JP2022042092A - Stationery writing tool - Google Patents

Stationery writing tool Download PDF

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JP2022042092A
JP2022042092A JP2020147295A JP2020147295A JP2022042092A JP 2022042092 A JP2022042092 A JP 2022042092A JP 2020147295 A JP2020147295 A JP 2020147295A JP 2020147295 A JP2020147295 A JP 2020147295A JP 2022042092 A JP2022042092 A JP 2022042092A
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writing
pen core
writing tool
ink
pen
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JP7503456B2 (en
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徹 中島
Toru Nakajima
瑛太 中田
Eita Nakata
俊史 神谷
Toshifumi Kamiya
弥 佐川
Wataru Sagawa
彩 米谷
Aya Yonetani
新也 六樂内
Shinya Murauchi
千絵 福田
Chie Fukuda
菜美子 江藤
Namiko Eto
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Mitsubishi Pencil Co Ltd
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Mitsubishi Pencil Co Ltd
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Abstract

To provide a writing tool capable of reducing the shaft diameter of the writing tool while maintaining the writing line width even if a thick pen core is used.SOLUTION: It is a writing tool A capable of writing by supplying ink 15 in a shaft cylinder 10 which is a writing tool main body to a pen core 30 provided on the tip side of the shaft cylinder, and is provided with a step portion whose diameter expands in a radial direction on the outer circumference of the pen core and the writing tool is characterized in that a space for air replacement is formed in the axial direction of the maximum outer diameter portion.SELECTED DRAWING: Figure 1

Description

本発明は、筆記描線幅が太めとなるペン芯を用いても、その筆記描線幅を維持しつつ、筆記具の軸径を細くできる筆記具に関する。 The present invention relates to a writing instrument capable of reducing the shaft diameter of a writing instrument while maintaining the writing line width even when a pen core having a thick writing line width is used.

従来より、筆記具において、筆記描線幅が太めとなる太めのペン芯を用いる場合にはそれに合わせて筆記具の軸径も太くなるものであり、また、筆記描線幅が細いものなる細めのペン芯を用いる場合にはそれに合わせて筆記具の軸径も細いものであった。
筆記描線幅が太めとなるペン芯を備えたマーキングペンなどは、軸径も太いものであるため、筆箱などに収納する場合、スペースを取り、例えば、ペン芯が太い複数本のマーキングペンと軸径が細い筆記具などを一緒に筆箱に収容する場合、筆箱自体大きいサイズを用意しなければならないなどの煩わしさがあった。
Conventionally, when a thick pen core having a wide writing line width is used in a writing instrument, the shaft diameter of the writing instrument is also increased accordingly, and a thin pen core having a narrow writing line width is used. When used, the shaft diameter of the writing instrument was also small accordingly.
Marking pens equipped with a pen core with a wide writing line width have a large shaft diameter, so when storing them in a pencil case, take up space, for example, multiple marking pens and shafts with a thick pen core. When storing a writing tool with a small diameter in a pencil case together, there is a trouble such as having to prepare a large size of the pencil case itself.

筆記具のペン芯の大きさ、形状、インク供給機構などを考慮した筆記具としては、例えば、
1) ペン先とインキを収容する本体部の間にバルブ機構を 備え、ペン先の押圧によりバルブ機構が開放し、本体部内のインキがペン先に誘導される筆記具であって、キャップ体装着時にバルブ機構が開放されていることを特徴とする筆記具(例えば、特許文献1参照)。
2) 複数のペン体を有し、軸筒に設けたインク貯蔵部内のインクをペン体に供給するマーキングペンにおいて、ペン体はインクを導通する材料からなり、複数のペン体同士が直接接して前記インク貯蔵部内のインクがペン体に導通可能に連結されていることを特徴とするマーキングペン(例えば、特許文献2参照)
3) 軸筒と、該軸筒に収容されるインキ吸蔵体と、該インキ吸蔵体に接続される交換可能なペン先とからなるペン先交換式筆記具であって、交換後ペン先のインキ吸蔵体との差し込み長さが、交換前ペン先のインキ吸蔵体との差し込み長さより長いことを特徴とするペン先交換式筆記具、並びに、前記ペン先が係止用段部と、該係止用段部の前方に形成される縮径部とを備え、交換後ペン先の縮径部の長さが、交換前ペン先の縮径部の長さより長いことを特徴とするペン先交換式筆記具(例えば、特許文献3参照)、
4) 筆記具軸筒の先端部に、細いペン先体より、太い径の太ペン先体を装着したホルダを着脱自在に装着し、装着した状態で、細いペン先体の先端面と太ペン先体の後端面とが接触するように設けたことを特徴とする筆記具(例えば、特許文献4参照)
As a writing instrument considering the size, shape, ink supply mechanism, etc. of the pen core of the writing instrument, for example,
1) A writing tool that has a valve mechanism between the pen tip and the main body that stores ink, and the valve mechanism is opened by pressing the pen tip, and the ink in the main body is guided to the pen tip. A writing instrument characterized in that the valve mechanism is open (see, for example, Patent Document 1).
2) In a marking pen that has a plurality of pen bodies and supplies ink in an ink storage unit provided in a barrel to the pen body, the pen body is made of a material that conducts ink, and the plurality of pen bodies are in direct contact with each other. A marking pen characterized in that the ink in the ink storage unit is conductively connected to the pen body (see, for example, Patent Document 2).
3) A pen tip exchangeable writing tool consisting of a shaft cylinder, an ink storage body housed in the shaft cylinder, and a replaceable pen tip connected to the ink storage body, and the ink storage of the pen tip after replacement. A pen tip exchangeable writing tool characterized in that the insertion length with the body is longer than the insertion length of the pen tip before replacement with the ink storage body, and the pen tip is for locking and for locking. A pen tip exchange type writing tool provided with a reduced diameter portion formed in front of the step portion, wherein the length of the reduced diameter portion of the pen tip after replacement is longer than the length of the reduced diameter portion of the pen tip before replacement. (See, for example, Patent Document 3),
4) A holder with a thick pen tip with a thicker diameter than a thin pen tip is detachably attached to the tip of the writing instrument shaft tube, and with the holder attached, the tip surface of the thin pen tip and the thick pen tip A writing tool provided so as to be in contact with the rear end surface of the body (see, for example, Patent Document 4).

しかしながら、上記特許文献1~3の筆記具等は、ペン先体などの外径の変化はなく、筆記具の軸径を細くできるという技術思想はないものである。上記特許文献4の筆記具は、細いペン先体に、太い径の太ペン先体を装着したホルダを単に着脱自在に装着したものであり、筆記具の軸径を変化させずに、筆記目的に応じて、細いペン先体又は太いペン先体による筆記により、筆記描線の太さを選択することができるものであるが、太いペン先体による筆記の場合に、空気置換などは考慮されておらず、良好な筆記を行うことができないなどの課題があるものである。 However, the writing tools of Patent Documents 1 to 3 do not have a change in the outer diameter of the pen tip or the like, and there is no technical idea that the shaft diameter of the writing tool can be reduced. The writing tool of Patent Document 4 is a thin pen tip to which a holder with a thick pen tip of a thick diameter is simply detachably attached, and the shaft diameter of the writing tool is not changed, depending on the purpose of writing. Therefore, the thickness of the writing line can be selected by writing with a thin pen tip or a thick pen tip, but in the case of writing with a thick pen tip, air replacement etc. are not considered. , There are problems such as not being able to write well.

特開2008-265147号公報(特許請求の範囲、図1~図4)Japanese Unexamined Patent Publication No. 2008-265147 (Claims, FIGS. 1 to 4) 特開2017- 52248号公報(特許請求の範囲、図1等)JP-A-2017-52248 (Claims, FIG. 1, etc.) 特開2005-131896号公報(特許請求の範囲、図1~図4)JP-A-2005-131896 (Claims, FIGS. 1 to 4) 特開2012-176527号公報(特許請求の範囲、図1~図4)Japanese Unexamined Patent Publication No. 2012-176527 (Claims, FIGS. 1 to 4)

本発明は、上記従来技術の課題などに鑑み、これを解消しようとするものであり、筆記描線幅が太めとなる太めのペン芯を用いても、その筆記描線幅を維持しつつ、筆記具の軸径を細くできる筆記具などを提供することを目的とする。 The present invention is to solve this problem in view of the above-mentioned problems of the prior art, and even if a thick pen core having a thick writing line width is used, the writing instrument can be used while maintaining the writing line width. The purpose is to provide a writing instrument that can reduce the shaft diameter.

本発明者らは、上記従来の課題等を解決するために鋭意検討した結果、筆記具本体となる軸筒内のインクを軸筒の先端側に設けたペン芯に供給して筆記可能となる筆記具であって、前記ペン芯の外周を特定構造とすると共に、最大外径部の軸線方向に特定の構造を形成することにより、上記目的の筆記具が得られることを見出し、本発明を完成するに至ったのである。 As a result of diligent studies to solve the above-mentioned conventional problems, the present inventors supply ink in the barrel, which is the main body of the writing instrument, to the pen core provided on the tip side of the barrel to enable writing. The present invention has been completed by finding that the writing instrument of the above object can be obtained by forming a specific structure on the outer periphery of the pen core and forming a specific structure in the axial direction of the maximum outer diameter portion. It came.

すなわち、本発明の筆記具は、筆記具本体となる軸筒内のインクを軸筒の先端側に設けたペン芯に供給して筆記可能となる筆記具であって、前記ペン芯の外周に径方向に拡径する段部を設けると共に、最大外径部の軸線方向に空気置換用の空間部を形成したことを特徴とする。
軸筒内には弁機構を備えると共に、ペン芯の後端部の最小外径部は、弁機構の弁体と連結していることが好ましい。
上記構成の筆記具に用いるペン芯であって、該ペン芯は外周にホルダ部材と内周に細ペン芯とで構成し、かつ、上記構成の筆記具のペン芯と互いに交換可能な構造であることが好ましい。
本発明の筆記具セットは、上記構成の筆記具と、上記構成のペン芯とからなることを特徴とする。
That is, the writing instrument of the present invention is a writing instrument capable of writing by supplying ink in a shaft cylinder, which is a writing instrument main body, to a pen core provided on the tip side of the shaft cylinder, and is capable of writing on the outer periphery of the pen core in the radial direction. It is characterized by providing a step portion for expanding the diameter and forming a space portion for air replacement in the axial direction of the maximum outer diameter portion.
It is preferable that the shaft cylinder is provided with a valve mechanism and the minimum outer diameter portion of the rear end portion of the pen core is connected to the valve body of the valve mechanism.
The pen core used for the writing tool having the above configuration, the pen core is composed of a holder member on the outer circumference and a fine pen core on the inner circumference, and has a structure that can be exchanged with the pen core of the writing tool having the above configuration. Is preferable.
The writing tool set of the present invention is characterized by comprising the writing tool having the above structure and the pen core having the above structure.

本発明によれば、筆記描線幅が太めとなる太めのペン芯を用いても、その筆記描線幅を維持しつつ、筆記具の軸径を細く(スリム化)できる筆記具が提供される。
また、本発明の筆記具セットによれば、太ペン芯と細ペン芯との交換により生じるインク供給の不良などはなく、スムーズなインクの供給、太め、細めの良好な筆記描線が得られるものとなる。
本発明の目的及び効果は、特に請求項において指摘される構成要素及び組み合わせを用いることによって認識され且つ得られるものである。上述の一般的な説明及び後述の詳細な説明の両方は、例示的及び説明的なものであり、特許請求の範囲に記載されている本発明を制限するものではない。
According to the present invention, there is provided a writing instrument capable of reducing (slimming) the shaft diameter of a writing instrument while maintaining the writing line width even if a thick pen core having a thick writing line width is used.
Further, according to the writing tool set of the present invention, there is no defect in ink supply caused by replacement of the thick pen core and the thin pen core, and smooth ink supply and good writing lines of thick and thin can be obtained. Become.
The object and effect of the present invention are recognized and obtained particularly by using the components and combinations pointed out in the claims. Both the general description above and the detailed description below are exemplary and descriptive and do not limit the invention described in the claims.

本発明の実施形態の一例を示す筆記具の図面であり、(a)は正面図、(b)は縦断面図である。It is a drawing of the writing instrument which shows an example of the Embodiment of this invention, (a) is a front view, (b) is a vertical sectional view. 図1の筆記具に用いるペン芯の図面であり、(a)は斜視図、(b)は平面図、(c)は左側面図、(d)は正面図、(e)は右側面図である。It is a drawing of the pen core used for the writing tool of FIG. 1, (a) is a perspective view, (b) is a plan view, (c) is a left side view, (d) is a front view, (e) is a right side view. be. 本発明の実施形態の他例を示す筆記具の図面であり、(a)は正面図、(b)は縦断面図である。It is the drawing of the writing instrument which shows the other example of embodiment of this invention, (a) is a front view, (b) is a vertical sectional view. 図3の筆記具に用いるペン芯の図面であり、(a)は斜視図、(b)は平面図、(c)は左側面図、(d)は正面図、(e)は右側面図、(f)は縦断面図である。3A is a drawing of a pen core used for a writing tool, (a) is a perspective view, (b) is a plan view, (c) is a left side view, (d) is a front view, and (e) is a right side view. (F) is a vertical sectional view. 本発明の筆記具に用いるペン芯の他例を示す図面であり、(a)は斜視図、(b)は平面図、(c)は左側面図、(d)は正面図、(e)は右側面図である。It is a drawing which shows the other example of the pen core used for the writing tool of this invention, (a) is a perspective view, (b) is a plan view, (c) is a left side view, (d) is a front view, (e) is. It is a right side view. 本発明の実施形態の他例を示す筆記具の図面であり、(a)は正面図、(b)は縦断面図である。It is the drawing of the writing instrument which shows the other example of embodiment of this invention, (a) is a front view, (b) is a vertical sectional view. 図6の筆記具において、ペン芯の後端部と弁機構の弁部とを連結する連結部材となる把持用コマ部材の一例を示す図面であり、(a)は斜視図、(b)は正面図、(c)は縦断面図である。6 is a drawing showing an example of a gripping top member serving as a connecting member for connecting the rear end portion of the pen core and the valve portion of the valve mechanism in the writing tool of FIG. 6, where FIG. 6A is a perspective view and FIG. 6B is a front view. FIG. 3C is a vertical sectional view.

以下に、本発明の実施形態について図面を参照しながら詳しく説明する。但し、本発明の技術的範囲は下記で詳述するそれぞれの実施の形態に限定されず、特許請求の範囲に記載された発明とその均等物に及ぶ点に留意されたい。 Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. However, it should be noted that the technical scope of the present invention is not limited to the respective embodiments detailed below, but extends to the inventions described in the claims and their equivalents.

図1は、本発明の実施形態の一例を示す筆記具の正面図と縦断面図であり、図2は図1の筆記具に用いるペン芯の各図面である。
本実施形態の筆記具Aは、図1~図2に示すように、筆記具本体となる軸筒10と、該軸筒10内に直接収容した筆記具用インク15と、先軸20、ペン芯30、弁機構40とを少なくとも有し、筆記具本体となる軸筒10内のインク15を軸筒10の先端側に固着した先軸20に保持したペン芯30に供給して筆記可能とするものである。
FIG. 1 is a front view and a vertical sectional view of a writing tool showing an example of an embodiment of the present invention, and FIG. 2 is a drawing of a pen core used for the writing tool of FIG.
As shown in FIGS. 1 to 2, the writing tool A of the present embodiment includes a shaft cylinder 10 which is a writing tool main body, a writing tool ink 15 directly housed in the shaft cylinder 10, a tip shaft 20, and a pen core 30. It has at least a valve mechanism 40, and supplies ink 15 in a shaft cylinder 10 which is a writing tool main body to a pen core 30 held on a tip shaft 20 fixed to the tip end side of the shaft cylinder 10 to enable writing. ..

筆記具本体となる軸筒10は、例えば、ポリアセタール系樹脂、ポリエチレン系樹脂、アクリル系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、ポリウレタン系樹脂、ポリオレフィン系樹脂、ポリビニル系樹脂、ポリカーボネート系樹脂、ポリエーテル系樹脂、ポリフェニレン系樹脂などの熱可塑性樹脂、熱硬化性樹脂(以下、上記各々の樹脂を単に「各樹脂」という)や金属等を用いて形成されるものであり、筒状体で、後端部は閉鎖しており、先端側は開口部11となっており、その開口部11内には先軸20が嵌合により固着されている。 The shaft cylinder 10 serving as the main body of the writing tool is, for example, a polyacetal resin, a polyethylene resin, an acrylic resin, a polyester resin, a polyamide resin, a polyurethane resin, a polyolefin resin, a polyvinyl resin, a polycarbonate resin, or a polyether resin. It is formed by using a resin, a thermoplastic resin such as a polyphenylene resin, a thermosetting resin (hereinafter, each of the above resins is simply referred to as "each resin"), a metal, or the like, and is a tubular body at the rear end. The portion is closed, the tip end side is an opening 11, and the toe shaft 20 is fixed in the opening 11 by fitting.

軸筒10内に収容される筆記具用インク15の組成は、特に限定されず、筆記具の用途等に応じて、水性インク、油性インク、熱変色性インクなどの好適な配合処方とすることができ、例えば、アンダーラインペン等ではインクに蛍光色素、例えば、ベーシックバイオレット11、ベーシックイエロー40などを用いることができ、また、熱変色性マイクロカプセル顔料などを含有させることができる。 The composition of the writing instrument ink 15 housed in the shaft cylinder 10 is not particularly limited, and a suitable compounding formulation such as a water-based ink, an oil-based ink, and a heat-discoloring ink can be prepared according to the use of the writing instrument and the like. For example, in an underline pen or the like, a fluorescent dye such as Basic Violet 11, Basic Yellow 40 or the like can be used in the ink, and a heat-discolorable microcapsule pigment or the like can be contained in the ink.

より好適には、水と、水溶性有機溶剤と、着色剤と、グリセリルグルコシドとを少なくとも含む筆記具用インクを組成物とすることで、ペン先乾燥の抑制効果に優れ、筆跡の表面が早く乾燥して筆跡を擦っても伸びず、低温環境下においても筆跡がカスレたりすることをさらに防ぐことができる。 More preferably, by using a writing instrument ink containing at least water, a water-soluble organic solvent, a colorant, and glyceryl glucoside as a composition, the effect of suppressing the drying of the pen tip is excellent, and the surface of the handwriting dries quickly. Even if the handwriting is rubbed, it does not stretch, and it is possible to further prevent the handwriting from being scratched even in a low temperature environment.

用いるグリセリルグルコシドとは、グリセリンとグルコースがα結合で縮合したαグリセリルグルコシドと、β結合で縮合したβグリセリルグルコシドであり、マルトオリゴ糖とグリセリンの混合液にα-グルコシダーゼを作用させることで得られる酵素反応生成物であっても、グリセリンとグルコースの縮合反応によって得られる生成物であっても良い。グリセリルグルコシドとしては、αグリセリルグルコシドとβグリセリルグルコシドが挙げられ、αグリセリルグルコシドがより好ましく、αグリセリルグルコシドの具体例としてαGG、αGG-L(以上、JST株式会社製)などが挙げられる。これらのグリセリルグルコシドの添加量はインク組成物全量に対し、0.5質量%以上30.0質量%以下が好ましい。これらのグリセリルグルコシドは、単独、あるいは2種以上混合して使用しても良い。 The glyceryl glucoside used is α-glyceryl glucoside in which glycerin and glucose are condensed by α bond and β glyceryl glucoside condensed by β bond, and is an enzyme obtained by allowing α-glucosidase to act on a mixed solution of maltooligosaccharide and glycerin. It may be a reaction product or a product obtained by a condensation reaction of glycerin and glucose. Examples of the glyceryl glucoside include α-glyceryl glucoside and β-glyceryl glucoside, more preferably α-glyceryl glucoside, and specific examples of the α-glyceryl glucoside include αGG and αGG-L (all manufactured by JST Co., Ltd.). The amount of these glyceryl glucosides added is preferably 0.5% by mass or more and 30.0% by mass or less with respect to the total amount of the ink composition. These glyceryl glucosides may be used alone or in combination of two or more.

筆記具用インクで用いることができる水としては、水道水、地下水、イオン交換水、純水、超純水などが挙げられ、特に限定されることなく使用できる。 Examples of the water that can be used for the ink for writing tools include tap water, groundwater, ion-exchanged water, pure water, ultrapure water, and the like, and can be used without particular limitation.

筆記具用インクで用いることができる着色剤は、特に制限されることなく染料、顔料が使用できる。 The colorant that can be used in the ink for writing tools is not particularly limited, and dyes and pigments can be used.

染料は、水溶性染料が使用できる。水溶性染料の具体的としては、直接染料、酸性染料、塩基性染料などが挙げられる。これらの染料は、単独、あるいは2種以上混合して使用しても良い。 As the dye, a water-soluble dye can be used. Specific examples of the water-soluble dye include direct dyes, acid dyes, and basic dyes. These dyes may be used alone or in combination of two or more.

顔料の具体例としては、ファーネストブラック、コンタクトブラック、サーマルブラック、アセチレンブラックなどのカーボンブラック、黒色酸化鉄、黄色酸化鉄、赤色酸化鉄、群青、紺青、コバルトブルー、チタンイエロー、ターコイズ、モリブデートオレンジ、酸化チタン、金粉、銀粉、銅粉、アルミニウム粉、真鍮粉、錫粉、雲母系顔料、C.I.PIGMENT RED 2、同3、同5、同17、同22、同38、同41、同48:2、同48:3、同49、同50:1、同53:1、同57:1、同58:2、同60、同63:1、同63:2、同64:1、同88、同112、同122、同123、同144、同146、同149、同166、同168、同170、同176、同177、同178、同179、同180、同185、同190、同194、同206、同207、同209、同216、同245、C.I.PIGMENT ORANGE 5、同10、同13、同16、同36、同40、同43、C.I.PIGMENT VIOLET 19、同23、同31、同33、同36、同38、同50、C.I.PIGMENT BLUE 2、同15、同15:1、同15:2、同15:3、同15:4、同15:5、同16、同17、同22、同25、同60、同66、C.I.PIGMENT BROWN 25、同26、C.I.PIGMENT YELLOW 1、同3、同12、同13、同24、同93、同94、同95、同97、同99、同108、同109、同110、同117、同120、同139、同153、同166、同167、同173、C.I.PIGMENT GREEN 7、同10、同36、などが挙げられる。これらの顔料は、単独、あるいは2種以上混合して使用しても良い。また、着色剤として顔料と染料を併用して用いることもできる。 Specific examples of pigments include carbon black such as furnest black, contact black, thermal black, and acetylene black, black iron oxide, yellow iron oxide, red iron oxide, ultramarine, navy blue, cobalt blue, titanium yellow, turquoise, and molybdate. Orange, titanium oxide, gold powder, silver powder, copper powder, aluminum powder, brass powder, tin powder, mica pigment, C.I. I. PIGMENT RED 2, same 3, same 5, same 17, same 22, same 38, same 41, same 48: 2, same 48: 3, same 49, same 50: 1, same 53: 1, same 57: 1, 58: 2, 60, 63: 1, 63: 2, 64: 1, 88, 112, 122, 123, 144, 146, 149, 166, 168, 170, 176, 177, 178, 179, 180, 185, 190, 194, 206, 207, 209, 216, 245, C.I. I. PIGMENT ORANGE 5, 10, 13, 16, 16, 36, 40, 43, C.I. I. PIGMENT VIOLET 19, 23, 31, 33, 36, 38, 50, C.I. I. PIGMENT BLUE 2, 15: 1, 15: 2, 15: 3, 15: 4, 15: 5, 16, 17, 17, 22, 25, 60, 66, C. I. PIGMENT BROWN 25, 26, C.I. I. PIGMENT YELLOW 1, same 3, same 12, same 13, same 24, same 93, same 94, same 95, same 97, same 99, same 108, same 109, same 110, same 117, same 120, same 139, same 153, 166, 167, 173, C.I. I. PIGMENT GREEN 7, 10, 36, and the like can be mentioned. These pigments may be used alone or in combination of two or more. Further, a pigment and a dye can be used in combination as a colorant.

着色剤に顔料を用いた場合は、顔料を安定に分散させるために分散剤を使用することもできる。分散剤として、従来一般に用いられている水溶性樹脂もしくは水可溶性樹脂や、アニオン系もしくはノニオン系の界面活性剤などの、顔料の分散剤として用いられるものを用いることができる。これらの水可溶性樹脂および界面活性剤の添加量は顔料10.0重量%に対し、0.05質量%以上20.0質量%以下が好ましい。これらの水可溶性樹脂および界面活性剤は、単独、あるいは2種以上混合して使用しても良い。 When a pigment is used as the colorant, a dispersant can also be used in order to stably disperse the pigment. As the dispersant, those used as dispersants for pigments, such as water-soluble resins or water-soluble resins generally used in the past, and anionic or nonionic surfactants, can be used. The amount of these water-soluble resins and surfactants added is preferably 0.05% by mass or more and 20.0% by mass or less with respect to 10.0% by weight of the pigment. These water-soluble resins and surfactants may be used alone or in combination of two or more.

また、顔料を水性媒体に分散した顔料分散体も用いることができる。顔料分散体としては、無機顔料、有機顔料、蛍光顔料などが使用でき、単独、あるいは2種以上混合して使用しても良い。ただし、着色された樹脂粒子を着色剤として用いる場合は、樹脂粒子が有機溶剤に溶解しないものを用いる。 Further, a pigment dispersion in which the pigment is dispersed in an aqueous medium can also be used. As the pigment dispersion, an inorganic pigment, an organic pigment, a fluorescent pigment and the like can be used, and they may be used alone or in combination of two or more. However, when the colored resin particles are used as a colorant, those in which the resin particles are not dissolved in an organic solvent are used.

上記で記載された着色剤以外に、色味を調整するために樹脂粒子やワックス粒子、樹脂エマルションのような無色粒子を用いることができる。中でも酸化ポリエチレンワックス粒子を用いることで筆跡の裏移りを同時に抑制することができる。 In addition to the colorants described above, colorless particles such as resin particles, wax particles, and resin emulsions can be used to adjust the color. Above all, by using polyethylene oxide wax particles, it is possible to suppress the set-off of handwriting at the same time.

着色剤、無色粒子に限らず、筆記具用インク中の固形分濃度を25質量%以上にすることで筆跡の裏移りを抑制することができるため好ましい。また、酸化ポリエチレンワックス粒子を用いると筆記具インク中の固形分濃度が25質量%以下であっても筆跡の裏移りを抑制でき、酸化ポリエチレンワックス粒子の含有量は、インク組成物全量に対し、0.1質量%以上50.0質量%以下が好ましく、より好ましくは0.5質量%以上23.0質量%以下であり、最も好ましくは1.0質量%以上15.0質量%以下である。 Not limited to colorants and colorless particles, it is preferable to set the solid content concentration in the ink for writing tools to 25% by mass or more because the set-off of handwriting can be suppressed. Further, when the polyethylene oxide wax particles are used, even if the solid content concentration in the writing instrument ink is 25% by mass or less, the set-off of the brush stroke can be suppressed, and the content of the polyethylene oxide wax particles is 0 with respect to the total amount of the ink composition. .1% by mass or more and 50.0% by mass or less is preferable, more preferably 0.5% by mass or more and 23.0% by mass or less, and most preferably 1.0% by mass or more and 15.0% by mass or less.

筆記具用インクに用いられる水溶性有機溶剤は、水100gに対して10g以上溶解することのできる有機溶剤を示す。これらの水溶性有機溶剤の中でも、筆跡の紙への浸透性とペン先乾燥抑制の観点から、グリコールエーテルや環状構造を持つ水溶性有機溶剤が好ましく、環状構造を持つ水溶性有機溶剤がより好ましい。また、これらの水溶性有機溶剤の中でも、グリコールエーテル及び/または環状構造を持つ水溶性有機溶剤と多価アルコールとを併用することで、グリセリルグルコシドと水溶性有機溶剤との相互作用によって、ペン先乾燥の抑制と筆跡の紙への浸透性が一層向上するため好ましい。これらの水溶性有機溶剤の添加量は、インク組成物全量に対し0.1質量%以上50.0質量%以下が好ましく、5.0質量%以上20.0質量%以下がより好ましい。これらの水溶性有機溶剤は、単独、あるいは2種以上混合して使用しても良い。 The water-soluble organic solvent used in the ink for writing tools indicates an organic solvent capable of dissolving 10 g or more in 100 g of water. Among these water-soluble organic solvents, glycol ether and water-soluble organic solvents having a cyclic structure are preferable, and water-soluble organic solvents having a cyclic structure are more preferable, from the viewpoint of penetrability of handwriting into paper and suppression of pen tip drying. .. In addition, among these water-soluble organic solvents, by using a water-soluble organic solvent having a glycol ether and / or a cyclic structure in combination with a polyhydric alcohol, the pen tip is produced by the interaction between the glyceryl glucoside and the water-soluble organic solvent. It is preferable because it suppresses drying and further improves the permeability of the brush to the paper. The amount of these water-soluble organic solvents added is preferably 0.1% by mass or more and 50.0% by mass or less, and more preferably 5.0% by mass or more and 20.0% by mass or less with respect to the total amount of the ink composition. These water-soluble organic solvents may be used alone or in combination of two or more.

筆記具用水性インクの粘度は、測定温度25℃、剪断速度76.6s-1において1.0mPa・s以上20.0mPa・s以下が好ましい。また、表面張力は30~60mN/mであることが好ましい。 The viscosity of the water-based ink for writing tools is preferably 1.0 mPa · s or more and 20.0 mPa · s or less at a measurement temperature of 25 ° C. and a shear rate of 76.6 s- 1 . Further, the surface tension is preferably 30 to 60 mN / m.

上記成分の他に、必要に応じて、潤滑剤、粘度調整剤、潤滑剤、防腐剤、防黴剤、防錆剤、消泡剤、pH調整剤などの添加剤を併用して用いることができる。これらの、添加剤は、単独、あるいは2種以上混合して使用しても良い。 In addition to the above components, additives such as lubricants, viscosity regulators, lubricants, preservatives, fungicides, rust inhibitors, defoamers, and pH adjusters may be used in combination, if necessary. can. These additives may be used alone or in combination of two or more.

筆記具用水性インクを製造するには、上記の顔料及び/又は顔料分散体と、染料とから選ばれる1種もしくは2種以上の着色剤と、水及び/又は有機溶剤と、分散剤と、をホモミキサー等の分散機にて充分に混合攪拌した後、他の添加剤、例えば粘度調整剤や、pH調整剤、色調調整のための染料、潤滑剤等を混合し、更に均一になるまで溶解、混合することで得られるが、場合によって混合したインクをさらに分散機にて分散したり、得られたインクを濾過や遠心分離機に掛けて粗大粒子や不溶解成分を除いたりすることは何ら差し支えない。 In order to produce a water-based ink for writing tools, the above-mentioned pigment and / or pigment dispersion, one or more colorants selected from dyes, water and / or an organic solvent, and a dispersant are used. After sufficiently mixing and stirring with a disperser such as a homomixer, other additives such as a viscosity modifier, a pH adjuster, a dye for adjusting the color tone, a lubricant, etc. are mixed and dissolved until they become more uniform. , It can be obtained by mixing, but in some cases, the mixed ink may be further dispersed by a disperser, or the obtained ink may be filtered or centrifuged to remove coarse particles and insoluble components. There is no problem.

先軸20は、概略管状構造であり、軸線方向の中央部外周にフランジ部21を有し、フランジ部21の後方側筒状部22が軸筒10の開口部11内に嵌合し、フランジ部21の前方側は先細の筒状部23となっており、先軸20内にペン芯30が配置される。 The toe shaft 20 has a substantially tubular structure, has a flange portion 21 on the outer periphery of the central portion in the axial direction, and the rear side cylindrical portion 22 of the flange portion 21 is fitted into the opening 11 of the shaft cylinder 10 to form a flange. The front side of the portion 21 is a tapered tubular portion 23, and the pen core 30 is arranged in the toe shaft 20.

ペン芯30は、図2(a)~(e)に示すように、先端側が筆記部31となる大径部32、中央部側の中径部33、後端側が小径部34と順に段状に縮径したものであり、中径部33前方側外周に径方向に拡径する段部35を設けると共に、最大外径部となる大径部32の軸線方向に空気置換用の溝状(凹状)の空間部36が形成されている。空気置換用の空間部35の形状は、筆記の際にインクの供給と空気置換が効率よく順調に行われるものであれば、その形状、長さ、個数などは特に限定されず、例えば、平面状としてもよいものである。
このペン芯30は、先端となる筆記部31側が砲弾状(丸芯)を呈ししている。なお、丸芯の他、角芯であってもよい。
As shown in FIGS. 2A to 2E, the pen core 30 has a large diameter portion 32 having a writing portion 31 on the tip side, a medium diameter portion 33 on the center portion side, and a small diameter portion 34 on the rear end side in this order. The diameter is reduced to the above, and a step portion 35 that expands in the radial direction is provided on the outer periphery on the front side of the medium diameter portion 33, and a groove shape for air replacement in the axial direction of the large diameter portion 32 that is the maximum outer diameter portion ( A concave) space 36 is formed. The shape, length, number, and the like of the space portion 35 for air replacement are not particularly limited as long as the ink supply and air replacement are efficiently and smoothly performed during writing. For example, a flat surface is used. It may be in the form.
The pen core 30 has a bullet-shaped (round core) on the writing portion 31 side, which is the tip thereof. In addition to the round core, it may be a square core.

上記構成のペン芯30は、全体が多孔質部材から構成されるものであり、例えば、天然繊維、獣毛繊維、ポリアセタール系樹脂、ポリエチレン系樹脂、アクリル系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、ポリウレタン系樹脂、ポリオレフィン系樹脂、ポリビニル系樹脂、ポリカーボネート系樹脂、ポリエーテル系樹脂、ポリフェニレン系樹脂などの1種又は2種以上の組み合わせからなる並行繊維束、フェルト等の繊維束を加工又はこれらの繊維束を樹脂加工した繊維芯、または、ポリオレフィン系樹脂、アクリル系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、ポリウレタン系樹脂等の熱可塑性樹脂などのプラスチック粉末などを焼結したポーラス体(焼結芯)、押し出し成形した押出成形芯などから構成される。
好ましいペン芯30としては、繊維束芯、繊維芯、焼結芯、フェルト芯、無機多孔体芯などが挙げられ、これらの外周を更に樹脂フィルムなどで被覆した被覆繊維芯などであってもよいものである。また、用いるペン芯30の気孔率、硬度などは、インク種、筆記具の種類等により、変動するものであり、例えば、気孔率では30~60%とすることが好ましい。また、本発明において、「気孔率」は、下記のようにして算出される。まず、既知の質量及び見掛け体積を有する筆記芯を水中に浸し、十分に水を浸み込ませた後、水中から取り出した状態で質量を測定する。測定した質量から、筆記芯に浸み込ませた水の体積が導出される。この水の体積を筆記芯の気孔体積と同一として、下記式から、気孔率が算出される。
気孔率(単位:%)=(水の体積)/(ペン芯30の見掛け体積)×100
The pen core 30 having the above configuration is entirely composed of a porous member, and for example, natural fiber, animal hair fiber, polyacetal resin, polyethylene resin, acrylic resin, polyester resin, polyamide resin, etc. Processing or processing of parallel fiber bundles consisting of one or more combinations of polyurethane resin, polyolefin resin, polyvinyl resin, polycarbonate resin, polyether resin, polyphenylene resin, etc., fiber bundles such as felt, etc. A fiber core made by processing a fiber bundle with a resin, or a porous body made by sintering plastic powder such as a polyolefin resin, an acrylic resin, a polyester resin, a polyamide resin, or a thermoplastic resin such as a polyurethane resin (sintered core). ), Extruded core, etc.
Preferred pen cores 30 include fiber bundle cores, fiber cores, sintered cores, felt cores, inorganic porous cores, and the like, and may be coated fiber cores whose outer periphery is further coated with a resin film or the like. It is a thing. The porosity, hardness, and the like of the pen core 30 to be used vary depending on the type of ink, the type of writing instrument, and the like. For example, the porosity is preferably 30 to 60%. Further, in the present invention, the "porosity" is calculated as follows. First, a writing core having a known mass and apparent volume is immersed in water, sufficiently immersed in water, and then the mass is measured in a state of being taken out of the water. From the measured mass, the volume of water soaked in the writing core is derived. The porosity is calculated from the following formula, assuming that the volume of this water is the same as the volume of the pores of the writing core.
Porosity (unit:%) = (volume of water) / (apparent volume of pen core 30) x 100

前記軸筒10内に固着した先軸20の後端側には、弁(バルブ)機構40が内蔵されている。この弁機構40は、図1(b)に示すように、弁ホルダ41、弁体42、弁座43及びスプリングからなる弾性部材44とを備えている。
前記弁ホルダ41は、先端にフランジ41aを備え、後部面にインク流通孔41bの形成された筒状体である。このインク流通孔内41bに、弁体42の後部が進退動可能に装着される。
前記弁体42は、その中央部の周面に傘状の環状突起42aが形成されている。前記弁体42の先端部は中空開口42bを備え、前記開口42b(弁体42の先端面)にはペン芯30の後端部の最小外径部34の後端が嵌合して連結されている。
A valve mechanism 40 is built in the rear end side of the front shaft 20 fixed in the shaft cylinder 10. As shown in FIG. 1B, the valve mechanism 40 includes a valve holder 41, a valve body 42, a valve seat 43, and an elastic member 44 including a spring.
The valve holder 41 is a tubular body having a flange 41a at the tip and an ink flow hole 41b formed at the rear surface. The rear portion of the valve body 42 is movably mounted in the ink flow hole 41b.
The valve body 42 has an umbrella-shaped annular protrusion 42a formed on the peripheral surface of the central portion thereof. The tip of the valve body 42 is provided with a hollow opening 42b, and the rear end of the minimum outer diameter portion 34 of the rear end of the pen core 30 is fitted and connected to the opening 42b (the tip surface of the valve body 42). ing.

また、弁ホルダ41の先端部には、長さ寸法が弁ホルダ41よりも短い筒状の弁座43が装着されている。弁座43の周囲のフランジ部43aが、弁ホルダ41のフランジの先端面に当接することによって、弁座43は弁ホルダ41に位置決めされる。その弁座43の後部の凹部形状の座面43bに、前記弁体42周面が当接・離脱して弁機能を奏するように構成されている。
更に、弾性部材44が、弁体42と弁ホルダ41との間に装着されている。この弾性部材44は、弁座43から離脱した弁体42を、弾性部材44の反発力によって、弁体42が弁座43に当接する状態に戻すものである。なお、前記弁ホルダ41、弁体42、弁座43は樹脂材からなる。弾性部材44はSUSや樹脂等のスプリング部材から構成される。
本実施形態では、先軸20の筒状部23の後端側にはペン芯30の中径部33の外周に円筒状のインク吸液部材36が装着されている。この吸液部材36は、弁操作により、弁機構40からペン芯30側に流入等し、過剰等となるインクを吸液(吸収)し、筆記具Aからのインクの漏れを抑制するものである。
Further, a cylindrical valve seat 43 having a length dimension shorter than that of the valve holder 41 is attached to the tip end portion of the valve holder 41. The valve seat 43 is positioned on the valve holder 41 by the flange portion 43a around the valve seat 43 coming into contact with the tip end surface of the flange of the valve holder 41. The peripheral surface of the valve body 42 is configured to abut and detach from the concave seat surface 43b at the rear of the valve seat 43 to perform a valve function.
Further, the elastic member 44 is mounted between the valve body 42 and the valve holder 41. The elastic member 44 returns the valve body 42 separated from the valve seat 43 to a state in which the valve body 42 comes into contact with the valve seat 43 due to the repulsive force of the elastic member 44. The valve holder 41, the valve body 42, and the valve seat 43 are made of a resin material. The elastic member 44 is composed of a spring member such as SUS or resin.
In the present embodiment, a cylindrical ink absorbing member 36 is mounted on the outer periphery of the medium diameter portion 33 of the pen core 30 on the rear end side of the tubular portion 23 of the toe shaft 20. The liquid absorbing member 36 absorbs (absorbs) excess ink that flows from the valve mechanism 40 to the pen core 30 side by operating the valve, and suppresses ink leakage from the writing tool A. ..

このように構成される筆記具Aでは、以下の動作、作用によりペン芯30の筆記部31に対して、インクの供給、遮断がなされる。
筆記部31を紙面に対して、弾性部材44の反発力に抗しながら、押圧(ポンピング)すると、筆記部31は前方側筒状部23に対して、後方に移動し、弁体42を後方に押す。そして、押された弁体42は、弁座43から離脱し、弁を開放し、軸筒10内に収容されたインクをペン芯30の毛管により筆記部31へと供給する。
一方、筆記部31を紙面から離すと、弾性部材44の反発力によって、ペン芯30の筆記部31及び弁体42は先方に移動する。そして、先方に移動した弁体42は、弁座43に当接し、弁を閉じ、インクの供給を遮断している。
本実施形態では、ペン芯30は、後方側へいくほど段落としとなっており、ポンピング時に弁機構(バルブ)40内に潜り込む構成となっている。
In the writing tool A configured as described above, ink is supplied and shut off to the writing portion 31 of the pen core 30 by the following operations and actions.
When the writing portion 31 is pressed (pumped) against the paper surface while resisting the repulsive force of the elastic member 44, the writing portion 31 moves backward with respect to the front cylindrical portion 23, and the valve body 42 is moved backward. Press to. Then, the pressed valve body 42 is separated from the valve seat 43, the valve is opened, and the ink contained in the barrel 10 is supplied to the writing portion 31 by the capillary tube of the pen core 30.
On the other hand, when the writing portion 31 is separated from the paper surface, the writing portion 31 and the valve body 42 of the pen core 30 move to the front due to the repulsive force of the elastic member 44. Then, the valve body 42 that has moved to the front side abuts on the valve seat 43, closes the valve, and shuts off the ink supply.
In the present embodiment, the pen core 30 has a step toward the rear side, and is configured to slip into the valve mechanism (valve) 40 at the time of pumping.

本実施形態は、太めのペン芯〔筆記描線幅(実寸)が1.8~2.5mm〕を用いても、軸径を60%スリム化(内径φを16.5mmから10.3mm)するもの、すなわち、細めのペン芯〔筆記描線幅(実寸)が0.9~1.4mm〕用の軸径10.3mmの筆記具に太めのペン芯〔筆記描線幅(実寸)が1.8~2.5mm〕を用いても、太めのペン芯30には空気置換用の溝状(凹状)の空間部35が形成されているので、インクの供給がスムーズであり、筆記も良好に行うことができ、その筆記描線幅(1.8~2.5mm)を維持しつつ、筆記具の軸径を細く(60%スリム化)できることが判った。これにより、太めのペン芯を用いても軸径をスリム化した今までにない斬新なスマートな筆記具では、持ち運びの煩わしさを解消でき、多色のペンセットを持ち運ぶなどの日常使いしてもらうことによりアートクラフト意欲等も満足できるものとなる。
本実施形態では、筆記描線幅が太めとなる太めのペン芯を用いても、筆記具としての機能を損なうことなく軸径を細くできることを効果的に発揮させる点から、ペン芯30の最大外径は、軸筒(筆記具本体)10の軸径の20%~50%であることが好ましい。
また、インク吸液部材37の内径よりもペン芯30の外径が大きいペン芯を搭載しており、ペン芯30の外径端面とインク吸液部材37の端面の距離(隙間)が2mm以上、更に好ましくは、2mm以上6mm以下空いている構造としている。これにより、ポンピング時に圧縮して泡が発生してインク流出を阻害してしまうことを防止することができるものとなる。
In this embodiment, the shaft diameter is reduced by 60% (inner diameter φ is 16.5 mm to 10.3 mm) even if a thick pen core [writing line width (actual size) is 1.8 to 2.5 mm] is used. That is, a writing tool with a shaft diameter of 10.3 mm for a thin pen core [writing line width (actual size) of 0.9 to 1.4 mm] and a thick pen core [writing line width (actual size) of 1.8 to Even if 2.5 mm] is used, the thick pen core 30 has a groove-shaped (concave) space portion 35 for air replacement, so that the ink supply is smooth and writing is performed well. It was found that the shaft diameter of the writing tool can be reduced (60% slimmer) while maintaining the writing line width (1.8 to 2.5 mm). As a result, even with a thick pen core, the shaft diameter has been slimmed down, and with a novel and smart writing tool that has never been seen before, the hassle of carrying it can be eliminated, and people can use it daily, such as carrying a multicolored pen set. As a result, the motivation for art crafting will be satisfied.
In the present embodiment, even if a thick pen core having a thick writing line width is used, the maximum outer diameter of the pen core 30 can be effectively exhibited from the viewpoint that the shaft diameter can be reduced without impairing the function as a writing tool. Is preferably 20% to 50% of the shaft diameter of the shaft cylinder (writing tool main body) 10.
Further, a pen core having an outer diameter larger than the inner diameter of the ink absorbing member 37 is mounted, and the distance (gap) between the outer diameter end surface of the pen core 30 and the end surface of the ink absorbing member 37 is 2 mm or more. More preferably, the structure is 2 mm or more and 6 mm or less. As a result, it is possible to prevent the ink from being compressed and bubbles are generated during pumping to hinder the ink outflow.

図3及び図4は、本発明の実施形態の他例を示す筆記具の正面図と縦断面図、並びに、この筆記具に用いるペン芯の各図面である。なお、図3以降の各実施形態において、図1及び図2の筆記具A、ペン芯と同様の構成は、同じ図示符号を示して、その説明を省略する。
本実施形態の筆記具Bは、図3~図4に示すように、ペン芯38の構成が、上記実施形態の筆記具Aのペン芯30の外径(大径部32)より小さい細字ペン芯38aを用いたものであり、大径部を省略して中径部33aと小径部34aで構成した点、細字ペン芯38aの外径(中径部33a)が上記実施形態の筆記具Aのペン芯30の外径(大径部32)より小さいため、ペン芯30の外径(大径部32)と同じ外径となるホルダ部材50を細字ペン芯38aの外周に装着して先軸10内に固着した点、該ホルダ部材50には、軸線方向に空気置換用の離間状の空間部51を備えた点、外周にホルダ部材50と内周に細ペン芯38aとで構成したペン芯38と上記ペン芯30とが互いに交換可能な構造とした点で、上記実施形態の筆記具Aと相違するものである。
3 and 4 are a front view and a vertical sectional view of a writing tool showing another example of the embodiment of the present invention, and drawings of a pen core used for the writing tool. In each embodiment after FIG. 3, the same configurations as the writing tool A and the pen core of FIGS. 1 and 2 show the same illustrated reference numerals, and the description thereof will be omitted.
As shown in FIGS. 3 to 4, the writing tool B of the present embodiment has a fine pen core 38a in which the pen core 38 is smaller than the outer diameter (large diameter portion 32) of the pen core 30 of the writing tool A of the above embodiment. The point that the large-diameter portion is omitted and the medium-diameter portion 33a and the small-diameter portion 34a are formed, and the outer diameter (medium-diameter portion 33a) of the fine pen core 38a is the pen core of the writing tool A of the above embodiment. Since it is smaller than the outer diameter of 30 (large diameter portion 32), a holder member 50 having the same outer diameter as the outer diameter of the pen core 30 (large diameter portion 32) is attached to the outer periphery of the fine pen core 38a and inside the toe shaft 10. The holder member 50 is provided with a space portion 51 for air replacement in the axial direction, and the pen core 38 is composed of a holder member 50 on the outer circumference and a fine pen core 38a on the inner circumference. It is different from the writing tool A of the above embodiment in that the pen core 30 and the pen core 30 are interchangeable with each other.

このように構成される筆記具B、また、筆記具Aとペン芯38との筆記具セットでは、ホルダ部材50を装着したペン芯38aと外径が同じとなる、上述の太めのペン芯30〔筆記描線幅(実寸)が1.8~2.5mm〕を用いた筆記具の軸体10(先軸20)に固着することができ、しかも、ホルダ部材50には、軸線方向に空気置換用の離間状の空間部51(上述のペン芯30の空間部36より小さい体積分となる空間部51)を備えているので、細めのペン芯38aへのインクの供給もスムーズであり、筆記も良好に行うことができ、しかも、ペン芯30とペン芯38とは互いに交換可能に装着できる構造としたので、太ペン芯と細ペン芯との交換により生じるインク供給の不良などはなく、スムーズなインクの供給、太め、細めの良好な筆記描線が得られる筆記具、筆記具セットが得られるものとなる。 In the writing tool B configured as described above, and in the writing tool set of the writing tool A and the pen core 38, the above-mentioned thick pen core 30 [writing line] having the same outer diameter as the pen core 38a to which the holder member 50 is attached. The width (actual size) is 1.8 to 2.5 mm], and it can be fixed to the shaft body 10 (front shaft 20) of the writing tool, and the holder member 50 has a separation shape for air replacement in the axial direction. Since the space portion 51 (the space portion 51 having a smaller body integral than the space portion 36 of the pen core 30 described above) is provided, the ink can be smoothly supplied to the thin pen core 38a and the writing can be performed well. Moreover, since the pen core 30 and the pen core 38 are interchangeably mounted, there is no defect in ink supply caused by the replacement of the thick pen core and the thin pen core, and the ink is smooth. It is possible to obtain a writing tool and a writing tool set that can obtain good writing lines for supply, thickening, and thinning.

図5は、本発明の実施形態の他例となるペン芯の各図面である。
本実施形態のペン芯39は、図5(a)~(e)に示すように、ペン芯38の構成が、上記実施形態の筆記具Aのペン芯30の、軸線方向に空気置換用の溝状(凹状)の空間部50の長さを小さくした面削ぎ状の空間部39aとした点で、上記実施形態の筆記具Aと相違するものである。
このペン芯39を用いて図1の筆記具としても、筆記具Aと同様に、インクの供給がスムーズであり、筆記も良好に行うことができ、太めのペン芯を用いても、その筆記描線幅を維持しつつ、筆記具の軸径を細く(60%スリム化)できることが判った。
FIG. 5 is a drawing of a pen core which is another example of the embodiment of the present invention.
As shown in FIGS. 5A to 5E, the pen core 39 of the present embodiment has a structure of the pen core 38 for air replacement in the axial direction of the pen core 30 of the writing tool A of the above embodiment. It differs from the writing tool A of the above-described embodiment in that the length of the shaped (concave) space portion 50 is reduced to form a face-cut space portion 39a.
As with the writing instrument A, the pen core 39 can be used as a writing instrument with smooth ink supply and good writing, and even if a thick pen core is used, the writing line width thereof. It was found that the shaft diameter of the writing instrument can be reduced (60% slimmer) while maintaining the above.

図6及び図7は、本発明の実施形態の他例を示す筆記具の正面図と縦断面図、並びに、ペン芯の各図面である。
本実施形態の筆記具Cは、図6~図7に示すように、ペン芯30の後端部の最小外径部を弁機構40の弁体42と連結することなく、ペン芯30の後端部と弁体20との先端とを把持用コマ部材60を介して連結している点で、上記筆記具A、Bと相違するものである。
この把持用コマ部材60は、先端側にペン芯30の後端部の中径部33に形成した嵌合用の凹部33aに嵌合する突起部61と、上記中径部33の外径が同じ本体部62と、後端側に弁体42の開口42b内に嵌合する後端部63とから構成されている。上記嵌合の他、把持用コマ部材60を用いる場合、接着剤にて連結してもよいものである。
この実施形態の筆記具Cも、筆記具A、Bと同様に、インクの供給がスムーズであり、筆記も良好に行うことができ、太めのペン芯を用いても、その筆記描線幅を維持しつつ、筆記具の軸径を細く(60%スリム化)でき、しかも、筆記具Bのペン芯38と互いに交換可能に装着できる構造であるので、筆記具Bと同様に、太ペン芯と細ペン芯との交換により生じるインク供給の不良などはなく、スムーズなインクの供給、太め、細めの良好な筆記描線が得られる筆記具、筆記具セットが得られるものとなる。
6 and 7 are a front view and a vertical sectional view of a writing tool showing another example of the embodiment of the present invention, and drawings of a pen core.
As shown in FIGS. 6 to 7, the writing tool C of the present embodiment has the rear end of the pen core 30 without connecting the minimum outer diameter portion of the rear end of the pen core 30 to the valve body 42 of the valve mechanism 40. It differs from the above-mentioned writing tools A and B in that the portion and the tip of the valve body 20 are connected via the gripping piece member 60.
The gripping top member 60 has the same outer diameter as the protrusion 61 that fits into the fitting recess 33a formed in the middle diameter portion 33 of the rear end portion of the pen core 30 on the tip end side. It is composed of a main body portion 62 and a rear end portion 63 fitted in the opening 42b of the valve body 42 on the rear end side. In addition to the above fitting, when the gripping top member 60 is used, it may be connected with an adhesive.
Like the writing tools A and B, the writing tool C of this embodiment also has a smooth ink supply and can write well, and even if a thick pen core is used, the writing line width is maintained. Since the shaft diameter of the writing tool can be reduced (60% slimmer) and the pen core 38 of the writing tool B can be exchanged with each other, the thick pen core and the thin pen core can be attached in the same manner as the writing tool B. There is no defect in ink supply caused by replacement, and a writing tool and writing tool set that can obtain smooth ink supply and good thick and thin writing lines can be obtained.

更にまた、上記各実施形態の筆記具A~Cでは、筆記具用のインク(水性インク、油性インク、熱変色性インク)で説明したが、液状化粧料、液状薬剤、塗布液、修正液などの液状体としてもよいものである。 Furthermore, in the writing tools A to C of each of the above embodiments, the inks for writing tools (water-based ink, oil-based ink, heat-discoloring ink) have been described, but liquids such as liquid cosmetics, liquid chemicals, coating liquids, and correction fluids have been described. It is good as a body.

次に、実施例により、本発明を更に詳述するが、本発明は下記実施例に限定されるものではない。 Next, the present invention will be described in more detail by way of examples, but the present invention is not limited to the following examples.

〔実施例1〕
下記構成及び図1、図2及び図4に準拠するペン芯を有する筆記具、ペン芯、下記組成の筆記具用インクを使用した。ペン芯、筆記具の寸法等は下記に示す大きさ等を使用した。
[Example 1]
A writing tool having a pen core conforming to the following configuration and FIGS. 1, 2 and 4, a pen core, and a writing tool ink having the following composition were used. For the dimensions of the pen core and writing instrument, the sizes shown below were used.

(筆記具の構成)
軸筒10:ポリプロピレン製、長さ120mm、中央部内径φ7mm;外径φ10mm
ペン芯30:ポリエステル製繊維芯、全長25mm、最大外径部φ4mm、中径部φ2mmm、最小外径部φ1.5mm、空気置換用空間部36:幅1mm、深さ0.4mm、気孔率70%
インク吸液部材37:ウレタン製、気孔率80%、大きさ:φ7×2mm
弁機構:弾性部材44(ステンレス製)以外、ポリプロピレン製
ペン芯38:ポリエステル製繊維芯、全長30mm、中径部33a:φ2mm、最小外径部34a:φ1.5mm、気孔率70%
ホルダ部材50:ポリアセタール製、全長10mm、肉厚1mm
空気置換用空間部51:幅1mm、深さ1mm
(Composition of stationery)
Shaft cylinder 10: Made of polypropylene, length 120 mm, central inner diameter φ7 mm; outer diameter φ10 mm
Pen core 30: Polyester fiber core, total length 25 mm, maximum outer diameter part φ4 mm, medium diameter part φ2 mm, minimum outer diameter part φ1.5 mm, air replacement space 36: width 1 mm, depth 0.4 mm, porosity 70 %
Ink liquid absorbing member 37: Made of urethane, porosity 80%, size: φ7 x 2 mm
Valve mechanism: Except for elastic member 44 (made of stainless steel), polypropylene pen core 38: polyester fiber core, total length 30 mm, medium diameter part 33a: φ2 mm, minimum outer diameter part 34a: φ1.5 mm, porosity 70%
Holder member 50: Made of polyacetal, total length 10 mm, wall thickness 1 mm
Space for air replacement 51: Width 1 mm, depth 1 mm

(筆記具用インク組成、インク色:黒色)
筆記具用インクとして、下記組成のインク(合計100質量%)を使用した。
活性剤:メガファック F410(フッ素系アニオン界面活性剤、パーフルオロアルキル基含有カルボン酸塩、DIC株式会社製) 1質量%
防黴剤:ベンゾイソチアゾリン-3-オン 0.2質量%
グリセリルグルコシド水溶液:αGG(高濃度αグリセリルグルコシド水溶液、αグリセリルグルコシド60%水溶液、株式会社JTS製) 3質量%
顔料水分散体:FUJI SP BLACK 8041(黒色顔料水分散体、固形分20%、冨士色素株式会社製) 20質量%
水溶性有機溶剤:グリセリン 5質量%
水溶性有機溶剤:エチレングリコール 5質量%
水(溶媒):イオン交換水 65.8質量%
粘度(25℃):3.6mPa・s(コンプレート型粘度計、TOKIMEC社製、TV-20)
表面張力(25℃):40mN/m(自動表面張力計、協和界面科学社製、DY-300)
(Ink composition for writing tools, ink color: black)
As the ink for writing tools, inks having the following composition (total 100% by mass) were used.
Activator: Megafuck F410 (fluorine-based anionic surfactant, perfluoroalkyl group-containing carboxylate, manufactured by DIC Corporation) 1% by mass
Antifungal agent: Benzoisothiazolin-3-one 0.2% by mass
Glyceryl glucoside aqueous solution: αGG (high concentration α glyceryl glucoside aqueous solution, α glyceryl glucoside 60% aqueous solution, manufactured by JTS Co., Ltd.) 3% by mass
Pigment water dispersion: FUJI SP BLACK 8041 (black pigment water dispersion, solid content 20%, manufactured by Fuji Dye Co., Ltd.) 20% by mass
Water-soluble organic solvent: glycerin 5% by mass
Water-soluble organic solvent: Ethylene glycol 5% by mass
Water (solvent): Ion-exchanged water 65.8% by mass
Viscosity (25 ° C): 3.6 mPa · s (Complate type viscometer, manufactured by TOKIMEC, TV-20)
Surface tension (25 ° C): 40 mN / m (automatic surface tension meter, manufactured by Kyowa Interface Science, DY-300)

上記構成となる筆記具用インクを搭載した筆記具Aでは、太めのペン芯30〔筆記描線幅(実寸)が1.8~2.5mm〕を用いても、軸径を60%スリム化(内径φを11.6mmから7mm)するもの、すなわち、細めのペン芯38〔筆記描線幅(実寸)が0.9~1.4mm〕用の軸径(外径)10mmの筆記具に太めのペン芯30〔筆記描線幅(実寸)が1.8~2.5mm〕を用いても、太めのペン芯30には空気置換用の溝状(凹状)の空間部35が形成されているので、インクの供給がスムーズであり、筆記も良好に行うことができ、その筆記描線幅(1.8~2.5mm)を維持しつつ、筆記具の軸径を細く(60%スリム化)できることが確認できた。
また、上記筆記具Aとペン芯38との筆記具セットでは、ホルダ部材50を装着したペン芯38と外径が同じとなる、上述の太めのペン芯30〔筆記描線幅(実寸)が1.8~2.5mm〕を用いた筆記具の軸体10(先軸20)に固着することができ、しかも、ホルダ部材50には、軸線方向に空気置換用の離間状の空間部51(上述のペン芯30の空間部36より小さい体積分となる空間部51)を備えているので、細めのペン芯38へのインクの供給もスムーズであり、筆記も良好に行うことができ、しかも、ペン芯30とペン芯38とは互いに交換可能に装着できる構造としたので、太ペン芯30と細ペン芯38との交換により生じるインク供給の不良などはなく、スムーズなインクの供給、太め、細めの良好な筆記描線が得られるスマートな筆記具、筆記具セットが得られることが確認できた。
In the writing tool A equipped with the writing tool ink having the above configuration, the shaft diameter is reduced by 60% (inner diameter φ) even if a thick pen core 30 [writing line width (actual size) is 1.8 to 2.5 mm] is used. 11.6 mm to 7 mm), that is, a writing tool with a shaft diameter (outer diameter) of 10 mm for a thin pen core 38 [writing line width (actual size) is 0.9 to 1.4 mm] and a thick pen core 30. Even if [writing line width (actual size) is 1.8 to 2.5 mm] is used, the thick pen core 30 has a groove-shaped (concave) space portion 35 for air replacement, so that the ink can be used. It was confirmed that the supply was smooth, writing was good, and the shaft diameter of the writing tool could be reduced (60% slimmer) while maintaining the writing line width (1.8 to 2.5 mm). ..
Further, in the writing tool set of the writing tool A and the pen core 38, the thick pen core 30 [writing line width (actual size) is 1.8, which has the same outer diameter as the pen core 38 to which the holder member 50 is attached. It can be fixed to the shaft body 10 (front shaft 20) of the writing tool using [~ 2.5 mm], and the holder member 50 has a space portion 51 (the above-mentioned pen) for air replacement in the axial direction. Since the space portion 51), which has a smaller body integration than the space portion 36 of the core 30, is provided, ink can be smoothly supplied to the thin pen core 38, writing can be performed well, and the pen core can be written well. Since the structure is such that the 30 and the pen core 38 can be mounted interchangeably with each other, there is no defective ink supply caused by the replacement of the thick pen core 30 and the thin pen core 38, and smooth ink supply, thickening, and thinning are possible. It was confirmed that a smart writing tool and a writing tool set that can obtain good writing lines can be obtained.

本発明では、太めのペン芯を用いても、その筆記描線幅を維持しつつ、筆記具の軸径を細く(スリム化)できるマーキングペン、サインペン、ペイントマーカーなどの筆記具に好適に使用される。 In the present invention, even if a thick pen core is used, it is suitably used for writing instruments such as marking pens, felt-tip pens, and paint markers that can reduce (slim) the shaft diameter of the writing instrument while maintaining the writing line width.

10 軸筒
18 筆記具用インク
20 先軸
30 ペン芯(太めのペン芯)
36 空気置換用の空間部
38 ペン芯(細めのペン芯)
40 弁機構
42 弁体
50 ホルダ部材
60 把持用コマ部材
10 Shaft cylinder 18 Writing tool ink 20 Tip shaft 30 Pen core (thick pen core)
36 Space for air replacement 38 Pen core (thin pen core)
40 Valve mechanism 42 Valve body 50 Holder member 60 Gripping top member

Claims (4)

筆記具本体となる軸筒内のインクを軸筒の先端側に設けたペン芯に供給して筆記可能となる筆記具であって、前記ペン芯の外周に径方向に拡径する段部を設けると共に、最大外径部の軸線方向に空気置換用の空間部を形成したことを特徴とする筆記具。 It is a writing instrument that enables writing by supplying ink in the shaft cylinder, which is the main body of the writing instrument, to the pen core provided on the tip side of the shaft cylinder. A writing instrument characterized by forming a space for air replacement in the axial direction of the maximum outer diameter. 軸筒内には弁機構を備えると共に、ペン芯の後端部の最小外径部は、弁機構の弁体と連結していることを特徴とする請求項1に記載の筆記具。 The writing tool according to claim 1, wherein the shaft cylinder is provided with a valve mechanism, and the minimum outer diameter portion of the rear end portion of the pen core is connected to the valve body of the valve mechanism. 請求項1又は2に記載の筆記具に用いるペン芯であって、該ペン芯は外周にホルダ部材と内周に細ペン芯とで構成し、かつ、請求項1又は2に記載の筆記具のペン芯と互いに交換可能な構造であることを特徴とするペン芯。 The pen core used for the writing tool according to claim 1 or 2, wherein the pen core is composed of a holder member on the outer periphery and a fine pen core on the inner circumference, and the pen of the writing tool according to claim 1 or 2. A pen core characterized by having a structure that can be exchanged with the core. 請求項1又は2に記載の筆記具と、請求項3記載のペン芯とからなることを特徴とする筆記具セット。 A writing tool set comprising the writing tool according to claim 1 or 2 and the pen core according to claim 3.
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