JP2022080142A - Foamable oil-in-water type emulsified fat composition - Google Patents

Foamable oil-in-water type emulsified fat composition Download PDF

Info

Publication number
JP2022080142A
JP2022080142A JP2020191149A JP2020191149A JP2022080142A JP 2022080142 A JP2022080142 A JP 2022080142A JP 2020191149 A JP2020191149 A JP 2020191149A JP 2020191149 A JP2020191149 A JP 2020191149A JP 2022080142 A JP2022080142 A JP 2022080142A
Authority
JP
Japan
Prior art keywords
weight
oil
emulsifier
fat
fat composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2020191149A
Other languages
Japanese (ja)
Inventor
敏秀 磯部
Toshihide Isobe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaneka Corp
Original Assignee
Kaneka Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaneka Corp filed Critical Kaneka Corp
Priority to JP2020191149A priority Critical patent/JP2022080142A/en
Publication of JP2022080142A publication Critical patent/JP2022080142A/en
Pending legal-status Critical Current

Links

Landscapes

  • Grain Derivatives (AREA)
  • Edible Oils And Fats (AREA)

Abstract

To provide whipped cream not inferior in melting feeling in the mouth nor excessively sweet, having high overrun, with shape-retaining properties and syneresis resistance while allowing easy normal-temperature selling, and to provide a foamable oil-in-water type emulsified fat composition to be served as a raw material thereof.SOLUTION: A foamable oil-in-water type emulsified fat composition contains 15 to 40 wt.% of prescribed fat, 36 to 57 wt.% of water component, 17 to 23 wt.% of saccharide, 0.01 to 0.25 wt.% of potassium sorbate and 0.048 to 0.8 wt.% of protein, specified quantities of three kinds of prescribed emulsifier, specified quantities of two kinds of polysaccharide, and 2 to 75 ppm, with pH 3 to 6. The foamable oil-in-water type emulsified fat composition is to be used to produce whipped cream for normal-temperature selling. Whipped cream for normal-temperature selling is obtained by whipping the foamable oil-in-water type emulsified fat composition and has overrun of 200 to 350%.SELECTED DRAWING: None

Description

本発明は、ホイップドクリーム用の起泡性水中油型乳化油脂組成物、並びに、該組成物がホイップされた常温販売用ホイップドクリーム及びそれを含む食品に関する。 The present invention relates to a foamable oil-in-water emulsified oil / fat composition for whipped cream, a whipped cream for sale at room temperature to which the composition is whipped, and a food containing the same.

近年、食品の販売形態において、設備やエネルギーの観点から、常温で販売できて、日持ちのする食品が重要になってきており、菓子やパンでも同様で、更にソフトで軽い食感が求められている。そこで、このような菓子やパンとの相性の良さの観点から、口溶けが良好で、食感が軽くソフトで、常温でも形崩れせず良好な保形性を有し、且つ離水しにくいホイップドクリームが望まれている。 In recent years, in the form of food sales, foods that can be sold at room temperature and have a long shelf life have become important from the viewpoint of equipment and energy, and the same applies to confectionery and bread, and a softer and lighter texture is required. There is. Therefore, from the viewpoint of compatibility with such confectionery and bread, whipped cream that melts in the mouth well, has a light and soft texture, does not lose its shape even at room temperature, has good shape retention, and does not easily separate from water. Cream is desired.

常温での販売を可能にするためには、通常、糖を多くして静菌作用を強めたり、融点の高い油脂を用いて保形性を高める。その状態でオーバーランが低いと口溶けが悪く、重い食感の甘いホイップドクリームになる。そこで、オーバーランを高めるためには、通常、乳化剤を多用したり、ヒドロキシプロピルメチルセルロース(HPMC)を使用する。しかし、それでも常温での保形性や離水耐性は不充分であり、また乳化剤が多いと異味が強くなるし、HPMCが多過ぎると粘性が上がって口溶けが悪化したり、オーバーランが低下したり、離水耐性が低下したり、溶解させ難いために生産性が落ちる。 In order to enable sales at room temperature, usually, sugar is increased to enhance the bacteriostatic effect, or fats and oils having a high melting point are used to enhance the shape retention. If the overrun is low in that state, it will not melt in the mouth and will become a sweet whipped cream with a heavy texture. Therefore, in order to enhance overrun, emulsifiers are usually used extensively or hydroxypropylmethyl cellulose (HPMC) is usually used. However, even so, the shape retention and water separation resistance at room temperature are insufficient, and if the amount of emulsifier is large, the taste becomes strong, and if the amount of HPMC is too large, the viscosity increases, the melting in the mouth worsens, and the overrun decreases. , The water separation resistance is lowered and the productivity is lowered because it is difficult to dissolve.

例えば、特許文献1には水溶性炭水化物と、(b1)水素化植物性脂肪と、(c)9未満のHLBを有する乳化剤配合物と、(d1)第1のHPMCと、(d2)第2のHPMCと、(e)タンパク質と、(g)水と、を含み、第2のHPMC(d2)に対する第1のHPMC(d1)の重量比が特定の範囲内にある、高いオーバーラン、硬度(口当たり)、高さ変化率、及び良好な離水性を有するホイップトッピング組成物が開示されている。しかしながら、実施例1のホイップトッピング組成物は、オーバーラン292%で、25℃で5日間での保形性や離水耐性は良好なものの、水分少な目且つHPMC含量が多いため、口溶けが悪く、実施例2のホイップトッピング組成物は、オーバーラン309%で、HPMC含量が多いが水分が多く、口溶けに問題はないものの、離水耐性が不十分であり、25℃1日間で離水が発生するため常温販売に耐えられない。 For example, Patent Document 1 describes a water-soluble carbohydrate, (b1) hydrogenated vegetable fat, (c) an emulsifier formulation having an HLB of less than 9, (d1) a first HPMC, and (d2) a second. HPMC, (e) protein, (g) water, and the weight ratio of the first HPMC (d1) to the second HPMC (d2) is within a specific range, high overrun, hardness. A whip topping composition having (mouthfeel), rate of change in height, and good water release is disclosed. However, the whipped topping composition of Example 1 had an overrun of 292%, and although it had good shape retention and water separation resistance at 25 ° C. for 5 days, it was poorly melted in the mouth due to its low water content and high HPMC content. The whipped topping composition of Example 2 has an overrun of 309%, a high HPMC content but a large amount of water, and although there is no problem in melting in the mouth, the water separation resistance is insufficient and water separation occurs at 25 ° C for 1 day, so that the temperature is normal temperature. I can't stand the sale.

国際公開第2014/063327号International Publication No. 2014/0633227

本発明の目的は、常温販売が容易にできるにもかかわらず、高オーバーランで、保形性及び離水耐性を有し、口溶けに問題がない甘さ控えめのホイップドクリーム、及びその原料となる起泡性水中油型乳化油脂組成物を提供することである。 An object of the present invention is a whipped cream having a high overrun, shape retention and water separation resistance, and a low sweetness that does not cause a problem in melting in the mouth, even though it can be easily sold at room temperature, and a raw material thereof. It is to provide a foamable oil-in-water emulsified oil / fat composition.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、油脂、水分、糖類、ソルビン酸カリウム、タンパク質を特定量含み、特定の乳化剤を特定量含み、特定の多糖類を特定量含み、カルシウムを特定量含み、前記油脂中に特定の油脂を特定量含み、油滴のメジアン径及びpHが特定範囲である起泡性水中油型乳化油脂組成物を起泡させて得たホイップドクリームは、高オーバーラン、25℃で5日の保形性および離水耐性を実現でき、口溶けに問題がなく、甘さ控えめであることを見出し、本発明を完成するに至った。 As a result of diligent research to solve the above problems, the present inventors have included a specific amount of fat, water, saccharide, potassium sorbate, and protein, a specific amount of a specific emulsifier, and a specific amount of a specific polysaccharide. A whip obtained by foaming a foamable oil-in-water emulsified oil / fat composition containing a specific amount of calcium, a specific amount of a specific oil / fat in the oil / fat, and a specific range of median diameter and pH of oil droplets. It has been found that the docream can achieve high overrun, shape retention for 5 days at 25 ° C. and water separation resistance, has no problem in melting in the mouth, and has a modest sweetness, and has completed the present invention.

即ち、本発明の第一は、起泡性水中油型乳化油脂組成物全体中、油脂を15~40重量%、水分を36~57重量%、糖類を17~23重量%(乾燥重量)、ソルビン酸カリウムを0.01~0.25重量%、タンパク質を0.048~0.8重量%含有し、乳化剤Aを0.3~0.5重量%、乳化剤Bを0.1~0.25重量%、乳化剤Cを0.1~0.25重量%含有し、且つ乳化剤B/乳化剤A(重量比)が0.2~0.67、乳化剤C/(乳化剤A+乳化剤B)(重量比)が0.14~0.5であり、多糖類Xを0.01~0.4重量%、多糖類Yを0.1~0.3重量%含有し、且つ多糖類Y/多糖類X(重量比)が0.25~30であり、カルシウムを2~75ppm含有し、前記油脂全体中、油脂Aの含有量が48~100重量%であり、前記起泡性水中油型乳化油脂組成物中の油滴のメジアン径が0.1~1.2μmであり、pHが3~6である、常温販売用ホイップドクリームの作製に用いる起泡性水中油型乳化油脂組成物(油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中50~60重量%含み、25℃のSFCが20~85%、且つ35℃のSFCが3~15%である油脂、乳化剤A:HLBが112~18、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリソルベート、乳化剤B:HLBが0~9、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリグリセリン脂肪酸エステル、乳化剤C:C16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含む、蒸留されたグリセリン酸脂肪酸モノエステル、多糖類X:脱アシル型ジェランガム、多糖類Y:2%水溶液の20℃での粘度が20~110mPa・sであるヒドロキシプロピルメチルセルロース)に関する。好ましい実施態様は、前記起泡性水中油型乳化油脂組成物中の乳化剤A、乳化剤B及び乳化剤Cの混合物のHLB(加重平均)が9.5~12.9である、前記記載の起泡性水中油型乳化油脂組成物に関する。
本発明の第二は、前記記載の起泡性水中油型乳化油脂組成物がホイップされた、オーバーランが200~350%である常温販売用ホイップドクリームに関する。
本発明の第三は、前記記載の常温販売用ホイップドクリームを、サンド、ナッペ、フィリング、又はトッピングした食品に関する。
本発明の第四は、起泡性水中油型乳化油脂組成物全体中、油脂を15~40重量%、水分を36~57重量%含有し、前記油脂全体中、油脂Aの含有量が48~100重量%であり、油滴のメジアン径が0.1~1.2μmである起泡性水中油型乳化油脂組成物の製造方法であって、水に、起泡性水中油型乳化油脂組成物全体中、乳化剤Aを0.3~0.5重量%、糖類を17~23重量%(乾燥重量)、ソルビン酸カリウムを0.01~0.25重量%、タンパク質を0.048~0.8重量%、多糖類Xを0.01~0.4重量%、多糖類Yを0.1~0.3重量%、カルシウムを2~75ppm含み、且つ多糖類Y/多糖類X(重量比)が0.25~30となるよう各々を溶解した水相部に、前記油脂に、起泡性水中油型乳化油脂組成物全体中、乳化剤Bを0.1~0.25重量%、乳化剤Cを0.1~0.25重量%含み、乳化剤B/乳化剤A(重量比)が0.2~0.67且つ乳化剤C/(乳化剤A+乳化剤B)(重量比)が0.14~0.5となるように各々を溶解した油相部を添加して予備乳化し、1段目5~52MPa/2段目3~12の圧力で均質化した後に、殺菌処理することを特徴とする、pHが3~6である、常温販売用ホイップドクリームの作製に用いる起泡性水中油型乳化油脂組成物の製造方法(油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中50~60重量%含み、25℃のSFCが20~85%、且つ35℃のSFCが3~15%である油脂、乳化剤A:HLBが12~18、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリソルベート、乳化剤B:HLBが0~9、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリグリセリン脂肪酸エステル、乳化剤C:C16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含む、蒸留されたグリセリン酸脂肪酸モノエステル、多糖類X:脱アシル型ジェランガム、多糖類Y:2%水溶液の20℃での粘度が20~110mPa・sであるヒドロキシプロピルメチルセルロース)に関する。
That is, the first of the present invention is to add 15 to 40% by weight of fat and oil, 36 to 57% by weight of water, and 17 to 23% by weight of saccharides (dry weight) in the whole foamable oil-in-water emulsified fat and oil composition. It contains 0.01 to 0.25% by weight of potassium sorbate, 0.048 to 0.8% by weight of protein, 0.3 to 0.5% by weight of emulsifier A, and 0.1 to 0% by weight of emulsifier B. It contains 25% by weight, emulsifier C in an amount of 0.1 to 0.25% by weight, and emulsifier B / emulsifier A (weight ratio) is 0.2 to 0.67, emulsifier C / (embroider A + emulsifier B) (weight ratio). ) Is 0.14 to 0.5, contains 0.01 to 0.4% by weight of polysaccharide X, 0.1 to 0.3% by weight of polysaccharide Y, and polysaccharide Y / polysaccharide X. (Weight ratio) is 0.25 to 30, contains 2 to 75 ppm of calcium, and the content of fat A is 48 to 100% by weight in the whole fat and oil, and the foamable oil-in-water emulsified fat and oil composition. Foamable oil-in-water emulsified fat composition (fat A) used for producing whipped cream for sale at room temperature, having a median diameter of 0.1 to 1.2 μm and a pH of 3 to 6 in the substance. : Fats and oils containing 50 to 60% by weight of saturated fatty acid of C12 or less, 20 to 85% SFC at 25 ° C, and 3 to 15% SFC at 35 ° C, emulsifier A: 112 to HLB. 18 and a polysorbate containing 90 to 100% by weight of saturated fatty acids of C 16 to C 18 in total, emulsifier B: HLB of 0 to 9 and saturated fatty acids of C 16 to C 18 in total. Polyglycerin fatty acid ester containing 90 to 100% by weight, emulsifier C: Distilled glyceric acid fatty acid monoester containing 90 to 100% by weight of saturated fatty acids of C 16 to C 18 in total, polysaccharide X: Deacylated gellan gum, hydroxypropylmethyl cellulose having a viscosity of a 2% aqueous solution of polysaccharide Y: 2% at 20 ° C. of 20 to 110 mPa · s). In a preferred embodiment, the foaming according to the above description, wherein the HLB (weighted average) of the mixture of emulsifier A, emulsifier B and emulsifier C in the foamable oil-in-water emulsified oil / fat composition is 9.5 to 12.9. The present invention relates to an oil-in-water emulsified oil / fat composition.
The second aspect of the present invention relates to a whipped cream for sale at room temperature having an overrun of 200 to 350%, to which the above-mentioned foamable oil-in-water emulsified oil / fat composition is whipped.
A third aspect of the present invention relates to a food product obtained by sandwiching, napping, filling, or topping the above-mentioned whipped cream for sale at room temperature.
The fourth aspect of the present invention is to contain 15 to 40% by weight of fat and oil and 36 to 57% by weight of water in the whole foamable oil-in-water emulsified fat and oil composition, and the content of fat and oil A is 48 in the whole fat and oil. It is a method for producing a foamable oil-in-water emulsified oil / fat composition having an amount of ~ 100% by weight and a median diameter of oil droplets of 0.1 to 1.2 μm. In the whole composition, emulsifier A is 0.3 to 0.5% by weight, sugar is 17 to 23% by weight (dry weight), potassium sorbate is 0.01 to 0.25% by weight, and protein is 0.048 to 0.048%. It contains 0.8% by weight of polysaccharide X, 0.01 to 0.4% by weight of polysaccharide Y, 0.1 to 0.3% by weight of polysaccharide Y, 2 to 75 ppm of calcium, and polysaccharide Y / polysaccharide X ( In the aqueous phase portion in which each was dissolved so that the weight ratio) was 0.25 to 30, the emulsifier B was added to the oil and fat in an amount of 0.1 to 0.25% by weight in the entire foamable oil-in-water emulsified oil and fat composition. , Embroidery C is contained in an amount of 0.1 to 0.25% by weight, emulsifier B / emulsifier A (weight ratio) is 0.2 to 0.67, and emulsifier C / (embroidery A + emulsifier B) (weight ratio) is 0.14. It is characterized by adding an oil phase portion in which each is dissolved so as to be ~ 0.5, pre-emulsifying, homogenizing at a pressure of 5 to 52 MPa in the first stage / 3 to 12 in the second stage, and then sterilizing. A method for producing a foamable oil-in-water emulsified fat / oil composition used for producing a whipped cream for sale at room temperature having a pH of 3 to 6 (fat A: C. Fats and oils containing up to 60% by weight, SFC at 25 ° C. is 20 to 85%, and SFC at 35 ° C. is 3 to 15%, emulsifier A: HLB is 12 to 18, and saturated fatty acids C 16 to C 18 are totaled. Polysolvate containing 90 to 100% by weight of total fatty acid, emulsifier B: Polyglycerin fatty acid ester containing 90 to 100% by weight of saturated fatty acids having HLB of 0 to 9 and C16 to C18 in total, emulsifier. C: Distilled glyceric acid fatty acid monoester containing 90 to 100% by weight of saturated fatty acids of C 16 to C 18 in total, polysaccharide X: deacylated gellan gum, polysaccharide Y: 2% aqueous solution. Hydroxypropylmethylcellulose) having a viscosity at 20 ° C. of 20-110 mPa · s).

本発明に従えば、常温販売が容易にできるにもかかわらず、高オーバーランで、保形性及び離水耐性を有し、口溶けに問題がない甘さ控えめのホイップドクリーム、及びその原料となる起泡性水中油型乳化油脂組成物を提供することができる。 According to the present invention, a whipped cream having high overrun, shape retention and water separation resistance, and having no problem of melting in the mouth, and a low-sweetness whipped cream, which can be easily sold at room temperature, and a raw material thereof. A foamable oil-in-water emulsified oil / fat composition can be provided.

以下、本発明につき、さらに詳細に説明する。本発明の起泡性水中油型乳化油脂組成物は、油相と水相からなる水中油型の乳化物で起泡性を有し、特定の油脂、水分、糖類、ソルビン酸カリウム、タンパク質、乳化剤、多糖類及びカルシウムを有し、油滴のメジアン径やpHが特定範囲である。 Hereinafter, the present invention will be described in more detail. The foamable oil-in-water emulsified oil / fat composition of the present invention is an oil-in-water emulsion composed of an oil phase and an aqueous phase and has a foaming property. It has emulsifiers, polysaccharides and calcium, and the median diameter and pH of oil droplets are in a specific range.

起泡性水中油型乳化油脂組成物全体中には、油脂が15~40重量%含まれることが好ましい。20~40重量%がより好ましく、20~35重量%が更に好ましい。15重量%より少ないと、常温販売に十分な保形性が得られない場合があり、40重量%より多いと口溶けが問題になるほど悪くなる場合がある。そして前記油脂としては、少なくとも油脂Aを含む。 It is preferable that the foamable oil-in-water emulsified oil / fat composition contains 15 to 40% by weight of the oil / fat. 20 to 40% by weight is more preferable, and 20 to 35% by weight is further preferable. If it is less than 15% by weight, sufficient shape retention may not be obtained for normal temperature sales, and if it is more than 40% by weight, melting in the mouth may become a problem. The fats and oils include at least fats and oils A.

前記油脂Aは、C12以下の飽和脂肪酸を構成脂肪酸全体中50~60重量%含み、更に25℃のSFCが20~85%であり、50~85%が好ましく、60~85%がより好ましく、且つ35℃のSFCが3~15%であり、3~12%が好ましい。25℃のSFCが20%より低いと常温販売に十分な保形性や離水耐性が得られない場合があり、85%より高いと口溶けが問題になるほど悪くなる場合がある。また、35℃のSFCが3%より低いと常温販売に十分な保形性や離水耐性が得られない場合があり、15%より高いと口溶けが問題になるほど悪くなる場合がある。ここで、SFCの測定は、IUPAC 2.150(a)に準拠して行う。また構成脂肪酸の測定は、FID恒温ガスクロマトグラフ法により行う。FID恒温ガスクロマトグラフ法は、社団法人日本油化学協会編「基準油脂分析試験法」(発行年:1996年)の「2.4.2.1 脂肪酸組成」に記載された方法に準拠して行う。 The fat A contains 50 to 60% by weight of saturated fatty acids of C12 or less in the total constituent fatty acids, and the SFC at 25 ° C. is 20 to 85%, preferably 50 to 85%, and more preferably 60 to 85%. Moreover, the SFC at 35 ° C. is 3 to 15%, preferably 3 to 12%. If the SFC at 25 ° C is lower than 20%, sufficient shape retention and water separation resistance may not be obtained for normal temperature sales, and if it is higher than 85%, melting in the mouth may become a problem. Further, if the SFC at 35 ° C. is lower than 3%, sufficient shape retention and water separation resistance may not be obtained for normal temperature sales, and if it is higher than 15%, melting in the mouth may become a problem. Here, the measurement of SFC is performed according to IUPAC 2.150 (a). The constituent fatty acids are measured by the FID constant temperature gas chromatograph method. The FID constant temperature gas chromatograph method is performed in accordance with the method described in "2.4.2.1 Fatty Acid Composition" of "Standard Oil and Fat Analysis Test Method" (published year: 1996) edited by Japan Oil Chemistry Association. ..

前記油脂Aの含有量は、起泡性水中油型乳化油脂組成物に含まれる油脂全体中48~100重量%が好ましく、48~90重量%がより好ましく、60~80重量%が更に好ましく、60~70重量%が特に好ましい。48重量%より少ないと、常温販売に十分な保形性や離水耐性が得られない場合がある。 The content of the oil / fat A is preferably 48 to 100% by weight, more preferably 48 to 90% by weight, still more preferably 60 to 80% by weight, based on the total amount of the oil / fat contained in the foamable oil-in-water emulsified oil / fat composition. 60-70% by weight is particularly preferable. If it is less than 48% by weight, sufficient shape retention and water separation resistance may not be obtained for normal temperature sales.

前記油脂には、油脂A以外にも、本発明の効果を阻害しない範囲において他の食用油脂を含んでも良い。そのような他の食用油脂としては、ホイップドクリームに用いられ得るものであれば特に限定はなく、例えば、パーム油、ヤシ油、菜種油、大豆油、サフラワー油、コーン油、米油、綿実油などの植物由来の油脂や乳脂肪などの動物由来の油脂、および、これらの油脂の分別油、極度硬化油、エステル交換油や、それらの混合油などが挙げられる。口溶けを良好にする観点からはヤシ油、パーム核油などが好ましい。 In addition to the fat and oil A, the fat and oil may contain other edible fats and oils as long as the effects of the present invention are not impaired. Such other edible oils and fats are not particularly limited as long as they can be used for whipped cream, and for example, palm oil, palm oil, rapeseed oil, soybean oil, safflower oil, corn oil, rice oil and cottonseed oil. Examples thereof include oils and fats derived from plants such as oils and fats derived from animals such as milk fats, oils separated from these oils and fats, extremely hardened oils, ester exchange oils, and mixed oils thereof. From the viewpoint of improving melting in the mouth, coconut oil, palm kernel oil and the like are preferable.

起泡性水中油型乳化油脂組成物全体中には、水分を36~57重量%含むことが好ましく、40~55重量%がより好ましく、45~55重量%がさらに好ましい。36重量%より少ないと、乳化安定性が悪くなる場合があり、57重量%より多いと常温販売に十分な保形性や離水耐性、静菌作用が弱くなり過ぎる場合がある。本発明において、静菌作用とは、一般生菌の増殖を抑制する作用のことである。 The foamable oil-in-water emulsified oil / fat composition preferably contains 36 to 57% by weight, more preferably 40 to 55% by weight, still more preferably 45 to 55% by weight. If it is less than 36% by weight, the emulsification stability may be deteriorated, and if it is more than 57% by weight, the shape retention property, water separation resistance and bacteriostatic action sufficient for normal temperature sales may be too weak. In the present invention, the bacteriostatic action is an action of suppressing the growth of general viable bacteria.

前記糖類としては、例えば、上白糖、三温糖、グラニュー糖、ざらめ糖、加工糖、液糖などの砂糖類、水あめ、ぶどう糖、異性化糖、果糖、麦芽糖、乳糖などの糖類、還元水あめ、還元麦芽糖水あめなどの糖アルコール類などが例示でき、それらの群より選ばれる少なくとも1種を用いることができる。 Examples of the saccharides include sugars such as white sugar, warm sugar, granulated sugar, grain sugar, processed sugar and liquid sugar, high fructose corn syrup, glucose, isomerized sugar, fructose, maltose and lactose, and reduced water candy. , Sugar alcohols such as reduced maltose sugar syrup can be exemplified, and at least one selected from those groups can be used.

前記糖類の含有量は、起泡性水中油型乳化油脂組成物全体中に乾燥重量で17~23重量%が好ましく、20~23重量%がより好ましい。17重量%より少ないと、甘さが足りなかったり、常温販売に十分な保形性や離水耐性が得られなかったり、静菌作用が弱くなり過ぎる場合がある。23重量%より多いと、甘過ぎる場合がある。 The content of the saccharide is preferably 17 to 23% by weight, more preferably 20 to 23% by weight, by weight in the entire foamable oil-in-water emulsified oil / fat composition. If it is less than 17% by weight, the sweetness may be insufficient, the shape retention and water separation resistance sufficient for normal temperature sales may not be obtained, and the bacteriostatic effect may be too weak. If it is more than 23% by weight, it may be too sweet.

前記ソルビン酸カリウムは、ソルビン酸のカリウム塩である。その含有量は、前記起泡性水中油型乳化油脂組成物全体中0.01~0.25重量%であることが好ましく、0.05~0.15重量%がより好ましく、0.07~0.12重量%がさらに好ましい。ソルビン酸カリウムの含有量が0.01重量%より少ないと、静菌作用が弱くなり過ぎ常温販売に耐えない場合があり、0.25重量%より多いと、風味が悪くなる場合がある。 The potassium sorbate is a potassium salt of sorbic acid. The content thereof is preferably 0.01 to 0.25% by weight, more preferably 0.05 to 0.15% by weight, and 0.07 to 0.07 to the total content of the foamable oil-in-water emulsified oil / fat composition. 0.12% by weight is more preferable. If the content of potassium sorbate is less than 0.01% by weight, the bacteriostatic action may be too weak to withstand normal temperature sales, and if it is more than 0.25% by weight, the flavor may be deteriorated.

また、前記ソルビン酸カリウムの静菌作用をより大きくするには、前記起泡性水中油型乳化油脂組成物のpHを3~6にすることが好ましく、風味の観点を加味すると4~5がより好ましい。本発明において、pHの測定は、ガラス電極法で測定可能なpH計で行えば良い。 Further, in order to further increase the bacteriostatic effect of the potassium sorbate, it is preferable to set the pH of the foamable oil-in-water emulsified oil / fat composition to 3 to 6, and from the viewpoint of flavor, 4 to 5 is preferable. More preferred. In the present invention, the pH may be measured by a pH meter that can be measured by the glass electrode method.

前記タンパク質としては、カゼインタンパク、ホエイタンパク、大豆タンパク、エンドウタンパクなどが例示でき、それらの群より選ばれる少なくとも1種を用いることができる。風味の良さと耐酸性の観点からは、ホエイタンパクを用いることが好ましい。 Examples of the protein include casein protein, whey protein, soybean protein, pea protein and the like, and at least one selected from the group thereof can be used. From the viewpoint of good flavor and acid resistance, it is preferable to use whey protein.

前記タンパク質の含有量は、起泡性水中油型乳化油脂組成物全体中0.048~0.8重量%が好ましく、0.1~0.5重量%がより好ましく、0.15~0.4重量%が更に好ましい。0.048重量%より少なければ常温販売に十分な離水耐性が得られない場合や、ホイップドクリームの内層のキメが悪くなる場合があり、0.8重量%より多いとオーバーランが高くならない場合がある。 The content of the protein is preferably 0.048 to 0.8% by weight, more preferably 0.1 to 0.5% by weight, and 0.15 to 0% by weight in the whole foamable oil-in-water emulsified oil / fat composition. 4% by weight is more preferable. If it is less than 0.048% by weight, sufficient water separation resistance may not be obtained for normal temperature sales, or the texture of the inner layer of whipped cream may deteriorate, and if it is more than 0.8% by weight, overrun may not increase. There is.

前記乳化剤としては、乳化剤A、乳化剤B、乳化剤Cの3種類を含み、それぞれ以下の通りである。 The emulsifier includes three types of emulsifier A, emulsifier B, and emulsifier C, and each is as follows.

前記乳化剤Aは、HLBが12~18であり、14~16が好ましく、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリソルベートであり、モノステアリン酸ポリオキシエチレンソルビタンが好ましい。 The emulsifier A is a polysorbate having an HLB of 12 to 18, preferably 14 to 16, and containing 90 to 100% by weight of the total saturated fatty acids of C 16 to C 18 in the total constituent fatty acids, and is a polyoxymonostearate. Ethylene sorbitan is preferred.

前記乳化剤Aは水相に添加され、その含有量は、起泡性水中油型乳化油脂組成物全体中、0.3~0.5重量%が好ましく、0.35~0.5重量%がより好ましく、0.4~0.5重量%が更に好ましい。0.3重量%より少ないと、オーバーランが高くならない場合がある。0.5重量%より多いと頭打ちになる本発明の効果があったり、口溶けが問題になるほど悪くなったり、風味が悪くなる場合がある。 The emulsifier A is added to the aqueous phase, and the content thereof is preferably 0.3 to 0.5% by weight, preferably 0.35 to 0.5% by weight, based on the entire foamable oil-in-water emulsified oil / fat composition. More preferably, 0.4 to 0.5% by weight is further preferable. If it is less than 0.3% by weight, the overrun may not be high. If it is more than 0.5% by weight, the effect of the present invention may reach a plateau, it may be so bad that melting in the mouth becomes a problem, or the flavor may be bad.

前記乳化剤Bは、HLBが0~9であり、好ましくは2~9、より好ましくは3~9、更に好ましくは5~9であり、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリグリセリン脂肪酸エステルであり、具体的にはその中でもヘキサグリセリントリステアリン酸エステル、ヘキサグリセリンペンタステアリン酸エステル、テトラグリセリンモノステアリン酸エステル、テトラグリセリントリステアリン酸エステル、テトラグリセリンペンタステアリン酸エステルが好ましく、それらの群より選ばれる少なくとも1種を用いることができる。 The emulsifier B has an HLB of 0 to 9, preferably 2 to 9, more preferably 3 to 9, still more preferably 5 to 9, and is composed of a total of saturated esters of C 16 to C 18 as a whole. It is a polyglycerin fatty acid ester containing 90 to 100% by weight, and specifically, among them, hexaglycerin tristearic acid ester, hexaglycerin pentastearic acid ester, tetraglycerin monostearic acid ester, tetraglycerin tristearic acid ester, tetraglycerin. Pentastearate is preferred, and at least one selected from the group can be used.

前記乳化剤Bは油相に添加され、その含有量は、起泡性水中油型乳化油脂組成物全体中、0.1~0.25重量%が好ましく、0.13~0.22重量%がより好ましく、0.15~0.22重量%が更に好ましい。0.1重量%より少ないとオーバーランが高くならない場合があり、0.25重量%より多いと常温販売に十分な保形性が得られない場合がある。 The emulsifier B is added to the oil phase, and the content thereof is preferably 0.1 to 0.25% by weight, preferably 0.13 to 0.22% by weight, based on the entire foamable oil-in-water emulsified oil / fat composition. More preferably, 0.15 to 0.22% by weight is further preferable. If it is less than 0.1% by weight, the overrun may not be high, and if it is more than 0.25% by weight, sufficient shape retention may not be obtained for normal temperature sales.

前記乳化剤Cは、C16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含む、蒸留されたグリセリン脂肪酸モノエステル(モノグリセライド)であり、HLBは概ね4前後となる。乳化剤Cとしてはグリセリンモノステアレートが好ましい。ここで構成脂肪酸の測定は、FID恒温ガスクロマトグラフ法により行う。FID恒温ガスクロマトグラフ法は、社団法人日本油化学協会編「基準油脂分析試験法」(発行年:1996年)の「2.4.2.1 脂肪酸組成」に記載された方法に準拠して行う。 The emulsifier C is a distilled glycerin fatty acid monoester (monoglyceride) containing 90 to 100% by weight of the total constituent fatty acids of saturated fatty acids C 16 to C 18 , and the HLB is about 4. As the emulsifier C, glycerin monostearate is preferable. Here, the constituent fatty acids are measured by the FID constant temperature gas chromatograph method. The FID constant temperature gas chromatograph method is performed in accordance with the method described in "2.4.2.1 Fatty Acid Composition" of "Standard Oil and Fat Analysis Test Method" (published year: 1996) edited by Japan Oil Chemistry Association. ..

前記乳化剤Cは油相に添加され、その含有量は、起泡性水中油型乳化油脂組成物全体中0.1~0.25重量%が好ましく、0.13~0.22重量%がより好ましく、0.15~0.22重量%が更に好ましい。0.1重量%より少ないとオーバーランが高くならない場合があり、0.25重量%より多いと本発明の効果によっては頭打ちになったり、常温販売に十分な保形性が得られない場合がある。 The emulsifier C is added to the oil phase, and the content thereof is preferably 0.1 to 0.25% by weight, more preferably 0.13 to 0.22% by weight, based on the total amount of the foamable oil-in-water emulsified oil / fat composition. It is preferable, and more preferably 0.15 to 0.22% by weight. If it is less than 0.1% by weight, the overrun may not be high, and if it is more than 0.25% by weight, it may reach a plateau depending on the effect of the present invention, or sufficient shape retention may not be obtained for normal temperature sales. be.

前記乳化剤B/前記乳化剤A(重量比)は、0.2~0.67が好ましく、0.26~0.57がより好ましい。該比が0.2より小さいとオーバーランが高くならない場合があり、0.67より大きいと常温販売に十分な保形性が得られない場合がある。 The emulsifier B / emulsifier A (weight ratio) is preferably 0.2 to 0.67, more preferably 0.26 to 0.57. If the ratio is smaller than 0.2, the overrun may not be high, and if it is larger than 0.67, sufficient shape retention for normal temperature sales may not be obtained.

また、乳化剤C/(乳化剤A+乳化剤B)(重量比)は、0.14~0.5であることが好ましく、0.18~0.42がより好ましい。該比が0.14より小さいとオーバーランが高くならない場合があり、0.5より大きいと常温販売に十分な保形性が得られない場合がある。 The emulsifier C / (emulsifier A + emulsifier B) (weight ratio) is preferably 0.14 to 0.5, more preferably 0.18 to 0.42. If the ratio is less than 0.14, the overrun may not be high, and if it is more than 0.5, sufficient shape retention for normal temperature sales may not be obtained.

さらには、オーバーランを高くする観点から、前記起泡性水中油型乳化油脂組成物中の前記乳化剤A、前記乳化剤B及び前記乳化剤Cの混合物のHLB(加重平均)が、9.5~12.9であることが好ましく、10~12がより好ましい。 Further, from the viewpoint of increasing overrun, the HLB (weighted average) of the mixture of the emulsifier A, the emulsifier B and the emulsifier C in the foamable oil-in-water emulsified oil / fat composition is 9.5 to 12. It is preferably 9.9, more preferably 10-12.

前記多糖類としては、多糖類X、多糖類Yの2種類を含み、それぞれ以下の通りである。 The polysaccharides include two types, polysaccharide X and polysaccharide Y, and are as follows.

前記多糖類Xは、アシル基が除去された脱アシル型ジェランガムのことである。前記多糖類Xは水相に添加され、その含有量は、起泡性水中油型乳化油脂組成物全体中0.01~0.4重量%が好ましく、0.03~0.3重量%がより好ましく、0.03~0.2重量%が更に好ましく、0.05~0.15重量%が特に好ましい。0.01重量%より少なければ常温販売に十分な離水耐性が得られない場合があり、0.4重量%より多いとオーバーランが高くならない場合がある。 The polysaccharide X is a deacylated gellan gum from which an acyl group has been removed. The polysaccharide X is added to the aqueous phase, and the content thereof is preferably 0.01 to 0.4% by weight, preferably 0.03 to 0.3% by weight, based on the total amount of the foamable oil-in-water emulsified oil / fat composition. More preferably, 0.03 to 0.2% by weight is further preferable, and 0.05 to 0.15% by weight is particularly preferable. If it is less than 0.01% by weight, sufficient water separation resistance may not be obtained for normal temperature sales, and if it is more than 0.4% by weight, overrun may not be high.

前記多糖類Yは、2%水溶液の20℃での粘度が20~110mPa・sのヒドロキシプロピルメチルセルロース(略称:HPMC)であり、該粘度は20~90mPa・sが好ましく、30~80mPa・sがより好ましい。ここで前記粘度は、B型粘度計(TOKIMEC INC.製)を用い測定することができる。 The polysaccharide Y is hydroxypropylmethyl cellulose (abbreviation: HPMC) having a viscosity of a 2% aqueous solution at 20 ° C. of 20 to 110 mPa · s, preferably 20 to 90 mPa · s, preferably 30 to 80 mPa · s. More preferred. Here, the viscosity can be measured using a B-type viscometer (manufactured by TOKIMEC INC.).

前記多糖類Yは水相に添加され、その含有量は、起泡性水中油型乳化油脂組成物全体中0.1~0.3重量%が好ましく、0.13~0.3重量%がより好ましく、0.15~0.3重量%が更に好ましく、0.15~0.25重量%が特に好ましい。0.1重量%より少なければ常温販売に十分な離水耐性が得られない場合があり、0.3重量%より多いと口溶けが問題になるほど悪くなる場合がある。 The polysaccharide Y is added to the aqueous phase, and the content thereof is preferably 0.1 to 0.3% by weight, preferably 0.13 to 0.3% by weight, based on the total amount of the foamable oil-in-water emulsified oil / fat composition. More preferably, 0.15 to 0.3% by weight is further preferable, and 0.15 to 0.25% by weight is particularly preferable. If it is less than 0.1% by weight, sufficient water separation resistance may not be obtained for normal temperature sales, and if it is more than 0.3% by weight, melting in the mouth may become a problem.

そして、多糖類Y/多糖類X(重量比)は、0.25~30であることが好ましく、0.75~10がより好ましく、1.8~8が更に好ましく、1.8~5が特に好ましい。該比が0.25より小さいと常温販売に十分な保形性が得られない場合があり、30より大きいとオーバーランが高くならない場合がある。 The polysaccharide Y / polysaccharide X (weight ratio) is preferably 0.25 to 30, more preferably 0.75 to 10, further preferably 1.8 to 8, and preferably 1.8 to 5. Especially preferable. If the ratio is less than 0.25, sufficient shape retention may not be obtained for normal temperature sales, and if it is larger than 30, overrun may not be high.

前記カルシウムは、供給源として生乳や、牛乳、脱脂乳、脱脂粉乳、全脂粉乳、バターミルク、バターミルクパウダー、脱脂濃縮乳、全脂濃縮乳、加糖練乳、無糖練乳、クリーム、バター、チーズ、ホエイパウダー、ホエイパーミエイトパウダー、ホエイタンパク、カゼインタンパク、乳清ミネラルなどのカルシウムを含有する生乳由来の乳加工品、炭酸カルシウム、乳酸カルシウム、塩化カルシウム、硫酸カルシウムなどのカルシウム塩などが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。風味の観点からは、特にバターミルクパウダー、ホエイパーミエイトパウダー、ホエイタンパクを用いることが好ましい。 The calcium can be supplied from raw milk, milk, skim milk, skim milk powder, whole fat powder, butter milk, butter milk powder, skim concentrated milk, full fat concentrated milk, sweetened milk, sugar-free milk, cream, butter, cheese. , Whey powder, whey permeate powder, whey protein, casein protein, processed milk products derived from raw milk containing calcium such as milky minerals, calcium salts such as calcium carbonate, calcium lactate, calcium chloride, calcium sulfate, etc. At least one selected from these groups can be used. From the viewpoint of flavor, it is particularly preferable to use buttermilk powder, whey permeate powder, and whey protein.

前記カルシウムは水相に添加され、その含有量は、起泡性水中油型乳化油脂組成物全体中2~75ppmが好ましく、20~70ppmがより好ましい。2ppmより少ないと常温販売に十分な保形性が得られない場合があり、75ppmより多いとオーバーランが高くならない場合がある。 The calcium is added to the aqueous phase, and the content thereof is preferably 2 to 75 ppm, more preferably 20 to 70 ppm in the entire foamable oil-in-water emulsified oil / fat composition. If it is less than 2 ppm, sufficient shape retention may not be obtained for normal temperature sales, and if it is more than 75 ppm, overrun may not be high.

本発明の起泡性水中油型乳化油脂組成物は、本発明の効果を損なわない範囲で、必要に応じて、前述したもの以外の他の乳化剤、増粘剤、乳原料、呈味剤、日持ち向上剤、着色料、香料、塩類、ビタミン類、ミネラル類、酸化防止剤、その他の食品成分を含有してもよい。 The foamable oil-in-water emulsified oil / fat composition of the present invention is, if necessary, an emulsifier, a thickener, a dairy raw material, a taste agent other than those described above, as long as the effect of the present invention is not impaired. It may contain shelf life improvers, colorants, flavors, salts, vitamins, minerals, antioxidants and other food ingredients.

前記他の乳化剤としては、乳化剤Aを除くポリソルベート、乳化剤Bを除くポリグリセリン脂肪酸エステル、乳化剤Cを除くグリセリン酸脂肪酸モノエステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル等の合成乳化剤などが挙げられる。これらの群より選ばれる少なくとも1種を用いることができる。 Examples of the other emulsifier include polysorbates excluding emulsifier A, polyglycerin fatty acid esters excluding emulsifier B, glyceric acid fatty acid monoesters excluding emulsifier C, sucrose fatty acid esters, sorbitan fatty acid esters, synthetic emulsifiers such as propylene glycol fatty acid esters, and the like. Can be mentioned. At least one selected from these groups can be used.

前記増粘剤としては、例えば、アシル基を有するジェランガム、グアガム、キサンタンガム、寒天、ペクチン、アルギン酸ナトリウム、カラギーナン、ローカストビーンガム、アラビアガム、カルボキシメチルセルロース、乳化剤Yに該当しないヒドロキシメチルセルロース、結晶セルロース、微結晶セルロース、澱粉、デキストリン等が挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the thickener include gellan gum having an acyl group, guar gum, xanthan gum, agar, pectin, sodium alginate, carrageenan, locust bean gum, arabic gum, carboxymethyl cellulose, hydroxymethyl cellulose not corresponding to emulsifier Y, crystalline cellulose, and fine. Crystalline cellulose, starch, dextrin and the like can be mentioned, and at least one selected from these groups can be used.

前記乳原料としては、前記カルシウムの供給源として挙げた生乳や、カルシウムを含有する生乳由来の乳加工品を用いてもよく、さらに、UF膜やイオン交換樹脂処理等により蛋白質を分離、分画したものや、カゼインナトリウムやカゼインカリウムのような乳蛋白質の塩類等などが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 As the milk raw material, the raw milk mentioned as the source of calcium or a processed milk product derived from raw milk containing calcium may be used, and further, the protein is separated and fractionated by a UF film, ion exchange resin treatment, or the like. , And salts of milk proteins such as casein sodium and casein potassium, and the like, and at least one selected from these groups can be used.

前記呈味剤としては、前記乳原料を酵素分解、加熱、分離、分画等をしたもの等などが挙げられ、これらの群より少なくとも1種を使用することができる。 Examples of the taste agent include those obtained by enzymatically decomposing, heating, separating, fractionating, etc. the milk raw material, and at least one of these groups can be used.

前記日持ち向上剤としては、グリシン、酢酸ナトリウム、リゾチーム等、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the shelf life improver include those that can be used for food purposes such as glycine, sodium acetate, and lysozyme, and at least one selected from these groups can be used.

前記着色料としては、天然成分や人工成分に関わらず、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the colorant include those that can be used for food purposes regardless of natural ingredients or artificial ingredients, and at least one selected from these groups can be used.

前記香料としては、天然成分や人工成分に関わらず、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the flavoring include those that can be used for food purposes regardless of natural ingredients or artificial ingredients, and at least one selected from these groups can be used.

前記塩類としては、一般に食品に用いられている塩類であれば特に制限はなく、例えば、塩化ナトリウム、クエン酸ナトリウム、クエン酸カリウム、乳酸ナトリウム、水酸化ナトリウム、炭酸ナトリウム、炭酸カリウム、炭酸アンモニウム、炭酸水素ナトリウム、炭酸水素カリウム、リン酸3ナトリウム、リン酸水素2ナトリウム等などが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 The salts are not particularly limited as long as they are salts generally used in foods, and for example, sodium chloride, sodium citrate, potassium citrate, sodium lactate, sodium hydroxide, sodium carbonate, potassium carbonate, ammonium carbonate, etc. Examples thereof include sodium hydrogen carbonate, potassium hydrogen carbonate, trisodium phosphate, disodium hydrogen phosphate and the like, and at least one selected from these groups can be used.

前記ビタミン類としては、ビタミンA、ビタミンB群、ビタミンC、ビタミンD、ビタミンE、ビタミンKを主成分とする食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the vitamins include those that can be used for foods containing vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, and vitamin K as main components, and at least one selected from these groups is used. can do.

前記ミネラル類としては、亜鉛、カリウム、クロム、セレン、鉄、銅、ナトリウム、マグネシウム、マンガン、モリブデン、ヨウ素、リン等などが挙げられ、これらの成分を含む食品及び/又は食品添加物に分類されるものを少なくとも1種を使用することができる。 Examples of the minerals include zinc, potassium, chromium, selenium, iron, copper, sodium, magnesium, manganese, molybdenum, iodine, phosphorus and the like, and are classified into foods and / or food additives containing these components. At least one of them can be used.

前記酸化防止剤としては、ビタミンE、ローズマリー抽出物等の抗酸化成分を主成分とする食品用途として使用できるもの等などが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the antioxidant include those that can be used for foods containing antioxidant components such as vitamin E and rosemary extract as main components, and at least one selected from these groups may be used. can.

前記起泡性水中油型乳化油脂組成物の油滴のメジアン径は、0.1~1.2μmであることが好ましく、0.3~1μmがより好ましく、0.5~0.9μmが更に好ましい。0.1μmより小さいと、製造が困難な場合があり、1.2μmより大きいと常温販売に十分な保形性が得られない場合がある。ここで油滴のメジアン径は、レーザ回折/散乱式粒度分布測定装置LA-960V2(株式会社掘場製作所)で測定した、体積基準での積算分布曲線の50%に相当する粒子径である。 The median diameter of the oil droplets of the foamable oil-in-water emulsified oil / fat composition is preferably 0.1 to 1.2 μm, more preferably 0.3 to 1 μm, and further preferably 0.5 to 0.9 μm. preferable. If it is smaller than 0.1 μm, it may be difficult to manufacture, and if it is larger than 1.2 μm, sufficient shape retention for normal temperature sales may not be obtained. Here, the median diameter of the oil droplet is a particle diameter corresponding to 50% of the integrated distribution curve on a volume basis measured by a laser diffraction / scattering type particle size distribution measuring device LA-960V2 (Doriba Seisakusho Co., Ltd.).

また、常温販売における静菌作用の観点から、本発明の起泡性水中油型乳化油脂組成物の水分活性(Aw)は0.9~0.96の範囲であることが好ましい。Awは0.9~0.95の範囲であることがより好ましく、0.91~0.94の範囲であることが更に好ましい。水分活性が0.9より低いと結果的に糖類を減らすことになって風味が悪化する場合があり、0.96より高いと静菌作用が弱くなり過ぎ常温販売に耐えない場合がある。Awを上記の範囲とするには、水相中の糖類の濃度や塩濃度を高めれば良い。ここで前記水分活性は、水分活性測定装置(METER社製)を用い測定することができる。 Further, from the viewpoint of bacteriostatic action in normal temperature sales, the water activity (Aw) of the foamable oil-in-water emulsified oil / fat composition of the present invention is preferably in the range of 0.9 to 0.96. Aw is more preferably in the range of 0.9 to 0.95, and even more preferably in the range of 0.91 to 0.94. If the water activity is lower than 0.9, the sugar may be reduced as a result and the flavor may be deteriorated, and if it is higher than 0.96, the bacteriostatic effect may be too weak to withstand normal temperature sales. In order to keep Aw in the above range, the concentration of saccharides and the salt concentration in the aqueous phase may be increased. Here, the water activity can be measured using a water activity measuring device (manufactured by METER).

本発明の起泡性水中油型乳化油脂組成物および該起泡性水中油型乳化油脂組成物を用いたホイップドクリームの製造方法を以下に例示する。まずは、水に、起泡性水中油型乳化油脂組成物全体中、乳化剤Aを0.3~0.5重量%、糖類を20~35重量%、タンパク質を0.048~0.8重量%、多糖類Xを0.01~0.4重量%、多糖類Yを0.1~0.3重量%、カルシウムを2.0~75ppm含み、且つ多糖類Y/多糖類X(重量比)が0.25~30となるよう各々を溶解した水相部を作製する。 The foaming oil-in-water emulsified oil / fat composition of the present invention and the method for producing whipped cream using the foaming oil-in-water emulsified oil / fat composition are exemplified below. First, in water, the emulsifier A is 0.3 to 0.5% by weight, the saccharide is 20 to 35% by weight, and the protein is 0.048 to 0.8% by weight in the whole foamable oil-in-water emulsified oil / fat composition. , Polysaccharide X is 0.01 to 0.4% by weight, polysaccharide Y is 0.1 to 0.3% by weight, calcium is 2.0 to 75 ppm, and polysaccharide Y / polysaccharide X (weight ratio). An aqueous phase portion in which each is dissolved is prepared so that the value is 0.25 to 30.

次いで、油脂に、起泡性水中油型乳化油脂組成物全体中、乳化剤Bを0.1~0.25重量%、乳化剤Cを0.1~0.25重量%含み、乳化剤B/乳化剤A(重量比)が0.2~0.67且つ乳化剤C/(乳化剤A+乳化剤B)(重量比)が0.14~0.5となるように各々を溶解した油相部を作製し、それを水相部に添加して予備乳化し、好ましくは、1段目5~52MPa/2段目3~12MPaの圧力、より好ましくは、1段目20~25MPa/2段目3~5MPaの圧力で均質化した後に、常法に従って殺菌処理することを特徴とする。 Next, the fat and oil contains 0.1 to 0.25% by weight of emulsifier B and 0.1 to 0.25% by weight of emulsifier C in the entire foamable oil-in-water emulsified fat and oil composition, and emulsifier B / emulsifier A. An oil phase portion in which each was dissolved was prepared so that the (weight ratio) was 0.2 to 0.67 and the emulsifier C / (emulsifier A + emulsifier B) (weight ratio) was 0.14 to 0.5. Is pre-emulsified by adding to the aqueous phase portion, preferably the pressure of the first stage is 5 to 52 MPa / the pressure of the second stage is 3 to 12 MPa, and more preferably the pressure of the first stage is 20 to 25 MPa / the pressure of the second stage is 3 to 5 MPa. It is characterized by being sterilized according to a conventional method after being homogenized with.

そして、得られた起泡性水中油型乳化油脂組成物を、オープン式ホイッパーや密閉式連続ホイップマシンを用いて、サンド、ナッペ、フィリング、又はトッピング等の使用目的に沿った適度な硬さに到達するまでホイップすることで、本発明のホイップドクリームが得られる。 Then, the obtained foamable oil-in-water emulsified oil / fat composition is subjected to an appropriate hardness according to the purpose of use such as sand, nappe, filling, or topping by using an open type whipper or a closed type continuous whipping machine. By whipping until it reaches, the whipped cream of the present invention can be obtained.

本発明の起泡性水中油型乳化油脂組成物を、オーバーランが200~350%になるまでホイップして得られるホイップドクリームは、常温販売が容易にでき、保形性及び離水耐性を有し、口溶けに問題がない。 The whipped cream obtained by whipping the foamable oil-in-water emulsified oil / fat composition of the present invention until the overrun reaches 200 to 350% can be easily sold at room temperature, and has shape retention and water separation resistance. However, there is no problem with melting in the mouth.

そして、前記ホイップドクリームをサンド、ナッペ、フィリング、又はトッピングすることで様々な食品を提供することができる。 Then, various foods can be provided by sandwiching, napping, filling, or topping the whipped cream.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 Examples are shown below and the present invention will be described in more detail, but the present invention is not limited to these examples. In the examples, "part" and "%" are based on weight.

<実施例、比較例及び参考例で使用した原料>
1)(株)カネカ製「パーム核極度硬化油」(C12以下の飽和脂肪酸含有量:53.0重量%、C12:46.4重量%、25℃におけるSFC:69.2%、35℃のSFC:11.9%)
2)(株)カネカ製「パーム極度硬化油」(C16~C22の飽和脂肪酸含有量:96.8重量%、ヨウ素価:0.3)
3)(株)カネカ製「パーム核油」(C12以下の飽和脂肪酸:51.2重量%、25℃におけるSFC:17.6%、35℃のSFC:0%)
4)阪本薬品工業(株)製テトラグリセリンモノステアリン酸エステル「SYグリスターMS-3S」(C16~C18の飽和脂肪酸含有量:98.3重量%、HLB:8.4)
5)理研ビタミン(株)製モノグリセリンステアリン酸エステル「エマルジーMS」(C16~C18の飽和脂肪酸含有量:96.1重量%、HLB:4.3)
6)ADM(株)製「Yelkin TS」
7)フジ日本精糖(株)製グラニュー糖「グラニュー糖 FNGMS」(水分含量:0重量%)
8)昭和産業(株)製含水結晶ぶどう糖「昭和含水結晶ぶどう糖(CRD)」(水分含量:8.8重量%)
9)昭和産業(株)製マルトースシロップ「MR25‐50」(水分含量:24.6重量%)
10)CPケルコ社製脱アシル型ジェランガム「ケルコゲル」
11)The Dow Chemical Company社製HPMC「Methocel F50」(2%水溶液の20℃での粘度:50mPa・s)
12)花王(株)製ポリソルベート60「エマゾールS-120V」(C16~18の飽和脂肪酸含有量:90.0重量%、HLB:14.9)
13)Lactalis Ingredients社製ホエイパーミエイトパウダー「WHEY PERMEATE POWDER - Food grade」(タンパク質含有量:4.5重量%、カルシウム含有量:0.638重量%)
14)Warrnambool Cheese & Butter Factory Company Holdings Limited社製ホエイタンパク「WPC80」(タンパク質含有量:76.5重量%、カルシウム含有量:0.4重量%)
15)よつ葉乳業(株)製バターミルクパウダー「バターミルクパウダー」(タンパク質含有量:31.0重量%、カルシウム含有量:0.960重量%、乳脂肪含有量7.3重量%)
16))米山化学工業(株)製リン酸水素二ナトリウム「リン酸二ナトリウム(無水)」
17)米山化学工業(株)製リン酸三ナトリウム「リン酸三ナトリウム」
18)ナイカイ塩業(株)製食塩「ナクルN」
19)上野製薬(株)製ソルビン酸カリウム「ソルビン酸カリウム」
20)扶桑化学工業(株)製クエン酸「精製クエン酸(無水)」
21)(株)カネカ製「ヤシ極度硬化油」(C12以下の飽和脂肪酸含有量:52.6重量%、C12:41.5重量%、25℃におけるSFC:20.1%、35℃のSFC:5.1%)
22)(株)カネカ製「パーム核分別硬質部硬化油」(C12以下の飽和脂肪酸含有量:54.7重量%、C12:50.3重量%)、25℃におけるSFC:83.9%、35℃のSFC:3.9%)
23)(株)カネカ製「ヤシ油」(C12以下の飽和脂肪酸含有量:57.6重量%、C12:45.1重量%、25℃におけるSFC:1.1%、35℃のSFC:0%)
24)(株)カネカ製「パーム核分別軟質部硬化油」(C12以下の飽和脂肪酸含有量:46.7重量%、C12:40.0重量%、25℃におけるSFC:64.7%、35℃のSFC:21.0%)
25)阪本薬品工業(株)製テトラグリセリントリステアリン酸エステル「SYグリスターTS-3S」(C16~C18の飽和脂肪酸含有量:98.3重量%、HLB:4.6)
26)三栄源エフ・エフ・アイ(株)製キサンタンガム「サンエース」
27)The Dow Chemical Company製HPMC「Methocel K99」(2%水溶液の20℃での粘度:99mPa・s)
28)The Dow Chemical Company製HPMC「Methocel E19」(2%水溶液の20℃での粘度:19mPa・s)
29)The Dow Chemical Company製HPMC「Methocel F4M」(2%水溶液の20℃での粘度:4000mPa・s)
30)花王(株)製ポリソルベート80「エマゾールO-120V」(C16~C18の飽和脂肪酸含有量:5.0重量%、HLB:15.0)
31)阪本薬品工業(株)製ポリグリセリン混酸エステル「SYグリスターTHL-15」(C16~C18の飽和脂肪酸含有量:56.2重量%、HLB:3.3)
<Raw materials used in Examples, Comparative Examples and Reference Examples>
1) "Palm kernel extremely hydrogenated oil" manufactured by Kaneka Corporation (saturated fatty acid content of C 12 or less: 53.0% by weight, C 12 : 46.4% by weight, SFC at 25 ° C.: 69.2%, 35 SFC at ° C: 11.9%)
2) "Palm Extremely Hardened Oil" manufactured by Kaneka Corporation (saturated fatty acid content of C 16 to C 22 : 96.8% by weight, iodine value: 0.3)
3 ) "Palm kernel oil" manufactured by Kaneka Corporation (saturated fatty acid of C12 or less: 51.2% by weight, SFC at 25 ° C: 17.6%, SFC at 35 ° C: 0%)
4) Tetraglycerin monostearic acid ester "SY Glycer MS-3S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Saturated fatty acid content of C 16 to C 18 : 98.3% by weight, HLB: 8.4)
5) Riken Vitamin Co., Ltd. monoglycerin stearic acid ester "Emulgy MS" (saturated fatty acid content of C 16 to C 18 : 96.1% by weight, HLB: 4.3)
6) "Yelkin TS" manufactured by ADM Co., Ltd.
7) Granulated sugar "Granulated sugar FNGMS" manufactured by Fuji Nihon Seito Corporation (water content: 0% by weight)
8) Showa Sangyo Co., Ltd. Hydrous Crystal Glucose "Showa Hydrous Crystal Glucose (CRD)" (Moisture content: 8.8% by weight)
9) Maltose syrup "MR25-50" manufactured by Showa Sangyo Co., Ltd. (moisture content: 24.6% by weight)
10) CP Kelco's deacylated gellan gum "Kelcogel"
11) HPMC "Methocel F50" manufactured by The Dow Chemical Company (viscosity of 2% aqueous solution at 20 ° C: 50 mPa · s)
12) Kao Corporation Polysorbate 60 "Emazole S-120V" (Saturated fatty acid content of C16-18: 90.0% by weight, HLB: 14.9)
13) Whey Permeate Powder "WHEY PERMEATE POWDER --Food grade" manufactured by Lactalis Ingredients (protein content: 4.5% by weight, calcium content: 0.638% by weight)
14) Warrnambool Cheese & Butter Factory Company Holdings Limited whey protein "WPC80" (protein content: 76.5% by weight, calcium content: 0.4% by weight)
15) Buttermilk powder "Buttermilk powder" manufactured by Yotsuba Milk Products Co., Ltd. (protein content: 31.0% by weight, calcium content: 0.960% by weight, milk fat content 7.3% by weight)
16)) Disodium Hydrogen Phosphate "Disodium Phosphate (Anhydrous)" manufactured by Yoneyama Chemical Industry Co., Ltd.
17) Trisodium Phosphate "Trisodium Phosphate" manufactured by Yoneyama Chemical Industry Co., Ltd.
18) Naikai Salt Industries Co., Ltd. Salt "Nacle N"
19) Potassium sorbate manufactured by Ueno Fine Chemicals Industry Co., Ltd. "Potassium sorbate"
20) Citric acid manufactured by Fuso Chemical Industry Co., Ltd. "Purified citric acid (anhydrous)"
21) Kaneka Corporation "Palm Extremely Hardened Oil" (C 12 or less saturated fatty acid content: 52.6% by weight, C 12 : 41.5% by weight, SFC at 25 ° C: 20.1%, 35 ° C SFC: 5.1%)
22) Kaneka Corporation "Palm kernel fractionated hard hydrogenated oil" (saturated fatty acid content of C 12 or less: 54.7% by weight, C 12 : 50.3% by weight), SFC at 25 ° C: 83.9 %, SFC at 35 ° C: 3.9%)
23) "Palm oil" manufactured by Kaneka Corporation (saturated fatty acid content of C12 or less: 57.6 % by weight, C12 : 45.1% by weight, SFC at 25 ° C: 1.1%, SFC at 35 ° C : 0%)
24) Kaneka Corporation "Palm kernel fractionated soft part hydrogenated oil" (C 12 or less saturated fatty acid content: 46.7% by weight, C 12 : 40.0% by weight, SFC at 25 ° C: 64.7% , 35 ° C SFC: 21.0%)
25) Tetraglycerin tristearic acid ester "SY Glycer TS-3S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Saturated fatty acid content of C 16 to C 18 : 98.3% by weight, HLB: 4.6)
26) Xanthan gum "San Ace" manufactured by Saneigen FFI Co., Ltd.
27) HPMC "Methocel K99" manufactured by The Dow Chemical Company (viscosity of 2% aqueous solution at 20 ° C: 99 mPa · s)
28) HPMC "Methocel E19" manufactured by The Dow Chemical Company (viscosity of 2% aqueous solution at 20 ° C: 19 mPa · s)
29) HPMC "Methocel F4M" manufactured by The Dow Chemical Company (viscosity of 2% aqueous solution at 20 ° C: 4000 mPa · s)
30) Polysorbate 80 "Emazole O-120V" manufactured by Kao Corporation (saturated fatty acid content of C16 to C18: 5.0% by weight, HLB: 15.0)
31) Polyglycerin mixed acid ester "SY Glycer THL-15" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Saturated fatty acid content of C 16 to C 18 : 56.2% by weight, HLB: 3.3)

<保形性評価>
実施例・比較例で得られたホイップドクリームを、25℃で5日間の保存し、保存後の状態を以下の評価基準に従って評価した。
5点 保存前後の高さの保持率が95%以上であり、常温での保形性が非常に良い
4点 保存前後の高さの保持率が85%以上95%未満であり、常温での保形性が良い
3点 保存前後の高さの保持率が75%以上85%未満であり、常温での保形性に問題がない
2点 保存前後の高さの保持率が65%以上75%未満であり、常温での保形性がやや悪い
1点 保存前後の高さの保持率が65%未満であり、常温での保形性が非常に悪い
<Evaluation of shape retention>
The whipped cream obtained in Examples and Comparative Examples was stored at 25 ° C. for 5 days, and the state after storage was evaluated according to the following evaluation criteria.
The height retention rate before and after 5-point storage is 95% or more, and the shape retention at room temperature is very good. The height retention rate before and after 4-point storage is 85% or more and less than 95%, at room temperature. Good shape retention 3 points Height retention before and after storage is 75% or more and less than 85%, and there is no problem with shape retention at room temperature 2 points Height retention before and after storage is 65% or more 75 %, The shape retention at room temperature is slightly poor. 1 point The height retention rate before and after storage is less than 65%, and the shape retention at room temperature is very poor.

<離水耐性評価>
実施例・比較例で得られたホイップドクリームを、25℃で5日間保存し、保存後の状態を目視で観察して5点満点で評価した。
5点 実施例X2と比べ、常温での離水耐性が非常に高い
4点 実施例X2と比べ、常温での離水耐性が高い
3点 実施例X2と同等で、常温での離水耐性に問題がない
2点 実施例X2と比べ、常温での離水耐性がやや低く、やや問題がある
1点 実施例X2と比べ、常温での離水耐性が非常に低く、問題がある
<Evaluation of water separation resistance>
The whipped cream obtained in Examples and Comparative Examples was stored at 25 ° C. for 5 days, and the state after storage was visually observed and evaluated on a scale of 5 points.
5 points Higher water separation resistance at room temperature than Example X2 4 points Higher water separation resistance at room temperature than Example X2 3 points Same as Example X2, no problem with water separation resistance at room temperature 2 points Compared to Example X2, the water separation resistance at room temperature is slightly lower, and there is a slight problem. 1 point Compared to Example X2, the water separation resistance at room temperature is very low, and there is a problem.

<静菌作用の評価>
実施例・比較例で得られたホイップドクリームを、25℃で5日間保存し、3M PetrifilmAerobic Count Plate(AC Plate)を用いて一般生菌数を測定した。一般生菌数が1×10個/gを超えた日数を評価し、N=3で最も短い日数を評価点とした。
5点 120時間(5日間)保存後一般生菌数が1×10個/g未満
4点 96時間(4日間)保存後一般生菌数が1×10個/g未満
3点 72時間(3日間)保存後一般生菌数が1×10個/g未満
2点 48時間(2日間)保存後一般生菌数が1×10個/g未満
1点 24時間(1日間)保存後一般生菌数が1×10個/g未満
<Evaluation of bacteriostatic action>
The whipped cream obtained in Examples and Comparative Examples was stored at 25 ° C. for 5 days, and the general viable cell count was measured using a 3M Petrifilm Aerobic Count Plate (AC Plate). The number of days when the general viable cell count exceeded 1 × 10 5 cells / g was evaluated, and the shortest number of days at N = 3 was used as the evaluation point.
5 points 120 hours (5 days) general viable cell count less than 1 x 10 5 cells / g 4 points 96 hours (4 days) general viable cell count after storage 1 x 10 less than 5 cells / g 3 points 72 hours (3 days) General viable cell count after storage is 1 x 10 5 cells / g or less 2 points 48 hours (2 days) General viable cell count after storage is 1 x 10 5 cells / g or less 1 point 24 hours (1 day) General viable cell count after storage is less than 1 x 10 5 cells / g

<口どけ評価>
実施例・比較例で得られたホイップドクリームを、熟練のパネラー10人が口に含み、5点満点で評価して、その平均点を評価点とした。その際の評価基準は、以下の通りであった。
5点 実施例X3と比べ口どけが非常に良い
4点 実施例X3と比べ口どけが良い
3点 実施例X3と口どけが同等で、問題がない
2点 実施例X3と比べ口どけがやや悪い
1点 実施例X3と比べ口どけが非常に悪い
<Mouth melting evaluation>
The whipped cream obtained in Examples and Comparative Examples was put in the mouth by 10 skilled panelists and evaluated on a scale of 5 points, and the average score was used as the evaluation point. The evaluation criteria at that time were as follows.
5 points Mouth-melting is very good compared to Example X3 4 points Mouth-melting is better than Example X3 3 points Mouth-melting is equivalent to Example X3 and there is no problem 2 points Mouth-melting is slightly better than Example X3 Bad 1 point Very bad mouthfeel compared to Example X3

<甘さ評価>
実施例・比較例で得られたホイップドクリームを、熟練のパネラー10人が口に含み、5点満点で評価して、その平均点を評価点とした。その際の評価基準は、以下の通りであった。
5点 実施例X2と比べ甘さがかなり控えめである
4点 実施例X2と比べ甘さがより控えめである
3点 実施例X2と同等に甘さが控えめである
2点 実施例X2と比べ甘さがやや強い
1点 実施例X2と比べ甘さがかなり強い
<Sweetness evaluation>
The whipped cream obtained in Examples and Comparative Examples was put in the mouth by 10 skilled panelists and evaluated on a scale of 5 points, and the average score was used as the evaluation point. The evaluation criteria at that time were as follows.
5 points Sweetness is considerably less than Example X2 4 points Sweetness is more modest than Example X2 3 points Sweetness is as modest as Example X2 2 points Sweeter than Example X2 Slightly strong 1 point Sweetness is considerably stronger than Example X2

<総合評価>
A:オーバーランが300%以上350%未満、静菌作用評価が3点以上であって、且つ保形性・口溶け・離水耐性・甘さの評価が全て3.5点以上であるもの
B:オーバーランが210%以上300%未満、静菌作用評価が3点以上であって、且つ保形性・口溶け・離水耐性・甘さの評価が全て3.5点以上であるもの
C:オーバーランが200%以上350%未満、静菌作用評価が3点以上であって、保形性・口溶け・離水耐性・甘さの評価が全て3.0点以上であり、且つ3.0点以上3.5点未満が少なくとも1項目あるもの、又はオーバーランが200%以上210%未満、静菌作用評価が3点以上であって、且つ保形性・口溶け・離水耐性・甘さの評価が全て3.0点以上であるもの
D:Eの要件を満たさず、オーバーランが190%以上200%未満である、及び/又は保形性・口溶け・離水耐性・静菌作用・甘さの評価が全て2.0点以上であり、且つ2.0点以上3.0点未満が少なくとも1項目あるもの
E:オーバーランが190%未満である、及び/又は保形性・口溶け・離水耐性・静菌作用・甘さの評価のうち少なくとも1項目が2.0点未満であるもの
(実施例A1)起泡性水中油型乳化油脂組成物A1の作製
表1の配合に従い、油脂A(パーム核極度硬化油、C12以下の飽和脂肪酸含有量:53.0重量%、25℃でのSFC:69.2、35℃でのSFC:11.9)16.5重量部、パーム核油9.0重量部に、乳化剤B(テトラグリセリンモノステアリン酸エステル、C16~C18の飽和脂肪酸含有量:98.3重量%、HLB:8.4)0.20重量部、乳化剤C(モノグリセリンステアリン酸エステル、C16~C18の飽和脂肪酸含有量:96.1重量%、HLB:4.3)0.20重量部、大豆レシチン0.12重量部を添加し、65℃で溶解して油相部を作製した。
<Comprehensive evaluation>
A: Overrun is 300% or more and less than 350%, bacteriostatic action evaluation is 3 points or more, and shape retention, melting in the mouth, water separation resistance, and sweetness are all 3.5 points or more. B: Overrun is 210% or more and less than 300%, bacteriostatic action evaluation is 3 points or more, and shape retention, melting in the mouth, water separation resistance, and sweetness are all 3.5 points or more. C: Overrun 200% or more and less than 350%, bacteriostatic action evaluation is 3 points or more, shape retention, mouth melting, water separation resistance, and sweetness are all 3.0 points or more, and 3.0 points or more 3 .There is at least one item with less than 5 points, or overrun is 200% or more and less than 210%, bacteriostatic action evaluation is 3 points or more, and all evaluations of shape retention, melting in the mouth, water separation resistance, and sweetness are all. Those with a score of 3.0 or higher do not meet the requirements of D: E, and have an overrun of 190% or more and less than 200%, and / or are evaluated for shape retention, melting in the mouth, resistance to water separation, bacteriostatic action, and sweetness. All with 2.0 points or more and at least one item with 2.0 points or more and less than 3.0 points E: Overrun is less than 190% and / or shape retention, melting in the mouth, water separation resistance, static At least one item in the evaluation of bacterial action / sweetness is less than 2.0 points (Example A1) Preparation of foamable oil-in-water emulsified oil / fat composition A1 Oil / fat A (palm nucleus) according to the formulation shown in Table 1. Extremely hardened oil, saturated fatty acid content of C12 or less: 53.0% by weight, SFC at 25 ° C: 69.2 , SFC at 35 ° C: 11.9) 16.5 parts by weight, palm kernel oil 9.0 parts by weight, emulsifier B (Tetraglycerin monostearate ester, saturated fatty acid content of C 16 to C 18 : 98.3% by weight, HLB: 8.4) 0.20 parts by weight, emulsifier C (monoglycerin stearate ester, saturated of C 16 to C 18 ) Fatty acid content: 96.1% by weight, HLB: 4.3) 0.20 part by weight and 0.12 part by weight of soybean esterin were added and dissolved at 65 ° C. to prepare an oil phase part.

一方、グラニュー糖6.0重量部、ぶどう糖14.0重量部、多糖類X(脱アシル型ジェランガム)0.08重量部、多糖類Y(ヒドロキシプロピルメチルセルロース、2%水溶液の20℃での粘度:50mPa・s)0.20重量部、乳化剤A(ポリソルベート、C16~C18の飽和脂肪酸含有量:90.0重量%、HLB:14.9)0.45重量部、ホエイパーミエイトパウダー0.20重量部、ホエイタンパク0.20重量部、食塩0.15重量部、ソルビン酸カリウム0.10重量部、クエン酸0.05重量部を50℃の温水52.55重量部に溶解して水相部を作製した。 On the other hand, 6.0 parts by weight of granulated sugar, 14.0 parts by weight of grape sugar, 0.08 part by weight of polysaccharide X (deacylated gellan gum), and viscosity of polysaccharide Y (hydroxypropylmethylcellulose, 2% aqueous solution at 20 ° C.: 50 mPa · s) 0.20 parts by weight, emulsifier A (polysorbate, saturated fatty acid content of C 16 to C 18 : 90.0% by weight, HLB: 14.9) 0.45 parts by weight, whey permeate powder 0.20 parts by weight, whey An aqueous phase portion was prepared by dissolving 0.20 parts by weight of protein, 0.15 parts by weight of salt, 0.10 parts by weight of potassium sorbate, and 0.05 parts by weight of citrate in 52.55 parts by weight of warm water at 50 ° C. ..

前記水相部を撹拌しながら、そこへ前記油相部を混合して10分間予備乳化後、高圧ホモジナイザーを用いて1段目25.0MPa/2段目5.0MPaの圧力で均質化した後に、プレート式加熱機を用いて90℃まで予備加熱した後、UHT殺菌機(スチームインジェクション)を用いて140℃で4秒間殺菌処理し、90℃まで蒸発冷却後プレート式冷却機を用いて45℃まで冷却し、再び高圧ホモジナイザーを用いて1段目25.0MPa/2段目5.0MPaの圧力で均質化し、その後、プレート式冷却機で5℃まで冷却したものを容器に充填し、-18℃で3日間冷凍し、5℃の冷蔵庫で解凍し、Aw(水分活性):0.965、pH:4.9の起泡性水中油型乳化油脂組成物A1を得た。得られた起泡性水中油型乳化油脂組成物A1のメジアン径の測定を行い、それらの結果を表1にまとめた。 While stirring the aqueous phase portion, the oil phase portion is mixed there and pre-emulsified for 10 minutes, and then homogenized at a pressure of 25.0 MPa in the first stage / 5.0 MPa in the second stage using a high-pressure homogenizer. After preheating to 90 ° C using a plate-type heater, sterilize at 140 ° C for 4 seconds using a UHT sterilizer (steam injection), evaporate and cool to 90 ° C, and then use a plate-type cooler to 45 ° C. After cooling to 5 ° C. using a high-pressure homogenizer again to homogenize at a pressure of 25.0 MPa in the first stage / 5.0 MPa in the second stage, the container is filled with a plate-type cooler cooled to 5 ° C., and the container is filled with -18. The mixture was frozen at ° C. for 3 days and thawed in a refrigerator at 5 ° C. to obtain a foamable oil-in-water emulsified oil / fat composition A1 having Aw (water activity): 0.965 and pH: 4.9. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A1 was measured, and the results are summarized in Table 1.

Figure 2022080142000001
Figure 2022080142000001

(実施例A2)起泡性水中油型乳化油脂組成物A2の作製
表1に従って、油脂A:17.4重量部に変更し、パーム核油を加えずにパーム極度硬化油(C16~C22の飽和脂肪酸含有量:96.8重量%、ヨウ素価:0.3)を0.60重量部加え、グラニュー糖:10.0重量部に変更し、水の量を調整した以外は実施例A1と同様にして、Aw:0.932、pH:4.9の起泡性水中油型乳化油脂組成物A2を得た。得られた起泡性水中油型乳化油脂組成物A2のメジアン径の測定を行い、それらの結果を表1にまとめた。
(Example A2) Preparation of foamable oil-in-water emulsified oil / fat composition A2 According to Table 1, the oil / fat A: was changed to 17.4 parts by weight, and palm extremely hydrogenated oil (C 16 to C) without adding palm kernel oil. 22 Saturated fatty acid content: 96.8% by weight, iodine value: 0.3) was added by 0.60 parts by weight, changed to 10.0 parts by weight of granulated sugar, and the same as in Example A1 except that the amount of water was adjusted. Then, a foamable oil-in-water emulsified oil / fat composition A2 having Aw: 0.932 and pH: 4.9 was obtained. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A2 was measured, and the results are summarized in Table 1.

(実施例A3)起泡性水中油型乳化油脂組成物A3の作製
表1に従って、油脂A:36.5重量部に変更し、パーム核油を加えずにパーム極度硬化油を1.5重量部加え、水の量を調整した以外は実施例A1と同様にして、Aw:0.952、pH:4.9の起泡性水中油型乳化油脂組成物A3を得た。得られた起泡性水中油型乳化油脂組成物A3のメジアン径の測定を行い、それらの結果を表1にまとめた。
(Example A3) Preparation of foamable oil-in-water emulsified oil / fat composition A3 According to Table 1, the oil / fat A: was changed to 36.5 parts by weight, and 1.5 weight of palm extremely hydrogenated oil was added without adding palm kernel oil. A foamable oil-in-water emulsified oil / fat composition A3 having Aw: 0.952 and pH: 4.9 was obtained in the same manner as in Example A1 except that the amount of water was adjusted. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A3 was measured, and the results are summarized in Table 1.

(実施例A4)起泡性水中油型乳化油脂組成物A4の作製
表1に従って、油脂Aを29.0重量部に変更し、パーム核油を加えずパーム極度硬化油を9.0重量部加え、水の量を調整した以外は実施例A2と同様にして、Aw:0.937、pH:4.9の起泡性水中油型乳化油脂組成物A4を得た。得られた起泡性水中油型乳化油脂組成物A4のメジアン径の測定を行い、それらの結果を表1にまとめた。
(Example A4) Preparation of foamable oil-in-water emulsified oil / fat composition A4 According to Table 1, the oil / fat A was changed to 29.0 parts by weight, and 9.0 parts by weight of palm extremely hydrogenated oil was added without adding palm kernel oil. In addition, a foamable oil-in-water emulsified oil / fat composition A4 having Aw: 0.937 and pH: 4.9 was obtained in the same manner as in Example A2 except that the amount of water was adjusted. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A4 was measured, and the results are summarized in Table 1.

(実施例X1~X4)ホイップドクリームX1~X4の作製
起泡性水中油型乳化油脂組成物A1~A4をそれぞれカントーミキサー(関東混合機工業(株)製「CS型20」)に4kg入れ、品温を5℃に調整し、高速撹拌条件(380rpm)で硬さが0.30Nになるまでホイップし、ホイップドクリームX1~X4を得た。得られたホイップドクリームX1~X4のオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表1にまとめた。
(Examples X1 to X4) Preparation of whipped cream X1 to X4 Put 4 kg of foamable oil-in-water emulsified fat composition A1 to A4 into a canto mixer ("CS type 20" manufactured by Kanto Mixer Industry Co., Ltd.). The product temperature was adjusted to 5 ° C., and whipping was performed under high-speed stirring conditions (380 rpm) until the hardness became 0.30 N to obtain whipped creams X1 to X4. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of the obtained whipped creams X1 to X4 were evaluated, and the results are summarized in Table 1.

表1にまとめた結果より、以下のことがわかった。実施例X1~X4より、本発明の効果を奏するには起泡性水中油型乳化油脂組成物全体中における油脂含有量が15~40重量%の範囲において本発明の効果を奏し、20~35重量%の範囲であって、且つ水分含量が36~57重量%の範囲において本発明の効果が大きくなることがわかった。 From the results summarized in Table 1, the following was found. From Examples X1 to X4, in order to exert the effect of the present invention, the effect of the present invention is exhibited in the range of the oil and fat content in the entire foamable oil-in-water emulsified oil and fat composition in the range of 15 to 40% by weight, and the effect of the present invention is 20 to 35. It was found that the effect of the present invention was increased in the range of% by weight and the water content was in the range of 36 to 57% by weight.

(実施例A5、A6、比較例B1)起泡性水中油型乳化油脂組成物A5、A6、B1の作製
表2に従って、油脂Aをそれぞれ24.2重量部、13.0重量部、11.5重量部に変更し、パーム核油をそれぞれ1.3重量部12.5重量部、14.0重量部に変更した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A5、A6、B1を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A5、A6、B1のメジアン径の測定を行い、それらの結果を表2にまとめた。
(Examples A5, A6, Comparative Example B1) Preparation of foamable oil-in-water emulsified fat composition A5, A6, B1 According to Table 2, the fat A was added in an amount of 24.2 parts by weight, 13.0 parts by weight, and 11. Foamable oil-in-water emulsified oil composition in the same manner as in Example A1 except that the amount was changed to 5 parts by weight and the palm kernel oil was changed to 1.3 parts by weight and 14.0 parts by weight, respectively. Objects A5, A6 and B1 were obtained. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A5, A6, and B1 were measured, and the results are summarized in Table 2.

Figure 2022080142000002
Figure 2022080142000002

(実施例X5、X6、比較例Y1)ホイップドクリームX5、X6、Y1の作製
起泡性水中油型乳化油脂組成物A5、A6、B1をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX5、X6、Y1を得た。得られたホイップドクリームX5、X6、Y1のオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表2にまとめた。
(Examples X5, X6, Comparative Example Y1) Preparation of whipped cream X5, X6, Y1 Foamable oil-in-water emulsified fat composition A5, A6, B1 are whipped and whipped in the same manner as in Example X1, respectively. Creams X5, X6 and Y1 were obtained. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of the obtained whipped creams X5, X6, and Y1 were evaluated, and the results are summarized in Table 2.

表2にまとめた結果より、以下のことがわかった。実施例X1、X3、X5、X6及び比較例Y1より、油脂全体中における油脂Aの含有量が48~100重量%の範囲において本発明の効果を奏し、48~90重量%において本発明の効果が大きくなることが明らかとなった。また、前記油脂Aの含有量が51.0重量%の場合、全ての評価値が良好だったのに対し、油脂Aの含有量が45.0重量%の場合、常温販売に十分な保形性及び離水耐性が得られなかったことから、油脂全体中の油脂Aの含有量が48重量%を下回ると、本発明の効果を十分に奏さないことが推察された。 From the results summarized in Table 2, the following was found. From Examples X1, X3, X5, X6 and Comparative Example Y1, the effect of the present invention is exhibited in the range where the content of the fat A in the whole fat and oil is in the range of 48 to 100% by weight, and the effect of the present invention is obtained in the range of 48 to 90% by weight. It became clear that Further, when the content of the fat A was 51.0% by weight, all the evaluation values were good, whereas when the content of the fat A was 45.0% by weight, the shape was sufficiently retained for normal temperature sales. Since the properties and water separation resistance were not obtained, it was presumed that if the content of the fat A in the whole fat was less than 48% by weight, the effect of the present invention would not be sufficiently exhibited.

(実施例A7)起泡性水中油型乳化油脂組成物A7の作製
表3に従って、油脂Aとしてパーム核極度硬化油の代わりにヤシ油極度硬化油(C12以下の飽和脂肪酸含有量:52.6重量%、C12:41.5重量%、25℃におけるSFC:20.1%、35℃のSFC:5.1%)を配合した以外は実施例A1と同様にして、Aw:0.965、pH:4.9の起泡性水中油型乳化油脂組成物A7を得た。得られた起泡性水中油型乳化油脂組成物A7のメジアン径の測定を行い、それらの結果を表3にまとめた。
(Example A7) Preparation of foamable oil-in-water emulsified oil / fat composition A7 According to Table 3 , coconut oil extremely hydrogenated oil (saturated fatty acid content of C12 or less: 52.6 weight) was used as oil / fat A instead of palm nucleus extremely hydrogenated oil. %, C 12 : 41.5% by weight, SFC at 25 ° C: 20.1%, SFC at 35 ° C: 5.1%) in the same manner as in Example A1, Aw: 0.965, pH: 4.9. A foamable oil-in-water emulsified oil / fat composition A7 was obtained. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A7 was measured, and the results are summarized in Table 3.

Figure 2022080142000003
Figure 2022080142000003

(実施例A8)起泡性水中油型乳化油脂組成物A8の作製
表3に従って、油脂Aとしてパーム核極度硬化油の代わりにパーム核分別硬質部硬化油(C12以下の飽和脂肪酸含有量:54.7重量%、C12:50.3重量%、25℃におけるSFC:83.9%、35℃のSFC:3.9%)を配合した以外は実施例A1と同様にして、Aw:0.965、pH:4.9の起泡性水中油型乳化油脂組成物A8を得た。得られた起泡性水中油型乳化油脂組成物A8のメジアン径の測定を行い、それらの結果を表3にまとめた。
(Example A8) Preparation of foamable oil-in-water emulsified oil / fat composition A8 According to Table 3 , instead of palm nucleus extremely hydrogenated oil as oil / fat A, palm nucleus fractionated hard hydrogenated oil (saturated fatty acid content of C12 or less: Aw: 0.965, pH: 4 . A foamable oil-in-water emulsified oil / fat composition A8 of 9 was obtained. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A8 was measured, and the results are summarized in Table 3.

(比較例B2)起泡性水中油型乳化油脂組成物B2の作製
表3に従って、油脂Aを配合せず、代わりにパーム核分別軟質部硬化油(C12以下の飽和脂肪酸含有量:46.7重量%、C12:40.0重量%、25℃におけるSFC:64.7%、35℃のSFC:21.0%):16.5重量部を配合した以外は実施例A1と同様にして、Aw:0.965、pH:4.9の起泡性水中油型乳化油脂組成物B2を得た。得られた起泡性水中油型乳化油脂組成物B2のメジアン径の測定を行い、それらの結果を表3にまとめた。
(Comparative Example B2) Preparation of foamable oil-in-water emulsified oil / fat composition B2 According to Table 3 , the oil / fat A was not blended, and instead, the hydrogenated oil in the palm nucleus fractionated soft part (saturated fatty acid content of C12 or less: 46.7 weight). %, C 12 : 40.0% by weight, SFC at 25 ° C: 64.7%, SFC at 35 ° C: 21.0%): 16.5 parts by weight in the same manner as in Example A1, Aw: 0.965, A foamable oil-in-water emulsified oil / fat composition B2 having a pH of 4.9 was obtained. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition B2 was measured, and the results are summarized in Table 3.

(比較例B3)起泡性水中油型乳化油脂組成物B3の作製
表3に従って、油脂Aを配合せず、代わりにヤシ油(C12以下の飽和脂肪酸含有量:57.6重量%、C12:45.1重量%、25℃におけるSFC:1.1%、35℃のSFC:0%):16.5重量部を配合した以外は実施例A1と同様にして、Aw:0.965、pH:4.9の起泡性水中油型乳化油脂組成物B3を得た。得られた起泡性水中油型乳化油脂組成物B3のメジアン径の測定を行い、それらの結果を表3にまとめた。
(Comparative Example B3) Preparation of foamable oil-in-water emulsified oil / fat composition B3 According to Table 3, coconut oil (saturated fatty acid content of C 12 or less: 57.6% by weight, C 12 :) was not blended with oil / fat A. 45.1% by weight, SFC at 25 ° C: 1.1%, SFC at 35 ° C: 0%): 16.5 parts by weight in the same manner as in Example A1, Aw: 0.965, pH: 4.9. The foamable oil-in-water emulsified oil / fat composition B3 was obtained. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition B3 was measured, and the results are summarized in Table 3.

(実施例X7、X8、比較例Y2、Y3)ホイップドクリームX7、X8、Y2、Y3の作製
起泡性水中油型乳化油脂組成物A7、A8、B2、B3をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX7、X8、Y2、Y3を得た。得られた各ホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶、甘さの評価を行い、それらの結果を表3にまとめた。
(Examples X7, X8, Comparative Examples Y2, Y3) Preparation of whipped cream X7, X8, Y2, Y3 Foamable oil-in-water emulsified fat composition A7, A8, B2, B3 were made in the same manner as in Example X1, respectively. And whipped to obtain whipped creams X7, X8, Y2 and Y3. The overrun, shape retention, water separation resistance, bacteriostatic effect, mouth-dissolving, and sweetness of each of the obtained whipped creams were evaluated, and the results are summarized in Table 3.

表3にまとめた結果より、以下のことがわかった。X1、X7、X8及び比較例Y2、Y3より、油脂A中のC12以下の飽和脂肪酸含有量が50~60重量%の範囲において本発明の効果を奏することが明らかとなった。また、25℃のSFC:83.9%、35℃のSFC:3.9%(実施例X8)、25℃のSFC:69.2%、35℃のSFC:11.9%(実施例X1)では全ての評価値が良好だったのに対し、25℃のSFC:20.1%、35℃のSFC:5.1%(実施例X7)では保形性及び離水耐性の評価値が3であり、25℃のSFC:1.1%、35℃のSFC:0%(比較例Y3)では保形性及び離水耐性の評価値が1、25℃のSFC:64.7%、35℃のSFC:21.0%(比較例Y3)では口溶けの評価値が2.0だったことから、25℃でのSFCが20~85%の範囲を満たし、尚且つ35℃でのSFCが3~15%の範囲を満たす場合において本発明の効果を奏することが明らかとなった。また、25℃のSFCが50~85%、且つ35℃のSFCが3~15%を満たす範囲において本発明の効果がより大きいことが推察された。 From the results summarized in Table 3, the following was found. From X1, X7, X8 and Comparative Examples Y2 and Y3, it was clarified that the effect of the present invention is exhibited in the range of the saturated fatty acid content of C12 or less in the fat A in the range of 50 to 60% by weight. Further, SFC at 25 ° C.: 83.9%, SFC at 35 ° C.: 3.9% (Example X8), SFC at 25 ° C.: 69.2%, SFC at 35 ° C.: 11.9% (Example X1). ), All the evaluation values were good, whereas at 25 ° C. SFC: 20.1% and 35 ° C. SFC: 5.1% (Example X7), the evaluation values of shape retention and water separation resistance were 3. At 25 ° C. SFC: 1.1% and 35 ° C. SFC: 0% (Comparative Example Y3), the evaluation values of shape retention and water separation resistance were 1,25 ° C. SFC: 64.7%, 35 ° C. SFC: 21.0% (Comparative Example Y3) had an evaluation value of melting in the mouth of 2.0, so the SFC at 25 ° C satisfied the range of 20 to 85%, and the SFC at 35 ° C was 3. It has been clarified that the effect of the present invention is exhibited when the range of about 15% is satisfied. Further, it was presumed that the effect of the present invention was greater in the range where the SFC at 25 ° C. was 50 to 85% and the SFC at 35 ° C. was 3 to 15%.

(実施例A9、比較例B4)起泡性水中油型乳化油脂組成物A9、B4の作製
表4に従って、ホイエパーミエイトパウダーを配合せず、ホエイタンパク:0.06重量部、0.04重量部にそれぞれ変更し、水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A9、B4を得た。それらのAwは0.966(A9)、0.966(B4)であり、pHは4.8(A9)、4.8(B4)であった。得られた起泡性水中油型乳化油脂組成物A9、B4のメジアン径の測定を行い、それらの結果を表4にまとめた。
(Example A9, Comparative Example B4) Preparation of foamable oil-in-water emulsified oil / fat compositions A9 and B4 According to Table 4, whey protein: 0.06 part by weight, 0.04 weight without blending whey permeate powder. Foamable oil-in-water emulsified oil / fat compositions A9 and B4 were obtained in the same manner as in Example A1 except that the amounts of water were adjusted. Their Aw was 0.966 (A9), 0.966 (B4) and the pH was 4.8 (A9), 4.8 (B4). The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A9 and B4 were measured, and the results are summarized in Table 4.

Figure 2022080142000004
Figure 2022080142000004

(実施例A10、比較例B5)起泡性水中油型乳化油脂組成物A10、B5の作製
表4に従って、ホエイタンパク:0.70重量部、1.05重量部にそれぞれ変更し、それぞれにバターミルクパウダー:0.70重量部を加え、水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A10、B5を得た。それらのAwは0.963(A10)、0.963(B5)であり、pHは5.4(A10)、5.5(B5)であった。得られた起泡性水中油型乳化油脂組成物A10、B5のメジアン径の測定を行い、それらの結果を表4にまとめた。
(Example A10, Comparative Example B5) Preparation of foamable oil-in-water emulsified oil / fat compositions A10 and B5 According to Table 4, whey protein was changed to 0.70 part by weight and 1.05 part by weight, respectively, and butter was used for each. Milk powder: 0.70 parts by weight was added to obtain foamable oil-in-water emulsified oil / fat compositions A10 and B5 in the same manner as in Example A1 except that the amount of water was adjusted. Their Aw was 0.963 (A10) and 0.963 (B5), and the pH was 5.4 (A10) and 5.5 (B5). The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A10 and B5 were measured, and the results are summarized in Table 4.

(実施例X9、X10、比較例Y4、Y5)ホイップドクリームX9、X10、Y4、Y5の作製
起泡性水中油型乳化油脂組成物A9、A10、B4、B5をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX9、X10、Y4、Y5を得た。得られたホイップドクリームX9、X10、Y4、Y5のオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表4にまとめた。尚、ホイップドクリームY4は、内層のキメが不均一になっていた。
(Examples X9, X10, Comparative Examples Y4, Y5) Preparation of whipped cream X9, X10, Y4, Y5 Foamable oil-in-water emulsified fat composition A9, A10, B4, B5 were made in the same manner as in Example X1, respectively. And whipped to obtain whipped creams X9, X10, Y4 and Y5. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of the obtained whipped creams X9, X10, Y4, and Y5 were evaluated, and the results are summarized in Table 4. In the whipped cream Y4, the texture of the inner layer was uneven.

表4にまとめた結果より、以下のことがわかった。実施例X1、X9、X10及び比較例Y4、Y5より、起泡性水中油型乳化油脂組成物全体中のタンパク質含有量が0.048~0.8重量%の範囲において本発明の効果を奏し、0.1~0.5重量%の範囲において本発明の効果がより大きいことが明らかとなった。また、タンパク質含有量が0.17重量%より少なくなるにつれて離水耐性及び静菌作用の評価値が低下する傾向がみられ、該含有量が0.05重量%の場合、保形性及び離水耐性は常温販売に問題の無いレベルであった一方、該含有量が0.03重量%の場合、常温販売に十分な離水耐性が得られなかったことから、タンパク質含有量が0.048重量%を下回る場合、本発明の効果を十分に奏さないことが推察された。更に、タンパク質含有量が0.17重量%より多くなるにつれてオーバーランの値及び口溶けの評価値が低下する傾向がみられ、該含有量が0.79重量%の場合、口溶けは3.5であり問題の無いレベルであった一方、該含有量が1.07重量%の場合、口溶けが問題になるほど悪かったことから、タンパク質含有量が0.8重量%を上回る場合、本発明の効果を十分に奏さないことが推察された。 From the results summarized in Table 4, the following was found. From Examples X1, X9, X10 and Comparative Examples Y4 and Y5, the effect of the present invention was exhibited in the range of the protein content in the whole foamable oil-in-water emulsified oil / fat composition in the range of 0.048 to 0.8% by weight. , The effect of the present invention was found to be greater in the range of 0.1 to 0.5% by weight. Further, as the protein content becomes less than 0.17% by weight, the evaluation values of water separation resistance and bacteriostatic action tend to decrease, and when the content is 0.05% by weight, shape retention and water separation resistance tend to decrease. On the other hand, when the content was 0.03% by weight, sufficient water separation resistance was not obtained for normal temperature sales, so the protein content was 0.048% by weight. If it is less than that, it is presumed that the effect of the present invention is not sufficiently exhibited. Furthermore, as the protein content increases above 0.17% by weight, the overrun value and the evaluation value of melting in the mouth tend to decrease, and when the content is 0.79% by weight, the melting in the mouth is 3.5. On the other hand, when the content was 1.07% by weight, it was so bad that melting in the mouth became a problem. Therefore, when the protein content exceeds 0.8% by weight, the effect of the present invention is exhibited. It was inferred that it did not play well.

また、実施例X9、X10及び比較例Y4より、起泡性水中油型乳化油脂組成物全体中のカルシウム含有量が2~75ppmの範囲において本発明の効果を奏し、20~70ppmの範囲において本発明の効果がより大きいことが明らかとなった。また、カルシウム含有量が26ppmより多くなるほどオーバーランが低下する傾向がみられ、該含有量が71ppmの場合、オーバーランの値が280%だったのに対し、該含有量が79ppmの場合、オーバーランが245で、口どけが悪くなり過ぎたことから、カルシウム含有量が75ppmを上回る場合、本発明の効果を十分に奏さないことが推察された。また、カルシウム含有量が26ppmより少なくなるほど保形性及び離水耐性が低下する傾向がみられ、該含有量が2.4ppmの場合、離水耐性の評価値が3(常温販売に問題が無い)であったことから、カルシウム含有量が2ppmを下回ると常温販売に十分な離水耐性が得られないことが推察された。 Further, from Examples X9, X10 and Comparative Example Y4, the effect of the present invention was exhibited in the range of the calcium content in the whole foamable oil-in-water emulsified oil / fat composition in the range of 2 to 75 ppm, and the present invention was exhibited in the range of 20 to 70 ppm. It became clear that the effect of the invention was greater. In addition, the overrun tends to decrease as the calcium content exceeds 26 ppm. When the content is 71 ppm, the overrun value is 280%, whereas when the content is 79 ppm, the overrun tends to decrease. Since the orchid was 245 and the mouthfeel became too bad, it was inferred that the effect of the present invention was not sufficiently exhibited when the calcium content exceeded 75 ppm. Further, as the calcium content is less than 26 ppm, the shape retention and water separation resistance tend to decrease, and when the content is 2.4 ppm, the evaluation value of water separation resistance is 3 (there is no problem in normal temperature sales). Therefore, it was inferred that if the calcium content was less than 2 ppm, sufficient water separation resistance could not be obtained for normal temperature sales.

(実施例A11、A12、比較例B6、B7)起泡性水中油型乳化油脂組成物A11、A12、B6、B7の作製
表5に従って、乳化剤Aの配合量をそれぞれ0.32重量部、0.48重量部、0.25重量部、0重量部(配合なし)に変更し、水の量を調整し、比較例B7のみポリソルベート(C16~C18の飽和脂肪酸含有量:5.0重量%、HLB:15.0):0.45重量部を配合した以外は実施例A1と同様にして、泡性水中油型乳化油脂組成物A11、A12、B6、B7を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A11、A12、B6、B7のメジアン径の測定を行い、それらの結果を表5にまとめた。
(Examples A11, A12, Comparative Examples B6, B7) Preparation of foamable oil-in-water emulsified oil / fat composition A11, A12, B6, B7 According to Table 5, the blending amounts of emulsifier A were 0.32 parts by weight and 0, respectively. Change to .48 parts by weight, 0.25 parts by weight, and 0 parts by weight (without compounding), adjust the amount of water, and polysorbate only in Comparative Example B7 (saturated fatty acid content of C 16 to C 18 : 5.0% by weight, HLB: 15.0): Foamable oil-in-water emulsified fat composition A11, A12, B6, B7 was obtained in the same manner as in Example A1 except that 0.45 parts by weight was blended. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A11, A12, B6, and B7 were measured, and the results are summarized in Table 5.

Figure 2022080142000005
Figure 2022080142000005

(実施例X11、X12、比較例Y6、Y7)ホイップドクリームX11、X12、Y6、Y7の作製
起泡性水中油型乳化油脂組成物A11、A12、B6、B7をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX11、X12、Y6、Y7を得た。得られたホイップドクリームX11、X12、Y6、Y7のオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表5にまとめた。
(Examples X11, X12, Comparative Examples Y6, Y7) Preparation of whipped cream X11, X12, Y6, Y7 Foamable oil-in-water emulsified fat composition A11, A12, B6, B7 were made in the same manner as in Example X1, respectively. And whipped to obtain whipped creams X11, X12, Y6 and Y7. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of the obtained whipped creams X11, X12, Y6, and Y7 were evaluated, and the results are summarized in Table 5.

表5にまとめた結果より、以下のことがわかった。実施例X1、X11、X12及び比較例Y6より、起泡性水中油型乳化油脂組成物全体中の乳化剤Aの含有量が0.3~0.5重量%の範囲において本発明の効果を奏し、0.4~0.5重量%の範囲において本発明の効果がより大きいことが明らかとなった。また、該含有量が0.48重量%より少なくなるほどオーバーラン値が低くなる傾向がみられ、0.32重量%の場合のオーバーラン値が263%であり、0.25重量%の場合、オーバーランが高くならなかったことから、乳化剤Aの含有量が0.3を下回ると本発明の効果を十分に奏さないことが推察された。 From the results summarized in Table 5, the following was found. From Examples X1, X11, X12 and Comparative Example Y6, the effect of the present invention was exhibited in the range of the content of emulsifier A in the whole foamable oil-in-water emulsified oil / fat composition in the range of 0.3 to 0.5% by weight. , 0.4 to 0.5% by weight, revealed that the effect of the present invention is greater. Further, the overrun value tends to decrease as the content is less than 0.48% by weight, and the overrun value is 263% when the content is 0.32% by weight and 0.25% by weight. Since the overrun did not increase, it was inferred that the effect of the present invention would not be sufficiently exerted if the content of emulsifier A was less than 0.3.

また、乳化剤AのHLBは12~18且つC16~C18の飽和脂肪酸の合計含有量が構成脂肪酸全体中90重量%以上であれば本願効果を奏することが明らかとなり、乳化剤AのC16~C18の飽和脂肪酸の合計含有量が構成脂肪酸全体中5.0重量%、HLBが15.0の場合の場合、オーバーランが十分に高くならず、口溶けも悪くなったことから、前記飽和脂肪酸の合計含有量が90重量%を下回ると本発明の効果を十分に奏さないことが推察された。 Further, it was clarified that the effect of the present application is exhibited when the HLB of emulsifier A is 12 to 18 and the total content of saturated fatty acids of C 16 to C 18 is 90% by weight or more in the total constituent fatty acids, and C 16 to C 16 of emulsifier A. When the total content of the saturated fatty acid of C18 was 5.0% by weight in the total constituent fatty acids and the HLB was 15.0, the overrun was not sufficiently high and the melt-in-the-mouth was poor. It is presumed that the effect of the present invention is not sufficiently exhibited when the total content of the above is less than 90% by weight.

(実施例A13、比較例B8)起泡性水中油型乳化油脂組成物A13、B8の作製
表6に従って、乳化剤B(テトラグリセリンモノステアリン酸エステル、C16~C18の飽和脂肪酸含有量:98.3重量%、HLB:8.4)の配合量をそれぞれ0.12重量部、0.05重量部に変更し水の量を調整した以外は、実施例A1と同様にして起泡性水中油型乳化油脂組成物A13、B8を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A13、B8のメジアン径の測定を行い、それらの結果を表6にまとめた。
(Example A13, Comparative Example B8) Preparation of foamable oil-in-water emulsified oil / fat compositions A13 and B8 According to Table 6, emulsifier B (tetraglycerin monostearic acid ester, saturated fatty acid content of C 16 to C 18 : 98.3). Foamable oil-in-water emulsified fat and oil in the same manner as in Example A1 except that the blending amounts of% by weight and HLB: 8.4) were changed to 0.12 parts by weight and 0.05 parts by weight, respectively, and the amount of water was adjusted. Compositions A13 and B8 were obtained. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A13 and B8 were measured, and the results are summarized in Table 6.

Figure 2022080142000006
Figure 2022080142000006

(実施例A14、比較例B9)起泡性水中油型乳化油脂組成物A14、B9の作製
表6に従って、乳化剤B(テトラグリセリンモノステアリン酸エステル、C16~C18の飽和脂肪酸含有量:98.3重量%、HLB:8.4)を配合せず、実施例A14では乳化剤B(テトラグリセリントリステアリン酸エステル、C16~C18の飽和脂肪酸含有量:98.3重量%、HLB:4.6):0.20重量部を配合し、比較例B9ではポリグリセリン脂肪酸エステル(C16~C18の飽和脂肪酸含有量:56.2重量%、HLB:3.3):0.20重量部を配合した以外は、実施例A1と同様にして起泡性水中油型乳化油脂組成物A14、B9を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A14、B9のメジアン径の測定を行い、それらの結果を表6にまとめた。
(Example A14, Comparative Example B9) Preparation of foamable oil-in-water emulsified oil / fat compositions A14 and B9 According to Table 6, emulsifier B (tetraglycerin monostearic acid ester, saturated fatty acid content of C 16 to C 18 : 98.3). Weight%, HLB: 8.4) was not added, and in Example A14, emulsifier B (tetraglycerin tristearic acid ester, saturated fatty acid content of C 16 to C 18 : 98.3% by weight, HLB: 4.6): 0.20 weight. In Comparative Example B9, the same as in Example A1 except that the polyglycerin fatty acid ester (saturated fatty acid content of C 16 to C 18 : 56.2% by weight, HLB: 3.3): 0.20 part by weight was blended. The foamable oil-in-water emulsified oil / fat compositions A14 and B9 were obtained. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A14 and B9 were measured, and the results are summarized in Table 6.

(実施例X13、X14、比較例Y8、Y9)ホイップドクリームX13、X14、Y8、Y9の作製
起泡性水中油型乳化油脂組成物A13、A14、B8、B9をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX13、X14、Y8、Y9を得た。得られたホイップドクリームX13、X14、Y8、Y9のオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表6にまとめた。
(Examples X13, X14, Comparative Examples Y8, Y9) Preparation of whipped cream X13, X14, Y8, Y9 Foamable oil-in-water emulsified fat composition A13, A14, B8, B9 were made in the same manner as in Example X1, respectively. And whipped to obtain whipped creams X13, X14, Y8 and Y9. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of the obtained whipped creams X13, X14, Y8, and Y9 were evaluated, and the results are summarized in Table 6.

表6にまとめた結果より、以下のことがわかった。実施例X1、X13及び比較例Y8より、起泡性水中油型乳化油脂組成物全体中の乳化剤Bの含有量が0.1~0.25重量%の範囲において本発明の効果を奏することが明らかとなった。また、該含有量が0.20重量%より少なくなるにつれてオーバーラン値及び口溶けの評価値が低下する傾向がみられ、0.12重量%の場合、口溶けの評価値が3.5であったのに対し、0.05重量%の場合、口溶けが問題になるほど悪かったことから、乳化剤Bの含有量が0.1重量%を下回ると本発明の効果を十分に奏さないことが推察された。 From the results summarized in Table 6, the following was found. From Examples X1 and X13 and Comparative Example Y8, it is possible to exert the effect of the present invention in the range of the content of emulsifier B in the whole foamable oil-in-water emulsified oil / fat composition in the range of 0.1 to 0.25% by weight. It became clear. Further, as the content was less than 0.20% by weight, the overrun value and the evaluation value of melting in the mouth tended to decrease, and in the case of 0.12% by weight, the evaluation value of melting in the mouth was 3.5. On the other hand, in the case of 0.05% by weight, it was so bad that melting in the mouth became a problem, so it was inferred that the effect of the present invention would not be sufficiently exerted if the content of emulsifier B was less than 0.1% by weight. ..

また、実施例X1、X14、及び比較例Y9より、乳化剤BのHLBは0~9であれば本願効果を奏し、5~9の範囲において本発明の効果がより大きいことが明らかとなった。更には、C16~C18の飽和脂肪酸の合計含有量が構成脂肪酸全体中56.2重量%の場合、口溶けが問題になるほど悪くなることが明らかとなった。 Further, from Examples X1, X14, and Comparative Example Y9, it was clarified that if the HLB of the emulsifier B was 0 to 9, the effect of the present application was exhibited, and the effect of the present invention was greater in the range of 5 to 9. Furthermore, it was clarified that when the total content of the saturated fatty acids C 16 to C 18 was 56.2% by weight in the total constituent fatty acids, the melting in the mouth became a problem.

更に、実施例X1、X11、X13、X14及び比較例Y6、Y8より、乳化剤B/乳化剤Aの重量比が0.2~0.67の範囲内であれば本発明の効果を好適に奏すること、該重量比が0.80ではオーバーランが高くならず、0.11では口溶けが問題になるほど悪くなることが明らかとなった。 Further, from Examples X1, X11, X13, X14 and Comparative Examples Y6 and Y8, if the weight ratio of emulsifier B / emulsifier A is within the range of 0.2 to 0.67, the effect of the present invention is suitably exhibited. It was clarified that when the weight ratio was 0.80, the overrun did not increase, and when it was 0.11, it became so bad that melting in the mouth became a problem.

(実施例A15、A16、比較例B10)起泡性水中油型乳化油脂組成物A15、A16、B10の作製
表7に従って、乳化剤C(モノグリセリンステアリン酸エステル、C16~C18の飽和脂肪酸含有量:96.1重量%、HLB:4.3)の配合量をそれぞれ0.12重量部、0.24重量部、0.05重量部に変更し、水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A15、A16、B10を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A15、A16、B10のメジアン径の測定を行い、それらの結果を表7にまとめた。
(Examples A15, A16, Comparative Example B10) Preparation of foamable oil-in-water emulsified oil / fat compositions A15, A16, B10 According to Table 7, emulsifier C (monoglycerin stearic acid ester, saturated fatty acid containing C 16 to C 18 ) is contained. Amount: 96.1% by weight, HLB: 4.3) were changed to 0.12 parts by weight, 0.24 parts by weight, and 0.05 parts by weight, respectively, and the same as in Example A1 except that the amount of water was adjusted. The foamable oil-in-water emulsified oil / fat compositions A15, A16, and B10 were obtained. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A15, A16, and B10 were measured, and the results are summarized in Table 7.

Figure 2022080142000007
Figure 2022080142000007

(実施例X15、X16、比較例Y10)ホイップドクリームX15、X16、Y10の作製
得られた起泡性水中油型乳化油脂組成物A15、A16、B10をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX15、X16、Y10を得た。得られたホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶けの評価を行い、それらの結果を表7にまとめた。
(Examples X15, X16, Comparative Example Y10) Preparation of whipped creams X15, X16, Y10 The obtained foaming oil-in-water emulsified oil / fat compositions A15, A16, and B10 were whipped in the same manner as in Example X1, respectively. , Whipped creams X15, X16, Y10 were obtained. The overrun, shape retention, water separation resistance, bacteriostatic action, and melting in the mouth of each of the obtained whipped creams were evaluated, and the results are summarized in Table 7.

表7にまとめた結果より、以下のことがわかった。実施例X1、X15、X16及び比較例Y10より、起泡性水中油型乳化油脂組成物全体中の乳化剤Cの含有量が0.1~0.25重量%の範囲において本発明の効果を奏し、0.18~0.22重量%の範囲において本発明の効果がより大きいこと、該含有量が0.05重量%の場合、オーバーランが高くならず、口溶けも問題になるほど悪くなることが明らかとなった。 From the results summarized in Table 7, the following was found. From Examples X1, X15, X16 and Comparative Example Y10, the effect of the present invention was exhibited in the range of the content of emulsifier C in the whole foamable oil-in-water emulsified oil / fat composition in the range of 0.1 to 0.25% by weight. , The effect of the present invention is greater in the range of 0.18 to 0.22% by weight, and when the content is 0.05% by weight, the overrun does not become high and the melting in the mouth becomes so bad that it becomes a problem. It became clear.

更に、表5、6、7にまとめた結果より、以下のことがわかった。実施例X1、X11~X26及び比較例Y6~Y10より、乳化剤C/(乳化剤A+B)の重量比が0.14~0.5の範囲内であれば本発明の効果を奏することが示唆され、該重量比が0.08では、オーバーランが高くならず口溶けも問題になるほど悪く、1.00では口溶けが問題になるほど悪くなることが明らかとなった。 Furthermore, from the results summarized in Tables 5, 6 and 7, the following was found. From Examples X1, X11 to X26 and Comparative Examples Y6 to Y10, it is suggested that the effect of the present invention is exhibited when the weight ratio of emulsifier C / (emulsifier A + B) is within the range of 0.14 to 0.5. It was clarified that when the weight ratio was 0.08, the overrun was not high and the melting in the mouth became a problem, and when the weight ratio was 1.00, the melting in the mouth became a problem.

(実施例A17~A20、比較例B11)起泡性水中油型乳化油脂組成物17~A20、B11の作製
表8に従って、多糖類X:0.03重量部、0.35重量部、0.01重量部、0.35重量部、0.42重量部にそれぞれ変更し、多糖類Y:0.20重量部、0.10重量部、0.10重量部、0.25重量部、0.20重量部とし、それぞれ水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A17~A20、B11を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A17~A20、B11のメジアン径の測定を行い、それらの結果を表8にまとめた。
(Examples A17 to A20, Comparative Example B11) Preparation of foamable oil-in-water emulsified oil / fat compositions 17 to A20 and B11 Polysaccharide X: 0.03 parts by weight, 0.35 parts by weight, 0. Change to 01 parts by weight, 0.35 parts by weight, 0.42 parts by weight, and polysaccharide Y: 0.20 parts by weight, 0.10 parts by weight, 0.10 parts by weight, 0.25 parts by weight, 0. Foamable oil-in-water emulsified oil / fat compositions A17 to A20 and B11 were obtained in the same manner as in Example A1 except that the amount of water was adjusted to 20 parts by weight. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A17 to A20 and B11 were measured, and the results are summarized in Table 8.

Figure 2022080142000008
Figure 2022080142000008

(比較例B12)起泡性水中油型乳化油脂組成物B12の作製
表8に従って、多糖類Xを配合せず、代わりにキサンタンガム:0.08重量部を加えた以外は実施例A1と同様にして、Aw:0.965、pH:4.9の起泡性水中油型乳化油脂組成物B12を得た。得られた起泡性水中油型乳化油脂組成物B12のメジアン径の測定を行い、それらの結果を表8にまとめた。
(Comparative Example B12) Preparation of foamable oil-in-water emulsified oil / fat composition B12 According to Table 8, the same as in Example A1 except that the polysaccharide X was not blended and xanthan gum: 0.08 part by weight was added instead. Then, a foamable oil-in-water emulsified oil / fat composition B12 having Aw: 0.965 and pH: 4.9 was obtained. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition B12 was measured, and the results are summarized in Table 8.

(実施例X17~X20、比較例Y11、Y12)ホイップドクリームX17~X20、Y11、Y12の作製
起泡性水中油型乳化油脂組成物A17~A20、B11、B12をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX17~X20、Y11、Y12を得た。得られたホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表8にまとめた。
(Examples X17 to X20, Comparative Examples Y11 and Y12) Preparation of whipped creams X17 to X20, Y11 and Y12 Foamable oil-in-water emulsified oil and fat compositions A17 to A20, B11 and B12 are made in the same manner as in Example X1, respectively. And whipped to obtain whipped creams X17 to X20, Y11 and Y12. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of each of the obtained whipped creams were evaluated, and the results are summarized in Table 8.

表8にまとめた結果より、以下のことがわかった。実施例X1、X17及び比較例Y11より、起泡性水中油型乳化油脂組成物全体中の多糖類Xの含有量が0.01~0.4重量%の範囲において本発明の効果を奏し、0.05~0.15重量%の範囲において本発明の効果がより大きいこと、また0.42重量%の場合、オーバーランが高くならず、口溶けも問題になるほど悪くなることが明らかとなった。更に、実施例X1及び比較例Y12より、脱アシル型ジェランガムである多糖類Xの代わりにキサンタンガムを用いると、常温販売に十分な離水耐性が得られないことが明らかとなった。 From the results summarized in Table 8, the following was found. From Examples X1 and X17 and Comparative Example Y11, the effect of the present invention was exhibited in the range of the content of polysaccharide X in the whole foamable oil-in-water emulsified oil / fat composition in the range of 0.01 to 0.4% by weight. It has been clarified that the effect of the present invention is greater in the range of 0.05 to 0.15% by weight, and that in the case of 0.42% by weight, the overrun does not increase and the melting in the mouth becomes so bad that it becomes a problem. .. Furthermore, from Example X1 and Comparative Example Y12, it was clarified that when xanthan gum was used instead of polysaccharide X, which is a deacylated gellan gum, sufficient water separation resistance could not be obtained for normal temperature sales.

(実施例A21、A22)起泡性水中油型乳化油脂組成物A21、A22の作製
表9に従って、多糖類Y(HPMC、2%水溶液の20℃での粘度:50mPa・s)の配合量をそれぞれ0.12重量部、0.28重量部に変更し、それぞれ水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A21、A22を得た。それらのAwはそれぞれ0.965であり、pHはそれぞれ4.9であった。得られた起泡性水中油型乳化油脂組成物A21、A22のメジアン径の測定を行い、それらの結果を表9にまとめた。
(Examples A21 and A22) Preparation of foamable oil-in-water emulsified oil and fat compositions A21 and A22 According to Table 9, the blending amount of the polysaccharide Y (HPMC, viscosity of 2% aqueous solution at 20 ° C.: 50 mPa · s) was adjusted. Foamable aqueous oil-type emulsified oil / fat compositions A21 and A22 were obtained in the same manner as in Example A1 except that the amounts were changed to 0.12 parts by weight and 0.28 parts by weight, respectively, and the amount of water was adjusted. Their Aw was 0.965 and the pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A21 and A22 were measured, and the results are summarized in Table 9.

Figure 2022080142000009
Figure 2022080142000009

(実施例A23、比較例B13、B14)起泡性水中油型乳化油脂組成物A23、B13、B14の作製
表9に従って、多糖類Y(HPMC、2%水溶液の20℃での粘度:50mPa・s)を添加せず、代わりに多糖類Y(HPMC、2%水溶液の20℃での粘度:99mPa・s):0.20重量部、HPMC(2%水溶液の20℃での粘度:19mPa・s):0.20重量部、HPMC(2%水溶液の20℃での粘度:4000mPa・s):0.20重量部にそれぞれ変更した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A23、B13、B14を得た。それらのAwはそれぞれ0.965であり、それぞれpHは4.9であった。得られた起泡性水中油型乳化油脂組成物A23、B13、B14のメジアン径の測定を行い、それらの結果を表9にまとめた。
(Examples A23, Comparative Examples B13, B14) Preparation of foamable oil-in-water emulsified oil / fat compositions A23, B13, B14 According to Table 9, the viscosity of the polysaccharide Y (HPMC, 2% aqueous solution at 20 ° C.: 50 mPa. s) is not added, instead the polysaccharide Y (HPMC, viscosity of 2% aqueous solution at 20 ° C.: 99 mPa · s): 0.20 parts by weight, HPMC (viscosity of 2% aqueous solution at 20 ° C.: 19 mPa · s). s): 0.20 part by weight, HPMC (viscosity of 2% aqueous solution at 20 ° C.: 4000 mPa · s): Foamable polysaccharide oil in the same manner as in Example A1 except that it was changed to 0.20 part by weight. Molded emulsified oil and fat compositions A23, B13 and B14 were obtained. Their Aw was 0.965, respectively, and their pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A23, B13, and B14 were measured, and the results are summarized in Table 9.

(実施例X21~X23、比較例Y13、Y14)ホイップドクリームX21~X23、Y13、Y14の作製
得られた起泡性水中油型乳化油脂組成物A21~A23、B13、B14をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX21~X23、Y13、Y14を得た。得られたホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表9にまとめた。
(Examples X21 to X23, Comparative Examples Y13 and Y14) Preparation of whipped creams X21 to X23, Y13 and Y14 The obtained foamable oil-in-water emulsified oil and fat compositions A21 to A23, B13 and B14 are used in Examples X1 respectively. The whipped creams X21 to X23, Y13, and Y14 were obtained by whipping in the same manner. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of each of the obtained whipped creams were evaluated, and the results are summarized in Table 9.

表9にまとめた結果より、以下のことがわかった。実施例X1、X21、X22より、起泡性水中油型乳化油脂組成物全体中の多糖類Yの含有量が0.1~0.3重量%の範囲、より好ましくは0.15~0.25重量%の範囲において本発明の効果を好適に奏することが明らかとなった。また、該含有量が0.20重量%の場合(実施例X1)と0.12重量%(実施例X21)の場合を比較すると、該含有量が低い実施例X21の方が離水耐性が低く、評価値が3(常温販売に問題がない)であることから、該含有量が0.1重量%を下回ると常温販売に十分な離水耐性が得られないことが推察された。また、該含有量が0.20重量%の場合(実施例X1)と0.28重量%(実施例X22)の場合を比較すると、該含有量が高い実施例X22の方が口溶けの評価値が低く3.7であったことから、該含有量が0.3重量%を上回ると口溶けが問題になるほど悪くなることが示唆された。 From the results summarized in Table 9, the following was found. From Examples X1, X21, and X22, the content of the polysaccharide Y in the entire foamable oil-in-water emulsified oil / fat composition is in the range of 0.1 to 0.3% by weight, more preferably 0.15 to 0. It has been clarified that the effect of the present invention is suitably exhibited in the range of 25% by weight. Further, when the case where the content is 0.20% by weight (Example X1) and the case where the content is 0.12% by weight (Example X21) are compared, the water separation resistance of Example X21 having a low content is lower. Since the evaluation value was 3 (there was no problem in normal temperature sales), it was inferred that if the content was less than 0.1% by weight, sufficient water separation resistance could not be obtained for normal temperature sales. Further, when the case where the content is 0.20% by weight (Example X1) and the case where the content is 0.28% by weight (Example X22) are compared, the evaluation value of melting in the mouth is higher in Example X22 having a higher content. The low value was 3.7, suggesting that if the content exceeds 0.3% by weight, melting in the mouth becomes a problem.

また、実施例X1、X23及び比較例Y13、Y14より、多糖類Yとして用いるヒドロキシプロピルメチルセルロースの2%水溶液の20℃での粘度が20~110mPa・sの範囲であれば本発明の効果を奏し、30~70mPa・sが好ましいこと、該粘度が19mPa・sの場合、常温販売に十分な離水耐性が得られなくなること、4000mPa・sではオーバーランが高くならず、口溶けも問題になるほど悪くなることが明らかとなった。 Further, from Examples X1 and X23 and Comparative Examples Y13 and Y14, the effect of the present invention is exhibited if the viscosity of a 2% aqueous solution of hydroxypropylmethylcellulose used as the polysaccharide Y at 20 ° C. is in the range of 20 to 110 mPa · s. , 30 to 70 mPa · s is preferable, when the viscosity is 19 mPa · s, sufficient water separation resistance cannot be obtained for normal temperature sales, and at 4000 mPa · s, overrun does not increase and melting in the mouth becomes so bad that it becomes a problem. It became clear.

そして、表8、表9にまとめた結果より、以下のことがわかった。実施例X1、X27~X23及び比較例Y11、Y12より、起泡性水中油型乳化油脂組成物全体中の多糖類Y/多糖類X(重量比)が0.25~30の範囲において本発明の効果を奏すること、1.8~5の範囲において本発明の効果がより大きいことが明らかとなった。 Then, from the results summarized in Tables 8 and 9, the following was found. From Examples X1, X27 to X23 and Comparative Examples Y11 and Y12, the present invention has a polysaccharide Y / polysaccharide X (weight ratio) in the range of 0.25 to 30 in the entire foamable oil-in-water emulsified oil / fat composition. It has been clarified that the effect of the present invention is greater in the range of 1.8 to 5.

(実施例A24、A25)起泡性水中油型乳化油脂組成物A24、A25の作製
表10に従って、グラニュー糖:4.2重量部、8.0重量部に変更し、実施例A25のみマルトースシロップ:2.7重量部を加え、水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A24、A25を得た。それらのAwはそれぞれ0.971(A24),0.952(A25)であり、それぞれpHは4.9であった。得られた起泡性水中油型乳化油脂組成物A24、A25のメジアン径の測定を行い、それらの結果を表10にまとめた。
(Examples A24 and A25) Preparation of foamable oil-in-water emulsified oil and fat compositions A24 and A25 Granule sugar: 4.2 parts by weight and 8.0 parts by weight were changed according to Table 10, and only Example A25 was maltose syrup. : 2.7 parts by weight was added and the amount of water was adjusted in the same manner as in Example A1 to obtain foamable oil-in-water emulsified oil and fat compositions A24 and A25. Their Aw were 0.971 (A24) and 0.952 (A25), respectively, and their pH was 4.9, respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A24 and A25 were measured, and the results are summarized in Table 10.

Figure 2022080142000010
Figure 2022080142000010

(実施例X24、X25)ホイップドクリームX24、X25の作製
実施例A24、A25で得られた起泡性水中油型乳化油脂組成物X24、X25をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX24、X25を得た。得られたホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表10にまとめた。
(Examples X24 and X25) Preparation of whipped creams X24 and X25 The foamable oil-in-water emulsified oil and fat compositions X24 and X25 obtained in Examples A24 and A25 are whipped and whipped in the same manner as in Example X1, respectively. Docream X24 and X25 were obtained. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of each of the obtained whipped creams were evaluated, and the results are summarized in Table 10.

表10にまとめた結果より、以下のことがわかった。実施例X1、X24、X25より、起泡性水中油型乳化油脂組成物全体中の糖類の含有量(乾燥重量)が17~23重量%の範囲において本発明の効果を奏し、18~21重量%の範囲において本発明の効果がより大きいことが明らかとなった。また、該含有量が18.9重量%の場合(実施例X1)と比べ17.1重量%の場合(実施例X24)、離水耐性が低く評価値が3であったことから、前記範囲を下回ると常温販売に十分な離水耐性が得られないことが推察された。また、該含有量が18.9重量%の場合(実施例X1)と比べ22.8重量%の場合(実施例X25)、甘さが強く評価値が3.0であったことから、前記範囲を上回ると甘さが強くなりすぎてしまうことが推察された。 From the results summarized in Table 10, the following was found. From Examples X1, X24, and X25, the effect of the present invention was exhibited in the range of 17 to 23% by weight of the saccharide content (dry weight) in the whole foamable oil-in-water emulsified oil / fat composition, and 18 to 21% by weight. It became clear that the effect of the present invention was greater in the range of%. Further, when the content was 17.1% by weight (Example X24) as compared with the case where the content was 18.9% by weight (Example X1), the water separation resistance was low and the evaluation value was 3, so the above range was set. If it falls below this, it is inferred that sufficient water separation resistance cannot be obtained for normal temperature sales. Further, when the content was 22.8% by weight (Example X25) as compared with the case where the content was 18.9% by weight (Example X1), the sweetness was strong and the evaluation value was 3.0. It was speculated that if the range was exceeded, the sweetness would become too strong.

(実施例A26、A27)起泡性水中油型乳化油脂組成物A26、A27の作製
表11に従って、ソルビン酸カリウム:0.03重量部、0.23重量部に変更し、水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A26、A27を得た。それらのAwはそれぞれ0.965(A26)、0.962(A27)であり、pHはそれぞれ4.7(A26)、5.4(A27)であった。得られた起泡性水中油型乳化油脂組成物A26、A27のメジアン径の測定を行い、それらの結果を表11にまとめた。なお、ホイップドクリームX27はホイップドクリームX1と比べわずかに苦味が感じられるものであった。
(Examples A26 and A27) Preparation of foamable oil-in-water emulsified oil and fat compositions A26 and A27 According to Table 11, potassium sorbate was changed to 0.03 part by weight and 0.23 part by weight, and the amount of water was adjusted. Foamable oil-in-water emulsified oil / fat compositions A26 and A27 were obtained in the same manner as in Example A1. Their Aw were 0.965 (A26) and 0.962 (A27), respectively, and their pH was 4.7 (A26) and 5.4 (A27), respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A26 and A27 were measured, and the results are summarized in Table 11. The whipped cream X27 had a slightly bitter taste than the whipped cream X1.

Figure 2022080142000011
Figure 2022080142000011

(実施例A28、A29)起泡性水中油型乳化油脂組成物A28、A29の作製
表11に従って、クエン酸:0.10重量部、0.015重量部に変更し、水の量を調整した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A28、A29を得た。それらのAwはそれぞれ0.965(A28),0.965(A29)であり、pHはそれぞれ3.3(A28),5.8(A29)であった。得られた起泡性水中油型乳化油脂組成物A28、A29のメジアン径の測定を行い、それらの結果を表11にまとめた。
(Examples A28 and A29) Preparation of foamable oil-in-water emulsified oil and fat compositions A28 and A29 According to Table 11, citric acid was changed to 0.10 parts by weight and 0.015 parts by weight, and the amount of water was adjusted. Foamable oil-in-water emulsified oil / fat compositions A28 and A29 were obtained in the same manner as in Example A1 except for the above. Their Aw were 0.965 (A28) and 0.965 (A29), respectively, and their pH was 3.3 (A28) and 5.8 (A29), respectively. The median diameters of the obtained foamable oil-in-water emulsified oil / fat compositions A28 and A29 were measured, and the results are summarized in Table 11.

(実施例X26~X29)ホイップドクリームX26~X29の作製
実施例A26~A29で得られた起泡性水中油型乳化油脂組成物A26~A29をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX26~X29を得た。得られたホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表11にまとめた。なお、ホイップドクリームX28はホイップドクリームX1と比べわずかに酸味が感じられるものであった。
(Examples X26 to X29) Preparation of whipped creams X26 to X29 The foamable oil-in-water emulsified oil and fat compositions A26 to A29 obtained in Examples A26 to A29 are whipped and whipped in the same manner as in Example X1, respectively. Docreams X26-X29 were obtained. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of each of the obtained whipped creams were evaluated, and the results are summarized in Table 11. The whipped cream X28 had a slightly more sour taste than the whipped cream X1.

表11にまとめた結果より、以下のことがわかった。実施例X1、X26、X27より、起泡性水中油型乳化油脂組成物全体中のソルビン酸カリウムの含有量が0.01~0.25重量%の範囲において本発明の効果を奏することが明らかとなった。また、該含有量が0.10重量%である実施例X1と0.03重量%である実施例X26とを比べると、該含有量が少ないX26の方が静菌作用が低かったことから、前記含有量が0.01重量%より低いと静菌作用が常温販売に十分な強さとならないことが推察された。また、該含有量が0.10重量%である実施例X1と0.23重量%である実施例X27とを比べると、該含有量が多いX27はわずかに苦味が感じられるものであったことから、0.25重量%より高いと苦味が強くなり過ぎてしまう場合があることが推察された。 From the results summarized in Table 11, the following was found. From Examples X1, X26, and X27, it is clear that the effect of the present invention is exhibited in the range of the content of potassium sorbate in the whole foamable oil-in-water emulsified oil / fat composition in the range of 0.01 to 0.25% by weight. It became. Further, when the Example X1 having the content of 0.10% by weight and the Example X26 having the content of 0.03% by weight were compared, the bacteriostatic effect was lower in the X26 having the smaller content. It was speculated that if the content was lower than 0.01% by weight, the bacteriostatic action would not be sufficient for normal temperature sales. Further, when the Example X1 having the content of 0.10% by weight and the Example X27 having the content of 0.23% by weight were compared, the X27 having a large content had a slightly bitter taste. Therefore, it was inferred that if the content is higher than 0.25% by weight, the bitterness may become too strong.

また、実施例X1、X28、X29より、起泡性水中油型乳化油脂組成物全体中のpHが3~6の範囲において本発明の効果を奏することが明らかとなった。また、pH4.9である実施例X1とpH3.3である実施例X28とを比べると、pHが低いX28はわずかに酸味が感じられるものであったことから、pHが3より低いと酸味が強くなり過ぎてしまうことが推察された。また、pH4.9である実施例X1とpH5.8である実施例X29とを比べると、pHが高いX29の方が静菌作用が弱く評価値が3であったことから、pHが6より高いと静菌作用が常温販売に十分な強さとならない場合があることが推察された。 Further, from Examples X1, X28, and X29, it was clarified that the effect of the present invention is exhibited in the range of pH in the whole foamable oil-in-water emulsified oil / fat composition in the range of 3 to 6. Further, comparing Example X1 having a pH of 4.9 and Example X28 having a pH of 3.3, X28 having a low pH had a slightly sour taste. Therefore, when the pH was lower than 3, the sour taste was felt. It was inferred that it would become too strong. Further, comparing Example X1 having a pH of 4.9 and Example X29 having a pH of 5.8, the pH of X29 was higher than that of 6 because the bacteriostatic effect was weaker and the evaluation value was 3. It was speculated that if it was high, the bacteriostatic action might not be strong enough for normal temperature sales.

(実施例A30)起泡性水中油型乳化油脂組成物A30の作製
表12に従って、殺菌後の高圧ホモジナイザーの圧力を1段目50.0MPa/2段目10.0MPaに変更した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A30を得た。起泡性水中油型乳化油脂組成物A30のAwは0.965、pHは4.9であった。得られた起泡性水中油型乳化油脂組成物A30のメジアン径の測定を行い、結果を表12にまとめた。
(Example A30) Preparation of foamable oil-in-water emulsified oil / fat composition A30 Examples except that the pressure of the high-pressure homogenizer after sterilization was changed to 50.0 MPa in the first stage and 10.0 MPa in the second stage according to Table 12. In the same manner as in A1, a foamable oil-in-water emulsified oil / fat composition A30 was obtained. The foamable oil-in-water emulsified oil / fat composition A30 had an Aw of 0.965 and a pH of 4.9. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A30 was measured, and the results are summarized in Table 12.

Figure 2022080142000012
Figure 2022080142000012

(実施例A31)起泡性水中油型乳化油脂組成物A31の作製
表12に従って、殺菌後の高圧ホモジナイザーの圧力を1段目6.0MPa/2段目2.0MPaに変更した以外は実施例A1と同様にして、起泡性水中油型乳化油脂組成物A31を得た起泡性水中油型乳化油脂組成物A31のAwは0.965、pHは4.9であった。得られた起泡性水中油型乳化油脂組成物A31のメジアン径の測定を行い、結果を表12にまとめた。
(Example A31) Preparation of foamable oil-in-water emulsified oil / fat composition A31 Example except that the pressure of the high-pressure homogenizer after sterilization was changed to 6.0 MPa in the first stage / 2.0 MPa in the second stage. In the same manner as in A1, the foamable oil-in-water emulsified oil / fat composition A31 was obtained, and the foamable oil-in-water emulsified oil / fat composition A31 had an Aw of 0.965 and a pH of 4.9. The median diameter of the obtained foamable oil-in-water emulsified oil / fat composition A31 was measured, and the results are summarized in Table 12.

(実施例X30、X31)ホイップドクリームX30、X31の作製
実施例A30、A31で得られた起泡性水中油型乳化油脂組成物A30、A31をそれぞれ実施例X1と同様にしてホイップし、ホイップドクリームX30、X31を得た。得られたホイップドクリームそれぞれのオーバーラン、保型性、離水耐性、静菌作用、口溶け、甘さの評価を行い、それらの結果を表12にまとめた。
(Examples X30 and X31) Preparation of whipped creams X30 and X31 The foamable oil-in-water emulsified oil and fat compositions A30 and A31 obtained in Examples A30 and A31 are whipped and whipped in the same manner as in Example X1, respectively. Docream X30 and X31 were obtained. The overrun, shape retention, water separation resistance, bacteriostatic action, melting in the mouth, and sweetness of each of the obtained whipped creams were evaluated, and the results are summarized in Table 12.

表12にまとめた結果より、以下のことがわかった。実施例X1、X30、X31より、水中油型乳化油脂組成物の油滴のメジアン径が0.1~1.2μmの範囲において本発明の効果を奏することが明らかとなった。また、該値が0.552μmである実施例A1と該値が1.192μmである実施例X31とを比べると、実施例X31の方が保形性及び離水耐性の評価値が低く3であったことから、該値が1.2μmを上回ると常温販売に十分な保形性や離水耐性を得られないことが推察された。更に、該値が0.552μmである実施例A1と該値が0.246μmである実施例A30とを比べると、実施例A30の方がオーバーランの値及び口溶けの評価値が低く口溶けの評価値が3.4であったことから、該値が0.1μmを下回るとオーバーランが高くならず、口溶けが問題になるほど悪くなることが推察された。 From the results summarized in Table 12, the following was found. From Examples X1, X30, and X31, it was clarified that the effect of the present invention is exhibited in the range of the median diameter of the oil droplets of the oil-in-water emulsified oil / fat composition in the range of 0.1 to 1.2 μm. Further, when Example A1 having the value of 0.552 μm and Example X31 having the value of 1.192 μm are compared, the evaluation value of shape retention and water separation resistance is lower in Example X31, which is 3. From this, it was inferred that if the value exceeds 1.2 μm, sufficient shape retention and water separation resistance cannot be obtained for normal temperature sales. Further, when the example A1 having the value of 0.552 μm and the example A30 having the value of 0.246 μm are compared, the overrun value and the evaluation value of melting in the mouth are lower in the example A30, and the evaluation of melting in the mouth is evaluated. Since the value was 3.4, it was inferred that if the value was less than 0.1 μm, the overrun did not increase and the melting in the mouth became a problem.

また、水相部に油相部を添加して予備乳化した後の均質化の圧力条件が1段目:5~52MPa、2段目:3~12MPaの範囲において本発明の効果を好適に奏する水中油型乳化油脂組成物が得られることが明らかとなった。 Further, the effect of the present invention is suitably exhibited in the range of the pressure condition for homogenization after the oil phase portion is added to the aqueous phase portion and pre-emulsified in the range of the first stage: 5 to 52 MPa and the second stage: 3 to 12 MPa. It was clarified that an oil-in-water emulsified oil / fat composition can be obtained.

以上より、本発明に従えば、常温販売が容易にできるにもかかわらず、高オーバーランで、保形性及び離水耐性を有し、口溶けに問題がない甘さ控えめのホイップドクリーム、及びその原料となる起泡性水中油型乳化油脂組成物を提供することができることがわかった。 Based on the above, according to the present invention, a whipped cream having a high overrun, shape retention and water separation resistance, and a low sweetness that does not cause a problem in melting in the mouth, even though it can be easily sold at room temperature, and the whipped cream thereof. It was found that a foamable oil-in-water emulsified oil / fat composition as a raw material can be provided.

Claims (5)

起泡性水中油型乳化油脂組成物全体中、油脂を15~40重量%、水分を36~57重量%、糖類を17~23重量%(乾燥重量)、ソルビン酸カリウムを0.01~0.25重量%、タンパク質を0.048~0.8重量%含有し、乳化剤Aを0.3~0.5重量%、乳化剤Bを0.1~0.25重量%、乳化剤Cを0.1~0.25重量%含有し、且つ乳化剤B/乳化剤A(重量比)が0.2~0.67、乳化剤C/(乳化剤A+乳化剤B)(重量比)が0.14~0.5であり、多糖類Xを0.01~0.4重量%、多糖類Yを0.1~0.3重量%含有し、且つ多糖類Y/多糖類X(重量比)が0.25~30であり、カルシウムを2~75ppm含有し、
前記油脂全体中、油脂Aの含有量が48~100重量%であり、
前記起泡性水中油型乳化油脂組成物中の油滴のメジアン径が0.1~1.2μmであり、
pHが3~6である、
常温販売用ホイップドクリームの作製に用いる起泡性水中油型乳化油脂組成物。
油脂A:C12以下の飽和脂肪酸を構成脂肪酸全体中50~60重量%含み、25℃のSFCが20~85%、且つ35℃のSFCが3~15%である油脂。
乳化剤A:HLBが12~18、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリソルベート
乳化剤B:HLBが0~9、且つC16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含むポリグリセリン脂肪酸エステル
乳化剤C:C16~C18の飽和脂肪酸を合計で構成脂肪酸全体中90~100重量%含む、蒸留されたグリセリン酸脂肪酸モノエステル
多糖類X:脱アシル型ジェランガム
多糖類Y:2%水溶液の20℃での粘度が20~110mPa・sであるヒドロキシプロピルメチルセルロース
In the whole foamable oil-in-water emulsified oil / fat composition, oil / fat is 15-40% by weight, water content is 36-57% by weight, saccharide is 17-23% by weight (dry weight), and potassium sorbate is 0.01-0. .25% by weight, protein 0.048-0.8% by weight, emulsifier A 0.3-0.5% by weight, emulsifier B 0.1-0.25% by weight, emulsifier C 0. It contains 1 to 0.25% by weight, and emulsifier B / emulsifier A (weight ratio) is 0.2 to 0.67, and emulsifier C / (emulsifier A + emulsifier B) (weight ratio) is 0.14 to 0.5. It contains 0.01 to 0.4% by weight of the polysaccharide X, 0.1 to 0.3% by weight of the polysaccharide Y, and 0.25 to 0.25 to the polysaccharide Y / polysaccharide X (weight ratio). 30 and contains 2 to 75 ppm of calcium,
The content of the fat A is 48 to 100% by weight in the whole fat and oil.
The median diameter of the oil droplets in the foamable oil-in-water emulsified oil / fat composition is 0.1 to 1.2 μm.
The pH is 3-6,
A foamable oil-in-water emulsified oil / fat composition used for producing whipped cream for sale at room temperature.
Fats and oils A: Fats and oils containing 50 to 60% by weight of saturated fatty acids of C12 or less, 20 to 85% SFC at 25 ° C., and 3 to 15% SFC at 35 ° C.
Embroidery A: Polysolvate containing 12 to 18 HLB and 90 to 100% by weight of saturated fatty acids C 16 to C 18 in total Ester Ester B: Saturated fatty acids C 16 to C 18 with 0 to 9 HLB Polyglycerin fatty acid ester containing 90 to 100% by weight of the total constituent fatty acids Ester emulsifier C: Distilled glyceric acid fatty acid monoester containing 90 to 100% by weight of the saturated fatty acids of C 16 to C18 in the total constituent fatty acids. Polysaccharide X: Deacylated gellan gum Polysaccharide Y: Hydroxypropylmethylcellulose having a viscosity of a 2% aqueous solution at 20 ° C. of 20 to 110 mPa · s.
前記起泡性水中油型乳化油脂組成物中の乳化剤A、乳化剤B及び乳化剤Cの混合物のHLB(加重平均)が9.5~12.9である、請求項1に記載の起泡性水中油型乳化油脂組成物。 The foamable water according to claim 1, wherein the HLB (weighted average) of the mixture of emulsifier A, emulsifier B and emulsifier C in the foaming oil-type emulsified oil / fat composition is 9.5 to 12.9. Oil-type emulsified oil / fat composition. 請求項1又は2の何れかに記載の起泡性水中油型乳化油脂組成物がホイップされた、オーバーランが200~350%である常温販売用ホイップドクリーム。 A whipped cream for sale at room temperature having an overrun of 200 to 350%, to which the foamable oil-in-water emulsified oil / fat composition according to any one of claims 1 or 2 is whipped. 請求項3に記載の常温販売用ホイップドクリームを、サンド、ナッペ、フィリング、又はトッピングした食品。 A food product to which the whipped cream for sale at room temperature according to claim 3 is sandwiched, napped, filled, or topped. 起泡性水中油型乳化油脂組成物全体中、油脂を15~40重量%、水分を36~57重量%含有し、前記油脂全体中、油脂Aの含有量が48~100重量%であり、油滴のメジアン径が0.1~1.2μmである起泡性水中油型乳化油脂組成物の製造方法であって、水に、起泡性水中油型乳化油脂組成物全体中、乳化剤Aを0.3~0.5重量%、糖類を17~23重量%(乾燥重量)、ソルビン酸カリウムを0.01~0.25重量%、タンパク質を0.048~0.8重量%、多糖類Xを0.01~0.4重量%、多糖類Yを0.1~0.3重量%、カルシウムを2~75ppm含み、且つ多糖類Y/多糖類X(重量比)が0.25~30となるよう各々を溶解した水相部に、前記油脂に、起泡性水中油型乳化油脂組成物全体中、乳化剤Bを0.1~0.25重量%、乳化剤Cを0.1~0.25重量%含み、乳化剤B/乳化剤A(重量比)が0.2~0.67且つ乳化剤C/(乳化剤A+乳化剤B)(重量比)が0.14~0.5となるように各々を溶解した油相部を添加して予備乳化し、1段目5~52MPa/2段目3~12の圧力で均質化した後に、殺菌処理することを特徴とする、pHが3~6である、常温販売用ホイップドクリームの作製に用いる起泡性水中油型乳化油脂組成物の製造方法。 The foamable oil-in-water emulsified oil / fat composition contains 15 to 40% by weight of oil and fat and 36 to 57% by weight of water, and the content of oil and fat A is 48 to 100% by weight in the whole oil and fat. A method for producing a foamable oil-in-water emulsified oil / fat composition having a median diameter of oil droplets of 0.1 to 1.2 μm. 0.3-0.5% by weight, sugar 17-23% by weight (dry weight), potassium sorbate 0.01-0.25% by weight, protein 0.048-0.8% by weight, many It contains 0.01 to 0.4% by weight of saccharide X, 0.1 to 0.3% by weight of polysaccharide Y, 2 to 75 ppm of calcium, and 0.25 of polysaccharide Y / polysaccharide X (weight ratio). Emulsifier B is 0.1 to 0.25% by weight and emulsifier C is 0.1 in the whole foamable oil-in-water emulsified oil / fat composition in the aqueous phase portion in which each is dissolved so as to be ~ 30. Emulsifier B / emulsifier A (weight ratio) is 0.2 to 0.67 and emulsifier C / (emulsifier A + emulsifier B) (weight ratio) is 0.14 to 0.5. The oil phase portion in which each is dissolved is added to the emulsifier to pre-emulsify it, homogenize it at a pressure of 5 to 52 MPa in the first stage / 3 to 12 in the second stage, and then sterilize it. 6. A method for producing a foamable oil-in-water emulsified oil / fat composition used for producing a whipped cream for sale at room temperature.
JP2020191149A 2020-11-17 2020-11-17 Foamable oil-in-water type emulsified fat composition Pending JP2022080142A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2020191149A JP2022080142A (en) 2020-11-17 2020-11-17 Foamable oil-in-water type emulsified fat composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2020191149A JP2022080142A (en) 2020-11-17 2020-11-17 Foamable oil-in-water type emulsified fat composition

Publications (1)

Publication Number Publication Date
JP2022080142A true JP2022080142A (en) 2022-05-27

Family

ID=81731694

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2020191149A Pending JP2022080142A (en) 2020-11-17 2020-11-17 Foamable oil-in-water type emulsified fat composition

Country Status (1)

Country Link
JP (1) JP2022080142A (en)

Similar Documents

Publication Publication Date Title
CN107114551B (en) Frozen beverage added with high milk content and preparation method thereof
JP5721918B1 (en) Whipped cream and method for producing the same
US8603559B2 (en) Stable whippable and whipped food products
EP2688423B1 (en) Edible oil-in-water emulsion composition
EP2503904B1 (en) An emulsion whippable at room-temperature
US20210186043A1 (en) Non-hydrogenated mixed butterfat and non-dairy cream, and preparation method therefor
TWI607707B (en) Dairy products supressured in browning and producing method thereof
WO2011084570A1 (en) Yogurt topping
US20220346397A1 (en) Dairy product and process
JP2017086071A (en) Creaming powder having high emulsion stability
JP2011244735A (en) Oil-in-water emulsified oil and fat composition ineaded into pudding
JP6612491B2 (en) Edible cream and method for producing the same
JP6061263B2 (en) Gel-like food and method for producing the same
EP1662899B1 (en) Uht treated 100 % non dairy whipping cream
CN110839707B (en) Normal-temperature low-acid gel type milk-containing dessert capable of preventing browning and preparation method thereof
JP2022080142A (en) Foamable oil-in-water type emulsified fat composition
JP5877605B2 (en) Gel-like food for energy supply and method for producing the same
JP7312922B2 (en) Foamable oil-in-water emulsified fat composition, whipped cream for normal temperature sale, food, and method for producing the foamable oil-in-water emulsified fat composition
JP2022080141A (en) Foamable oil-in-water type emulsified fat composition
CA3171465A1 (en) Phase-stable protein beverage and methods of making same
JP2003325104A (en) Foamable oil-in-water emulsified oil-and-fat composition, air-containing oil-in-water emulsified oil-and-fat composition
JP6359437B2 (en) Frozen dessert and method for producing the same
JP2022155220A (en) Foamable oil-in-water type emulsified oil and fat composition
JP2022053326A (en) Foamable oil-in-water type emulsified fat composition
JP2022155219A (en) Foamable oil-in-water type emulsified oil and fat composition

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20230906