JP2022124400A - Oil-in-water emulsion oil-and-fat composition for chou dough - Google Patents

Oil-in-water emulsion oil-and-fat composition for chou dough Download PDF

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JP2022124400A
JP2022124400A JP2021022145A JP2021022145A JP2022124400A JP 2022124400 A JP2022124400 A JP 2022124400A JP 2021022145 A JP2021022145 A JP 2021022145A JP 2021022145 A JP2021022145 A JP 2021022145A JP 2022124400 A JP2022124400 A JP 2022124400A
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和彦 近藤
Kazuhiko Kondo
哲太郎 友枝
Tetsutaro Tomoe
健太 大石
Kenta Oishi
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Adeka Corp
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Abstract

To provide an oil composition for chou dough that gives a chou case, which really melts in the mouth, can be easily bitten off, and has a good flavor, as well as is excellent in volume and shape retention.SOLUTION: An oil-in-water emulsion oil-and-fat composition for chou dough has an oil phase with SFC of 55-100% at 10°C, 30-100% at 20°C, and 15% or less at 40°C. Preferably it contains milk raw material, the solid of which contains phospholipids of 2 mass% or more. Preferably it also contains total milk protein and/or milk protein concentrate.SELECTED DRAWING: None

Description

本発明はシュー生地用水中油型乳化油脂組成物に関する。 TECHNICAL FIELD The present invention relates to an oil-in-water emulsified fat composition for puff pastry.

シューケース(シュー皮)を製造するためのシュー生地は、シュー用マーガリンなどの油脂類を水とともに加熱煮沸して熱水と溶解した油脂の混合物とし、この中に小麦粉などの澱粉類を添加して捏和して十分に糊化状態にした後、液卵などの卵成分をミキシングしながら数回に分けて加えて十分に乳化することにより得ることができるが、使用する油脂類の選択によって、得られるシューケースの体積や風味や食感が大きく異なることが知られている。シューケースの焼成には従来、バターかラードが使用されてきたが、これらには以下の長所と短所がある。 The choux pastry for manufacturing the choux case (choux skin) is made by heating and boiling oils and fats such as margarine for choux with water to make a mixture of hot water and dissolved oils and fats, and adding starches such as wheat flour to this mixture. After kneading to a sufficiently gelatinized state, it can be obtained by adding egg ingredients such as liquid eggs in several portions while mixing and emulsifying sufficiently, but depending on the selection of oils and fats to be used It is known that the volume, flavor and texture of the resulting shoe case are greatly different from each other. Traditionally, butter or lard has been used to bake shoe cases, but they have the following advantages and disadvantages.

即ち、バターは、風味と口溶けは良好だが、シューケースの皮が厚くなり、焼き伸びがやや悪いとされ、ラードは、口溶けと体積は良好であるが、特有の風味を有し、風味劣化が起こりやすいとされている。 In other words, butter has a good flavor and melts in the mouth, but the skin of the shoe case becomes thicker and the baking spread is a little poorer. considered to be likely to occur.

ここで、液状油を用いると、ソフトな食感で口溶けは良好となり、焼成時の生地の伸展性も良好であるが保型性が劣るためつぶれて体積が出なくなる。また、融点の高い油脂、例えば牛脂を使用すると、体積は出るもののワキシーな食感となり口溶けが著しく悪化してしまうという問題があった(例えば非特許文献1参照)。 Here, when liquid oil is used, the texture is soft and melts well in the mouth, and the spreadability of the dough during baking is good, but the shape retention is poor and the dough collapses and loses volume. In addition, when fats and oils with a high melting point, such as beef tallow, are used, there is a problem that although the volume increases, the texture becomes waxy and the meltability in the mouth is significantly deteriorated (see, for example, Non-Patent Document 1).

このように、バター、ラード、液状油、牛脂等の天然の油脂を使用すると、体積の大きなシューケースを安定して製造することはできなかった。
体積の大きなシューケースを安定して生産するためには、シュー生地を製造する際に小麦粉等の澱粉類を十分に糊化させ、その生地に十分な伸展性があることが必要である。このため、油脂、乳化剤、カゼインのナトリウム塩の3種成分を使用するのが有効であり、これらの3種成分を含む油中水型のシュー用油脂が広く使用されている。
As described above, when using natural oils such as butter, lard, liquid oil, beef tallow, etc., it has not been possible to stably produce shoe cases having a large volume.
In order to stably produce a shoe case with a large volume, it is necessary to sufficiently gelatinize starches such as wheat flour when producing the shoe dough and to have sufficient extensibility of the dough. Therefore, it is effective to use three components of oil, emulsifier, and casein sodium salt, and water-in-oil type shoe oil containing these three components is widely used.

しかし、最近では、乳化剤や、カゼインのナトリウム塩に起因する風味が問題になりつつあり、また、最近の食品添加物の使用を控える風潮からもこれらの乳化剤やカゼインのナトリウム塩の使用量を減じた場合、或いは使用しない場合であっても、体積の大きなシューケースを安定して製造することのできるシュー生地用油脂が求められるようになってきた。 However, recently, the flavor caused by emulsifiers and casein sodium salts has become a problem, and due to the recent trend of refraining from using food additives, the amount of these emulsifiers and casein sodium salts used has been reduced. A demand has arisen for an oil and fat for puff pastry that can stably produce a shoe case with a large volume even when it is used or when it is not used.

ここで、単に、乳化剤を使用しないでシューケースを製造するには、ラードやバター等の、乳化剤を含有しない油脂類を使用すればよいが、上述のように、体積の大きなシューケースを安定して得ることはできない。 Here, in order to simply manufacture a shoe case without using an emulsifier, fats and oils that do not contain an emulsifier, such as lard and butter, may be used. you can't get it.

一方、カゼインのナトリウム塩を使用せずとも大きな体積のシューケースを得る方法としては、水相のpHが5.2~5.9であるシュー皮用乳化油脂組成物を使用する方法(例えば特許文献1参照)や、ホエイ蛋白質:カゼイン蛋白質の質量比率が3:7~5:5である乳蛋白質を固形分換算で0.5~4.5質量%含有することを特徴とするシュー用乳化油脂組成物を使用する方法(例えば特許文献2参照)、更には、油相中に、SOS(S:炭素数16~22である飽和脂肪酸残基、O:オレイン酸残基)で表わされるトリアシルグリセロールを60質量%以上含有する油脂を、10~100質量%含有することを特徴とするシュー用油脂組成物を使用する方法(例えば特許文献3参照)、特定の油脂と特定の乳成分を含有するシュー用油脂(特許文献4参照)、特定の乳成分の酸処理品を使用する方法(特許文献5参照)が提案されている。 On the other hand, as a method of obtaining a shoe case of large volume without using the sodium salt of casein, there is a method of using an emulsified oil and fat composition for shoe skin whose aqueous phase has a pH of 5.2 to 5.9 (for example, patent Reference 1), and a puff emulsifier characterized by containing 0.5 to 4.5% by mass of milk protein with a mass ratio of whey protein: casein protein of 3:7 to 5:5 in terms of solid content. A method using an oil-fat composition (see, for example, Patent Document 2), and furthermore, in the oil phase, S L OS L (S L : saturated fatty acid residue having 16 to 22 carbon atoms, O: oleic acid residue) A method of using an oil-and-fat composition for shoes, characterized by containing 10 to 100% by mass of oil containing 60% by mass or more of triacylglycerol represented by (see Patent Document 4), and a method of using an acid-treated product of a specific milk component (see Patent Document 5).

しかし、特許文献1~3に記載された方法で得られたシューケースは十分な体積が得られないという問題があった。また、特許文献4に記載された方法で得られたシューケースは口溶けの点でやや問題があった。また、特許文献5記載の方法は歯切れの点でやや問題があった。
このように、乳化剤やカゼインのナトリウム塩の使用量を減じた場合、或いは使用しない場合であっても体積が大きく、保型性が良好で、口溶けと歯切れが良好であるシューケースを製造することができるシュー生地用油脂組成物が求められていた。
However, there is a problem that the shoe cases obtained by the methods described in Patent Documents 1 to 3 do not have a sufficient volume. In addition, the shoe case obtained by the method described in Patent Document 4 has a problem of melting in the mouth. Moreover, the method described in Patent Document 5 has a problem in terms of crispness.
Thus, a shoe case having a large volume, good shape retention, good meltability in the mouth and good crispness can be produced even when the amount of emulsifier or casein sodium salt used is reduced or not used. There has been a demand for an oil and fat composition for choux pastry that can

特開平06-165632号公報JP-A-06-165632 特開2001-224308号公報Japanese Patent Application Laid-Open No. 2001-224308 特開2004-267165号公報JP 2004-267165 A 特開2008-295414号公報JP 2008-295414 A 特開2017-212898号公報JP 2017-212898 A

したがって、本発明の目的は、口溶け、歯切れ及び風味が良好で、かつ、体積及び保型性が良好なシューケースを得ることが可能であるシュー生地用油脂組成物を提供することにある。 Accordingly, an object of the present invention is to provide an oil-and-fat composition for puff pastry which is meltable in the mouth, has good crispness and good flavor, and which is capable of producing a shoe case with good volume and shape retention.

本発明者等は、上記目的を達成すべく種々検討した結果、シュー生地製造に使用する油脂類について、通常使用される油中水型乳化物の形態ではなく、水中油型乳化物の形態として使用し、該水中油型乳化物の油相を特定のSFCとすることで上記課題を達成可能であることを見出した。 As a result of various studies to achieve the above object, the present inventors have found that the oils and fats used in the production of puff pastry are not in the form of water-in-oil emulsions that are commonly used, but in the form of oil-in-water emulsions. It was found that the above object can be achieved by using a specific SFC as the oil phase of the oil-in-water emulsion.

本発明は、上記知見により得られたものであり、油相のSFCが10℃で55~100%、20℃で30~100%、40℃で15%以下である、シュー生地用水中油型乳化油脂組成物を提供するものである。 The present invention was obtained based on the above findings, and the SFC of the oil phase is 55 to 100% at 10 ° C., 30 to 100% at 20 ° C., and 15% or less at 40 ° C. Oil-in-water emulsification for puff pastry A fat composition is provided.

また本発明は、シュー生地用水中油型乳化油脂組成物を含有するシュー生地及び当該シュー生地を焼成したシュー製品を提供するものである。 The present invention also provides a puff pastry containing an oil-in-water emulsified fat composition for puff pastry and a puff product obtained by baking the puff pastry.

本発明のシュー生地用水中油型乳化油脂組成物及びシュー生地を使用することにより、口溶け、歯切れ及び風味が良好で、かつ、体積及び保型性が良好なシューケースを得ることができる。また本発明のシュー生地用水中油型乳化油脂組成物及びシュー生地を使用して得られたシューケースは、口溶け、歯切れ及び風味が良好で、かつ、体積及び保型性が良好である。 By using the oil-in-water emulsified oil composition for puff pastry and the puff pastry of the present invention, it is possible to obtain a shoe case with good meltability in the mouth, good crispness and flavor, and good volume and shape retention. In addition, the shoe case obtained by using the oil-in-water emulsified oil composition for puff pastry and the puff pastry of the present invention has good meltability in the mouth, good crispness and flavor, and also good volume and shape retention.

以下、本発明のシュー生地用水中油型乳化油脂組成物について詳述する。
本発明のシュー生地用水中油型乳化油脂組成物は、油相のSFC(固体脂含量)が10℃で55~100%、20℃で30~100%、40℃で15%以下であることが必要であるが、好ましくは10℃で55~90%、20℃で30~75%、40℃で5%以下であり、より好ましくは10℃で55~80、20℃で30~45%、40℃で4%以下である。
Hereinafter, the oil-in-water emulsified fat composition for choux pastry of the present invention will be described in detail.
In the oil-in-water emulsified fat composition for puff pastry of the present invention, the SFC (solid fat content) of the oil phase is 55 to 100% at 10°C, 30 to 100% at 20°C, and 15% or less at 40°C. Although necessary, it is preferably 55 to 90% at 10°C, 30 to 75% at 20°C, and 5% or less at 40°C, more preferably 55 to 80% at 10°C, and 30 to 45% at 20°C. It is 4% or less at 40°C.

油相のSFCが10℃で55%未満、または20℃で30%未満の場合、得られるシューケースの体積が小さくなることに加え、歯切れが悪化する。40℃で15%を超える場合はシューケースの口溶けが悪化する。
なお、水相中に2種以上の油相を含む場合は、そのすべての油相を合一させてSFCを測定するものとする。
If the SFC of the oil phase is less than 55% at 10°C or less than 30% at 20°C, the volume of the resulting shoe case will be small and the crispness will deteriorate. If it exceeds 15% at 40°C, the shoe case melts in the mouth.
When the aqueous phase contains two or more oil phases, the SFC shall be measured by combining all the oil phases.

尚、上記SFCは、次のようにして測定する。即ち、先ず、油相を60℃に30分保持して完全に融解した後、0℃に30分保持して固化させる。次いで、25℃に30分保持し、テンパリングを行い、その後、0℃に30分保持する。これをSFCの各測定温度(10℃、15℃、20℃、25℃、30℃、35℃、40℃及び60℃)に順次30分保持後、SFCを測定する。 The SFC is measured as follows. That is, first, the oil phase is held at 60° C. for 30 minutes to melt completely, and then held at 0° C. for 30 minutes to solidify. Then, it is held at 25° C. for 30 minutes for tempering, and then held at 0° C. for 30 minutes. The SFC is measured after successively maintaining this at each measurement temperature for SFC (10°C, 15°C, 20°C, 25°C, 30°C, 35°C, 40°C and 60°C) for 30 minutes.

ここで、上記SFCとするために使用する油脂としては特に限定されないが、例えば、パーム核油、ヤシ油、ババス油、パーム油、米油、コーン油、綿実油、大豆油、ナタネ油(キャノーラ油)、ハイエルシンナタネ油、ヒマワリ油、サフラワー油、ハイオレイックヒマワリ油、ハイオレイックサフラワー油、牛脂、乳脂、豚脂、カカオ脂、魚油、鯨油、等の各種植物油脂、動物油脂並びにこれらを水素添加、分別及びエステル交換から選択される一又は二以上の処理を施した加工油脂が挙げられる。本発明においては、これらの油脂を単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。 Here, the oils and fats used to make the SFC are not particularly limited, but examples include palm kernel oil, coconut oil, babassu oil, palm oil, rice oil, corn oil, cottonseed oil, soybean oil, rapeseed oil (canola oil ), high el cinnamon oil, sunflower oil, safflower oil, high oleic sunflower oil, high oleic safflower oil, beef tallow, milk fat, lard, cacao butter, fish oil, whale oil, various vegetable oils, animal oils and fats Processed oils and fats obtained by subjecting these to one or more treatments selected from hydrogenation, fractionation and transesterification are exemplified. In the present invention, these fats and oils can be used alone, or two or more of them can be used in combination.

なかでも本発明では、特に風味が良好で、体積が大きく、口溶け及び歯切れが良好なシューケースが得られる点で、パーム核油、ヤシ油、ババス油などのラウリン系油脂、並びにこれらを水素添加、分別及びエステル交換から選択される一又は二以上の処理を施した加工油脂を使用することが好ましい。
また、上記ラウリン系油脂を使用する場合、ラウリン系油脂に必要に応じその他の油脂を添加した油脂配合物のエステル交換油脂の形で使用することも可能である。エステル交換油脂の形で使用することにより、保型性を良好なものとすることができる。
風味が良好で、体積が大きく、口溶け及び歯切れが良好なシューケースが一層得やすい点でラウリン系油脂を使用する場合、油脂組成物の油相中の構成脂肪酸組成における炭素数14以下の飽和脂肪酸含量が10~85質量%とすることが好ましく、より好ましくは25~80質量%であることが好ましい。
Among them, in the present invention, lauric oils and fats such as palm kernel oil, coconut oil, babassu oil, and hydrogenation of these are used in that a shoe case having a particularly good flavor, a large volume, and good melting and crispness in the mouth can be obtained. It is preferable to use a processed fat that has been subjected to one or more treatments selected from , fractionation and transesterification.
When using the laurin-based fat, it is also possible to use it in the form of an ester-exchanged fat blended with other fats and oils added to the laurin-based fat, if necessary. By using it in the form of transesterified oil, it is possible to improve shape retention.
In the case of using a lauric oil, a saturated fatty acid having 14 or less carbon atoms in the fatty acid composition in the oil phase of the oil-fat composition The content is preferably 10 to 85% by mass, more preferably 25 to 80% by mass.

なお本発明のシュー生地用水中油型乳化油脂組成物では、融点が50℃を超える油脂、とくに極度硬化油脂は、得られるシューケースの口溶けが悪化しやすい点で含有しないことが好ましい。なお、エステル交換油脂の製造に使用する分には問題ない。なお、本発明のシュー生地用水中油型乳化油脂組成物に極度硬化油が含まれる場合、その量は、使用する全油脂中2質量%以下であることが好ましく、0.9質量%以下であることがより好ましい。 The oil-in-water emulsified fat composition for shoe dough of the present invention preferably does not contain fats and oils having a melting point of more than 50° C., particularly extremely hardened fats and oils, because the meltability of the resulting shoe case tends to deteriorate. In addition, there is no problem in the amount used for producing transesterified fats and oils. In addition, when the oil-in-water emulsified fat composition for puff pastry of the present invention contains extremely hardened oil, the amount thereof is preferably 2% by mass or less, and 0.9% by mass or less in the total fat and oil used. is more preferable.

なお、本発明のシュー生地用水中油型乳化油脂組成物の油相の融点は22~50℃であることが好ましく、より好ましくは24~45℃である。
油相の融点を22℃以上とすることによりシューケースの体積及び保型性を良好なものとすることができ、油相の融点を50℃以下とすることにより、口溶けの悪化を防止することが可能となる。
なお、本明細書において油相の融点とは上昇融点であり、日本油化学会制定の基準油脂分析試験法に記載の方法により測定することができる。
The melting point of the oil phase of the oil-in-water emulsified oil composition for puff pastry of the present invention is preferably 22 to 50°C, more preferably 24 to 45°C.
By setting the melting point of the oil phase to 22°C or higher, the volume and shape retention of the shoe case can be improved, and by setting the melting point of the oil phase to 50°C or lower, deterioration of melting in the mouth can be prevented. becomes possible.
In the present specification, the melting point of the oil phase is an elevated melting point, which can be measured by the method described in the Standard Fats and Oils Analysis Test Method established by the Japan Oil Chemists' Society.

本発明のシュー生地用水中油型乳化油脂組成物は、エステル交換油脂を含有する場合、シューケースの保型性向上等の利点があるが、エステル交換油脂を含有していなくてもよい。エステル交換油脂を含有する場合、その量としては、油相中例えば20質量%以上が挙げられる。エステル交換油脂を用いる場合、その融点としては、本発明の特定のSFCを有する油脂を得やすい点等から、22~50℃であることが好ましく、より好ましくは24~45℃であることが更に好ましい。 When the oil-in-water emulsified oil composition for puff pastry of the present invention contains an interesterified oil, it has the advantage of improving the shape retention of the shoe case. When transesterified fats and oils are contained, the amount thereof is, for example, 20% by mass or more in the oil phase. When the transesterified fat is used, its melting point is preferably 22 to 50° C., more preferably 24 to 45° C., because it is easy to obtain the fat having the specific SFC of the present invention. preferable.

また、本発明のシュー生地用水中油型乳化油脂組成物における油脂分含量は20~65質量%であることが好ましく、より好ましくは30~50質量%である。油脂分含量が20質量%以上であると、シュー生地の製造時にシュー生地用水中油型乳化油脂組成物の添加量が多くせずに済み、本発明の効果が得易い。また、65%以下であることで、シュー生地用水中油型乳化油脂組成物の製造時における増粘を抑制し、乳化安定性の悪化に起因して安定的な生産や保管・配送が困難となってしまうおそれを防止できる。 The oil-in-water emulsified fat composition for puff pastry of the present invention preferably has a fat content of 20 to 65% by mass, more preferably 30 to 50% by mass. When the fat and oil content is 20% by mass or more, the addition amount of the oil-in-water emulsified oil composition for puff pastry does not need to be increased during the production of the puff pastry, and the effect of the present invention can be easily obtained. In addition, if it is 65% or less, thickening during production of the oil-in-water emulsified oil composition for puff pastry is suppressed, and stable production, storage and delivery become difficult due to deterioration of emulsion stability. You can prevent the risk of being lost.

なお、上記油脂分含量には、下記の乳由来の固形分中のリン脂質の含有量が2質量%以上である乳原料及び下記のその他の成分に含まれる油脂分も含むものとする。 In addition, the fat and oil content includes the fat and oil contained in the milk raw material having a phospholipid content of 2% by mass or more in the milk-derived solids described below and the other ingredients described below.

また、本発明のシュー生地用水中油型乳化油脂組成物における水分含量は30~78質量%であることが好ましく、より好ましくは45~68質量%である。
なお、上記水分含量には、下記のその他の成分に含まれる水分も含むものとする。
The water content in the oil-in-water emulsified fat composition for choux pastry of the present invention is preferably 30 to 78% by mass, more preferably 45 to 68% by mass.
In addition, the water content mentioned above includes the water contained in the following other components.

また、本発明のシュー生地用水中油型乳化油脂組成物では、より良好な風味を有し、且つ、乳化剤やカゼインのナトリウム塩の使用量を減じても乳化安定性が良好なシュー生地用水中油型乳化油脂組成物を得ることが可能な点、及び、得られるシューケースの歯切れが向上する点から、乳由来の固形分中のリン脂質の含有量が2質量%以上である乳原料を使用することが好ましい。 In addition, the oil-in-water emulsified oil composition for puff pastry of the present invention has a better flavor and exhibits good emulsion stability even when the amount of emulsifier and casein sodium salt used is reduced. A dairy raw material having a phospholipid content of 2% by mass or more in the milk-derived solid content is used because it is possible to obtain an emulsified oil and fat composition and the crispness of the resulting shoe case is improved. is preferred.

上記乳原料としては、乳由来の固形分中のリン脂質の含有量が、該固形分を基準として、3質量%以上である乳原料を使用することが好ましく、更に好ましくは4質量%以上、最も好ましくは5~40質量%である乳原料を使用する。
上記乳由来の固形分中のリン脂質とは、乳由来の固形分中に含まれる乳由来のリン脂質のことを指す。
As the dairy raw material, it is preferable to use a dairy raw material in which the content of phospholipids in the milk-derived solid content is 3% by mass or more, more preferably 4% by mass or more, based on the solid content. Most preferably 5-40% by weight of dairy raw material is used.
The phospholipids in the milk-derived solids refer to milk-derived phospholipids contained in the milk-derived solids.

また、上記乳原料は、液体状でも、粉末状でも、濃縮物でも構わない。但し、溶剤を用いて乳由来の固形分中のリン脂質の含有量が2質量%以上となるように濃縮した乳原料は、風味上の問題から、本発明においては、上記乳原料として用いないのが好ましい。 Moreover, the dairy raw material may be liquid, powder, or concentrate. However, a dairy raw material that has been concentrated using a solvent so that the phospholipid content in the milk-derived solid content is 2% by mass or more is not used as the dairy raw material in the present invention due to flavor problems. is preferred.

尚、上記乳原料の起源となる乳としては、牛乳、ヤギ乳、ヒツジ乳、人乳等の乳を例示することができるが、特に牛乳が好ましい。
乳由来のリン脂質を含有する乳原料の固形分中のリン脂質の定量方法としては、例えば下記の定量方法が挙げられる。但し、抽出方法等については乳原料の形態等によって適正な方法が異なるため、下記の定量方法に限定されるものではない。
先ず、乳由来のリン脂質を含有する乳原料の脂質をFolch法により抽出する。次いで、抽出した脂質溶液を湿式分解法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載の湿式分解法に準じる)にて分解した後、モリブデンブルー吸光度法(日本薬学会編、衛生試験法・注解2000 2.1食品成分試験法に記載のリンのモリブデン酸による定量に準じる)によりリン量を求める。求められたリン量から、以下の計算式を用いて、乳由来のリン脂質を含有する乳原料の固形分100g中のリン脂質の含有量(g)を求める。
Examples of the milk that is the source of the above milk raw material include milk such as cow's milk, goat's milk, sheep's milk and human's milk, with cow's milk being particularly preferred.
Methods for quantifying the phospholipids in the solid content of the milk raw material containing phospholipids derived from milk include, for example, the following quantification methods. However, the extraction method and the like are not limited to the following quantification method, since the appropriate method differs depending on the form of the milk raw material and the like.
First, lipids of milk raw materials containing milk-derived phospholipids are extracted by the Folch method. Next, after decomposing the extracted lipid solution by a wet decomposition method (according to the wet decomposition method described in the Pharmaceutical Society of Japan, Sanitary Test Method and Commentary 2000 2.1 Food Component Test Method), molybdenum blue absorbance method (Japan The amount of phosphorus is determined according to the determination of phosphorus using molybdic acid described in 2.1 Food Component Test Methods, edited by the Pharmaceutical Society of Japan, Sanitary Test Methods and Commentary 2000. From the calculated amount of phosphorus, the content (g) of phospholipids in 100 g of the solid content of the milk-derived phospholipid-containing milk raw material is calculated using the following formula.

リン脂質(g/100g)=〔リン量(μg)/(乳由来のリン脂質を含有する乳原料-乳由来のリン脂質を含有する乳原料の水分(g))〕×25.4×(0.1/1000)
上記乳由来の固形分中のリン脂質の含有量が該固形分を基準として2質量%以上である乳原料としては、例えば、クリーム又はバターからバターオイルを製造する際に生じる水相成分が挙げられる。該クリーム又はバターからバターオイルを製造する際に生じる水相成分は、通常のクリームからバターを製造する際に生じるいわゆるバターミルクとは組成が大きく異なり、リン脂質を多量に含有しているという特徴がある。バターミルクは、その製法の違いによって大きく異なるが、乳由来の固形分中のリン脂質の含有量が、通常0.5~1.5質量%程度であるのに対して、上記クリーム又はバターからバターオイルを製造する際に生じる水相成分は、乳由来の固形分中のリン脂質の含有量が、おおよそ2~15質量%であり、多量のリン脂質を含有している。
Phospholipid (g / 100 g) = [Phosphorus amount (μg) / (dairy raw material containing milk-derived phospholipid - water content (g) of milk raw material containing milk-derived phospholipid)] × 25.4 × ( 0.1/1000)
Examples of the dairy raw material in which the phospholipid content in the milk-derived solid content is 2% by mass or more based on the solid content include, for example, the aqueous phase component generated when butter oil is produced from cream or butter. be done. The water phase component produced when butter oil is produced from the cream or butter has a composition that is greatly different from that of so-called buttermilk produced when butter is produced from ordinary cream, and is characterized in that it contains a large amount of phospholipids. There is Buttermilk varies greatly depending on the manufacturing method, but the content of phospholipids in the milk-derived solids is usually about 0.5 to 1.5% by mass, whereas the cream or butter contains The aqueous phase component produced when butter oil is produced contains a large amount of phospholipids, with a phospholipid content of approximately 2 to 15% by mass in the milk-derived solids.

本発明において、上記乳由来の固形分中のリン脂質の含有量が2質量%以上である乳原料として、通常のクリームからバターを製造する際に生じるいわゆるバターミルクそのものを用いることはできないが、バターミルクを乳由来の固形分中のリン脂質の含有量が2質量%以上となるように濃縮した濃縮物、或いはその乾燥物を用いることは可能である。 In the present invention, the so-called buttermilk itself, which is produced when producing butter from ordinary cream, cannot be used as the dairy raw material having a phospholipid content of 2% by mass or more in the milk-derived solids. It is possible to use a concentrate obtained by concentrating buttermilk so that the phospholipid content in the milk-derived solid content is 2% by mass or more, or a dried product thereof.

上記クリーム又はバターからバターオイルを製造する際に生じる水相成分の製造方法の一例を以下に説明する。
上記クリームからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。
An example of a method for producing an aqueous phase component produced when butter oil is produced from the above cream or butter will be described below.
The method for producing the aqueous phase component produced when butter oil is produced from the cream is, for example, as follows.

先ず、牛乳を遠心分離して得られる脂肪濃度30~40質量%のクリームをプレートで加温し、遠心分離機によってクリームの脂肪濃度を70~95質量%まで高める。次いで、乳化破壊機で乳化を破壊し、再び遠心分離機で処理することによってバターオイルが得られる。本発明で用いることができる上記水相成分は、最後の遠心分離の工程でバターオイルの副産物として発生するものである。
一方、上記バターからバターオイルを製造する際に生じる水相成分の製造方法は、例えば以下の通りである。
First, cream with a fat concentration of 30-40% by mass obtained by centrifuging milk is heated on a plate, and the fat concentration of the cream is increased to 70-95% by mass by a centrifuge. Then, the emulsification is broken with an emulsifying machine, and the butter oil is obtained by treating with a centrifugal separator again. The aqueous phase component that can be used in the present invention is generated as a by-product of butter oil in the final centrifugation step.
On the other hand, the method for producing the aqueous phase component produced when butter oil is produced from the butter is, for example, as follows.

先ず、バターを溶解機で溶解し、熱交換機で加温する。これを遠心分離機で分離することによってバターオイルが得られる。本発明で用いることができる上記水相成分は、遠心分離の工程でバターオイルの副産物として発生するものである。該バターオイルの製造に用いられるバターとしては、通常のものが用いられる。
本発明で用いることができる上記水相成分としては、乳由来の固形分中のリン脂質の含有量が該固形分を基準として2質量%以上であれば、上記クリーム又はバターからバターオイルを製造する際に生じる水相成分をそのまま用いてもよく、また、噴霧乾燥、濃縮、冷凍等の処理を施したものを用いてもよい。
First, butter is melted with a melter and heated with a heat exchanger. Butter oil is obtained by separating this with a centrifuge. The aqueous phase component that can be used in the present invention is generated as a by-product of butter oil in the centrifugation process. Ordinary butter is used as the butter used for producing the butter oil.
As the aqueous phase component that can be used in the present invention, if the content of phospholipids in the milk-derived solid content is 2% by mass or more based on the solid content, butter oil is produced from the cream or butter. The aqueous phase component generated when the water phase is used may be used as it is, or may be used after being subjected to a treatment such as spray drying, concentration, or freezing.

但し、乳由来のリン脂質は、高温加熱するとその機能が低下するため、上記加温処理や上記濃縮処理中或いは殺菌等により加熱する際の温度は、100℃未満であることが好ましい。 However, since milk-derived phospholipids lose their function when heated to a high temperature, the temperature during the above-mentioned heating treatment, the above-mentioned concentration treatment, or when heating by sterilization or the like is preferably less than 100°C.

また、本発明では、上記の乳原料中のリン脂質の一部又は全部がリゾ化されたリゾ化物を使用することもできる。該リゾ化物は、乳原料をそのままリゾ化したものであっても良く、また乳原料を濃縮した後にリゾ化したものであってもよい。また、得られたリゾ化物に、更に濃縮或いは噴霧乾燥処理等を施してもよい。これらのリゾ化物は本発明におけるリン脂質の含有量に含めるものとする。 In addition, in the present invention, a lyso-formed product obtained by lyso-forming a part or all of the phospholipids in the dairy raw material can also be used. The lyso compound may be a milk raw material directly lyso-formed, or may be lyso-formed after concentrating the milk raw material. Further, the obtained lyso compound may be further subjected to concentration or spray drying treatment. These lysates are included in the content of phospholipids in the present invention.

上記の乳原料中のリン脂質をリゾ化するには、ホスホリパーゼAで処理すればよい。ホスホリパーゼAは、リン脂質分子のグリセロール部分と脂肪酸残基とを結びつけている結合を切断し、この脂肪酸残基を水酸基で置換する作用を有する酵素である。ホスホリパーゼAは、作用する部位の違いによってホスホリパーゼA1とホスホリパーゼA2とに分かれるが、ホスホリパーゼA2が好ましい。ホスホリパーゼA2の場合、リン脂質分子のグリセロール部分の2位の脂肪酸残基が選択的に切り離される。 Phospholipase A treatment may be used to lysolyze the phospholipids in the above milk raw materials. Phospholipase A is an enzyme that cleaves the bond connecting the glycerol portion of a phospholipid molecule and a fatty acid residue and replaces the fatty acid residue with a hydroxyl group. Phospholipase A is divided into phospholipase A1 and phospholipase A2 depending on the site of action, and phospholipase A2 is preferred. In the case of phospholipase A2, the fatty acid residue at position 2 of the glycerol portion of the phospholipid molecule is selectively cleaved off.

また、本発明では、上記の乳原料の添加効果を更に向上させることができる点で、好ましくはpHが3~6、より好ましくはpH4~6、更に好ましくは4.7~5.8となるように酸処理を行ったものであることが好ましい。
上記酸処理を行うには、酸を添加する方法であっても、また、乳酸醗酵等の醗酵処理を行う方法であってもよいが、好ましくは酸を添加する。該酸としては、無機酸であっても有機酸であってもよいが、有機酸であることが好ましい。該有機酸としては、酢酸、乳酸、クエン酸、グルコン酸、フィチン酸、ソルビン酸、アジピン酸、コハク酸、酒石酸、フマル酸、リンゴ酸、アスコルビン酸等が挙げられ、果汁、濃縮果汁、発酵乳、ヨーグルト等の有機酸を含有する飲食品も用いることができるが、本発明においてはより酸味が少なく、風味に影響しない点でフィチン酸及び/又はグルコン酸を使用することが好ましい。
Further, in the present invention, the pH is preferably 3 to 6, more preferably 4 to 6, and still more preferably 4.7 to 5.8, in that the effect of adding the milk raw material can be further improved. It is preferable that the acid treatment is performed as described above.
The acid treatment may be carried out by adding an acid or by performing a fermentation treatment such as lactic acid fermentation. Preferably, an acid is added. The acid may be an inorganic acid or an organic acid, but is preferably an organic acid. Examples of the organic acid include acetic acid, lactic acid, citric acid, gluconic acid, phytic acid, sorbic acid, adipic acid, succinic acid, tartaric acid, fumaric acid, malic acid, ascorbic acid, fruit juice, concentrated fruit juice, and fermented milk. Although foods and drinks containing organic acids such as yoghurt can also be used, it is preferable to use phytic acid and/or gluconic acid in the present invention because they are less sour and do not affect the flavor.

上記酸の添加によるpHの調整は、上記酸を上記乳原料自体に添加することにより行ってもよいし、シュー生地用水中油型乳化油脂組成物の製造時に上記酸を添加することにより行ってもよい。
また、本発明では、上記の乳原料に、リン脂質含有量1質量部あたり、好ましくは0.01~1質量部、より好ましくは0.02~0.5質量部、更に好ましくは0.05~0.3質量部のカルシウム塩を添加してもよい。
The pH adjustment by adding the acid may be performed by adding the acid to the milk raw material itself, or may be performed by adding the acid during the production of the oil-in-water emulsified oil composition for puff pastry. good.
Further, in the present invention, preferably 0.01 to 1 part by mass, more preferably 0.02 to 0.5 part by mass, and even more preferably 0.05 part by mass per 1 part by mass of phospholipid content in the above milk raw material ˜0.3 parts by weight of calcium salt may be added.

上記カルシウム塩としては塩化カルシウム、乳酸カルシウム、リン酸カルシウム、グルコン酸カルシウム、クエン酸カルシウム、炭酸カルシウム、グルタミン酸カルシウム、アスコルビン酸カルシウム等が例示され、このうち1種又は2種以上を組み合わせて用いることができるが、本発明においては得られるシュー生地用水中油型乳化油脂組成物の風味を損ねず、またシュー生地の物性に影響のない点で塩化カルシウム及び/又は乳酸カルシウムを使用することが好ましい。 Examples of the calcium salt include calcium chloride, calcium lactate, calcium phosphate, calcium gluconate, calcium citrate, calcium carbonate, calcium glutamate, calcium ascorbate, and the like, and one or more of these may be used in combination. However, in the present invention, it is preferable to use calcium chloride and/or calcium lactate in that it does not impair the flavor of the obtained oil-in-water emulsified oil composition for puff pastry and does not affect the physical properties of the puff pastry.

また、本発明で用いる上記の乳原料は、シュー生地用水中油型乳化油脂組成物を製造する際に、水相やシュー生地用水中油型乳化油脂組成物への分散性を高めることが可能である点、及び得られるシュー生地用水中油型乳化油脂組成物の乳化安定性をより高めることができる点で、均質化処理を行なったものであることが好ましい。特に上記リゾ化処理、酸処理、カルシウム塩添加を行なう場合は、その効果を高めるために均質化処理を行なうことが特に好ましい。均質化処理は1回でもよく、2回以上行ってもよい。また、粘性が高い等の場合は、加水により粘度を調整してから均質化処理を行なってもよい。 In addition, the above-described dairy raw material used in the present invention can improve the dispersibility in the aqueous phase and the oil-in-water emulsified oil composition for puff pastry when producing the oil-in-water emulsified oil composition for puff pastry. It is preferable that the homogenization treatment is performed in that the emulsification stability of the obtained oil-in-water emulsified oil composition for puff pastry can be further improved. In particular, when performing the lyso treatment, acid treatment, and calcium salt addition, it is particularly preferable to perform a homogenization treatment in order to enhance the effects thereof. The homogenization treatment may be performed once or twice or more. Moreover, when the viscosity is high, the homogenization treatment may be performed after adjusting the viscosity by adding water.

上記均質化処理に用いられる均質化機としては、例えば、ケトル型チーズ乳化釜、ステファンミキサーの様な高速せん断乳化釜、スタティックミキサー、インラインミキサー、バブル式ホモジナイザー、ホモミキサー、コロイドミル、ディスパーミル等が挙げられる。均質化圧力は特に制限はないが、好ましくは0~100MPaである。2段式ホモジナイザーを用いて均質化処理をする場合は、例えば、1段目3~100MPa、2段目0~5MPaの均質化圧力にて行ってもよい。 Homogenizers used for the homogenization include, for example, a kettle-type cheese emulsifying vessel, a high-speed shearing emulsifying vessel such as a Stephan mixer, a static mixer, an in-line mixer, a bubble-type homogenizer, a homomixer, a colloid mill, a disper mill, and the like. is mentioned. Although the homogenization pressure is not particularly limited, it is preferably 0 to 100 MPa. When the homogenization treatment is performed using a two-stage homogenizer, the homogenization pressure may be, for example, 3 to 100 MPa in the first stage and 0 to 5 MPa in the second stage.

更に本発明で用いる上記の乳原料は、UHT加熱処理を行ってもよい。UHT加熱処理の条件としては特に制限はないが、処理温度は好ましくは120~150℃であり、処理時間は好ましくは1~6秒である。
このようにして得られる本発明で用いる上記の乳原料や乳原料加工品は、液状、ペースト状、粉末状、固形状等の状態のものとすることができ、本発明のシュー生地用水中油型乳化油脂組成物では、何れの状態のものでも使用できるが、上記乳原料や乳原料加工品は、液状又はペースト状のものを使用することが、本発明の効果が安定して得られる点で好ましい。
Further, the above milk raw material used in the present invention may be subjected to UHT heat treatment. Conditions for the UHT heat treatment are not particularly limited, but the treatment temperature is preferably 120 to 150° C., and the treatment time is preferably 1 to 6 seconds.
The above milk raw material and processed milk raw material used in the present invention thus obtained can be in the state of liquid, paste, powder, solid, etc. The emulsified oil and fat composition can be used in any state, but it is preferable to use a liquid or a paste as the dairy raw material or the processed dairy raw material, since the effects of the present invention can be stably obtained. preferable.

本発明のシュー生地用水中油型乳化油脂組成物では、上記乳由来の固形分中のリン脂質の含有量が該固形分を基準として2質量%以上である乳原料を、固形分として、好ましくは0.1~8質量%、更に好ましくは0.5~7質量%、最も好ましくは0.5~4質量%含有する。 In the oil-in-water emulsified oil-and-fat composition for puff pastry of the present invention, a milk raw material having a phospholipid content of 2% by mass or more based on the solid content of the milk-derived solid content is preferably 0.1 to 8 mass %, more preferably 0.5 to 7 mass %, most preferably 0.5 to 4 mass %.

本発明のシュー生地用水中油型乳化油脂組成物は、カゼインのナトリウム塩を含有せずとも体積の大きなシューケースが得られること、及び、良好な風味のシューケースを得ることが可能であることから、トータルミルクプロテイン及び/又はミルクプロテインコンセントレートを含有することが好ましい。トータルミルクプロテイン及び/又はミルクプロテインコンセントレートとは、カゼイン蛋白質、ホエイ蛋白質の両方を含有する乳由来の蛋白質であり、牛乳中に含まれる蛋白質を限外濾過技術により濃縮・噴霧乾燥することなどにより得られる。
本発明のシュー生地用水中油型乳化油脂組成物における、トータルミルクプロテイン及び/又はミルクプロテインコンセントレートの含有量は合計して1~5質量%、より好ましくは1~3質量%である。
The oil-in-water emulsified oil composition for puff pastry of the present invention can provide a shoe case with a large volume without containing a sodium salt of casein, and a shoe case with a good flavor. , total milk protein and/or milk protein concentrate. Total milk protein and/or milk protein concentrate are proteins derived from milk that contain both casein protein and whey protein. can get.
The total content of total milk protein and/or milk protein concentrate in the oil-in-water emulsified fat composition for choux pastry of the present invention is 1 to 5% by mass, more preferably 1 to 3% by mass.

本発明のシュー生地用水中油型乳化油脂組成物は、本発明の効果を阻害しない範囲において、必要に応じ、油脂、水、乳由来の固形分中のリン脂質の含有量が2質量%以上である乳原料、トータルミルクプロテイン及びミルクプロテインコンセントレート以外のその他の成分(以下、単に「その他の成分」ともいう。)を含有していてもよい。その他の成分としては、乳化剤、安定剤、増粘安定剤、上記以外の乳及び乳製品、糖類及び甘味料、果汁、ジャム、カカオ及びカカオ製品、コーヒー及びコーヒー製品等の呈味成分、調味料、食塩、酸味料、着香料、着色料、保存料、酸化防止剤、pH調整剤等が挙げられる。その他の成分の配合量は、本発明の効果を阻害しない範囲において、通常の使用量の範囲で使用することができる。 The oil-in-water emulsified fat composition for puff pastry of the present invention has a phospholipid content of 2% by mass or more in the solid content derived from fats, water, and milk, as long as the effects of the present invention are not impaired. It may contain ingredients other than certain dairy ingredients, total milk protein and milk protein concentrate (hereinafter also simply referred to as "other ingredients"). Other ingredients include emulsifiers, stabilizers, thickening stabilizers, milk and dairy products other than the above, sugars and sweeteners, fruit juices, jams, cacao and cacao products, flavoring ingredients such as coffee and coffee products, and seasonings. , salt, acidulants, flavoring agents, coloring agents, preservatives, antioxidants, pH adjusters and the like. The amount of other ingredients to be blended can be used within the range of normal usage amounts as long as the effects of the present invention are not impaired.

上記その他の成分としての乳化剤(以下、単に「上記乳化剤」とも記載する。)としては、特に限定されないが、例えば、レシチン、グリセリン脂肪酸エステル、グリセリン酢酸脂肪酸エステル、グリセリン乳酸脂肪酸エステル、グリセリンコハク酸脂肪酸エステル、グリセリンジアセチル酒石酸脂肪酸エステル、ソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ショ糖酢酸イソ酪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタンモノグリセリド等が挙げられる。これらの乳化剤は単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。
本発明における上記乳化剤の含有量は、好ましくは0.001~5質量%、より好ましくは0.01~1質量%である。尚、上記乳由来の固形分中のリン脂質の含有量が2質量%以上である乳原料を使用する場合は、上記乳化剤の含量を減じることができ、その場合の上記乳化剤の好ましい含有量は0~1質量%、より好ましくは0~0.5質量%、最も好ましくは上記乳化剤を使用しないことが好ましい。
The emulsifier (hereinafter also simply referred to as "the emulsifier") as the other component is not particularly limited, but for example, lecithin, glycerin fatty acid ester, glycerin acetic acid fatty acid ester, glycerin lactic acid ester, glycerin succinic acid fatty acid Ester, glycerin diacetyl tartaric acid ester, sorbitan fatty acid ester, sucrose fatty acid ester, sucrose acetate isobutyric acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, calcium stearoyl lactylate, sodium stearoyl lactylate, poly oxyethylene sorbitan monoglyceride and the like. These emulsifiers can be used alone or in combination of two or more.
The content of the emulsifier in the invention is preferably 0.001 to 5% by mass, more preferably 0.01 to 1% by mass. In addition, when using a dairy raw material having a phospholipid content of 2% by mass or more in the milk-derived solid content, the content of the emulsifier can be reduced, and in that case, the preferred content of the emulsifier is 0 to 1% by weight, more preferably 0 to 0.5% by weight, most preferably no emulsifier is used.

上記安定剤としては、リン酸塩(ヘキサメタリン酸、第2リン酸、第1リン酸)、クエン酸のアルカリ金属塩(カリウム、ナトリウム等)等が挙げられる。これらの安定剤は、単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。 Examples of the stabilizer include phosphates (hexametaphosphate, secondary phosphoric acid, primary phosphoric acid), alkali metal salts of citric acid (potassium, sodium, etc.), and the like. These stabilizers can be used alone or in combination of two or more.

上記増粘安定剤としては、キサンタンガム、グアーガム、アラビアガム、プルラン、タマリンドシードガム、サイリウムシードガム、カラギーナン、アルギン酸塩、ファーセルラン、ローカストビーンガム、ペクチン、カードラン、澱粉、化工澱粉、結晶セルロース、カルボキシメチルセルロース、メチルセルロース、ゼラチン、デキストリン、寒天、デキストラン、白キクラゲ多糖等が挙げられる。これらの増粘安定剤は、単独で用いることもでき、又は2種以上を組み合わせて用いることもできる。 Examples of the thickening stabilizer include xanthan gum, guar gum, gum arabic, pullulan, tamarind seed gum, psyllium seed gum, carrageenan, alginate, farcellulan, locust bean gum, pectin, curdlan, starch, modified starch, and crystalline cellulose. , carboxymethylcellulose, methylcellulose, gelatin, dextrin, agar, dextran, white fungus polysaccharide, and the like. These thickening stabilizers can be used alone or in combination of two or more.

本発明のシュー生地用水中油型乳化油脂組成物は、通常のシュー用油脂と異なり、水中油型の乳化型であることが特徴である。水相を含まないショートニングや液状油、流動ショートニング、あるいは水相を含むマーガリンやファットスプレッドなどの油中水型や油中水中油型の乳化形態であると、本発明の効果は得られない。
なお、本発明において、水中油型乳化物には、水中油中水型などの多重乳化型を含むものとする。
The oil-in-water emulsified fat composition for puff pastry of the present invention is characterized in that it is an oil-in-water emulsified fat composition, unlike ordinary fats for puffs. The effects of the present invention cannot be obtained with water-in-oil or oil-in-oil-in-oil emulsified forms such as shortening, liquid oil, liquid shortening, or margarine or fat spread containing an aqueous phase.
In the present invention, the oil-in-water emulsion includes multiple emulsions such as the water-in-oil-in-water emulsion.

以下に、本発明のシュー生地用水中油型乳化油脂組成物の製造方法を説明する。
本発明のシュー生地用水中油型乳化油脂組成物は、その製造方法が特に制限されるものではないが、例えば以下の方法により製造することができる。
先ず、油脂及び必要によりその他の原料を含有させた油相と、水及び必要によりその他の原料を含有させた水相とをそれぞれ個別に調製し、次いで、該油相と該水相とを混合乳化し、水中油型に乳化することにより、本発明のシュー生地用水中油型乳化油脂組成物が得られる。
The method for producing the oil-in-water emulsified fat composition for choux pastry of the present invention is described below.
The oil-in-water emulsified fat composition for puff pastry of the present invention is not particularly limited in its production method, but can be produced, for example, by the following method.
First, an oil phase containing fats and oils and optionally other raw materials and an aqueous phase containing water and optionally other raw materials are separately prepared, and then the oil phase and the aqueous phase are mixed. By emulsifying and emulsifying into an oil-in-water type, the oil-in-water type emulsified fat composition for puff pastry of the present invention is obtained.

この際、乳由来の固形分中のリン脂質の含有量が2質量%以上である乳原料、トータルミルクプロテイン及び/又はミルクプロテインコンセントレートをはじめとする水溶性成分は水相に、油溶性成分は油相に含有させるのが基本であるが、水相への溶解性が乏しくだまになりやすい場合など、水溶性成分を油相に添加してもよい。 At this time, water-soluble components such as milk raw materials, total milk protein and / or milk protein concentrate having a phospholipid content of 2% by mass or more in the milk-derived solids are added to the aqueous phase, oil-soluble components is basically contained in the oil phase, but if the solubility in the water phase is poor and the substance tends to clump, a water-soluble component may be added to the oil phase.

得られた水中油型乳化油脂組成物は、必要により、バルブ式ホモジナイザー、ホモミキサー、コロイドミル等の均質化装置により、圧力0~100MPaの範囲で均質化してもよい。また、必要によりインジェクション式、インフージョン式等の直接加熱方式、プレート式、チューブラー式、掻き取り式等の間接加熱方式を用いたUHT・HTST・低温殺菌、バッチ式、レトルト、マイクロ波加熱等の加熱滅菌又は加熱殺菌処理を施してもよく、直火等の加熱調理により加熱してもよい。さらに、加熱後に必要に応じて再度均質化してもよく、必要により急速冷却、徐冷却等の冷却操作を施してもよい。 The resulting oil-in-water emulsified fat composition may be homogenized at a pressure in the range of 0 to 100 MPa with a homogenizer such as a valve homogenizer, a homomixer, or a colloid mill, if necessary. In addition, UHT, HTST, pasteurization, batch type, retort, microwave heating, etc., using direct heating methods such as injection and infusion methods, and indirect heating methods such as plate, tubular, and scraping methods, if necessary. may be subjected to heat sterilization or heat sterilization treatment, or may be heated by heat cooking such as direct fire. Further, after heating, the mixture may be homogenized again as necessary, and cooling operation such as rapid cooling or slow cooling may be performed as necessary.

上記本発明のシュー生地用水中油型乳化油脂組成物は、シュー生地の製造用に使用するものである。すなわち、澱粉類、油脂類、卵成分及び水を主要原料とし、澱粉の糊化作用を利用して得られる従来のシュー生地において、油脂類の一部または全部を本発明のシュー生地用水中油型乳化油脂組成物を使用するものである。 The oil-in-water emulsified fat composition for puff pastry of the present invention is used for producing puff pastry. That is, in the conventional choux pastry obtained by using starch, fats, eggs, and water as main raw materials and utilizing the gelatinization action of starch, part or all of the fats are replaced with the oil-in-water type choux pastry of the present invention. An emulsified fat composition is used.

本発明のシュー生地用水中油型乳化油脂組成物の添加量はシュー生地の種類や、シュー生地用水中油型乳化油脂組成物の油脂分含量によって適宜選択可能であるが、シュー生地中に、好ましくは10~70質量%、より好ましくは25~65質量%、さらに好ましくは35~55質量%である。 The amount of the oil-in-water emulsified oil composition for puff pastry of the present invention to be added can be appropriately selected according to the type of puff pastry and the oil content of the oil-in-water emulsified oil composition for puff pastry. 10 to 70% by mass, more preferably 25 to 65% by mass, still more preferably 35 to 55% by mass.

また、本発明のシュー生地用水中油型乳化油脂組成物の添加量はシュー生地に使用する澱粉類100質量部に対し、シュー生地用水中油型乳化油脂組成物由来の油脂分として好ましくは33~160質量部、より好ましくは41~160質量部、さらに好ましくは54~150質量部、最も好ましくは85~130質量部となる量であることが好ましい。 Further, the amount of the oil-in-water emulsified oil composition for puff pastry of the present invention to be added is preferably 33 to 160 as the fat content derived from the oil-in-water emulsified oil composition for puff pastry per 100 parts by mass of the starch used in the puff pastry. Parts by weight, more preferably 41 to 160 parts by weight, still more preferably 54 to 150 parts by weight, most preferably 85 to 130 parts by weight.

上記澱粉類としては、例えば、強力粉、準強力粉、中力粉、薄力粉、デュラム粉、全粒粉等の小麦粉類、ライ麦粉、大麦粉、米粉、とうもろこし粉、大麦粉、粟粉等のその他の穀粉類、アーモンド粉、へーゼルナッツ粉、カシュ―ナッツ粉、オーナッツ粉、松実粉等の堅果粉、コーンスターチ、タピオカ澱粉、小麦澱粉、甘藷澱粉、サゴ澱粉、米澱粉等の澱粉や、これらに対しアミラーゼ等の酵素で処理したものや、α化処理、分解処理、エーテル化処理、エステル化処理、架橋処理、グラフト化処理等の中から選ばれた1種又は2種以上の処理を施した化工澱粉等が挙げられる。
本発明のシュー生地では、澱粉類中、好ましくは小麦粉類を50質量%以上、より好ましくは70質量%以上、更に好ましくは100質量%使用する。
Examples of the starches include, for example, flours such as strong flour, semi-strong flour, all-purpose flour, weak flour, durum flour, and whole wheat flour, and other cereal flours such as rye flour, barley flour, rice flour, corn flour, barley flour, and millet flour. , almond flour, hazelnut flour, cashew nut flour, oat flour, pine nut flour, etc., corn starch, tapioca starch, wheat starch, sweet potato starch, sago starch, rice starch, etc., and amylase, etc. for these , or modified starch that has been subjected to one or more treatments selected from pregelatinization treatment, decomposition treatment, etherification treatment, esterification treatment, cross-linking treatment, grafting treatment, etc. is mentioned.
The choux pastry of the present invention preferably contains 50% by mass or more, more preferably 70% by mass or more, and even more preferably 100% by mass of wheat flour among starches.

また、本発明のシュー生地用水中油型乳化油脂組成物の添加量は、当該水中油型乳化油脂組成物の油脂分が、シュー生地に含まれる油脂分の、好ましくは25~95質量%、より好ましくは33~95質量%、さらに好ましくは54~90質量%、最も好ましくは75~90質量%となる量であることが好ましい。なお、上記シュー生地に含まれる油脂分とは、本発明のシュー生地用水中油型乳化油脂組成物及び上記澱粉類をはじめ、卵成分など、下記のその他の原材料に含まれる油脂分をも含めた含有量である。 In addition, the amount of the oil-in-water emulsified oil composition for puff dough of the present invention to be added is preferably 25 to 95% by mass of the oil content of the oil-in-water emulsified oil composition contained in the puff dough, The amount is preferably 33 to 95% by mass, more preferably 54 to 90% by mass, and most preferably 75 to 90% by mass. The oil and fat contained in the choux pastry includes the oil-in-water emulsified oil and fat composition for choux pastry of the present invention and the above-mentioned starches, as well as the oil and fat contained in the following other raw materials such as egg components. content.

なお、上記シュー生地に使用する上記油脂類として、本発明のシュー生地用水中油型乳化油脂組成物に加え、通常のシュー生地製造時に使用する油中水型乳化型のシュー用マーガリン、水相を含まないショートニング、ラード、ヘット、流動ショートニング等の水中油型の乳化形態以外の油脂類を併用することも可能であるが、その際は、油脂類の油脂分の、好ましくは30質量%以上、より好ましくは60質量%以上、さらに好ましくは80質量%以上、最も好ましくは100%が水中油型乳化油脂組成物由来であることが好ましい。 In addition to the oil-in-water emulsified oil composition for choux pastry of the present invention, the oils and fats used in the choux pastry include a water-in-oil emulsified choux margarine used in the production of ordinary choux pastry, and an aqueous phase. It is also possible to use oils and fats other than oil-in-water emulsified forms such as shortening, lard, hett, and liquid shortening that do not contain, but in that case, the fat content of the oils and fats is preferably 30% by mass or more, More preferably 60% by mass or more, still more preferably 80% by mass or more, and most preferably 100% is derived from the oil-in-water emulsified fat composition.

次に、本発明のシュー生地について述べる。
本発明のシュー生地は、上記のシュー生地用水中油型乳化油脂組成物を使用したシュー生地であり、詳しくは上記シュー生地用水中油型乳化油脂組成物を練込んでなるものである。
なお、シュー生地における、上記本発明のシュー生地用水中油型乳化油脂組成物の好ましい添加量は上述のとおりである。その他、シュー生地用水中油型乳化油脂組成物について上記で述べた説明はすべて本発明のシュー生地及び本発明のシュー製品の説明に適用できる。また、後述するシュー生地及びシュー製品の説明はすべて上記のシュー生地用水中油型乳化油脂組成物の説明に適用できる。
Next, the choux pastry of the present invention will be described.
The choux pastry of the present invention is a choux pastry using the oil-in-water emulsified oil composition for choux pastry, and more specifically, it is obtained by kneading the oil-in-water emulsified oil composition for choux pastry.
The preferred amount of the oil-in-water emulsified oil composition for choux pastry of the present invention to be added to the choux pastry is as described above. In addition, all the explanations given above regarding the oil-in-water emulsified fat composition for puff pastry are applicable to the explanation of the puff pastry of the present invention and the puff product of the present invention. Further, all the explanations of the choux pastry and choux products described later can be applied to the above explanation of the oil-in-water emulsified fat composition for choux pastry.

本発明のシュー生地としては、上記本発明のシュー生地用水中油型乳化油脂組成物を使用する以外は従来の一般的なシュー生地と同様、澱粉類、油脂類、卵成分及び水を主要原料とし、澱粉の糊化作用を利用して得られる従来のシュー生地に使用する原材料を、特に制限なく用いることができる。 The puff pastry of the present invention is made mainly of starches, oils, egg components and water in the same manner as conventional general puff pastry except that the oil-in-water emulsified oil composition for puff pastry of the present invention is used. , the raw materials used for conventional choux pastry obtained by utilizing the gelatinization action of starch can be used without particular limitation.

上記シュー生地で使用する卵成分としては、全卵、卵黄、卵白、加塩全卵、加塩卵黄、加塩卵白、加糖全卵、加糖卵黄、加糖卵白、乾燥全卵、乾燥卵白、乾燥卵黄、凍結全卵、凍結卵黄、凍結卵白、凍結加糖全卵、凍結加糖卵黄、凍結加糖卵白、酵素処理全卵、酵素処理卵黄等を用いることができ、これらの中から選ばれた1種又は2種以上を用いることができる。 Egg ingredients used in the above puff pastry include whole egg, egg yolk, egg white, salted whole egg, salted egg yolk, salted egg white, sweetened whole egg, sweetened egg yolk, sweetened egg white, dried whole egg, dried egg white, dried egg yolk, frozen whole egg Eggs, frozen egg yolks, frozen egg whites, frozen sweetened whole eggs, frozen sweetened egg yolks, frozen sweetened egg whites, enzyme-treated whole eggs, enzyme-treated egg yolks, etc. can be used, and one or more selected from these can be used. can be used.

なお、上記シュー生地中の水は、その一部又は全部を、下記の任意の原材料に記載の例えば、牛乳、果汁等の、水を多く含む食品や食品素材で置換しても良い。
なお、上記本発明のシュー生地用水中油型乳化油脂組成物に含まれる水のみで十分である場合は、別途水を添加する必要はない。
Some or all of the water in the choux pastry may be replaced with foods or food materials containing a large amount of water, such as milk and fruit juice, described in the optional raw materials below.
When the water contained in the oil-in-water emulsified oil composition for puff pastry of the present invention is sufficient, it is not necessary to add additional water.

また、上記シュー生地には、本発明の目的の範囲内で所望により上記澱粉類、油脂類、卵成分及び水以外の任意の原材料を配合することができる。上記のシュー生地に使用できる上記成分以外の原材料としては、例えば、上白糖・グラニュー糖・粉糖・液糖・ブドウ糖・果糖・ショ糖・麦芽糖・乳糖・酵素糖化水飴・還元澱粉糖化物・異性化液糖・ショ糖結合水飴・オリゴ糖・還元糖ポリデキストロース・還元乳糖・ソルビトール・トレハロース・キシロース・キシリトール・マルチトール・エリスリトール・マンニトール・フラクトオリゴ糖・大豆オリゴ糖・ガラクトオリゴ糖・乳果オリゴ糖・ラフィノース・ラクチュロース・パラチノースオリゴ糖等の糖類、牛乳・クリーム・部分脱脂乳・脱脂乳・発酵乳・乳酸菌飲料・乳飲料・加工乳・チーズ・濃縮ホエイ・濃縮乳・脱脂濃縮乳・無糖練乳・無糖脱脂練乳・加糖練乳・加糖脱脂練乳・全粉乳・脱脂粉乳・クリームパウダー・ホエイパウダー・蛋白質濃縮ホエイパウダー・バターミルクパウダー・加糖粉乳・調製粉乳等の乳や乳製品、岩塩・精製塩・天塩等の食塩、カゼインカルシウム・カゼインナトリウム・カゼインカリウム等の乳蛋白、アミラーゼ・プロテアーゼ・アミログルコシダーゼ・プルラナーゼ・ペントサナーゼ・セルラーゼ・ヘミセルラーゼ・リパーゼ・ホスフォリパーゼ・カタラーゼ・リポキシゲナーゼ・アスコルビン酸オキシダーゼ・スルフィドリルオキシダーゼ・ヘキソースオキシダーゼ・グルコースオキシダーゼ等の酵素、グリセリン脂肪酸エステル・ポリグリセリン脂肪酸エステル・グリセリン有機酸脂肪酸エステル・レシチン・ショ糖脂肪酸エステル・ステアロイル乳酸カルシウム等の乳化剤、重炭酸アンモニウム・重曹・バーキングパウダー・イスパタ等の膨張剤、アスコルビン酸・シスチン等の酸化剤や還元剤、トコフェロール・茶抽出物・アスコルビン酸脂肪酸エステル等の酸化防止剤、β―カロチン・カラメル・紅麹色素等の着色料類、酢酸・乳酸・グルコン酸等の酸味料、塩化カリウム等の呈味剤、調味料、pH調整剤、食品保存料、日持ち向上剤、果実、果汁、コーヒー、紅茶、緑茶、ウーロン茶、プアール茶、日向夏茶、柚子茶、ナッツペースト、香辛料、カカオマス、ココアパウダー、コーヒー、紅茶、デキストリン類、野菜類・肉類・酒類・魚介類等の食品素材、着香料等が挙げられる。 In addition, the choux pastry may optionally contain any raw materials other than the starches, fats, eggs, and water within the scope of the present invention. Raw materials other than the above ingredients that can be used for the above choux pastry include, for example, white sugar, granulated sugar, powdered sugar, liquid sugar, glucose, fructose, sucrose, maltose, lactose, enzyme-saccharified starch syrup, reduced starch saccharified product, isomer Liquid sugar, sucrose-bound starch syrup, oligosaccharide, reduced sugar polydextrose, reduced lactose, sorbitol, trehalose, xylose, xylitol, maltitol, erythritol, mannitol, fructo-oligosaccharide, soybean oligosaccharide, galacto-oligosaccharide, milk oligosaccharide, Sugars such as raffinose, lactulose, and palatinose oligosaccharides, milk, cream, partially skimmed milk, skimmed milk, fermented milk, lactic acid beverages, milk drinks, processed milk, cheese, concentrated whey, concentrated milk, concentrated skimmed milk, sugar-free condensed milk, Sugar-free condensed milk, sweetened condensed milk, sweetened condensed skim milk, whole milk powder, skimmed milk powder, cream powder, whey powder, protein-concentrated whey powder, buttermilk powder, sweetened milk powder, modified milk powder, milk and dairy products, rock salt, refined salt, Salt such as Teshio, milk proteins such as calcium caseinate, sodium caseinate, potassium caseinate, amylase, protease, amyloglucosidase, pullulanase, pentosanase, cellulase, hemicellulase, lipase, phospholipase, catalase, lipoxygenase, ascorbic acid oxidase, sulfhydryl Enzymes such as oxidase, hexose oxidase, glucose oxidase, emulsifiers such as glycerin fatty acid ester, polyglycerin fatty acid ester, glycerin organic acid fatty acid ester, lecithin, sucrose fatty acid ester, calcium stearoyl lactylate, ammonium bicarbonate, baking soda, baking powder, Bulking agents such as Ispata, oxidizing agents and reducing agents such as ascorbic acid and cystine, antioxidants such as tocopherol, tea extract, ascorbic acid fatty acid ester, coloring agents such as β-carotene, caramel, monascus pigment, acetic acid・Acidulants such as lactic acid and gluconic acid, flavoring agents such as potassium chloride, seasonings, pH adjusters, food preservatives, shelf life improvers, fruit, fruit juice, coffee, black tea, green tea, oolong tea, puer tea, Hyuganatsu Examples include tea, yuzu tea, nut paste, spices, cacao mass, cocoa powder, coffee, black tea, dextrins, food materials such as vegetables, meats, alcoholic beverages, seafood, and flavoring agents.

次に、本発明のシュー生地の好ましい製造方法について述べる。
本発明のシュー生地は、本発明のシュー生地用水中油型乳化油脂組成物を使用する以外は、一般のシュー生地の製造方法に準じて行えばよく、例えば以下のようにして製造することができる。
本発明のシュー生地用水中油型乳化油脂組成物に、必要に応じ水及び/又は該水中油型乳化油脂組成物以外の油脂類を添加し加熱煮沸し、ここに小麦粉等の澱粉類を添加して捏和し、一般のシューケースと同様にシューケースを形成するに適した十分な糊化状態にした後、液卵をミキシングしながら数回に分けて加えて十分に乳化し、必要に応じ更に液卵で硬さを調整してシュー生地を得る。該液卵としては、膨張剤を溶解した液卵を使用してもよい。尚、必要に応じ、前述した乳化剤、糖類及び糖アルコール、澱粉類、無機塩、有機酸塩、ゲル化剤、乳や乳製品、卵製品、カカオ及びカカオ製品、コーヒー及びコーヒー製品、その他各種食品素材全般、着香料、調味料等の呈味成分、着色料、保存料、pH調整剤等を、加熱煮沸時或いは液卵の乳化時に添加、混合する。
Next, a preferred method for producing the choux pastry of the present invention will be described.
The puff pastry of the present invention may be produced according to a general method for producing puff pastry, except that the oil-in-water emulsified oil composition for puff pastry of the present invention is used. For example, it can be produced as follows. .
Water and/or oils other than the oil-in-water emulsified oil composition are added to the oil-in-water emulsified oil-fat composition for puff pastry of the present invention, if necessary, and the mixture is heated and boiled, and starch such as wheat flour is added thereto. After kneading to a sufficiently gelatinized state suitable for forming a shoe case like a general shoe case, add the liquid egg in several portions while mixing to fully emulsify, and if necessary Further, the hardness is adjusted with a liquid egg to obtain choux pastry. As the liquid egg, a liquid egg in which a swelling agent is dissolved may be used. If necessary, the above emulsifiers, sugars and sugar alcohols, starches, inorganic salts, organic acid salts, gelling agents, milk and dairy products, egg products, cacao and cacao products, coffee and coffee products, and other various foods Materials in general, taste components such as flavors and seasonings, coloring agents, preservatives, pH adjusters, etc. are added and mixed during heating and boiling or during emulsification of the liquid egg.

また、シュー生地は、生地の状態で、或いは絞って玉にした状態で冷凍することも可能である。シュー生地を冷凍する場合は、-30℃~-45℃の急速冷凍庫を使用し、急速冷凍を行うことが好ましい。
なお、糊化澱粉を使用するインスタントシューの場合は、シュー生地原料を混合するのみでよい。
The choux pastry can also be frozen in the form of dough or squeezed into balls. When freezing the puff pastry, it is preferable to use a quick freezer at -30°C to -45°C for quick freezing.
In the case of instant choux using gelatinized starch, it is only necessary to mix choux pastry raw materials.

次に、本発明のシュー製品について述べる。
本発明のシュー製品は、本発明のシュー生地を焼成してなるものである。シュー製品はシューケースであることが好ましい。
本発明のシュー製品がシューケースである場合は、特に、口溶け、歯切れ及び風味が良好で、かつ、体積及び保型性が良好であるという特徴を有する。
尚、シュー生地を焼成する際は、通常、天板或いはコンベア上に積置するが、焼型に入れて焼成してもよい。焼成する際の温度は、通常のシューケース同様、好ましくは160℃~250℃、より好ましくは170℃~220℃である。焼成温度が160℃未満であると火どおりが悪く、焼成時間が延びてしまうことに加え、窯落ちが発生するおそれがある。また焼成温度が250℃を超えると、シューケースが焦げついてしまい、外観が悪化することに加え体積も劣ったものとなってしまうおそれがある。尚、焼成時に蓋をかぶせる等の方法で蒸気圧を高めた状態で焼成することで、更に体積の大きなシューケースとすることも可能である。
Next, the shoe product of the present invention will be described.
The choux product of the present invention is obtained by baking the choux pastry of the present invention. Preferably, the shoe product is a shoe case.
When the shoe product of the present invention is a shoe case, it is particularly characterized by good meltability in the mouth, good crispness and flavor, and good volume and shape retention.
When baking the choux pastry, it is usually stacked on a top plate or a conveyor, but it may be baked in a baking mold. The firing temperature is preferably 160° C. to 250° C., more preferably 170° C. to 220° C., similarly to a normal shoe case. If the firing temperature is lower than 160° C., the firing is poor, and the firing time is extended. If the baking temperature exceeds 250° C., the shoe case may be scorched, resulting in poor appearance and inferior volume. Incidentally, it is also possible to make a shoe case with a larger volume by firing in a state where the vapor pressure is increased by a method such as covering the lid during firing.

次に、実施例、比較例等を挙げて本発明を更に具体的に説明するが、これらの実施例等は本発明を制限するものではない。 EXAMPLES Next, the present invention will be described in more detail with reference to examples, comparative examples, etc., but these examples and the like are not intended to limit the present invention.

<エステル交換油脂の製造>
[エステル交換油脂Aの製造]
パーム核油及びパーム極度硬化油を50:50の質量比率で混合した油脂配合物を、化学触媒を用いてランダムエステル交換し、融点43℃のエステル交換油脂Aを得た。
<Production of transesterified fats and oils>
[Production of transesterified fat A]
A fat composition obtained by mixing palm kernel oil and extremely hardened palm oil at a mass ratio of 50:50 was subjected to random transesterification using a chemical catalyst to obtain transesterified fat A having a melting point of 43°C.

[エステル交換油脂Bの製造]
パーム核油及びパームステアリンを45:55の質量比率で混合した油脂配合物を、化学触媒を用いてランダムエステル交換し、融点37℃のエステル交換油脂Bを得た。
[Production of transesterified fat B]
A fat and oil blend obtained by mixing palm kernel oil and palm stearin at a mass ratio of 45:55 was subjected to random transesterification using a chemical catalyst to obtain transesterified fat and oil B having a melting point of 37°C.

[エステル交換油脂Cの製造]
ヨウ素価55のパーム分別軟部油50質量部、ハイエルシン菜種極度硬化油25質量部及びパーム核油25質量部を溶解、混合した油脂配合物を、化学触媒を用いてランダムエステル交換し、融点39℃のエステル交換油脂Cを得た。
[Production of transesterified fat C]
50 parts by mass of fractionated soft palm oil with an iodine value of 55, 25 parts by mass of high erucine rapeseed extremely hardened oil, and 25 parts by mass of palm kernel oil are dissolved and mixed to form an oil-and-fat blend that undergoes random transesterification using a chemical catalyst, and has a melting point of 39°C. A transesterified oil C was obtained.

[エステル交換油脂Dの製造]
パーム核油及びパーム極度硬化油を75:25の質量比率で混合した油脂配合物を、化学触媒を用いてランダムエステル交換し、融点32℃のエステル交換油脂Dを得た。
[Production of transesterified fat D]
A fat blend obtained by mixing palm kernel oil and extremely hardened palm oil at a mass ratio of 75:25 was subjected to random transesterification using a chemical catalyst to obtain a transesterified fat D having a melting point of 32°C.

[エステル交換油脂Eの製造]
ヨウ素価55のパーム分別軟部油を、化学触媒を用いてランダムエステル交換し、融点40℃のエステル交換油脂Eを得た。
[Production of transesterified fat E]
Fractionated soft palm oil having an iodine value of 55 was randomly transesterified using a chemical catalyst to obtain a transesterified fat E having a melting point of 40°C.

〔実施例1〕
<シュー生地用水中油型乳化油脂組成物の製造>
60℃に加温したエステル交換油脂A45質量%からなる油相を用意した。一方、60℃に加温した水48質量%にクリームからバターオイルを製造する際に生じる水相成分の濃縮物(乳固形分38質量%、乳固形分中のリン脂質の含有量9.8質量%、水分62%)5質量%、トータルミルクプロテイン2質量%を添加・分散した水相を用意した。該油相と水相を65℃で混合し、攪拌して水中油型の予備乳化物を調製した。該予備乳化物をVTIS殺菌機(アルファラバル社製UHT殺菌機ステリラボ)で143℃にて5秒間殺菌し、10MPaの圧力で均質化後、5℃まで冷却し、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Aを得た。
[Example 1]
<Production of oil-in-water emulsified oil composition for puff pastry>
An oil phase consisting of 45% by mass of transesterified fat A heated to 60° C. was prepared. On the other hand, the concentrate of the aqueous phase component produced when producing butter oil from cream in 48% by mass of water heated to 60 ° C. (38% by mass of milk solids, 9.8% of phospholipid content in milk solids) An aqueous phase was prepared by adding and dispersing 5% by mass (% by mass, 62% by mass of water) and 2% by mass of total milk protein. The oil phase and the water phase were mixed at 65° C. and stirred to prepare an oil-in-water pre-emulsion. The pre-emulsified product is sterilized at 143 ° C. for 5 seconds with a VTIS sterilizer (UHT sterilizer Sterilab manufactured by Alfa Laval), homogenized at a pressure of 10 MPa, cooled to 5 ° C., and the oil content is 45% by mass. The water content is 51.1% by mass, the SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, the melting point of the oil phase is 43°C, and the constituent fatty acid composition is An oil-in-water emulsified fat composition A for puff pastry of the present invention having a saturated fatty acid content of 36% by mass with 14 or less carbon atoms was obtained.

<シューケースの配合及び製造法>
上記シュー生地用水中油型乳化油脂組成物A256質量部をミキサーボウルに計量し、ガスコンロにかけ、95℃になるまで加熱溶解した。これに薄力粉(油脂分含量1.5質量%)100質量部を一気に投入し、十分糊化・混合して糊化物を得た。ミキサーボウルをミキサーにセットし、中速で1分混合後、全卵(油脂分含量10質量%)190質量部に重炭酸アンモニウム1質量部を溶解した卵液を、中速でミキシングしながら徐々に加え、均一なシュー生地とし、本発明のシュー生地Aを得た。絞り袋にシュー生地Aを充填し、ベーキングシートを敷いた展板に25g絞り、上火180℃、下火220℃に設定した固定オーブンで25分(17分経過後はダンパー開け)焼成し、本発明のシューケースAを得た。
<Formulation and manufacturing method of shoe case>
256 parts by mass of the oil-in-water emulsified oil composition A for choux pastry was weighed into a mixer bowl, placed on a gas stove, and dissolved by heating to 95°C. 100 parts by mass of soft flour (oil content: 1.5% by mass) was added at once to the mixture, and the mixture was sufficiently gelatinized and mixed to obtain a gelatinized product. Set the mixer bowl in the mixer and mix for 1 minute at medium speed, then gradually add the egg liquid obtained by dissolving 1 part by weight of ammonium bicarbonate in 190 parts by weight of whole egg (fat content: 10% by weight) while mixing at medium speed. In addition, a uniform choux pastry was obtained to obtain a choux pastry A of the present invention. Fill a piping bag with choux pastry A, squeeze 25 g onto a spreading plate lined with a baking sheet, bake in a fixed oven set at 180 ° C on the top and 220 ° C on the bottom for 25 minutes (open the damper after 17 minutes), and A shoe case A of the invention was obtained.

〔実施例2〕
実施例1で使用したエステル交換油脂Aに代えて、エステル交換油脂Bを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で61%、20℃で41%、40℃で0%であり、油相の融点は36℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が32質量%である本発明のシュー生地用水中油型乳化油脂組成物Bを得た。
得られたシュー生地用水中油型乳化油脂組成物Bを使用した以外は実施例1同様にして、本発明のシュー生地B及び本発明のシューケースBを得た。
[Example 2]
The oil content was 45% by mass and the water content was 51.1 in the same manner as in Example 1, except that transesterified oil B was used instead of transesterified oil A used in Example 1. The SFC of the oil phase is 61% at 10°C, 41% at 20°C, and 0% at 40°C. The melting point of the oil phase is 36°C. An oil-in-water emulsified fat composition B for puff pastry of the present invention having a fatty acid content of 32% by mass was obtained.
A puff pastry B of the present invention and a shoe case B of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition B for puff pastry was used.

〔実施例3〕
実施例1で使用したエステル交換油脂Aに代えて、エステル交換油脂Cを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で55%、20℃で36%、40℃で3%であり、油相の融点は39℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が12質量%である本発明のシュー生地用水中油型乳化油脂組成物Cを得た。
得られたシュー生地用水中油型乳化油脂組成物Cを使用した以外は実施例1同様にして、本発明のシュー生地C及び本発明のシューケースCを得た。
[Example 3]
The oil content was 45% by mass and the water content was 51.1 in the same manner as the blending and manufacturing method of Example 1, except that the transesterified fat C was used instead of the transesterified fat A used in Example 1. The SFC of the oil phase is 55% at 10°C, 36% at 20°C, and 3% at 40°C, and the melting point of the oil phase is 39°C. An oil-in-water emulsified oil composition C for puff pastry of the present invention having a fatty acid content of 12% by mass was obtained.
A puff pastry C of the present invention and a shoe case C of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition C for puff pastry was used.

〔実施例4〕
実施例1で使用したエステル交換油脂Aに代えて、エステル交換油脂Dを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で72%、20℃で51%、40℃で1%であり、油相の融点は32℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が51質量%である本発明のシュー生地用水中油型乳化油脂組成物Dを得た。
得られたシュー生地用水中油型乳化油脂組成物Dを使用した以外は実施例1同様にして、本発明のシュー生地D及び本発明のシューケースDを得た。
[Example 4]
The oil content was 45% by mass and the water content was 51.1 in the same manner as in Example 1, except that transesterified oil D was used instead of transesterified oil A used in Example 1. The SFC of the oil phase is 72% at 10°C, 51% at 20°C, and 1% at 40°C. The melting point of the oil phase is 32°C. An oil-in-water emulsified fat composition D for puff pastry of the present invention having a fatty acid content of 51% by mass was obtained.
A choux pastry D of the present invention and a shoe case D of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition D for choux pastry was used.

〔実施例5〕
実施例1で使用したエステル交換油脂Aに代えて、パーム核油(融点27℃)を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で59%、20℃で38%、40℃で0%であり、油相の融点は26℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が72質量%である本発明のシュー生地用水中油型乳化油脂組成物Eを得た。
得られたシュー生地用水中油型乳化油脂組成物Eを使用した以外は実施例1同様にして、本発明のシュー生地E及び本発明のシューケースEを得た。
[Example 5]
In the same manner as in Example 1, except that palm kernel oil (melting point 27 ° C.) was used instead of transesterified oil A used in Example 1, the oil content was 45% by mass, and the water content was 45% by mass. is 51.1% by mass, the SFC of the oil phase is 59% at 10°C, 38% at 20°C, and 0% at 40°C, the melting point of the oil phase is 26°C, and the number of carbon atoms in the constituent fatty acid composition An oil-in-water emulsified oil composition E for puff pastry of the present invention having a saturated fatty acid content of 14 or less of 72% by mass was obtained.
A choux pastry E of the present invention and a shoe case E of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition E for choux pastry was used.

〔実施例6〕
実施例1で使用したエステル交換油脂Aに代えて、パーム核分別高融点部(融点32℃)を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で85%、20℃で74%、40℃で0%であり、油相の融点は32℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が82質量%である本発明のシュー生地用水中油型乳化油脂組成物Fを得た。
得られたシュー生地用水中油型乳化油脂組成物Fを使用した以外は実施例1同様にして、本発明のシュー生地F及び本発明のシューケースFを得た。
[Example 6]
In place of the transesterified fat A used in Example 1, the high-melting-point part of palm kernel fraction (melting point: 32°C) was used. , the water content is 51.1% by mass, the SFC of the oil phase is 85% at 10°C, 74% at 20°C, and 0% at 40°C, the melting point of the oil phase is 32°C, and the constituent fatty acid composition to obtain an oil-in-water emulsified oil composition F for puff pastry according to the present invention, in which the content of saturated fatty acids having 14 or less carbon atoms is 82% by mass.
A choux pastry F of the present invention and a shoe case F of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition F for choux pastry was used.

〔実施例7〕
実施例1で使用したエステル交換油脂A45質量部に代えて、エステル交換油脂A9質量部及びパーム核油36質量部からなる混合油脂を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で65%、20℃で45%、40℃で3%であり、油相の融点は28℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が65質量%である本発明のシュー生地用水中油型乳化油脂組成物Gを得た。
得られたシュー生地用水中油型乳化油脂組成物Gを使用した以外は実施例1同様にして、本発明のシュー生地G及び本発明のシューケースGを得た。
[Example 7]
In place of 45 parts by mass of transesterified oil A used in Example 1, a mixed oil consisting of 9 parts by mass of transesterified oil A and 36 parts by mass of palm kernel oil was used. , the oil content is 45% by mass, the water content is 51.1% by mass, the SFC of the oil phase is 65% at 10°C, 45% at 20°C, and 3% at 40°C, and the melting point of the oil phase is An oil-in-water emulsified oil composition G for puff pastry of the present invention having a temperature of 28° C. and a saturated fatty acid content of 65% by mass having 14 or less carbon atoms in the constituent fatty acid composition was obtained.
A puff pastry G of the present invention and a shoe case G of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition G for puff pastry was used.

〔実施例8〕
実施例1で使用したエステル交換油脂A45質量部を、乳脂9質量部及びパーム核油36質量部からなる混合油脂を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で55%、20℃で33%、40℃で0%であり、油相の融点は27℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が62質量%である本発明のシュー生地用水中油型乳化油脂組成物Hを得た。
得られたシュー生地用水中油型乳化油脂組成物Hを使用した以外は実施例1同様にして、本発明のシュー生地H及び本発明のシューケースHを得た。
[Example 8]
In the same manner as in Example 1, except that 45 parts by mass of transesterified oil A used in Example 1 was used as a mixed oil consisting of 9 parts by mass of milk fat and 36 parts by mass of palm kernel oil. is 45% by mass, the water content is 51.1% by mass, the SFC of the oil phase is 55% at 10°C, 33% at 20°C, and 0% at 40°C, and the melting point of the oil phase is 27°C. , to obtain an oil-in-water emulsified fat composition H for puff pastry of the present invention, in which the content of saturated fatty acids having 14 or less carbon atoms in the constituent fatty acid composition is 62% by mass.
A puff pastry H of the present invention and a shoe case H of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition H for puff pastry was used.

〔実施例9〕
実施例1で使用したエステル交換油脂A45質量部を、エステル交換油脂A18質量部及び乳脂27質量部からなる混合油脂を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で58%、20℃で40%、40℃で5%であり、油相の融点は36℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が27質量%である本発明のシュー生地用水中油型乳化油脂組成物Iを得た。
得られたシュー生地用水中油型乳化油脂組成物Iを使用した以外は実施例1同様にして、本発明のシュー生地I及び本発明のシューケースIを得た。
[Example 9]
In the same manner as in the blending and manufacturing method of Example 1, except that a mixed fat consisting of 18 parts by mass of transesterified fat A and 27 parts by mass of milk fat was used instead of 45 parts by mass of transesterified fat A used in Example 1. Oil content is 45% by mass, the water content is 51.1% by mass, the SFC of the oil phase is 58% at 10°C, 40% at 20°C, and 5% at 40°C, and the melting point of the oil phase is 36°C. Thus, an oil-in-water emulsified fat composition I for puff pastry of the present invention was obtained, in which the content of saturated fatty acids having 14 or less carbon atoms in the constituent fatty acid composition was 27% by mass.
A puff pastry I of the present invention and a shoe case I of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition I for puff pastry was used.

〔実施例10〕
実施例1で使用したエステル交換油脂Aに代えて、ヨウ素価(IV)が35であるパーム分別中融点部(融点34℃)を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で91%、20℃で80%、40℃で0%であり、油相の融点は33℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が1質量%である本発明のシュー生地用水中油型乳化油脂組成物Jを得た。
得られたシュー生地用水中油型乳化油脂組成物Jを使用した以外は実施例1と同様にして、本発明のシュー生地J及び本発明のシューケースJを得た。
[Example 10]
In place of the transesterified fat A used in Example 1, the same formulation and manufacturing method as in Example 1 was used, except that a palm fractionated middle melting point part (melting point 34 ° C.) with an iodine value (IV) of 35 was used. , the oil content is 45% by mass, the water content is 51.1% by mass, the SFC of the oil phase is 91% at 10°C, 80% at 20°C, and 0% at 40°C, and the melting point of the oil phase is An oil-in-water emulsified fat composition J for puff pastry of the present invention was obtained, which had a temperature of 33° C. and a saturated fatty acid content of 14% or less in the constituent fatty acid composition of the present invention.
A choux pastry J of the present invention and a shoe case J of the present invention were obtained in the same manner as in Example 1, except that the obtained oil-in-water emulsified oil composition J for choux pastry was used.

〔実施例11〕
実施例1で使用したエステル交換油脂Aの配合量を32質量%に変更し、水の配合量を61質量%に変更した以外は、実施例1の配合・製法と同様にして、油脂分含量が32質量%、水分含量が64.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Kを得た。
得られたシュー生地用水中油型乳化油脂組成物Kを使用した以外は実施例1同様にして、本発明のシュー生地K及び本発明のシューケースKを得た。
[Example 11]
The blending and manufacturing method of Example 1 was repeated in the same manner as in Example 1, except that the blending amount of transesterified fat A used in Example 1 was changed to 32% by mass and the blending amount of water was changed to 61% by mass. is 32% by mass, the water content is 64.1% by mass, the SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, and the melting point of the oil phase is 43°C. , to obtain an oil-in-water emulsified oil composition K for puff pastry of the present invention, in which the content of saturated fatty acids having 14 or less carbon atoms in the constituent fatty acid composition is 36% by mass.
A choux pastry K of the present invention and a shoe case K of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition K for choux pastry was used.

〔実施例12〕
実施例1で使用したエステル交換油脂Aの配合量を58質量%に変更し、水の配合量を35質量%に変更した以外は、実施例1の配合・製法と同様にして、油脂分含量が58質量%、水分含量が38.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Lを得た。
得られたシュー生地用水中油型乳化油脂組成物Kを使用した以外は実施例1同様にして、本発明のシュー生地L及び本発明のシューケースLを得た。
[Example 12]
The blending and manufacturing method of Example 1 was repeated in the same manner as in Example 1, except that the blending amount of transesterified fat A used in Example 1 was changed to 58% by mass, and the blending amount of water was changed to 35% by mass. is 58% by mass, the water content is 38.1% by mass, the SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, and the melting point of the oil phase is 43°C. , to obtain an oil-in-water emulsified fat composition L for puff pastry of the present invention having a saturated fatty acid content of 36% by mass with 14 or less carbon atoms in the constituent fatty acid composition.
A puff pastry L of the present invention and a shoe case L of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition K for puff pastry was used.

〔実施例13〕
実施例1で使用したクリームからバターオイルを製造する際に生じる水相成分の濃縮物5質量%を無添加に変更し、レシチン0.15質量%及びソルビタン脂肪酸エステル0.15質量%を油相に添加し、水の配合量を48質量%から52.7質量%に変更した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が52.7質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Mを得た。
得られたシュー生地用水中油型乳化油脂組成物Mを使用した以外は実施例1同様にして、本発明のシュー生地M及び本発明のシューケースMを得た。
[Example 13]
5% by mass of the concentrate of the aqueous phase components produced when producing butter oil from the cream used in Example 1 was changed to no additive, and 0.15% by mass of lecithin and 0.15% by mass of sorbitan fatty acid ester were added to the oil phase. and the amount of water was changed from 48% by mass to 52.7% by mass, in the same manner as in Example 1, except that the oil content was 45% by mass and the water content was 52.7%. The SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, and the melting point of the oil phase is 43°C. An oil-in-water emulsified fat composition M for puff pastry of the present invention having a fatty acid content of 36% by mass was obtained.
A puff pastry M of the present invention and a shoe case M of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition M for puff pastry was used.

〔実施例14〕
実施例1で使用したトータルミルクプロテインに代えてミルクプロテインコンセントレートを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Nを得た。
得られたシュー生地用水中油型乳化油脂組成物Nを使用した以外は実施例1同様にして、本発明のシュー生地N及び本発明のシューケースNを得た。
[Example 14]
The oil content was 45% by mass and the water content was 51.1% by mass in the same manner as in Example 1, except that the milk protein concentrate was used instead of the total milk protein used in Example 1. The SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, and the melting point of the oil phase is 43°C. An oil-in-water emulsified fat composition N for puff pastry of the present invention having a content of 36% by mass was obtained.
A puff pastry N of the present invention and a shoe case N of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition N for puff pastry was used.

〔実施例15〕
実施例1で使用したトータルミルクプロテインに代えて脱脂粉乳を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Oを得た。
得られたシュー生地用水中油型乳化油脂組成物Oを使用した以外は実施例1同様にして、本発明のシュー生地O及び本発明のシューケースOを得た。
[Example 15]
The oil content was 45% by mass and the water content was 51.1% by mass in the same manner as in Example 1, except that skimmed milk powder was used instead of the total milk protein used in Example 1. , the SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, the melting point of the oil phase is 43°C, and the content of saturated fatty acids with 14 or less carbon atoms in the constituent fatty acid composition An oil-in-water emulsified oil composition O for puff pastry of the present invention having a content of 36% by mass was obtained.
A puff pastry O of the present invention and a shoe case O of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition O for puff pastry was used.

〔実施例16〕
実施例1で使用したトータルミルクプロテインに代えてホエイたんぱく質濃縮物を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Pを得た。
得られたシュー生地用水中油型乳化油脂組成物Pを使用した以外は実施例1同様にして、本発明のシュー生地P及び本発明のシューケースPを得た。
[Example 16]
The blending and manufacturing method of Example 1 was repeated except that the whey protein concentrate was used instead of the total milk protein used in Example 1, and the oil content was 45% by mass and the water content was 51.1% by mass. The SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, and the melting point of the oil phase is 43°C. An oil-in-water emulsified oil composition P for puff pastry of the present invention having a content of 36% by mass was obtained.
A choux pastry P of the present invention and a shoe case P of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition P for choux pastry was used.

〔実施例17〕
実施例1で使用したトータルミルクプロテインに代えてカゼインナトリウムを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で87%、20℃で77%、40℃で13%であり、油相の融点は43℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が36質量%である本発明のシュー生地用水中油型乳化油脂組成物Qを得た。
得られたシュー生地用水中油型乳化油脂組成物Qを使用した以外は実施例1同様にして、本発明のシュー生地Q及び本発明のシューケースQを得た。
[Example 17]
The blending and manufacturing method of Example 1 was repeated except that sodium caseinate was used instead of the total milk protein used in Example 1, and the fat content was 45% by mass and the water content was 51.1% by mass , the SFC of the oil phase is 87% at 10°C, 77% at 20°C, and 13% at 40°C, the melting point of the oil phase is 43°C, and the content of saturated fatty acids with 14 or less carbon atoms in the constituent fatty acid composition An oil-in-water emulsified oil composition Q for puff pastry of the present invention having a content of 36% by mass was obtained.
A puff pastry Q of the present invention and a shoe case Q of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition Q for puff pastry was used.

〔比較例1〕
実施例1で使用したエステル交換油脂Aに代えて、パーム油を使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で50%、20℃で20%、40℃で3%であり、油相の融点は36℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が1質量%である比較例のシュー生地用水中油型乳化油脂組成物Rを得た。
得られたシュー生地用水中油型乳化油脂組成物Rを使用した以外は実施例1同様にして、本発明のシュー生地R及び本発明のシューケースRを得た。
[Comparative Example 1]
The oil content was 45% by mass and the water content was 51.1% by mass in the same manner as in Example 1, except that palm oil was used instead of transesterified oil A used in Example 1. The SFC of the oil phase is 50% at 10°C, 20% at 20°C, and 3% at 40°C, and the melting point of the oil phase is 36°C. An oil-in-water emulsified oil composition R for choux pastry was obtained as a comparative example having a content of 1% by mass.
A puff pastry R of the present invention and a shoe case R of the present invention were obtained in the same manner as in Example 1 except that the obtained oil-in-water emulsified oil composition R for puff pastry was used.

〔比較例2〕
実施例1で使用したエステル交換油脂Aに代えて、ヨウ素価(IV)が57であるパームオレインを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で35%、20℃で5%、40℃で0%であり、油相の融点は25℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が1質量%である比較例のシュー生地用水中油型乳化油脂組成物Sを得た。
得られたシュー生地用水中油型乳化油脂組成物Sを使用した以外は実施例1同様にして、本発明のシュー生地S及び本発明のシューケースSを得た。
[Comparative Example 2]
In place of transesterified fat A used in Example 1, palm olein having an iodine value (IV) of 57 was used, and the fat content was 45% by mass in the same manner as the blending and manufacturing method of Example 1. , the water content is 51.1% by mass, the SFC of the oil phase is 35% at 10°C, 5% at 20°C, and 0% at 40°C, the melting point of the oil phase is 25°C, and the constituent fatty acid composition An oil-in-water emulsified fat composition S for puff pastry was obtained as a comparative example in which the content of saturated fatty acids having 14 or less carbon atoms was 1% by mass.
A puff pastry S of the present invention and a shoe case S of the present invention were obtained in the same manner as in Example 1, except that the obtained oil-in-water emulsified oil composition S for puff pastry was used.

〔比較例3〕
実施例1で使用したエステル交換油脂Aに代えて、エステル交換油脂Eを使用した以外は、実施例1の配合・製法と同様にして、油脂分含量が45質量%、水分含量が51.1質量%であり、油相のSFCが10℃で43%、20℃で23%、40℃で5%であり、油相の融点は39℃であり、構成脂肪酸組成における炭素数14以下の飽和脂肪酸の含有量が2質量%である比較例のシュー生地用水中油型乳化油脂組成物Tを得た。
得られたシュー生地用水中油型乳化油脂組成物Tを使用した以外は実施例1同様にして、比較例のシュー生地T及び比較例のシューケースTを得た。
[Comparative Example 3]
The oil content was 45% by mass and the water content was 51.1 in the same manner as in Example 1, except that transesterified oil E was used instead of transesterified oil A used in Example 1. The SFC of the oil phase is 43% at 10°C, 23% at 20°C, and 5% at 40°C, and the melting point of the oil phase is 39°C. An oil-in-water emulsified fat composition T for choux pastry was obtained as a comparative example having a fatty acid content of 2% by mass.
A puff pastry T of Comparative Example and a shoe case T of Comparative Example were obtained in the same manner as in Example 1, except that the obtained oil-in-water emulsified oil composition T for puff pastry was used.

〔実施例18〕
上記シュー生地用水中油型乳化油脂組成物A170質量部、水33質量部、及びシュー用マーガリン(「ネオシューM-A」:株式会社ADEKA製)(油中水型乳化物、油脂分含量77質量%、水分含量19質量%)50質量部をミキサーボウルに計量し、ガスコンロにかけ、95℃になるまで加熱溶解した。これに薄力粉(油脂分含量1.5質量%)100質量部を一気に投入し、十分糊化・混合して糊化物を得た。ミキサーボウルをミキサーにセットし、中速で1分混合後、全卵(油脂分含量10質量%)190質量部に重炭酸アンモニウム1質量部を溶解した卵液を、中速でミキシングしながら徐々に加え、均一なシュー生地とし、本発明のシュー生地Uを得た。絞り袋にシュー生地Uを充填し、ベーキングシートを敷いた展板に25g絞り、上火180℃、下火220℃に設定した固定オーブンで25分(17分経過後はダンパー開け)焼成し、本発明のシューケースUを得た。
[Example 18]
170 parts by mass of the oil-in-water emulsified oil composition A for puff pastry, 33 parts by mass of water, and margarine for puff ("Neo-Shoe MA": manufactured by ADEKA Co., Ltd.) (water-in-oil emulsion, fat content 77% by mass) , water content of 19% by mass) was weighed into a mixer bowl, placed on a gas stove, and heated to 95°C to dissolve. 100 parts by mass of soft flour (oil content: 1.5% by mass) was added at once to the mixture, and the mixture was sufficiently gelatinized and mixed to obtain a gelatinized product. Set the mixer bowl in the mixer and mix for 1 minute at medium speed, then gradually add the egg liquid obtained by dissolving 1 part by weight of ammonium bicarbonate in 190 parts by weight of whole egg (fat content: 10% by weight) while mixing at medium speed. In addition, a uniform choux pastry was obtained to obtain the choux pastry U of the present invention. Fill a piping bag with choux pastry U, squeeze 25 g onto a spreading board lined with a baking sheet, bake in a fixed oven set at 180 ° C on the top and 220 ° C on the bottom for 25 minutes (open the damper after 17 minutes). A shoe case U of the invention was obtained.

〔実施例19〕
上記シュー生地用水中油型乳化油脂組成物A85質量部、水66質量部、及びシュー用マーガリン(「ネオシューM-A」:株式会社ADEKA製)(油中水型乳化物、油脂分含量77質量%、水分含量19質量%)100質量部をミキサーボウルに計量し、ガスコンロにかけ、95℃になるまで加熱溶解した。これに薄力粉(油脂分含量1.5質量%)100質量部を一気に投入し、十分糊化・混合して糊化物を得た。ミキサーボウルをミキサーにセットし、中速で1分混合後、全卵(油脂分含量10質量%)190質量部に重炭酸アンモニウム1質量部を溶解した卵液を、中速でミキシングしながら徐々に加え、均一なシュー生地とし、本発明のシュー生地Vを得た。絞り袋にシュー生地Vを充填し、ベーキングシートを敷いた展板に25g絞り、上火180℃、下火220℃に設定した固定オーブンで25分(17分経過後はダンパー開け)焼成し、本発明のシューケースVを得た。
[Example 19]
85 parts by mass of the oil-in-water emulsified oil composition A for the puff pastry, 66 parts by mass of water, and margarine for the puff ("Neo-Shoe MA": manufactured by ADEKA Co., Ltd.) (water-in-oil emulsion, fat content 77% by mass) , water content 19% by mass) was weighed into a mixer bowl, placed on a gas stove, and heated to 95°C to dissolve. 100 parts by mass of soft flour (oil content: 1.5% by mass) was added at once to the mixture, and the mixture was sufficiently gelatinized and mixed to obtain a gelatinized product. Set the mixer bowl in the mixer and mix for 1 minute at medium speed, then gradually add the egg liquid obtained by dissolving 1 part by weight of ammonium bicarbonate in 190 parts by weight of whole egg (fat content: 10% by weight) while mixing at medium speed. In addition, a uniform choux pastry was obtained to obtain the choux pastry V of the present invention. Fill a piping bag with choux pastry V, squeeze 25 g onto a spreading plate lined with a baking sheet, bake in a fixed oven set at 180 ° C on the top and 220 ° C on the bottom for 25 minutes (open the damper after 17 minutes), and bake. A shoe case V of the invention was obtained.

〔比較例4〕
水100質量部、及びシュー用マーガリン(「ネオシューM-A」:株式会社ADEKA製)(油中水型乳化物、油脂分含量77質量%、水分含量19質量%)150質量部をミキサーボウルに計量し、ガスコンロにかけ、95℃になるまで加熱溶解した。これに薄力粉(油脂分含量1.5質量%)100質量部を一気に投入し、十分糊化・混合して糊化物を得た。ミキサーボウルをミキサーにセットし、中速で1分混合後、全卵(油脂分含量10質量%)190質量部に重炭酸アンモニウム1質量部を溶解した卵液を、中速でミキシングしながら徐々に加え、均一なシュー生地とし、比較例のシュー生地Wを得た。絞り袋にシュー生地Wを充填し、ベーキングシートを敷いた展板に25g絞り、上火180℃、下火220℃に設定した固定オーブンで25分(17分経過後はダンパー開け)焼成し、比較例のシューケースWを得た。
[Comparative Example 4]
100 parts by mass of water and 150 parts by mass of margarine for puff ("Neosho MA": manufactured by ADEKA Co., Ltd.) (water-in-oil emulsion, oil content 77% by mass, water content 19% by mass) in a mixer bowl It was weighed, placed on a gas stove, and dissolved by heating to 95°C. 100 parts by mass of soft flour (oil content: 1.5% by mass) was added at once to the mixture, and the mixture was sufficiently gelatinized and mixed to obtain a gelatinized product. Set the mixer bowl in the mixer and mix for 1 minute at medium speed, then gradually add the egg liquid obtained by dissolving 1 part by weight of ammonium bicarbonate in 190 parts by weight of whole egg (fat content: 10% by weight) while mixing at medium speed. In addition, a uniform choux pastry was obtained to obtain a choux pastry W of a comparative example. Fill the pastry bag with choux pastry W, squeeze 25 g onto a spreading plate lined with a baking sheet, and bake in a fixed oven set at 180 ° C on the top and 220 ° C on the bottom for 25 minutes (open the damper after 17 minutes) and compare. Example shoe case W was obtained.

<評価方法及び評価基準>
得られたシューケースA~Wの食感(口溶け、歯切れ)、風味、体積及び保型性について以下の基準に従って評価し、結果を表1に記載した。
<Evaluation method and evaluation criteria>
Texture (dissolving in the mouth, crispness), flavor, volume and shape retention of the resulting shoe cases A to W were evaluated according to the following criteria, and the results are shown in Table 1.

(食感及び風味)
焼成1日後のシューケースについて、歯切れ、口溶け、及び風味を、パネラー21名にて下記の基準にて評価し、その一番多かった評価を表1に記載した。なお同数の場合は一段上の評価とした。
(Texture and flavor)
Twenty-one panelists evaluated the crispness, melting in the mouth, and flavor of the shoe cases one day after baking according to the following criteria. In addition, in the case of the same number, it was evaluated as one rank higher.

(歯切れ評価基準)
◎:歯切れがよい
○:やや歯切れがよい
△:歯切れが悪い
×:非常に歯切れが悪い
(Clear evaluation criteria)
◎: Good crispness ○: Slightly crispy △: Poor crispness ×: Very poor crispness

(口溶け評価基準)
◎:非常に良好
○+:良好
○:やや良好
△:やや不良
×:不良
(Evaluation criteria for melting in the mouth)
◎: Very good ○ +: Good ○: Slightly good △: Slightly poor ×: Poor

(風味評価基準)
◎:非常に良好
○+:良好
○:やや良好
△:やや不良
×:不良
(Flavor Evaluation Criteria)
◎: Very good ○ +: Good ○: Slightly good △: Slightly poor ×: Poor

(体積評価基準)
焼成1日後のシューケース各21個を、3Dレーザースキャナー(アステックス社製)でシューケースの容積を測定し、それをシューケースの重量で除して比容積(cm/g)を測定し、その平均値を算出し、下記の基準にて評価した。
◎:比容積17(cm/g)以上
○:比容積15(cm/g)以上17(cm/g)未満
△:比容積15(cm/g)未満
(Volume evaluation standard)
The volume of each 21 shoe cases after one day of baking was measured with a 3D laser scanner (manufactured by Astex), and the volume was divided by the weight of the shoe case to measure the specific volume (cm 3 /g). , the average value was calculated and evaluated according to the following criteria.
◎: Specific volume 17 (cm 3 /g) or more ○: Specific volume 15 (cm 3 /g) or more and less than 17 (cm 3 /g) △: Specific volume less than 15 (cm 3 /g)

(保型性評価基準)
焼成1日後のシューケースについて、熟練したパネラーが目視にて下記の基準で保型性を評価した。
◎:腰もちがよく、非常に良好
○:良好
△:やや潰れており、不良である
×:潰れており、不良である
(Evaluation criteria for retention of shape)
A skilled panelist visually evaluated the shape retention of the shoe case one day after baking according to the following criteria.
◎: Good waist, very good ○: Good △: Slightly collapsed, poor ×: Collapsed, poor

Figure 2022124400000001
Figure 2022124400000001

Claims (5)

油相のSFCが10℃で55~100%、20℃で30~100%、40℃で15%以下である、シュー生地用水中油型乳化油脂組成物。 An oil-in-water emulsified fat composition for puff pastry, wherein the SFC of the oil phase is 55 to 100% at 10°C, 30 to 100% at 20°C, and 15% or less at 40°C. 乳固形分中のリン脂質の含有量が2質量%以上である乳原料を含有する、請求項1記載のシュー生地用水中油型乳化油脂組成物。 2. The oil-in-water emulsified fat composition for puff pastry according to claim 1, which contains a milk raw material having a phospholipid content of 2% by mass or more in milk solids. トータルミルクプロテイン及び/又はミルクプロテインコンセントレートを含有する、請求項1又は2記載のシュー生地用水中油型乳化油脂組成物。 The oil-in-water emulsified fat composition for choux pastry according to claim 1 or 2, which contains total milk protein and/or milk protein concentrate. 請求項1~3のいずれか一項に記載のシュー生地用水中油型乳化油脂組成物を使用したシュー生地。 A puff pastry using the oil-in-water emulsified fat composition for puff pastry according to any one of claims 1 to 3. 請求項4記載のシュー生地を焼成したシュー製品。







A choux product obtained by baking the choux pastry according to claim 4.







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