JP2022032448A - Oil-and-fat containing starch composition, mixed flour for batter, and production method thereof - Google Patents

Oil-and-fat containing starch composition, mixed flour for batter, and production method thereof Download PDF

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JP2022032448A
JP2022032448A JP2020136238A JP2020136238A JP2022032448A JP 2022032448 A JP2022032448 A JP 2022032448A JP 2020136238 A JP2020136238 A JP 2020136238A JP 2020136238 A JP2020136238 A JP 2020136238A JP 2022032448 A JP2022032448 A JP 2022032448A
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oil
fat
emulsifier
batter
modified starch
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良太 河内
Ryota Kawauchi
千聡 臼井
Chisato Usui
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NIPPN Corp
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Abstract

To provide an oil-and-fat containing starch composition for making a batter, which has an excellent dispersibility in water, is hard to make lumps, gives a good binding capacity between the fried foods and the batter, and hence makes the texture of fries excellent.SOLUTION: An oil-and-fat containing starch composition contains starch containing processed oil-and-fat, oil-and-fat, and an emulsifier. And the content of the oil-and-fat in proportion to the total weight of the oil-and-fat and the emulsifier is 22 - 97 wt.%, and the total weight of the oil-and-fat and the emulsifier in proportion to the oil-and-fat containing starch composition as 100 wt.% is 0.05 - 17 wt.%.SELECTED DRAWING: None

Description

本発明は、油脂加工澱粉組成物、揚げ物衣材用ミックス粉及び揚げ物並びにこれらの製造方法に関する。 The present invention relates to a modified starch composition for fats and oils, a mixed powder for fried food batter and a fried food, and a method for producing these.

フライやから揚げ等の揚げ物は、揚げ種をバッター等の衣材で被覆した後、適度に加熱した油槽で油ちょう(乾熱加熱)することにより製造される。揚げ種と衣との結着性が低い場合、しばしば揚げ物から衣が剥がれることがあり、これは外観や食感等の品質が低下する原因の一つとなる。従って、揚げ物には、揚げ種と衣との結着性が高く、衣が揚げ種から剥がれにくいことが求められている。このような問題を解決するために、油脂加工澱粉を衣材に使用して、揚げ種からの衣剥がれを抑制することが提案されている(例えば、特許文献1、特許文献2)。 Fried foods such as fried foods and fried chicken are produced by covering the fried seeds with a batter such as batter and then oiling them in an appropriately heated oil tank (dry heat heating). When the bond between the fried seeds and the batter is low, the batter often peels off from the fried food, which is one of the causes of deterioration in quality such as appearance and texture. Therefore, the fried food is required to have a high binding property between the fried seed and the batter, and the batter is not easily peeled off from the fried seed. In order to solve such a problem, it has been proposed to use modified starch as a batter material to suppress batter peeling from fried seeds (for example, Patent Document 1 and Patent Document 2).

油脂加工澱粉とは、澱粉の表面に油脂を付着させた後、加熱熟成して得られる加工澱粉である。そのため、油脂加工澱粉の表面は疎水的な性質を有している。このような油脂加工澱粉を揚げ物用バッター液に用いる場合、油脂加工澱粉の水分に対する分散性が悪いために、バッター調製時においてダマが出来やすくなり、その結果バッターのロット間で粘性が安定し難く、揚げ種への衣材の付着量にムラが生じる等、作業性が悪くなることがあった。これらの問題を解決するために、油脂加工澱粉の製造において、油脂と乳化剤の両方を用いて澱粉を処理する方法が検討されている。例えば、特許文献3には、原料澱粉に食用油脂及び乳化剤を添加及び混合した後、40℃以上に加温して油脂加工澱粉を製造することが記載されている。 The oil-and-fat modified starch is a modified starch obtained by adhering oil and fat on the surface of the starch and then aging it by heating. Therefore, the surface of the modified starch has a hydrophobic property. When such modified starch is used as a batter solution for deep-fried foods, the dispersibility of the modified starch in water is poor, so that lumps are likely to occur during the preparation of the batter, and as a result, the viscosity is difficult to stabilize between lots of the batter. In some cases, workability deteriorated, such as uneven adhesion of the batter to the fried seeds. In order to solve these problems, a method of treating starch using both fat and oil and an emulsifier has been studied in the production of modified starch. For example, Patent Document 3 describes that edible oils and fats and emulsifiers are added to and mixed with raw material starch and then heated to 40 ° C. or higher to produce oil-and-fat modified starch.

特開2016-174535号公報Japanese Unexamined Patent Publication No. 2016-174535 特開2019-195305号公報Japanese Unexamined Patent Publication No. 2019-195305 特開2005-73506号公報Japanese Unexamined Patent Publication No. 2005-73506

しかしながら、このようにして得られる油脂加工澱粉は、乳化剤を使用せず油脂のみを使用して得られる油脂加工澱粉よりも水分への分散性がある程度改善されるものの、分散性、揚げ種との結着性、揚げ物の食感に関して更なる改良が求められている。 However, the oil-and-fat modified starch thus obtained has improved dispersibility in water to some extent as compared with the oil-and-fat-processed starch obtained by using only the oil and fat without using an emulsifier, but has dispersibility and fried seeds. Further improvements are required regarding the binding property and the texture of fried foods.

本発明の目的は、バッターを調製する際に、水分への分散性に優れ、ダマが出来難く、かつ揚げ種との結着性を良好にし、揚げ物の食感を良好にすることができる油脂加工澱粉組成物を提供することである。 An object of the present invention is an oil or fat that has excellent dispersibility in water, is difficult to form lumps, has good binding properties to fried seeds, and can improve the texture of fried foods when preparing a batter. The present invention is to provide a modified starch composition.

本発明者らは、鋭意研究を重ねた結果、油脂加工澱粉、油脂及び乳化剤を含む油脂加工澱粉組成物において、油脂及び乳化剤の合計量に対する油脂の含有割合を特定の割合とし、油脂及び乳化剤の合計量を特定の量とすることにより、上記課題を解決できることを見出し、本発明を完成するに至った。 As a result of diligent research, the present inventors have set the content ratio of fats and oils to the total amount of fats and oils and emulsifiers as a specific ratio in the fats and oils modified starch composition containing fats and oils and emulsifiers. We have found that the above problems can be solved by setting the total amount to a specific amount, and have completed the present invention.

すなわち、本発明は、以下の態様を包含する。
[1]油脂加工澱粉、油脂及び乳化剤を含み、
前記油脂及び前記乳化剤の合計量に対する前記油脂の含有割合が22~97質量%であり、
前記油脂及び前記乳化剤の合計量が前記油脂加工澱粉100質量部に対して0.05~17質量部である、
油脂加工澱粉組成物。
[2][1]に記載の油脂加工澱粉組成物を含有する、揚げ物衣材用ミックス粉。
[3][1]に記載の油脂加工澱粉組成物又は[2]に記載の揚げ物衣材用ミックス粉を使用してなる、揚げ物。
[4]油脂及び乳化剤を混合して、前記油脂を22~97質量%含む油脂-乳化剤混合物を得る工程、及び
油脂加工澱粉100質量部に対して0.05~17質量部の前記油脂-乳化剤混合物を混合する工程を含む、
油脂加工澱粉組成物の製造方法。
[5][4]に記載の方法によって得られた油脂加工澱粉組成物を使用する、揚げ物衣材用ミックス粉の製造方法。
[6][4]に記載の方法によって得られた油脂加工澱粉組成物又は[5]に記載の方法によって得られた揚げ物衣材用ミックス粉を使用する、揚げ物の製造方法。
That is, the present invention includes the following aspects.
[1] Contains modified starch, fat and emulsifier,
The content ratio of the fat and oil to the total amount of the fat and oil and the emulsifier is 22 to 97% by mass.
The total amount of the fat and oil and the emulsifier is 0.05 to 17 parts by mass with respect to 100 parts by mass of the modified starch.
Oil-processed starch composition.
[2] A mixed powder for fried food batter containing the oil-and-fat modified starch composition according to [1].
[3] A fried food made by using the oil-and-fat modified starch composition according to [1] or the mixed powder for fried food batter according to [2].
[4] A step of mixing an oil and an emulsifier to obtain an oil-fat-emulsifier mixture containing 22 to 97% by mass of the oil and fat, and 0.05 to 17 parts by mass of the oil-emulsifier with respect to 100 parts by mass of the modified starch. Including the step of mixing the mixture,
A method for producing a modified starch composition.
[5] A method for producing a mixed powder for deep-fried food batter, using the oil-and-fat modified starch composition obtained by the method according to [4].
[6] A method for producing a deep-fried food using the oil-and-fat modified starch composition obtained by the method according to [4] or the mixed powder for deep-fried food batter obtained by the method according to [5].

本発明によれば、バッターを調製する際に、水分への分散性に優れ、ダマが出来難く、かつ揚げ種との結着性を良好にし、揚げ物の食感を良好にすることができる油脂加工澱粉組成物を提供することができる。 According to the present invention, when preparing a batter, fats and oils that are excellent in dispersibility in water, difficult to form lumps, have good binding properties with fried seeds, and can improve the texture of fried foods. A modified starch composition can be provided.

以下、本発明を実施するための形態を説明する。 Hereinafter, embodiments for carrying out the present invention will be described.

〔油脂加工澱粉組成物〕
本発明の油脂加工澱粉組成物は、油脂加工澱粉、油脂及び乳化剤を含む。本発明において、油脂及び乳化剤は、油脂加工澱粉に由来するものを含まないものとする。すなわち、本発明の油脂加工澱粉組成物は、油脂及び乳化剤が、油脂加工澱粉に対して外割で含まれている。本発明の油脂加工澱粉組成物は、バッターを調製する際に、水分への分散性に優れ、ダマが出来難く、かつ揚げ種との結着性を良好にし、揚げ物の食感を良好にすることができるため、揚げ物バッター用油脂加工澱粉組成物であることが好ましい。
[Fat modified starch composition]
The modified starch composition of the present invention contains modified starch, oil and emulsifier. In the present invention, the fat and oil and the emulsifier do not include those derived from the fat and oil modified starch. That is, the oil-and-fat modified starch composition of the present invention contains the oil and fat and the emulsifier in an outer ratio with respect to the oil-and-fat modified starch. When preparing a batter, the oil-and-fat modified starch composition of the present invention has excellent dispersibility in water, is difficult to form lumps, has good binding properties with fried seeds, and has a good texture of fried foods. Therefore, it is preferable to use an oil-processed starch composition for fried food batter.

〔油脂加工澱粉〕
本発明において、油脂加工澱粉とは、澱粉及び食用油脂を混合して澱粉の表面に油脂を付着させた後、任意に乾燥し、加熱熟成(油脂加工)して得られるものをいう。
油脂加工澱粉の原料となる澱粉としては、特に限定されず、一般に食用に供される澱粉であればいずれも好適に使用することができ、例えば、タピオカ澱粉、馬鈴薯澱粉、コーンスターチ、小麦澱粉、米澱粉、甘藷澱粉、緑豆澱粉、サゴ澱粉等、並びにこれらのワキシー種及びハイアミロース種の未変性澱粉、並びにその未変性澱粉にα化、エーテル化、エステル化、架橋、酸化等の変性処理から選択される1種以上の変性処理を施した変性澱粉が挙げられる。上記澱粉は、これらのうちの1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。
[Fixed starch]
In the present invention, the modified starch is obtained by mixing starch and edible oil and fat, adhering the oil and fat to the surface of the starch, drying the starch arbitrarily, and aging it by heating (oil and fat processing).
The starch used as a raw material for the oil-processed starch is not particularly limited, and any starch generally used for food can be preferably used. For example, tapioca starch, horse bell starch, corn starch, wheat starch, rice. Select from starch, sweet potato starch, green bean starch, sago starch, etc., and unmodified starches of these waxy and hyamylose species, and modification treatments such as pregelatinization, etherification, esterification, cross-linking, and oxidation of the unmodified starch. Examples thereof include modified starch that has been subjected to one or more types of modification treatments. As the starch, only one of these may be used, or two or more of them may be used in combination.

油脂加工澱粉の原料となる油脂としては、特に限定されず、一般に食用に供される油脂であればいずれも好適に使用することができ、例えば、大豆油、菜種油、サフラワー油、エゴマ油、シソ油、コーン油、ヒマワリ油、綿実油、ゴマ油、オリーブ油、ヤシ油、米油、亜麻仁油、パーム油等の植物性油脂、魚油、牛脂、豚脂(ラード油)、鶏脂等の動物性油脂、これらを2種類以上組み合わせた混合油脂、及びこれらの油脂のうち1種又は2種以上の組み合わせに分別操作、エステル交換、水素添加等の加工処理を行った加工油脂等が挙げられる。上記油脂は、これらのうちの1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。 The oil and fat that is the raw material of the oil-processed starch is not particularly limited, and any oil and fat that is generally used for food can be preferably used. Vegetable fats and oils such as perilla oil, corn oil, sunflower oil, cottonseed oil, sesame oil, olive oil, palm oil, rice oil, flaxseed oil, palm oil, fish oil, beef fat, pork fat (lard oil), chicken fat and other animal fats and oils. Examples thereof include mixed oils and fats in which two or more of these are combined, and processed oils and fats in which one or more of these oils and fats are subjected to a sorting operation, ester exchange, hydrogenation or other processing. As the oil and fat, only one of these may be used, or two or more thereof may be used in combination.

油脂加工澱粉の製造において、油脂の使用量は、澱粉100質量部に対して0.005~10質量部であることが好ましく、0.01~1質量部であることがより好ましい。また、油脂の代わりに、前記植物性油脂を分離精製する前の油糧種子を粉砕した油糧種子粉砕物を使用してもよい。この場合、澱粉に対する油脂の割合は、油糧種子に含まれる油脂の割合から適宜換算して求めることができる。 In the production of modified starch, the amount of fat and oil used is preferably 0.005 to 10 parts by mass, more preferably 0.01 to 1 part by mass with respect to 100 parts by mass of starch. Further, instead of the oil and fat, a crushed oil seed product obtained by crushing the oil seed before separating and refining the vegetable oil and fat may be used. In this case, the ratio of fats and oils to starch can be appropriately converted from the ratio of fats and oils contained in oil seeds.

澱粉の表面に油脂を付着させる手法としては、特に限定されず、例えば、ミキサー等で機械的に澱粉を撹拌しながら油脂を徐々に添加して撹拌混合する手法、澱粉を気流中に均一分散させて油脂をスプレー噴射する手法等、公知の手法を用いることができる。 The method of adhering the fat and oil to the surface of the starch is not particularly limited, and for example, a method of gradually adding the fat and oil while mechanically stirring the starch with a mixer or the like and stirring and mixing the starch, and uniformly dispersing the starch in the air flow. A known method such as a method of spraying oil or fat can be used.

表面に油脂を付着させた澱粉を加熱熟成する手法としては、特に限定されず、例えば、樹脂製容器に密封して恒温室内に静置する等、公知の手法を用いることができる。加熱熟成は、通例、30~130℃で1時間~25日間程度行われるが、使用する澱粉と油脂の性状及び加熱熟成中の状態変化を鑑みて、適宜加熱温度や熟成時間を調節することができる。 The method for heat-aging the starch having the oil and fat adhered to the surface is not particularly limited, and a known method such as sealing the starch in a resin container and allowing it to stand in a constant temperature room can be used. Heat aging is usually carried out at 30 to 130 ° C. for about 1 hour to 25 days, but the heating temperature and aging time may be appropriately adjusted in consideration of the properties of the starch and fats and oils used and the state change during heat aging. can.

上記油脂加工澱粉は、澱粉を油脂と油脂以外の他の任意成分との存在下で油脂加工したものであってもよい。上記任意成分としては、各種HLB値の乳化剤;アミラーゼ、セルラーゼ、リパーゼ、リポキシゲナーゼ等の酵素製剤;小麦蛋白、卵白及び/又は卵黄由来の卵蛋白、乳蛋白、大豆蛋白、緑豆蛋白等の蛋白質材料;小麦粉、大麦粉、米粉、大豆粉等の穀粉;有機酸及びその塩、アスコルビン酸及びその塩等のpH調整剤等が挙げられる。中でも、上記油脂加工澱粉は、バッター作製時のダマの発生を効果的に抑制する観点からは、澱粉を油脂と乳化剤との存在下で油脂加工したものであることが好ましい。 The above-mentioned oil-and-fat modified starch may be obtained by processing starch with oil and fat in the presence of the oil and fat and an optional component other than the oil and fat. As the above optional components, emulsifiers having various HLB values; enzyme preparations such as amylases, cellulase, lipase, lipoxygenase; protein materials such as wheat protein, egg white and / or egg yolk-derived egg protein, milk protein, soy protein, and green bean protein; Flour such as wheat flour, barley flour, rice flour, soybean flour; pH adjusters such as organic acid and its salt, ascorbic acid and its salt, and the like can be mentioned. Above all, the oil-and-fat modified starch is preferably a starch processed with oil and fat in the presence of the oil and fat and an emulsifier from the viewpoint of effectively suppressing the generation of lumps during the production of batter.

上記油脂加工澱粉は、市販のものを使用することもできる。市販されている油脂加工澱粉としては、例えば、ミルフィクスD(王子コーンスターチ株式会社製)、バッター用澱粉BT-800(三和澱粉工業株式会社製)、日食バッタースターチ#500(日本食品化工株式会社製)等が挙げられる。 As the modified starch for fats and oils, commercially available starch can also be used. Examples of commercially available modified starches include Milfix D (manufactured by Oji Cornstarch Co., Ltd.), Starch for Batter BT-800 (manufactured by Sanwa Cornstarch Co., Ltd.), and Nisshoku Batter Starch # 500 (Nihon Shokuhin Kako Co., Ltd.). Made) and the like.

〔油脂〕
本発明の油脂加工澱粉組成物に含まれる油脂は、特に限定されず、食用に供される油脂であればいずれも好適に使用することができ、例えば、大豆油、菜種油、サフラワー油、エゴマ油、シソ油、コーン油、ヒマワリ油、綿実油、ゴマ油、オリーブ油、ヤシ油、米油、亜麻仁油、パーム油等の植物性油脂、魚油、牛脂、豚脂(ラード油)、鶏脂等の動物性油脂、これらを2種類以上組み合わせた混合油脂、及びこれらの油脂のうち1種又は2種以上の組み合わせに分別操作、エステル交換、水素添加等の加工処理を行った加工油脂等が挙げられる。上記油脂は、これらのうちの1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。上記油脂は、大豆油、菜種油、ゴマ油、パーム油、豚脂及びこれらの組み合わせから選択される1種以上であることが好ましく、大豆油、菜種油、ゴマ油及びこれらの組み合わせから選択される1種以上であることがより好ましい。
[Fat and oil]
The fats and oils contained in the fats and oils processed starch composition of the present invention are not particularly limited, and any fats and oils used for food can be preferably used, for example, soybean oil, rapeseed oil, safflower oil, and egoma. Vegetable oils such as oil, perilla oil, corn oil, sunflower oil, cottonseed oil, sesame oil, olive oil, palm oil, rice oil, flaxseed oil, palm oil, fish oil, beef oil, pork oil (lard oil), chicken oil and other animals Examples thereof include sex oils and fats, mixed oils and fats in which two or more kinds of these are combined, and processed oils and fats in which one or more of these oils and fats are subjected to a separation operation, ester exchange, hydrogenation and other processing treatments. As the oil and fat, only one of these may be used, or two or more thereof may be used in combination. The oil and fat is preferably one or more selected from soybean oil, rapeseed oil, sesame oil, palm oil, lard and a combination thereof, and one or more selected from soybean oil, rapeseed oil, sesame oil and a combination thereof. Is more preferable.

上記油脂は、室温で固体状の油脂及び室温で液状の油脂のいずれであってもよいが、液状にする作業上の手間を考慮すると、室温で液状の油脂を使用することが好ましい。また、油脂の代わりに、前記植物性油脂を分離精製する前の油糧種子を粉砕した油糧種子粉砕物を使用してもよい。この場合、澱粉に対する油脂の割合は、油糧種子に含まれる油脂の割合から適宜換算して求めることができる。 The fats and oils may be either solid fats and oils at room temperature or liquid fats and oils at room temperature, but it is preferable to use fats and oils that are liquid at room temperature in consideration of the time and effort required to make them liquid. Further, instead of the oil and fat, a crushed oil seed product obtained by crushing the oil seed before separating and refining the vegetable oil and fat may be used. In this case, the ratio of fats and oils to starch can be appropriately converted from the ratio of fats and oils contained in oil seeds.

〔乳化剤〕
本発明において、乳化剤とは、1分子中に親油性基(疎水基)及び親水性基を含む両親媒性化合物をいう。親油性基は油脂に馴染みやすく、親水性基は水に馴染みやすい性質を有する。乳化剤は、レシチン(大豆、卵黄等に由来)、サポニン(キラヤやダイズ等に由来)、カゼインナトリウム(牛乳由来)等の天然乳化剤と合成乳化剤とに大別される。食品利用できる合成乳化剤は、親油性基が炭素数8~22の飽和脂肪酸及び/又は不飽和脂肪酸で構成され、親水性基がグリセリン、ポリグリセリン、ショ糖、プロピレングリコール、ソルビタン等で構成される。HLB値は、乳化剤の疎水性と親水性とのバランスを示す数値であり、低いHLB値を有する乳化剤は疎水性が高く、高いHLB値を有する乳化剤は親水性が高い。
〔emulsifier〕
In the present invention, the emulsifier refers to an amphipathic compound containing a lipophilic group (hydrophobic group) and a hydrophilic group in one molecule. Lipophilic groups have the property of being easily compatible with fats and oils, and hydrophilic groups have the property of being easily compatible with water. Emulsifiers are roughly classified into natural emulsifiers such as lecithin (derived from soybeans, egg yolks, etc.), saponins (derived from Kiraya, soybeans, etc.), casein sodium (derived from milk), and synthetic emulsifiers. Synthetic emulsifiers that can be used in foods have lipophilic groups composed of saturated fatty acids and / or unsaturated fatty acids having 8 to 22 carbon atoms, and hydrophilic groups composed of glycerin, polyglycerin, sucrose, propylene glycol, sorbitan and the like. .. The HLB value is a numerical value indicating the balance between the hydrophobicity and the hydrophilicity of the emulsifier. The emulsifier having a low HLB value is highly hydrophobic, and the emulsifier having a high HLB value is highly hydrophilic.

本発明の油脂加工澱粉組成物に含まれる乳化剤は、特に限定されず、食用に供される乳化剤であればいずれも好適に使用することができ、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、有機酸モノグリセリド、有機酸ジグリセリド、ショ糖脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、レシチン等が挙げられる。上記乳化剤は、ショ糖ステアリン酸エステル、ショ糖パルミチン酸、グリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン、及びこれらの組み合わせから選択される1種以上であることが好ましい。上記乳化剤は、これらのうちの1種のみを用いてもよく、2種以上を組み合わせて用いてもよい。
乳化剤のHLB値は、特に限定されないが、3~18であることが好ましい。
The emulsifier contained in the oil-processed starch composition of the present invention is not particularly limited, and any edible emulsifier can be preferably used, for example, glycerin fatty acid ester, polyglycerin fatty acid ester, and organic. Examples thereof include acid monoglyceride, organic acid diglyceride, sucrose fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, and lecithin. The emulsifier is preferably one or more selected from sucrose stearic acid ester, sucrose palmitic acid, glycerin fatty acid ester, propylene glycol fatty acid ester, lecithin, and a combination thereof. As the emulsifier, only one of these may be used, or two or more of them may be used in combination.
The HLB value of the emulsifier is not particularly limited, but is preferably 3 to 18.

〔油脂加工澱粉組成物の製造方法〕
本発明の油脂加工澱粉組成物の製造方法としては、油脂加工澱粉、油脂及び乳化剤を均質に混合することができれば特に限定されないが、予め油脂と乳化剤の混合物(以下、「油脂-乳化剤混合物」という)を調製し、得られた油脂-乳化剤混合物を油脂加工澱粉に徐々に添加して混合することが好ましい。具体的には、油脂及び乳化剤をミキサーに投入して均質になるまで撹拌して油脂-乳化剤混合物を調製し、油脂加工澱粉を別のミキサーに投入して撹拌しながら、得られた油脂-乳化剤混合物を徐々に添加し、均質になるまで撹拌混合することにより油脂加工澱粉組成物を得ることが好ましい。なお、混合(撹拌)手法としては、ミキサー(リボンミキサー、ナウターミキサー、カスケードミキサー、ドラムミキサー、V字ミキサー等)を用いてもよく、手混ぜによって行ってもよい。
[Manufacturing method of modified starch composition]
The method for producing the modified starch composition of the present invention is not particularly limited as long as the modified starch, the oil and the emulsifier can be uniformly mixed, but is previously referred to as a mixture of the modified starch and the emulsifier (hereinafter referred to as "fat-emulsifier mixture"). ) Is prepared, and the obtained oil-fat-emulsifier mixture is preferably gradually added to the modified starch and mixed. Specifically, the fat and oil and the emulsifier are put into a mixer and stirred until they become homogeneous to prepare a fat and oil-emulsifier mixture, and the fat and oil modified starch is put into another mixer and stirred while stirring to obtain the obtained fat and oil-emulsifier. It is preferable to gradually add the mixture and stir and mix until it becomes homogeneous to obtain an oil-processed starch composition. As the mixing (stirring) method, a mixer (ribbon mixer, nouter mixer, cascade mixer, drum mixer, V-shaped mixer, etc.) may be used, or manual mixing may be performed.

上記乳化剤としてHLB値の高い親水性の乳化剤を使用する場合、油脂-乳化剤組成物の調製中に乳化剤が次第に沈降して油脂中に乳化剤の密度勾配が生じるため、油脂-乳化剤混合物を調製後、15分以内に次の工程で使用することが好ましい。15分以上静置して油脂中に乳化剤の密度勾配が生じたとしても、適宜混合して密度勾配を解消して使用することができる。また、油脂-乳化剤混合物を調製する際、30~80℃に加温して乳化剤を油脂中に均一に溶解又は分散させることが好ましいが、室温で調製してもよい。 When a hydrophilic emulsifier having a high HLB value is used as the emulsifier, the emulsifier gradually precipitates during the preparation of the fat-emulsifier composition, and a density gradient of the emulsifier is generated in the fat. It is preferably used in the next step within 15 minutes. Even if the emulsifier has a density gradient in the fat and oil after being allowed to stand for 15 minutes or more, it can be mixed appropriately to eliminate the density gradient before use. Further, when preparing the fat-emulsifier mixture, it is preferable to heat the mixture to 30 to 80 ° C. to uniformly dissolve or disperse the emulsifier in the fat, but it may be prepared at room temperature.

本発明の油脂加工澱粉組成物の製造において、油脂加工澱粉及び油脂-乳化剤混合物の混合温度及びその後の保持温度は、室温(例えば15~30℃)であってもよく、油脂加工澱粉の加熱熟成に相当する温度であってもよい。 In the production of the modified starch composition of the present invention, the mixing temperature of the modified starch and the oil-emulsifier mixture and the subsequent holding temperature may be room temperature (for example, 15 to 30 ° C.), and the modified starch is heat-aged. It may be a temperature corresponding to.

本発明の油脂加工澱粉組成物における油脂-乳化剤混合物の含有量は、油脂加工澱粉100質量部に対して0.05~17質量部である。0.05質量部未満であると、バッター調製時にダマの発生を十分に抑制することができず、17質量部を超えると、揚げ種と衣との間がねちゃついた食感となる。油脂加工澱粉組成物における油脂-乳化剤混合物の含有量は、油脂加工澱粉100質量部に対して0.1~16質量部であることが好ましく、0.5~15質量部であることがより好ましく、1~10質量部であることが更に好ましい。 The content of the oil-fat-emulsifier mixture in the oil-and-fat modified starch composition of the present invention is 0.05 to 17 parts by mass with respect to 100 parts by mass of the oil-and-fat modified starch. If it is less than 0.05 parts by mass, the generation of lumps cannot be sufficiently suppressed at the time of batter preparation, and if it exceeds 17 parts by mass, the texture between the fried seeds and the batter becomes sticky. The content of the fat-emulsifier mixture in the modified starch composition is preferably 0.1 to 16 parts by mass, more preferably 0.5 to 15 parts by mass with respect to 100 parts by mass of the modified starch. It is more preferably 1 to 10 parts by mass.

バッター作製時におけるダマの発生を抑制する観点からは、油脂加工澱粉組成物における油脂の含有量は、油脂加工澱粉100質量部に対して0.05~14質量部であることが好ましく、0.08~12質量部であることがより好ましく、0.2~10質量部であることが更に好ましい。 From the viewpoint of suppressing the generation of lumps during the production of batter, the content of fat and oil in the modified starch composition is preferably 0.05 to 14 parts by mass with respect to 100 parts by mass of the modified starch. It is more preferably 08 to 12 parts by mass, and even more preferably 0.2 to 10 parts by mass.

また、バッター作製時におけるダマの発生を抑制する観点からは、油脂加工澱粉組成物における乳化剤の含有量は、油脂100質量部に対して3~350質量部であることが好ましく、5~300質量部であることがより好ましく、11~233質量部であることが更に好ましい。 Further, from the viewpoint of suppressing the generation of lumps during the production of the batter, the content of the emulsifier in the modified starch composition is preferably 3 to 350 parts by mass with respect to 100 parts by mass of the fat and oil, and is preferably 5 to 300 parts by mass. The amount is more preferably 11 to 233 parts by mass, and further preferably 11 to 233 parts by mass.

食感に優れた揚げ物を得る観点からは、上記油脂-乳化剤混合物における油脂の含有量は、上記油脂加工澱粉100質量部に対して13.5質量部以下であることが好ましく、12質量部以下であることがより好ましく、10質量部以下であることが更に好ましい。 From the viewpoint of obtaining a fried food having an excellent texture, the content of fat and oil in the fat and oil-emulsifier mixture is preferably 13.5 parts by mass or less, preferably 12 parts by mass or less, based on 100 parts by mass of the modified starch. It is more preferably 10 parts by mass or less.

本発明の油脂加工澱粉組成物において、油脂-乳化剤混合物の合計量に対する油脂の含有割合は、22~97質量%である。上記油脂の含有割合が22質量%未満又は97質量%を超えると、バッター調製時にダマの発生を十分に抑制することが出来ない。上記油脂の含有割合は、25~95質量%であることが好ましく、40~90質量%であることがより好ましく、50~80質量%であることが更に好ましい。 In the modified starch composition of the present invention, the content ratio of the fat and oil to the total amount of the fat and oil-emulsifier mixture is 22 to 97% by mass. If the content ratio of the above fats and oils is less than 22% by mass or more than 97% by mass, the generation of lumps cannot be sufficiently suppressed during the batter preparation. The content ratio of the fats and oils is preferably 25 to 95% by mass, more preferably 40 to 90% by mass, and even more preferably 50 to 80% by mass.

〔揚げ物衣材用ミックス粉〕
本発明の揚げ物衣材用ミックス粉は、上記油脂加工澱粉組成物を含有する。本発明の揚げ物衣材用ミックス粉は、上記油脂加工澱粉組成物を使用して製造される。上記揚げ物衣材用ミックス粉は、上記油脂加工澱粉組成物以外に、本発明の効果を損なわない範囲で他の成分を含有してもよい。上記他の成分としては、例えば、小麦粉、大麦粉、デュラム小麦粉、ライ麦粉、米粉、大豆粉、緑豆粉、コーンフラワー等の穀物粉;タピオカ澱粉、馬鈴薯澱粉、コーンスターチ、小麦澱粉、米澱粉、甘藷澱粉、緑豆澱粉、サゴ澱粉等、並びにこれらのワキシー種及びハイアミロース種の未変性澱粉、並びにその未変性澱粉にα化、エーテル化、エステル化、架橋、酸化等の変性処理から選択される1種以上の変性処理を施した変性澱粉;キサンタンガム、ローカストビーンガム、ジェランガム、ペクチン、カラギーナン、グアガム、タマリンドガム、アラビアガム等の増粘多糖類;メチルセルロース等のセルロース誘導体;小麦蛋白、卵蛋白、乳蛋白、大豆蛋白、緑豆蛋白等の蛋白質素材;ブドウ糖、果糖、乳糖、砂糖、イソマルトース等の糖類;卵黄、卵白、全卵及びそれらを粉末化したものやその他の卵に由来する成分である卵成分;粉乳、脱脂粉乳、大豆粉乳等の乳成分;ショートニング、ラード、マーガリン、バター、液状油等の油脂類;乳化剤;膨張剤;食塩等の無機塩類;保存料;香料;香辛料;ビタミン;カルシウム等の強化剤等の通常揚げ物衣材用ミックス粉の製造に用いる副原料が挙げられる。
[Mixed powder for fried food batter]
The mixed powder for fried food batter of the present invention contains the above-mentioned modified starch composition. The mixed powder for fried food batter of the present invention is produced by using the above-mentioned oil-processed starch composition. The mixed powder for fried food batter may contain other components in addition to the oil-and-fat modified starch composition as long as the effects of the present invention are not impaired. Examples of the above other components include grain flour such as wheat flour, barley flour, durum wheat flour, rye flour, rice flour, soybean flour, green bean flour, and corn flour; tapioca starch, horse bell starch, corn starch, wheat starch, rice starch, and sweet potato. Starch, green bean starch, sago starch and the like, unmodified starches of these waxy and hyamylose species, and the unmodified starch are selected from modification treatments such as pregelatinization, etherification, esterification, cross-linking and oxidation 1. Modified starch that has undergone more than seed-modified treatment; thickening polysaccharides such as xanthan gum, locust bean gum, gellan gum, pectin, carrageenan, guar gum, tamarind gum, and arabic gum; cellulose derivatives such as methyl cellulose; wheat protein, egg protein, milk Protein materials such as protein, soybean protein, and green bean protein; sugars such as starch, fructose, lactose, sugar, and isomaltose; egg yolk, egg white, whole egg, powdered starch, and other egg-derived components. Ingredients: Milk ingredients such as starch, defatted starch, soybean starch; oils and fats such as starching, lard, margarine, butter, and liquid oil; emulsifiers; swelling agents; inorganic salts such as salt; preservatives; fragrances; spices; vitamins; calcium Examples thereof include auxiliary raw materials used for producing mixed starch for normal fried foods such as fortifiers such as starch.

本発明の揚げ物衣材用ミックス粉は、揚げ物用バッターミックスとして使用できるほか、単独又は小麦粉等の穀粉や澱粉等と混合して打ち粉として使用したり、揚げ種に直接まぶして使用したり、調味料及び任意に小麦粉等の穀粉や澱粉等と混合してマリネードミックスとして使用したりすることもできる。 The mixed flour for deep-fried foods of the present invention can be used as a batter mix for deep-fried foods, or can be used alone or mixed with flour such as wheat flour or starch, or sprinkled directly on fried seeds. It can also be used as a marinade mix by mixing it with a seasoning and optionally a flour such as wheat flour or starch.

〔揚げ物〕
本発明の揚げ物は、上記油脂加工澱粉組成物又は上記揚げ物衣材用ミックス粉を使用してなる。本発明の揚げ物は、上記油脂加工澱粉組成物又は上記揚げ物衣材用ミックス粉を使用する以外は、公知の手法を用いて製造することができる。例えば、事前に任意に下味をつけ及び/又は任意に打ち粉をまぶした揚げ種を用い、上記揚げ物衣材用ミックス粉を水溶きした揚げ物用バッター液に浸漬又は付着させ、任意にパン粉、粗く砕いた穀物粉、あられ、適当なサイズに砕いた乾麺等の固形衣材を付着させ、160~200℃に予熱した油槽で油ちょうする手法等が挙げられる。油ちょうする代わりに、衣付けした揚げ種を、油を薄く引いたフライパンで加熱してもよく、オーブン加熱して揚げ物様食品を得てもよい。上記揚げ物用バッター液は、例えば、上記油脂加工澱粉組成物100質量部に対し、50~500質量部の水を加えて混合することで調製することができる。上記揚げ物としては、天ぷら、から揚げ、カツ、フライ、フリッター等が挙げられる。
〔Fried food〕
The fried food of the present invention is made by using the above-mentioned oil-and-fat modified starch composition or the above-mentioned mixed powder for fried food batter. The fried food of the present invention can be produced by a known method except that the above-mentioned oil-and-fat modified starch composition or the above-mentioned mixed powder for fried food batter is used. For example, using a deep-fried food that has been arbitrarily seasoned and / or dusted in advance, the above-mentioned mixed powder for deep-fried food and batter is dipped or adhered to a water-soluble batter solution for deep-fried food, and optionally breaded or coarsely crushed. Examples thereof include a method in which solid batter such as bread crumbs, hail, and dried noodles crushed to an appropriate size is attached and oiled in an oil tank preheated to 160 to 200 ° C. Instead of oiling, the battered fried seeds may be heated in a frying pan lightly oiled or oven-heated to obtain fried food-like food. The fried food batter liquid can be prepared, for example, by adding 50 to 500 parts by mass of water to 100 parts by mass of the modified starch composition for oil and fat and mixing them. Examples of the fried food include tempura, fried chicken, cutlet, fried food, fritters and the like.

上記油ちょうに使用する食用油としては、特に限定されず、例えば、菜種油、ごま油、大豆油、コーン油、紅花油、オリーブ油、米油、綿実油、ひまわり油、サラダ油、オリーブ油、ショートニング、ラード油等が挙げられる。
上記揚げ種としては、特に限定されず、揚げ物として通常使用される食材を使用することができ、例えば、畜肉、魚介、野菜、山菜等が挙げられる。
The edible oil used for the above oil is not particularly limited, and for example, rapeseed oil, sesame oil, soybean oil, corn oil, red flower oil, olive oil, rice oil, cottonseed oil, sunflower oil, salad oil, olive oil, shortening, lard oil and the like. Can be mentioned.
The fried food is not particularly limited, and ingredients usually used as fried food can be used, and examples thereof include livestock meat, fish and shellfish, vegetables, and wild plants.

以下、実施例を挙げて本発明を更に詳細に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.

〔製造例1:油脂加工澱粉組成物の製造〕
(1)80質量部の油脂(日清サラダ油、日清オイリオグループ株式会社、大豆油及び菜種油の混合油)及び20質量部の乳化剤(リョートーシュガーエステルS-1670、三菱ケミカルフーズ株式会社製、ショ糖ステアリン酸エステル、HLB値:16)をミキサー(MX-X501、パナソニック株式会社製)を用いて、室温で均一になるまで混合して油脂-乳化剤混合物を調製した。
(2)100質量部の油脂加工澱粉(日食バッタースターチ#500、日本食品化工株式会社製)をFM型ミキサー(日本コークス工業株式会社製)に投入し、油脂加工澱粉を室温で撹拌しながら、(1)で得られた油脂-乳化剤混合物1質量部を、油脂-乳化剤混合物を調製してから15分以内に徐々に添加し、均一になるまで撹拌混合して油脂加工澱粉組成物を調製した。
[Production Example 1: Production of modified starch composition]
(1) 80 parts by mass of fat (Nisshin Salad Oil, Nisshin Oillio Group Co., Ltd., mixed oil of soybean oil and rapeseed oil) and 20 parts by mass of emulsifier (Ryoto Sugar Ester S-1670, manufactured by Mitsubishi Chemical Foods Co., Ltd.) A sucrose stearic acid ester, HLB value: 16) was mixed using a mixer (MX-X501, manufactured by Panasonic Corporation) until uniform at room temperature to prepare an oil-emulsifier mixture.
(2) Put 100 parts by mass of modified starch (Nissho Batter Starch # 500, manufactured by Nippon Foods Chemicals Co., Ltd.) into an FM type mixer (manufactured by Nippon Coke Industries Co., Ltd.) and stir the modified starch at room temperature. , 1 part by mass of the oil-fat-emulsifier mixture obtained in (1) is gradually added within 15 minutes after the oil-fat-emulsifier mixture is prepared, and stirred and mixed until uniform to prepare a modified starch composition. did.

〔製造例2:揚げ物(トンカツ)の製造〕
(1)製造例1で得られた油脂加工澱粉組成物100質量部及び冷水300質量部をスリーワンモーター(新東科学株式会社製、撹拌翼かい十字を先端に取り付けた撹拌棒を使用)を用いて1200rpmで3分間撹拌混合することにより、揚げ物用バッター液を調製した。
(2)厚さ1.5cmの豚肉塊100gを(1)で得られた揚げ物用バッター液で満遍なく被覆し、更に生パン粉を満遍なく付着させて衣付き揚げ種を調製した。バッター被覆直後及びパン粉付着直後に揚げ種を重量測定(n=10)したところ、各々平均110g、125gであった。
(3)食用油を170℃に予熱した油槽に(2)の衣付き揚げ種を投入し、反転含めて5分間油ちょうしてトンカツを得た。
[Manufacturing example 2: Production of fried food (pork cutlet)]
(1) Using a three-one motor (manufactured by Shinto Kagaku Co., Ltd., using a stirring rod with a stirring blade cage cross attached to the tip) for 100 parts by mass of the oil-processed starch composition obtained in Production Example 1 and 300 parts by mass of cold water. A batter solution for deep-fried food was prepared by stirring and mixing at 1200 rpm for 3 minutes.
(2) 100 g of pork lumps having a thickness of 1.5 cm were evenly covered with the fried food batter solution obtained in (1), and raw bread crumbs were evenly adhered to prepare battered fried seeds. When the fried seeds were weighed (n = 10) immediately after the batter coating and immediately after the bread crumbs adhered, the averages were 110 g and 125 g, respectively.
(3) The fried seeds with batter of (2) were put into an oil tank in which cooking oil was preheated to 170 ° C., and the oil was squeezed for 5 minutes including inversion to obtain pork cutlet.

〔評価例1:油脂加工澱粉組成物の分散性〕
粉体を水分に溶いた場合に、粉体の分散性が悪いとダマが形成される。この形成されたダマを定量化することにより、粉体の水分への分散性を評価することができる。
製造例2(1)で得られた揚げ物用バッター液を目開き1mmのメッシュに通し、メッシュを通過しメッシュ下部に付着した揚げ物用バッター液をゴムベラで十分にぬぐい取り、メッシュを上皿天秤に乗せて重量を測定した。未使用時のメッシュの重量を差し引いて、メッシュを通過しない揚げ物用バッター(ダマ)の重量を算出した。メッシュを通過しない揚げ物用バッターの重量を、メッシュに供した揚げ物用バッター液全量の重量で除した値を、ダマの割合と算出することにより、油脂加工澱粉組成物の水分への分散性を評価した。例えば、400gの揚げ物用バッター液をメッシュに通し、メッシュを通過しない揚げ物用バッターが80g存在する場合、ダマの割合を20%とする。
[Evaluation Example 1: Dispersibility of modified starch composition]
When the powder is dissolved in water, lumps are formed if the dispersibility of the powder is poor. By quantifying the formed lumps, the dispersibility of the powder in water can be evaluated.
Pass the fried food batter liquid obtained in Production Example 2 (1) through a mesh with an opening of 1 mm, thoroughly wipe off the fried food batter liquid that has passed through the mesh and adhered to the bottom of the mesh with a rubber spatula, and put the mesh on a precision balance. It was put on and weighed. The weight of the fried food batter (dama) that does not pass through the mesh was calculated by subtracting the weight of the unused mesh. The dispersibility of the oil-processed starch composition in water is evaluated by calculating the lump ratio by dividing the weight of the fried food batter that does not pass through the mesh by the weight of the total amount of the fried food batter liquid supplied to the mesh. did. For example, when 400 g of fried food batter liquid is passed through a mesh and 80 g of fried food batter that does not pass through the mesh is present, the ratio of lumps is set to 20%.

〔評価例2:トンカツの食感評価〕
油ちょうしたトンカツを油切りバットに上げて油切りし、短手方向に約2cmに切断し、熟練パネラー10名により下記評価表1に従って評価し、平均点を求めた。
評価表1 食感評価

Figure 2022032448000001
[Evaluation example 2: Evaluation of texture of pork cutlet]
The oiled tonkatsu was raised in an oil draining vat, drained, cut into pieces of about 2 cm in the lateral direction, evaluated by 10 skilled panelists according to the following evaluation table 1, and the average score was calculated.
Evaluation table 1 Texture evaluation
Figure 2022032448000001

〔評価例3:衣の結着性評価〕
フライしたトンカツを油切りバットに上げて油切りし、短手方向に約2cm幅に切断し、豚肉と衣との接着部分の剥がれの程度を目視で確認し、下記評価表2に従って評価した。なお、各試験区に対して10枚のトンカツを用いて評価し、衣剥がれ(豚肉の全表面積に対する衣が剥がれている部分の豚肉の表面積)が10%未満を合格とした。
評価表2 結着性評価

Figure 2022032448000002
[Evaluation example 3: Evaluation of batter binding]
The fried pork cutlet was raised in an oil draining vat, drained, cut to a width of about 2 cm in the lateral direction, and the degree of peeling of the adhesive portion between the pork and the garment was visually confirmed and evaluated according to the following evaluation table 2. In addition, each test group was evaluated using 10 pork cutlets, and the case where the batter peeling (the surface area of the pork in the part where the batter was peeled off with respect to the total surface area of the pork) was less than 10% was accepted.
Evaluation table 2 Cohesiveness evaluation
Figure 2022032448000002

〔試験例1:油脂加工澱粉及び油脂-乳化剤混合物の割合の検討〕
油脂及び乳化剤の合計量に対する油脂の含有割合を80質量%に固定し、油脂-乳化剤混合物の配合量を下記表1に記載の通りにしたこと以外は、製造例1及び2に従ってトンカツを製造し、評価例1~3に従って評価した。結果を表1に示す。なお*印は、油脂加工澱粉100質量部に対する油脂-乳化剤混合物における油脂及び乳化剤の添加量(質量部)であることを表す。
[Test Example 1: Examination of the ratio of modified starch and oil-emulsifier mixture]
Tonkatsu was produced according to Production Examples 1 and 2 except that the content ratio of the fat and oil to the total amount of the fat and oil and the emulsifier was fixed at 80% by mass and the blending amount of the fat and oil-emulsifier mixture was as shown in Table 1 below. , Evaluation examples 1 to 3 were evaluated. The results are shown in Table 1. The * mark indicates the amount (parts by mass) of the fat and the emulsifier added in the fat-emulsifier mixture with respect to 100 parts by mass of the modified starch.

Figure 2022032448000003
Figure 2022032448000003

表1より、油脂加工澱粉のみを使用した比較例1では、ダマの割合が15%を超え、水分への分散性が悪かった。一方、油脂-乳化剤混合物を含む油脂加工澱粉組成物を使用した場合は、油脂-乳化剤混合物の配合量が増加するに従ってダマの割合が減少し、15質量部加えた実施例6では、ダマがほとんど発生しなかった。油脂-乳化剤混合物の配合量が多い比較例2では、ダマの発生は抑制されたが、衣と豚肉の間の食感が悪かった。衣の豚肉への結着性は、実施例及び比較例共に衣剥がれが少なく、いずれも合格レベルであった。 From Table 1, in Comparative Example 1 in which only the oil-and-fat modified starch was used, the proportion of lumps exceeded 15%, and the dispersibility in water was poor. On the other hand, when a modified starch composition containing an oil / fat / emulsifier mixture was used, the proportion of lumps decreased as the blending amount of the oil / fat / emulsifier mixture increased, and in Example 6 in which 15 parts by mass was added, most of the lumps were present. It did not occur. In Comparative Example 2 in which the amount of the oil-fat-emulsifier mixture was large, the occurrence of lumps was suppressed, but the texture between the clothes and the pork was poor. As for the binding property of the batter to pork, the batter was less peeled off in both the examples and the comparative examples, and both were at the acceptable level.

〔試験例2:油脂-乳化剤混合物における油脂及び乳化剤の割合の検討〕
油脂-乳化剤混合物における油脂及び乳化剤の割合を下記表2及び3に記載の通りにしたこと以外は、実施例3と同様にしてトンカツを製造し(油脂加工澱粉100質量部に対して油脂-乳化剤混合物が1質量部)、評価例1~3に従って評価した。結果を表2及び3に示す。
[Test Example 2: Examination of the ratio of fat and emulsifier in the fat-emulsifier mixture]
Tonkatsu was produced in the same manner as in Example 3 except that the ratio of fat and emulsifier in the fat-emulsifier mixture was as shown in Tables 2 and 3 below (fat-emulsifier with respect to 100 parts by mass of modified starch). The mixture was evaluated according to 1 part by mass) and Evaluation Examples 1 to 3. The results are shown in Tables 2 and 3.

Figure 2022032448000004
Figure 2022032448000004

Figure 2022032448000005
Figure 2022032448000005

表2及び3より、油脂加工澱粉に油脂のみを添加した比較例3及び油脂加工澱粉に乳化剤のみを添加した比較例6は、何も添加しない比較例1に比べると、若干ダマの割合を抑制されているが、合格レベルには達しなかった。油脂-乳化剤混合物における油脂の含有割合が99質量%である比較例4及び20%である比較例5は、比較例3と比較してダマの割合が抑制されているが、依然としてダマの割合が10%を超えており、油脂加工澱粉組成物の水分への分散性が悪かった。一方、油脂-乳化剤混合物における油脂の含有割合が95質量%である実施例7では、ダマの割合が10%以下となり、油脂の含有割合が少なくなるほどダマの割合が減少し、油脂の含有割合が70質量%のとき(実施例10)に最もダマの割合が少なくなった。更に油脂の含有割合を少なくすると、ダマの割合は増加していったが、いずれも合格レベルであった(実施例11、12)。 From Tables 2 and 3, Comparative Example 3 in which only the oil and fat was added to the modified starch and Comparative Example 6 in which only the emulsifier was added to the modified starch in the oil and fat slightly suppressed the proportion of lumps as compared with Comparative Example 1 in which nothing was added. However, it did not reach the passing level. In Comparative Example 4 in which the content ratio of fat and oil in the fat-emulsifier mixture is 99% by mass and Comparative Example 5 in which the content ratio of fat and oil is 20%, the ratio of lumps is suppressed as compared with Comparative Example 3, but the ratio of lumps is still high. It exceeded 10%, and the dispersibility of the modified starch composition in water was poor. On the other hand, in Example 7 in which the content ratio of the fat and oil in the fat and oil-emulsifier mixture is 95% by mass, the ratio of lumps is 10% or less, and as the content ratio of the fats and oils decreases, the ratio of lumps decreases and the content ratio of the fats and oils increases. When it was 70% by mass (Example 10), the proportion of lumps was the smallest. Further, when the content ratio of fats and oils was further reduced, the ratio of lumps increased, but all of them were at the passing level (Examples 11 and 12).

〔試験例3:油脂-乳化剤混合物における油脂の種類の検討〕
油脂-乳化剤混合物の製造に際して使用される油脂の種類を下記表4に記載の通りにしたこと以外は、実施例3と同様にしてトンカツを製造し、評価例1~3に従って評価した。なお、常温で固体の油脂(パーム油及びラード油)は、加温して完全に融解した状態で使用した。結果を表4に示す。
[Test Example 3: Examination of types of fats and oils in a fat and oil-emulsifier mixture]
Tonkatsu was produced in the same manner as in Example 3 except that the types of oils and fats used in the production of the oil and fat-emulsifier mixture were as shown in Table 4 below, and evaluated according to Evaluation Examples 1 to 3. The fats and oils (palm oil and lard oil) solid at room temperature were used in a state of being completely melted by heating. The results are shown in Table 4.

Figure 2022032448000006
Figure 2022032448000006

表4より、油脂の種類がいずれのものであっても、トンカツの食感及び衣の豚肉に対する結着性を良好に維持しつつ、バッターを調製する際のダマの発生を効果的に抑制することができた。 From Table 4, regardless of the type of fat and oil, the texture of pork cutlet and the binding property of batter to pork are well maintained, and the occurrence of lumps when preparing batter is effectively suppressed. I was able to.

〔試験例4:油脂-乳化剤混合物における乳化剤の種類の検討〕
油脂-乳化剤混合物の製造に際して使用される乳化剤の種類を下記表5に記載の通りにしたこと以外は、実施例3と同様にしてトンカツを製造し、評価例1~3に従って評価した。なお、表5に記載の乳化剤1~7は、以下の通りである。
乳化剤1:三菱ケミカルフーズ株式会社製、リョートーシュガーエステルS-1670(HLB値:16)
乳化剤2:三菱ケミカルフーズ株式会社製、リョートーシュガーエステルS-1170(HLB値:11)
乳化剤3:三菱ケミカルフーズ株式会社製、リョートーシュガーエステルS-370(HLB値:3)
乳化剤4:三菱ケミカルフーズ株式会社製、リョートーシュガーエステルP-1670(HLB値:16)
乳化剤5:太陽化学株式会社製、サンソフトQ-185SP(HLB値:4.5)
乳化剤6:理研ビタミン株式会社製、リケマールPS-100(HLB値:3.7)
乳化剤7:太陽化学株式会社製、サンレシチンA-1
乳化剤1~3は、ショ糖ステアリン酸エステルであり、乳化剤4は、ショ糖パルミチン酸エステルであり、乳化剤5は、グリセリン脂肪酸エステルであり、乳化剤6は、プロピレングリコール脂肪酸エステルであり、乳化剤7は、レシチンである。
[Test Example 4: Examination of the type of emulsifier in a fat-emulsifier mixture]
Tonkatsu was produced in the same manner as in Example 3 except that the types of emulsifiers used in the production of the oil-fat-emulsifier mixture were as shown in Table 5 below, and evaluated according to Evaluation Examples 1 to 3. The emulsifiers 1 to 7 shown in Table 5 are as follows.
Emulsifier 1: Ryoto Sugar Ester S-1670 (HLB value: 16) manufactured by Mitsubishi Chemical Foods Co., Ltd.
Emulsifier 2: Ryoto Sugar Ester S-1170 (HLB value: 11) manufactured by Mitsubishi Chemical Foods Co., Ltd.
Emulsifier 3: Ryoto Sugar Ester S-370 (HLB value: 3) manufactured by Mitsubishi Chemical Foods Co., Ltd.
Emulsifier 4: Ryoto Sugar Ester P-1670 (HLB value: 16) manufactured by Mitsubishi Chemical Foods Co., Ltd.
Emulsifier 5: Sunsoft Q-185SP manufactured by Taiyo Kagaku Co., Ltd. (HLB value: 4.5)
Emulsifier 6: Riken Vitamin Co., Ltd., Rikemar PS-100 (HLB value: 3.7)
Emulsifier 7: Sanrecithin A-1 manufactured by Taiyo Kagaku Co., Ltd.
Emulsifiers 1 to 3 are sucrose stearic acid esters, emulsifier 4 is sucrose palmitate, emulsifier 5 is glycerin fatty acid ester, emulsifier 6 is propylene glycol fatty acid ester, and emulsifier 7 is. , Emulsifier.

Figure 2022032448000007
Figure 2022032448000007

表5より、乳化剤の種類がいずれのものであっても、トンカツの食感及び衣の豚肉に対する結着性を良好に維持しつつ、バッターを調製する際のダマの発生を効果的に抑制することができた。 From Table 5, regardless of the type of emulsifier, the texture of pork cutlet and the binding property of batter to pork are well maintained, and the generation of lumps when preparing batter is effectively suppressed. I was able to.

〔試験例5:油脂加工澱粉の種類の検討〕
油脂加工澱粉の種類を下記表6に記載の通りにしたこと以外は、実施例3と同様にしてトンカツを製造し(油脂-乳化剤混合物に対する油脂の含有割合は80質量%)、評価例1~3に従って評価した。結果を表6に示す。なお、表6に記載の油脂加工澱粉1~5は、以下の通りである。
油脂加工澱粉1:日本食品化工株式会社製、日食バッタースターチ#500(乳化剤不含)
油脂加工澱粉2:王子コーンスターチ株式会社製、ミルフィクスD(乳化剤不含)
油脂加工澱粉3:東海デキストリン株式会社製、OC-2(乳化剤不含)
油脂加工澱粉4:日本食品化工株式会社製、日食バッタースターチ#200N(乳化剤含有)
油脂加工澱粉5:三和澱粉工業株式会社製、バッター用澱粉BT-800(乳化剤含有)
[Test Example 5: Examination of types of modified starch]
Tonkatsu was produced in the same manner as in Example 3 except that the types of modified starch were as shown in Table 6 below (the content ratio of fat and oil in the fat and oil-emulsifier mixture was 80% by mass), and Evaluation Examples 1 to 1 to It was evaluated according to 3. The results are shown in Table 6. The oil-and-fat modified starches 1 to 5 shown in Table 6 are as follows.
Oil-processed starch 1: Nihon Shokuhin Kako Co., Ltd., Nissho Batter Starch # 500 (without emulsifier)
Oil-processed starch 2: Made by Oji Corn Starch Co., Ltd., Milfix D (without emulsifier)
Oil-processed starch 3: Made by Tokai Dextrin Co., Ltd., OC-2 (without emulsifier)
Oil-processed starch 4: Nihon Shokuhin Kako Co., Ltd., Nissho Batter Starch # 200N (containing emulsifier)
Oil-processed starch 5: Sanwa Cornstarch Co., Ltd., starch for batter BT-800 (containing emulsifier)

Figure 2022032448000008
Figure 2022032448000008

表6より、いずれの油脂加工澱粉を使用しても、油脂-乳化剤混合物を添加することにより油脂加工澱粉組成物を水溶きしてバッターを調製する際のダマの発生を抑制し、得られたトンカツの食感及び衣の豚肉に対する結着性が良好に維持されていた。
油脂加工澱粉4及び5は乳化剤を使用して製造されたものであり、これらを単独で使用した(油脂-乳化剤混合物を添加しない)比較例9及び10では、乳化剤を使用せずに製造された油脂加工澱粉1~3を単独で使用した比較例1、7及び8よりもダマの発生が抑制されているが、合格レベルには達しなかった。一方、油脂加工澱粉4及び5に油脂-乳化剤混合物を添加して油脂加工澱粉組成物とした実施例26及び27では、ダマの発生が7%未満と低い値を示した。
From Table 6, no matter which oil-processed starch is used, the pork cutlet obtained by adding the oil-fat-emulsifier mixture to dissolve the oil-and-fat modified starch composition in water to suppress the generation of lumps when preparing the batter. The texture of the batter and the binding property of the batter to the pork were well maintained.
The oil-processed starches 4 and 5 were produced using an emulsifier, and in Comparative Examples 9 and 10 using these alone (without adding the oil-emulsifier mixture), they were produced without using an emulsifier. Although the generation of lumps was suppressed as compared with Comparative Examples 1, 7 and 8 in which the oil-processed starches 1 to 3 were used alone, the acceptance level was not reached. On the other hand, in Examples 26 and 27 in which the oil-and-fat-modified starch mixture was added to the oil-and-fat modified starch 4 and 5 to prepare the oil-and-fat modified starch composition, the occurrence of lumps was as low as less than 7%.

Claims (6)

油脂加工澱粉、油脂及び乳化剤を含み、
前記油脂及び前記乳化剤の合計量に対する前記油脂の含有割合が22~97質量%であり、
前記油脂及び前記乳化剤の合計量が前記油脂加工澱粉100質量部に対して0.05~17質量部である、
油脂加工澱粉組成物。
Contains modified starch, fats and emulsifiers,
The content ratio of the fat and oil to the total amount of the fat and oil and the emulsifier is 22 to 97% by mass.
The total amount of the fat and oil and the emulsifier is 0.05 to 17 parts by mass with respect to 100 parts by mass of the modified starch.
Oil-processed starch composition.
請求項1に記載の油脂加工澱粉組成物を含有する、揚げ物衣材用ミックス粉。 A mixed powder for fried food batter containing the oil-and-fat modified starch composition according to claim 1. 請求項1に記載の油脂加工澱粉組成物又は請求項2に記載の揚げ物衣材用ミックス粉を使用してなる、揚げ物。 A fried food made by using the oil-and-fat modified starch composition according to claim 1 or the mixed powder for fried food batter according to claim 2. 油脂及び乳化剤を混合して、前記油脂を22~97質量%含む油脂-乳化剤混合物を得る工程、及び
油脂加工澱粉100質量部に対して0.05~17質量部の前記油脂-乳化剤混合物を混合する工程を含む、
油脂加工澱粉組成物の製造方法。
The step of mixing the fat and the emulsifier to obtain the fat-emulsifier mixture containing 22 to 97% by mass of the fat and oil, and mixing 0.05 to 17 parts by mass of the fat-emulsifier mixture with 100 parts by mass of the modified starch. Including the process of
A method for producing a modified starch composition.
請求項4に記載の方法によって得られた油脂加工澱粉組成物を使用する、揚げ物衣材用ミックス粉の製造方法。 A method for producing a mixed powder for deep-fried food batter, using the oil-and-fat modified starch composition obtained by the method according to claim 4. 請求項4に記載の方法によって得られた油脂加工澱粉組成物又は請求項5に記載の方法によって得られた揚げ物衣材用ミックス粉を使用する、揚げ物の製造方法。 A method for producing a deep-fried food using the oil-and-fat modified starch composition obtained by the method according to claim 4 or the mixed powder for deep-fried food batter obtained by the method according to claim 5.
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