JP2022175998A5 - - Google Patents
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- JP2022175998A5 JP2022175998A5 JP2021082841A JP2021082841A JP2022175998A5 JP 2022175998 A5 JP2022175998 A5 JP 2022175998A5 JP 2021082841 A JP2021082841 A JP 2021082841A JP 2021082841 A JP2021082841 A JP 2021082841A JP 2022175998 A5 JP2022175998 A5 JP 2022175998A5
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- 235000014113 dietary fatty acids Nutrition 0.000 claims description 21
- 229930195729 fatty acid Natural products 0.000 claims description 21
- 239000000194 fatty acid Substances 0.000 claims description 21
- -1 polyoxyethylene Polymers 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 14
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 239000000600 sorbitol Substances 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- 230000008719 thickening Effects 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000006353 oxyethylene group Chemical group 0.000 claims 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 6
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 3
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 229960002446 octanoic acid Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Description
すなわち、本発明は、グリセリン（Ａ１）および２価アルコール（Ａ２）からなり、これらの質量比（Ａ１／Ａ２）が９９／１～９０／１０である多価アルコール（Ａ）を７５～９５質量％、
式（Ｉ）で表されるグリセリンのアルキレンオキシド付加誘導体（Ｂ）を０．１～１０質量％、
ＨＬＢが１０～１６であり、ポリオキエシエチレン脂肪酸グリセリルおよびポリオキシエチレン脂肪酸ソルビトールの中から選ばれる１種または２種以上のノニオン性界面活性剤（Ｃ）を０．５～８質量％、
アクリル酸系増粘性高分子（Ｄ）を０．１～０．７質量％、
下記式（II）および（III）で表される各構成単位を含む共重合体（Ｅ）を０．００５～０．２５質量％
含有する温感皮膚洗浄料である。
That is, in the present invention, a polyhydric alcohol (A) consisting of glycerin (A1) and a dihydric alcohol (A2) and having a mass ratio (A1/A2) of 99/1 to 90/10 is used in an amount of 75 to 95% by mass. %,
0.1 to 10% by mass of the alkylene oxide addition derivative (B) of glycerin represented by formula (I),
HLB is 10 to 16, and 0.5 to 8 mass of one or more nonionic surfactants (C) selected from polyoxyethylene fatty acid glyceryl and polyoxyethylene fatty acid sorbitol %,
0.1 to 0.7% by mass of acrylic acid-based thickening polymer (D),
0.005 to 0.25% by mass of copolymer (E) containing each structural unit represented by the following formulas (II) and (III)
A warming skin cleansing agent containing:
〔ノニオン性界面活性剤（Ｃ）〕
本発明の洗浄料に用いられるノニオン性界面活性剤（Ｃ）は、ポリオキエシエチレン脂肪酸グリセリルおよびポリオキシエチレン脂肪酸ソルビトールの中から選ばれる１種または２種以上のノニオン性界面活性剤であり、ＨＬＢ（Hydrophile-Lipophile Balance）が１０～１６である。
[Nonionic surfactant (C)]
The nonionic surfactant (C) used in the cleaning agent of the present invention is one or more nonionic surfactants selected from polyoxyethylene fatty acid glyceryl and polyoxyethylene fatty acid sorbitol . and the HLB (Hydrophile-Lipophile Balance) is 10-16.
ポリオキエシエチレン脂肪酸グリセリルおよびポリオキシエチレン脂肪酸ソルビトールにおける脂肪酸としては、炭素数８～２２、好ましくは炭素数８～１８の直鎖または分岐の脂肪酸が挙げられ、具体的には、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸等の飽和脂肪酸；オレイン酸、リノール酸、リノレン酸等の不飽和脂肪酸；カプリル酸／カプリン酸、ヤシ油脂肪酸、パーム核油脂肪酸等の混合脂肪酸が例示される。
また、ポリオキエシエチレン脂肪酸グリセリルおよびポリオキシエチレン脂肪酸ソルビトールにおけるエチレンオキシドの平均付加モル数は、好ましくは４～５０であり、より好ましくは５～４０、さらに好ましくは６～３５である。平均付加モル数が小さすぎると、配合が困難になることがあり、平均付加モル数が大きすぎると、洗浄力が低下することがある。また、エステルの数は、好ましくは１～６であり、より好ましくは１～４である。
The fatty acids in polyoxyethylene fatty acid glyceryl and polyoxyethylene fatty acid sorbitol include straight chain or branched fatty acids having 8 to 22 carbon atoms, preferably 8 to 18 carbon atoms, and specifically, caprylic acid, saturated fatty acids such as capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid; unsaturated fatty acids such as oleic acid, linoleic acid, linolenic acid; caprylic acid/capric acid, coconut oil fatty acid, palm kernel Mixed fatty acids such as oil fatty acids are exemplified.
Further, the average number of moles of ethylene oxide added in polyoxyethylene fatty acid glyceryl and polyoxyethylene fatty acid sorbitol is preferably 4 to 50, more preferably 5 to 40, and still more preferably 6 to 35. If the average number of added moles is too small, blending may become difficult, and if the average number of added moles is too large, the detergency may decrease. Further, the number of esters is preferably 1 to 6, more preferably 1 to 4.
ポリオキエシエチレン脂肪酸グリセリルとして具体的には、ヤシ油脂肪酸ＰＥＧ－７グリセリル、ＰＥＧ－８（カプリル酸／カプリン酸）グリセリル、ＰＥＧ－３０グリセリルココエート等が挙げられる。
ポリオキシエチレン脂肪酸ソルビトールとして具体的には、テトラオレイン酸ソルベス－３０、テトライソステアリン酸ソルベス－３０等が挙げられる。
Specific examples of polyoxyethylene fatty acid glyceryl include coconut oil fatty acid PEG-7 glyceryl, PEG-8 (caprylic acid/capric acid) glyceryl, PEG-30 glyceryl cocoaate, and the like.
Specific examples of the polyoxyethylene fatty acid sorbitol include sorbet-30 tetraoleate and sorbet-30 tetraisostearate.
ノニオン性界面活性剤（Ｃ）として、ポリオキエシエチレン脂肪酸グリセリルおよびポリオキシエチレン脂肪酸ソルビトールの中から選ばれる１種または２種以上を用いることができるが、洗浄性の観点から２種以上を併用することが好ましい。 As the nonionic surfactant (C), one or more types selected from polyoxyethylene fatty acid glyceryl and polyoxyethylene fatty acid sorbitol can be used, but from the viewpoint of detergency, two types are used. It is preferable to use the above in combination.
〔実施例１～５および比較例１～５〕
表１に記載の成分を表１に示す組成で温感皮膚洗浄料として調製し、下記の方法により評価を行った。
なお、成分（Ａ）は多価アルコール（Ａ）であり、成分（Ａ１）はグリセリン、成分（Ａ２）は１，３－ブチレングリコールである。
成分（Ｂ）のグリセリンのアルキレンオキシド付加誘導体ａは、「ＷＩＬＢＲＩＤＥ（登録商標） Ｓ－７５３」（日油株式会社製）であり、上記式（Ｉ）で示されるアルキレンオキシド誘導体において、ａ＋ｂが４．３、ｃが１であり、ＰＯとＥＯの含有比（ＰＯ／ＥＯ）が質量比で４／５であるポリオキシブチレンポリオキシエチレンポリオキシプロピレングリセリルエーテル（３ＢＯ）（８ＥＯ）（５ＰＯ）である。
成分（Ｃ）のノニオン性界面活性剤はヤシ油脂肪酸ＰＥＧ－７グリセリル (ＨＬＢ＝１３．０)、テトラオレイン酸ソルベス－３０ (ＨＬＢ＝１１．２)である。
成分（Ｄ）のアクリル酸系増粘性高分子は、カルボキシビニルポリマー「ＣＡＲＢＯＰＯＬ（登録商標）Ｕｌｔｒｅｚ １０ Ｐｏｌｙｍｅｒ」（日本ルーブリゾール株式会社製）である。
成分（Ｅ）の共重合体ａは「Ｌｉｐｉｄｕｒｅ（登録商標）－ＰＭＢ」（日油株式会社製）であり、上記式（II）、（III）で表される構成単位からなる二元共重合体である。式（II）および（III）中、Ｒ１およびＲ２はそれぞれメチル基であり、式（III）中、ｍ＝３である。式（II）で表される構成単位と式（III）で表される構成単位の含有量比（ｎ１：ｎ２）（モル比）は４：１であり、重量平均分子量は約６００，０００である。
[Examples 1 to 5 and Comparative Examples 1 to 5]
A warming skin cleansing agent was prepared using the ingredients shown in Table 1 with the composition shown in Table 1, and evaluated by the following method.
Note that component (A) is polyhydric alcohol (A), component (A1) is glycerin, and component (A2) is 1,3-butylene glycol.
The alkylene oxide addition derivative a of glycerin as component (B) is "WILBRIDE (registered trademark) S-75 3" (manufactured by NOF Corporation), and in the alkylene oxide derivative represented by the above formula (I), a+b is 4.3, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ether (3BO) (8EO) (5PO) where c is 1 and the content ratio of PO and EO (PO/EO) is 4/5 by mass ratio It is.
The nonionic surfactants of component (C) are coconut oil fatty acid PEG-7 glyceryl (HLB=13.0) and sorbeth-30 tetraoleate (HLB=11.2).
The acrylic acid-based thickening polymer of component (D) is a carboxyvinyl polymer "CARBOPOL (registered trademark) Ultrez 10 Polymer" (manufactured by Japan Lubrizol Co., Ltd.).
Copolymer a of component (E) is "Lipidure (registered trademark)-PMB" (manufactured by NOF Corporation), which is a binary copolymer consisting of structural units represented by formulas (II) and (III) above. It is a combination. In formulas (II) and (III), R 1 and R 2 are each a methyl group, and in formula (III), m=3. The content ratio (n1:n2) (molar ratio) of the structural unit represented by formula (II) and the structural unit represented by formula (III) is 4:1, and the weight average molecular weight is approximately 600,000. be.
Claims (1)
式（Ｉ）で表されるグリセリンのアルキレンオキシド付加誘導体（Ｂ）を０．１～１０質量％、
ＨＬＢが１０～１６であり、ポリオキエシエチレン脂肪酸グリセリルおよびポリオキシエチレン脂肪酸ソルビトールの中から選ばれる１種または２種以上のノニオン性界面活性剤（Ｃ）を０．５～８質量％、
アクリル酸系増粘性高分子（Ｄ）を０．１～０．７質量％、
下記式（II）および（III）で表される各構成単位を含む共重合体（Ｅ）を０．００５～０．２５質量％
含有する温感皮膚洗浄料。
Ｇｌｙ－［Ｏ｛（ＰＯ）ａ（ＥＯ）ｂ｝－（ＢＯ）ｃＨ］３ 式（Ｉ）
（式（Ｉ）中、Ｇｌｙはグリセリンから水酸基を除いた残基、ＰＯはオキシプロピレン基、ＥＯはオキシエチレン基、ＢＯはオキシブチレン基であり、ａ、ｂおよびｃはそれぞれＰＯ、ＥＯおよびＢＯの平均付加モル数であって、ａ＋ｂは１～３０、ｃは１～５であり、ＰＯとＥＯの付加形態はランダム状でもブロック状でも良く、質量比ＰＯ／ＥＯは１／５～５／１である。）
0.1 to 10% by mass of the alkylene oxide addition derivative (B) of glycerin represented by formula (I),
HLB is 10 to 16, and 0.5 to 8 mass of one or more nonionic surfactants (C) selected from polyoxyethylene fatty acid glyceryl and polyoxyethylene fatty acid sorbitol %,
0.1 to 0.7% by mass of acrylic acid-based thickening polymer (D),
0.005 to 0.25% by mass of copolymer (E) containing each structural unit represented by the following formulas (II) and (III)
Contains a warming skin cleanser.
Gly-[O{(PO) a (EO) b }-(BO) c H] 3 Formula (I)
(In formula (I), Gly is a residue obtained by removing the hydroxyl group from glycerin, PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxybutylene group, and a, b, and c are PO, EO, and BO, respectively. is the average number of moles added, a+b is 1 to 30, c is 1 to 5, the addition form of PO and EO may be random or block, and the mass ratio PO/EO is 1/5 to 5/ 1.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021082841A JP2022175998A (en) | 2021-05-14 | 2021-05-14 | Temperature sensitive skin cleansing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021082841A JP2022175998A (en) | 2021-05-14 | 2021-05-14 | Temperature sensitive skin cleansing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2022175998A JP2022175998A (en) | 2022-11-25 |
| JP2022175998A5 true JP2022175998A5 (en) | 2024-01-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021082841A Pending JP2022175998A (en) | 2021-05-14 | 2021-05-14 | Temperature sensitive skin cleansing agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2022175998A (en) |
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2021
- 2021-05-14 JP JP2021082841A patent/JP2022175998A/en active Pending
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