JP2024010556A - Oil-based solid cleansing cosmetic - Google Patents
Oil-based solid cleansing cosmetic Download PDFInfo
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- JP2024010556A JP2024010556A JP2022111953A JP2022111953A JP2024010556A JP 2024010556 A JP2024010556 A JP 2024010556A JP 2022111953 A JP2022111953 A JP 2022111953A JP 2022111953 A JP2022111953 A JP 2022111953A JP 2024010556 A JP2024010556 A JP 2024010556A
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- Prior art keywords
- component
- oil
- mass
- based solid
- charcoal powder
- Prior art date
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 68
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- 239000003610 charcoal Substances 0.000 claims abstract description 46
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- 229940079593 drug Drugs 0.000 description 1
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- TVQGDYNRXLTQAP-UHFFFAOYSA-N ethyl heptanoate Chemical compound CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
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- 239000000284 extract Substances 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
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- 239000003205 fragrance Substances 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
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- 239000003349 gelling agent Substances 0.000 description 1
- 238000012812 general test Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
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- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
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- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
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- 239000000600 sorbitol Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
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- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- Chemical & Material Sciences (AREA)
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- Microbiology (AREA)
- Botany (AREA)
- Biotechnology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、油性固形状クレンジング化粧料に関する。 The present invention relates to an oil-based solid cleansing cosmetic composition.
近年、メイクアップ化粧料の除去を目的とした油性固形状クレンジング化粧料が提案されている。油性固形状クレンジング化粧料は、常温で固形状であることから、使用時の垂れ落ちがなく、固形油と液状油とノニオン性界面活性剤とを主成分とする油性クレンジング化粧料であることから、メイクアップ化粧料の除去性能に優れるという特徴を有する。 In recent years, oil-based solid cleansing cosmetics have been proposed for the purpose of removing makeup cosmetics. Since oil-based solid cleansing cosmetics are solid at room temperature, they do not drip during use, and because they are oil-based cleansing cosmetics whose main ingredients are solid oil, liquid oil, and nonionic surfactant. It has the characteristic of having excellent makeup cosmetic removal performance.
特許文献1には、融点が60~120℃の炭化水素油、エステル油、所定のノニオン性界面活性剤を所定量含有することで、メイクアップ化粧料とのなじみ性が良く、汚れ落ちに優れ、かつ洗浄後のさっぱり感に優れる固形状油性クレンジング化粧料が得られることが開示されている。しかしながら、炭粉末などの粉体成分を配合することについては開示されていない。 Patent Document 1 discloses that by containing a predetermined amount of a hydrocarbon oil with a melting point of 60 to 120°C, an ester oil, and a predetermined nonionic surfactant, it has good compatibility with makeup cosmetics and is excellent in removing stains. It is disclosed that a solid oil-based cleansing cosmetic composition which also provides an excellent refreshing feeling after washing can be obtained. However, there is no disclosure about blending powder components such as charcoal powder.
また、特許文献2には、固形油分、液状油、特定のHLB値を有するノニオン性界面活性剤と共に、粉体及び煙霧状シリカを特定比率で含有することで、たれ落ちがなく、クレンジング力及びマッサージ効果が高く、洗い流しやすさと洗い流し後のさっぱり感に優れ、且つ、品質の安定性に優れる油性固形クレンジング化粧料が得られることが開示されている。しかしながら、炭粉末を均一に配合する技術については開示されていない。 In addition, Patent Document 2 discloses that powder and fumed silica are contained in a specific ratio along with solid oil, liquid oil, and a nonionic surfactant having a specific HLB value, so that there is no dripping and cleansing power and It is disclosed that an oil-based solid cleansing cosmetic can be obtained which has a high massage effect, is easy to wash off, provides a refreshing feeling after washing off, and has excellent quality stability. However, a technique for uniformly blending charcoal powder is not disclosed.
油性固形状クレンジング化粧料は、前記の主成分とその他の成分とを溶融させ、固化させることで調製される。よって、炭粉末などの凝集及び沈降する性質を有する成分を配合する場合、固化するまでに凝集や沈降が発生してしまい、不均一な組成になりやすいという問題があった。 Oil-based solid cleansing cosmetics are prepared by melting and solidifying the main component and other components. Therefore, when a component such as charcoal powder that has the property of agglomerating and settling is blended, there is a problem that aggregation and settling occur before solidification, which tends to result in a non-uniform composition.
本発明の目的は、炭粉末を含有するにも関わらず、炭粉末が凝集及び沈降することなく、炭粉末の分散性に優れた油性固形状クレンジング化粧料を提供することにある。 An object of the present invention is to provide an oil-based solid cleansing cosmetic that does not cause agglomeration or sedimentation of the charcoal powder and has excellent dispersibility of the charcoal powder even though it contains charcoal powder.
本発明者らは上記課題を解決すべく鋭意検討した結果、固形油、液状油、HLB値が2~6のノニオン性界面活性剤、HLB値が8~15のノニオン性界面活性剤、所定の炭粉末及び水を含有する油性固形状クレンジング化粧料とすることで、炭粉末が凝集及び沈降することなく、均一性に優れた油性固形状クレンジング化粧料が得られることを見出し、本発明を完成させた。 As a result of intensive studies to solve the above problems, the present inventors found that solid oil, liquid oil, nonionic surfactant with HLB value of 2 to 6, nonionic surfactant with HLB value of 8 to 15, and predetermined The present invention was completed based on the discovery that by making an oil-based solid cleansing cosmetic containing charcoal powder and water, an oil-based solid cleansing cosmetic with excellent uniformity can be obtained without the charcoal powder coagulating or settling. I let it happen.
すなわち、本発明は、下記成分Aを4.0~20質量%、下記成分Bを50~90質量%、下記成分Cを0.01~5.0質量%、下記成分Dを8~22質量%、下記成分Eを0.01~5.0質量%、下記成分Fを0.5~6.0質量%含有する油性固形状クレンジング化粧料に関する。
成分A:融点が50~120℃である固形油
成分B:液状油
成分C:HLB値が2~6のノニオン性界面活性剤
成分D:HLB値が8~15のノニオン性界面活性剤
成分E:体積基準のメジアン径が1~35μmの炭粉末
成分F:水
That is, in the present invention, the following component A is 4.0 to 20 mass%, the following component B is 50 to 90 mass%, the following component C is 0.01 to 5.0 mass%, and the following component D is 8 to 22 mass%. %, an oil-based solid cleansing cosmetic containing 0.01 to 5.0 mass % of the following component E and 0.5 to 6.0 mass % of the following component F.
Component A: Solid oil having a melting point of 50 to 120°C Component B: Liquid oil component C: Nonionic surfactant component D having an HLB value of 2 to 6: Nonionic surfactant component E having an HLB value of 8 to 15 : Charcoal powder component with a volume-based median diameter of 1 to 35 μm F: Water
本発明の油性固形状クレンジング化粧料は、炭粉末を含有するにも関わらず、炭粉末が凝集及び沈降することなく、炭粉末の分散性に優れた油性固形状クレンジング化粧料である。 Although the oil-based solid cleansing cosmetic composition of the present invention contains charcoal powder, the charcoal powder does not aggregate or settle, and the charcoal powder has excellent dispersibility.
本発明の油性固形状クレンジング化粧料は、融点が50~120℃である固形油(成分A)、液状油(成分B)、HLB値が2以上6未満のノニオン性界面活性剤(成分C)、HLB値が8~15のノニオン性界面活性剤(成分D)、体積基準のメジアン径が1~35μmの炭粉末(成分E)、及び水(成分F)を所定量含有することを特徴とする。 The oil-based solid cleansing cosmetic of the present invention comprises a solid oil (component A) with a melting point of 50 to 120°C, a liquid oil (component B), and a nonionic surfactant with an HLB value of 2 or more and less than 6 (component C). , a nonionic surfactant with an HLB value of 8 to 15 (component D), charcoal powder with a volume-based median diameter of 1 to 35 μm (component E), and water (component F) in predetermined amounts. do.
すなわち、本発明の油性固形状クレンジング化粧料は、成分A、成分B、成分C、成分D、成分E、及び成分Fを少なくとも含有する。本発明の油性固形状クレンジング化粧料は、求める使用感などに応じて、さらに、必須成分である成分A~F以外の成分を含んでいてもよい。本発明の油性固形状クレンジング化粧料に含まれる上記成分A~F及び他の成分などの各成分は、それぞれ、1種のみを用いてもよいし、2種以上を用いてもよい。 That is, the oil-based solid cleansing cosmetic of the present invention contains at least component A, component B, component C, component D, component E, and component F. The oil-based solid cleansing cosmetic composition of the present invention may further contain components other than the essential components A to F, depending on the desired feeling of use. Each of the above-mentioned components A to F and other components contained in the oil-based solid cleansing cosmetic composition of the present invention may be used alone or in combination of two or more.
本発明の油性固形状クレンジング化粧料は、常温で固形状であることから、使用時の垂れ落ちがなく、固形油と液状油とノニオン性界面活性剤とを主成分とする油性クレンジング化粧料であることから、メイクアップ化粧料の除去性能に優れるという特徴を有する。さらに、本発明の油性固形状クレンジング化粧料は、所定の炭粉末を配合し、成分A及び成分Bの配合量を所定の範囲とし、所定量の成分C及び成分Fとを配合することから、炭粉末を含有するにも関わらず、炭粉末が凝集及び沈降することなく、炭粉末の分散性優れるという特徴を有する。 Since the oil-based solid cleansing cosmetic of the present invention is solid at room temperature, it does not drip during use, and is an oil-based cleansing cosmetic whose main ingredients are solid oil, liquid oil, and nonionic surfactant. Because of this, it has the characteristic of being excellent in the removal performance of makeup cosmetics. Furthermore, the oil-based solid cleansing cosmetic of the present invention is formulated with a predetermined charcoal powder, the amount of component A and component B is within a predetermined range, and a predetermined amount of component C and component F is blended. Despite containing charcoal powder, the charcoal powder does not agglomerate or settle, and is characterized by excellent dispersibility of the charcoal powder.
以下に、本発明の油性固形状クレンジング化粧料の必須成分である成分A~Fについて説明する。 Components A to F, which are essential components of the oil-based solid cleansing cosmetic composition of the present invention, will be explained below.
[成分A]
成分Aは25℃で固形であり、融点が50~120℃である固形油である。なお、本明細書において、「25℃で固形」とは、25℃で流動性がない性状を意味する。また、成分Aの融点は、医薬部外品原料規格の一般試験法である融点測定法第2法によって測定することができる。
[Component A]
Component A is a solid oil that is solid at 25°C and has a melting point of 50-120°C. In addition, in this specification, "solid at 25 degreeC" means the property which has no flowability at 25 degreeC. Further, the melting point of component A can be measured by Melting Point Measurement Method 2, which is a general test method of the Standard for Quasi-drug Raw Materials.
成分Aの融点は、調製時に均一な固形状に成型できる(成型性)という観点、及び経時安定性の観点から50℃以上であり、55℃以上が好ましく、60℃以上がより好ましい、また、成分Aの融点は、使用時の指取れ及び塗布時の感触(使用感)の観点から120℃以下であり、115℃以下が好ましく、110℃以下がより好ましい。 The melting point of component A is 50°C or higher, preferably 55°C or higher, more preferably 60°C or higher, from the viewpoint of being able to be molded into a uniform solid shape during preparation (moldability) and stability over time. The melting point of component A is 120° C. or lower, preferably 115° C. or lower, and more preferably 110° C. or lower, from the viewpoint of finger removal during use and feel (feel in use) during application.
成分Aとしては、動植物ワックス等のワックスエステル、鉱物ワックス、炭化水素ワックス等が挙げられる。 Examples of component A include wax esters such as animal and vegetable waxes, mineral waxes, and hydrocarbon waxes.
上記動植物ワックスとしては、カルナウバワックス、ヒマワリ種子ワックス、キャンデリラワックス、モクロウ、ミツロウ、ライスワックス、コメヌカワックス、セラックロウ及び鯨ロウなどが挙げられる。 Examples of the animal and plant waxes include carnauba wax, sunflower seed wax, candelilla wax, Japanese wax, beeswax, rice wax, rice bran wax, shellac wax, spermaceti wax, and the like.
上記鉱物ワックスとしては、モンタンワックス等が挙げられる。 Examples of the mineral wax include montan wax and the like.
上記炭化水素ワックスは、石油由来のワックスであってもよく、合成ワックスであってもよい。上記炭化水素ワックスとしては、例えば、セレシン、オゾケライト、パラフィンワックス、マイクロクリスタリンワックス、ポリエチレンワックス、エチレン-プロピレンコポリマー及びフィッシャー・トロプシュワックス(合成ワックス)等が挙げられる。 The hydrocarbon wax may be a petroleum-derived wax or a synthetic wax. Examples of the hydrocarbon wax include ceresin, ozokerite, paraffin wax, microcrystalline wax, polyethylene wax, ethylene-propylene copolymer, and Fischer-Tropsch wax (synthetic wax).
成分Aとしては、加熱時に酸化が起こりにくく均一な油性固形状クレンジング化粧料が得られるという観点から、炭化水素ワックスが好ましく、マイクロクリスタリンワックス、及びフィッシャー・トロプシュワックス(合成ワックス)がより好ましい。 As component A, hydrocarbon wax is preferable, and microcrystalline wax and Fischer-Tropsch wax (synthetic wax) are more preferable, from the viewpoint that oxidation is unlikely to occur during heating and a uniform oil-based solid cleansing cosmetic composition can be obtained.
本発明の油性固形状クレンジング化粧料中の成分Aの含有量は、4.0~20質量%であり、好ましくは4.2~18質量%であり、より好ましくは4.4~16質量%である。上記含有量が4.0質量%以上であると、成型性に優れ、炭粉末の凝集及び沈降抑制効果に優れる。また、上記含有量が20質量%以下であると、使用感に優れ、硬化し過ぎて起こる輸送時などの崩壊を抑制できる。上記成分Aの含有量は、本発明の油性固形状クレンジング化粧料中の全ての成分Aの含有量の合計である。 The content of component A in the oil-based solid cleansing cosmetic of the present invention is 4.0 to 20% by mass, preferably 4.2 to 18% by mass, and more preferably 4.4 to 16% by mass. It is. When the content is 4.0% by mass or more, moldability is excellent and the effect of suppressing agglomeration and sedimentation of charcoal powder is excellent. Moreover, when the content is 20% by mass or less, the usability is excellent and it is possible to suppress collapse during transportation, which occurs due to excessive hardening. The above content of component A is the total content of all components A in the oil-based solid cleansing cosmetic composition of the present invention.
[成分B]
成分Bは、液状油であり、25℃で流動性がある性状を有する油分、融点が50℃未満である半固形油分、沸点が260℃未満の揮発性油分が含まれる。成分Bを用いることで、使用時に指取れし易くなり、また、塗布時における伸び及びメイクなじみに優れた油性固形状クレンジング化粧料とすることができる。
[Component B]
Component B is a liquid oil, and includes an oil component having fluidity at 25°C, a semi-solid oil component having a melting point of less than 50°C, and a volatile oil component having a boiling point of less than 260°C. By using component B, it is possible to obtain an oil-based solid cleansing cosmetic that is easy to remove from fingers during use, and has excellent spreadability and makeup compatibility when applied.
成分Bとしては、エステル油、動植物油、炭化水素油、シリコーン油、高級脂肪酸、高級アルコールなどが挙げられる。 Component B includes ester oils, animal and vegetable oils, hydrocarbon oils, silicone oils, higher fatty acids, higher alcohols, and the like.
上記エステル油としては、イソステアリン酸イソセチル、ジ-2-エチルヘキサン酸エチレングリコール、2-エチルヘキサン酸セチル、トリ-2-エチルヘキサン酸トリメチロールプロパン、テトラ-2-エチルヘキサン酸ペンタエリトリット、オクタン酸セチル、テトラオクタン酸ペンタエリスリル、トリ-2-ヘプチルウンデカン酸グリセライド、アジピン酸ジイソブチル、セバシン酸2-ヘキシルデシル、トリオクタン酸グリセリン、トリイソパルミチン酸グリセリン、リンゴ酸ジイソステアリル、イソプロピルミリステート、2-オクチルドデシルオレエート、ジメチルオクタン酸ヘキシルデシル、ミリスチン酸2-ヘキシルデシル、ミリスチン酸ミリスチル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、2-エチルヘキシルパルミテート、パルミチン酸2-ヘキシルデシル、パルミチン酸2-ヘプチルウンデシル、ステアリン酸ブチル、ステアリン酸イソセチル、オレイン酸デシル、ドデシルオレエート、オレイン酸オレイル、乳酸ミリスチル、乳酸セチル、12-ヒドロキシステアリン酸コレステリル、ヒマシ油脂肪酸メチルエステル、コハク酸2-エチルヘキシル、アジピン酸2-ヘキシルデシル、アジピン酸ジ-2-ヘプチルウンデシル、セバチン酸ジイソプロピル、セバチン酸ジ-2-エチルヘキシル、ジカプリン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、トリ-2-エチルヘキサン酸グリセリン、トリミリスチン酸グリセリン、トリ-2-ヘプチルウンデカン酸グリセライド、トリイソステアリン酸トリメチロールプロパン、トリ2-エチルヘキサン酸グリセリル、トリオクタン酸グリセリン、トリイソパルミチン酸グリセリン、トリグリセリン、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ラウリン酸へキシル、オレイン酸オレイル、オレイン酸デシル、ミリスチン酸オクチルドデシル、ジメチルオクタン酸ヘキシルデシル、フタル酸ジエチル、フタル酸ジブチル、コハク酸ジオクチル、フッ素変性エステル油、トリオクタノイン、ジピバリン酸トリプロピレングリコール等が挙げられる。 The above ester oils include isocetyl isostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, and octane. Cetyl acid, pentaerythryl tetraoctoate, tri-2-heptylundecanoic acid glyceride, diisobutyl adipate, 2-hexyldecyl sebacate, glyceryl trioctanoate, glyceryl triisopalmitate, diisostearyl malate, isopropyl myristate, 2-Octyldodecyloleate, hexyldecyl dimethyloctanoate, 2-hexyldecyl myristate, myristyl myristate, octyldodecyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-hexyldecyl palmitate Heptyl undecyl, butyl stearate, isocetyl stearate, decyl oleate, dodecyl oleate, oleyl oleate, myristyl lactate, cetyl lactate, cholesteryl 12-hydroxystearate, castor oil fatty acid methyl ester, 2-ethylhexyl succinate, adipine 2-hexyldecyl acid, di-2-heptylundecyl adipate, diisopropyl sebatate, di-2-ethylhexyl sebatate, neopentyl glycol dicaprate, neopentyl glycol dioctoate, glycerin tri-2-ethylhexanoate, Glyceryl myristate, tri-2-heptylundecanoic acid glyceride, trimethylolpropane triisostearate, glyceryl tri2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, triglycerin, isopropyl myristate, isopropyl palmitate, laurin Hexyl acid, oleyl oleate, decyl oleate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, diethyl phthalate, dibutyl phthalate, dioctyl succinate, fluorine-modified ester oil, trioctanoin, tripropylene glycol dipivalate, etc. can be mentioned.
上記動植物油としては、アマニ油、ツバキ油、マカデミアナッツ油、トウモロコシ油、ミンク油、オリーブ油、アボガド油、サザンカ油、ヒマシ油、サフラワー油、キョウニン油、シナモン油、ホホバ油、ブドウ油、ヒマワリ油、アルモンド油、ナタネ油、ゴマ油、小麦胚芽油、米胚芽油、米ヌカ油、綿実油、大豆油、落花生油、茶実油、月見草油、卵黄油、牛脚脂、肝油等が挙げられる。 The animal and vegetable oils mentioned above include linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanquat oil, castor oil, safflower oil, kyonin oil, cinnamon oil, jojoba oil, grape oil, and sunflower oil. , almond oil, rapeseed oil, sesame oil, wheat germ oil, rice germ oil, rice bran oil, cottonseed oil, soybean oil, peanut oil, tea seed oil, evening primrose oil, egg yolk oil, beef leg fat, and liver oil.
上記炭化水素油としては、α-オレフィンオリゴマー、軽質イソパラフィン、軽質流動イソパラフィン、流動イソパラフィン、流動パラフィン、合成スクワラン、植物性スクワラン、ポリブテン、水添ポリイソブテン、ワセリン等が挙げられる。 Examples of the hydrocarbon oil include α-olefin oligomer, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, liquid paraffin, synthetic squalane, vegetable squalane, polybutene, hydrogenated polyisobutene, petrolatum, and the like.
上記シリコーン油としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン等の鎖状シリコーン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン等の環状シリコーン、アミノ変性シリコーン油、ポリエーテル変性シリコーン油、カルボキシ変性シリコーン油、アルキル変性シリコーン油、アンモニウム塩変性シリコーン油、フッ素変性シリコーン油等が挙げられる。 Examples of the silicone oil include linear silicones such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane, cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane, and amino-modified silicones. Examples include silicone oil, polyether-modified silicone oil, carboxy-modified silicone oil, alkyl-modified silicone oil, ammonium salt-modified silicone oil, and fluorine-modified silicone oil.
上記高級脂肪酸としては、オレイン酸、トール油脂肪酸、イソステアリン酸等が挙げられる。 Examples of the higher fatty acids include oleic acid, tall oil fatty acid, isostearic acid, and the like.
上記高級アルコールとしては、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、オクチルドデカノール、ホホバアルコール等が挙げられる。 Examples of the higher alcohol include lauryl alcohol, oleyl alcohol, isostearyl alcohol, octyldodecanol, jojoba alcohol, and the like.
本発明の油性固形状クレンジング化粧料中の成分Bの含有量は、50~90質量%であり、好ましくは60~88質量%であり、より好ましくは70~86質量%である。上記含有量が50質量%以上であると、使用時の指取れや塗布時の伸びなじみに優れる。また、上記含有量が90質量%以下であると、成型性に優れる。上記成分Bの含有量は、本発明の油性固形状クレンジング化粧料中の全ての成分Bの含有量の合計である。 The content of component B in the oil-based solid cleansing cosmetic composition of the present invention is 50 to 90% by mass, preferably 60 to 88% by mass, and more preferably 70 to 86% by mass. When the content is 50% by mass or more, it is excellent in finger removal during use and spreadability during application. Moreover, when the content is 90% by mass or less, moldability is excellent. The above content of component B is the total content of all component B in the oil-based solid cleansing cosmetic composition of the present invention.
[成分C]
成分Cは、HLB値が2~6のノニオン性界面活性剤である。HLB値が6以下のノニオン性界面活性剤は、親水性が低く、親油性が高いノニオン性界面活性剤である。このようなノニオン性界面活性剤を、油性固形状クレンジング化粧料に配合した場合、クレンジング後に水またはぬるま湯で洗い落そうとしても、水との親和性が低いために洗い流すことが困難であり、クレンジング化粧料のぬるぬる感が感じられなくなるまでに時間を要するという問題がある。このため、油性固形状クレンジング化粧料にHLB値が低いノニオン性界面活性剤の配合は一般的に忌避される。しかしながら、特定量の成分C及び水を、炭粉末と組み合わせて用いることで、上記の問題を発生させずに、かつ炭粉末の凝集及び沈降を抑制できる。
[Component C]
Component C is a nonionic surfactant with an HLB value of 2 to 6. A nonionic surfactant with an HLB value of 6 or less is a nonionic surfactant with low hydrophilicity and high lipophilicity. When such a nonionic surfactant is blended into an oil-based solid cleansing cosmetic, even if you try to wash it off with water or lukewarm water after cleansing, it is difficult to wash it off due to its low affinity with water. There is a problem in that it takes time until the slimy feeling of the cosmetic is no longer felt. For this reason, the combination of nonionic surfactants with low HLB values in oil-based solid cleansing cosmetics is generally avoided. However, by using specific amounts of component C and water in combination with the charcoal powder, the above-mentioned problems can be avoided and the agglomeration and sedimentation of the charcoal powder can be suppressed.
成分CのHLB値は、2~6であり、好ましくは2~5、より好ましくは2~4である。上記HLB値が上記範囲内であることにより、炭粉末の凝集及び沈降を効果的に抑制できる。 The HLB value of component C is 2 to 6, preferably 2 to 5, more preferably 2 to 4. When the HLB value is within the above range, agglomeration and sedimentation of the charcoal powder can be effectively suppressed.
成分Cとしては、HLB値が2~6のノニオン性界面活性剤であれば特に限定されないが、トリイソステアリン酸ポリグリセリル-2、トリイソステアリン酸PEG-20水添ヒマシ油、トリイソステアリン酸PEG-5グリセリル、モノステアリン酸グリセリル、モノステアリン酸ジグリセリル、ペンタステアリン酸デカグリセリル、セスキステアリン酸ソルビタン、モノオレイン酸ソルビタン等が挙げられる。なかでも、洗い流し時の残り感などの使用感を損なうことなく、炭粉末の凝集及び沈降を抑制できることから、トリイソステアリン酸ポリグリセリル-2が好ましい。 Component C is not particularly limited as long as it is a nonionic surfactant with an HLB value of 2 to 6, but includes polyglyceryl-2 triisostearate, PEG-20 triisostearate, hydrogenated castor oil, and PEG-5 glyceryl triisostearate. , glyceryl monostearate, diglyceryl monostearate, decaglyceryl pentasteate, sorbitan sesquistearate, sorbitan monooleate, and the like. Among these, polyglyceryl-2 triisostearate is preferred because it can suppress agglomeration and sedimentation of charcoal powder without impairing the feeling of use, such as the residual feeling when washed away.
本発明の油性固形状クレンジング化粧料中の成分Cの含有量は、0.01~5.0質量%であり、好ましくは0.01~4.0質量%である。上記含有量が0.01質量%以上であると、炭粉末の凝集及び沈降を抑制できる。また、上記含有量が5.0質量%以下であると、洗い流し時の残り感を損なうことなく、炭粉末の凝集及び沈降を抑制できる。上記成分Cの含有量は、本発明の油性固形状クレンジング化粧料中の全ての成分Cの含有量の合計である。 The content of component C in the oil-based solid cleansing cosmetic composition of the present invention is 0.01 to 5.0% by mass, preferably 0.01 to 4.0% by mass. When the content is 0.01% by mass or more, agglomeration and sedimentation of the charcoal powder can be suppressed. Further, when the content is 5.0% by mass or less, agglomeration and sedimentation of the charcoal powder can be suppressed without impairing the residual feeling when washing away. The above content of component C is the total content of all components C in the oil-based solid cleansing cosmetic composition of the present invention.
[成分D]
成分Dは、HLB値が8~15のノニオン性界面活性剤である。成分Dを用いることにより、使用時のメイクなじみに優れ、洗い流し時の残り感が低い油性固形状クレンジング化粧料とすることができる。なお、本明細書におけるHLB値は、グリフィン(Griffin)法により算出することができる。
[Component D]
Component D is a nonionic surfactant with an HLB value of 8 to 15. By using component D, it is possible to obtain an oil-based solid cleansing cosmetic that has excellent makeup compatibility during use and has a low residual feeling when washed off. Note that the HLB value in this specification can be calculated by the Griffin method.
成分DのHLB値は、8~15であり、好ましくは8~14、より好ましくは8~13である。上記HLB値が上記範囲内であることにより、使用時のメイクなじみ、及び洗い流し性に優れる。 The HLB value of component D is 8 to 15, preferably 8 to 14, more preferably 8 to 13. When the above HLB value is within the above range, makeup blendability during use and washability are excellent.
成分Dとしては、HLB値が8~15のノニオン性界面活性剤であれば特に限定されないが、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、モノグリセリン脂肪酸エステル、及びこれらのアルキレンオキシド付加物、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレン脂肪酸エステル、ポリオキシアルキレンアルキルフェノール、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレンアルキルフェニルホルムアルデヒド縮合物、ポリオキシエチレンステロール及びその誘導体、ポリオキシエチレンラノリン及びその誘導体、ポリオキシエチレンミツロウ誘導体、シュガーエステル類、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油等が挙げられる。 Component D is not particularly limited as long as it is a nonionic surfactant with an HLB value of 8 to 15, but polyglycerin fatty acid esters, sorbitan fatty acid esters, monoglycerin fatty acid esters, alkylene oxide adducts thereof, polyoxyalkylene Alkyl ether, polyoxyalkylene fatty acid ester, polyoxyalkylene alkylphenol, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene alkylphenyl formaldehyde condensate, polyoxyethylene sterol and its derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene beeswax Examples include derivatives, sugar esters, polyoxyethylene hydrogenated castor oil, and polyoxyethylene castor oil.
成分Dは、使用時のメイクなじみに優れ、洗い流し後の肌にもっちりとした後肌感が得られるという観点から、ポリグリセリン脂肪酸エステルを含むことが好ましい。ポリグリセリン脂肪酸エステルとしては、ジカプリン酸ポリグリセリル-6、ジオレイン酸ポリグリセリル-10、カプリル酸ポリグリセリル-6、カプリン酸ポリグリセリル-2等が挙げられる。 Component D preferably contains a polyglycerin fatty acid ester, from the viewpoint of providing excellent make-up compatibility during use and providing a firm after-skin feel after rinsing. Examples of polyglycerin fatty acid esters include polyglyceryl-6 dicaprate, polyglyceryl-10 dioleate, polyglyceryl-6 caprylate, and polyglyceryl-2 caprate.
本発明の油性固形状クレンジング化粧料中の成分Dの含有量は、8~22質量%であり、好ましくは9~21質量%であり、より好ましくは10~20質量%である。上記含有量が8質量%以上であると、使用時のメイクなじみに優れる。また、上記含有量が22質量%以下であると、洗い流し性に優れる。 The content of component D in the oil-based solid cleansing cosmetic composition of the present invention is 8 to 22% by mass, preferably 9 to 21% by mass, and more preferably 10 to 20% by mass. When the content is 8% by mass or more, makeup blends well during use. Moreover, when the content is 22% by mass or less, the washability is excellent.
また、成分Dとしてポリグリセリン脂肪酸エステルを含有する場合、本発明の油性固形状クレンジング化粧料中のポリグリセリン脂肪酸エステルの含有量は、0.1~6.0質量%が好ましく、より好ましくは0.5~4.0質量%である。上記含有量が0.1質量%以上であると、洗い流し後の肌にもっちりとした後肌感が得られる。また、上記含有量が6.0質量%以下であると、洗い流し性により優れる。 Furthermore, when a polyglycerol fatty acid ester is contained as component D, the content of the polyglycerol fatty acid ester in the oil-based solid cleansing cosmetic of the present invention is preferably 0.1 to 6.0% by mass, more preferably 0. .5 to 4.0% by mass. When the content is 0.1% by mass or more, the skin feels firm after washing off. Moreover, when the content is 6.0% by mass or less, the washability is better.
[成分E]
成分Eは、所定の体積基準のメジアン径(以下、単にメジアン径とも記載する)を有する炭粉末である。成分Eを用いることにより、メイク汚れや皮脂汚れを炭粉末が吸着し、クレンジング力により優れる油性固形状クレンジング化粧料となる。油性固形状クレンジング化粧料の調製工程において炭粉末が凝集して沈降し、組成が不均一になるという問題があるが、所定量の成分C及び水と併用することで凝集及び沈降を抑制し、炭粉末の分散性に優れた油性固形状クレンジング化粧料とすることができる。
[Component E]
Component E is charcoal powder having a predetermined volume-based median diameter (hereinafter also simply referred to as median diameter). By using component E, the charcoal powder adsorbs makeup stains and sebum stains, resulting in an oil-based solid cleansing cosmetic with superior cleansing power. In the preparation process of oil-based solid cleansing cosmetics, there is a problem that charcoal powder aggregates and settles, resulting in non-uniform composition, but when used in combination with a predetermined amount of component C and water, aggregation and sedimentation can be suppressed, An oil-based solid cleansing cosmetic with excellent dispersibility of charcoal powder can be obtained.
成分Eは、特に限定されないが、多孔質の炭素物質であり、炭素以外にも、水素、酸素、無機成分等を含んでいてもよい。また、炭素物質を原料として高温でガスや薬品と反応させて作られる微細孔を持つ活性炭であることが好ましい。 Component E is a porous carbon material, although not particularly limited, and may contain hydrogen, oxygen, inorganic components, etc. in addition to carbon. Furthermore, it is preferable to use activated carbon with micropores, which is produced by reacting carbon material as a raw material with gas or chemicals at high temperatures.
成分Eの原料としては、特に限定されず、炭粉末の原料として一般的に用いられるものを用いることができる。具体的には、例えば、ヤシ殻、竹、木材、おが屑、石炭、フェノール樹脂、レーヨン、アクリロニトリル、石炭ピッチ、石油ピッチ等が挙げられる。中でも、ヤシ殻、竹、及び木材が好ましい。 The raw material for component E is not particularly limited, and those commonly used as raw materials for charcoal powder can be used. Specific examples include coconut shell, bamboo, wood, sawdust, coal, phenol resin, rayon, acrylonitrile, coal pitch, petroleum pitch, and the like. Among these, coconut shell, bamboo, and wood are preferred.
成分Eのメジアン径は、クレンジング力の観点から1μm以上であり、好ましくは3μm以上である。また、成分Eのメジアン径は、凝集及び沈降の抑制という観点及び洗い流し後の残り感の観点から35μm以下であり、好ましくは32μm以下である。 The median diameter of component E is 1 μm or more, preferably 3 μm or more from the viewpoint of cleansing power. In addition, the median diameter of component E is 35 μm or less, preferably 32 μm or less, from the viewpoint of suppressing aggregation and sedimentation and from the viewpoint of residual feeling after washing.
本明細書において、炭粉末の体積基準のメジアン径は、レーザー解析/散乱式粒子径分布測定法により測定することができ、例えば、「粒度分布計LA-950V2」(堀場製作所社製)により測定した値とすることができる。 In this specification, the volume-based median diameter of charcoal powder can be measured by laser analysis/scattering particle size distribution measuring method, for example, by "particle size distribution meter LA-950V2" (manufactured by Horiba, Ltd.). The value can be set as follows.
本発明の油性固形状クレンジング化粧料中の成分Eの含有量は、0.01~5.0質量%であり、好ましくは0.02~4.0質量%であり、より好ましくは0.03~3.5質量%である。上記含有量が0.01質量%以上であると、炭粉末を配合することによる効果が得られる。また、上記含有量が5.0質量%以下であると、洗い流し性に優れ、成分Eの凝集及び沈降を抑制することができる。上記成分Eの含有量は、本発明の油性固形状クレンジング化粧料中の全ての成分Eの含有量の合計である。 The content of component E in the oil-based solid cleansing cosmetic of the present invention is 0.01 to 5.0% by mass, preferably 0.02 to 4.0% by mass, more preferably 0.03% by mass. ~3.5% by mass. When the content is 0.01% by mass or more, the effect of blending the charcoal powder can be obtained. Moreover, when the content is 5.0% by mass or less, the washability is excellent and aggregation and sedimentation of component E can be suppressed. The above content of component E is the total content of all components E in the oil-based solid cleansing cosmetic composition of the present invention.
[成分F]
成分Fは水であり、特に限定されないが、精製水が好ましい。油性固形状クレンジング化粧料は、固形油分、液状油、及びノニオン性界面活性剤を主成分とし、分離や析出の恐れがあることから水を含有しないことが一般的であるといえる。しかしながら、所定量の成分C及び成分Eと併用することで、成分Eの凝集及び沈降を抑制し、炭粉末の分散性に優れた油性固形状クレンジング化粧料とすることができる。
[Component F]
Component F is water, and although not particularly limited, purified water is preferred. Oil-based solid cleansing cosmetics have solid oils, liquid oils, and nonionic surfactants as main components, and generally do not contain water to avoid separation or precipitation. However, by using it in combination with predetermined amounts of component C and component E, agglomeration and sedimentation of component E can be suppressed, and an oil-based solid cleansing cosmetic with excellent dispersibility of charcoal powder can be obtained.
本発明の油性固形状クレンジング化粧料中の成分Fの含有量は、0.5~6.0質量%であり、好ましくは0.6~5.5質量%であり、より好ましくは0.8~4.0質量%である。上記含有量が0.5質量%以上であると、成分Eの凝集及び沈降を抑制することができる。また、上記含有量が6.0質量%以下であると、使用時のメイクなじみに優れる。上記成分Fの含有量は、本発明の油性固形状クレンジング化粧料中の全ての成分Fの含有量の合計である。 The content of component F in the oil-based solid cleansing cosmetic composition of the present invention is 0.5 to 6.0% by mass, preferably 0.6 to 5.5% by mass, more preferably 0.8% by mass. ~4.0% by mass. When the content is 0.5% by mass or more, aggregation and sedimentation of component E can be suppressed. Moreover, when the content is 6.0% by mass or less, makeup blendability during use is excellent. The above content of component F is the total content of all components F in the oil-based solid cleansing cosmetic composition of the present invention.
[その他の成分]
本発明の油性固形状クレンジング化粧料は、成分A~F以外に、本発明の効果を損なわない範囲で、その他の成分を任意成分として含有してもよい。
[Other ingredients]
In addition to components A to F, the oil-based solid cleansing cosmetic composition of the present invention may optionally contain other components as long as the effects of the present invention are not impaired.
その他の成分としては、成分C及び成分D以外の界面活性剤、成分E以外の粉体、染料、油性ゲル化剤、油溶性樹脂、多価アルコール類、低級アルコール、美白剤、賦活剤、血行促進剤、抗脂漏剤、抗炎症剤、清涼剤(別名;冷感剤)、殺菌成分、制汗成分、紫外線吸収剤、紫外線散乱剤、保湿剤、香料、酸化防止剤、防腐剤、消泡剤、各種エキス等の添加剤などが挙げられる。 Other ingredients include surfactants other than component C and component D, powders other than component E, dyes, oil-based gelling agents, oil-soluble resins, polyhydric alcohols, lower alcohols, whitening agents, activators, and blood circulation agents. Accelerator, antiseborrheic agent, anti-inflammatory agent, refreshing agent (also known as cooling agent), bactericidal ingredient, antiperspirant ingredient, ultraviolet absorber, ultraviolet scattering agent, humectant, fragrance, antioxidant, preservative, disinfectant. Examples include additives such as foaming agents and various extracts.
[油性固形状クレンジング化粧料]
本発明の油性固形状クレンジング化粧料は、25℃で固形状である。上記固形状とは、流動性を有さないことを意味し、ペースト状やジェル状も含まれる。また、本発明の油性固形状クレンジング化粧料の形状は特に限定されず、スティック状、棒状、板状、ジャーなどの容器へ流し込み成形されたものなどが挙げられる。
[Oil-based solid cleansing cosmetic]
The oil-based solid cleansing cosmetic composition of the present invention is solid at 25°C. The above-mentioned solid form means not having fluidity, and includes paste form and gel form. Further, the shape of the oil-based solid cleansing cosmetic composition of the present invention is not particularly limited, and examples thereof include a stick shape, a bar shape, a plate shape, and a shape formed by pouring into a container such as a jar.
本発明の油性固形状クレンジング化粧料の製造方法は、特に限定されず、公知の油性固形状クレンジング化粧料の製造方法を採用することができる。本発明の油性固形状クレンジング化粧料の製造方法としては、例えば、加熱しながら各成分を混合して混合液を得た後、得られた混合液を冷却固化する方法等が挙げられる。各成分を混合する方法としては、ディスパーミキサー及びパドルミキサー等の撹拌装置を用いる方法等が挙げられる。但し、本発明は上述した製造方法にのみ限定されない。また、本発明の油性固形状クレンジング化粧料は、広口ジャー容器、チューブ容器などの容易に取り出すことが可能な容器に充填されることが好ましい。 The method for producing the oil-based solid cleansing cosmetic of the present invention is not particularly limited, and any known method for producing oil-based solid cleansing cosmetics can be employed. Examples of the method for producing the oil-based solid cleansing cosmetic of the present invention include a method in which each component is mixed while heating to obtain a mixed liquid, and then the obtained mixed liquid is cooled and solidified. Examples of the method for mixing each component include a method using a stirring device such as a disperse mixer and a paddle mixer. However, the present invention is not limited to the above-described manufacturing method. Moreover, the oil-based solid cleansing cosmetic composition of the present invention is preferably filled into a container that can be easily taken out, such as a wide-mouth jar container or a tube container.
本発明の油性固形状クレンジング化粧料を適用する部位としては、特に限定されず、例えば、顔(額、目元、目じり、頬、口元など)、身体(腕、肘、手の甲、指先、足、膝、かかと、首、脇、背中など)などが挙げられる。中でも、特に好ましくは顔である。 The areas to which the oil-based solid cleansing cosmetic of the present invention is applied are not particularly limited, and include, for example, the face (forehead, around the eyes, corners of the eyes, cheeks, mouth, etc.), the body (arms, elbows, backs of hands, fingertips, feet, knees, etc.). , heels, neck, armpits, back, etc.). Among these, the face is particularly preferred.
以下に、実施例に基づいて本発明をより詳細に説明するが、本発明はこれらの実施例にのみ限定されるものではない。なお、表に記載の配合量は、各成分の配合量(すなわち、各原料中の有効成分の配合量)であり、特記しない限り「質量%」で表す。また、表中の配合量における「-」は、その成分を配合していないことを示す。 The present invention will be explained in more detail below based on Examples, but the present invention is not limited only to these Examples. The blending amounts listed in the table are the blending amounts of each component (that is, the blending amounts of the active ingredients in each raw material), and are expressed in "% by mass" unless otherwise specified. In addition, "-" in the blending amount in the table indicates that the component is not blended.
実施例及び比較例
[各試料の調製]
表1及び表2に記した組成に従い、実施例及び比較例の油性固形状クレンジング化粧料を常法により調製し、下記評価試験に供した。評価結果は、表1及び2に併記する。
Examples and comparative examples [Preparation of each sample]
According to the compositions shown in Tables 1 and 2, oil-based solid cleansing cosmetics of Examples and Comparative Examples were prepared in a conventional manner and subjected to the following evaluation tests. The evaluation results are also listed in Tables 1 and 2.
表に記載の主な成分の詳細は次のとおりである。
<成分A>
合成ワックス:商品名「CireWax 80」、Cirebelle Fine Chemicals社製、融点:61~67℃
マイクロクリスタリンワックス:商品名「MULTIWAX W-835」、Sonneborn Inc社製、融点:73.9~79.4℃
<成分B>
エチルヘキサン酸セチル:商品名「NIKKOL-CIO」、日光ケミカルズ株式会社製
パルミチン酸エチルヘキシル:商品名「NIKKOL TGI-20」、日光ケミカルズ株式会社製
<成分C>
トリイソステアリン酸ポリグリセリル-2:商品名「コスモール 43V」、日清オイリオグループ株式会社製、HLB:2.5
<成分D>
トリイソステアリン酸PEG-20グリセリル:商品名「NIKKOL TGI-20」、日光ケミカルズ株式会社製、HLB:8
イソステアリン酸PEG-8グリセリル:商品名「ブラウノン RGL-8MISE」、青木油脂工業株式会社製、HLB:11.5
ジカプリン酸ポリグリセリル-6:商品名「サンソフトQ-102H-C」、太陽化学株式会社製、HLB:10.2
<成分E>
炭粉末1:商品名「薬用炭」、堀江生薬株式会社製、メジアン径:31.1μm
炭粉末2:商品名「微粉 備長炭末」、キリヤ化学株式会社製、メジアン径:1.2μm
炭粉末3:商品名「備長炭末」、キリヤ化学株式会社製、メジアン径:5.7μm
炭粉末4:商品名「竹炭パウダーMM」、株式会社ラテスト製、メジアン径:11.4μm
<その他成分>
炭粉末5:商品名「クラレコール PGW-20MD」、クラレケミカル株式会社製、メジアン径:36.9μm
Details of the main components listed in the table are as follows.
<Component A>
Synthetic wax: Product name "CireWax 80", manufactured by Cirebelle Fine Chemicals, melting point: 61-67°C
Microcrystalline wax: Product name “MULTIWAX W-835”, manufactured by Sonneborn Inc., melting point: 73.9-79.4°C
<Component B>
Cetyl ethylhexanoate: Product name "NIKKOL-CIO", manufactured by Nikko Chemicals Co., Ltd. Ethylhexyl palmitate: Product name "NIKKOL TGI-20", manufactured by Nikko Chemicals Co., Ltd. <Component C>
Polyglyceryl-2 triisostearate: Product name “Cosmol 43V”, manufactured by Nisshin Oilio Group Co., Ltd., HLB: 2.5
<Component D>
PEG-20 glyceryl triisostearate: Product name "NIKKOL TGI-20", manufactured by Nikko Chemicals Co., Ltd., HLB: 8
PEG-8 glyceryl isostearate: trade name "Brownon RGL-8MISE", manufactured by Aoki Yushi Kogyo Co., Ltd., HLB: 11.5
Polyglyceryl-6 dicaprate: Product name “Sunsoft Q-102HC”, manufactured by Taiyo Kagaku Co., Ltd., HLB: 10.2
<Component E>
Charcoal powder 1: Trade name "Medicinal charcoal", manufactured by Horie Herbal Medicine Co., Ltd., median diameter: 31.1 μm
Charcoal powder 2: Product name “Fine Bincho Charcoal Powder”, manufactured by Kiriya Chemical Co., Ltd., median diameter: 1.2 μm
Charcoal powder 3: Trade name “Bincho charcoal powder”, manufactured by Kiriya Chemical Co., Ltd., median diameter: 5.7 μm
Charcoal powder 4: Product name “Bamboo charcoal powder MM”, manufactured by Latest Co., Ltd., median diameter: 11.4 μm
<Other ingredients>
Charcoal powder 5: Product name “Kuraray Coal PGW-20MD”, manufactured by Kuraray Chemical Co., Ltd., median diameter: 36.9 μm
[製剤評価]
調製後の実施例及び比較例の各油性固形状クレンジング化粧料の外観を目視にて観察し、下記評価基準にしたがい評価した。
[Formulation evaluation]
The appearance of each of the oil-based solid cleansing cosmetics of Examples and Comparative Examples after preparation was visually observed and evaluated according to the following evaluation criteria.
<均一性>
A(優良):粉体が均一に分散しており沈降及び色味のグラデーションが確認できない。
B(良好):粉体が化粧量全体に分散しているが、Aと比較すると若干のグラデーションが確認できる。
C(実用可):粉体が化粧量全体に分散しているが、グラデーションが確認できる。実用上の問題はない。
D(不良):下端から1/3以上の層に粉体の沈降が確認できる。
<Uniformity>
A (Excellent): The powder is uniformly dispersed, and no sedimentation or color gradation is observed.
B (Good): Powder is dispersed throughout the makeup amount, but compared to A, some gradation can be observed.
C (practical): Powder is dispersed throughout the makeup amount, but gradation can be observed. There are no practical problems.
D (Poor): Powder sedimentation can be observed in 1/3 or more of the layer from the bottom.
[使用感評価]
前腕内側部に市販のリキッドファンデーション約0.05gを塗布後、半径約2cmの円となるように均一に延び広げた。次いで、実施例及び比較例で得られた各油性固形状クレンジング化粧料約0.5gを塗布部のメイク汚れに塗布し、十分馴染ませた後、指先で小さな円を描くように30秒間クレンジングを行い、その後温水でメイク汚れを洗い流した。メイクなじみ、洗い流し性、及び後肌感を、下記評価基準にしたがい評価した。なお、評価は専門評価員3名の合議体の協議の結果で決定した。
[Usability evaluation]
Approximately 0.05 g of commercially available liquid foundation was applied to the inner side of the forearm, and then spread out uniformly to form a circle with a radius of approximately 2 cm. Next, apply about 0.5 g of each oil-based solid cleansing cosmetic obtained in Examples and Comparative Examples to the makeup stains on the application area, and after thoroughly blending, cleanse for 30 seconds in small circular motions with your fingertips. After that, I washed off the makeup stains with warm water. Make-up blendability, washability, and after-skin feel were evaluated according to the following evaluation criteria. The evaluation was decided based on the results of discussions by a panel of three expert evaluators.
<メイクなじみ>
A(優良):メイク馴染みが良く、メイク汚れがしっかりと落ちていた。
B(良好):メイク馴染みにおいてAよりは劣るが、メイク汚れがしっかりと落ちていた。
C(実用可):メイク馴染みにおいてBよりは劣るが、メイク汚れがしっかりと落ちていた。
D(不良):メイク馴染みに劣り、メイク汚れが完全に落ちていない。
<Makeup familiarity>
A (Excellent): The makeup blended well and the makeup stains were removed well.
B (Good): Inferior to A in terms of makeup adhesion, but makeup stains were removed well.
C (Practical): Inferior to B in makeup adhesion, but makeup stains were removed well.
D (Poor): Poor makeup adhesion, makeup stains not completely removed.
<洗い流し性>
A(優良):クレンジング化粧料のぬるぬる感がなくなるまでの時間が充分に短く、実用上良好な洗い流し性である。
流し性である。
B(良好):クレンジング化粧料のぬるぬる感がなくなるまで時間がA超C未満であり、実用上良好な洗い流し性。
C(実用可):クレンジング化粧料のぬるぬる感がなくなるまで少し時間がかかるが、実用可能な洗い流し性である。
D(不良):クレンジング化粧料のぬるぬる感がなくなるまで1分以上の時間がかかり、実用に適さない洗い流し性である。
<Washability>
A (Excellent): The time required for the cleansing cosmetic to lose its slimy feel is sufficiently short, and the washability is good for practical use.
It is easy to flow.
B (good): The time until the slimy feeling of the cleansing cosmetic disappears is greater than A and less than C, and the washability is good in practical terms.
C (practical): It takes some time for the slimy feeling of the cleansing cosmetic to disappear, but the washability is practical.
D (Poor): It takes more than 1 minute for the slimy feeling of the cleansing cosmetic to disappear, and the washability is not suitable for practical use.
<後肌感>
A(優良):使用後の肌に心地よいもっちり感を感じる。
B(良好):使用後の肌に、A未満C超のもっちり感を感じる。
C(実用可):使用後の肌に少しもっちり感を感じる。
D(不良):使用後の肌にもっちり感を感じない。
<Back skin feeling>
A (Excellent): The skin feels comfortable and elastic after use.
B (Good): After use, the skin feels plump with a rating of less than A and more than C.
C (Practical): The skin feels a little sticky after use.
D (Poor): The skin does not feel sticky after use.
さらに、以下に、本発明に用いることができる油性固形状クレンジング化粧料の処方例を示す。 Furthermore, formulation examples of oil-based solid cleansing cosmetics that can be used in the present invention are shown below.
Claims (1)
成分A:融点が50~120℃である固形油
成分B:液状油
成分C:HLB値が2~6のノニオン性界面活性剤
成分D:HLB値が8~15のノニオン性界面活性剤
成分E:体積基準のメジアン径が1~35μmの炭粉末
成分F:水 The following component A is 4.0 to 20 mass%, the following component B is 50 to 90 mass%, the following component C is 0.01 to 5.0 mass%, the following component D is 8 to 22 mass%, the following component E is An oil-based solid cleansing cosmetic containing 0.01 to 5.0% by mass and 0.5 to 6.0% by mass of component F below.
Component A: Solid oil having a melting point of 50 to 120°C Component B: Liquid oil component C: Nonionic surfactant component D having an HLB value of 2 to 6: Nonionic surfactant component E having an HLB value of 8 to 15 : Charcoal powder component with a volume-based median diameter of 1 to 35 μm F: Water
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JP (1) | JP2024010556A (en) |
KR (1) | KR20240008775A (en) |
CN (1) | CN117379341A (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5779377B2 (en) | 2011-03-29 | 2015-09-16 | 花王株式会社 | Solid oily cleansing cosmetic |
JP6758663B2 (en) | 2018-08-18 | 2020-09-23 | ジェイオーコスメティックス株式会社 | Oily solid cleansing cosmetics |
-
2022
- 2022-07-12 JP JP2022111953A patent/JP2024010556A/en active Pending
-
2023
- 2023-03-08 CN CN202310216850.4A patent/CN117379341A/en active Pending
- 2023-03-09 KR KR1020230030918A patent/KR20240008775A/en unknown
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KR20240008775A (en) | 2024-01-19 |
CN117379341A (en) | 2024-01-12 |
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