JP2022031758A5 - - Google Patents

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JP2022031758A5
JP2022031758A5 JP2021188807A JP2021188807A JP2022031758A5 JP 2022031758 A5 JP2022031758 A5 JP 2022031758A5 JP 2021188807 A JP2021188807 A JP 2021188807A JP 2021188807 A JP2021188807 A JP 2021188807A JP 2022031758 A5 JP2022031758 A5 JP 2022031758A5
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photosensitive
resin composition
layer
insulating substrate
acid
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JP2021188807A
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JP7294389B2 (en
JP2022031758A (en
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Priority claimed from JP2016179479A external-priority patent/JP7035304B2/en
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Publication of JP2022031758A5 publication Critical patent/JP2022031758A5/ja
Priority to JP2023092165A priority patent/JP2023115039A/en
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(A)酸変性ビニル基含有エポキシ樹脂、(B)エチレン性不飽和結合を有する光重合性モノマー、(C)光重合開始剤及び(D)無機フィラーを含有してなる感光性樹脂組成物であり、(A)成分の酸変性ビニル基含有エポキシ樹脂が、下記一般式(1)で表されるノボラック型エポキシ樹脂であるエポキシ樹脂(a)と、ビニル基含有モノカルボン酸(b)とを反応させて得られる樹脂(A’)に、飽和若しくは不飽和基含有多塩基酸無水物を反応させて得られる樹脂(A’’)(ただし、Mw/Mn(重量平均分子量/数平均分子量)で表される分散度が2.0~5.0のもの。また、o-クレゾールノボラック樹脂とアクリル酸とを反応させた後、テトラヒドロ無水フタル酸を反応させてなる樹脂、及びo-クレゾールノボラック樹脂とアクリル酸とペンタエリスリトールトリアクリレート・無水コハク酸付加物とを反応させた後、無水コハク酸及びテトラヒドロ無水フタル酸と反応させてなる樹脂を除く。)を含み、かつ、(A)酸変性ビニル基含有エポキシ樹脂の含有量が全固形分量に対して15~60質量%であり、(D)無機フィラーの含有量が全固形分量に対し30~70質量%である感光性樹脂組成物。
Figure 2022031758000001

[一般式(1)中、R11は水素原子又はメチル基を示し、Yは水素原子又はグリシジル基を示し、n1は1以上の整数を示す。なお、複数存在するR11及びYはそれぞれ同一でも異なっていてもよい。但し、少なくとも一つのYはグリシジル基を示す
A photosensitive resin composition comprising (A) an acid-modified vinyl group-containing epoxy resin, (B) a photopolymerizable monomer having an ethylenically unsaturated bond, (C) a photopolymerization initiator, and (D) an inorganic filler and the acid-modified vinyl group-containing epoxy resin of the component (A) is an epoxy resin (a) which is a novolac epoxy resin represented by the following general formula (1), and a vinyl group-containing monocarboxylic acid (b) Resin (A'') obtained by reacting saturated or unsaturated group-containing polybasic acid anhydride with resin (A') obtained by reacting (however, Mw / Mn (weight average molecular weight / number average molecular weight ) and a resin obtained by reacting an o-cresol novolac resin with acrylic acid and then with tetrahydrophthalic anhydride, and o-cresol. ), and (A) an acid A photosensitive resin composition in which the content of the modified vinyl group-containing epoxy resin is 15 to 60% by mass relative to the total solid content, and (D) the content of the inorganic filler is 30 to 70% by mass relative to the total solid content. thing.
Figure 2022031758000001

[In general formula (1), R 11 represents a hydrogen atom or a methyl group, Y 1 represents a hydrogen atom or a glycidyl group, and n1 represents an integer of 1 or more. Plural R 11 and Y 1 may be the same or different. However, at least one Y1 represents a glycidyl group . ]
(B)エチレン性不飽和結合を有する光重合性モノマーが、エチレン性不飽和結合を1分子内に3つ以上有する多官能光重合性モノマーである請求項1に記載の感光性樹脂組成物。 2. The photosensitive resin composition according to claim 1, wherein (B) a photopolymerizable monomer having an ethylenically unsaturated bond is a polyfunctional photopolymerizable monomer having 3 or more ethylenically unsaturated bonds in one molecule. 更に(E)顔料を含む請求項1又は請求項2に記載の感光性樹脂組成物。 3. The photosensitive resin composition according to claim 1, further comprising (E) a pigment. 支持体と、請求項1~3のいずれか一項に記載の感光性樹脂組成物から形成された感光層とを備える、感光性フィルム。 A photosensitive film comprising a support and a photosensitive layer formed from the photosensitive resin composition according to any one of claims 1 to 3. 絶縁基板と前記絶縁基板上に形成された回路パターンを有する導体層とを備える積層基板の前記絶縁基板上に、前記導体層を覆うように請求項1~3のいずれか一項に記載の感光性樹脂組成物を用いて感光層を積層し、前記感光層の所定部分に活性光線を照射して露光部を形成し、次いで、前記感光層の前記露光部以外の部分を除去することを特徴とする、レジストパターンの形成方法。 The photosensitive material according to any one of claims 1 to 3, on the insulating substrate of a laminated substrate comprising an insulating substrate and a conductive layer having a circuit pattern formed on the insulating substrate, so as to cover the conductive layer. A photosensitive layer is laminated using a flexible resin composition, a predetermined portion of the photosensitive layer is irradiated with an actinic ray to form an exposed portion, and then portions of the photosensitive layer other than the exposed portion are removed. and a method of forming a resist pattern. 絶縁基板と、前記絶縁基板上に形成された回路パターンを有する導体層と、前記導体層を覆うように請求項1~3のいずれか一項に記載の感光性樹脂組成物を用いて形成された永久レジスト層とを備えるプリント配線板。 An insulating substrate, a conductor layer having a circuit pattern formed on the insulating substrate, and the photosensitive resin composition according to any one of claims 1 to 3 so as to cover the conductor layer. and a permanent resist layer.
JP2021188807A 2016-09-14 2021-11-19 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern, and printed wiring board Active JP7294389B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2021188807A JP7294389B2 (en) 2016-09-14 2021-11-19 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern, and printed wiring board
JP2023092165A JP2023115039A (en) 2016-09-14 2023-06-05 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern and printed wiring board

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016179479A JP7035304B2 (en) 2016-09-14 2016-09-14 A photosensitive resin composition, a photosensitive film using the photosensitive resin composition, a method for forming a resist pattern, and a printed wiring board.
JP2021188807A JP7294389B2 (en) 2016-09-14 2021-11-19 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern, and printed wiring board

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JP2016179479A Division JP7035304B2 (en) 2016-09-14 2016-09-14 A photosensitive resin composition, a photosensitive film using the photosensitive resin composition, a method for forming a resist pattern, and a printed wiring board.

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JP2023092165A Division JP2023115039A (en) 2016-09-14 2023-06-05 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern and printed wiring board

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JP2022031758A JP2022031758A (en) 2022-02-22
JP2022031758A5 true JP2022031758A5 (en) 2022-07-26
JP7294389B2 JP7294389B2 (en) 2023-06-20

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JP2021188807A Active JP7294389B2 (en) 2016-09-14 2021-11-19 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern, and printed wiring board
JP2023092165A Pending JP2023115039A (en) 2016-09-14 2023-06-05 Photosensitive resin composition, photosensitive film using the same, method for forming resist pattern and printed wiring board

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Publication number Priority date Publication date Assignee Title
JP4471149B2 (en) 2003-10-10 2010-06-02 日本化薬株式会社 Photosensitive resin composition and method for producing cured product thereof
JP5994201B2 (en) 2015-02-10 2016-09-21 東洋インキScホールディングス株式会社 Circuit board with electromagnetic shielding film and manufacturing method thereof

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