JP2022023698A - Sewage sludge fermentation raw material - Google Patents

Sewage sludge fermentation raw material Download PDF

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JP2022023698A
JP2022023698A JP2020126812A JP2020126812A JP2022023698A JP 2022023698 A JP2022023698 A JP 2022023698A JP 2020126812 A JP2020126812 A JP 2020126812A JP 2020126812 A JP2020126812 A JP 2020126812A JP 2022023698 A JP2022023698 A JP 2022023698A
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sewage sludge
mass
raw material
fermentation
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明宏 古賀
Akihiro Koga
英二 丸屋
Eiji Maruya
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Ube Corp
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Ube Industries Ltd
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Abstract

To provide a sewage sludge fermentation raw material that can easily and stably promote fermentation without adjusting a composition according to a fermentation state each time.SOLUTION: A sewage sludge fermentation raw material of the present invention for aerobic fermentation treatment contains sewage sludge and hydrated lime, and contains 1.5 mass.pts or more and 2.5 mass.pts or less of the hydrated lime with respect to 100 mass.pts of the sewage sludge. It is also preferable that the sewage sludge fermentation raw material further contain a nutritional auxiliary material, and it is also preferable that the nutritional auxiliary material be contained in the amount of 5 mass.pts or more and 50 mass.pts or less with respect to 100 mass.pts of the sewage sludge. It is also preferable that the sewage sludge fermentation raw material further contain an aeration auxiliary material, and it is also preferable that the aeration auxiliary material be contained in the amount of 5 mass.pts or more and 50 mass.pts or less with respect to 100 mass.pts of the sewage sludge.SELECTED DRAWING: Figure 1

Description

本発明は、下水汚泥を好気発酵させるための原料に関する。 The present invention relates to a raw material for aerobic fermentation of sewage sludge.

下水汚泥は、有機物及び水を含む泥状の物質であり、生活活動に伴う下水処理の過程で不可避的に排出されるものである。下水汚泥は、その排出量が下水処理量の増加に伴って増えており、都市ゴミと同様に、その処理が問題となっている。下水汚泥を処理するために、例えば該汚泥を焼却処理して、その際に生じた熱をエネルギー源として利用する試みが行われているが、更なる効率的な焼却処理を行うために、下水汚泥の含水率を下げることが望まれている。 Sewage sludge is a muddy substance containing organic matter and water, and is inevitably discharged in the process of sewage treatment associated with daily activities. The amount of sewage sludge discharged increases with the increase in the amount of sewage treatment, and the treatment of sewage sludge has become a problem, as with urban waste. In order to treat sewage sludge, for example, an attempt has been made to incinerate the sludge and use the heat generated at that time as an energy source, but in order to carry out a more efficient incineration treatment, sewage It is desired to reduce the water content of sludge.

下水汚泥の含水率を安価に低下させる技術として、下水汚泥を好気発酵させる技術が知られている。例えば、特許文献1~3には、脱水効率の向上及び悪臭防止等のために、有機汚泥と、フライアッシュとを混合して発酵する方法が開示されている。 As a technique for inexpensively reducing the water content of sewage sludge, a technique for aerobically fermenting sewage sludge is known. For example, Patent Documents 1 to 3 disclose a method of mixing and fermenting organic sludge and fly ash in order to improve dehydration efficiency and prevent malodor.

また特許文献4には、下水汚泥に通気性改善材を添加して好気発酵させて含水率を低下させる技術が開示されている。 Further, Patent Document 4 discloses a technique of adding a breathability improving material to sewage sludge and fermenting it aerobically to reduce the water content.

特開昭63-185881号公報Japanese Unexamined Patent Publication No. 63-185881 特開平09-074899号公報Japanese Unexamined Patent Publication No. 09-074899 特開平11-228257号公報Japanese Unexamined Patent Publication No. 11-228257 特開2005-111374号公報Japanese Unexamined Patent Publication No. 2005-11374

一般的に、好気性発酵を安定的に行うためには、通気量の他に、処理対象物に含まれる微生物の栄養減となる栄養素及び水の量、pHなどの各種条件の最適化が必要である。悪臭などの環境汚染防止の観点から密閉条件で好気発酵を行う場合、通気量が不足する傾向にあることに起因して、嫌気性発酵が進行して発酵系全体のpHが低くなり、有機物の分解速度が遅くなる。その結果、対象物の好気発酵処理が十分に行えないことがある。 In general, in order to stably perform aerobic fermentation, it is necessary to optimize various conditions such as the amount of nutrients and water that reduce the nutrition of microorganisms contained in the object to be treated, pH, etc., in addition to the aeration amount. Is. When aerobic fermentation is performed under closed conditions from the viewpoint of preventing environmental pollution such as foul odors, anaerobic fermentation progresses and the pH of the entire fermentation system becomes low due to the tendency for the aeration amount to be insufficient, resulting in organic matter. Decomposition speed slows down. As a result, the aerobic fermentation treatment of the object may not be sufficiently performed.

発酵が進行し低pHとなった発酵系全体のpHを中性又はアルカリ性側に調整して良好な発酵状態を維持することを目的として、例えば蓄分や有機性廃棄物などの原料に、アルカリ性になった堆肥等のアルカリ性物質を投入する方法がある。しかし、好気発酵処理の対象物として下水汚泥を使用する場合、下水汚泥の緩衝作用により発酵系全体のpHはあまり変化せず、pHを所望の範囲に調整することが困難となる場合がある。特に、密閉式縦型発酵槽などの大規模な連続式装置で下水汚泥を処理する場合には、原料投入口近傍での発酵状態と排出口近傍で発酵状態とが異なるため、発酵条件の調整が困難であった。 For the purpose of maintaining a good fermentation state by adjusting the pH of the entire fermentation system, which has become low pH due to the progress of fermentation, to the neutral or alkaline side, it is alkaline for raw materials such as stocks and organic waste. There is a method of adding alkaline substances such as fermented compost. However, when sewage sludge is used as an object of aerobic fermentation treatment, the pH of the entire fermentation system does not change much due to the buffering action of the sewage sludge, and it may be difficult to adjust the pH to a desired range. .. In particular, when treating sewage sludge with a large-scale continuous device such as a closed vertical fermenter, the fermentation state near the raw material input port differs from the fermentation state near the discharge port, so the fermentation conditions are adjusted. Was difficult.

上記のように、下水汚泥の好気発酵において、pH調整により発酵を促進させる場合には、好気発酵の促進効果を安定して得られる配合が求められていた。この点に関して、特許文献1~4に記載の技術では、好気発酵処理過程における発酵条件を適切に調整することや、密閉時あるいは圧縮時での発酵条件の最適化に関しては何ら検討されていない。 As described above, in the aerobic fermentation of sewage sludge, when the fermentation is promoted by adjusting the pH, a formulation that can stably obtain the promoting effect of the aerobic fermentation has been required. In this regard, in the techniques described in Patent Documents 1 to 4, no studies have been made on appropriately adjusting the fermentation conditions in the aerobic fermentation process and optimizing the fermentation conditions at the time of sealing or compression. ..

そこで本発明は、発酵状態に応じて配合を都度調整することなく、簡便かつ安定的に発酵促進できる下水汚泥発酵原料を提供することを目的とする。 Therefore, an object of the present invention is to provide a sewage sludge fermentation raw material that can easily and stably promote fermentation without adjusting the composition according to the fermentation state each time.

本発明者らは、上記の課題を解決すべく鋭意検討した結果、特定量の消石灰を下水汚泥へ添加することで、発酵対象物である下水汚泥の発酵が安定して促進されることを見出し、本発明を成すに至った。 As a result of diligent studies to solve the above problems, the present inventors have found that the fermentation of sewage sludge, which is a fermentation target, is stably promoted by adding a specific amount of sewage sludge to sewage sludge. , The present invention has been achieved.

すなわち、本発明は、下水汚泥と、消石灰とを含み、前記消石灰を、前記下水汚泥100質量部に対して1.5質量部以上2.5質量部以下含む、好気発酵処理用の下水汚泥発酵原料を提供するものである。 That is, the present invention contains sewage sludge and sewage sludge, and contains 1.5 parts by mass or more and 2.5 parts by mass or less of the sewage sludge with respect to 100 parts by mass of the sewage sludge. It provides a fermented raw material.

また本発明の好適な態様として、栄養助材をさらに含む、好気発酵処理用の下水汚泥発酵原料を提供するものである。 Further, as a preferred embodiment of the present invention, there is provided a sewage sludge fermentation raw material for aerobic fermentation treatment, which further contains a nutritional auxiliary material.

また本発明の好適な態様として、前記栄養助材を、前記下水汚泥100質量部に対して5質量部以上50質量部以下含む,好気発酵処理用の下水汚泥発酵原料を提供するものである。 Further, as a preferred embodiment of the present invention, there is provided a sewage sludge fermentation raw material for aerobic fermentation treatment, which comprises the nutritional auxiliary material in an amount of 5 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the sewage sludge. ..

また本発明の好適な態様として、通気助材をさらに含む、好気発酵処理用の下水汚泥発酵原料を提供するものである。 Further, as a preferred embodiment of the present invention, there is provided a sewage sludge fermentation raw material for aerobic fermentation treatment, which further comprises an aeration auxiliary material.

また本発明の好適な態様として、前記通気助材を、前記下水汚泥100質量部に対して5質量部以上50質量部以下含む、好気発酵処理用の下水汚泥発酵原料を提供するものである。 Further, as a preferred embodiment of the present invention, there is provided a sewage sludge fermentation raw material for aerobic fermentation treatment, which comprises 5 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the sewage sludge. ..

本発明によれば、下水汚泥に特定の材料を添加するという簡便な操作のみで、好気発酵を速やかに進行させることができ、下水汚泥を安定して発酵させることができる。これにより、セメント工場のような工業地域や住宅に隣接する地域でも、性状の異なる下水汚泥を大量に発酵処理することができ、資源の有効利用に繋げることができる。 According to the present invention, aerobic fermentation can be rapidly promoted and sewage sludge can be stably fermented only by a simple operation of adding a specific material to sewage sludge. As a result, even in industrial areas such as cement factories and areas adjacent to houses, sewage sludge with different properties can be fermented in large quantities, leading to effective use of resources.

図1は、密閉式縦型発酵槽の一実施形態を模式的に示す断面図である。FIG. 1 is a cross-sectional view schematically showing an embodiment of a closed vertical fermenter. 図2(a)は、実施例及び比較例における好気発酵評価に用いた発酵容器の外観及び寸法を示す斜視図であり、図2(b)は温度測定時における各部材の配置位置を示した断面図である。FIG. 2A is a perspective view showing the appearance and dimensions of the fermentation vessel used for the evaluation of aerobic fermentation in Examples and Comparative Examples, and FIG. 2B shows the arrangement position of each member at the time of temperature measurement. It is a cross-sectional view.

本発明の好適な実施形態を以下に説明する。なお、本発明は以下の実施形態に限定されるものではない。 Suitable embodiments of the present invention will be described below. The present invention is not limited to the following embodiments.

本発明の下水汚泥発酵原料は、その材料として、下水汚泥と、消石灰とを含む。この下水汚泥発酵原料は、下水汚泥の好気発酵処理に好適に用いられるものである。 The sewage sludge fermentation raw material of the present invention contains sewage sludge and slaked lime as the raw materials. This sewage sludge fermentation raw material is suitably used for aerobic fermentation treatment of sewage sludge.

本発明に用いられる下水汚泥は、排水処理又は下水処理の過程で生じる廃棄物であり、有機物、無機物及び水を含む泥状の物質である。このような下水汚泥としては、例えば一般下水汚泥、工業下水汚泥などが挙げられ、これらを単独で又は組み合わせて用いることができる。下水汚泥は、未消化汚泥としてそのまま用いてもよく、あるいは、脱水汚泥及び消化汚泥などの下水汚泥の自己発酵処理物を用いてもよい。 The sewage sludge used in the present invention is waste generated in the process of wastewater treatment or sewage treatment, and is a muddy substance containing organic matter, inorganic matter and water. Examples of such sewage sludge include general sewage sludge, industrial sewage sludge, and the like, and these can be used alone or in combination. The sewage sludge may be used as it is as undigested sludge, or a self-fermented product of sewage sludge such as dehydrated sludge and digested sludge may be used.

本発明の下水汚泥発酵原料は、消石灰(Ca(OH)、水酸化カルシウム)をさらに含む。本発明で用いられる消石灰は、後述する微視的な環境条件を適切に調整して、好気発酵をより促進させる観点から、消石灰の粒子径は好ましくは600μm以下、より好ましくは150μm以下の粉末状のものがより好適に使用できる。粉末状の消石灰の粒子径は1μm以上が現実的であり、好ましくは25μm以上である。消石灰は、例えば粉末状の固体を用いてもよく、溶液又は分散液として用いてもよい。本発明の効果が奏される限りにおいて、消石灰は、例えば園芸用消石灰や各種の工業用消石灰等の市販品を用いることができる。工業用消石灰を用いる場合、消石灰として例えばJIS R9001の規定に適合するものを用いることができる。消石灰の粒子径は、例えばJIS Z8801-1:2019に準拠したふるいを用いて消石灰粉末をふるい分けしたときに、消石灰粉末の95質量%以上が通過したふるいのうち最小の公称目開きとすることができる。 The sewage sludge fermentation raw material of the present invention further contains slaked lime (Ca (OH) 2 , calcium hydroxide). The slaked lime used in the present invention is a powder having a particle size of preferably 600 μm or less, more preferably 150 μm or less, from the viewpoint of appropriately adjusting the microscopic environmental conditions described later and further promoting aerobic fermentation. The shape can be used more preferably. The particle size of powdered slaked lime is realistically 1 μm or more, preferably 25 μm or more. As the slaked lime, for example, a powdery solid may be used, or a solution or a dispersion may be used. As long as the effect of the present invention is exhibited, commercially available products such as slaked lime for gardening and various industrial slaked lime can be used. When industrial slaked lime is used, for example, slaked lime conforming to JIS R9001 can be used. The particle size of slaked lime may be the smallest nominal opening of the sieves that 95% by mass or more of the slaked lime powder has passed through, for example, when the slaked lime powder is sieved using a sieve compliant with JIS Z8801-1: 2019. can.

本発明の下水汚泥発酵原料における消石灰の含有量は、下水汚泥100質量部に対して、好ましくは1質量部以上4質量部以下、更に好ましくは1.5質量部以上2.5質量部以下である。このとき、基準となる下水汚泥の質量は含水状態での質量とする。このような範囲にあることによって、下水汚泥の好気発酵を簡便に促進し、発酵の進行状態を高いレベルで安定化させることができる。この消石灰の含有量は、本技術分野で用いられる消石灰の典型的な含有量よりもはるかに低い値であるので、上述の含有量の範囲で消石灰を添加することに起因する下水汚泥発酵原料全体のpHへの影響はほぼ観察されない。 The content of sewage lime in the sewage sludge fermentation raw material of the present invention is preferably 1 part by mass or more and 4 parts by mass or less, and more preferably 1.5 parts by mass or more and 2.5 parts by mass or less with respect to 100 parts by mass of sewage sludge. be. At this time, the mass of the reference sewage sludge is the mass in the water-containing state. Within such a range, aerobic fermentation of sewage sludge can be easily promoted, and the progress of fermentation can be stabilized at a high level. Since the content of this slaked lime is much lower than the typical content of slaked lime used in the present technology, the whole sewage sludge fermentation raw material resulting from the addition of slaked lime within the above-mentioned content range. No effect on pH is observed.

本技術分野で用いられ得る消石灰は、典型的には、発酵対象物のpHをアルカリ性側に調整するためのpH調整剤としての機能を有する。しかし、下水汚泥あるいは下水汚泥を含む発酵原料に対するpH調整を目的として消石灰を含有させる場合、下水汚泥がpH緩衝作用を有しているので、好気発酵を効率よく進行させるために発酵系全体のpHを均一に調整しようとすると多量の消石灰が必要となり、その結果、処理コストが増大してしまう。
下水汚泥の好気発酵の促進に関して本発明者が鋭意検討したところ、発酵系全体のpH(マクロ的なpH)を均一に調整することを目的として消石灰の含有量を決定するのではなく、発酵系内の消石灰の存在領域での微視的な(ミクロ的な)環境条件を考慮して消石灰の含有量を決定することによって、意外にも、下水汚泥の好気発酵を簡便に且つ安定的に促進させることができ、また処理コストを顕著に低減できることを見出した。消石灰の含有量を本技術分野で用いられる典型的な含有量よりもはるかに低くした場合であっても下水汚泥の好気発酵を促進できることは、従来の技術では何ら検討されておらず、本発明者によって初めて見出されたものである。
The slaked lime that can be used in the present art typically has a function as a pH adjuster for adjusting the pH of the fermentation object to the alkaline side. However, when slaked lime is contained for the purpose of adjusting the pH of sewage sludge or fermented raw materials containing sewage sludge, the sewage sludge has a pH buffering action, and therefore, in order to efficiently proceed with aerobic fermentation, the entire fermentation system is used. Attempts to uniformly adjust the pH require a large amount of slaked lime, resulting in increased processing costs.
As a result of diligent studies by the present inventor regarding the promotion of aerobic fermentation of sewage sludge, the content of slaked lime is not determined for the purpose of uniformly adjusting the pH (macro pH) of the entire fermentation system, but fermentation. Surprisingly, aerobic fermentation of sewage sludge is easy and stable by determining the content of slaked lime in consideration of the microscopic (micro) environmental conditions in the region where slaked lime is present in the system. It was found that it can be promoted and the processing cost can be significantly reduced. The ability to promote aerobic fermentation of sewage sludge even when the sewage content is much lower than the typical content used in the art has not been investigated in any prior art. It was first discovered by the inventor.

本発明の下水汚泥発酵原料に消石灰を特定の添加量で含有させることによって、好気発酵が効率的に進行的に進行する理由を、本発明者は以下のように推測している。下水汚泥に消石灰を添加した場合、下水汚泥が有するpH緩衝作用により、系全体のpH上昇(マクロ的なpH上昇)はほぼ観察されないが、微視的環境である消石灰の存在領域(例えば消石灰粒子の表面及び近傍のミクロな領域)ではpHがアルカリ性側に調整されて、微生物による有機物の分解に適した値までpHが上昇し、好気発酵が効率よく進行していると考えられる。
消石灰の添加量が上述した範囲よりも少ない場合は、アルカリの供給が不足して、下水汚泥の微視的なpHを上昇させることが困難となる。また添加量が消石灰の添加量が上述した範囲よりも多い場合は、消石灰が占める部分が下水汚泥や微生物に比べて過剰となり、pHが過剰に高い領域を局所的に且つ複数形成してしまい、好気発酵が促進されにくくなる。したがって、消石灰の含有量を上述の範囲に制御することによって、下水汚泥発酵原料全体のpHはほぼ変化していないが、pHが有機物の分解に適する値となった微視的な領域が適切に下水汚泥発酵原料中に均一に分布しているので、下水汚泥の好気発酵を簡便に且つ効率良く進行させることができる。
The present inventor speculates the reason why aerobic fermentation proceeds efficiently and progressively by containing sewage sludge fermentation raw material of the present invention in a specific addition amount as follows. When slaked lime is added to sewage sludge, a pH increase in the entire system (macro pH increase) is hardly observed due to the pH buffering action of the sewage sludge, but the region where slaked lime exists (for example, slaked lime particles), which is a microscopic environment, is observed. It is considered that the pH is adjusted to the alkaline side on the surface and in the vicinity of the microscopic region, and the pH rises to a value suitable for the decomposition of organic substances by microorganisms, and aerobic fermentation is proceeding efficiently.
When the amount of slaked lime added is less than the above range, the supply of alkali is insufficient, and it becomes difficult to raise the microscopic pH of sewage sludge. When the amount of slaked lime added is larger than the above range, the portion occupied by slaked lime becomes excessive as compared with sewage sludge and microorganisms, and a plurality of regions having an excessively high pH are locally formed. Aerobic fermentation is less likely to be promoted. Therefore, by controlling the content of slaked lime to the above range, the pH of the whole sewage sludge fermentation raw material does not change, but the microscopic region where the pH becomes a value suitable for the decomposition of organic substances is appropriate. Since it is uniformly distributed in the sewage sludge fermentation raw material, aerobic fermentation of sewage sludge can be easily and efficiently proceeded.

本発明の下水汚泥発酵原料は、下水汚泥及び消石灰のみから構成されていてもよく、これに加えて、本発明の効果を阻害しない範囲で、下水汚泥、消石灰以外の他の資材(以下、これを単に「資材」ともいう。)を更に含むことも好ましい。資材としては、例えば、下水汚泥発酵原料を発酵に供する際に安定的な好気発酵を促すための材料が挙げられ、具体的には、下水汚泥の含水率を低減させたり、下水汚泥発酵原料の発酵時における通気性を向上させたり、好気発酵に寄与する微生物の栄養源となる易分解性有機分を供給したりする等を目的とした材料が挙げられる。 The raw material for fermenting sewage sludge of the present invention may be composed only of sewage sludge and sewage lime, and in addition to this, materials other than sewage sludge and sewage lime (hereinafter, this) as long as the effects of the present invention are not impaired. Is also simply referred to as “material”). Examples of the material include a material for promoting stable aerobic fermentation when the sewage sludge fermentation raw material is subjected to fermentation, and specifically, a material for reducing the water content of the sewage sludge or a sewage sludge fermentation raw material. Examples of the material are intended to improve the air permeability during fermentation of sewage, and to supply easily decomposable organic components that are nutrient sources for microorganisms that contribute to aerobic fermentation.

好気発酵に寄与する微生物の栄養源を下水汚泥発酵原料に供給するための材料として、栄養助材を更に含むことが好ましい。このような栄養助材の具体例としては、食品汚泥、廃白土、肉骨粉、製紙スラッジ、廃食油、生ごみ、し尿、家禽や家畜などの糞、堆肥等が挙げられる。これらは単独で又は組み合わせて用いることができる。また堆肥としては、市販品を用いてもよく、汚泥発酵物(本発明の下水汚泥発酵原料を好気発酵処理して生成された発酵物)を用いてもよい。
これらのうち、栄養助材として肉骨粉を用いることが、下水汚泥と混合した際の栄養成分(油脂、たんぱく質、窒素等の成分)を好気性微生物の活動に最適な条件となるように簡便に調整しやすくして、下水汚泥の好気発酵を更に促進できる点で好ましい。また、栄養助材として堆肥を用いることが、堆肥中に存在する多様な好気性微生物を下水汚泥発酵原料中に十分に供給して、下水汚泥の好気発酵を更に促進できる点で好ましい。特に、好気発酵の進行を栄養面及び好気性微生物の多様性の面の双方から最適な範囲に簡便に調整しやすくして、下水汚泥の好気発酵をより一層促進させる観点から、栄養助材として肉骨粉及び堆肥を組み合わせて用いることが一層好ましい。
It is preferable to further include a nutritional auxiliary material as a material for supplying the nutrient source of microorganisms contributing to aerobic fermentation to the sewage sludge fermentation raw material. Specific examples of such nutritional aids include food sludge, waste white soil, meat-and-bone meal, paper sludge, waste cooking oil, swill, human waste, feces of poultry and livestock, compost and the like. These can be used alone or in combination. Further, as the compost, a commercially available product may be used, or a sludge fermented product (a fermented product produced by aerobic fermentation treatment of the sewage sludge fermentation raw material of the present invention) may be used.
Of these, using meat-and-bone meal as a nutritional aid is convenient so that the nutritional components (components such as fats and oils, proteins, nitrogen, etc.) when mixed with sewage sludge become the optimum conditions for the activity of aerobic microorganisms. It is preferable in that it can be easily adjusted and aerobic fermentation of sewage sludge can be further promoted. Further, it is preferable to use compost as a nutritional auxiliary material in that various aerobic microorganisms present in the compost can be sufficiently supplied into the sewage sludge fermentation raw material to further promote the aerobic fermentation of the sewage sludge. In particular, nutritional assistance is made from the viewpoint of facilitating the progress of aerobic fermentation to be easily adjusted to the optimum range from both the nutritional aspect and the diversity of aerobic microorganisms, and further promoting the aerobic fermentation of sewage sludge. It is more preferable to use meat-and-bone meal and compost in combination as the material.

下水汚泥発酵原料に栄養助材を更に含む場合、下水汚泥発酵原料における栄養助材の含有量は、下水汚泥100質量部に対して、好ましくは5質量部以上50質量部以下、より好ましくは10質量部以上35質量部以下、更に好ましくは15質量部以上25質量部以下である。このとき、基準となる下水汚泥及び栄養助材の質量はいずれも含水状態での質量とする。また栄養助材を複数種含む場合、栄養助材の含有量はその総量に基づく。このような範囲にあることによって、好気性微生物の活動に必要な栄養成分のバランスを簡便に調整しやすくできるので、下水汚泥の好気発酵を更に促進して、発酵の進行状態を高いレベルで安定化させることができる。 When the sewage sludge fermentation raw material further contains a nutritional auxiliary material, the content of the nutritional auxiliary material in the sewage sludge fermentation raw material is preferably 5 parts by mass or more and 50 parts by mass or less, more preferably 10 parts by mass with respect to 100 parts by mass of sewage sludge. It is 5 parts by mass or more and 35 parts by mass or less, more preferably 15 parts by mass or more and 25 parts by mass or less. At this time, the mass of the reference sewage sludge and the nutrient aid material shall be the mass in the water-containing state. When multiple kinds of nutritional aids are included, the content of the nutritional aids is based on the total amount. By being in such a range, it is possible to easily adjust the balance of nutritional components necessary for the activity of aerobic microorganisms, which further promotes aerobic fermentation of sewage sludge and keeps the progress of fermentation at a high level. Can be stabilized.

下水汚泥発酵原料に栄養助材を更に含む場合、栄養助材の固形分発熱量が3000kcal/kg以上であるものを用いることが好ましく、3300kcal/kg以上であるものを用いることが更に好ましい。3500kcal/kg以上であるものを用いることが更に好ましい。この固形分発熱量は、栄養助材一種あたりの発熱量である。一般的に、固形分発熱量が高いことは、好気発酵の進行に有用な栄養成分の一つである有機分が多く含まれていることを意味するので、このような発熱量を有する栄養助材を用いることによって、好気発酵を更に促進させることができ、下水汚泥の発酵処理を効率よく行うことができる。このような発熱量を有する栄養助材としては、例えば肉骨粉、家禽や家畜などの糞、堆肥等が挙げられる。 When the nutrient aid is further contained in the sewage sludge fermentation raw material, it is preferable to use a nutrient auxiliary material having a solid content calorific value of 3000 kcal / kg or more, and further preferably to use one having a solid content calorific value of 3300 kcal / kg or more. It is more preferable to use one having a temperature of 3500 kcal / kg or more. This calorific value of solid content is the calorific value per type of nutritional aid. In general, a high solid content calorific value means that a large amount of organic content, which is one of the nutritional components useful for the progress of aerobic fermentation, is contained. By using the auxiliary material, aerobic fermentation can be further promoted, and the fermentation treatment of sewage sludge can be efficiently performed. Examples of the nutritional aid having such a calorific value include meat-and-bone meal, feces of poultry and livestock, compost and the like.

下水汚泥発酵原料の通気性を向上させて下水汚泥の好気発酵を促すための材料として、通気助材を更に含むことが好ましい。本明細書における通気助材は、上述した消石灰は除外される。通気助材を含むことによって、下水汚泥発酵原料の圧縮の状態に依存せず、下水汚泥発酵原料の通気性を簡便に改善することができ、下水汚泥の好気発酵を安定的に行うことができる。特に、例えば後述する縦型発酵槽を用いて好気発酵する場合、下水汚泥発酵原料の堆積に起因して発酵槽内の下水汚泥が圧縮され、下水汚泥の好気発酵が進行しづらくなるところ、通気助材を含むことによって、過度の圧縮状態となることを更に抑制しつつ通気性を更に確保することができ、下水汚泥の好気発酵を安定的かつ効果的に進行させることができる点で有利である。 It is preferable to further include a ventilation auxiliary material as a material for improving the air permeability of the sewage sludge fermentation raw material and promoting the aerobic fermentation of the sewage sludge. The above-mentioned slaked lime is excluded from the ventilation aids in the present specification. By including the aeration auxiliary material, the air permeability of the sewage sludge fermentation raw material can be easily improved without depending on the compressed state of the sewage sludge fermentation raw material, and the aerobic fermentation of the sewage sludge can be stably performed. can. In particular, in the case of aerobic fermentation using, for example, a vertical fermenter, which will be described later, the sewage sludge in the fermenter is compressed due to the accumulation of the sewage sludge fermentation raw material, and the aerobic fermentation of the sewage sludge becomes difficult to proceed. By including the aeration auxiliary material, it is possible to further secure the aeration while further suppressing the excessive compression state, and it is possible to stably and effectively promote the aerobic fermentation of sewage sludge. Is advantageous.

通気助材としては、例えば、稲わら、もみがら、草木又はこれらの乾燥物若しくは破砕物などの有機系通気助材や、パーライト、ゼオライト、珪藻土、若しくはフライアッシュ等の石炭灰などの無機系通気助材等が挙げられ、これらは単独で又は組み合わせて用いることができる。これらのうち、石炭灰を用いることによって、比較的微細な粒子であり且つCaOやMgO等の酸化物成分を含むことに起因して、下水汚泥発酵原料中の分散性が高く、フロックの形成を均一に行うことができるので、好気発酵時における通気性を更に高められる点で好ましい。 Aeration aids include, for example, organic aeration aids such as rice straw, fir tree, vegetation or dried or crushed products thereof, and inorganic aeration such as pearlite, zeolite, diatomaceous earth, or coal ash such as fly ash. Auxiliary materials and the like can be mentioned, and these can be used alone or in combination. Of these, by using coal ash, it is relatively fine particles and contains oxide components such as CaO and MgO, so that it has high dispersibility in the sewage sludge fermentation raw material and forms flocs. Since it can be performed uniformly, it is preferable in that the air permeability during aerobic fermentation can be further enhanced.

下水汚泥発酵原料に通気助材を更に含む場合、下水汚泥発酵原料における通気助材の含有量は、下水汚泥100質量部に対して、好ましくは5質量部以上50質量部以下、より好ましくは5質量部以上30質量部以下、更に好ましくは5質量部以上15質量部以下である。このとき、基準となる下水汚泥及び通気助材の質量はいずれも含水状態での質量とする。通気助材を複数種含む場合、通気助材の含有量は総量に基づく。
このような範囲にあることによって、発酵開始から終了までの長い期間にわたって、下水汚泥発酵原料が過度の圧縮状態となることを抑制しつつ通気性を均一に確保することができ、下水汚泥の好気発酵を安定的かつ効果的に進行させることができる。特に、石炭灰は下水汚泥と同様に廃棄物として扱われるところ、石炭灰を下水汚泥とともに再利用することによって、資源の有効利用及び環境保護に寄与するという利点も奏される。
When the sewage sludge fermentation raw material further contains a ventilation auxiliary material, the content of the ventilation auxiliary material in the sewage sludge fermentation raw material is preferably 5 parts by mass or more and 50 parts by mass or less, more preferably 5 with respect to 100 parts by mass of sewage sludge. It is 5 parts by mass or more and 30 parts by mass or less, more preferably 5 parts by mass or more and 15 parts by mass or less. At this time, the mass of the reference sewage sludge and the ventilation auxiliary material shall be the mass in the water-containing state. When multiple types of ventilation aids are included, the content of the ventilation aids is based on the total amount.
By being in such a range, it is possible to ensure uniform air permeability while suppressing excessive compression of the sewage sludge fermentation raw material for a long period from the start to the end of fermentation, which is favorable for sewage sludge. The air fermentation can proceed stably and effectively. In particular, coal ash is treated as waste in the same way as sewage sludge, and by reusing coal ash together with sewage sludge, there is an advantage that it contributes to effective use of resources and environmental protection.

通気助材として石炭灰を用いる場合、石炭灰の嵩密度が好ましくは0.2g/cm以上1.5g/cm以下であり、且つブレーン比表面積が好ましくは1000cm/g以上20000cm/g以下である。かさ密度は、例えばJIS R1628に従って測定することができる。またブレーン比表面積は、例えばJIS R5201に従って測定することができる。 When coal ash is used as a ventilation aid, the bulk density of the coal ash is preferably 0.2 g / cm 3 or more and 1.5 g / cm 3 or less, and the brain specific surface area is preferably 1000 cm 2 / g or more and 20000 cm 2 /. It is less than or equal to g. Bulk density can be measured, for example, according to JIS R1628. The specific surface area of the brain can be measured according to, for example, JIS R5201.

上述した栄養助材及び通気助材等の各種資材の形状は特に制限はなく、例えば、固形状、顆粒状、粉末状、ペースト状、流動状、液状等の形状としてもよい。資材の合計総含有量は、用いられる材料の物性や目的に応じて適宜調整できるが、下水汚泥100質量部対する下水汚泥100質量部に対する資材の総質量部は、好ましくは1質量部以上180質量部以下、更に好ましくは5質量部以上100質量部以下とすることができる。このとき、基準となる下水汚泥の質量は、含水状態での質量とする。 The shapes of various materials such as the above-mentioned nutritional aids and ventilation aids are not particularly limited, and may be, for example, solid, granular, powdery, paste, fluid, liquid or the like. The total total content of the material can be appropriately adjusted according to the physical properties and purpose of the material used, but the total mass part of the material with respect to 100 parts by mass of sewage sludge is preferably 1 part by mass or more and 180 parts by mass with respect to 100 parts by mass of sewage sludge. It can be less than or equal to 5 parts by mass, more preferably 5 parts by mass or more and 100 parts by mass or less. At this time, the mass of the reference sewage sludge is the mass in the water-containing state.

発酵初期の時点から好気発酵を安定的に進行させるために十分な水分量を確保する観点から、下水汚泥発酵原料全体の含水率は、30質量%以上70質量%以下であることが好ましく、40質量%以上60質量%以下であることがより好ましい。含水率は、例えば市販のハロゲン水分計を用いて、120℃の加熱温度で乾燥したときの乾燥前後の質量の差に基づいて測定することができる。またこれに代えて、JIS A 1203「土の含水比試験方法」に準じて測定することができる。下水汚泥発酵原料の含水率は、例えば、所望の含水率となるように原材料を選択したり、原材料又は下水汚泥発酵原料に対して、水を添加したりすることによって適宜調整することができる。 From the viewpoint of ensuring sufficient water content for stable progress of aerobic fermentation from the initial stage of fermentation, the water content of the entire sewage sludge fermentation raw material is preferably 30% by mass or more and 70% by mass or less. It is more preferably 40% by mass or more and 60% by mass or less. The water content can be measured, for example, using a commercially available halogen moisture meter based on the difference in mass before and after drying when dried at a heating temperature of 120 ° C. Alternatively, the measurement can be performed according to JIS A 1203 “Soil water content ratio test method”. The water content of the sewage sludge fermentation raw material can be appropriately adjusted, for example, by selecting a raw material so as to have a desired water content, or by adding water to the raw material or the sewage sludge fermentation raw material.

このような材料を含む下水汚泥発酵原料は、例えば下水汚泥及び消石灰と、必要に応じて各種資材とを混合するか又は堆積させて、混合物又は堆積物として製造することができる。詳細には、下水汚泥および消石灰と、必要に応じて各種資材とを混合して下水汚泥発酵原料を得る方法、又は、屋内若しくは屋外で、各材料を任意の順序で堆積させた堆積物として下水汚泥発酵原料を得る方法等が挙げられる。あるいは、材料のうちいずれかを発酵槽等の容器に供給し、次いで他の原料を任意の順序で該容器内に供給して、該容器内で各原料を交互に若しくはランダムに堆積させた堆積物とし、これをそのままで、又はこれに加えて、該堆積物を発酵槽等の容器内で混合した混合物として、下水汚泥発酵原料を得る方法が挙げられる。 The sewage sludge fermentation raw material containing such a material can be produced as a mixture or a deposit by mixing or depositing, for example, sewage sludge and sewage lime and various materials as needed. Specifically, a method of mixing sewage sludge and sewage lime with various materials as needed to obtain a sewage sludge fermentation raw material, or sewage as a deposit in which each material is deposited indoors or outdoors in any order. Examples thereof include a method of obtaining a sludge fermentation raw material. Alternatively, one of the materials is supplied to a container such as a fermenter, and then the other raw materials are supplied into the container in an arbitrary order, and the respective raw materials are alternately or randomly deposited in the container. Examples thereof include a method of obtaining a sewage sludge fermentation raw material as a product as it is, or as a mixture in which the deposit is mixed in a container such as a fermenter.

上述の下水汚泥発酵原料は、堆積物及び混合物のいずれの形態であっても、下水汚泥の好気発酵処理の用途に適したものとなる。下水汚泥発酵原料は、これをそのまま屋外又は屋内に配するか、あるいはこれを堆積物又は混合物として容器内に収容して、下水汚泥の好気発酵処理を行うことができる。
詳細には、下水汚泥発酵原料は、これを堆肥舎内に堆積させたり、これを開放系又は密閉系の発酵槽に収容したりして、下水汚泥を好気発酵させることができる。下水汚泥発酵原料を発酵槽に供給して好気発酵処理に供する場合、発酵槽内の撹拌設備の有無あるいは撹拌方法は問わず、発酵初期から長期間にわたり安定的に好気発酵を行い、下水汚泥を効率良く処理することができる。悪臭などの周囲環境への悪影響を低減する観点から、下水汚泥発酵原料中の下水汚泥を好気発酵処理させる場合、密閉系の発酵槽内で好気発酵させることが好ましい。密閉系とは、好気発酵時において固体及び液体の進入が防止され、且つ空気等の気体の進入が妨げられない反応系を指し、開放系とは、好気発酵時において固体、液体及び気体の進入が妨げられない反応系を指す。
The above-mentioned sewage sludge fermentation raw material, in either form of sediment or mixture, is suitable for aerobic fermentation treatment of sewage sludge. The sewage sludge fermentation raw material can be arranged outdoors or indoors as it is, or it can be contained in a container as a deposit or a mixture to perform an aerobic fermentation treatment of sewage sludge.
Specifically, the sewage sludge fermentation raw material can be deposited in a compost house or housed in an open or closed fermenter to ferment the sewage sludge aerobically. When the raw material for sewage sludge fermentation is supplied to the fermenter and used for aerobic fermentation treatment, stable aerobic fermentation is performed for a long period of time from the initial stage of fermentation regardless of the presence or absence of a stirring facility in the fermenter or the stirring method. Sludge can be treated efficiently. From the viewpoint of reducing adverse effects on the surrounding environment such as foul odors, when the sewage sludge in the sewage sludge fermentation raw material is subjected to aerobic fermentation treatment, it is preferable to perform aerobic fermentation in a closed fermenter. The closed system refers to a reaction system in which the ingress of solids and liquids is prevented during aerobic fermentation and the ingress of gases such as air is not hindered, and the open system refers to solids, liquids and gases during aerobic fermentation. Refers to a reaction system in which the entry of the gas is not hindered.

特に、本発明の下水汚泥発酵原料は、密閉可能且つ縦型の発酵槽(以下、これを「密閉式縦型発酵槽」ともいう。)を用いて、密閉状態で好気発酵させて下水汚泥を発酵処理する場合に、成分の配合やpH等の環境条件を発酵状態に応じて都度変更しなくとも、下水汚泥の好気発酵を長期間にわたり安定的に進行させることができるので好適である。つまり、下水汚泥を発酵処理する方法として、下水汚泥及び消石灰と、必要に応じて資材とを任意の順序で密閉式縦型発酵槽内に供給するか、あるいはこれらの原料を含む混合物を密閉式縦型発酵槽内に供給して、好気発酵させる工程を有することが好ましく、当該工程は密閉系で行われることが更に好ましい。密閉式縦型発酵槽は、該発酵槽内を撹拌する撹拌設備を備えて、発酵槽内に供給された各原料を連続的に又は断続的に撹拌してもよい。 In particular, the sewage sludge fermentation raw material of the present invention is aerobically fermented in a closed state using a hermetically sealed and vertical fermenter (hereinafter, also referred to as a "sealed vertical fermenter") to sewage sludge. In the case of fermenting the sewage sludge, it is preferable because the aerobic fermentation of sewage sludge can proceed stably for a long period of time without changing the environmental conditions such as the composition of the components and the pH each time according to the fermentation state. .. That is, as a method for fermenting sewage sludge, sewage sludge and slaked lime and, if necessary, materials are supplied into a closed vertical fermenter in an arbitrary order, or a mixture containing these raw materials is sealed. It is preferable to have a step of supplying into a vertical fermenter for aerobic fermentation, and it is more preferable that the step is performed in a closed system. The closed vertical fermenter may be provided with a stirring device for stirring the inside of the fermenter, and each raw material supplied into the fermenter may be continuously or intermittently stirred.

密閉式縦型発酵槽を用いて密閉状態で好気発酵させる場合、下水汚泥発酵原料の堆積に起因して発酵槽内の下水汚泥発酵原料が圧縮され、下水汚泥の好気発酵が進行しづらくなるところ、好ましくは石炭灰等の通気助材を含むことによって、発酵槽内の下水汚泥発酵原料が過度の圧縮状態となることを抑制しつつ通気性を確保することができ、非圧縮状態と圧縮状態とのいずれであっても、下水汚泥の好気発酵を安定的かつ効果的に進行させることができる点で有利である。 When aerobic fermentation is performed in a closed state using a closed vertical fermenter, the sewage sludge fermentation raw material in the fermenter is compressed due to the accumulation of the sewage sludge fermentation raw material, and it is difficult for the sewage sludge to proceed with aerobic fermentation. By the way, preferably, by including an aeration auxiliary material such as coal ash, it is possible to secure the air permeability while suppressing the sewage sludge fermentation raw material in the fermenter from becoming an excessively compressed state, and the uncompressed state. Regardless of the compressed state, it is advantageous in that aerobic fermentation of sewage sludge can proceed stably and effectively.

図1には、本発明の下水汚泥発酵原料を発酵処理に好適に用いられる密閉式縦型発酵槽の一実施形態が示されている。密閉式縦型発酵槽10は、設置面に対して鉛直方向に延びており、下水汚泥および消石灰と、必要に応じて資材の混合物を収容可能な筒状の槽部20を有し、その上部に、該混合物を槽部20に投入可能な投入口30と、該槽部20の下部に、好気発酵処理された下水汚泥発酵原料を槽部20外へ排出可能な排出口40とを備えている。投入口30及び排出口40はともに開閉可能又は脱着可能な蓋状部材(図示せず)が設けられ、該蓋状部材を投入口30及び排出口40に装着することによって、発酵槽10における槽部20を密閉可能に構成されている。つまり、密閉式縦型発酵槽10は密閉系で下水汚泥の好気発酵を行って、下水汚泥を処理することができるものである。 FIG. 1 shows an embodiment of a closed vertical fermenter in which the sewage sludge fermentation raw material of the present invention is suitably used for fermentation treatment. The closed vertical fermenter 10 extends vertically with respect to the installation surface and has a tubular tank portion 20 capable of accommodating sewage sludge and sewage lime and, if necessary, a mixture of materials, and an upper portion thereof. In addition, a charging port 30 capable of charging the mixture into the tank section 20 and a discharging port 40 capable of discharging the aerobic fermentation-treated sewage sludge fermentation raw material to the outside of the tank section 20 are provided at the lower portion of the tank section 20. ing. Both the charging port 30 and the discharging port 40 are provided with a lid-shaped member (not shown) that can be opened and closed or detached, and by attaching the lid-shaped member to the charging port 30 and the discharging port 40, the tank in the fermentation tank 10 The portion 20 is configured to be hermetically sealed. That is, the closed vertical fermenter 10 can perform aerobic fermentation of sewage sludge in a closed system to treat the sewage sludge.

好気発酵効率をより向上させる観点から、密閉式縦型発酵槽10は、例えば槽部20の外周面に断熱材を配する等の方法によって、断熱構造を有していることが好ましい。また、密閉式縦型発酵槽10は、発酵槽内の原材料を混合して、成分の存在状態や通気性を均一にするための攪拌設備50を備えていることも好ましい。
図1に示す攪拌設備50は、例えば槽部20内に設けられた攪拌翼51と、該攪拌翼51に接続された攪拌軸52と、槽部20外に設けられたモータ(図示せず)とを備えている。攪拌翼51は、攪拌軸52を介して槽部20外に設けられたモータに接続されており、モータを駆動源として一定方向に回転するようになっている。攪拌設備50を更に備えることによって、下水汚泥発酵原料の好気発酵効率を一層向上させることができる。
From the viewpoint of further improving the aerobic fermentation efficiency, it is preferable that the closed vertical fermentation tank 10 has a heat insulating structure by, for example, arranging a heat insulating material on the outer peripheral surface of the tank portion 20. Further, it is also preferable that the closed vertical fermenter 10 is provided with a stirring device 50 for mixing the raw materials in the fermenter to make the presence state of the components and the air permeability uniform.
The stirring equipment 50 shown in FIG. 1 includes, for example, a stirring blade 51 provided inside the tank portion 20, a stirring shaft 52 connected to the stirring blade 51, and a motor provided outside the tank portion 20 (not shown). And have. The stirring blade 51 is connected to a motor provided outside the tank portion 20 via a stirring shaft 52, and rotates in a fixed direction using the motor as a drive source. By further providing the stirring equipment 50, the aerobic fermentation efficiency of the sewage sludge fermentation raw material can be further improved.

また、密閉式縦型発酵槽10は、空気や酸素などの酸素含有気体を発酵槽内に供給するための空気流通設備60と、槽部20内の気体を槽部20外へ排気可能な排気口70とを備えていることも好ましい。
図1に示す形態では、酸素含有気体Fは、槽部20外に設けられた空気流通設備60から、好ましくは中空の攪拌軸52及び攪拌翼51の各内部を介して、攪拌翼51の鉛直方向下方側に供給できるようになっている。攪拌翼51の鉛直方向下方側には、酸素含有気体Fを流通可能な気体流通孔(図示せず)を複数備えていることも好ましい。槽部20内に存在する酸素含有気体及び好気発酵によって生じたガスは、排気口70を介して、排気空気として槽部20の上部から排気される。
Further, the closed vertical fermenter 10 has an air flow facility 60 for supplying oxygen-containing gas such as air and oxygen into the fermenter, and an exhaust gas capable of exhausting the gas in the tank 20 to the outside of the tank 20. It is also preferable to have a mouth 70.
In the embodiment shown in FIG. 1, the oxygen-containing gas F is vertically connected to the stirring blade 51 from the air flow facility 60 provided outside the tank portion 20, preferably via the inside of the hollow stirring shaft 52 and the stirring blade 51. It can be supplied to the lower side in the direction. It is also preferable that the stirring blade 51 is provided with a plurality of gas flow holes (not shown) capable of flowing the oxygen-containing gas F on the lower side in the vertical direction. The oxygen-containing gas existing in the tank portion 20 and the gas generated by aerobic fermentation are exhausted from the upper part of the tank portion 20 as exhaust air through the exhaust port 70.

酸素含有気体の供給効率を高めて、下水汚泥の好気発酵効率を高める観点から、酸素含有気体Fは槽部20の鉛直方向下方側から供給され、且つ、酸素含有気体F及びガスは、槽部20の鉛直方向上方側から排気されることが好ましい。下水汚泥発酵原料は、投入口から連続的又は断続的に発酵槽における槽部20内に投入し、下水汚泥発酵原料を発酵槽内で2週間程度好気発酵させ、その後、発酵した下水汚泥発酵原料を汚泥発酵物として排出口から排出する。 From the viewpoint of increasing the supply efficiency of the oxygen-containing gas and increasing the aerobic fermentation efficiency of the sewage sludge, the oxygen-containing gas F is supplied from the lower side in the vertical direction of the tank portion 20, and the oxygen-containing gas F and the gas are in the tank. It is preferable that the gas is exhausted from the upper side of the portion 20 in the vertical direction. The sewage sludge fermentation raw material is continuously or intermittently put into the tank section 20 in the fermenter from the inlet, and the sewage sludge fermentation raw material is aerobically fermented in the fermenter for about 2 weeks, and then fermented sewage sludge fermentation. The raw material is discharged from the discharge port as a fermented sludge.

下水汚泥発酵原料を好気発酵に供することで生成される汚泥発酵物は、例えば肥料、土壌改良材、園芸用土壌等の緑農地材料、セメントクリンカ原料、固形燃料等の用途に用いることができ、資源の有効利用が可能となる。特に、汚泥発酵物は、これを石灰石などの原料と混合してセメントクリンカ原料として使用することが、生成された汚泥発酵物の使用量を増加させて資源の有効利用に一層寄与できる点から好ましい。また、この汚泥発酵物は、下水汚泥発酵原料の調製にあたって、本発明の栄養助材として再利用することも可能であり、この点でも資源の有効利用に寄与する。 The sludge fermented product produced by subjecting the sewage sludge fermentation raw material to aerobic fermentation can be used for, for example, fertilizer, soil conditioner, green farmland material such as horticultural soil, cement clinka raw material, solid fuel and the like. , Effective use of resources becomes possible. In particular, it is preferable to mix the fermented sludge with a raw material such as limestone and use it as a raw material for cement clinker because the amount of the fermented sludge produced can be increased and the effective use of resources can be further contributed. .. Further, this sludge fermented product can be reused as a nutritional auxiliary material of the present invention in the preparation of a sewage sludge fermentation raw material, which also contributes to the effective utilization of resources.

上述の説明から明らかなとおり、本明細書は、下水汚泥発酵原料だけでなく、下水汚泥発酵原料の製造方法、並びに下水汚泥発酵原料を用いた下水汚泥の処理方法も開示する。 As is clear from the above description, the present specification discloses not only a sewage sludge fermentation raw material, but also a method for producing a sewage sludge fermentation raw material, and a method for treating sewage sludge using the sewage sludge fermentation raw material.

以下、実施例により本発明を更に詳細に説明する。本発明の範囲は、かかる実施例に制限されない。以下に示す原料における含水率の測定は、ハロゲン水分計(アズワン株式会社製HM1105)を用いて120℃の加熱温度で乾燥したときの質量差から算出した。また、以下に示す発熱量は、固形分発熱量を示す。 Hereinafter, the present invention will be described in more detail by way of examples. The scope of the invention is not limited to such examples. The measurement of the water content in the raw materials shown below was calculated from the mass difference when dried at a heating temperature of 120 ° C. using a halogen moisture meter (HM1105 manufactured by AS ONE Corporation). The calorific value shown below indicates the calorific value of solid content.

〔実施例1および比較例1~3〕
[下水汚泥発酵原料の調製]
以下に示す下水汚泥及び消石灰と、資材としての栄養助材(肉骨粉及び堆肥)、並びに通気助材(石炭灰)とを以下の表1に示す含有割合でそれぞれ混合して、含水量が62.8質量%~65.2質量%の下水汚泥発酵原料を調製した。
(1)下水汚泥:下水処理場から入手した未消化汚泥(含水率80.35質量%)
(2)消石灰:園芸用消石灰市販品
(3)肉骨粉:肥料用肉骨粉(含水率0.7質量%、発熱量3600kcal/kg)
(4)堆肥:農業用堆肥市販品(含水率28質量%)
(5)石炭灰:石炭火力自家発電所より採取した石炭灰(宇部興産株式会社製、含水率16.18質量%)
[Example 1 and Comparative Examples 1 to 3]
[Preparation of raw materials for sewage sludge fermentation]
The following sewage sludge and sewage lime, nutritional aids (meat-and-bone meal and compost) as materials, and aeration aids (coal ash) are mixed at the content ratios shown in Table 1 below, and the water content is 62. A raw material for fermenting sewage sludge of 0.8% by mass to 65.2% by mass was prepared.
(1) Sewage sludge: Undigested sludge obtained from a sewage treatment plant (moisture content 80.35% by mass)
(2) Smelting lime: Commercially available shaving lime for horticulture (3) Meat-and-bone meal: Meat-and-bone meal for fertilizer (moisture content 0.7% by mass, calorific value 3600 kcal / kg)
(4) Compost: Commercially available agricultural compost (moisture content 28% by mass)
(5) Coal ash: Coal ash collected from a coal-fired private power plant (manufactured by Ube Industries, Ltd., moisture content 16.18% by mass)

[好気発酵試験]
実施例及び比較例の下水汚泥発酵原料を好気発酵処理に供して、下水汚泥の好気発酵の進行度合を試料の温度変化として評価した。発酵容器として500mL容量のポリビーカーと、該ビーカーの側面および底面を覆う簡易断熱容器を用いた。これらの配置位置及び寸法は、図2(a)に示すとおりとした。実施例1並びに比較例1~3の下水汚泥発酵原料を、ポリビーカーへ約400mLずつ収容し、試料を調製した。
[Aerobic fermentation test]
The sewage sludge fermentation raw materials of Examples and Comparative Examples were subjected to aerobic fermentation treatment, and the progress of aerobic fermentation of sewage sludge was evaluated as a temperature change of a sample. As a fermentation container, a polybeaker having a capacity of 500 mL and a simple heat insulating container covering the sides and bottom of the beaker were used. These arrangement positions and dimensions are as shown in FIG. 2 (a). About 400 mL each of the sewage sludge fermentation raw materials of Example 1 and Comparative Examples 1 to 3 was placed in a polybeaker to prepare a sample.

次いで、各試料を収容したポリビーカーを図2(b)に示すように断熱容器に設置し、ポリビーカー内の試料中心部にT型熱電対(株式会社チノー製)を挿入した。熱電対にデータロガーを接続し、試料の温度を連続的に計測可能な状態で好気発酵に供した。これらの実験は20℃に設定した室内で行った。好気発酵の進行度合は、測定された最高温度をピーク温度とし、ピーク温度と、ピーク温度に至るまでに要した日数にて評価した。ピーク温度が高く且つピーク温度に至るまでに要した日数が短いほど、下水汚泥の好気発酵が速やかに効率的に進行していることを意味する。結果を表1に示す。 Next, a polybeaker containing each sample was placed in a heat insulating container as shown in FIG. 2B, and a T-type thermocouple (manufactured by Chino Corporation) was inserted into the center of the sample in the polybeaker. A data logger was connected to the thermocouple and the sample was subjected to aerobic fermentation in a state where the temperature of the sample could be continuously measured. These experiments were performed in a room set at 20 ° C. The degree of progress of aerobic fermentation was evaluated by the peak temperature and the number of days required to reach the peak temperature, with the measured maximum temperature as the peak temperature. The higher the peak temperature and the shorter the number of days required to reach the peak temperature, the faster and more efficient the aerobic fermentation of sewage sludge is. The results are shown in Table 1.

Figure 2022023698000002
Figure 2022023698000002

表1に示すように、下水汚泥および消石灰を含み、かつ消石灰含有量を所定の範囲として実施例1の下水汚泥発酵原料は、比較例と比較して、ピーク温度が高く、且つピーク温度の到達所要日数が短いことが判る。したがって,実施例の下水汚泥発酵原料は、発酵状態に応じて配合を都度調整することなく、簡便な操作で、安定的に下水汚泥の好気発酵を早期にかつ効率よく進行させることができる。
As shown in Table 1, the sewage sludge fermentation raw material of Example 1 containing sewage sludge and slaked lime and having the slaked lime content within a predetermined range has a higher peak temperature and reaches the peak temperature as compared with the comparative example. It can be seen that the required number of days is short. Therefore, the sewage sludge fermentation raw material of the example can stably and efficiently proceed with aerobic fermentation of sewage sludge by a simple operation without adjusting the composition each time according to the fermentation state.

Claims (8)

下水汚泥と消石灰とを含み、該消石灰を下水汚泥100質量部に対して1質量部以上4質量部以下含む、好気発酵処理用の下水汚泥発酵原料。 A sewage sludge fermentation raw material for aerobic fermentation treatment, which comprises sewage sludge and sewage lime, and contains the sewage sludge by 1 part by mass or more and 4 parts by mass or less with respect to 100 parts by mass of sewage sludge. 栄養助材をさらに含む,請求項1に記載の下水汚泥発酵原料。 The sewage sludge fermentation raw material according to claim 1, further comprising a nutritional aid. 前記栄養助材を、前記下水汚泥100質量部に対して5質量部以上50質量部以下含む,請求項2に記載の下水汚泥発酵原料。 The sewage sludge fermentation raw material according to claim 2, wherein the nutritional auxiliary material is contained in an amount of 5 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the sewage sludge. 通気助材をさらに含む,請求項1~3のいずれか一項に記載の下水汚泥発酵原料。 The sewage sludge fermentation raw material according to any one of claims 1 to 3, further comprising a ventilation auxiliary material. 前記通気助材を、前記下水汚泥100質量部に対して5質量部以上50質量部以下含む,請求項4に記載の下水汚泥発酵原料。 The sewage sludge fermentation raw material according to claim 4, wherein the aeration auxiliary material is contained in an amount of 5 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the sewage sludge. 下水汚泥及び消石灰を含む下水汚泥発酵原料を好気発酵させて、該下水汚泥を処理する工程を備え、
前記消石灰は、前記下水汚泥100質量部に対して1質量部以上4質量部以下含む、下水汚泥の処理方法。
A step of aerobically fermenting a sewage sludge fermentation raw material containing sewage sludge and slaked lime to treat the sewage sludge is provided.
A method for treating sewage sludge, wherein the slaked lime contains 1 part by mass or more and 4 parts by mass or less with respect to 100 parts by mass of the sewage sludge.
栄養助材及び通気助材を更に含む前記下水汚泥発酵原料を用い、
前記栄養助材は、前記下水汚泥100質量部に対して5質量部以上50質量部以下含み、
前記通気助材は、前記下水汚泥100質量部に対して5質量部以上50質量部以下含む、請求項6に記載の下水汚泥の処理方法。
Using the sewage sludge fermentation raw material further containing a nutritional aid and a ventilation aid,
The nutritional aid contains 5 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the sewage sludge.
The method for treating sewage sludge according to claim 6, wherein the ventilation auxiliary material contains 5 parts by mass or more and 50 parts by mass or less with respect to 100 parts by mass of the sewage sludge.
前記下水汚泥発酵原料を密閉式且つ縦型の発酵槽内で好気発酵させる、請求項6又は7に記載の下水汚泥の処理方法。
The method for treating sewage sludge according to claim 6 or 7, wherein the sewage sludge fermentation raw material is aerobically fermented in a closed and vertical fermenter.
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