JP2022163286A - Aryl azole compound and pest control agent - Google Patents
Aryl azole compound and pest control agent Download PDFInfo
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- JP2022163286A JP2022163286A JP2021068132A JP2021068132A JP2022163286A JP 2022163286 A JP2022163286 A JP 2022163286A JP 2021068132 A JP2021068132 A JP 2021068132A JP 2021068132 A JP2021068132 A JP 2021068132A JP 2022163286 A JP2022163286 A JP 2022163286A
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Abstract
Description
本発明はアリールアゾール化合物および有害生物防除剤に関する。より詳細に、本発明は、優れた殺虫・殺ダニ・殺線虫活性を有し、安全性に優れ、かつ工業的に有利に合成できるアリールアゾール化合物ならびにこれを有効成分として含有する有害生物防除剤に関する。 The present invention relates to arylazole compounds and pesticides. More specifically, the present invention provides an arylazole compound that has excellent insecticidal, acaricidal, and nematicidal activity, is excellent in safety, and can be industrially synthesized advantageously, and pest control containing this as an active ingredient. Regarding agents.
殺虫・殺ダニ・殺線虫活性を有する化合物が種々提案されている。そのような化合物を農薬として実用するためには、効力が十分に高いだけでなく、薬剤抵抗性が生じ難いこと、植物に対する薬害や土壌汚染を生じさせないこと、家畜や魚類などに対する毒性が低いことなどが要求される。 Various compounds having insecticidal, acaricidal and nematicidal activities have been proposed. In order for such compounds to be practically used as pesticides, they must not only have sufficiently high efficacy, but also must be resistant to drug resistance, not cause phytotoxicity or soil contamination to plants, and have low toxicity to livestock and fish. etc. is required.
特許文献1には式(A)及び(B)で表される化合物が開示されている。特許文献1によれば、これらの化合物は有害生物防除剤として有用であるらしい。 Patent document 1 discloses compounds represented by formulas (A) and (B). According to U.S. Pat. No. 6,200,000, these compounds appear to be useful as pest control agents.
特許文献2には式(C)で表される化合物が開示されている。特許文献2によれば、これらの化合物は殺虫剤として有用であるらしい。 Patent document 2 discloses a compound represented by formula (C). According to U.S. Pat. No. 6,200,000, these compounds appear to be useful as insecticides.
特許文献3には式(D)で表される化合物が開示されている。特許文献3によれば、これらの化合物は殺虫剤として有用であるらしい。 Patent document 3 discloses a compound represented by formula (D). According to US Pat. No. 5,330,009, these compounds appear to be useful as insecticides.
特許文献4には、式(E)で表される化合物などが開示されている。特許文献4によれば、これらの化合物は有害生物防除剤として有用であるらしい。 Patent document 4 discloses a compound represented by formula (E) and the like. According to U.S. Pat. No. 6,200,000, these compounds appear to be useful as pesticides.
特許文献5には、式(F)で表される化合物が開示されている。特許文献5によれば、これらの化合物は殺虫剤として有用であるらしい。 Patent document 5 discloses a compound represented by formula (F). According to US Pat. No. 5,430,009, these compounds appear to be useful as insecticides.
本発明の課題は、有害生物防除活性、その中でも特に殺虫活性、殺ダニ活性および/または殺線虫活性に優れ、安全性に優れ、且つ工業的に有利に合成できるアリールアゾール化合物、ならびにこれを有効成分として含有する有害生物防除剤を提供することである。 An object of the present invention is to provide an arylazole compound that has excellent pesticidal activity, especially insecticidal activity, miticidal activity and / or nematicidal activity, is excellent in safety, and can be industrially advantageously synthesized. An object of the present invention is to provide a pest control agent containing as an active ingredient.
上記課題を解決すべく鋭意検討した結果、以下の形態を包含する本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present invention including the following aspects has been completed.
本発明のアリールアゾール化合物は、有害生物防除活性、その中でも特に殺虫活性、殺ダニ活性および/または殺線虫活性に優れ、安全性に優れ、且つ工業的に有利に合成できる。
本発明の有害生物防除剤は、農作物に対して有害な生物または衛生面で問題となる有害生物を防除することができる。本発明の有害生物防除剤は、低い濃度であっても、農業害虫を防除する効果に優れる。
INDUSTRIAL APPLICABILITY The arylazole compound of the present invention has excellent pesticidal activity, particularly insecticidal activity, acaricidal activity and/or nematicidal activity, is excellent in safety, and can be industrially advantageously synthesized.
The pest control agent of the present invention can control organisms that are harmful to agricultural crops or pests that pose a problem in terms of hygiene. The pest control agent of the present invention is highly effective in controlling agricultural pests even at low concentrations.
〔表1に記載の化合物〕
本発明のアリールアゾール化合物は、下記の表1に記載の化合物であることが好ましい。
[Compounds listed in Table 1]
The arylazole compound of the present invention is preferably a compound shown in Table 1 below.
〔表2に記載の化合物〕
本発明のアリールアゾール化合物は、下記の表2に記載の化合物であることが好ましい。オキシム基の窒素炭素交差二重結合の配置を「立体配置」の欄に記入した。「E」はE配置であることを示し、「Z」はZ配置であることを示し、「E/Z」は化合物が両配置の化合物の混合物であることを示す。
[Compounds listed in Table 2]
The arylazole compound of the present invention is preferably a compound listed in Table 2 below. The configuration of the nitrogen-carbon crossing double bond of the oxime group is entered in the "Configuration" column. "E" indicates the E configuration, "Z" indicates the Z configuration, and "E/Z" indicates that the compound is a mixture of compounds of both configurations.
〔表3に記載の化合物〕
本発明のアリールアゾール化合物は、下記の表3に記載の化合物であることが好ましい。ビニル基の炭素炭素交差二重結合の配置を「立体配置」の欄に記入した。「E」はE配置であることを示し、「Z」はZ配置であることを示し、「E/Z」は化合物が両配置の化合物の混合物であることを示す。
[Compounds listed in Table 3]
The arylazole compound of the present invention is preferably a compound listed in Table 3 below. The configuration of the carbon-carbon crossing double bond of the vinyl group is entered in the "Configuration" column. "E" indicates the E configuration, "Z" indicates the Z configuration, and "E/Z" indicates that the compound is a mixture of compounds of both configurations.
〔表4に記載の化合物〕
本発明のアリールアゾール化合物は、下記の表4に記載の化合物であることが好ましい。
[Compounds listed in Table 4]
The arylazole compound of the present invention is preferably a compound listed in Table 4 below.
〔表5に記載の化合物〕
本発明のアリールアゾール化合物は、下記の表5に記載の化合物であることが好ましい。
[Compounds listed in Table 5]
The arylazole compound of the present invention is preferably a compound listed in Table 5 below.
本発明のアリールアゾール化合物は、その製造方法によって特に限定されない。本発明のアリールアゾール化合物は、公知の製造方法によって得ることができる。 The arylazole compound of the present invention is not particularly limited by its production method. The arylazole compound of the present invention can be obtained by a known production method.
本発明のアリールアゾール化合物は、植物の生育に影響する各種の農業害虫、ダニ類、線虫類などの有害生物の防除効果に優れている。
また、本発明のアリールアゾール化合物は、作物に対する薬害がなく、魚類や温血動物への毒性が低いため、安全性の高い化合物である。そのため、殺虫剤、殺ダニ剤または殺線虫剤の有効成分として有用である。
さらに、近年、コナガ、ウンカ、ヨコバイ、アブラムシなど多くの害虫において各種既存薬剤に対する抵抗性が発達し、それら薬剤の効力不足問題を生じており、抵抗性系統の害虫にも有効な薬剤が望まれている。本発明のアリールアゾール化合物は、感受性系統のみならず、各種抵抗性系統の害虫や、さらに殺ダニ剤抵抗性系統のダニ類にも優れた防除効果を示す。
The arylazole compound of the present invention is excellent in controlling pests such as various agricultural pests, mites, and nematodes that affect plant growth.
In addition, the arylazole compounds of the present invention are highly safe compounds because they do not cause phytotoxicity to crops and have low toxicity to fish and warm-blooded animals. Therefore, it is useful as an active ingredient of insecticides, acaricides or nematicides.
Furthermore, in recent years, many insect pests, such as diamondback moths, planthoppers, leafhoppers, and aphids, have developed resistance to various existing pesticides, causing the problem of insufficient efficacy of these pesticides. ing. The arylazole compound of the present invention exhibits an excellent control effect not only on susceptible strains, but also on various resistant strains of insect pests and miticide-resistant strains of mites.
また、本発明のアリールアゾール化合物は、防除の対象となる生物のすべての発育ステージにおいて効力を示し、例えば、ダニ、昆虫、線虫などの卵、若虫、幼虫、蛹、成虫に対して優れた防除効果を示す。 In addition, the arylazole compound of the present invention exhibits efficacy in all developmental stages of organisms to be controlled, and is excellent against, for example, eggs, nymphs, larvae, pupae, and adults of ticks, insects, and nematodes. It shows control effect.
〔有害生物防除剤〕
本発明の有害生物防除剤は、本発明化合物から選ばれる少なくともひとつを有効成分として含有する。本発明の有害生物防除剤に含まれる本発明化合物の量は有害生物の防除効果を示す限りにおいて特に制限されない。有害生物防除剤は、有害生物を防除するものであればよく、例えば、殺虫もしくは殺ダニ剤、殺線虫剤、内部寄生虫防除もしくは駆除剤などを包含するものである。
[Pest control agent]
The pest control agent of the present invention contains at least one compound selected from the compounds of the present invention as an active ingredient. The amount of the compound of the present invention contained in the pest control agent of the present invention is not particularly limited as long as the pest controlling effect is exhibited. Pest control agents may be those that control pests, and include, for example, insecticides or acaricides, nematicides, internal parasite control or extermination agents, and the like.
〔殺虫、殺ダニもしくは殺線虫剤〕
本発明の殺虫、殺ダニもしくは殺線虫剤は、本発明のアリールアゾール化合物から選ばれる少なくともひとつを有効成分として含有する。本発明の殺虫、殺ダニもしくは殺線虫剤に含まれる本発明のアリールアゾール化合物の量は有害生物の防除効果を示す限りにおいて特に制限されない。
[insecticide, acaricide or nematicide]
The insecticide, acaricide or nematicide of the present invention contains at least one selected from the arylazole compounds of the present invention as an active ingredient. The amount of the arylazole compound of the present invention contained in the insecticide, acaricide or nematicide of the present invention is not particularly limited as long as the pest controlling effect is exhibited.
本発明の殺虫、殺ダニもしくは殺線虫剤は、穀物類;野菜類;根菜類;イモ類;花卉類;果樹類;観葉植物、茶、コーヒー、カカオなどの樹木類;牧草類;芝類;ワタなどの植物に対して用いることが好ましい。
植物への施用において、本発明の有害生物防除剤、または殺虫、殺ダニもしくは殺線虫剤は、葉、茎、柄、花、蕾、果実、種子、スプラウト、根、塊茎、塊根、苗条、挿し木などのいずれの部位に用いてもよい。
また、本発明殺虫、殺ダニもしくは殺線虫剤は、施用される植物の種によって特に制限されない。植物の種としては、例えば、原種、変種、改良品種、栽培品種、突然変異体、ハイブリッド体、遺伝子組み換え体(GMO)などを挙げることができる。
The insecticide, acaricide or nematicide of the present invention includes: cereals; vegetables; root crops; potatoes; it is preferably used for plants such as cotton.
In application to plants, the pesticides, or insecticides, acaricides or nematicides of the present invention are applied to leaves, stems, stems, flowers, buds, fruits, seeds, sprouts, roots, tubers, tubers, shoots, You may use for any part, such as cuttings.
In addition, the insecticide, acaricide or nematicide of the present invention is not particularly limited by the plant species to which it is applied. Plant species include, for example, original species, varieties, improved varieties, cultivars, mutants, hybrids, genetically modified organisms (GMO), and the like.
本発明の殺虫、殺ダニもしくは殺線虫剤は、各種の農業害虫、ダニ類および線虫類を防除するために、種子処理、茎葉散布、土壌施用、水面施用などに使用することができる。 The insecticide, acaricide or nematicide of the present invention can be used in seed treatment, foliar application, soil application, surface application, etc. to control various agricultural pests, mites and nematodes.
本発明の殺虫、殺ダニもしくは殺線虫剤によって防除可能な各種の農業害虫、ダニ類および線虫類の具体例を以下に示す。 Specific examples of various agricultural pests, mites and nematodes that can be controlled by the insecticides, acaricides or nematicides of the present invention are given below.
(1)鱗翅目(Lepidoptera)のチョウまたは蛾
(a)ヒトリガ科(Arctiidae)のガ、例えば、アメリカシロヒトリ(Hyphantria cunea)、クワゴマダラヒトリ(Lemyra imparilis);
(b)チビガ科(Bucculatricidae)のガ、例えば、ナシチビガ(Bucculatrix pyrivorella);
(c)シンクイガ科(Carposinidae)、例えば、モモシンクイガ(Carposina sasakii);(d)ツトガ科(Crambidae)のガ、例えば、ジアファニア属種(Diaphania spp.)の、ワタヘリクロノメイガ(Diaphania indica)、アメリカウリノメイガ (Diaphania nitidalis);例えば、オストリニア属種(Ostrinia spp.)の、アワノメイガ(Ostrinia furnacalis)、ヨーロピアンコーンボーラー(Ostrinia nubilalis)、アズキノメイガ(Ostrinia scapulalis);その他、ニカメイガ(Chilo suppressalis)、コブノメイガ(Cnaphalocrocis medinalis)、モモノゴマダラノメイガ(Conogethes punctiferalis)、サウスウエスタンコーンボーラー(Diatraea grandiosella)、クワノメイガ(Glyphodes pyloalis)、ハイマダラノメイガ(Hellula undalis)、シバツトガ(Parapediasia teterrella);
(e)キバガ科(Gelechiidae)のガ、例えば、イモキバガ(Helcystogramma triannulella)、ワタアカミムシ(Pectinophora gossypiella)、ジャガイモキバガ(Phthorimaea operculella)、バクガ(Sitotroga cerealella);
(f)シャクガ科(Geometridae)のガ、例えば、ヨモギエダシャク(Ascotis selenaria);
(g)ホソガ科(Gracillariidae)のガ、例えば、チャノホソガ(Caloptilia theivora)、ミカンハモグリガ(Phyllocnistis citrella)、キンモンホソガ(Phyllonorycter ringoniella);
(h)セセリチョウ科(Hesperiidae)のチョウ、例えば、イチモンジセセリ(Parnara guttata);
(i)カレハガ科(Lasiocampidae)のガ、例えば、オビカレハ(Malacosoma neustria);
(j)ドクガ科(Lymantriidae)のガ、例えば、リマントリア属種(Lymantria spp.)の、マイマイガ(Lymantria dispar)、ノンネマイマイ(Lymantria monacha);その他の、チャドクガ(Euproctis pseudoconspersa)、ヒメシロモンドクガ(Orgyia thyellina);
(1) Lepidoptera butterflies or moths (a) Arctiidae moths, such as Hyphantria cunea, Lemyra imparilis;
(b) moths of the family Bucculatricidae, such as Bucculatrix pyrivorella;
(c) Carposinidae, e.g., Carposina sasakii; (d) Crambidae, e.g., Diaphania spp., Diaphania indica, USA Diaphania nitidalis; for example, Ostrinia spp., Ostrinia furnacalis, European corn borer (Ostrinia nubilalis), Ostrinia scapulalis; Cnaphalocrocis medinalis), Prunus punctiferalis), Southwestern corn borer (Diatraea grandiosella), Glyphodes pyloalis, Hellula undalis, Shibattoga (Parapediasia teterrella);
(e) Moths of the Gelechiidae family, for example, Helcystogramma triannulella, Pectinophora gossypiella, Phthorimaea operculella, Sitotroga cerealella;
(f) moths of the Geometridae family, such as Ascotis selenaria;
(g) moths of the Gracilariidae family, such as Caloptilia theivora, Phyllocnistis citrella, and Phyllonorycter ringoniella;
(h) butterflies of the family Hesperiidae, such as Parnara guttata;
(i) moths of the family Lasiocampidae, such as Malacosoma neustria;
(j) Moths of the family Lymantriidae, such as Lymantria spp., Lymantria dispar, Lymantria monacha; other Euproctis pseudoconspersa, Orgyia thyellina);
(k)モグリガ科(Lyonetiidae )のガ、例えば、リオネチア属種(Lyonetia spp.)の、モモハモグリガ(Lyonetia clerkella)、ギンモンハモグリガ(Lyonetia prunifoliellamalinella);
(l)ヤガ科(Noctuidae)のガ、例えば、スポドプテラ属種(Spodoptera spp.)の、スジキリヨトウ(Spodoptera depravata)、サザンアーミーワーム(Spodoptera eridania)、シロイチモジヨトウ(Spodoptera exigua)、ツマジロクサヨトウ(Spodoptera frugiperda)、アフリカヨトウ(Spodoptera littoralis)、ハスモンヨトウ(Spodoptera litura);例えば、オートグラファ属種(Autographa spp.)の、ガマキンウワバ (Autographa gamma)、タマナギンウワバ(Autographa nigrisigna);例えば、アグロチス属種(Agrotis spp.)の、タマナヤガ(Agrotis ipsilon)、カブラヤガ(Agrotis segetum);例えば、ヘリコベルパ属種(Helicoverpa spp.)の、オオタバコガ(Helicoverpa armigera)、タバコガ(Helicoverpa assulta)、コットンボールワーム(Helicoverpa zea);例えば、ヘリオチス属種(Heliothis spp.)の、ワタキバガ(Heliothis armigera)、ニセアメリカタバコガ(Heliothis virescens);その他の、ナカジロシタバ(Aedia leucomelas)、ミツモンキンウワバ(Ctenoplusia agnata)、アケビコノハ(Eudocima tyrannus)、ヨトウガ(Mamestra brassicae)、アワヨトウ(Mythimna separata)、フタオビコヤガ(Naranga aenescens)、マツキリガ(Panolis japonica)、ニセタマナヤガ(Peridroma saucia)、ソイビーンルーパー(Pseudoplusia includens)、イラクサギンウワバ(Trichoplusia ni);
(m)コブガ科(Nolidae) のガ、例えば、ミスジアオリンガ(Earias insulana);
(n)シロチョウ科(Pieridae)のチョウ、例えば、モンシロチョウ属種(Pieris spp.)のオオモンシロチョウ(Pieris brassicae)、モンシロチョウ(Pieris rapae crucivora);
(o)コナガ科(Plutellidae)のガ、例えば、アクロレピオプシス属種(Acrolepiopsis spp.)の、ネギコガ(Acrolepiopsis sapporensis)、ヤマノイモコガ(Acrolepiopsis suzukiella);その他、コナガ(Plutella xylostella);
(p)メイガ科(Pyralidae)のガ、例えば、スジマダラメイガ(Cadra cautella)、モロコシマダラメイガ(Elasmopalpus lignosellus)、シロイチモジマダラメイガ(Etiella zinckenella)、ハチノスツヅリガ (Galleria mellonella);
(q)スズメガ科(Sphingidae)のガ、例えば、マンジュカ属種(Manduca spp.)の、トマトホーンワーム(Manduca quinquemaculata)、タバコホーンワーム(Manduca sexta);
(K) moths of the family Lyonetiidae, for example, Lyonetia spp., Lyonetia clerkella, Lyonetia prunifoliellamalinella;
(l) Noctuidae moths, for example, Spodoptera spp., Spodoptera depravata, Southern army worms (Spodoptera eridania), Spodoptera exigua, Spodoptera frugiperda ), Spodoptera littoralis, Spodoptera litura; for example, Autographa spp., Autographa gamma, Autographa nigrisigna; for example, Agrotis spp. of Agrotis ipsilon, Agrotis segetum; e.g., Helicoverpa spp., Helicoverpa armigera, Helicoverpa assulta, cotton ballworm (Helicoverpa zea); of species (Heliothis spp.), Heliothis armigera, Heliothis virescens; others, Aedia leucomelas, Ctenoplusia agnata, Eudocima tyrannus, Mamestra brassicae ), armyworm (Mythimna separata), Naranga aenescens, Panolis japonica, Peridroma saucia, Soybean looper (Pseudoplusia includens), Trichoplusia ni;
(m) Nolidae moths, such as Earias insulana;
(n) butterflies of the family Pieridae, for example, Pieris brassicae and Pieris rapae crucivora of the genus Pieris spp.;
(O) Plutellidae moths, for example, Acrolepiopsis spp., Acrolepiopsis sapporensis, Acrolepiopsis suzukiella; other, Plutella xylostella;
(p) Pyralidae moths, for example, Cadra cautella, Elasmopalpus lignosellus, Etiella zinckenella, Galleria mellonella;
(q) moths of the family Sphingidae, such as Manduca spp., tomato hornworm (Manduca quinquemaculata), tobacco hornworm (Manduca sexta);
(r)ニセマイコガ科(Stathmopodidae)のガ、例えば、カキノヘタムシガ(Stathmopodamasinissa);
(s)ヒロズコガ科(Tineidae)のガ、例えば、イガ(Tinea translucens);
(t)ハマキガ科(Tortricidae)のガ、例えば、アドキソフィエス属種(Adoxophyes spp.)の、チャノコカクモンハマキ(Adoxophyes honmai)、リンゴコカクモンハマキ(Adoxophyes orana);例えば、アルチプス属種(Archips spp.)の、リンゴモンハマキ(Archips breviplicanus)、ミダレカクモンハマキ(Archips fuscocupreanus);その他の、トウヒノシントメハマキ(Choristoneura fumiferana)、コドリンガ(Cydia pomonella)、ブドウホソハマキ(Eupoecilia ambiguella)、ナシヒメシンクイ(Grapholitha molesta)、チャハマキ(Homona magnanima)、マメシンクイガ(Leguminivora glycinivorella)、ホソバヒメハマキ(Lobesia botrana)、マメヒメサヤムシガ(Matsumuraeses phaseoli)、トビハマキ(Pandemis heparana)、テングハマキ(Sparganothis pilleriana);
(u)スガ科(Yponomeutidae)のガ、例えば、リンゴヒメシンクイ(Argyresthia conjugella)。
(r) Moths of the family Stathmopodidae, such as Stathmopodamasinissa;
(s) Moths of the family Tineidae, such as Tinea translucens;
(t) Tortricidae moths, e.g., Adoxophyes spp., Adoxophyes honmai, Adoxophyes orana; e.g., Archips spp. ), Archips breviplicanus, Archips fuscocupreanus; others, Choristoneura fumiferana, Cydia pomonella, Eupoecilia ambiguella, Grapholitha molesta ), Homona magnanima, Leguminivora glycinivorella, Lobesia botrana, Matsumuraeses phaseoli, Pandemis heparana, Sparganothis pilleriana;
(u) Moths of the family Yponomeutidae, such as Argyrestia conjugella.
(2)アザミウマ目(Thysanoptera)害虫
(a)クダアザミウマ科(Phlaeothripidae)の、例えば、カキクダアザミウマ(Ponticulothrips diospyrosi);
(b)アザミウマ科(Thripidae)の、例えば、フランクリニェラ属種(Frankliniella spp.)の、ヒラズハナアザミウマ(Frankliniella intonsa)、ミカンキイロアザミウマ(Frankliniella occidentalis);例えば、トリプス属種(Thrips spp.)の、ミナミキイロアザミウマ(Thrips palmi)、ネギアザミウマ(Thrips tabaci);その他の、クロトンアザミウマ(Heliothrips haemorrhoidalis)、チャノキイロアザミウマ(Scirtothrips dorsalis)。
(2) Thysanoptera pest (a) Phlaeothripidae, for example, Ponticulothrips diospyrosi;
(b) Thripidae, e.g., Frankliniella spp., Frankliniella intonsa, Frankliniella occidentalis; e.g., Thrips spp., Southern yellow Thrips (Thrips palmi), Thrips tabaci; others, Croton thrips (Heliothrips haemorrhoidalis), Tea thrips (Scirtothrips dorsalis).
(3)カメムシ目(Hemiptera)の害虫
(A)頸吻亜目(Archaeorrhyncha)
(a)ウンカ科(Delphacidae)の、例えば、ヒメトビウンカ(Laodelphax striatella)、トビイロウンカ(Nilaparvata lugens)、クロフツノウンカ(Perkinsiella saccharicida)、セジロウンカ(Sogatella furcifera)。
(3) Hemiptera pests (A) Archaeorrhyncha
(a) Planthoppers (Delphacidae), such as Laodelphax striatella, Nilaparvata lugens, Perkinsiella saccharicida, and Sogatella furcifera.
(B)頸吻亜目(Clypeorrhyncha)
(a)ヨコバイ科(Cicadellidae)の、例えば、エンポアスカ属種(Empoasca spp.)の、ジャガイモヒメヨコバイ(Empoasca fabae)、カキノヒメヨコバイ(Empoasca nipponica)、チャノミドリヒメヨコバイ(Empoasca onukii)、マメノミドリヒメヨコバイ(Empoasca sakaii)、;その他の、フタテンヒメヨコバイ(Arboridia apicalis)、ミドリナガヨコバイ(Balclutha saltuella)、フタテンオオヨコバイ(Epiacanthus stramineus)、ヒメフタテンヨコバイ(Macrosteles striifrons)、ツマグロヨコバイ(Nephotettix cinctinceps)。
(B) Clypeorrhyncha
(a) Cicadellidae, for example, Empoasca spp. Empoasca fabae, Empoasca nipponica, Empoasca onukii, green bean leafhopper Leafhopper (Empoasca sakaii); other Leafhopper (Arboridia apicalis), Leafhopper (Balclutha saltuella), Leafhopper (Epiacanthus stramineus), Leafhopper (Macrosteles striifrons), Leafhopper (Nephotettix cinctinceps) ).
(C)カメムシ亜目(Heteroptera)
(a)ホソヘリカメムシ科(Alydidae)の、例えば、ホソヘリカメムシ(Riptortus clavatus);
(b)ヘリカメムシ科(Coreidae)の、例えば、ホソハリカメムシ(Cletus punctiger)、クモヘリカメムシ(Leptocorisa chinensis);
(c)ナガカメムシ科(Lygaeidae)の、例えば、アメリカコバネナガカメムシ(Blissus leucopterus)、カンシャコバネナガカメムシ(Cavelerius saccharivorus)、コバネヒョウタンナガカメムシ(Togo hemipterus);
(d)カスミカメムシ科(Miridae)の、例えば、クロトビカスミカメ(Halticus insularis)、サビイロカスミカメ(Lygus lineolaris)、コットンフリーホッパー(Psuedatomoscelis seriatus)、ナガムギカスミカメ(Stenodema sibiricum)、アカスジカスミカメ(Stenotus rubrovittatus)、イネホソミドリカスミカメ(Trigonotylus caelestialium);
(C) Heteroptera (Heteroptera)
(a) Alydidae, for example, Riptortus clavatus;
(B) Helicopter bug family (Coreidae), for example, Cletus punctiger, Spider Helicopter bug (Leptocorisa chinensis);
(c) Lygaeidae (Lygaeidae), for example, Blissus leucopterus, Cavelerius saccharivorus, Togo hemipterus;
(d) Miridae, for example, Halticus insularis, Lygus lineolaris, Psuedatomoscelis seriatus, Stenodema sibiricum, Stenotus rubrovittatus ), Trigonotylus caelestialium;
(e)カメムシ科(Pentatomidae)の、例えば、ネザラ属種(Nezara spp.)の、アオクサカメムシ(Nezara antennata)、ミナミアオカメムシ(Nezara viridula);例えば、シラホシカメムシ属種(Eysarcoris spp.)の、トゲシラホシカメムシ(Eysarcoris aeneus)、オオトゲシラホシカメムシ(Eysarcoris lewisi)、シラホシカメムシ(Eysarcoris ventralis)、その他の、ブチヒゲカメムシ(Dolycoris baccarum)、ナガメ(Eurydema rugosum)、ツヤアオカメムシ(Glaucias subpunctatus)、サギカメムシ(Halyomorpha halys)、クイチモンジカメムシ(Piezodorus hybneri)、チャバネアオカメムシ(Plautia crossota)、イネクロカメムシ(Scotinophora lurida);
(f)ホシカメムシ科(Pyrrhocoridae)の、例えば、アカホシカメムシ(Dysdercus cingulatus);
(g)ヒメヘリカメムシ科(Rhopalidae)の、例えば、アカヒメヘリカメムシ(Rhopalus msculatus);
(h)キンカメムシ科(Scutelleridae)の、例えば、ムギチャイロカメムシ(Eurygasterintegriceps);
(i)グンバイムシ科(Tingidae)の、例えば、ナシグンバイ(Stephanitis nashi)。
(e) Pentatomidae, for example, Nezara spp., Nezara antennata, Nezara viridula; for example, Eysarcoris spp. , Eysarcoris aeneus, Eysarcoris lewisi, Eysarcoris ventralis, Others, Dolycoris baccarum, Eurydema rugosum, Glaucias subpunctatus, Heron stink bug ( Halyomorpha halys), Piezodorus hybneri, Plautia crossota, Scotinophora lurida;
(f) Pyrrhocoridae, such as Dysdercus cingulatus;
(g) Rhopalidae, for example, Rhopalus msculatus;
(h) Scutelleridae, for example, Eurygasterintegriceps;
(i) Tingidae, such as Stephanitis nashi;
(D)腹吻亜目(Sternorrhyncha)
(a)カサアブラムシ科(Adelgidae)の、例えば、カラマツカサアブラムシ(Adelges laricis);
(b)コナジラミ科(Aleyrodidae)例えば、ベミシア属種(Bemisia spp.)の、シルバーリーフコナジラミ(Bemisia argentifolii)、タバココナジラミ(Bemisia tabaci);その他の、ミカントゲコナジラミ(Aleurocanthus spiniferus)、ミカンコナジラミ(Dialeurodes citri)、オンシツコナジラミ(Trialeurodes vaporariorum);
(c)アブラムシ科(Aphididae)、例えば、アフィス属種(Aphis spp.)の、マメアブラムシ(Aphis craccivora)、マメクロアブラムシ(Aphis fabae)、イチゴネアブラムシ(Aphis forbesi)、ワタアブラムシ(Aphis gossypii)、ヨーロッパリンゴアブラムシ(Aphis pomi)、ニワトコアブラムシ(Aphis sambuci)、ユキヤナギアブラムシ(Aphisspiraecola);例えば、ロパロシフム属種(Rhopalosiphum spp.)の、トウモロコシアブラムシ(Rhopalosiphum maidis)、ムギクビレアブラムシ(Rhopalosiphum padi);例えば、ジサフィス属種(Dysaphis spp.)の、オオバコアブラムシ(Dysaphis plantaginea)、ギシギシネアブラムシ(Dysaphis radicola);例えば、マクロシフム属種(Macrosiphum spp.)の、ムギヒゲナガアブラムシ(Macrosiphum avenae)、チューリップヒゲナガアブラムシ(Macrosiphum euphorbiae);例えば、ミズス属種(Myzus spp.)の、ニワウメクロコブアブラムシ(Myzus cerasi)、モモアカアブラムシ(Myzus persicae)、カワリコブアブラムシ(Myzus varians);その他の、エンドウヒゲナガアブラムシ(Acyrthosiphon pisum)、ジャガイモヒゲナガアブラムシ(Aulacorthum solani)、ムギワラギクオマルアブラムシ(Brachycaudus helichrysi)、ダイコンアブラムシ(Brevicoryne brassicae)、イチゴケナガアブラムシ(Chaetosiphon fragaefolii)、モモコフキアブラムシ(Hyalopterus pruni)、チシャミドリアブラムシ(Hyperomyzus lactucae)、ニセダイコンアブラムシ(Lipaphis erysimi)、ソラマメヒゲナガアブラムシ(Megoura viciae)、ムギウスイロアブラムシ(Metopolophium dirhodum)、レタスアブラムシ(Nasonovia ribis-nigri)、ホップイボアブラムシ(Phorodon humuli)、ムギミドリアブラムシ(Schizaphis graminum)、ムギヒゲナガアブラムシ(Sitobion avenae)、コミカンアブラムシ(Toxoptera aurantii);
(D) Sternorrhyncha
(a) of the Adelgidae family, such as Adelges laricis;
(b) Aleyrodidae, for example, Bemisia spp., Bemisia argentifolii, Bemisia tabaci; Others, Aleurocanthus spiniferus, Dialeurodes citri), whitefly (Trialeurodes vaporariorum);
(c) Aphididae, e.g. Aphis spp., Aphis craccivora, Aphis fabae, Aphis forbesi, Aphis gossypii , Aphis pomi, Aphis sambuci, Aphisspiraecola; e.g. Rhopalosiphum spp., Rhopalosiphum madis, Rhopalosiphum padi; e.g. , Dysaphis spp., Dysaphis plantaginea, Dysaphis radicola; e.g., Macrosiphum spp., Macrosiphum avenae, Tulip aphid ( e.g., Myzus spp., Myzus cerasi, Myzus persicae, Myzus varians; others, Acyrthosiphon pisum ), Aulacorthum solani, Brachycaudus helichrysi, Brevicoryne brassicae, Chaetosiphon fragaefolii, Hyalopterus pruni, Hyperomyzus lactucae, Pseudodaikon aphid (Lipaphis erysimi), Vicia faba aphid (Megoura viciae), Metopolophium dirhodum, lettuce aphid (Nasonovia ribis-nigri), hoppy Phorodon humuli, Schizaphis graminum, Sitobion avenae, Toxoptera aurantii;
(d)カタカイガラムシ科(Coccidae)の、例えば、セロプラスター属種(Ceroplastes spp.)の、ツノロウムシ(Ceroplastes ceriferus)、ルビーロウムシ(Ceroplastes rubens);
(e)マルカイガラムシ科(Diaspididae)の、シューダウラカスピス属種(Pseudaulacaspis spp.)の、クワシロカイガラムシ(Pseudaulacaspis pentagona)、ウメシロカイガラムシ(Pseudaulacaspis prunicola);例えば、ウナスピス属種(Unaspis spp.)の、マサキナガカイガラムシ(Unaspis euonymi)、ヤノネカイガラムシ(Unaspis yanonensis);その他の、アカマルカイガラムシ(Aonidiella aurantii)、ナシマルカイガラムシ(Comstockaspis perniciosa)、チャコノハカイガラムシ(Fiorinia theae)、チャノマルカイガラムシ(Pseudaonidia paeoniae);
(f)ワタフキカイガラムシ科(Margarodidae)の、例えば、オオワラジカイガラムシ(Drosicha corpulenta)、イセリアカイガラムシ(Icerya purchasi);
(g)ネアブラムシ科(Phylloxeridae)の、例えば、ブドウネアブラムシ(Viteus vitifolii);
(h)コナカイガラムシ科(Pseudococcidae )の、例えば、プラノコッカス属種(Planococcus spp.)の、ミカンコナカイガラムシ(Planococcus citri)、フジコナカイガラムシ(Planococcus kuraunhiae);その他の、ナスコナカイガラムシ(Phenacoccus solani)、クワコナカイガラムシ(Pseudococcus comstocki);
(i)キジラミ科(Psyllidae)の、例えば、プスルラ属種(Psylla spp.)の、リンゴキジラミ(Psylla mali)、ナシキジラミ(Psylla pyrisuga);その他の、ミカンキジラミ(Diaphorina citri)。
(d) Coccidae, for example, Ceroplastes spp., Ceroplastes ceriferus, Ceroplastes rubens;
(e) Diaspididae, Pseudaulacaspis spp., Pseudaulacaspis pentagona, Pseudaulacaspis prunicola; for example, Unaspis spp. Others, Aonidiella aurantii, Comstockaspis perniciosa, Fiorinia theae, Pseudaonidia paeoniae );
(f) from the family Margarodidae, for example, Drosicha corpulenta, Icerya purchasi;
(g) Phylloxeridae, such as Viteus vitifolii;
(h) Pseudococcidae, for example, Planococcus spp., Planococcus citri, Planococcus kuraunhiae; other Phenacoccus solani , Pseudococcus comstocki;
(i) Psyllidae, such as Psylla spp., Psylla mali, Psylla pyrisuga; other, Diaphorina citri.
(4)カブトムシ亜目(Polyphaga)の害虫
(a)シバンムシ科(Anobiidae)の、例えば、タバコシバンムシ(Lasioderma serricorne);
(b)オトシブミ科(Attelabidae)の、例えば、ドロハマキチョッキリ(Byctiscus betulae)、モモチョッキリゾウムシ(Rhynchites heros);
(c)ナガシンクイムシ科(Bostrichidae)の、例えば、ヒラタキクイムシ(Lyctus brunneus);
(d)ミツギリゾウムシ科(Brentidae)の、例えば、アリモドキゾウムシ(Cylas formicarius);
(e)タマムシ科(Buprestidae )の、例えば、アカバナガタマムシ (Agrilus sinuatus);
(f)カミキリムシ科(Cerambycidae)の、例えば、ゴマダラカミキリ(Anoplophora malasiaca)、マツノマダラカミキリ(Monochamus alternatus)、キボシカミキリ(Psacothea hilaris)、ブドウトラカミキリ(Xylotrechus pyrrhoderus);
(g)ハムシ科(Chrysomelidae)の、例えば、ブルクス属種(Bruchus spp.)の、エンドウマメゾウムシ(Bruchus pisorum)、ソラマメゾウムシ(Bruchus rufimanus);例えば、ジアブロチカ属種(Diabrotica spp.)の、ノーザンコーンルートワーム(Diabrotica barberi)、サザンコーンルートワーム(Diabrotica undecimpunctata)、ウエスタンコーンルートワーム(Diabrotica virgifera);例えば、フィロトレタ属種(Phyllotreta spp.)の、ノミトビヨロイムシ(Phyllotreta nemorum)、キスジノミハムシ(Phyllotreta striolata);その他の、ウリハムシ(Aulacophora femoralis)、アズキゾウムシ(Callosobruchus chinensis)、カメノコハムシ(Cassida nebulosa)、テンサイトビハムシ(Chaetocnema concinna)、コロラドハムシ(Leptinotarsa decemlineata)、イネクビホソハムシ(Oulema oryzae)、ナスナガスネトビハムシ(Psylliodes angusticollis);
(4) pests of the suborder Polyphaga (a) of the family Anobiidae, for example, Lasioderma serricorne;
(b) of the family Attelabidae, for example, Byctiscus betulae, Rhynchites heroes;
(c) Bostrichidae, for example, Lyctus brunneus;
(d) of the family Brentidae, for example, Cylas formalicarius;
(e) of the Buprestidae family (Buprestidae), for example, Agrilus sinuatus;
(f) Cerambycidae, for example, Anoplophora malasiaca, Monochamus alternatus, Psacothea hilaris, and Xylotrechus pyrrhoderus;
(g) Chrysomelidae, e.g., Bruchus spp., Bruchus pisorum, Bruchus rufimanus; e.g., Diabrotica spp., northern corn Rootworm (Diabrotica barberi), Southern Corn Rootworm (Diabrotica undecimpunctata), Western Corn Rootworm (Diabrotica virgifera); ); others, Aulacophora femoralis, Callosobruchus chinensis, Cassida nebulosa, Chaetocnema concinna, Leptinotarsa decemlineata, Oulema oryzae, eggplant Psylliodes angusticollis;
(h)テントウムシ科(Coccinellidae)の、例えば、エピラクナ属種(Epilachna spp.)の、インゲンテントウ(Epilachna varivestis)、ニジュウヤホシテントウ(Epilachna vigintioctopunctata);
(i)ゾウムシ科(Curculionidae)の、例えば、アントノムス属種(Anthonomus spp.)の、ワタミゾウムシ(Anthonomus grandis)、ナシハナゾウムシ(Anthonomus pomorum);例えば、シトフィルスコクゾウムシ属種(Sitophilus spp.)の、グラナリーウィービル(Sitophilus granarius)、コクゾウムシ(Sitophilus zeamais);その他の、イネゾウムシ(Echinocnemus squameus)、イモゾウムシ(Euscepes postfasciatus)、マツアナアキゾウムシ(Hylobius abietis)、アルファルファタコゾウムシ(Hypera postica)、イネミズゾウムシ(Lissohoptrus oryzophilus)、キンケクチブトゾウムシ(Otiorhynchus sulcatus)、アカアシチビコフキゾウムシ(Sitona lineatus)、シバオサゾウムシ(Sphenophorus venatus);
(j)コメツキムシ科(Elateridae)の、例えば、メラノツス属種(Melanotus spp.)の、マルクビクシコメツキ(Melanotus fortnumi)、カンシャクシコメツキ(Melanotus tamsuyensis);
(k)ケシキスイ科(Nitidulidae)の、例えば、ヒメヒラタケシキスイ(Epuraea domina);
(l)コガネムシ科(Scarabaeidae)の、例えば、アノマラ属種(Anomala spp.)の、ドウガネブイブイ(Anomala cuprea)、ヒメコガネ(Anomala rufocuprea);その他の、キンイロハナムグリ(Cetonia aurata)、コアオハナムグリ(Gametis jucunda)、ナガチャコガネ(Heptophylla picea)、ヨーロッパコフキコガネ(Melolontha melolontha)、マメコガネ(Popillia japonica);
(m)キクイムシ科(Scolytidae)の、例えば、ヤツバキクイ(Ips typographus);
(n)ハネカクシ科(Staphylinidae)の、例えば、アオバアリガタハネカクシ(Paederusfuscipes);
(o)ゴミムシダマシ科(Tenebrionidae)の、例えば、チャイロコメノゴミムシダマシ(Tenebrio molitor)、コクヌストモドキ(Tribolium castaneum);
(p)コクヌスト科(Trogossitidae)の、例えば、コクヌスト(Tenebroides mauritanicus)。
(h) Coccinellidae, for example, Epilachna spp., Epilachna varivestis, Epilachna vigintioctopunctata;
(i) of the Curculionidae family, e.g., Anthonomus spp., Anthonomus grandis, Anthonomus pomorum; e.g., Sitophilus spp. , Granary weevils (Sitophilus granarius), Sitophilus zeamais; Lissohoptrus oryzophilus);
(j) Elateridae, for example, Melanotus spp., Melanotus fortnumi, Melanotus tamsuyensis;
(k) Nitidulidae, for example, Epuraea domina;
(l) Scarabaeidae, for example, Anomala spp., Anomala cuprea, Anomala rufocuprea; other Cetonia aurata, Gametis jucunda ), Heptophylla picea, Melolontha melolontha, Popillia japonica;
(m) Scolytidae, for example, Ips typographus;
(n) Staphylinidae, for example, Paederusfuscipes;
(O) Tenebrionidae, for example, Tenebrio molitor, Tribolium castaneum;
(p) Of the family Trigossitidae, for example, Tenebroides mauritanicus.
(5)ハエ目(Diptera)の害虫
(A)ハエ亜目(Brachycera)
(a)ハモグリバエ科(Agromyzidae)の、例えば、リリオマイザ属種(Liriomyza spp.)の、ナスハモグリバエ(Liriomyza bryoniae)、ネギハモグリバエ(Liriomyza chinensis)、トマトハモグリバエ(Liriomyza sativae)、マメハモグリバエ(Liriomyza trifolii);その他の、ナモグリバエ(Chromatomyia horticola)、イネハモグリバエ(Agromyza oryzae);
(b)ハナバエ科(Anthomyiidae)の、例えば、デリア属種(Delia spp.)の、タネバエ(Delia platura)、キャベツハナバエ(Delia radicum);その他の、テンサイモグリハナバエ(Pegomya cunicularia);
(c)ショウジョウバエ科(Drosophilidae)の、例えば、ショウジョウバエ属種(Drosophila spp.)の、キイロショウジョウバエ(Drosophila melanogaster)、オウトウショウジョウバエ(Drosophila suzukii);
(d)ミギワバエ科(Ephydridae)の、例えば、イネヒメハモグリバエ(Hydrellia griseola);
(e)ハネオレバエ科(Psilidae)の、例えば、ニンジンサビバエ(Psila rosae);
(f)ミバエ科(Tephritidae)の、例えば、バクトロセラ属種(Bactrocera spp.)の、ウリミバエ(Bactrocera cucurbitae)、ミカンコミバエ(Bactrocera dorsalis);例えば、ラゴレチス属種(Rhagoletis spp.)の、ヨーロッパオウトウミバエ(Rhagoletis cerasi)、リンゴミバエ(Rhagoletis pomonella);その他の、チチュウカイミバエ(Ceratitis capitata)、オリーブミバエ(Dacus oleae)。
(5) Diptera pests (A) Brachycera
(a) Agromyzidae, for example, Liriomyza spp., Liriomyza bryoniae, Liriomyza chinensis, Liriomyza sativae, Liriomyza trifolii; other Chromatomyia horticola, Agromyza oryzae;
(b) Anthomyiidae, such as Delia spp., Delia platura, Delia radicum; other Pegomya cunicularia;
(c) Drosophilidae, for example Drosophila spp., Drosophila melanogaster, Drosophila suzukii;
(d) Ephydridae, for example, Hydrellia griseola;
(e) Psilidae, such as Psila rosae;
(f) Tephritidae, for example, Bactrocera spp., Bactrocera cucurbitae, Bactrocera dorsalis; Rhagoletis cerasi), Rhagoletis pomonella; others, Ceratitis capitata, Olive fruit fly (Dacus oleae).
(B)カ亜目(Nematocera)
(a)タマバエ科(Cecidomyiidae)の、例えば、ダイズサヤタマバエ(Asphondylia yushimai)、ソルガムタマバエ(Contarinia sorghicola)、ヘシアンバエ(Mayetiola destructor)、ムギアカタマバエ(Sitodiplosis mosellana)。
(B) Nematocera
(a) Cecidomyiidae, for example, Asphondylia yushimai, Contarinia sorghicola, Mayetiola destructor, and Sitodiplosis moselana.
(6)バッタ目(Orthoptera)の害虫
(a)バッタ科(Acrididae)の、例えば、スキストセルカ属種(Schistocerca spp.)の、アメリカイナゴ(Schistocerca americana)、サバクトビバッタ(Schistocerca gregaria);その他の、オーストラリアトビバッタ(Chortoicetes terminifera)、モロッコイナゴ(Dociostaurus maroccanus)、トノサマバッタ(Locusta migratoria)、ブラウンイナゴ(Locustana pardalina)、アカトビバッタ(Nomadacris septemfasciata)、コバネイナゴ(Oxya yezoensis);
(b)コオロギ科(Gryllidae)の、例えば、ヨーロッパイエコオロギ(Acheta domestica)、エンマコオロギ(Teleogryllus emma);
(c)ケラ科(Gryllotalpidae)の、例えば、ケラ(Gryllotalpa orientalis);
(d)キリギリス科(Tettigoniidae)の、例えば、クラズミウマ(Tachycines asynamorus)。
(6) Pests of the order Orthoptera (a) Acrididae, for example, Schistocerca spp., Schistocerca americana, Schistocerca gregaria; Australian Flying Locust (Chortoicetes terminifera), Moroccan Locust (Dociostaurus maroccanus), Migratory Locust (Locusta migratoria), Brown Locust (Locustana pardalina), Red Flying Locust (Nomadacris septemfasciata), Oxya yezoensis;
(b) of the family Gryllidae, such as Acheta domestica and Teleogryllus emma;
(c) of the family Gryllotalpidae, such as Gryllotalpa orientalis;
(d) Tettigoniidae, such as Tachycines asynamorus.
(7)ダニ類(Acari)
(A)無気門目(Astigmata)のコナダニ類(Acaridida)
(a)コナダニ科(Acaridae)のダニ、例えば、リゾギルホス属種(Rhizoglyphus spp.)の、ネダニ(Rhizoglyphus echinopus)、ロビンネダニ(Rhizoglyphus robini);例えば、ケナガコナダニ属種(Tyrophagus spp.)の、オンシツケナガコナダニ(Tyrophagus neiswanderi)、オオケナガコナダニ(Tyrophagus perniciosus)、ケナガコナダニ(Tyrophagus putrescentiae)、ホウレンソウケナガコナダニ(Tyrophagus similis);その他、アシブトコナダニ(Acarus siro)、ムギコナダニ(Aleuroglyphus ovatus)、ニセケナガコナダニ(Mycetoglyphus fungivorus);
(7) Mites (Acari)
(A) Acaridida of the order Astigmata
(a) Mites of the family Acaridae, e.g., Rhizoglyphus spp., Rhizoglyphus echinopus, Rhizoglyphus robini; e.g., Tyrophagus spp. (Tyrophagus neiswanderi), Tyrophagus perniciosus, Tyrophagus putrescentiae, Tyrophagus similis; others, Acarus siro, Aleuroglyphus ovatus, Mycetoglyphus fungus;
(B)前気門目(Prostigmata)のケダニ類(Actinedida)
(a)ハダニ科(Tetranychidae)のダニ、例えば、ブリオビア属種(Bryobia spp.)の、クローバーハダニ(Bryobia praetiosa)、ニセクローバーハダニ(Bryobia rubrioculus);例えば、エオテトラニクス属種(Eotetranychus spp.)の、コウノシロハダニ(Eotetranychus asiaticus)、アンズハダニ(Eotetranychus boreus)、エノキハダニ(Eotetranychus celtis)、ミチノクハダニ(Eotetranychus geniculatus)、ミヤケハダニ(Eotetranychus kankitus)、クリハダニ(Eotetranychus pruni)、シイノキハダニ(Eotetranychus shii)、スミスハダニ(Eotetranychus smithi)、スギナミハダニ(Eotetranychus suginamensis)、クルミハダニ(Eotetranychus uncatus);例えば、オリゴニクス属種(Oligonychus spp.)の、スギノハダニ(Oligonychus hondoensis)、チビコブハダニ(Oligonychus ilicis)、カラマツハダニ(Oligonychus karamatus)、マンゴーハダニ(Oligonychus mangiferus)、サトウキビハダニ(Oligonychus orthius)、アボガドハダニ(Oligonychus perseae)、エゾスギハダニ(Oligonychus pustulosus)、イネハダニ(Oligonychus shinkajii)、トドマツハダニ(Oligonychus ununguis);例えば、パノニクス属種(Panonychus spp.)の、ミカンハダニ(Panonychus citri)、クワオオハダニ(Panonychus mori)、リンゴハダニ(Panonychus ulmi);例えば、テトラニクス属種(Tetranychus spp.)の、ニセナミハダニ(Tetranychus cinnabarinus)、カンザワハダニ(Tetranychus kanzawai)、アシノワハダニ(Tetranychus ludeni)、ミズナラハダニ(Tetranychus quercivorus)、サガミハダニ(Tetranychus phaselus)、ナミハダニ(Tetranychus urticae)、オウトウハダニ(Tetranychus viennensis);例えば、アポニクス属(Aponychus spp.)の、イトマキハダニ(Aponychus corpuzae)、タイリクハダニ(Aponychus firmianae);例えば、ミドリハダニ属(Sasanychus spp.)の、ミドリハダニ(Sasanychus akitanus)、ヒメミドリハダニ(Sasanychus pusillus);例えば、シゾテトラニクス属(Shizotetranychus spp.)の、タケスゴモリハダニ(Shizotetranychus celarius)、ケナガスゴモリハダニ(Shizotetranychus longus)、ススキスゴモリハダニ(Shizotetranychus miscanthi)、ヒメササハダニ(Shizotetranychus recki)、ヤナギハダニ(Shizotetranychus schizopus);その他、カタバミハダニ(Tetranychinaharti)、ナミケナガハダニ(Tuckerella pavoniformis)、ケウスハダニ(Yezonychus sapporensis);
(B) Actinedida of Prostigmata
(a) mites of the Tetranychidae family, e.g. Bryobia spp., Bryobia praetiosa, Bryobia rubrioculus; e.g. Eotetranychus spp. Eotetranychus asiaticus, Eotetranychus boreus, Eotetranychus celtis, Eotetranychus geniculatus, Eotetranychus kankitus, Eotetranychus pruni, Eotetranychus shii, Smith mite (Eotetranychus smithi), Eotetranychus suginamensis, Eotetranychus uncatus; Oligonychus mangiferus, Oligonychus orthius, Oligonychus perseae, Oligonychus pustulosus, Oligonychus shinkajii, Oligonychus ununguis; for example Panonychus spp. of Tetranychus citri, Panonychus mori, Apple spider mite (Panonychus ulmi); ), Mizunara spider mites (Tet ranychus quercivorus, Tetranychus phaselus, Tetranychus urticae, Tetranychus viennensis; e.g. Aponychus spp., Aponychus corpuzae, Aponychus firmianae; Sasanychus akitanus, Sasanychus pusillus of the genus Sasanychus spp.; for example, Shizotetranychus celarius of the genus Shizotetranychus spp., Shizotetranychus longus ), Shizotetranychus miscanthi, Shizotetranychus recki, Shizotetranychus schizopus; Tetranychinaharti, Tuckerella pavoniformis, Yezonychus sapporensis;
(b)ヒメハダニ科(Tenuipalpidae)のダニ、例えば、ブレビパルプス属種(Brevipalpus spp.)の、ブドウヒメハダニ(Brevipalpus lewisi)、チャノヒメハダニ(Brevipalpus obovatus)、ミナミヒメハダニ(Brevipalpus phoenicis)、サボテンヒメハダニ(Brevipalpus russulus)、オンシツヒメハダニ(brevipalpus californicus);例えば、テニパルプス属種(Tenuipalpus spp.)の、ランヒメハダニ(Tenuipalpus pacificus)、カキヒメハダニ(Tenuipalpus zhizhilashviliae);その他、パイナップルヒメハダニ(Dolichotetranychus floridanus);
(c)フシダニ科(Eriophyidae)のダニ、例えば、アセリア属種(Aceria spp.)の、カキサビダニ(Aceria diospyri)、イチジクモンサビダニ(Aceria ficus)、クリフシダニ(Aceria japonica)、クコフシダニ(Aceria kuko)、カーネーションサビダニ(Aceria paradianthi)、クコハモグリダニ(Aceria tiyingi)、チューリップサビダニ(Aceria tulipae)、シバハマキフシダニ(Aceria zoysiea);例えば、エリオフィエス属種(Eriophyes spp.)の、ニセナシサビダニ(Eriophyes chibaensis)、ウメフシダニ(Eriophyes emarginatae);例えばアクロプス属種(Aculops spp.)の、トマトサビダニ(Aculops lycopersici)、ミカンサビダニ(Aculops pelekassi);例えば、アクルス属種(Aculus spp.)の、モモサビダニ(Aculus fockeui)、リンゴサビダニ(Aculus schlechtendali);その他、チャノナガサビダニ(Acaphylla theavagrans)、チャノサビダニ(Calacarus carinatus)、ブドウハモグリダニ(Colomerus vitis)、ブドウサビダニ(Calepitrimerus vitis)、ナシサビダニ(Epitrimerus pyri)、キンモクサビダニ(Paraphytoptus kikus)、マキサビダニ(Paracalacarus podocarpi)、リュウキュウミカンサビダニ(Phyllocotruta citri);
(d)ホコリダニ科(Transonemidae)のダニ、例えば、タルソネムス属種(Tarsonemus spp.)の、スジブトホコリダニ(Tarsonemus bilobatus)、アシボソホコリダニ(Tarsonemus waitei);その他、シクラメンホコリダニ(Phytonemus pallidus)、チャノホコリダニ(Polyphagotarsonemus latus);
(e)ハシリダニ科(Penthaleidae)のダニ、例えば、ペンタレウス属種(Penthaleus spp.)の、ハクサイダニ(Penthaleus erythrocephalus)、ムギダニ(Penthaleus major)。
(b) mites of the family Tenuipalpidae, for example Brevipalpus spp., Brevipalpus lewisi, Brevipalpus obovatus, Brevipalpus phoenicis, Brevipalpus russulus), brevipalpus californicus; for example, Tenuipalpus spp., Tenuipalpus pacificus, Tenuipalpus zhizhilashviliae;
(c) Mites of the family Eriophyidae, such as Aceria spp., Aceria diospyri, Aceria ficus, Aceria japonica, Aceria kuko, carnation Aceria paradianthi, Aceria tiyingi, Aceria tulipae, Aceria zoysiea; e.g. Eriophyes chibaensis, Eriophyes of Eriophyes spp. emarginatae; e.g. Aculops spp., Aculops lycopersici, Aculops pelekassi; e.g., Aculus spp., Aculus fockeui, Aculus schlechtendali); others, Acaphylla theavagrans, Calacarus carinatus, Colomerus vitis, Calepitrimerus vitis, Epitrimerus pyri, Paraphytoptus kikus, Paracalacarus podocarpi), Phyllocotruta citri;
(d) mites of the family Transonemidae, for example, Tarsonemus spp., Tarsonemus bilobatus, Tarsonemus waitei; Others, Phytonemus pallidus, Polyphagotarsonemus latus );
(e) mites of the family Penthaleidae, for example, Penthaleus erythrocephalus, Penthaleus major of Penthaleus spp.
(8)植物寄生性線虫類
(A)クキセンチュウ目(Tylenchida)
(a)アングイナ科(Anguinidae)の、例えば、アングイナ属種(Anguina spp.)の、アングイナ・フネスタ(Anguina funesta)、コムギツブセンチュウ(Anguina tritici);ジチレンクス属種(Ditylenchus spp.)の、イモグサレセンチュウ(Ditylenchus destructor)、ナミクキセンチュウ(Ditylenchus dipsaci)、キノコセンチュウ(Ditylenchusmyceliophagus);
(b)アフェレンコイデス科(Aphelenchoididae)の、例えば、アフェレンコイデス属種(Aphelenchoides spp.)の、イネシンガレセンチュウ(Aphelenchoides besseyi)、イチゴセンチュウ(Aphelenchoides fragariae)、ハガレセンチュウ(Aphelenchoides ritzemabosi)、イネシンガレセンチュウ(Aphelenchoides besseyi);ブルサフェレンクス属種(Bursaphelenchus spp.)の、マツノザイセンチュウ(Bursaphelenchus xylophilus);
(c)ベロノライムス科(Belonolaimidae)の、例えば、ベロノライムス属種(Belonolaimus spp.)の、ベロノライムス・ロンギカウダツス(Belonolaimus longicaudatus);チレンコリンクス属種(Tylenchorhynchus spp.)の、ナミイシュクセンチュウ(Tylenchorhynchus claytoni)、チレンコリンクス・ズビウス(Tylenchorhynchus dubius);
(d)クリコネマ科(Criconematidae)の、例えば、クリコネマ・ムタビル(Criconema mutabile);
(e)ドリコドルス科(Dolichodoridae)の、例えば、ドリコドルス・メディテラネウス(Dolichodorus mediterraneus);
(f)エクフャドフォラ科(Ecphyadophoridae)の、例えば、エクフャドフォラ・テヌイシマ(Ecphyadophora tenuissima)
(g)ヘミシクリオフォラ科(Hemicycliophoridae)の、例えば、ローフィア・チエネマニ(Loofia thienemanni);
(h)ヘテロデラ科(Heteroderidae)の、例えば、グロボデラ属種(Globodera spp.)の、ジャガイモシストセンチュウ(Globodera rostochiensis)、ジャガイモシロシストセンチュウ(Globodera pallida)、タバコシストセンチュウ(Globodera tabacum);ヘテロデア属種(Heterodera spp.)の、ムギシストセンチュウ(Heterodera avenae)、ヘテロデア・フルシフェラ(Heterodera cruciferae)、ダイズシストセンチュウ (Heterodera glycines)、テンサイシストセンチュウ (Heterodera schachtii)、クローバシストセンチュウ(Heterodera trifolii);
(i)ホプロライムス科(Hoplolaimidae)の、例えば、ヘリコチレンクス属種(Helicotylenchus spp.)の、ナミラセンセンチュウ(Helicotylenchus dihystera)、ヘリコチレンクス・ムルチシンクツス(Helicotylenchus multicinctus);ホプロライムス属種(Hoplolaimus spp.)の、ホプロライムス・コロンブス(Hoplolaimus columbus)、ホプロライムス・ガレアツス(Hoplolaimus galeatus);その他の、ロチレンカス・ロブスタス(Rotylenchus robustus)、ロチレンクルス・レニホルミス(Rotylenchulus reniformis);
(j)メロイドギネ科(Meloidogynidae)の、例えば、メロイドギネ属種の(Meloidogynespp.)、アレナリアネコブセンチュウ(Meloidogyne arenaria)、コロンビアネコブセンチュウ(Meloidogyne chitwoodi)、キタネコブセンチュウ(Meloidogyne hapla)、サツマイモネコブセンチュウ(Meloidogyne incognita)、ジャワネコブセンチュウ(Meloidogyne javanica)、テムズネコブセンチュウ(Meloidogyne thamesi);
(k)ノスティレンクス科(Nothotylenchidae)の、例えば、イチゴメセンチュウ(Nothotylenchus acris);
(l)パラティレンクス科(Paratylenchidae)の、例えば、パラティレンクス属種(Paratylenchus spp.)の、チャピンセンチュウ(Paratylenchus curvitatus)、ヒメピンセンチュウ(Paratylenchus elachistus);
(m)プラティレンクス科(Pratylenchidae)の、例えば、プラティレンクス属(Pratylenchus spp.)種の、プラティレンクスネグサレセンチュウ(Pratylenchus brachyurus)、ミナミネグサレセンチュウ(Pratylenchus coffeae)、ピンセンチュウ(Pratylenchuscurvitatus)、キクネグサレセンチュウ(Pratylenchus fallax)、プラティレンクス・ゴーデイ(Pratylenchus goodeyi)、プラティレンクス・ネグレクツス(Pratylencus neglectus)、キタネグサレセンチュウ(Pratylenchus penetrans)、プラティレンクス・スクリブネリ(Pratylenchus scribneri)、クルミネグサレセンチュウ(Pratylenchus vulnus)、モロコシネグサレセンチュウ(Pratylenchus zeae);その他の、ニセネコブセンチュウ(Nacobbus aberrans)、バナナネモグリセンチュウ(Radopholus similis)、ミカンネセンチュウ(Tylenchulus semipenetrans)、カンキツネモグリセンチュウ(Radopholus citrophilus)。
(8) Plant parasitic nematodes (A) Tylenchida
(a) Anguinidae, for example, Anguina spp., Anguina funesta, Anguina tritici; Ditylenchus spp., Imogusare nematode ( Ditylenchus destructor), Ditylenchus dipsaci, Ditylenchus myceliophagus;
(b) Aphelenchoides family (Aphelenchoididae), for example, Aphelenchoides spp., Aphelenchoides besseyi, Aphelenchoides fragariae, Aphelenchoides ritzemabosi, rice Aphelenchoides besseyi; Bursaphelenchus xylophilus, of Bursaphelenchus spp.;
(c) Belonolaimidae, e.g., Belonolaimus spp., Belonolaimus longicaudatus; Tylenchorhynchus spp., Tylenchorhynchus claytoni , Tylenchorhynchus dubius;
(d) of the family Criconematidae, such as Criconema mutabile;
(e) of the family Dolichoodoridae, such as Dolichoodorus mediterraneus;
(f) Ecphyadophoridae, for example, Ecphyadophora tenuissima
(g) Hemicycliophoridae, such as Loofia thienemanni;
(h) Globodera rostochiensis, Globodera pallida, Globodera tabacum of the family Heteroderidae, e.g. Globodera spp.; (Heterodera spp.), Heterodera avenae, Heterodera cruciferae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii;
(i) of the family Hoplolimidae, for example, Helicotylenchus spp., Helicotylenchus dihystera, Helicotylenchus multicinctus; Columbus (Hoplolaimus columbus), Hoplolaimus galeatus; Others, Rotylenchus robustus, Rotylenchus reniformis;
(j) Meloidogyne family (Meloidogynidae), for example, Meloidogyne spp. Meloidogyne javanica, Meloidogyne thamesi;
(k) of the family Nothotylenchidae, such as Nothotylenchus acris;
(l) Paratylenchidae, for example, Paratylenchus spp., Paratylenchus curvitatus, Paratylenchus elachistus;
(m) Pratylenchus family (Pratylenchidae), for example, Platylenchus spp. Species, Platylenchus brachyurus, Pratylenchus coffeae, Pinnematode (Pratylenchus curvitatus) , Pratylenchus fallax, Pratylenchus goodeyi, Pratylenchus neglectus, Pratylenchus penetrans, Platylenchus scribneri, Walnut Pratylenchus vulnus, Pratylenchus zeae; others, Nacobbus aberrans, Radopholus similis, Tylenchulus semipenetrans, Radopholus citrophilus ).
(B)ドリライムス目(Dorylaimida)
(a)ロンギドルス科(Longidoridae)の、例えば、ロンギドルス属種(Longidorus spp.)の、ロンギドルス・エロンガテス(Longidorus elongates);キシフィネマ属種(Xiphinema)の、アメリカオオハリセンチュウ(Xiphinema americanum)、キシフィネマ・ブレビコーレ(Xiphinema brevicolle)、ブドウオオハリセンチュウ(Xiphinema index)、キシフィネマ・ディバーシカウダツム(Xiphinema diversicaudatum)。
(B) Dorylaimida
(a) Longidoridae, e.g., Longidorus spp., Longidorus elongates; Xiphinema, Xiphinema americanum, Xiphinema brevicole (Xiphinema brevicolle), Grape Nematode (Xiphinema index), Xiphinema diversicaudatum (Xiphinema diversicaudatum).
(C)トリプロンキダ目(Triplonchida)
(a)トリコドルス科(Trichodoridae)の、例えば、トリコドルス・プリミチブス(Trichodorus primitivus)、ヒメユミハリセンチュウ(Paratrichodorus minor)。
(C) Triplonchida
(a) Trichodoridae family (Trichodoridae), for example, Trichodorus primitibus (Trichodorus primitibus), Nematode nematode (Paratrichodorus minor).
本発明の有害生物防除剤は、殺菌剤、殺虫・殺ダニ剤、殺線虫剤、殺土壌害虫剤などの他の有効成分;植物調節剤、除草剤、共力剤、肥料、土壌改良剤、動物用飼料などと混用または併用してもよい。
本発明化合物と他の有効成分との組合せは、殺虫・殺ダニ・殺線虫活性に関して相乗効果が期待できる。相乗効果は、定法に従ってコルビーの式(Colby.S.R. ; Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ; Weeds 15, 20-22頁, 1967)により確認することができる。
The pest control agent of the present invention includes other active ingredients such as fungicides, insecticides/miticides, nematicides, and soil pesticides; plant regulators, herbicides, synergists, fertilizers, and soil conditioners. , animal feed, etc., may be mixed or used together.
The combination of the compound of the present invention and other active ingredients can be expected to have a synergistic effect with respect to insecticidal, acaricidal and nematicidal activities. The synergistic effect can be confirmed by Colby's formula (Colby. SR; Calculating Synergistic and Antagonistic Responses of Herbicide Combinations; Weeds 15, pp. 20-22, 1967) according to the standard method.
〔内部寄生虫防除もしくは駆除剤〕
本発明の内部寄生虫防除もしくは駆除剤は、本発明のアリールアゾール化合物から選ばれる少なくともひとつを有効成分として含有する。
[Internal Parasite Control or Pesticide]
The internal parasite control or extermination agent of the present invention contains at least one selected from the arylazole compounds of the present invention as an active ingredient.
本発明の内部寄生虫防除もしくは駆除剤の対象となる寄生虫は、宿主動物、特には温血動物や魚類の体内に寄生する(内部寄生虫)。本発明の内部寄生虫防除もしくは駆除剤が有効な宿主動物としては、ヒト、家畜哺乳動物(例えば、ウシ、ウマ、ブタ、ヒツジ、ヤギなど)、実験動物(例えば、マウス、ラット、スナネズミなど)、愛玩動物(例えば、ハムスター、モルモット、イヌ、ネコ、ウマ、リス、ウサギ、フェレットなど)、野生および動物園の哺乳動物(サル、キツネ、シカ、バッファローなど)、家禽(シチメンチョウ、アヒル、ニワトリ、ウズラ、ガチョウなど)、愛玩鳥(ハト、オウム、九官鳥、文鳥、インコ、ジュウシマツ、カナリアなど)などの温血動物;または、サケ、マス、ニシキゴイなどの魚類を挙げることができる。寄生虫を防除および駆除することで、寄生虫が媒介する寄生虫疾患を予防または治療することができる。 The parasites targeted by the endoparasite control or extermination agent of the present invention parasitize in the body of host animals, particularly warm-blooded animals and fish (endoparasites). Host animals for which the internal parasite control or extermination agent of the present invention is effective include humans, livestock mammals (eg, cows, horses, pigs, sheep, goats, etc.), experimental animals (eg, mice, rats, gerbils, etc.). , companion animals (e.g., hamsters, guinea pigs, dogs, cats, horses, squirrels, rabbits, ferrets, etc.), wild and zoo mammals (monkeys, foxes, deer, buffalo, etc.), poultry (turkeys, ducks, chickens, quail, etc.) , geese, etc.), pet birds (pigeons, parrots, myna birds, Java sparrows, parakeets, marigolds, canaries, etc.); or fishes, such as salmon, trout and koi. Parasite-borne parasitic diseases can be prevented or treated by controlling and eliminating parasites.
防除または駆除対象の寄生虫としては、以下のものを挙げることができる。
(1)腎虫目(Dioctophymatida)の線虫類
(a)腎虫科(Dioctophymatidae)の腎虫、例えば、ディオクトフィーマ属種(Dioctophyma spp.)の、腎虫(Dioctophyma renale);
(b)ソブリフィメ科(Soboliphymatidae)の腎虫、例えば、ソブリフィメ属種(Soboliphyme spp.)の、ソブリフィメ・アベイ(Soboliphyme abei)、ソブリフィメ・ブツリニ(Soboliphyme baturini)。
Parasites to be controlled or exterminated include the following.
(1) nematodes of the order Dioctophymatida (a) kidney worms of the family Dioctophymatidae, such as Dioctophyma renale of the genus Dioctophyma spp.;
(b) kidney worms of the family Soboliphymatidae, for example, Soboliphyme abei, Soboliphyme baturini of Soboliphyme spp.
(2)毛頭虫目(Trichocephalida)の線虫類
(a)旋毛虫科(Trichinellidae)の旋毛虫、例えば、旋毛虫属種(Trichinella spp.)の、旋毛虫(Trichinella spiralis);
(b)鞭虫科(Trichuridae)の鞭虫、例えば、キャピラリア属種(Capillaria spp.)の、有環毛細線虫(Capillaria annulata)、捻転毛細線虫(Capillaria contorta)、肝毛細線虫(Capillaria hepatica)、穿通毛細線虫(Capillaria perforans)、キャピラリア・プリカ(Capillaria plica)、豚毛細線虫(Capillaria suis);トリキュリス属種(Trichuris spp.)の、犬鞭虫(Trichuris vulpis)、牛鞭虫(Trichuris discolor)、羊鞭虫(Trichuris ovis)、トリキュリス・スクリジャビニー(Trichuris skrjabini)、豚鞭虫(Trichuris suis)。
(2) nematodes of the order Trichocephalida (a) trichinella of the family Trichinellidae, such as Trichinella spiralis of the genus Trichinella spp.;
(b) whipworms of the Trichuridae family, for example, Capillaria spp., Capillaria annulata, Capillaria contorta, Hepatic Capillaries ( Capillaria hepatica, Capillaria perforans, Capillaria plica, Capillaria suis; Trichuris spp., Trichuris vulpis, cattle Trichuris discolor, Trichuris ovis, Trichuris skrjabini, Trichuris suis.
(3)桿線虫目(Rhabditida)の線虫類
糞線虫科(Strongyloididae)の糞線虫、例えば、糞線虫属種(Strongyloides spp.)の、乳頭糞線虫(Strongyloides papillosus)、猫糞線虫(Strongyloides planiceps)、豚糞線虫(Strongyloides ransomi)、豚糞線虫(Strongyloides suis)、糞線虫(Strongyloides stercoralis )、アメリカ猫糞線虫(Strongyloides tumefaciens)、ネズミ糞線虫(Strongyloides ratti)。
(3) Nematodes of the order Rhabditida Strongyloidae of the Strongyloididae family, for example, Strongyloides papillosus of the genus Strongyloides spp., cat droppings Strongyloides planiceps, Strongyloides ransomi, Strongyloides suis, Strongyloides stercoralis, Strongyloides tumefaciens, Strongyloides ratti .
(4)円虫目(Strongylida)の線虫類
鈎虫科(Ancylostomatidae)の鉤虫、例えば、鉤虫属種(Ancylostoma spp.)の、ブラジル鉤虫(Ancylostoma braziliense)、犬鉤虫(Ancylostoma caninum)、ズビニ鉤虫(Ancylostoma duodenale)、ネコ鈎虫(Ancylostoma tubaeforme);ウンシナリア属種(Uncinaria stenocephala)の、狭頭鉤虫(Uncinaria stenocephala);ブノストマム属種(Bunostomum spp.)の、牛鉤虫(Bunostomum phlebotomum)、羊鉤虫(Bunostomum trigonocephalum)。
(4) Nematodes of the order Strongylida Hookworms of the family Ancylostomatidae, for example, Ancylostoma braziliense, Ancylostoma caninum, and Ancylostoma caninum of the genus Ancylostoma spp. Ancylostoma duodenale, Ancylostoma tubaeforme; Uncinaria stenocephala, Uncinaria stenocephala; Bunostomum phlebotomum, Bunostomum spp. Bunostomum trigonocephalum).
(5)円虫目(Strongylida)の線虫類
(a)住血線虫科(Angiostrongylidae)の線虫、例えば、ネコ肺虫属種(Aelurostrongylus spp.)の、猫肺虫(Aelurostrongylus abstrusus);住血線虫属種(Angiostrongylusspp.)の、住血線虫(Angiostrongylus vasorum)、広東住血線虫(Angiostrongylus cantonesis);
(b)クレノゾーマ科(Crenosomatidae)の線虫、例えば、クレノゾーマ属種(Crenosomaspp.)の、肺毛細線虫(Crenosoma aerophila)、キツネ肺虫(Crenosoma vulpis);
(c)フィラロイデス科(Filaroididae)の線虫、例えば、フィラロイデス属種(Filaroides spp.)の、犬肺虫(Filaroides hirthi)、フィラロイデス・オスレリ(Filaroides osleri);
(d)肺虫科(Metastrongylidae)の肺虫、例えば、豚肺虫属種(Metastrongylus spp.)の、豚肺虫(Metastrongylus apri)、メタストロンギルス・アシムメトリクス(Metastrongylus asymmetricus)、メタストロンギルス・プデンドテクタス(Metastrongylus pudendotectus)、メタストロンギルス・サルミィ(Metastrongylus salmi);
(e)開嘴虫科(Syngamidae)の開嘴虫、例えば、シアトストーマ属種(Cyathostoma spp.)の、水鳥肺虫(Cyathostoma bronchialis);シンガムス属種(Syngamus spp.)の、スクリジャビン開嘴虫(Syngamus skrjabinomorpha)、鶏開嘴虫(Syngamus trachea)。
(5) nematodes of the order Strongylida (a) nematodes of the family Angiostrongylidae, such as Aelurostrongylus abstrusus of the genus Aelurostrongylus spp.; of Angiostrongylus spp., Angiostrongylus vasorum, Angiostrongylus cantonesis;
(b) nematodes of the Crenosomatidae family, such as Crenosoma aerophila, Crenosoma vulpis of the genus Crenosoma spp.;
(c) nematodes of the family Filaroididae, for example Filaroides spp., Filaroides hirthi, Filaroides osleri;
(d) lungworms of the family Metastrongylidae, such as Metastrongylus spp., Metastrongylus apri, Metastrongylus asymmetricus, Metastrongylus pudendoctus ( Metastrongylus pudendotectus), Metastrongylus salmi;
(e) Syngamidae, for example, Cyathostoma bronchialis of Cyathostoma spp.; Syngamus skrjabinomorpha), chicken beak (Syngamus trachea).
(6)円虫目(Strongylida)の線虫類
(a)モリネウス科(Molineidae)の線虫、例えば、ネマトジルス属種(Nematodirus spp.)の、細頸毛円虫(Nematodirus filicollis)、ネマトジルス・スパティガー(Nematodirus spathiger);
(b)ディクチオカウルス科(Dictyocaulidae)の線虫、例えば、ディクチオカウルス属種(Dictyocaulus spp.)の、糸状肺虫(Dictyocaulus filaria)、牛肺虫(Dictyocaulus viviparus );
(c)捻転胃虫科(Haemonchidae )の線虫、例えば、ヘモンクス属種(Haemonchus spp.)の、捻転胃虫(Haemonchus contortus);メキストシリウス属種(Mecistocirrus spp.)の、牛捻転胃虫(Mecistocirrus digitatus);
(d)捻転胃虫科(Haemonchidae)の線虫、例えば、胃虫属種(Ostertagia spp.)の、オステルターグ胃虫(Ostertagia ostertagi );
(e)ヘリグモネラ科(Heligmonellidae )の線虫、例えば、ニッポストロンジルス属種(Nippostrongylus spp.)の、ネズミ円虫(Nippostrongylus braziliensis);
(f)毛様線虫科(Trichostrongylidae)の線虫、例えば、毛様線虫属種(Trichostrongylus spp.)の、皺胃毛様線虫(Trichostrongylus axei )、蛇状毛様線虫(Trichostrongylus colubriformis )、毛様線虫科(Trichostrongylus tenuis);ヒオストロンギルス属種(Hyostrongylus spp.)の、紅色毛様線虫(Hyostrongylus rubidus);オベリスコイデス属種(Obeliscoides spp.)の、オベリスコイデス・クニクリ(Obeliscoides cuniculi)。
(6) Nematodes of the order Strongylida (a) Nematodes of the Molineidae family, for example, Nematodirus filicollis of the genus Nematodirus spp., Nematodirus spa Tigger (Nematodirus spathiger);
(b) Nematodes of the family Dictyocaulidae, for example, Dictyocaulus spp., Dictyocaulus filaria, Dictyocaulus viviparus;
(c) nematodes of the Haemonchidae family, for example, Haemonchus contortus of the spp. Haemonchus spp.; Bovine spp. of the spp. Mecistocirrus (Mecistocirrus digitatus);
(d) nematodes of the family Haemonchidae, for example Ostertagia ostertagi of the genus Ostertagia spp.;
(e) nematodes of the family Heligmonellidae, for example, Nippostrongylus braziliensis of the genus Nippostrongylus spp.;
(f) Nematodes of the Trichostrongylidae family, for example Trichostrongylus axei, Trichostrongylus colubriformis of the genus Trichostrongylus spp. ), Trichostrongylus tenuis; Hyostrongylus spp., Hyostrongylus rubidus; Obeliscoides spp., Obeliscoides cuniculi ).
(7)円虫目(Strongylida)の線虫類
(a)シャベルティア科(Chabertiidae)の線虫、例えば、シャベルティア属種(Chabertia spp.)の、羊縮小線虫(Chabertia ovina);腸結節虫属種(Oesophagostomum spp.)の、腸結節虫(豚)(Oesophagostomum brevicaudatum)、コロンビア腸結節虫(Oesophagostomum columbianum)、豚腸結節虫(Oesophagostomum dentatum)、腸結節虫(豚)(Oesophagostomum georgianum)、腸結節虫(Oesophagostomum maplestonei)、腸結節虫(豚)(Oesophagostomum quadrispinulatum)、牛腸結節虫(Oesophagostomum radiatum)、山羊腸結節虫(Oesophagostomum venulosum)、腸結節虫(イノシシ)(Oesophagostomum watanabei);
(b)豚腎虫科(Stephanuridae)の線虫、例えば、ステファヌラス属種(Stephanurus spp.)の、豚腎虫(Stephanurus dentatus );
(c)円虫科(Strongylidae)の線虫、例えば、円虫属種(Strongylus spp.)の、ロバ円虫(Strongylus asini )、無歯円虫(Strongylus edentatus)、馬円虫(Strongylus equinus)、普通円虫(Strongylus vulgaris)。
(7) Nematodes of the order Strongylida (a) Nematodes of the family Chabertiidae, such as Chabertia ovina of the genus Chabertia spp.; Oesophagostomum spp., Oesophagostomum brevicaudatum, Oesophagostomum columbianum, Oesophagostomum dentatum, Oesophagostomum georgianum, Oesophagostomum maplestonei, Oesophagostomum quadrispinulatum, Oesophagostomum radiatum, Oesophagostomum venulosum, Oesophagostomum watanabei;
(b) Nematodes of the Stephanuridae family, such as Stephanurus dentatus of Stephanurus spp.;
(c) nematodes of the family Strongylidae, e.g., of the genus Strongylus spp., Strongylus asini, Strongylus edentatus, Strongylus equinus , common roundworm (Strongylus vulgaris).
(8)蟯虫目(Oxyurida)の線虫類
蟯虫科(Oxyuridae)の線虫、例えば、エンテロビウス属種(Enterobius spp.)の、チンパンジー蟯虫(Enterobius anthropopitheci)、蟯虫(Enterobius vermicularis);
オキシルス属(Oxyuris spp.)の、馬蟯虫(Oxyuris equi);パサルルス属種(Passalurus spp.)の、ウサギ蟯虫(Passalurus ambiguus)。
(8) Nematodes of the order Oxyurida Nematodes of the Oxyuridae family, for example, Enterobius spp., Chimpanzee pinworm (Enterobius anthropopitheci), Pinworm (Enterobius vermicularis);
Oxyuris equi of Oxyuris spp.; Passalurus ambiguus of Passalurus spp.
(9)回虫目(Ascaridida)の線虫類
(a)ニワトリ回虫科(Ascaridiidae)の線虫、例えば、ニワトリ回虫属種(Ascaridia spp.)の、ニワトリ回虫(Ascaridia galli);
(b)盲腸虫科(Heterakidae)の線虫、例えば、ヘテラキス属種(Heterakis spp.)の、ヘテラキス・ベラムポリア(Heterakis beramporia)、ヘテラキス・ブレビスピクルム(Heterakis brevispiculum)、鶏盲腸虫(Heterakis gallinarum)、ヘテラキス・プシーラ(Heterakis pusilla)、ヘテラキス・プトオーストラリス(Heterakis putaustralis);
(c)アニサキス科(Anisakidae)の線虫、例えば、アニサキス属種(Anisakis spp.)の、アニサキス線虫(Anisakis simplex);
(d)回虫科(Ascarididae)の線虫、例えば、回虫属種(Ascaris spp.)の、ヒト回虫(Ascaris lumbricoides)、豚回虫(Ascaris suum);パラスカリア属種(Parascaris spp.)の、馬回虫(Parascaris equorum);
(e)トキソカーラ科(Toxocaridae)の線虫、例えば、トキソカーラ属種(Toxocara spp.)の、犬回虫(Toxocara canis)、犬小回虫(Toxocara leonina)、豚回虫(Toxocarasuum)、牛回虫(Toxocara vitulorum)、猫回虫(Toxocara cati)。
(9) nematodes of the order Ascaridida (a) nematodes of the Ascaridiidae family, for example Ascaridia galli of Ascaridia spp.;
(b) Nematodes of the family Heterakidae, such as Heterakis spp., Heterakis beramporia, Heterakis brevispiculum, Heterakis gallinarum , Heterakis pusilla, Heterakis putaustralis;
(c) nematodes of the Anisakidae family, such as Anisakis simplex of Anisakis spp.;
(d) Nematodes of the Ascarididae family, such as Ascaris lumbricoides, Ascaris suum of Ascaris spp.; Horse roundworm of Parascaria spp. (Parascaris equorum);
(e) Nematodes of the Toxocaridae family, for example, Toxocara spp., Toxocara canis, Toxocara leonina, Toxocarasuum, Toxocara vitulorum ), Toxocara cati.
(10)旋尾線虫目(Spirurida)の線虫類
(a)オンコセルカ科(Onchocercidae)の線虫、例えば、ブルギア属種(Brugia spp.)の、マレー糸状虫(Brugia malayi)、ブルギア・パハンギィ(Brugia pahangi)、ブルギア・パティ(Brugia patei);ディペタロネーマ属種(Dipetalonema spp.)の、ディペタロネーマ・リコンディトゥム(Dipetalonema reconditum);イヌ糸状虫属種(Dirofilaria spp.)の、イヌ糸状虫(Dirofilaria immitis);フィラリア属種(Filaria spp.)の、フィラリア・オクリィ(Filaria oculi);オンコセルカ属種(Onchocerca spp.)の、頸部糸状虫(Onchocerca cervicalis)、ギブソン糸状虫(Onchocerca gibsoni)、咽頭糸状虫(Onchocerca gutturosa);
(b)セタリア科(Setariidae)の線虫、例えば、セタリア属種(Setaria spp.)の、指状糸状虫(Setaria digitata)、馬糸条虫(Setaria equina)、唇乳頭糸状虫(Setaria labiatopapillosa)、マーシャル糸状虫(Setaria marshalli);ブケレリア属種(Wuchereria spp.)の、バンクロフト糸状虫(Wuchereria bancrofti);
(c)糸状虫科(Filariidae)の線虫、例えば、パラフィラリア属種(Parafilaria spp.)の、多乳頭糸状虫(Parafilaria multipapillosa);ステファノフィラリア属種(Stephanofilaria spp.)の、ステファノフィラリア・アッサムエンシス(Stephanofilaria assamensis)、ステファノフィラリア・デドエシー(Stephanofilaria dedoesi)、ステファノフィラリア・カエリー(Stephanofilaria kaeli)、沖縄糸状虫(Stephanofilaria okinawaensis)、ステファノフィラリア・スティレシー(Stephanofilaria stilesi)。
(10) nematodes of the order Spirurida (a) nematodes of the family Onchocercidae, for example, Brugia malayi of Brugia spp., Brugia pahangi (Brugia pahangi), Brugia patei; Dipetalonema spp., Dipetalonema reconditum; Dirofilaria spp., Dirofilaria immitis; Filaria spp., Filaria oculi; Onchocerca spp., Onchocerca cervicalis, Onchocerca gibsoni, pharyngeal filamentous bugs (Onchocerca gutturosa);
(b) nematodes of the Setariidae family, for example, Setaria spp., Setaria digitata, Setaria equina, Setaria labiatopapillosa , Setaria marshalli; Wuchereria spp., Wuchereria bancrofti;
(c) Nematodes of the family Filariidae, such as Parafilaria multipapillosa of the spp. Parafilaria spp.; Stephanofilaria assam of the spp. Stephanofilaria spp. Stephanofilaria assamensis, Stephanofilaria dedoesi, Stephanofilaria kaeli, Stephanofilaria okinawaensis, Stephanofilaria stilesi.
(11)旋尾線虫目(Spirurida)の線虫類
(a)顎口虫科(Gnathostomatidae)の線虫、例えば、顎口虫属種(Gnathostoma spp.)の、顎口虫(Gnathostoma doloresi)、有棘顎口虫(Gnathostoma spinigerum);
(b)ハブロネマ科(Habronematidae)の線虫、例えば、ハブロネマ属種(Habronema spp.)の、小口胃虫(Habronema majus)、小口胃虫(Habronema microstoma)、蠅馬胃虫(Habronema muscae);ドラスキア属種(Draschia spp.)の、大口馬胃虫(Draschia megastoma);
(c)フィザロプテラ科(Physalopteridae)の線虫、例えば、フィサロプテラ属種(Physaloptera spp.)の、犬胃虫(Physaloptera canis)、キツネ胃虫(Physaloptera cesticillata)、フィサロプテラ・エルドシオーナ(Physaloptera erdocyona)、フィサロプテラ・フェリディス(Physaloptera felidis)、エジプト猫胃虫(Physaloptera gemina)、フィサロプテラ・パピロラディラータ(Physaloptera papilloradiata)、猫胃虫(Physaloptera praeputialis)、フィサロプテラ・シュードプラエルティアリス(Physaloptera pseudopraerutialis)、ラーラ胃虫(Physaloptera rara)、フィサロプテラ・シビリカ(Physaloptera sibirica)、フィサロプテラ・ブルピニウス(Physaloptera vulpineus);
(d)ゴンギロネマ科(Gongylonematidae)の線虫、例えば、ゴンギロネマ属種(Gongylonema spp.)の、美麗食道虫(Gongylonema pulchrum);
(e)スピロセルカ科(Spirocercidae)の線虫、例えば、アスカロプス属種(Ascarops spp.)の、類円豚胃虫(Ascarops strongylina);
(f)テラジア科(Thelaziidae)の線虫、例えば、テラジア属種(Thelazia spp.)の、東洋眼虫(Thelazia callipaeda)、テラジア・グローサ(Thelazia gulosa)、涙眼虫(Thelazia lacrymalis)、ロデシア眼虫(Thelazia rhodesi)、スクリャービン眼虫(Thelazia skrjabini)。
(11) nematodes of the order Spirurida (a) nematodes of the family Gnathostomatidae, for example, Gnathostoma doloresi of the genus Gnathostoma spp. , Gnathostoma spinigerum;
(b) nematodes of the Habronematidae family, such as Habronema majus, Habronema microstoma, Habronema muscae of Habronema spp.; Draschia megastoma, of the genus Draschia spp.;
(c) Nematodes of the Physaloptera family (Physalopteridae), for example, Physaloptera spp., Physaloptera canis, Physaloptera cesticillata, Physaloptera erdocyona, Physaloptera spp. Physaloptera felidis, Physaloptera gemina, Physaloptera papilloradiata, Physaloptera praeputialis, Physaloptera pseudopraerutialis, Physaloptera rara), Physaloptera sibirica, Physaloptera vulpineus;
(d) nematodes of the family Gongylonematidae, such as Gongylonema pulchrum of the genus Gongylonema spp.;
(e) nematodes of the family Spirocercidae, for example Ascarops strongylina of Ascarops spp.;
(f) Nematodes of the Thelaziidae family, such as Thelazia spp., Thelazia callipaeda, Thelazia gulosa, Thelazia lacrymalis, Rhodesian eye Worm (Thelazia rhodesi), scriabin eye worm (Thelazia skrjabini).
〔外部寄生虫防除剤〕
本発明の外部寄生虫防除剤は、本発明のアリールアゾール化合物から選ばれる少なくともひとつを有効成分として含有するものである。本発明の外部寄生虫防除剤に含まれるアルコキシピラゾール化合物の量は外部寄生虫の防除効果を示す限りにおいて特に制限されない。
[Ectoparasite control agent]
The ectoparasite control agent of the present invention contains, as an active ingredient, at least one selected from the arylazole compounds of the present invention. The amount of the alkoxypyrazole compound contained in the ectoparasite-controlling agent of the present invention is not particularly limited as long as the ectoparasite-controlling effect is exhibited.
本発明の外部寄生虫防除剤の処理の対象となる宿主動物としては、ヒト、家畜哺乳動物(例えば、ウシ、ウマ、ブタ、ヒツジ、ヤギなど)、実験動物(例えば、マウス、ラット、スナネズミなど)、愛玩動物(例えば、ハムスター、モルモット、イヌ、ネコ、ウマ、リス、ウサギ、フェレットなど)、野生および動物園の哺乳動物(サル、キツネ、シカ、バッファローなど)、家禽(シチメンチョウ、アヒル、ニワトリ、ウズラ、ガチョウなど)、愛玩鳥(ハト、オウム、九官鳥、文鳥、インコ、ジュウシマツ、カナリアなど)などの温血動物;または、サケ、マス、ニシキゴイなどの魚類を挙げることができる。その他にも、ミツバチ、クワガタムシ、カブトムシを挙げることができる。 Host animals to be treated with the ectoparasite control agent of the present invention include humans, livestock mammals (e.g., cows, horses, pigs, sheep, goats, etc.), experimental animals (e.g., mice, rats, gerbils, etc.). ), companion animals (e.g., hamsters, guinea pigs, dogs, cats, horses, squirrels, rabbits, ferrets, etc.), wild and zoo mammals (monkeys, foxes, deer, buffalo, etc.), poultry (turkeys, ducks, chickens, warm-blooded animals such as quails, geese, etc.), companion birds (pigeons, parrots, myna birds, Java sparrows, parakeets, marigolds, canaries, etc.); or fishes such as salmon, trout and koi. Others include bees, stag beetles, and beetles.
本発明の外部寄生虫防除剤は、公知の獣医学的な手法(局所、経口、非経口または皮下投与)で施用することができる。その方法として、錠剤、カプセル、飼料混入などにより動物に経口的に投与する方法;浸漬液、坐薬、注射(筋肉内、皮下、静脈内、腹腔内など)などにより動物に投与する方法;油性または水性液剤を噴霧、ポアオン、スポットオンなどにより局所的に投与する方法;樹脂に外部寄生虫防除剤を練り込み、前記混練物を首輪、耳札などの適当な形状に成形し、それを動物に装着し局所的に投与する方法;などを挙げることができる。 The ectoparasite control agent of the present invention can be applied by known veterinary techniques (topical, oral, parenteral or subcutaneous administration). Methods include oral administration to animals by tablets, capsules, mixed feed, etc.; A method of locally administering an aqueous solution by spraying, pour-on, spot-on, etc.; kneading an ectoparasite control agent into a resin, molding the kneaded product into a suitable shape such as a collar or ear tag, and applying it to an animal. a method of wearing and administering locally; and the like.
外部寄生虫は、宿主動物、特には温血動物の中および上に寄生する。詳しくは、宿主動物の背、脇下、下腹部、内股部などに寄生して動物から血液やフケなどの栄養源を得て生息する。外部寄生虫としては、ダニ類、シラミ類、ノミ類、カ、サシバエ、ニクバエなどを挙げることができる。本発明の外部寄生虫防除剤によって防除可能な外部寄生虫の具体例を以下に示す。 Ectoparasites live in and on host animals, especially warm-blooded animals. Specifically, it lives in the host animal's back, armpit, lower abdomen, inner thigh, etc., and obtains nutrients such as blood and dander from the animal. Ectoparasites include mites, lice, fleas, mosquitoes, stable flies, flesh flies, and the like. Specific examples of ectoparasites that can be controlled by the ectoparasite control agent of the present invention are shown below.
(1)ダニ類(Acari)
ワクモ科(Dermanyssidae)のダニ、オオサシダニ科(Macronyssidae)のダニ、トゲダニ科(Laelapidae)のダニ、ヘギダニ科(Varroidae)のダニ、ヒメダニ科(Argasidae)のダニ、マダニ科(Ixodidae)のダニ、キュウセンヒゼンダニ科(Psoroptidae)のダニ、ヒゼンダニ科(Sarcoptidae)のダニ、トリヒゼンダニ科(Knemidokoptidae)のダニ、ニキビダニ科(Demodixidae)のダニ、ツツガムシ科(Trombiculidae)のダニ、クワガタナカセ類等の昆虫寄生性のダニ。
(2)シラミ目(Phthiraptera)
ケモノジラミ科(Haematopinidae)のシラミ、ケモノホソジラミ科(Linognathidae)のシラミ、タンカクハジラミ科(Menoponidae)のハジラミ、チョウカクハジラミ科(Philopteridae)のハジラミ、ケモノハジラミ科(Trichodectidae)のハジラミ。
(3)ノミ目(Siphonaptera)
ヒトノミ科(Pulicidae)のノミ、例えば、イヌノミ属種(Ctenocephalides spp.)の、イヌノミ(Ctenocephalides canis)、ネコノミ(Ctenocephalides felis);スナノミ科(Tungidae)のノミ、ナガノミ科(Ceratophyllidae)のノミ、ホソノミ科(Leptopsyllidae)のノミ。
(4)カメムシ目(Hemiptera)。
(5)ハエ目(Diptera)の害虫
カ科(Culicidae)のカ、ブユ科(Simuliidae)のブユ、ヌカカ科(Ceratopogonidae)のヌカカ、アブ科(Tabanidae)のアブ、イエバエ科(Muscidae)のハエ、ツエツエバエ科(Glossinidae)のシェシェバエ、ニクバエ科のニクバエ、シラミバエ科(Hippoboscidae)のハエ、クロバエ科(Calliphoridae)のハエ、ヒツジバエ科(Oestridae)のハエ。
(1) Mites (Acari)
Dermanyssidae ticks, Macronyssidae ticks, Laelapidae ticks, Varroidae ticks, Argasidae ticks, Ixodidae ticks, Dirtid mites Insect-parasitic mites such as Psoroptidae mites, Sarcoptidae mites, Knemidokoptidae mites, Demodixidae mites, Trombiculidae mites, and Stag beetles .
(2) Phthiraptera
Lice of the family Haematopinidae, lice of the family Linognathidae, lice of the family Menoponidae, lice of the family Philopteridae, and lice of the family Trichodectidae.
(3) Siphonaptera
Fleas of the family Pulicidae, such as Ctenocephalides spp., Ctenocephalides canis, Ctenocephalides felis; (Leptopsyllidae) fleas.
(4) Hemiptera.
(5) Mosquitoes of the family Culicidae of the order Diptera, blackflies of the family Simuliidae, blackflies of the family Ceratopogonidae, horseflies of the family Tabanidae, flies of the Housefly family (Muscidae), flies of the family Glossinidae, flies of the family Glossinidae, flies of the family Hippoboscidae, flies of the family Calliphoridae, and flies of the family Oestridae.
〔その他の有害生物についての防除剤〕
本発明のアリールアゾール化合物は、その他にも、毒針や毒液を持ち、人獣に被害を加える害虫、各種の病原体・病原菌を媒介する害虫、人に不快感を与える害虫(有毒害虫・衛生害虫・不快害虫など)の防除効果に優れている。
[Control agent for other harmful organisms]
The arylazole compounds of the present invention also include pests that have poisonous needles or venom and damage humans and animals, pests that transmit various pathogens and pathogens, and pests that cause discomfort to humans (toxic pests, sanitary pests).・Excellent control effect against unpleasant pests, etc.
以下に、その具体例を示す。
(1)ハチ目(Hymenoptera)の害虫
ミフシババチ科(Argidae)のハチ、タマバチ科(Cynipidae)のハチ、マツハバチ科(Diprionidae)のハチ、アリ科(Formicidae)のアリ、アリバチ科(Mutillidae )のハチ、スズメバチ科(Vespidae)のハチ。
Specific examples are shown below.
(1) Hymenoptera pests Argidae bees, Cynipidae bees, Diprionidae Diprionidae bees, Formicidae ants, Mutillidae bees, A bee of the Vespidae family.
(2)その他の害虫
ゴキブリ類(Blattodea)、シロアリ類(termite)、クモ類(Araneae)、ムカデ類(cetipede)、ヤスデ類(millipede)、甲殻類(crustacea)、南京虫(Cimex lectularius)。
(2) Other pests Blattodea, termites, Araneae, cetipede, millipedes, crustacea, Cimex lectularius.
〔製剤処方〕
本発明の有害生物防除剤、殺虫もしくは殺ダニ剤、外部寄生虫防除剤または内部寄生虫防除もしくは駆除剤の製剤処方を若干示すが、添加物および添加割合は、これら実施例に限定されるべきものではなく、広範囲に変化させることが可能である。製剤処方中の部は重量部を示す。
[Formulation formulation]
Some formulations of the pest control agent, insecticide or acaricide, ectoparasite control agent or internal parasite control or extermination agent of the present invention are shown, but the additives and addition ratios should be limited to these examples. It can be varied in a wide range. Parts in formulations are parts by weight.
以下に農園芸用および水稲用の製剤処方を示す。 Formulations for agricultural and horticultural use and paddy rice are shown below.
(製剤1:水和剤)
本発明のアリールアゾール化合物40部、珪藻土53部、高級アルコール硫酸エステル4部、およびアルキルナフタレンスルホン酸塩3部を均一に混合して微細に粉砕して、有効成分40%の水和剤を得る。
(Formulation 1: wettable powder)
40 parts of the arylazole compound of the present invention, 53 parts of diatomaceous earth, 4 parts of higher alcohol sulfate and 3 parts of alkylnaphthalene sulfonate are uniformly mixed and finely pulverized to obtain a wettable powder containing 40% of the active ingredient. .
(製剤2:乳剤)
本発明のアリールアゾール化合物30部、キシレン33部、ジメチルホルムアミド30部、およびポリオキシエチレンアルキルアリルエーテル7部を混合溶解して、有効成分30%の乳剤を得る。
(Formulation 2: emulsion)
30 parts of the arylazole compound of the present invention, 33 parts of xylene, 30 parts of dimethylformamide and 7 parts of polyoxyethylene alkylallyl ether are mixed and dissolved to obtain an emulsion containing 30% active ingredient.
(製剤3:粒剤)
本発明のアリールアゾール化合物5部、タルク40部、クレー38部、ベントナイト10部、およびアルキル硫酸ソーダ7部を均一に混合して微細に粉砕後、直径0.5~1.0mmの粒状に造粒して有効成分5%の粒剤を得る。
(Formulation 3: granules)
5 parts of the arylazole compound of the present invention, 40 parts of talc, 38 parts of clay, 10 parts of bentonite, and 7 parts of sodium alkylsulfate are uniformly mixed and finely pulverized, and then formed into granules having a diameter of 0.5 to 1.0 mm. Granulate to obtain granules with 5% active ingredient.
(製剤4:粒剤)
本発明のアリールアゾール化合物5部、クレー73部、ベントナイト20部、ジオクチルスルホサクシネートナトリウム塩1部、およびリン酸カリウム1部をよく粉砕混合し、水を加えてよく練り合せた後、造粒乾燥して有効成分5%の粒剤を得る。
(Formulation 4: granules)
5 parts of the arylazole compound of the present invention, 73 parts of clay, 20 parts of bentonite, 1 part of dioctylsulfosuccinate sodium salt, and 1 part of potassium phosphate are thoroughly pulverized and mixed, water is added, and the mixture is kneaded well, and then granulated. Dry to obtain 5% active ingredient granules.
(製剤5:懸濁剤)
本発明のアリールアゾール化合物10部、ポリオキシエチレンアルキルアリルエーテル4部、ポリカルボン酸ナトリウム塩2部、グリセリン10部、キサンタンガム0.2部、および水73.8部を混合し、粒度が3ミクロン以下になるまで湿式粉砕し、有効成分10%の懸濁剤を得る。
(Formulation 5: suspension agent)
10 parts of the arylazole compound of the present invention, 4 parts of polyoxyethylene alkylallyl ether, 2 parts of polycarboxylic acid sodium salt, 10 parts of glycerin, 0.2 parts of xanthan gum, and 73.8 parts of water are mixed to obtain a particle size of 3 microns. Wet grind to obtain a 10% active ingredient suspension.
以下に外部寄生虫防除剤、または内部寄生虫防除もしくは駆除剤の製剤処方を示す。 Below are formulations of ectoparasite control agents or endoparasite control or extermination agents.
(製剤6:顆粒剤)
本発明のアリールアゾール化合物5部を有機溶媒中で溶解させて溶液を得、該溶液をカオリン94部およびホワイトカーボン1部の上に噴霧し、次いで溶媒を減圧下蒸発させる。この種の顆粒は動物の餌と混合できる。
(Formulation 6: granules)
Five parts of the arylazole compound of the present invention are dissolved in an organic solvent to obtain a solution, the solution is sprayed onto 94 parts of kaolin and 1 part of white carbon, and the solvent is then evaporated under reduced pressure. Granules of this kind can be mixed with animal feed.
(製剤7:注入剤)
本発明のアリールアゾール化合物0.1~1部とラッカセイ油99~99.9部を均一に混合し、次いで滅菌フィルターによりろ過滅菌する。
(Formulation 7: injection)
0.1 to 1 part of the arylazole compound of the present invention and 99 to 99.9 parts of peanut oil are uniformly mixed and then filtered and sterilized with a sterilizing filter.
(製剤8:ポアオン剤)
本発明のアリールアゾール化合物5部、ミリスチン酸エステル10部、およびイソプロパノール85部を均一に混合してポアオン剤を得る。
(Formulation 8: pour-on agent)
A pour-on agent is obtained by uniformly mixing 5 parts of the arylazole compound of the present invention, 10 parts of myristate ester, and 85 parts of isopropanol.
(製剤9:スポットオン剤)
本発明のアリールアゾール化合物10~15部、パルミチン酸エステル10部、およびイソプロパノール75~80部を均一に混合してスポットオン剤を得る。
(Formulation 9: spot-on agent)
A spot-on agent is obtained by uniformly mixing 10 to 15 parts of the arylazole compound of the present invention, 10 parts of palmitate and 75 to 80 parts of isopropanol.
(製剤10:スプレー剤)
本発明のアリールアゾール化合物1部、プロピレングリコール10部、およびイソプロパノール89部を均一に混合してスプレー剤を得る。
(Formulation 10: Spray)
1 part of the arylazole compound of the present invention, 10 parts of propylene glycol and 89 parts of isopropanol are uniformly mixed to obtain a spray.
次に、実施例を示し、本発明をより具体的に説明する。ただし、本発明は以下の実施例によって何ら制限されるものではない。 EXAMPLES Next, the present invention will be described more specifically by showing examples. However, the present invention is by no means limited by the following examples.
次に、実施例を示し、本発明をより具体的に説明する。ただし、本発明は以下の実施例によって何ら制限されるものではない。 EXAMPLES Next, the present invention will be described more specifically by showing Examples. However, the present invention is by no means limited by the following examples.
〔生物試験〕
本発明のアリールアゾール化合物が、有害生物防除剤の有効成分として有用であることを以下の試験例で示す。なお「部」は重量基準である。
[Biological test]
The following test examples demonstrate that the arylazole compound of the present invention is useful as an active ingredient of a pest control agent. "Parts" are by weight.
(試験用乳剤の調製)
本発明アリールアゾール化合物5部、ジメチルホルムアミド93.6部、およびポリオキシエチレンアルキルアリールエーテル1.4部を混合溶解し、有効成分5%の乳剤(I)を調製した。
対照のために、ジメチルホルムアミド93.6部、およびポリオキシエチレンアルキルアリールエーテル1.4部を混合溶解して乳剤(II)を調製した。
(Preparation of test emulsion)
5 parts of the arylazole compound of the present invention, 93.6 parts of dimethylformamide and 1.4 parts of polyoxyethylene alkylaryl ether were mixed and dissolved to prepare emulsion (I) containing 5% active ingredient.
For control, emulsion (II) was prepared by mixing and dissolving 93.6 parts of dimethylformamide and 1.4 parts of polyoxyethylene alkylaryl ether.
殺虫率および殺線虫率は、下記の式により計算した。
殺虫率(%) = (死亡虫数/供試虫数)×100
殺線虫率(%) = (死亡線虫数/供試線虫数)×100
The insecticidal rate and the nematicidal rate were calculated by the following formulas.
Insect kill rate (%) = (number of dead insects/number of test insects) x 100
Nematicidal rate (%) = (number of dead nematodes / number of test nematodes) × 100
(試験例1)アワヨトウに対する効力試験
市販の人工飼料(インセクタLFS、日本農産工業社製)0.8gと乳剤(I)1μlをよく混和して試験用飼料を得た。
試験用飼料をプラスチック製試験容器(1.4ml容)に、一処理区当り0.2gを詰めた。次いでアワヨトウ2齢幼虫を一処理区当り2頭接種した。プラスチック製の蓋を幼虫が逃げないように試験容器に載せた。それを25℃の恒温室内に置き、第5日目に殺虫率と摂食量を調べた。試験は2反復で行った。
(Test Example 1) Efficacy test for armyworm 0.8 g of a commercially available artificial feed (Insector LFS, manufactured by Nihon Nosan Kogyo Co., Ltd.) was thoroughly mixed with 1 μl of emulsion (I) to obtain a test feed.
A plastic test container (1.4 ml capacity) was filled with 0.2 g of test feed per treatment plot. Then, 2nd instar larvae of armyworm were inoculated to 2 animals per treatment group. A plastic lid was placed on the test container to prevent larvae from escaping. It was placed in a temperature-controlled room at 25° C., and the insecticidal rate and food intake were examined on the fifth day. The test was done in duplicate.
対照区として、乳剤(I)を乳剤(II)に変えた以外は試験例1と同じ方法で、殺虫率と摂食量を調べた。 As a control plot, the insecticidal rate and food intake were examined in the same manner as in Test Example 1, except that emulsion (I) was changed to emulsion (II).
化合物番号a-1、a-2、b-1、b-2、b-3、b-4、b-7、b-12、b-14、b-15、b-17、b-19、b-20、b-21、b-22、b-23、b-29、c-1、c-2、c-6、d-13、d-18、d-19、d-20、d-21、d-22、d-23、d-24、d-26およびd-28の化合物について、アワヨトウに対する効力試験を行った。いずれの化合物もアワヨトウに対して、殺虫率が100%または摂食量が対照区比で10%以下であった。本発明アリールアゾール化合物はアワヨトウに対して有効であることがわかる。 compound numbers a-1, a-2, b-1, b-2, b-3, b-4, b-7, b-12, b-14, b-15, b-17, b-19, b-20, b-21, b-22, b-23, b-29, c-1, c-2, c-6, d-13, d-18, d-19, d-20, d- Compounds 21, d-22, d-23, d-24, d-26 and d-28 were tested for efficacy against armyworm. All of the compounds had an insecticidal rate of 100% against armyworm and a food intake of 10% or less compared to the control group. It can be seen that the arylazole compounds of the present invention are effective against armyworm.
(試験例2)コナガに対する効力試験
乳剤(I)を、本発明化合物の濃度が125ppmになるように水で希釈した。キャベツ葉を前記希釈液中に30秒間浸漬した。このキャベツ葉をシャーレに入れた。これにコナガ2齢幼虫5頭を放した。シャーレを温度25℃、湿度60%の恒温室内に置いた。放虫から3日間経過したときに生死判定を行い、殺虫率を算出した。試験は2反復で行った。
(Test Example 2) Efficacy test against diamondback moth Emulsion (I) was diluted with water so that the concentration of the compound of the present invention was 125 ppm. Cabbage leaves were immersed in the diluted solution for 30 seconds. This cabbage leaf was placed in a Petri dish. Five diamondback moth 2nd instar larvae were released to this. The petri dish was placed in a constant temperature room with a temperature of 25° C. and a humidity of 60%. After 3 days from the release of insects, life and death judgment was performed, and the insecticidal rate was calculated. The test was done in duplicate.
化合物番号a-3、b-1、b-2、b-7、b-8、b-9、b-10、b-11、b-12、b-13、b-14、b-15、b-19、b-20、b-22、b-24、b-25、b-26、b-27、c-1、c-6、d-18、d-21、d-25、d-26、d-30、e-1およびe-2の化合物について、コナガに対する効力試験を行った。いずれの化合物もコナガに対して80%以上の殺虫率を示した。 Compound numbers a-3, b-1, b-2, b-7, b-8, b-9, b-10, b-11, b-12, b-13, b-14, b-15, b-19, b-20, b-22, b-24, b-25, b-26, b-27, c-1, c-6, d-18, d-21, d-25, d- Compounds 26, d-30, e-1 and e-2 were tested for efficacy against diamondback moth. All compounds exhibited an insecticidal rate of 80% or more against diamondback moth.
(試験例3)キスジノミハムシに対する効力試験
乳剤(I)を本発明化合物が125ppmとなるように水で希釈し、試験用薬液を調製した。3寸鉢に植えたチンゲンサイ苗(第7本葉展開期)に前記試験用薬液を散布した。チンゲンサイ苗を風乾させ、次いでプラスチックカップに入れた。これに、キスジノミハムシ(Phyllotreta striolata)成虫10頭を放した。温度25℃、湿度65%の恒温室内で保管し、放虫から7日後に生死判定を行い、殺虫率を算出した。試験は2反復で行った。
(Test Example 3) Efficacy test against Chrysanthemum flea beetle Emulsion (I) was diluted with water so that the concentration of the compound of the present invention was 125 ppm to prepare a test solution. The test solution was sprayed on bok choy seedlings (seventh true leaf development stage) planted in a 3-inch pot. The bok choy seedlings were allowed to air dry and then placed in plastic cups. To this, 10 adults of Phyllotreta striolata were released. The insects were stored in a temperature-controlled room at a temperature of 25°C and a humidity of 65%, and life and death were determined 7 days after release, and the insecticidal rate was calculated. The test was done in duplicate.
化合物番号a-1、b-2、b-5、b-7、b-8、b-9、b-13、b-21、b-22、b-24、e-1およびe-2の化合物について、キスジノミハムシ成虫に対する効力試験を行った。該化合物はキスジノミハムシ成虫に対して80%以上の殺虫率を示した。 of compound numbers a-1, b-2, b-5, b-7, b-8, b-9, b-13, b-21, b-22, b-24, e-1 and e-2 Compounds were tested for efficacy against adult leaf beetles. The compound showed an insecticidal rate of 80% or more against adult leaf beetles.
(試験例4)マメアブラムシに対する効力試験
3寸鉢でササゲを育苗し、初生葉上にマメアブラムシ若虫を接種した。乳剤(I)を本発明化合物が125ppmになるように水で希釈し、マメアブラムシ若虫が寄生するササゲに前記希釈液を散布した。該ササゲを温度25℃、湿度60%の恒温室内に置いた。散布から4日間経過したときにマメアブラムシの生死判定を行い、殺虫率を算出した。試験は2反復で行った。
(Test Example 4) Efficacy test against bean aphid Cowpea seedlings were raised in a 3-inch pot, and bean aphid nymphs were inoculated on the primary leaves. Emulsion (I) was diluted with water so that the concentration of the compound of the present invention was 125 ppm, and the diluted solution was sprayed on cowpeas infested with nymphs of the bean aphid. The cowpea was placed in a constant temperature room with a temperature of 25° C. and a humidity of 60%. After 4 days from spraying, the bean aphid was determined for life and death, and the insecticidal rate was calculated. The test was done in duplicate.
化合物番号a-1、a-2、b-2、b-3、b-4、b-6、b-7、b-12、b-14、b-16、b-17、b-18、b-20、b-21、b-22、b-23、c-1、c-6、d-2、d-21、d-24およびd-26の化合物について、マメアブラムシに対する効力試験を行った。当該化合物は、マメアブラムシに対して80%以上の殺虫率を示した。 compound numbers a-1, a-2, b-2, b-3, b-4, b-6, b-7, b-12, b-14, b-16, b-17, b-18, Compounds b-20, b-21, b-22, b-23, c-1, c-6, d-2, d-21, d-24 and d-26 were tested for efficacy against bean aphid. rice field. The compound showed an insecticidal rate of 80% or more against the bean aphid.
(試験例5)ワタアブラムシに対する効力試験
乳剤(I)を、本発明化合物の濃度が125ppmになるように水で希釈した。3寸鉢でキュウリを育苗し、第一本葉上にワタアブラムシ若虫を接種した。前記希釈液をキュウリ苗に散布した。該キュウリを温度25℃、湿度60%の恒温室内に置いた。散布から4日間経過したときにワタアブラムシの生死判定を行い、殺虫率を算出した。試験は2反復で行った。
(Test Example 5) Efficacy test against Aphis gossypii Emulsion (I) was diluted with water so that the concentration of the compound of the present invention was 125 ppm. A cucumber seedling was raised in a 3-inch pot, and aphid gossypii nymphs were inoculated on the first true leaf. The diluted solution was sprayed on cucumber seedlings. The cucumber was placed in a constant temperature room with a temperature of 25°C and a humidity of 60%. After 4 days from spraying, the aphid gossypii was determined for life and death, and the insecticidal rate was calculated. The test was done in duplicate.
化合物番号b-2、b-7、b-8、b-9、b-13、b-20、b-21、b-22、b-24、c-2およびd-30の化合物について、ワタアブラムシに対する効力試験を行った。いずれの化合物も殺虫率が80%以上であった。 For compounds with compound numbers b-2, b-7, b-8, b-9, b-13, b-20, b-21, b-22, b-24, c-2 and d-30, cotton An efficacy test against aphids was performed. All compounds had an insecticidal rate of 80% or more.
本発明のアリールアゾール化合物の中から無作為に選択したものが、いずれも上記のような効果を奏することから、本発明の縮合複素環化合物は、例示しきれなかった化合物を含め、有害生物防除、特に殺ダニ、殺虫などの効果を有する化合物であることが理解できる。また、外部寄生虫などの人畜に害のある寄生虫にも効果を有する化合物であることが理解できる。 Since all of the arylazole compounds selected at random from the arylazole compounds of the present invention exhibit the above effects, the condensed heterocyclic compounds of the present invention, including compounds that could not be exemplified, can be used to control pests. , in particular, compounds having effects such as acaricidal and insecticidal effects. In addition, it can be understood that the compound is effective against parasites such as ectoparasites that are harmful to humans and animals.
本発明のアリールアゾール化合物は、有害生物防除活性、その中でも特に殺虫活性、殺ダニ活性および/または殺線虫活性に優れ、安全性に優れ、且つ工業的に有利に合成できる。
本発明の有害生物防除剤は、農作物に対して有害な生物または衛生面で問題となる有害生物を防除することができる。本発明の有害生物防除剤は、低い濃度であっても、農業害虫を防除する効果に優れる。
INDUSTRIAL APPLICABILITY The arylazole compound of the present invention has excellent pesticidal activity, particularly insecticidal activity, acaricidal activity and/or nematicidal activity, is excellent in safety, and can be industrially advantageously synthesized.
The pest control agent of the present invention can control organisms that are harmful to agricultural crops or pests that pose a problem in terms of hygiene. The pest control agent of the present invention is highly effective in controlling agricultural pests even at low concentrations.
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