. and di- or triesters of organic carboxylic acids. Further, some of the hydrogen atoms constituting these organic acids may be substituted with hydroxyl groups or the like. Preferably, higher fatty acids having 12 to 20 carbon atoms are used. Specifically, preferably myristic acid, palmitic acid, isostearic acid, metal salts of stearic acid, etc. can be used. More preferably, metal salts of palmitic acid and metal salts of stearic acid are used because they are inexpensive and easily available. Note that a compound that corresponds to both an organic acid metal salt and a β-diketone compound, such as zinc dehydroacetate described later, is referred to as a β-diketone compound in this specification. That is, the organic acid metal salt is a metal salt of an organic acid other than a β-diketone compound.
有機酸金属塩を形成する金属としては、例えば、Ca、Sr、Ba等のアルカリ土類金属およびZn、Pb、Sn等が挙げられる。有機酸金属塩のうち、Pbを含むものは鉛系安定剤、Snを含むものはSn系安定剤と称し、Pbを含まない安定剤であって、Sn系安定剤に分類されないものを一般にCa/Zn系安定剤と称する。Ca/Zn系安定剤はCaとZnの両方を含むもののみを意味せず、Znのみを含む安定剤やCaとZnのいずれも含まず、かつSnも含まない安定剤も含まれる。また、CaとZnの他に、助剤としてSn等のPb以外の金属元素を含む安定剤もCa/Zn系安定剤に含まれることがある。本明細書においては、Snを含んでいてもその含有量が0.5重量部以下のものをCa/Zn系安定剤、Snの含有量が0.5重量部を超えるものをSn系安定剤とする。 Examples of the metal forming the organic acid metal salt include alkaline earth metals such as Ca, Sr, and Ba, and Zn, Pb, and Sn. Among organic acid metal salts, those containing Pb are called lead-based stabilizers, those containing Sn are called Sn-based stabilizers, and stabilizers that do not contain Pb and are not classified as Sn-based stabilizers are generally called Ca-based stabilizers. /Zn-based stabilizer. The Ca/Zn-based stabilizer does not mean only those containing both Ca and Zn, but also includes stabilizers containing only Zn, and stabilizers containing neither Ca nor Zn, nor Sn. Further, in addition to Ca and Zn, a stabilizer containing a metal element other than Pb such as Sn as an auxiliary agent may also be included in the Ca/Zn-based stabilizer. In this specification, those containing Sn in a content of 0.5 parts by weight or less are referred to as Ca/Zn-based stabilizers, and those containing Sn in excess of 0.5 parts by weight are referred to as Sn-based stabilizers. shall be.
有機酸金属塩の含有量は任意の適切な値に設定され得る。例えば、樹脂100重量部に対して好ましくは0.01重量部以上であり、より好ましくは0.1重量部以上である。有機金属塩の含有量が上記範囲であれば、変色を抑制し得る。また、有機金属塩の含有量は樹脂100重量部に対し、好ましくは5重量部以下であり、より好ましくは2重量部以下である。これにより、耐熱性をより高めることができ、成形体の外観がより低下せず、色調もより良好なものとなり得る。 The content of the organic acid metal salt can be set to any appropriate value. For example, it is preferably at least 0.01 part by weight, more preferably at least 0.1 part by weight, based on 100 parts by weight of the resin. If the content of the organic metal salt is within the above range, discoloration can be suppressed. Further, the content of the organic metal salt is preferably 5 parts by weight or less, more preferably 2 parts by weight or less, based on 100 parts by weight of the resin. Thereby, the heat resistance can be further improved, the appearance of the molded article will not deteriorate more, and the color tone can also be made better.
β-ジケトン化合物としては任意の適切な化合物を用いることができる。例えば、ステアロイルアセチルメタン、ベンゾイルアセチルメタン、ジベンゾイルメタン、ステアロイルベンゾイルメタン、オクチルベンゾイルメタン、ビス(4-オクチルベンゾイル)メタン、4-メトキシベンゾイルベンゾイルメタン、ビス(4-カルボキシメチルベンゾイル)メタン、2-カルボキシメチルベンゾイルアセチルオクチルメタン、2-ベンゾイルシクロヘキサン等のアルカノイルアロイルメタンおよびジアロイルメタン;デヒドロ酢酸;ならびに、それらの金属塩が挙げられる。β-ジケトン化合物を含む場合、成形時の着色性改善を図ることができる。樹脂組成物を電線被覆材として用いる場合には、デヒドロ酢酸亜鉛を含むことが好適である。樹脂添加剤の業界ではデヒドロ酢酸亜鉛はβ-ジケトン化合物の金属塩として認知されているため本明細書でも同様に扱う。 Any suitable compound can be used as the β-diketone compound. For example, stearoyl acetylmethane, benzoylacetylmethane, dibenzoylmethane, stearoylbenzoylmethane, octylbenzoylmethane, bis(4-octylbenzoyl)methane, 4-methoxybenzoylbenzoylmethane, bis(4-carboxymethylbenzoyl)methane, 2- Examples include alkanoylaroylmethanes and dialoylmethanes such as carboxymethylbenzoylacetyloctylmethane and 2-benzoylcyclohexane; dehydroacetic acid; and metal salts thereof. When containing a β-diketone compound, it is possible to improve the coloring property during molding. When the resin composition is used as a wire coating material, it is suitable that zinc dehydroacetate is included. In the resin additive industry, zinc dehydroacetate is recognized as a metal salt of a β-diketone compound, so it will be treated similarly in this specification.
β-ジケトン化合物は任意の適切な含有量で用いられる。例えば、樹脂100重量部に対して2重量部以下であることが好ましく、より好ましくは0.1重量部~1重量部である。 The β-diketone compound can be used in any suitable content. For example, the amount is preferably 2 parts by weight or less, more preferably 0.1 part to 1 part by weight, based on 100 parts by weight of the resin.
充填剤としては任意の適切な充填剤が用いられる。例えば、無機塩類、無機酸化物、無機水酸化物等の無機粉体が挙げられる。具体的には、亜鉛、チタン、鉄、セリウム、バリウム、カルシウム、ケイ素、アルミニウム、マグネシウム、ストロンチウム、硼素、ジルコニウム等の塩類、酸化物、水酸化物、複合酸化物が挙げられる。塩類としては任意の適切な塩類を用いることができる。例えば、硫酸塩、炭酸塩、塩酸塩、酢酸塩、硝酸塩等が挙げられる。具体的には、例えば、炭酸カルシウム、炭酸亜鉛、炭酸マグネシウム、シリカ、酸化亜鉛、酸化チタン、酸化セリウム、酸化鉄、硫酸バリウム、硫酸ストロンチウム、硫酸マグネシウム、酸化ケイ素、酸化アルミニウム、酸化マグネシウム、ケイ酸亜鉛、チタン酸亜鉛、チタン酸バリウム、クレイ、タルク等が挙げられる。好ましくは、炭酸カルシウムである。充填剤を含む場合、成形品の寸法安定性や成形品の強度が向上するので、成形体用途に好ましい樹脂組成物となる。 Any suitable filler can be used as the filler. Examples include inorganic powders such as inorganic salts, inorganic oxides, and inorganic hydroxides. Specific examples include salts, oxides, hydroxides, and composite oxides of zinc, titanium, iron, cerium, barium, calcium, silicon, aluminum, magnesium, strontium, boron, zirconium, and the like. Any suitable salts can be used as the salts. Examples include sulfates, carbonates, hydrochlorides, acetates, nitrates, and the like. Specifically, for example, calcium carbonate, zinc carbonate, magnesium carbonate, silica, zinc oxide, titanium oxide, cerium oxide, iron oxide, barium sulfate, strontium sulfate, magnesium sulfate, silicon oxide, aluminum oxide, magnesium oxide, silicic acid. Examples include zinc, zinc titanate, barium titanate, clay, and talc. Preferably it is calcium carbonate. When a filler is included, the dimensional stability and strength of the molded article are improved, so the resin composition becomes preferable for use in molded articles.
ワックスとしては任意の適切なワックスを用いることができる。例えば、ポリエチレンワックス、パラフィンワックス等の炭化水素ワックス及び/又は脂肪酸エステルワックスが挙げられる。具体的には、ポリエチレンワックスとしては、例えば、三井化学社製ハイワックスシリーズ、三洋化成工業社製サンワックスシリーズ、三洋化成工業社製ビスコールシリーズ、日本精蝋社製ルバックスシリーズ等が挙げられる。エステルワックスとしては、例えば、リケンビタミン社製リケスタシリーズ、エメリー社製ロキシオールシリーズ等が挙げられる。ワックスを含む場合、成形中の樹脂混練状態の調整や成形品のツヤなど外観調整等を行うことができる。 Any suitable wax can be used as the wax. Examples include hydrocarbon waxes such as polyethylene wax and paraffin wax, and/or fatty acid ester waxes. Specifically, polyethylene waxes include, for example, the Hiwax series manufactured by Mitsui Chemicals, the Sunwax series manufactured by Sanyo Chemical Industries, Ltd., the Viscoll series manufactured by Sanyo Chemical Industries, Ltd., and the Luvax series manufactured by Nippon Seiro Co., Ltd. . Examples of the ester waxes include the Rikesta series manufactured by Riken Vitamin Co., Ltd. and the Roxiol series manufactured by Emery Co., Ltd., and the like. When wax is included, it is possible to adjust the resin kneading state during molding and to adjust the appearance of the molded product, such as gloss.
ワックスの含有量は任意の適切な値に設定され得る。例えば、樹脂100重量部に対して、好ましくは0.01重量部~1重量部であり、より好ましくは0.05重量部~0.5重量部である。 The wax content can be set to any suitable value. For example, the amount is preferably 0.01 part by weight to 1 part by weight, more preferably 0.05 part by weight to 0.5 part by weight, based on 100 parts by weight of the resin.
耐熱助剤としてはジペンタリスリトール等の多価アルコール化合物、エポキシ樹脂等のエポキシ化合物が挙げられる。滑剤としてはステアリン酸モノグリセライド、パルミチン酸モノグリセライド、ステアリン酸、パルミチン酸等が挙げられる。 Examples of the heat resistance aid include polyhydric alcohol compounds such as dipentyritol, and epoxy compounds such as epoxy resins. Examples of the lubricant include stearic acid monoglyceride, palmitic acid monoglyceride, stearic acid, and palmitic acid.
アンチモン系難燃剤以外の難燃剤としては、任意の適切な難燃剤を用いることができる。例えば、テトラブロモエタン、ヘキサブロモベンゼン等の臭素系難燃剤、リン酸アンモニウム、トリメチルホスフェート等のリン系難燃剤、メラミン系化合物やシアヌル酸系化合物等の窒素系難燃剤等が挙げられる。 Any suitable flame retardant can be used as the flame retardant other than the antimony-based flame retardant. Examples include bromine flame retardants such as tetrabromoethane and hexabromobenzene, phosphorus flame retardants such as ammonium phosphate and trimethyl phosphate, and nitrogen flame retardants such as melamine compounds and cyanuric acid compounds.
F.樹脂組成物の調製方法
本発明の実施形態の樹脂組成物は、任意の適切な方法で製造することができる。例えば、樹脂、アンチモン系難燃剤、および、式(1)で表されるハイドロタルサイト、ならびに、任意の適切な他の添加剤を任意の適切な手段により混合すればよい。混合は任意の適切な方法により行うことができる。例えば、ヘンシェルミキサーまたはスーパーミキサーで混合し、得られた混合物をロール、バンバリーミキサー、押出機等を用いて均一に混練することが好適である。
F. Method for Preparing Resin Composition The resin composition of the embodiment of the present invention can be produced by any suitable method. For example, the resin, antimony-based flame retardant, hydrotalcite represented by formula (1), and any other appropriate additives may be mixed by any appropriate means. Mixing can be done by any suitable method. For example, it is preferable to mix with a Henschel mixer or a super mixer, and then uniformly knead the resulting mixture using a roll, Banbury mixer, extruder, or the like.
G.用途
本発明の実施形態の樹脂組成物は、任意の適切な用途に用いることができる。上記のとおり、本発明の実施形態の樹脂組成物は、優れた難燃性を有する。したがって、難燃性を要求される用途に好適に用いることができる。1つの実施形態においては、成形体が提供される。本発明の実施形態の成形体は、上記樹脂組成物を用いてなる。1つの実施形態において、本発明の実施形態の樹脂組成物は、耐熱電線および絶縁電線等の電線被覆材として好適に用いることができる。1つの実施形態においては、電線被覆材が提供される。本発明の実施形態の電線被覆材は、上記樹脂組成物を用いて形成される。1つの実施形態においては、電線が提供される。本発明の実施形態の電線は、上記被覆材で被覆され得る。
G. Applications The resin composition of the embodiment of the present invention can be used for any appropriate application. As described above, the resin composition of the embodiment of the present invention has excellent flame retardancy. Therefore, it can be suitably used in applications requiring flame retardancy. In one embodiment, a shaped body is provided. A molded article according to an embodiment of the present invention is made using the above resin composition. In one embodiment, the resin composition of the embodiment of the present invention can be suitably used as a wire coating material for heat-resistant wires, insulated wires, and the like. In one embodiment, a wire coating is provided. The wire covering material of the embodiment of the present invention is formed using the above resin composition. In one embodiment, an electrical wire is provided. The electric wire of the embodiment of the present invention may be coated with the above coating material.
以下、実施例によって本発明を具体的に説明するが、本発明はこれら実施例によって限定されるものではない。 EXAMPLES Hereinafter, the present invention will be specifically explained with reference to Examples, but the present invention is not limited to these Examples.
[実施例1]
塩化ビニル樹脂(信越化学工業社製:TK-1000)100重量部に、可塑剤(水島可塑剤社製、トリメリット酸オクチル(TOTM))、絶縁剤(白石カルシウム社製、製品名:BURGESS 30(クレイ))、安定剤(カルシウム亜鉛系安定剤、堺化学工業社製、製品名:OW-3141Y)、アンチモン系難燃剤(三酸化アンチモン、山中産業社製、商品名:MSW)および、式(1)で表されるハイドロタルサイト(ハイドロタルサイトA、堺化学工業社製、商品名:HT-88F、Mg4.5Al2(OH)13CO3・3.5H2O、BET比表面積:10.2m2/g)を表1に記載の含有量で混合し、樹脂組成物を得た。
[Example 1]
100 parts by weight of vinyl chloride resin (manufactured by Shin-Etsu Chemical Co., Ltd.: TK-1000), a plasticizer (manufactured by Mizushima Plasticizer Co., Ltd., octyl trimellitate (TOTM)), an insulating agent (manufactured by Shiraishi Calcium Co., Ltd., product name: BURGESS 30) (clay)), stabilizer (calcium zinc stabilizer, manufactured by Sakai Chemical Industry Co., Ltd., product name: OW-3141Y), antimony-based flame retardant (antimony trioxide, manufactured by Yamanaka Sangyo Co., Ltd., product name: MSW), and the formula Hydrotalcite represented by (1) (Hydrotalcite A, manufactured by Sakai Chemical Industry Co., Ltd., product name: HT-88F, Mg 4.5 Al 2 (OH) 13 CO 3 3.5 H 2 O, BET ratio Surface area: 10.2 m 2 /g) were mixed in the contents shown in Table 1 to obtain a resin composition.
[実施例2~6]
アンチモン系難燃剤およびハイドロタルサイトAの含有量を表1に記載のように変更したこと、または、使用したハイドロタルサイトをハイドロタルサイトBに変更したこと以外は実施例1と同様にして、樹脂組成物を得た。
なお、ハイドロタルサイトBとして、ハイドロタルサイト(堺化学工業社製、商品名:HT-6、Mg6.0Al2(OH)16CO3・4H2O、BET比表面積:15.9m2/g)を高級脂肪酸金属塩(ステアリン酸ナトリウム)で4%コートしたものを用いた。
[Examples 2 to 6]
The same procedure as in Example 1 was carried out, except that the contents of the antimony-based flame retardant and hydrotalcite A were changed as shown in Table 1, or the hydrotalcite used was changed to hydrotalcite B. A resin composition was obtained.
In addition, as hydrotalcite B, hydrotalcite (manufactured by Sakai Chemical Industry Co., Ltd., product name: HT-6, Mg 6.0 Al 2 (OH) 16 CO 3.4H 2 O, BET specific surface area: 15.9 m 2 /g) coated with 4% higher fatty acid metal salt (sodium stearate) was used.
(比較例1~4)
アンチモン系難燃剤および式(1)で表されるハイドロタルサイトの含有量、ならびに、使用したハイドロタルサイト(ハイドロタルサイトCまたはD)を表1に記載のように変更した以外は実施例1と同様にして、樹脂組成物を得た。
なお、ハイドロタルサイトCとして堺化学工業社製の商品名:HT-1(Mg4.0Al2(OH)12CO3・3H2O、BET比表面積:9.2m2/g)を、ハイドロタルサイトDとして堺化学工業社製の商品名:HT-7(Mg3.5Zn0.5Al2(OH)13CO3・3.5H2O、BET比表面積:6.9m2/g)を、それぞれ用いた。
(Comparative Examples 1 to 4)
Example 1 except that the content of the antimony-based flame retardant and the hydrotalcite represented by formula (1), and the hydrotalcite used (hydrotalcite C or D) were changed as shown in Table 1. A resin composition was obtained in the same manner as above.
In addition, as hydrotalcite C, product name: HT-1 (Mg 4.0 Al 2 (OH) 12 CO 3.3H 2 O, BET specific surface area: 9.2 m 2 /g) manufactured by Sakai Chemical Industry Co., Ltd. Hydrotalcite D manufactured by Sakai Chemical Industry Co., Ltd. Product name: HT-7 (Mg 3.5 Zn 0.5 Al 2 (OH) 13 CO 3.3.5H 2 O, BET specific surface area: 6.9 m 2 / g) were used, respectively.
<評価>
実施例または比較例で得られた樹脂組成物をロール表面温度170℃に調整した8インチロール機(KANSAI ROLL社製)で5分間混錬し、厚さ0.6mmのロールシートを作製した。得られたシートを3枚重ねて、プレス表面温度170℃のプレス機(TOYOSEIKI MINI TEST PRESS-10)を用い、厚さ1.5mmになるように20kg/cm2~50kg/cm2の条件で5分間保持した。次いで、シートをカットして、縦125mm±5mm、横13mm±5mmの試験片を各6本ずつ作製した。
作製した試験片を用いて、燃焼試験機(スガ試験機株式会社製)を用いて、UL-94V規格に従って燃焼試験を実施した。具体的には、試験片をクランプに垂直に取付け、20mm炎による接炎を10秒間行い、燃焼時間を測定した。5個の試験片について燃焼試験を行い、クランプまで燃焼したサンプルの数、各燃焼時間のうちの最大値(max)、および5個の燃焼時間の合計(総燃焼時間:total)を記録した。また、その結果に基づいて、V-0、V-1、V-2、failの基準で判定を行った。難燃性はV-0が最も優れており、V-1、V-2、failの順に難燃性の程度が低くなることを示す。
<Evaluation>
The resin compositions obtained in Examples or Comparative Examples were kneaded for 5 minutes using an 8-inch roll machine (manufactured by KANSAI ROLL Co., Ltd.) whose roll surface temperature was adjusted to 170° C. to produce a roll sheet with a thickness of 0.6 mm. Three of the obtained sheets were stacked and pressed at a pressure of 20 kg/cm 2 to 50 kg/cm 2 to a thickness of 1.5 mm using a press machine (TOYOSEIKI MINI TEST PRESS-10) with a press surface temperature of 170°C. It was held for 5 minutes. Next, the sheet was cut to produce six test pieces each measuring 125 mm±5 mm in length and 13 mm±5 mm in width.
Using the prepared test piece, a combustion test was conducted using a combustion tester (manufactured by Suga Test Instruments Co., Ltd.) in accordance with the UL-94V standard. Specifically, the test piece was attached vertically to a clamp, and a 20 mm flame was applied for 10 seconds to measure the burning time. A combustion test was conducted on five test pieces, and the number of samples burned to the clamp, the maximum value (max) of each combustion time, and the sum of the five combustion times (total combustion time: total) were recorded. Further, based on the results, judgments were made using the criteria of V-0, V-1, V-2, and fail. V-0 is the best flame retardant, and V-1, V-2, and fail indicate lower degrees of flame retardancy.
本願実施例の樹脂組成物は、アンチモン系難燃剤の含有量を低減し、かつ、高い難燃性(UL-94V燃焼試験でのV-0評価)を有するものであった。 The resin compositions of Examples of the present application had a reduced content of antimony-based flame retardant and had high flame retardancy (V-0 rating in the UL-94V combustion test).
本発明の樹脂組成物は高い難燃性を有する。したがって、例えば、電線被覆材等の難燃性が要求される用途に好適に用いることができる。 The resin composition of the present invention has high flame retardancy. Therefore, it can be suitably used, for example, in applications where flame retardancy is required, such as electric wire coating materials.
Claims (8)
該樹脂100重量部に対して、式(1)で表されるハイドロタルサイトを3重量部以上と、
アンチモン系難燃剤を5重量部以下と、を含む、樹脂組成物
MgxAl2(OH)yCO3・nH2O (1)
(式中、xは4.3以上の数であり、yは12.6以上の数であり、nは3.0以上の数である)。 100 parts by weight of resin,
With respect to 100 parts by weight of the resin, 3 parts by weight or more of hydrotalcite represented by formula (1),
Resin composition containing 5 parts by weight or less of an antimony-based flame retardant Mg x Al 2 (OH) y CO 3 ·nH 2 O (1)
(In the formula, x is a number of 4.3 or more, y is a number of 12.6 or more, and n is a number of 3.0 or more).
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