JP2022012611A - Plastic fat composition for bakery and its manufacturing method - Google Patents

Plastic fat composition for bakery and its manufacturing method Download PDF

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JP2022012611A
JP2022012611A JP2020114561A JP2020114561A JP2022012611A JP 2022012611 A JP2022012611 A JP 2022012611A JP 2020114561 A JP2020114561 A JP 2020114561A JP 2020114561 A JP2020114561 A JP 2020114561A JP 2022012611 A JP2022012611 A JP 2022012611A
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智 岸野
Satoshi Kishino
礼央 杉山
Reo Sugiyama
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Showa Sangyo Co Ltd
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Abstract

To provide a plastic fat composition for bakery which is favorable in plasticity and excellent in temperature stability in a wide temperature range, has a reduced content of saturated fatty acid, and can impart excellent texture to the bakery product.SOLUTION: A plastic fat composition for bakery manufactured according to the following manner, to 70 mass% or larger of fat that is a liquid at 20°C, (A) a specific emulsifier of 5 to 30 mass%, or (B) a specific emulsifier of 3 to 12 mass% and an extremely hydrogenated oil of 2 to 10 mass%, in which a total of a specific emulsifier and extremely hydrogenated oil is 6 mass% or more, are blended, the mixture is added and mixed with a quality improver for bakery, followed by rapidly cooling and kneading to produce.EFFECT: It is possible to impart moist feeling and soft feeling to the texture of the bakery product, and to improve the workability.SELECTED DRAWING: Figure 1

Description

本発明は、幅広い温度域で可塑性が良好で温度安定性に優れ、より良好な食感をベーカリー製品に付与することができ、かつ飽和脂肪酸の含有量が低減された液状油からなる可塑性油脂組成物のベーカリー用途に関する。 INDUSTRIAL APPLICABILITY According to the present invention, a plastic oil / fat composition comprising a liquid oil having good plasticity in a wide temperature range, excellent temperature stability, a better texture can be imparted to a bakery product, and the content of saturated fatty acids is reduced. Regarding bakery use of things.

ショートニングやマーガリンの可塑性油脂組成物は、製菓や製パン用油脂として用いられ、可塑性を有することで生地への分散性が良好となり、物性に優れた菓子やパンを製造することができる。可塑性油脂組成物は自由に形を変えることができるために、パン生地中ではグルテン膜にそって薄い膜状に広がり、発酵中に生地が膨らみやすくなり、焼成後のパンの歯切れがよくなる。 The plastic fat and oil compositions of shortening and margarine are used as fats and oils for confectionery and bread making, and by having plasticity, the dispersibility in the dough becomes good, and confectionery and bread having excellent physical characteristics can be produced. Since the plastic fat and oil composition can change its shape freely, it spreads in a thin film along the gluten film in the bread dough, the dough tends to swell during fermentation, and the bread after baking becomes crisp.

可塑性油脂組成物には、好ましい硬さや加工適性が良いことが求められ、原料油脂の一部として天然の動植物油脂を水素添加処理した部分水素添加油脂や、牛脂、ラード、パーム油等の高融点、中融点油脂が使用されている。部分水素添加油脂には、水素添加処理の際に高度不飽和脂肪酸が異性化されて生成したトランス脂肪酸が含まれるため、血中のLDL量を上昇させることにより心血管疾患のリスクを高めるといわれている。そのため、トランス脂肪酸を含まない可塑性油脂組成物が求められている。 The plastic fat and oil composition is required to have good hardness and processability, and has a high melting point such as partially hydrogenated fat and oil obtained by hydrogenating natural animal and vegetable fat and oil as a part of raw material fat and oil, beef tallow, lard, palm oil and the like. , Medium melting point oils and fats are used. Partially hydrogenated fats and oils contain trans fatty acids produced by isomerization of polyunsaturated fatty acids during hydrogenation treatment, and are said to increase the risk of cardiovascular disease by increasing the amount of LDL in the blood. ing. Therefore, there is a demand for a plastic fat / oil composition that does not contain trans fatty acids.

中融点(融点30~40℃)油脂であるパーム油は、これを配合した可塑性油脂組成物に保形性を与えるが、多く配合すると保存中に次第に硬く変化したり、粗大結晶ができたり、高温で溶けやすく十分な可塑性を得ることができないことが知られている。そのため、パーム油を含む混合油をエステル交換によって改質したエステル交換油を可塑性油脂組成物に使用すること(特許文献1)や、パーム油を用いた可塑性油脂用の改質剤として、特定の飽和脂肪酸からなるトリグリセリドを用いること(特許文献2)により改良がなされている。 Palm oil, which is a medium melting point (melting point 30 to 40 ° C.), gives shape retention to the plastic fat and oil composition containing it, but if it is mixed in a large amount, it gradually changes to hard during storage and coarse crystals are formed. It is known that it melts easily at high temperatures and cannot obtain sufficient plasticity. Therefore, a transesterified oil obtained by modifying a mixed oil containing palm oil by transesterification can be used in a plastic fat / oil composition (Patent Document 1), or as a modifier for plastic fats and oils using palm oil. Improvements have been made by using triglycerides composed of saturated fatty acids (Patent Document 2).

しかし、パーム油には、45質量%以上の飽和脂肪酸が含まれているだけでなく、3-モノクロロプロパン-1,2-ジオール(3-MCPD)脂肪酸エステルおよびグリシドール脂肪酸エステルも含まれている。飽和脂肪酸、3-MCPD脂肪酸エステルおよびグリシドール脂肪酸エステルは、トランス脂肪酸のように人における健康被害は報告されていないものの、多量に摂取すると栄養学上の問題があることが指摘されており、近年の健康志向の高まりにより、より安心して摂取できる油脂を使用することが求められている。同様にベーカリー製品においても、飽和脂肪酸量等の低減が求められている。 However, palm oil contains not only 45% by mass or more of saturated fatty acids, but also 3-monochromopropane-1,2-diol (3-MCPD) fatty acid esters and glycidol fatty acid esters. Although saturated fatty acids, 3-MCPD fatty acid esters and glycidol fatty acid esters have not been reported to cause health problems in humans like trans fatty acids, it has been pointed out that there are nutritional problems when taken in large amounts. With increasing health consciousness, it is required to use fats and oils that can be ingested with greater peace of mind. Similarly, in bakery products, reduction of the amount of saturated fatty acids and the like is required.

可塑性油脂組成物中のトランス脂肪酸の含有量を低減させるものとして、エステル化率が60%以上であって、ポリグリセリンの平均重合度が4以上、構成脂肪酸中の飽和脂肪酸の炭素数と含有量とが特定の範囲にあるポリグリセリン脂肪酸エステルを用いた、20℃で液体である油脂を30%以上含有する可塑性油脂組成物(特許文献3)が知られており、実施例で製造した可塑性油脂組成物の硬度や伸展性が改善されたことが示されている。 To reduce the content of trans fatty acid in the plastic fat and oil composition, the esterification rate is 60% or more, the average degree of polymerization of polyglycerin is 4 or more, and the carbon number and content of saturated fatty acid in the constituent fatty acids. A plastic fat and oil composition containing 30% or more of fat and oil that is liquid at 20 ° C. using a polyglycerin fatty acid ester in a specific range (Patent Document 3) is known, and the plastic fat and oil produced in Examples are known. It has been shown that the hardness and extensibility of the composition were improved.

また、パーム油由来の飽和脂肪酸や3-MCPD脂肪酸エステルおよびグリシドール脂肪酸エステル、部分水素添加油脂由来のトランス脂肪酸を低減する目的で、サラダ油等の液状油を製パン材料として用いることが考えられるが、液状又は流動状の油脂は、パン類の生地に於いてグルテン膜の形成を阻害する作用を持ち、製パン性を著しく低下させることが知られている(特許文献4)。具体的には、製パンのミキシング工程において、最初に液状油を添加すると、生地のつながりが悪くなり、生地がまとまりにくくなる。また、ミキシングの後半に添加した場合には、生地の表面で液状油がすべってしまい、うまく混ざらない。また、マフィン等の油分の多い焼菓子類においては、液状油であるサラダ油を使用すると焼成後に油染みが発生してしまう等の欠点があった。 Further, it is conceivable to use liquid oil such as salad oil as a bread-making material for the purpose of reducing saturated fatty acids derived from palm oil, 3-MCPD fatty acid esters and glycidol fatty acid esters, and trans fatty acids derived from partially hydrogenated fats and oils. It is known that liquid or fluid fats and oils have an action of inhibiting the formation of a gluten film in bread dough and significantly reduce the bread-making property (Patent Document 4). Specifically, when liquid oil is first added in the bread-making mixing process, the dough is poorly connected and the dough becomes difficult to organize. In addition, when added in the latter half of mixing, the liquid oil slips on the surface of the dough and does not mix well. Further, in baked confectioneries having a large oil content such as muffins, there is a drawback that oil stains occur after baking when salad oil, which is a liquid oil, is used.

特開2010-11799号公報Japanese Unexamined Patent Publication No. 2010-11799 国際公開2010/119781号International Publication 2010/119781 特開2013-110975公報Japanese Unexamined Patent Publication No. 2013-110975 特開平6-217693号公報Japanese Unexamined Patent Publication No. 6-217693

本発明は、幅広い温度域で可塑性が良好で温度安定性に優れた物性を備えた液状油からなる可塑性油脂組成物をベーカリー製品に用いる際に、ベーカリー製品製造時の作業性を向上することができ、かつ、より良好な食感をベーカリー製品に付与することができるベーカリー用可塑性油脂組成物およびその製造方法を提供することを目的とする。 INDUSTRIAL APPLICABILITY The present invention can improve workability at the time of manufacturing a bakery product when a plastic oil / fat composition composed of a liquid oil having good plasticity and excellent temperature stability in a wide temperature range is used for a bakery product. It is an object of the present invention to provide a plastic oil / fat composition for bakery and a method for producing the same, which can give a better texture to a bakery product.

本発明者は、上記課題を解決するため鋭意研究を進めた結果、20℃で液体である油脂70質量%以上に対して、特定のポリグリセリン脂肪酸エステルを5~30質量%配合して、完全に融解させた後急冷捏和することにより、20℃で液体である油脂から、幅広い温度域で可塑性が良好で温度安定性が改善された可塑性油脂組成物が得られ、この可塑性油脂組成物に、液体状のものを含む種々のベーカリー用品質改良材を添加混合したベーカリー用可塑性油脂組成物が、ベーカリー製品の食感において、よりしっとり感やソフト感を付与できるだけでなく、ベーカリー製品製造時の作業性を向上することを見出し、本発明を完成するに至った。
また、乳化剤の添加量を減少できるか鋭意検討した結果、20℃で液体である油脂70質量%以上に対して、特定のポリグリセリン脂肪酸エステルを3~12質量%および極度硬化油を2~10質量%含有し、かつポリグリセリン脂肪酸エステルと極度硬化油との合計が6質量%以上となるよう配合して、完全に融解させた後急冷捏和することにより、乳化剤の量が少なくても同様に、20℃で液体である油脂から幅広い温度域で可塑性が良好で、温度安定性が改善された可塑性油脂組成物が得られた。
この可塑性油脂組成物に、液体状のものを含む種々のベーカリー用品質改良材が添加混合されているベーカリー用可塑性油脂組成物も、ベーカリー製品の食感において、よりしっとり感やソフト感を付与でき、ベーカリー製品製造時の作業性が向上する。
As a result of diligent research to solve the above problems, the present inventor has added 5 to 30% by mass of a specific polyglycerin fatty acid ester to 70% by mass or more of fats and oils that are liquid at 20 ° C. By quenching and kneading after melting in, a plastic fat and oil composition having good plasticity and improved temperature stability in a wide temperature range can be obtained from the fat and oil that is liquid at 20 ° C. The plastic oil and fat composition for bakery, which is obtained by adding and mixing various quality improving materials for bakery including liquid, not only gives a moist and soft feeling to the texture of bakery products, but also at the time of manufacturing bakery products. We have found that workability is improved, and have completed the present invention.
In addition, as a result of diligent studies on whether the amount of emulsifier added can be reduced, 3 to 12% by mass of a specific polyglycerin fatty acid ester and 2 to 10% of an extremely hardened oil are used with respect to 70% by mass or more of fats and oils that are liquid at 20 ° C. The same applies even if the amount of emulsifier is small by blending so that the total content of the polyglycerin fatty acid ester and the extremely hardened oil is 6% by mass or more, and the mixture is completely melted and then rapidly cooled and kneaded. In addition, a plastic fat and oil composition having good plasticity in a wide temperature range and improved temperature stability was obtained from fats and oils that are liquid at 20 ° C.
The plastic oil and fat composition for bakery, in which various quality improving materials for bakery including liquid ones are added and mixed with this plastic oil and fat composition, can also give a more moist and soft feeling to the texture of the bakery product. , Improves workability when manufacturing bakery products.

本発明は、以下の(1)ないし(3)のベーカリー用可塑性油脂組成物に係るものである。
(1)20℃で液体である油脂を70質量%以上と、(A)ポリグリセリン脂肪酸エステルを5~30質量%、または(B)ポリグリセリン脂肪酸エステルを3~12質量%および極度硬化油を2~10質量%含有し、かつポリグリセリン脂肪酸エステルと極度硬化油との合計が6質量%以上、とを含有する可塑性油脂組成物に、ベーカリー用品質改良材が添加混合されている、ベーカリー用可塑性油脂組成物であって、
前記ポリグリセリン脂肪酸エステルが、構成脂肪酸100%中、炭素数が16~18の飽和脂肪酸の含有量が90%以上であり、
前記可塑性油脂組成物が、該可塑性油脂組成物の全構成脂肪酸の質量に対して、40質量%以下の飽和脂肪酸を含有する、ベーカリー用可塑性油脂組成物。
(2)前記可塑性油脂組成物は、動的粘弾性測定における10℃と30℃の貯蔵弾性率の常用対数の数値の差が、1.0未満である、上記(1)に記載のベーカリー用可塑性油脂組成物。
(3)前記ベーカリー用品質改良材が、ベーカリー用可塑性油脂組成物中に50質量%以下添加されている、上記(1)または(2)に記載のベーカリー用可塑性油脂組成物。
The present invention relates to the following plastic fat and oil compositions for bakery (1) to (3).
(1) 70% by mass or more of fats and oils that are liquid at 20 ° C., 5 to 30% by mass of (A) polyglycerin fatty acid ester, or 3 to 12% by mass of (B) polyglycerin fatty acid ester, and extremely hydrogenated oil. For bakery, a quality improving material for bakery is added and mixed with a plastic fat composition containing 2 to 10% by mass and a total of 6% by mass or more of polyglycerin fatty acid ester and extremely hydrogenated oil. A plastic oil / fat composition,
The polyglycerin fatty acid ester contains 90% or more of saturated fatty acids having 16 to 18 carbon atoms in 100% of constituent fatty acids.
A plastic fat or oil composition for bakery, wherein the plastic fat or oil composition contains 40% by mass or less of saturated fatty acids with respect to the mass of all constituent fatty acids of the plastic fat or oil composition.
(2) The plastic oil / fat composition according to (1) above, wherein the difference between the common logarithm values of the storage elastic moduli at 10 ° C. and 30 ° C. in the dynamic viscoelasticity measurement is less than 1.0. Plastic fat composition.
(3) The plastic oil / fat composition for bakery according to (1) or (2) above, wherein the quality improving material for bakery is added in an amount of 50% by mass or less in the plastic oil / fat composition for bakery.

本発明は、以下の(4)のベーカリー生地、(5)のベーカリー製品、または(6)のベーカリー用可塑性油脂組成物を製造する方法に係るものである。
(4)上記(1)ないし(3)のいずれかに記載のベーカリー用可塑性油脂組成物を含んでなる、ベーカリー生地。
(5)上記(4)に記載のベーカリー生地が加熱調理されたベーカリー製品。
(6)20℃で液体である油脂70質量%以上に対して、
(A)ポリグリセリン脂肪酸エステル5~30質量%、または(B)ポリグリセリン脂肪酸エステルを3~12質量%および極度硬化油を2~10質量%含有し、かつポリグリセリン脂肪酸エステルと極度硬化油との合計が6質量%以上、を混合し、加熱して融解させた後急冷捏和し、ベーカリー用品質改良材を添加混合し、ベーカリー用可塑性油脂組成物を製造する方法であって、
ポリグリセリン脂肪酸エステルが、構成脂肪酸100%中、炭素数が16~18の飽和脂肪酸の含有量が90%以上であり、
可塑性油脂組成物の全構成脂肪酸の質量に対して40質量%以下の飽和脂肪酸を含有する可塑性油脂組成物を製造する、ベーカリー用可塑性油脂組成物の製造方法。
The present invention relates to the following method for producing a bakery dough (4), a bakery product (5), or a plastic oil / fat composition for bakery (6).
(4) A bakery dough containing the plastic oil / fat composition for bakery according to any one of (1) to (3) above.
(5) A bakery product in which the bakery dough according to (4) above is cooked.
(6) For 70% by mass or more of fats and oils that are liquid at 20 ° C.
(A) Polyglycerin fatty acid ester 5 to 30% by mass, or (B) Polyglycerin fatty acid ester 3 to 12% by mass and extremely hydrogenated oil 2 to 10% by mass, and polyglycerin fatty acid ester and extremely hydrogenated oil. A method for producing a plastic oil / fat composition for bakery by mixing 6% by mass or more of the above, heating and melting, quenching and kneading, adding and mixing a quality improving material for bakery.
The polyglycerin fatty acid ester contains 90% or more of saturated fatty acids having 16 to 18 carbon atoms in 100% of constituent fatty acids.
A method for producing a plastic fat or oil composition for bakery, which comprises producing a plastic fat or oil composition containing 40% by mass or less of saturated fatty acids with respect to the mass of all constituent fatty acids of the plastic fat or oil composition.

本発明によれば、20℃で液体の油、即ち、低融点油脂(常温で液状の油脂)70質量%以上に対して、特定の乳化剤を5~30質量%配合するか、または、特定の乳化剤を3~12質量%と極度硬化油を2~10質量%とを配合することにより、低融点油脂から簡単な操作により可塑性油脂組成物が製造でき、この可塑性油脂組成物は、幅広い温度域で可塑性が良好で温度安定性がよいという、作業性において非常に好適な物性をそなえており、油染みも少なく、口溶けも良いものであった。また、特定の乳化剤の一部に替えて極度硬化油を添加することにより、乳化剤の添加量を減らすことができ、乳化剤由来の風味と、高価な乳化剤のコストを軽減できる。 According to the present invention, 5 to 30% by mass of a specific emulsifier is blended with respect to 70% by mass or more of a liquid oil at 20 ° C., that is, a low melting point oil (fat or oil liquid at room temperature), or a specific oil or fat. By blending 3 to 12% by mass of an emulsifier and 2 to 10% by mass of an extremely hydrogenated oil, a plastic fat and oil composition can be produced from a low melting point fat and oil by a simple operation, and this plastic fat and oil composition can be produced in a wide temperature range. It has good physical properties such as good plasticity and good temperature stability, which is very suitable for workability, has little oil stain, and has good melting in the mouth. Further, by adding extremely hydrogenated oil instead of a part of a specific emulsifier, the amount of the emulsifier added can be reduced, and the flavor derived from the emulsifier and the cost of the expensive emulsifier can be reduced.

この可塑性油脂組成物を、そのままベーカリーに使用しても良好な食感のベーカリー製品が得られるが、この可塑性油脂組成物に、ベーカリー用品質改良材を添加混合してベーカリー用可塑性油脂組成物とすると、しっとり感、ソフト感が増してより良好な食感のベーカリー製品が得られた。
また、通常、食物繊維を増量する目的で小麦粉を大豆粉等に置きかえると、ベーカリー製品の食感が悪化することが多いが、この場合においても食感を改良することができる。
Even if this plastic fat / oil composition is used as it is in a bakery, a bakery product having a good texture can be obtained. Then, a bakery product with a better texture was obtained with an increased moist and soft feeling.
Further, usually, when wheat flour is replaced with soybean flour or the like for the purpose of increasing the amount of dietary fiber, the texture of the bakery product is often deteriorated, but even in this case, the texture can be improved.

また、ベーカリー用品質改良材が液体状や流動状(オリゴ糖、液体香料等)である場合や吸湿性の高い粉体(粉あめ等)である場合、粉体であるベーカリー用ミックスに添加するとダマの発生や固結の要因になってしまうため、ベーカリー製品製造時にミックスとは別に計量して添加する場合が多く、作業が煩雑になっていた。本発明では、あらかじめベーカリー用品質改良材が混合されているベーカリー用可塑性油脂組成物を用いることにより、ベーカリー製品製造時にベーカリー用品質改良材を別に計量する手間を省くことができ、さらに、ミキシング時に生地がまとまりやすく、生地のべたつきを抑制することができるため、作業性が向上する。 If the quality improving material for bakery is liquid or fluid (oligosaccharide, liquid fragrance, etc.) or powder with high hygroscopicity (powder candy, etc.), it can be added to the powder bakery mix. Since it causes lumps and solidification, it is often added by weighing separately from the mix when manufacturing bakery products, which complicates the work. In the present invention, by using the plastic oil / fat composition for bakery in which the quality improving material for bakery is mixed in advance, it is possible to save the trouble of separately weighing the quality improving material for bakery at the time of manufacturing the bakery product, and further, at the time of mixing. Workability is improved because the dough is easy to organize and the stickiness of the dough can be suppressed.

さらに、油分の多い菓子(例えば、マフィン等)においては、サラダ油等の液状油を使用する場合に比べて、生地がまとまりやすく、生地のべたつきが抑制され作業性が向上し、かつ、油染みを抑制する効果が得られる。これは、本発明の可塑性油脂組成物が広い温度帯で可塑性を持つためであると考えられる。本発明のベーカリー用可塑性油脂組成物は、ベーカリー用可塑性油脂としての優れた物性を有するだけでなく、飽和脂肪酸の含有量も低減されている健康志向に沿ったベーカリー用可塑性油脂組成物である。 Furthermore, in confectionery with a high oil content (for example, muffins), the dough is easier to organize, the stickiness of the dough is suppressed, the workability is improved, and the oil stain is suppressed, as compared with the case of using liquid oil such as salad oil. The effect of It is considered that this is because the plastic oil / fat composition of the present invention has plasticity in a wide temperature range. The plastic fat and oil composition for bakery of the present invention is a plastic fat and oil composition for bakery that not only has excellent physical properties as a plastic fat and oil for bakery but also has a reduced content of saturated fatty acids in line with health consciousness.

本発明で用いる可塑性油脂組成物Aの各温度における動的粘弾性測定結果の貯蔵弾性率(Pa)の常用対数(log10X)プロットCommon logarithm (log 10 X) plot of the storage elastic modulus (Pa) of the dynamic viscoelasticity measurement results of the plastic fat composition A used in the present invention at each temperature. 本発明で用いる可塑性油脂組成物Bの各温度における動的粘弾性測定結果の貯蔵弾性率(Pa)の常用対数(log10X)プロットCommon logarithm (log 10 X) plot of the storage elastic modulus (Pa) of the dynamic viscoelasticity measurement results of the plastic fat composition B used in the present invention at each temperature.

本発明で用いる可塑性油脂組成物は、水相を実質的に含有しないショートニングのような製品形態と、水相を含有するマーガリンやファットスプレッド形態のいずれの形態であってもよい。水相を実質的に含有しないとは、水分(揮発分を含む)の含有量が0.5質量%以下であることを意味する。マーガリンとは、油脂組成物中に占める油脂含有率が80質量%以上のものをいい、ファットスプレッドは80質量%未満のものをいう。
本発明で用いる可塑性油脂組成物がマーガリンやファットスプレッドの場合、水相の含有量は30質量%以下であるのが好ましい。
The plastic oil / fat composition used in the present invention may be in either a product form such as shortening that does not substantially contain an aqueous phase, or a margarine or fat spread form that contains an aqueous phase. The fact that the aqueous phase is substantially not contained means that the content of water (including volatile matter) is 0.5% by mass or less. The margarine means that the fat content in the fat composition is 80% by mass or more, and the fat spread is less than 80% by mass.
When the plastic oil / fat composition used in the present invention is margarine or fat spread, the content of the aqueous phase is preferably 30% by mass or less.

本発明の可塑性油脂組成物に用いる20℃で液体である油脂としては、食用の低融点油脂であれば限定されるものではない。たとえば、大豆油、高オレイン酸大豆油、ナタネ油、高オレイン酸ナタネ油、コーン油、ゴマ油、シソ油、亜麻仁油、落花生油、紅花油、高オレイン酸紅花油、綿実油、ブドウ種子油、マカデミアナッツ油、ヘーゼルナッツ油、アーモンド油、カシューナッツ油、カボチャ種子油、クルミ油、あんず油、椿油、茶実油、エゴマ油、オリーブ油、カラシ油、米油、米糠油、小麦胚芽油、ボラージ油、アボカド油、カヤ油、ヒマワリ油、高オレイン酸ヒマワリ油、魚油、藻類油およびこれらの分別油脂が挙げられる。これらの油脂は、一種類でも良いし、二種類以上を組み合わせて用いても良い。 The fats and oils that are liquid at 20 ° C. used in the plastic fats and oils composition of the present invention are not limited as long as they are edible low melting point fats and oils. For example, soybean oil, high oleic acid soybean oil, rapeseed oil, high oleic acid rapeseed oil, corn oil, sesame oil, perilla oil, flaxseed oil, peanut oil, red flower oil, high oleic acid red flower oil, cottonseed oil, grape seed oil, macadamia nuts. Oil, hazelnut oil, almond oil, cashew nut oil, pumpkin seed oil, walnut oil, anzu oil, camellia oil, brown seed oil, egoma oil, olive oil, mustard oil, rice oil, rice bran oil, wheat germ oil, borage oil, avocado oil , Kaya oil, sunflower oil, high oleic acid sunflower oil, fish oil, algae oil and their fractionated fats and oils. These fats and oils may be used alone or in combination of two or more.

飽和脂肪酸の含有量が高い油脂は、パーム油、ヤシ油、バター等の融点が25℃以上の油脂に多く、20℃で液体である上記油脂はいずれも好ましく用いられる。飽和脂肪酸が35質量%以下である油脂が好ましく、30質量%以下がより好ましく、25質量%以下がさらに好ましい。 The fats and oils having a high content of saturated fatty acids are mostly palm oil, coconut oil, butter and the like having a melting point of 25 ° C. or higher, and all of the above fats and oils that are liquid at 20 ° C. are preferably used. Fats and oils containing 35% by mass or less of saturated fatty acids are preferable, 30% by mass or less is more preferable, and 25% by mass or less is further preferable.

本発明で用いる可塑性油脂組成物中には、20℃で液体である油脂を75質量%以上含有させることが好ましく、80質量%以上がより好ましく、82%以上がさらに好ましい。70質量%未満であると、可塑性油脂組成物の可塑性と口溶けが悪くなる。
可塑性油脂組成物がショートニングである場合は、20℃で液体である油脂を70~95質量%含有させることが好ましく、80~93質量%がより好ましい。
可塑性油脂組成物が水相を含有するマーガリン、ファットスプレッドである場合は、20℃で液体である油脂を70~90質量%含有させることが好ましい。
The plastic fat / oil composition used in the present invention preferably contains 75% by mass or more of fats and oils that are liquid at 20 ° C., more preferably 80% by mass or more, and even more preferably 82% or more. If it is less than 70% by mass, the plasticity and melting in the mouth of the plastic fat composition deteriorate.
When the plastic fat / oil composition is shortening, it is preferably contained in an amount of 70 to 95% by mass, more preferably 80 to 93% by mass, which is a liquid fat or oil at 20 ° C.
When the plastic oil / fat composition is a margarine or fat spread containing an aqueous phase, it is preferable to contain 70 to 90% by mass of the oil / fat which is liquid at 20 ° C.

本発明の可塑性油脂組成物に用いる極度硬化油としては、特に限定されず、たとえば、大豆極度硬化油、菜種極度硬化油、ハイエルシン菜種極度硬化油、ヒマワリ極度硬化油、パーム極度硬化油、牛脂極度硬化油、豚脂極度硬化油、米極度硬化油等が挙げられる。これらの油脂は、一種類でも良いし、二種類以上を組み合わせて用いても良い。極度硬化油は100%飽和脂肪酸の固形油脂のため、液体油に硬さを付与するのに好適であり、乳化剤のポリグリセリン脂肪酸エステルの配合量を低減することができる。 The extremely hydrogenated oil used in the plastic oil and fat composition of the present invention is not particularly limited, and for example, soybean extremely hydrogenated oil, rapeseed extremely hydrogenated oil, hyelsin rapeseed extremely hydrogenated oil, sunflower extremely hydrogenated oil, palm extremely hydrogenated oil, and beef fat extremely hardened oil. Examples include hydrogenated oil, extremely hydrogenated pork fat, extremely hydrogenated rice oil, and the like. These fats and oils may be used alone or in combination of two or more. Since the extremely hydrogenated oil is a solid fat and oil of 100% saturated fatty acid, it is suitable for imparting hardness to the liquid oil, and the amount of the emulsifier polyglycerin fatty acid ester can be reduced.

本発明の可塑性油脂組成物に配合される乳化剤であるポリグリセリン脂肪酸エステルは、構成脂肪酸100%中、炭素数が16~18の飽和脂肪酸の含有量が90%以上である。炭素数が16~18の飽和脂肪酸としては、パルミチン酸(炭素数16)、ステアリン酸(炭素数18)が好ましい。パルミチン酸の含有量は、20~40%が好ましく、27~37%がより好ましい。ステアリン酸の含有量は、60~80%が好ましく、63~73%がより好ましい。 The polyglycerin fatty acid ester, which is an emulsifier blended in the plastic fat and oil composition of the present invention, has a content of saturated fatty acid having 16 to 18 carbon atoms of 90% or more in 100% of constituent fatty acids. As the saturated fatty acid having 16 to 18 carbon atoms, palmitic acid (16 carbon atoms) and stearic acid (18 carbon atoms) are preferable. The content of palmitic acid is preferably 20 to 40%, more preferably 27 to 37%. The content of stearic acid is preferably 60 to 80%, more preferably 63 to 73%.

本発明のポリグリセリン脂肪酸エステルのエステル化率は限定されないが、60質量%以上が好ましく、70質量%以上がより好ましい。
また、本発明のポリグリセリン脂肪酸エステルを構成するポリグリセリンの平均重合度は限定されないが、3以上が好ましく、6以上がより好ましく、8以上がさらに好ましく、10であることが最も好ましい。ここで、平均重合度(n)は、次式(式1)および(式2)に基づき算出することができる。
分子量=74n+18・・・(1)
水酸基価=56110(n+2)/分子量・・・(2)
上記ポリグリセリン脂肪酸エステルは、ポリグリセリンと脂肪酸とのエステル化生成物であり、自体公知のエステル化反応等により製造される。その製造方法の詳細は、上記特許文献3に記載されている。
The esterification rate of the polyglycerin fatty acid ester of the present invention is not limited, but is preferably 60% by mass or more, more preferably 70% by mass or more.
The average degree of polymerization of the polyglycerin constituting the polyglycerin fatty acid ester of the present invention is not limited, but is preferably 3 or more, more preferably 6 or more, still more preferably 8 or more, and most preferably 10. Here, the average degree of polymerization (n) can be calculated based on the following equations (Equation 1) and (Equation 2).
Molecular weight = 74n + 18 ... (1)
Hydroxy group value = 56110 (n + 2) / molecular weight ... (2)
The polyglycerin fatty acid ester is an esterification product of polyglycerin and a fatty acid, and is produced by an esterification reaction known per se. Details of the manufacturing method are described in Patent Document 3 above.

本発明で用いる可塑性油脂組成物100質量%中に、乳化剤であるポリグリセリン脂肪酸エステルを、5~30質量%配合する。5質量%未満であると、可塑性油脂組成物の可塑性が悪くなり、油染みがみられる。30質量%以上であると、可塑性油脂組成物の可塑性と口溶けが悪くなり、また、ポリグリセリン脂肪酸エステルの飽和脂肪酸量が高いため、可塑性油脂組成物に含まれる飽和脂肪酸の含有量が高くなる。 In 100% by mass of the plastic fat / oil composition used in the present invention, 5 to 30% by mass of polyglycerin fatty acid ester as an emulsifier is blended. If it is less than 5% by mass, the plasticity of the plastic oil / fat composition is deteriorated and oil stains are observed. When it is 30% by mass or more, the plasticity and melting in the mouth of the plastic fat / oil composition are deteriorated, and since the saturated fatty acid content of the polyglycerin fatty acid ester is high, the content of the saturated fatty acid contained in the plastic fat / oil composition is high.

本発明で用いる可塑性油脂組成物がショートニングである場合は、乳化剤であるポリグリセリン脂肪酸エステルを5~30質量%含有させることが好ましい。より好ましくは7質量%以上、さらに好ましくは8質量%以上、さらに好ましくは10質量%以上である。また、より好ましくは25質量%以下、さらに好ましくは20質量%以下、さらに好ましくは18質量%以下である。
可塑性油脂組成物が水相を含有するマーガリン、ファットスプレッドである場合は、乳化剤であるポリグリセリン脂肪酸エステルを5~30質量%含有させることが好ましい。より好ましくは7質量%以上、さらに好ましくは8質量%以上、さらに好ましくは10質量%以上である。また、より好ましくは25質量%以下、さらに好ましくは20質量%以下、さらに好ましくは18質量%以下である。
When the plastic fat / oil composition used in the present invention is shortened, it is preferable to contain 5 to 30% by mass of a polyglycerin fatty acid ester as an emulsifier. It is more preferably 7% by mass or more, further preferably 8% by mass or more, still more preferably 10% by mass or more. Further, it is more preferably 25% by mass or less, further preferably 20% by mass or less, still more preferably 18% by mass or less.
When the plastic oil / fat composition is a margarine or fat spread containing an aqueous phase, it is preferable to contain 5 to 30% by mass of a polyglycerin fatty acid ester as an emulsifier. It is more preferably 7% by mass or more, further preferably 8% by mass or more, still more preferably 10% by mass or more. Further, it is more preferably 25% by mass or less, further preferably 20% by mass or less, still more preferably 18% by mass or less.

あるいは、本発明の可塑性油脂組成物100質量%中に、乳化剤であるポリグリセリン脂肪酸エステルを3~12質量%と極度硬化油を2~10質量%とを配合する。極度硬化油を配合することにより、乳化剤のポリグリセリン脂肪酸エステルの配合量を減らすことができ、乳化剤由来の風味を軽減することができる。
この場合、ポリグリセリン脂肪酸エステルが3質量%未満で、かつ極度硬化油が3質量%未満であると、可塑性油脂組成物の可塑性が悪くなり、また油染みも多くみられる。そのため、ポリグリセリン脂肪酸エステルと極度硬化油との合計が6質量%以上である必要がある。また、ポリグリセリン脂肪酸エステルが12質量%より多く、極度硬化油が10質量%より多いと、可塑性油脂組成物の口溶けが悪くなる。ポリグリセリン脂肪酸エステルの配合量は、より好ましくは4~10質量%、さらに好ましくは5~9質量%であり、極度化油の配合量は、より好ましくは2~7質量%である。
ポリグリセリン脂肪酸エステルと極度硬化油との配合量の比率は限定されないが、極度硬化油がポリグリセリン脂肪酸エステルと等量、もしくは極度硬化油がポリグリセリン脂肪酸エステルよりも少なく配合されていることが好ましい。
Alternatively, 3 to 12% by mass of the polyglycerin fatty acid ester as an emulsifier and 2 to 10% by mass of the extremely hydrogenated oil are blended in 100% by mass of the plastic fat and oil composition of the present invention. By blending the extremely hydrogenated oil, the blending amount of the polyglycerin fatty acid ester of the emulsifier can be reduced, and the flavor derived from the emulsifier can be reduced.
In this case, when the polyglycerin fatty acid ester is less than 3% by mass and the extremely hydrogenated oil is less than 3% by mass, the plasticity of the plastic oil / fat composition is deteriorated and many oil stains are observed. Therefore, the total of the polyglycerin fatty acid ester and the extremely hydrogenated oil needs to be 6% by mass or more. Further, when the polyglycerin fatty acid ester is more than 12% by mass and the extremely hydrogenated oil is more than 10% by mass, the plastic fat / oil composition is poorly melted in the mouth. The blending amount of the polyglycerin fatty acid ester is more preferably 4 to 10% by mass, further preferably 5 to 9% by mass, and the blending amount of the extreme oil is more preferably 2 to 7% by mass.
The ratio of the amount of the polyglycerin fatty acid ester to the extremely hardened oil is not limited, but it is preferable that the extremely hardened oil is contained in the same amount as the polyglycerin fatty acid ester or the extremely hardened oil is contained in a smaller amount than the polyglycerin fatty acid ester. ..

本発明で用いる可塑性油脂組成物は公知の方法により製造することができる。
可塑性油脂組成物がショートニングである場合は、20℃で液体である油脂と、ポリグリセリン脂肪酸エステル、またはポリグリセリン脂肪酸エステルと極度硬化油を混合し、50~80℃、好ましくは60~70℃に加熱して融解する。得られた溶液を、急冷捏和装置により急冷捏和して、油脂の結晶化と練捏を連続的に行い、可塑性油脂組成物を得る。その後、10~30℃で24~72時間テンパリングするのが好ましい。
The plastic fat composition used in the present invention can be produced by a known method.
When the plastic oil / fat composition is shortening, the oil / fat which is liquid at 20 ° C. is mixed with a polyglycerin fatty acid ester or a polyglycerin fatty acid ester and an extremely hydrogenated oil to 50 to 80 ° C., preferably 60 to 70 ° C. Heat and melt. The obtained solution is rapidly cooled and kneaded by a quenching kneading device to continuously crystallize and knead the fat and oil to obtain a plastic fat and oil composition. Then, it is preferable to temper at 10 to 30 ° C. for 24 to 72 hours.

可塑性油脂組成物が水相を含有するマーガリン、ファットスプレッドである場合は、20℃で液体である油脂と、ポリグリセリン脂肪酸エステル、またはポリグリセリン脂肪酸エステルと極度硬化油を混合し、50~80℃、好ましくは60~70℃に加熱して融解して油相とする。次いで、油相と、精製水を主体とする水相とを混合撹拌し、得られた混合液を急冷捏和装置により急冷捏和して、油脂の結晶化と練捏を連続的に行い、可塑性油脂組成物を得る。その後、10~30℃で24~72時間テンパリングするのが好ましい。 When the plastic oil / fat composition is a margarine or fat spread containing an aqueous phase, the oil / fat which is liquid at 20 ° C. is mixed with a polyglycerin fatty acid ester or a polyglycerin fatty acid ester and an extremely hydrogenated oil, and the temperature is 50 to 80 ° C. It is preferably heated to 60 to 70 ° C. and melted to form an oil phase. Next, the oil phase and the aqueous phase mainly composed of purified water are mixed and stirred, and the obtained mixed liquid is rapidly cooled and kneaded by a quenching kneading device to continuously crystallize and knead the fat and oil. A plastic oil / fat composition is obtained. Then, it is preferable to temper at 10 to 30 ° C. for 24 to 72 hours.

急冷捏和装置は、一般に2つのユニットから構成されており、管型の掻き取り式熱交換機からなる一つ目のユニットと、製品の種類、目的により構造の異なる管からなる二つ目のユニットからなる。ショートニングでは、管の内壁およびシャフトにピンを設けた混練機等が用いられ、マーガリン、ファットスプレッドでは、中空管または内部に金網を設けた管等が用いられる。 The quenching and kneading device is generally composed of two units, the first unit consisting of a tube-type scraping heat exchanger and the second unit consisting of tubes having different structures depending on the product type and purpose. Consists of. For shortening, a kneader or the like having pins on the inner wall and shaft of the pipe is used, and for margarine and fat spread, a hollow pipe or a pipe having a wire mesh inside is used.

本発明においては、ベーカリー用品質改良材を、可塑性油脂組成物に公知の方法で混合添加することにより、本発明のベーカリー用可塑性油脂組成物を製造する。
ベーカリー用品質改良材を添加する工程に特に制限はなく、あらかじめ20℃で液体である油脂に混合しておいてもよく、20℃で液体である油脂とポリグリセリン脂肪酸エステルを、またはポリグリセリン脂肪酸エステルと極度硬化油とを混合して加熱融解する工程で添加してもよく、急冷捏和装置により急冷捏和する工程で添加してもよく、10~30℃でテンパリングする工程で添加してもよく、可塑性油脂組成物の製造後に添加してもよい。
In the present invention, the quality improving material for bakery is mixed and added to the plastic fat and oil composition by a known method to produce the plastic fat and oil composition for bakery of the present invention.
There is no particular limitation on the process of adding the quality improving material for bakery, and the oil and fat which is liquid at 20 ° C. may be mixed in advance, and the oil and fat and polyglycerin fatty acid ester which are liquid at 20 ° C., or polyglycerin fatty acid. It may be added in the step of mixing the ester and the extremely hydrogenated oil and heating and melting, or it may be added in the step of quenching and kneading with a quenching and kneading device, or it may be added in the step of tempering at 10 to 30 ° C. It may be added after the production of the plastic oil / fat composition.

本発明のベーカリー用品質改良材に特に制限はなく、たとえば、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の乳化剤、アスコルビン酸、臭素酸カリウム等の酸化剤、シスチン、グルタチオン等の還元剤、オリゴ糖、粉末水あめ、澱粉分解物、デキストリン、カルボキシメチルセルロース、澱粉、増粘多糖類等の糖質、アミラーゼ、βアミラーゼ、αアミラーゼ、キシラナーゼ、プロテアーゼ等の酵素、オイル系やエッセンス系の液体香料、粉末香料等の香料、液体色素、粉末色素等の色素、イーストフード等が挙げられる。好ましくは、糖質、酵素、香料、色素であり、特に、糖質としてはオリゴ糖、粉末水あめ、カルボキシメチルセルロース、酵素としてはβアミラーゼ、香料としては液体香料、色素としては液体色素が用いられる。
これらのベーカリー用品質改良材を、ベーカリー用可塑性油脂組成物中に50質量%以下の量で、好ましくは20~30質量%の量で混合することにより、可塑性油脂組成物と改良材の相加効果により、ベーカリー製品の食感において、よりしっとり感やソフト感を付与できる。
The quality improving material for bakery of the present invention is not particularly limited, and for example, emulsifiers such as glycerin fatty acid ester and sucrose fatty acid ester, oxidizing agents such as ascorbic acid and potassium bromide, reducing agents such as cystine and glutathione, oligosaccharides, and the like. Powdered water candy, starch decomposition products, dextrin, carboxymethyl cellulose, starch, sugars such as thickening polysaccharides, enzymes such as amylase, β-amylase, α-amylase, xylanase, protease, oil-based and essence-based liquid fragrances, powder fragrances, etc. Examples include fragrances, liquid pigments, pigments such as powder pigments, yeast foods and the like. Preferred are sugars, enzymes, fragrances and pigments, and in particular, oligosaccharides, powdered water candy and carboxymethyl cellulose as sugars, β-amylase as enzymes, liquid fragrances as fragrances and liquid pigments as pigments are used.
By mixing these quality improving materials for bakery in the plastic fat and oil composition for bakery in an amount of 50% by mass or less, preferably 20 to 30% by mass, the plastic fat and oil composition and the improving material are added. Due to the effect, it is possible to give a moist feeling and a soft feeling to the texture of the bakery product.

本発明によれば、液体状または流動状であるオリゴ糖や液体香料等を可塑性油脂組成物に混合すると、全体として柔らかくはなるが可塑性は維持されたベーカリー用可塑性油脂組成物となる。ベーカリー用品質改良材が液体や吸湿性が高い粉末である場合に、これらを粉末であるベーカリー用ミックスに混合すると、ダマや固結を生じてしまうが、あらかじめこれらが添加されている本発明のベーカリー用可塑性油脂組成物を用いると、ベーカリー製品製造時の作業性が向上する。 According to the present invention, when a liquid or fluid oligosaccharide, a liquid flavor, or the like is mixed with a plastic fat or oil composition, the plastic fat or oil composition for bakery becomes soft as a whole but maintains plasticity. When the quality improving material for bakery is a liquid or a powder with high hygroscopicity, if these are mixed with the bakery mix which is a powder, lumps and solidification will occur, but these are added in advance in the present invention. When a plastic fat composition for bakery is used, workability at the time of manufacturing a bakery product is improved.

本発明のベーカリー用可塑性油脂組成物は、製菓または製パン用としてロールイン用、練り込み用に用いる。ロールイン用とは、菓子またはパンの生地に折り込んで用いられることを指し、練り込み用とは、菓子またはパンの生地に練り込まれて用いられることを指す。本発明のベーカリー用可塑性油脂組成物を用いるベーカリー生地は、小麦粉を主成分とし、他に穀粉として、通常ベーカリー生地に配合されるものを含んでもよい。たとえば、大麦粉、ライ麦粉、燕麦粉、トウモロコシ粉、ホワイトソルガム粉、大豆粉(きな粉)、緑豆粉、そば粉、アマランサス粉、キビ粉、アワ粉、ヒエ粉、米粉が挙げられる。 The plastic fat composition for bakery of the present invention is used for roll-in and kneading for confectionery or bread making. For roll-in, it means that it is used by folding it into a confectionery or bread dough, and for kneading, it means that it is kneaded into a confectionery or bread dough. The bakery dough using the plastic oil / fat composition for bakery of the present invention may contain wheat flour as a main component and other flours that are usually blended in bakery dough. Examples thereof include barley flour, rye flour, swallow flour, corn flour, white sorghum flour, soybean flour (kina flour), green bean flour, buckwheat flour, amaranthus flour, millet flour, awa flour, hie flour and rice flour.

ベーカリー生地には、穀粉と本発明のベーカリー可塑性油脂組成物の他に、従来の公知の成分を含んでよい。そのような公知の成分としては、たとえば、砂糖、ぶどう糖、麦芽糖、異性化糖、水あめ、粉あめ、オリゴ糖、デキストリン、糖アルコール類、澱粉、加工澱粉等の糖質、バター、ラード、サラダ油、マーガリン、ショートニング等の油脂、脱脂粉乳、乾燥卵等のグルテン以外のたん白質、その他、イースト、ベーキングパウダー、増粘多糖類、食塩、カルシウム塩、調味料、香料、ビタミンC、乳化剤、イーストフード等が挙げられる。 The bakery dough may contain conventionally known ingredients in addition to the flour and the bakery plastic oil / fat composition of the present invention. Such known components include, for example, sugars, grape sugars, malt sugars, high fructose corn syrups, water candy, powdered candy, oligosaccharides, dextrins, sugar alcohols, starches, processed starches and other sugars, butter, lard, salad oil, and the like. Fats and oils such as margarine and shortening, non-gluten proteins such as defatted milk powder, dried eggs, yeast, baking powder, thickening polysaccharides, salt, calcium salt, seasonings, fragrances, vitamin C, emulsifiers, yeast foods, etc. Can be mentioned.

本発明のベーカリー用可塑性油脂組成物を用いて製造されるベーカリー製品としては、小麦粉を主成分として調製された生地を加熱することで製造される製品であれば、特に制限はない。例えば、パン、イーストドーナツ、ピザ、中華まんじゅう等のパン類、クッキー、サブレ、ビスケット、マドレーヌ、マフィン、ドーナツ、スポンジケーキ、パイ、ホットケーキ等の焼き菓子類等が挙げられる。 The bakery product produced by using the plastic oil / fat composition for bakery of the present invention is not particularly limited as long as it is a product produced by heating a dough prepared with wheat flour as a main component. Examples thereof include breads such as bread, yeast donuts, pizzas and Chinese manju, baked goods such as cookies, saberes, biscuits, madeleines, muffins, donuts, sponge cakes, pies and hot cakes.

次に、実施例に基づいて本発明を具体的に説明するが、本発明はこれらの実施例に限定されるものではない。以下実施例において、特に表示がなければ、「%」とは「質量%」を意味する。 Next, the present invention will be specifically described based on Examples, but the present invention is not limited to these Examples. In the following examples, unless otherwise specified, "%" means "mass%".

1.可塑性油脂組成物Aの製造
試験例として示した実施例または比較例において、ポリグリセリン脂肪酸エステルとして、乳化剤Aと乳化剤Bを用いた。乳化剤Aは、本発明のポリグリセリン脂肪酸エステル(HLB1.7、融点53℃、パルミチン酸32%、ステアリン酸67%、理研ビタミン株式会社製)である。乳化剤Bは、本発明のポリグリセリン脂肪酸エステルに該当しないポリグリセリン脂肪酸エステル(商品名TAISET50、パルミチン酸2%、ステアリン酸58%、太陽化学株式会社製)である。乳化剤A、Bの脂肪酸組成は、下記の脂肪酸分析方法により測定した。
1. 1. Production of Plastic Oil / Fat Composition A In the examples or comparative examples shown as test examples, emulsifier A and emulsifier B were used as the polyglycerin fatty acid ester. The emulsifier A is the polyglycerin fatty acid ester of the present invention (HLB 1.7, melting point 53 ° C., palmitic acid 32%, stearic acid 67%, manufactured by Riken Vitamin Co., Ltd.). The emulsifier B is a polyglycerin fatty acid ester (trade name: TAISET50, palmitic acid 2%, stearic acid 58%, manufactured by Taiyo Kagaku Co., Ltd.) that does not correspond to the polyglycerin fatty acid ester of the present invention. The fatty acid compositions of the emulsifiers A and B were measured by the following fatty acid analysis method.

また、下記の実施例で使用した油脂とそれぞれの飽和脂肪酸量は、以下の通りであった。飽和脂肪酸量は、下記の脂肪酸分析方法により測定した。
キャノーラ油(昭和産業株式会社):6.2質量%
綿実油(昭和産業株式会社):21.2質量%
高オレイン酸ヒマワリ油(昭和産業株式会社):6.9質量%
オリーブ油(昭和産業株式会社):13.7質量%
パームオレイン(IV60)(昭和産業株式会社):41.9質量%
パームオレイン(IV67)(昭和産業株式会社):36.6質量%
パーム中融点分別油脂(IV45)(太陽油脂株式会社):55.1質量%
なお、極度硬化油はすべて横関油脂工業株式会社のものであり、飽和脂肪酸含量は100質量%であった。
The fats and oils used in the following examples and the amounts of each saturated fatty acid were as follows. The amount of saturated fatty acid was measured by the following fatty acid analysis method.
Canola oil (Showa Sangyo Co., Ltd.): 6.2% by mass
Cottonseed oil (Showa Sangyo Co., Ltd.): 21.2% by mass
High oleic sunflower oil (Showa Sangyo Co., Ltd.): 6.9% by mass
Olive oil (Showa Sangyo Co., Ltd.): 13.7% by mass
Palm olein (IV60) (Showa Sangyo Co., Ltd.): 41.9% by mass
Palm olein (IV67) (Showa Sangyo Co., Ltd.): 36.6% by mass
Melting point fractionated fats and oils (IV45) in palm (Taiyo Yushi Co., Ltd.): 55.1% by mass
All the extremely hydrogenated oils were from Yokoseki Yushi Kogyo Co., Ltd., and the saturated fatty acid content was 100% by mass.

[分析方法]
脂肪酸組成および飽和脂肪酸量の分析は、基準油脂分析試験法2.4.2.3-2013 脂肪酸組成に準じて、試料をキャピラリーガスクロマトグラフ法で測定し、分析した。
[Analysis method]
The fatty acid composition and the amount of saturated fatty acid were analyzed by measuring and analyzing the sample by the capillary gas chromatograph method according to the standard fat and oil analysis test method 2.4.2.3-2013 fatty acid composition.

動的粘弾性測定には、AntonPaar社製 Modular Compact Rheometer MCR102を用いた。治具は25mm平行板治具、ギャップは1mm、周波数1.0rad/sec、ひずみ0.05%で、試料の温度を5℃から50℃まで1分間に2℃ずつ上昇させて、試料の温度依存の貯蔵弾性率(Pa)を測定した。 A Modular Compact Rheometer MCR102 manufactured by AntonioPaar was used for the dynamic viscoelasticity measurement. The jig is a 25 mm parallel plate jig, the gap is 1 mm, the frequency is 1.0 rad / sec, the strain is 0.05%, and the temperature of the sample is raised from 5 ° C to 50 ° C by 2 ° C per minute to the temperature of the sample. Dependent storage modulus (Pa) was measured.

破断応力(g)の測定には、英弘精機株式会社製 Texture Analyser TA TXplusを用いた。容器に充填した試料の温度を、15℃と25℃にそれぞれ調整し、治具は1mmψで、これを0.5mm/secで表面より12mm貫入させた際の破断応力(g)を測定した。 The Texture Analyzer TA TXplus manufactured by Eiko Seiki Co., Ltd. was used for the measurement of the breaking stress (g). The temperature of the sample filled in the container was adjusted to 15 ° C. and 25 ° C., respectively, and the jig was 1 mm ψ, and the breaking stress (g) when this was penetrated 12 mm from the surface at 0.5 mm / sec was measured.

[評価基準]
(1)可塑性評価
常温の試料をへらに取り、紙の上に伸ばした際の可塑性を、5名の専門パネルにより以下の評価基準で評価した。5名の合議結果を評価点とした。
評価基準
◎:非常に良好
○:良好
△:やや悪い
×:悪い
[Evaluation criteria]
(1) Plasticity evaluation The plasticity when a sample at room temperature was taken with a spatula and spread on paper was evaluated by the following evaluation criteria by a panel of 5 people. The result of the discussion of 5 people was used as the evaluation point.
Evaluation criteria
◎: Very good
○: Good
△: Slightly bad
×: Bad

(2)油染み評価
常温の試料をへらに取り、紙の上に伸ばした後、油の染み出しを、5名の専門パネルにより以下の評価基準で目視評価した。5名の合議結果を評価点とした。
評価基準
◎:油染みが無く非常に良好
○:油染みが少なく良好
△:油染みが見られるが許容範囲
×:油染みが多く悪い
(2) Oil stain evaluation After taking a sample at room temperature on a spatula and spreading it on paper, the oil stain was visually evaluated by a panel of 5 people according to the following evaluation criteria. The result of the discussion of 5 people was used as the evaluation point.
Evaluation criteria
◎: Very good with no oil stains
○: Good with little oil stain
Δ: Oil stains are seen, but acceptable range
×: Many oil stains are bad

(3)口溶け評価
専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:非常に良好
4:良好
3:許容範囲
2:やや悪い
1:悪い
(3) Evaluation of melting in the mouth Sensory evaluation was performed by 10 specialized panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: Very good
4: Good
3: Tolerance range
2: Somewhat bad
1: Bad

[可塑性油脂組成物Aの製造方法]
下記表2および表3に示す試験例1-1~1-18の配合割合で、それぞれの油脂と乳化剤を調合し、60℃で完全に融解させた後、急冷捏和装置で急冷捏和した。急冷捏和装置として、プライミクス株式会社製のAGI HOMOMIXER 2M-1を使用し、冷媒温度-10℃、パドルミキサー150rpm、ホモミキサー10000rpmの条件で、60℃から20℃まで冷却して、試験例1-1~1-18の可塑性油脂組成物Aを製造した。
各可塑性油脂組成物Aの飽和脂肪酸量、動的粘弾性、および破断応力を上記分析方法で測定し、可塑性、油染み、口溶け評価を上記評価基準で行った。
試験例1-1~1-7、1-9~1-11、1-15、1-16は本発明の実施例に相当し、試験例1-8、1-12~1-14、1-17、1-18は比較例に相当する。
[Method for producing plastic oil / fat composition A]
The respective fats and oils and emulsifiers were mixed in the blending ratios of Test Examples 1-1 to 1-18 shown in Tables 2 and 3 below, completely melted at 60 ° C., and then rapidly cooled and kneaded with a quenching kneader. .. AGI HOMOMIXER 2M-1 manufactured by Primix Corporation was used as a quenching and kneading device, and cooled from 60 ° C to 20 ° C under the conditions of a refrigerant temperature of -10 ° C, a paddle mixer of 150 rpm, and a homo mixer of 10000 rpm, and Test Example 1 The plastic fat composition A of -1 to 1-18 was produced.
The amount of saturated fatty acid, dynamic viscoelasticity, and breaking stress of each plastic oil / fat composition A were measured by the above analysis method, and plasticity, oil stain, and melting in the mouth were evaluated according to the above evaluation criteria.
Test Examples 1-1 to 1-7, 1-9 to 1-11, 1-15, 1-16 correspond to Examples of the present invention, and Test Examples 1-8, 1-12 to 1-14, 1 -17 and 1-18 correspond to comparative examples.

表1に、参考例1-1として雪印北海道バター 食塩不使用(雪印メグミルク株式会社)を、参考例1-2としてショートニングであるプレミックスオイル150(昭和産業株式会社)を用いた各分析結果、評価結果を示す。
また、以下の表2および表3には、製造した試験例1-1~1-18の油脂組成物について、それぞれの油脂と乳化剤の配合割合、その分析結果および評価結果を示す。
Table 1 shows the analysis results using Snow Brand Hokkaido Butter Salt-Free (Snow Brand Megmilk Co., Ltd.) as Reference Example 1-1 and shortening premix oil 150 (Showa Sangyo Co., Ltd.) as Reference Example 1-2. The evaluation result is shown.
Further, Tables 2 and 3 below show the blending ratios of the respective fats and oils and emulsifiers, the analysis results and the evaluation results thereof for the manufactured fats and oils compositions of Test Examples 1-1 to 1-18.

Figure 2022012611000002
Figure 2022012611000002

Figure 2022012611000003
Figure 2022012611000003
Figure 2022012611000004
Figure 2022012611000004

[分析結果]
各可塑性油脂組成物Aについて、その全構成脂肪酸の質量に対する飽和脂肪酸の含有量を測定した。本発明の乳化剤の飽和脂肪酸量が高いため、乳化剤の配合量が多くなるにつれて、可塑性油脂組成物の飽和脂肪酸量が高くなる傾向があったが、20℃で液体である油脂のみを用いた試験例1-1~1-11のいずれも飽和脂肪酸量が40質量%以下であった。
一方、パーム油およびパームに由来する油脂(パームオレイン、パーム油中融点分別油脂)を用いた試験例1-12~1-14の飽和脂肪酸量は40%以上であった。
[result of analysis]
For each plastic fat composition A, the content of saturated fatty acids with respect to the mass of all constituent fatty acids was measured. Since the amount of saturated fatty acid in the emulsifier of the present invention is high, the amount of saturated fatty acid in the plastic fat and oil composition tends to increase as the amount of the emulsifier blended increases. In all of Examples 1-1 to 1-11, the amount of saturated fatty acid was 40% by mass or less.
On the other hand, the amount of saturated fatty acids in Test Examples 1-12 to 1-14 using palm oil and oils and fats derived from palm (palm olein, oils and fats separated by melting point in palm oil) was 40% or more.

次に、可塑性油脂組成物の温度を変えて動的粘弾性を測定した貯蔵弾性率(Pa)の結果を、横軸の温度に対して縦軸にその貯蔵弾性率の値を常用対数(log10X)で示したものが、図1である。参考としてバター(参考例1)の測定結果も示すが、25℃を超えると急激に貯蔵弾性率が減少した。
室温の範囲として10℃から30℃を選択し、試料の10℃と30℃での貯蔵弾性率(Pa)の結果を常用対数にした値、およびそれら値の差を表1~3に示す。試験例1-1~1-12、1-18では、その値の差が1未満であり、温度変化の影響を受けづらく、安定した動的粘弾性を維持することがわかった。
一方、図1にも示した試験例1-15と1-16では、10℃と30℃での貯蔵弾性率(Pa)の常用対数の差の数値が1以上となり、日常の温度範囲内での温度変化に影響され、動的粘弾性が安定しないことが示された。
Next, the result of the storage elastic modulus (Pa) obtained by measuring the dynamic viscoelasticity by changing the temperature of the plastic oil / fat composition is obtained, and the value of the storage elastic modulus is shown on the vertical axis with respect to the temperature on the horizontal axis as the common logarithm (log). What is shown by 10 X) is FIG. The measurement result of butter (Reference Example 1) is also shown as a reference, but the storage elastic modulus sharply decreased when the temperature exceeded 25 ° C.
Tables 1 to 3 show the values obtained by selecting 10 ° C to 30 ° C as the room temperature range and using the results of the storage elastic modulus (Pa) of the sample at 10 ° C and 30 ° C as the common logarithm, and the differences between these values. In Test Examples 1-1 to 1-12 and 1-18, it was found that the difference between the values was less than 1, it was not easily affected by the temperature change, and stable dynamic viscoelasticity was maintained.
On the other hand, in Test Examples 1-15 and 1-16 also shown in FIG. 1, the value of the difference between the common logarithms of the storage elastic modulus (Pa) at 10 ° C and 30 ° C is 1 or more, which is within the daily temperature range. It was shown that the dynamic viscoelasticity was not stable due to the temperature change of.

破断応力は垂直の力に対する応力であり、硬度の指標である。この値が高くて可塑性油脂組成物が硬すぎる場合(たとえば、試験例1-8と試験例1-14)には、油脂が伸びず、可塑性の評価が悪くなった。 Fracture stress is a stress against a vertical force and is an index of hardness. When this value was high and the plastic fat composition was too hard (for example, Test Example 1-8 and Test Example 1-14), the fat did not stretch and the evaluation of plasticity was deteriorated.

[評価結果]
本発明の可塑性油脂組成物は、特に20℃で液体である油脂を85~90質量%、ポリグリセリン脂肪酸エステルを15~10質量%配合した場合、可塑性、油染み、口溶けの全ての評価が高かった。また、それ以外の配合量の場合の本発明の可塑性油脂組成物においても、可塑性、油染み、口溶けの評価は、総合的に良好なものであった。
[Evaluation results]
The plastic fat and oil composition of the present invention was highly evaluated for its plasticity, oil stain, and melting in the mouth, especially when 85 to 90% by mass of fat and oil liquid at 20 ° C. and 15 to 10% by mass of polyglycerin fatty acid ester were blended. .. Further, even in the plastic oil / fat composition of the present invention in the case of other blending amounts, the evaluation of plasticity, oil stain, and melting in the mouth was generally good.

2.ベーカリー用可塑性油脂組成物Aの製造
上記1.可塑性油脂組成物Aの製造と同じ方法で、下記表4に示す割合でキャノーラ油と乳化剤を調合して60℃で完全に融解させた後、急冷捏和装置で急冷捏和して、可塑性油脂組成物を製造し、この可塑性油脂組成物に、下記表4に示す割合で各資材を添加し混合機で混合することにより、本発明のベーカリー用可塑性油脂組成物である油脂ミックスA~Iの9種類を製造した。油脂ミックスの可塑性について、1.可塑性油脂組成物Aの製造に記載された、可塑性評価の基準に従って評価した。評価結果を表4に示した。
2. 2. Production of plastic fat composition A for bakery 1. In the same method as for producing the plastic fat composition A, canola oil and an emulsifier are mixed at the ratios shown in Table 4 below, completely melted at 60 ° C., and then rapidly cooled and kneaded with a quenching kneader to obtain the plastic fat and oil. By producing a composition, adding each material to the plastic oil / fat composition at the ratio shown in Table 4 below and mixing with a mixer, the oil / fat mix A to I which is the plastic oil / fat composition for bakery of the present invention can be prepared. Nine types were manufactured. Regarding the plasticity of the oil and fat mix, 1. The evaluation was made according to the criteria for evaluating plasticity described in the production of the plastic oil / fat composition A. The evaluation results are shown in Table 4.

Figure 2022012611000005
Figure 2022012611000005

3.パンの製造とその評価
表5にロールパンミックスの基本配合を示した。また、表6に示す配合でロールパンを製造した。
3. 3. Bread production and its evaluation Table 5 shows the basic composition of the roll bread mix. In addition, bread rolls were produced with the formulations shown in Table 6.

製造条件
参考例3-1および試験例3-1、3-3~3-12については、ミキサーに表5の原材料を添加し、低速で4分間、中速で8分間ミキシングした後、ショートニング、サラダ油、あるいは油脂ミックスを投入し、低速で3分30秒~5分間、中速で7~9分間ミキシングした(捏ね上げ温度24℃)。試験例3-2については、ミキサーに表5の原材料およびオリゴ糖を添加し、低速で4分間、中速で8分間ミキシングした後、ショートニングを投入し、低速で3分30秒~5分間、中速で7~9分間ミキシングした(捏ね上げ温度24℃)。得られた生地を27℃、湿度80%で5分間発酵させ70gに分割して丸めた。10分間ベンチタイムをとった後、成形して、38℃、湿度85%で60分間ホイロをとった後、200℃、10分間焼成してロールパンを得た。
得られたロールパンについて、下記の評価を行った。それぞれの評価結果は表6に示す。なお、試験例3-3~3-12は、本発明の実施例に相当し、試験例3-1、3-2は比較例に相当する。
Production conditions For Reference Example 3-1 and Test Examples 3-1 and 3-3 to 3-12, the raw materials shown in Table 5 were added to the mixer, mixed at low speed for 4 minutes and at medium speed for 8 minutes, and then shortened. Salad oil or oil / fat mix was added and mixed at low speed for 3 minutes 30 seconds to 5 minutes and at medium speed for 7 to 9 minutes (kneading temperature 24 ° C.). For Test Example 3-2, the raw materials and oligosaccharides shown in Table 5 were added to the mixer, mixed at low speed for 4 minutes and at medium speed for 8 minutes, then shortening was added, and the speed was 3 minutes 30 seconds to 5 minutes. Mixing was performed at medium speed for 7 to 9 minutes (kneading temperature 24 ° C.). The obtained dough was fermented at 27 ° C. and 80% humidity for 5 minutes, divided into 70 g and rolled. After taking a bench time of 10 minutes, it was molded, and a proof was taken at 38 ° C. and a humidity of 85% for 60 minutes, and then baked at 200 ° C. for 10 minutes to obtain a roll pan.
The obtained roll bread was evaluated as follows. The results of each evaluation are shown in Table 6. In addition, Test Examples 3-3 to 3-12 correspond to Examples of the present invention, and Test Examples 3-1 and 3-2 correspond to Comparative Examples.

(1)作業性評価
上記ロールパンの製造時における生地のまとまりやすさ、および生地のべたつきを作業性として評価した。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:非常に良好
4:良好
3:許容範囲
2:悪い
1:非常に悪い
(1) Workability evaluation The ease of cohesion of the dough and the stickiness of the dough at the time of manufacturing the above-mentioned roll pan were evaluated as workability. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: Very good
4: Good
3: Tolerance range
2: Bad
1: Very bad

(2)しっとり感
上記ロールパンの食感におけるしっとり感について、官能評価を行った。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:しっとり感が十分にあり、非常に良好
4:しっとり感が適度にあり、良好
3:しっとり感がややあり、許容範囲
2:しっとり感があまりなく、やや悪い
1:しっとり感がほとんどなく、悪い

(3)ソフト感
上記ロールパンの食感におけるソフト感について、官能評価を行った。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:ソフト感が十分にあり、非常に良好
4:ソフト感が適度にあり、良好
3:ソフト感がややあり、許容範囲
2:ソフト感があまりなく、やや悪い
1:ソフト感がほとんどなく、悪い

(4)風味
上記ロールパンの風味について、官能評価を行った。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:非常に良好
4:良好
3:許容範囲
2:やや悪い
1:悪い

Figure 2022012611000006
Figure 2022012611000007
(2) Moist feeling A sensory evaluation was performed on the moist feeling in the texture of the above-mentioned roll bread. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: There is enough moist feeling and it is very good.
4: Moderately moist and good
3: There is a slight moist feeling, and it is within the permissible range.
2: There is not much moist feeling and it is a little bad
1: There is almost no moist feeling and it is bad

(3) Soft texture A sensory evaluation was performed on the soft texture of the roll bread. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: There is enough soft feeling and it is very good.
4: Moderately soft and good
3: There is a slight soft feeling, and the allowable range
2: There is not much soft feeling and it is a little bad
1: There is almost no soft feeling and it is bad

(4) Flavor A sensory evaluation was performed on the flavor of the above-mentioned bread rolls. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: Very good
4: Good
3: Tolerance range
2: Somewhat bad
1: Bad

Figure 2022012611000006
Figure 2022012611000007

油脂ミックスA~Iを添加した試験例3-3~3-12では、特に作業性の評価が高かった。また、しっとり感、ソフト感、風味についても良い評価であった。一方、液状油であるサラダ油を添加した試験例3-1では、ミキシング工程において生地がまとまりにくく、生地がべたつき、作業性が非常に悪かった。また、ショートニングとオリゴ糖を別々に添加した試験例3-2では、しっとり感やソフト感は感じられ、風味は良好であった。しかし、原材料にオリゴ糖を添加する工程でダマが発生し、ミキシング工程で生地がまとまりにくく、また、生地がべたつき、作業性が悪かった。本発明の油脂ミックスを配合すると、パンの食感において、しっとり感、ソフト感が付与され、風味がよく、また、パンの製造時の作業性が良好になることがわかった。 In Test Examples 3-3-3-12 to which the oil / fat mixes A to I were added, the workability was particularly highly evaluated. In addition, the moist feeling, soft feeling, and flavor were also evaluated well. On the other hand, in Test Example 3-1 to which salad oil, which is a liquid oil, was added, the dough was difficult to be organized in the mixing step, the dough was sticky, and the workability was very poor. Further, in Test Example 3-2 in which shortening and oligosaccharide were added separately, a moist feeling and a soft feeling were felt, and the flavor was good. However, lumps were generated in the process of adding oligosaccharides to the raw materials, the dough was difficult to organize in the mixing process, the dough was sticky, and the workability was poor. It was found that when the oil and fat mix of the present invention was blended, a moist and soft texture was imparted to the texture of the bread, the flavor was good, and the workability during the production of the bread was improved.

さらに、栄養成分を調整する目的で、大豆粉や米粉を添加する場合、試験例3-13、3-14に示したとおり、しっとり感やソフト感が損なわれることがある。小麦粉の一部を大豆粉あるいは米粉に置き換え、本発明の油脂ミックスを添加した試験例3-15、3-16は、表7に示すように小麦粉を100%とした試験例3-2と同等の良好なしっとり感、ソフト感であった。

Figure 2022012611000008
Further, when soybean flour or rice flour is added for the purpose of adjusting the nutritional component, as shown in Test Examples 3-13 and 3-14, the moist feeling and the soft feeling may be impaired. Test Examples 3-15 and 3-16 in which a part of wheat flour was replaced with soybean flour or rice flour and the oil and fat mix of the present invention was added are equivalent to Test Example 3-2 in which 100% wheat flour is used as shown in Table 7. It was a good moist and soft feeling.

Figure 2022012611000008

4.マフィンの製造とその評価
表8に示す配合で、マフィンを製造した。
製造方法
全卵、砂糖、食塩、牛乳を混合した。篩った小麦粉とベーキングパウダーを加えた。つぎに、サラダ油、または50℃程度で溶解したマーガリン、油脂ミックスを加え、混ぜ合わせた。90gずつ紙ケースに分注し、オーブンにて焼成した。焼成条件は、200℃で20分間であった。焼成後、25℃にて24時間保管した。得られたマフィンについて、下記の評価を行った。それぞれの評価結果は表8に示す。
なお、試験例4-2~4-4は、本発明の実施例に相当し、試験例4-1は比較例に相当する。
4. Production of Muffins and Evaluation thereof Muffins were produced by the formulations shown in Table 8.
Production method Whole eggs, sugar, salt and milk were mixed. Sifted flour and baking powder were added. Next, salad oil, margarine dissolved at about 50 ° C., and an oil / fat mix were added and mixed. 90 g each was dispensed into a paper case and baked in an oven. The firing conditions were 200 ° C. for 20 minutes. After firing, it was stored at 25 ° C. for 24 hours. The obtained muffins were evaluated as follows. The results of each evaluation are shown in Table 8.
In addition, Test Examples 4-2 to 4-4 correspond to Examples of the present invention, and Test Examples 4-1 correspond to Comparative Examples.

(1)しっとり感
上記マフィンの食感におけるしっとり感について、官能評価を行った。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:しっとり感が十分にあり、非常に良好
4:しっとり感が適度にあり、良好
3:しっとり感がややあり、許容範囲
2:しっとり感があまりなく、やや悪い
1:しっとり感がほとんどなく、悪い

(2)風味
上記マフィンの風味について、官能評価を行った。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。 評価基準
5:非常に良好
4:良好
3:許容範囲
2:やや悪い
1:悪い

(3)油染み
上記マフィンの油染みについて、評価を行った。専門パネル10名により、以下の評価基準で官能評価を行い、その平均値を算出して、小数点第二位を四捨五入した値を評価点とした。
評価基準
5:紙ケースの油染みがなく、非常に良好
4:紙ケースの油染みがほとんどなく、良好
3:紙ケースの油染みがややあるが、許容範囲
2:紙ケースの油染みがあり、やや悪い
1:紙ケースの油染みが多くあり、悪い
(1) Moist feeling A sensory evaluation was performed on the moist feeling in the texture of the above muffins. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: There is enough moist feeling and it is very good.
4: Moderately moist and good
3: There is a slight moist feeling, and it is within the permissible range.
2: There is not much moist feeling and it is a little bad
1: There is almost no moist feeling and it is bad

(2) Flavor A sensory evaluation was performed on the flavor of the above muffins. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point. Evaluation criteria
5: Very good
4: Good
3: Tolerance range
2: Somewhat bad
1: Bad

(3) Oil stain The oil stain of the above muffin was evaluated. Sensory evaluation was performed by 10 expert panels according to the following evaluation criteria, the average value was calculated, and the value rounded to the second decimal place was used as the evaluation point.
Evaluation criteria
5: Very good with no oil stains on the paper case
4: Good with almost no oil stains on the paper case
3: There is some oil stain on the paper case, but it is acceptable.
2: There is an oil stain on the paper case, which is a little bad.
1: There are many oil stains on the paper case, which is bad.

Figure 2022012611000009
Figure 2022012611000009

液状油であるサラダ油を添加した試験例4-1では、油染みの発生がみられた。試験例4-2~4-4では、特に油染みが少なく、評価が高かった。 In Test Example 4-1 to which salad oil, which is a liquid oil, was added, oil stains were observed. In Test Examples 4-2 to 4-4, the oil stain was particularly small and the evaluation was high.

また、栄養成分を調整する目的で、大豆粉や米粉を添加する場合、試験例4-5、4-6に示したとおり、しっとり感が損なわれることがある。小麦粉の一部を大豆粉あるいは米粉に置き換え、本発明の油脂ミックスを添加した試験例4-7、4-8は、表9に示すように小麦粉を100%とした試験例4-2と同等の良好なしっとり感であった。

Figure 2022012611000010
Further, when soybean flour or rice flour is added for the purpose of adjusting the nutritional component, the moist feeling may be impaired as shown in Test Examples 4-5 and 4-6. Test Examples 4-7 and 4-8 in which a part of wheat flour was replaced with soybean flour or rice flour and the oil and fat mix of the present invention was added are equivalent to Test Example 4-2 in which 100% wheat flour is used as shown in Table 9. It was a good moist feeling.
Figure 2022012611000010

5.可塑性油脂組成物Bの製造
下記表10に示す試験例5-1~5-13の配合割合で、それぞれの油脂と乳化剤を調合し、60℃で完全に融解させた後、急冷捏和装置で急冷捏和した。急冷捏和装置として、プライミクス株式会社製のAGI HOMOMIXER 2M-1を使用し、冷媒温度-10℃、パドルミキサー150rpm、ホモミキサー8500rpmの条件で、60℃から10℃まで冷却して、25℃で24時間テンパリングし、試験例5-1~5-13の可塑性油脂組成物Bを製造した。使用した油脂および乳化剤は、実施例1に記載のものである。
各可塑性油脂組成物Bの飽和脂肪酸量、動的粘弾性、および破断応力を実施例1記載の分析方法で測定し、可塑性、油染み、口溶け評価を実施例1記載の評価基準で行った。
試験例5-2~5-7、5-9~5-12は本発明の実施例に相当し、試験例5-1、5-8、5-13は比較例に相当する。
5. Production of Plastic Oil and Fat Composition B The respective oils and fats and emulsifiers were prepared in the blending ratios of Test Examples 5-1 to 5-13 shown in Table 10 below, and after being completely melted at 60 ° C., a quenching kneader was used. It was rapidly cooled and kneaded. Using AGI HOMOMIXER 2M-1 manufactured by Primix Corporation as a quenching and kneading device, cool from 60 ° C to 10 ° C under the conditions of refrigerant temperature -10 ° C, paddle mixer 150 rpm, and homo mixer 8500 rpm, and at 25 ° C. After tempering for 24 hours, the plastic oil / fat composition B of Test Examples 5-1 to 5-13 was produced. The fats and oils and emulsifiers used are those described in Example 1.
The amount of saturated fatty acid, dynamic viscoelasticity, and breaking stress of each plastic oil / fat composition B were measured by the analysis method described in Example 1, and the plasticity, oil stain, and melting in the mouth were evaluated according to the evaluation criteria described in Example 1.
Test Examples 5-2 to 5-7 and 5-9 to 5-12 correspond to Examples of the present invention, and Test Examples 5-1, 5-8 and 5-13 correspond to Comparative Examples.

以下の表10に、製造した試験例5-1~5-13の可塑性油脂組成物Bについて、それぞれの油脂と乳化剤の配合割合、その分析結果および評価結果を示す。

Figure 2022012611000011
Table 10 below shows the blending ratios of the respective fats and oils and emulsifiers, the analysis results and the evaluation results for the plastic fat and oil compositions B of Test Examples 5-1 to 5-13 produced.
Figure 2022012611000011

[分析結果]
各可塑性油脂組成物Bについて、その全構成脂肪酸の質量に対する飽和脂肪酸の含有量を測定した。本発明の乳化剤の飽和脂肪酸量が高く、極度硬化油の飽和脂肪酸量が100質量%であるため、乳化剤と極度硬化油の配合量が多くなるにつれて、可塑性油脂組成物の飽和脂肪酸量が高くなる傾向があったが、試験例5-1~5-13いずれも飽和脂肪酸量が40質量%以下であった。
[result of analysis]
For each plastic fat composition B, the content of saturated fatty acids with respect to the mass of all constituent fatty acids was measured. Since the amount of saturated fatty acid of the emulsifier of the present invention is high and the amount of saturated fatty acid of the extremely hydrogenated oil is 100% by mass, the amount of saturated fatty acid of the plastic fat and oil composition increases as the amount of the emulsifier and the extremely hydrogenated oil increases. Although there was a tendency, the amount of saturated fatty acid was 40% by mass or less in all of Test Examples 5-1 to 5-13.

次に、可塑性油脂組成物の温度を変えて動的粘弾性を測定した貯蔵弾性率の結果を、横軸の温度に対して縦軸にその貯蔵弾性率の値を常用対数(log10X)で示したものが、図2である。
室温の範囲として10℃から30℃を選択し、試料の10℃と30℃での貯蔵弾性率の結果を常用対数にした値、およびそれら値の差を表10に示す。試験例5-1~5-12では、その値の差が1未満であり、温度変化の影響を受けづらく、安定した動的粘弾性を維持することがわかった。
一方、図2にも示した試験例5-13では、10℃と30℃での貯蔵弾性率の常用対数の差の数値が1以上となり、日常の温度範囲内での温度変化に影響され、動的粘弾性が安定しないことが示された。
Next, the results of the storage elastic modulus obtained by measuring the dynamic viscoelasticity by changing the temperature of the plastic oil / fat composition are shown in the common logarithm (log 10 X) with the value of the storage elastic modulus on the vertical axis with respect to the temperature on the horizontal axis. What is shown in FIG. 2 is FIG.
Table 10 shows the values obtained by selecting 10 ° C to 30 ° C as the room temperature range and using the results of the storage elastic modulus of the sample at 10 ° C and 30 ° C as the common logarithm, and the difference between these values. In Test Examples 5-1 to 5-12, it was found that the difference between the values was less than 1, it was not easily affected by the temperature change, and stable dynamic viscoelasticity was maintained.
On the other hand, in Test Example 5-13 also shown in FIG. 2, the value of the difference between the common logarithms of the storage elastic modulus at 10 ° C and 30 ° C is 1 or more, which is affected by the temperature change within the daily temperature range. It was shown that the dynamic viscoelasticity was not stable.

破断応力は垂直の力に対する応力であり、硬度の指標である。25℃、15℃のいずれにおいても、試験例5-2~5-12は適度な破断応力であったため、油脂が伸びやすく、可塑性が良好であることが確認された。試験例5-1は、破断応力が低く、可塑性が悪かった。また、油染みの評価も悪かった。 Fracture stress is a stress against a vertical force and is an index of hardness. Since Test Examples 5-2 to 5-12 had an appropriate breaking stress at both 25 ° C and 15 ° C, it was confirmed that the fats and oils were easy to spread and the plasticity was good. Test Example 5-1 had a low breaking stress and poor plasticity. The evaluation of oil stains was also poor.

[評価結果]
本発明の可塑性油脂組成物は、特に20℃で液体である油脂を80~93質量%、ポリグリセリン脂肪酸エステルを5~11質量%、極度硬化油を2~9質量%、配合した場合、可塑性、油染み、口溶けの全ての評価が高かった。また、それ以外の配合量の場合の本発明の可塑性油脂組成物においても、可塑性、油染み、口溶けの評価は、総合的に良好なものであった。20℃で液体である油脂を94.2質量%、ポリグリセリン脂肪酸エステルを2.9%、極度硬化油を2.9%配合した試験例5-1は、可塑性、油じみの評価が非常に悪かった。20℃で液体である油脂を76質量%、ポリグリセリン脂肪酸エステルを13%、極度硬化油を11%配合した試験例5-8は、可塑性、油染みの評価は非常に良好であったが、口溶けの評価が低かった。パーム油を使用し、ポリグリセリン脂肪酸エステルを1.5%、極度硬化油を1.5%配合した試験例5-13は、油染みの評価が低かった。なお、20℃で液体である油脂を96質量%、極度硬化油を1.5質量%、ポリグリセリン脂肪酸エステルを2.5質量%配合した場合、油脂が固まらず、可塑性油脂組成物として評価することができなかった。
[Evaluation results]
The plastic fat and oil composition of the present invention is plastic when 80 to 93% by mass of fat and oil, which is liquid at 20 ° C., 5 to 11% by mass of polyglycerin fatty acid ester, and 2 to 9% by mass of extremely hydrogenated oil are blended. , Oil stain, and melting in the mouth were all highly evaluated. Further, even in the plastic oil / fat composition of the present invention in the case of other blending amounts, the evaluation of plasticity, oil stain, and melting in the mouth was generally good. Test Example 5-1 containing 94.2% by mass of fat and oil that is liquid at 20 ° C, 2.9% of polyglycerin fatty acid ester, and 2.9% of extremely hydrogenated oil has a very high evaluation of plasticity and oil stain. It was bad. Test Example 5-8, which contained 76% by mass of fat and oil liquid at 20 ° C., 13% of polyglycerin fatty acid ester, and 11% of extremely hydrogenated oil, had very good evaluations of plasticity and oil stain, but melted in the mouth. The evaluation was low. Test Example 5-13 using palm oil and containing 1.5% of polyglycerin fatty acid ester and 1.5% of extremely hydrogenated oil had a low evaluation of oil stain. When 96% by mass of fats and oils that are liquid at 20 ° C., 1.5% by mass of extremely hydrogenated oil, and 2.5% by mass of polyglycerin fatty acid ester are blended, the fats and oils do not harden and are evaluated as a plastic fat and oil composition. I couldn't.

6.ベーカリー用可塑性油脂組成物Bの製造
上記4.可塑性油脂組成物Bの製造と同じ方法で、下記表11に示す割合でキャノーラ油と乳化剤と極度硬化油を調合して60℃で完全に融解させた後、急冷捏和装置で急冷捏和して、可塑性油脂組成物を製造し、この可塑性油脂組成物に、下記表11に示す割合で各資材を添加し混合機で混合することにより、本発明のベーカリー用可塑性油脂組成物Bである油脂ミックスJ~Rの9種類を製造した。油脂ミックスの可塑性について、1.可塑性油脂組成物Aの製造に記載された、可塑性評価の基準に従って評価した。評価結果を表11に示した。

Figure 2022012611000012
6. Production of plastic fat composition B for bakery 4. In the same method as for producing the plastic fat composition B, canola oil, an emulsifier and an extremely hydrogenated oil are mixed at the ratio shown in Table 11 below, completely melted at 60 ° C., and then rapidly cooled and kneaded with a quenching kneader. A plastic oil / fat composition is produced, and each material is added to the plastic oil / fat composition at the ratio shown in Table 11 below and mixed with a mixer to obtain the oil / fat composition B for bakery of the present invention. Nine types of mixes J to R were manufactured. Regarding the plasticity of the oil and fat mix, 1. The evaluation was made according to the criteria for evaluating plasticity described in the production of the plastic oil / fat composition A. The evaluation results are shown in Table 11.

Figure 2022012611000012

7.パンの製造とその評価
表12に示す配合で、ロールパンを製造した。
製造条件
参考例7-1および試験例7-1、7-3~7-12については、ミキサーに表5の原材料を添加し、低速で4分間、中速で8分間ミキシングした後、ショートニング、サラダ油、あるいは油脂ミックスを投入し、低速で3分30秒~5分間、中速で7~9分間ミキシングした(捏ね上げ温度24℃)。試験例7-2については、ミキサーに表5の原材料およびオリゴ糖を添加し、低速で4分間、中速で8分間ミキシングした後、ショートニングを投入し、低速で3分30秒~5分間、中速で7~9分間ミキシングした(捏ね上げ温度24℃)。得られた生地を27℃、湿度80%で5分間発酵させ70gに分割して丸めた。10分間ベンチタイムをとった後、成形して、38℃、湿度85%で60分間ホイロをとった後、200℃、10分間焼成してロールパンを得た。なお、試験例7-3~7-12は、本発明の実施例に相当し、試験例7-1、7-2は比較例に相当する。
参考例7-1および試験例7-1~7-12で製造したロールパンについて、「3.パンの製造とその評価」に記載の評価項目に従って評価を行った。それぞれの評価結果は表12に示す。
7. Bread production and its evaluation Roll bread was produced with the formulations shown in Table 12.
Production conditions For Reference Example 7-1 and Test Examples 7-1, 7-3 to 7-12, the raw materials shown in Table 5 were added to the mixer, mixed at low speed for 4 minutes and at medium speed for 8 minutes, and then shortened. Salad oil or oil / fat mix was added and mixed at low speed for 3 minutes 30 seconds to 5 minutes and at medium speed for 7 to 9 minutes (kneading temperature 24 ° C.). For Test Example 7-2, the raw materials and oligosaccharides shown in Table 5 were added to the mixer, mixed at low speed for 4 minutes and at medium speed for 8 minutes, then shortening was added, and the speed was 3 minutes 30 seconds to 5 minutes. Mixing was performed at medium speed for 7 to 9 minutes (kneading temperature 24 ° C.). The obtained dough was fermented at 27 ° C. and 80% humidity for 5 minutes, divided into 70 g and rolled. After taking a bench time of 10 minutes, it was molded, and a proof was taken at 38 ° C. and a humidity of 85% for 60 minutes, and then baked at 200 ° C. for 10 minutes to obtain a roll pan. In addition, Test Examples 7-3 to 7-12 correspond to Examples of the present invention, and Test Examples 7-1 and 7-2 correspond to Comparative Examples.
The roll breads produced in Reference Example 7-1 and Test Examples 7-1 to 7-1-12 were evaluated according to the evaluation items described in "3. Bread production and evaluation thereof". The results of each evaluation are shown in Table 12.

Figure 2022012611000013
Figure 2022012611000013

油脂ミックスJ~Rを添加した試験例7-3~7-12では、特に作業性の評価が高かった。また、しっとり感、ソフト感、風味についても良好な評価であった。一方、液状油であるサラダ油を添加した試験例7-1では、ミキシング工程において生地がまとまりにくく、生地がべたつき、作業性が非常に悪かった。また、ショートニングとオリゴ糖を別々に添加した試験例7-2では、しっとり感やソフト感、風味は良好であったが、原材料にオリゴ糖を添加する工程でダマが発生し、ミキシング工程で生地がまとまりにくく、また、生地がべたつき、作業性が悪かった。本発明の油脂ミックスを配合すると、パンの食感において、しっとり感、ソフト感が付与され、風味がよく、また、パンの製造時の作業性が良好になることがわかった。 In Test Examples 7-3 to 7-12 to which the oil and fat mixes J to R were added, the evaluation of workability was particularly high. In addition, the moist feeling, soft feeling, and flavor were also evaluated well. On the other hand, in Test Example 7-1 to which salad oil, which is a liquid oil, was added, the dough was difficult to be organized in the mixing step, the dough was sticky, and the workability was very poor. In Test Example 7-2 in which shortening and oligosaccharide were added separately, the moist feeling, softness, and flavor were good, but lumps were generated in the process of adding oligosaccharide to the raw material, and the dough was mixed in the mixing process. It was hard to get together, the dough was sticky, and the workability was poor. It was found that when the oil and fat mix of the present invention was blended, a moist and soft texture was imparted to the texture of the bread, the flavor was good, and the workability during the production of the bread was improved.

さらに、栄養成分を調整する目的で、大豆粉や米粉を添加する場合、試験例7-13、7-14に示したとおり、しっとり感やソフト感が損なわれることがある。小麦粉の一部を大豆粉あるいは米粉に置き換え、本発明の油脂ミックスを添加した試験例7-15、7-16は、表13に示すように小麦粉を100%とした試験例7-2と同等の良好なしっとり感、ソフト感であった。

Figure 2022012611000014
Further, when soybean flour or rice flour is added for the purpose of adjusting the nutritional component, the moist feeling and the soft feeling may be impaired as shown in Test Examples 7-13 and 7-14. Test Examples 7-15 and 7-16 in which a part of wheat flour was replaced with soybean flour or rice flour and the oil and fat mix of the present invention was added are equivalent to Test Example 7-2 in which 100% wheat flour is used as shown in Table 13. It was a good moist and soft feeling.

Figure 2022012611000014

8.マフィンの製造とその評価
表14に示す配合で、マフィンを製造した。製造方法は、上記4.マフィンの製造とその評価に従った。
得られたマフィンについて、上記4.マフィンの製造とその評価に記載の評価項目に従って評価を行った。それぞれの評価結果は表14に示す。なお、試験例8-2~8-4は、本発明の実施例に相当し、試験例8-1は比較例に相当する。
8. Production of Muffins and Evaluation thereof Muffins were produced by the formulations shown in Table 14. The manufacturing method is as described in 4. above. According to the production of muffins and their evaluation.
Regarding the obtained muffins, the above 4. The evaluation was performed according to the evaluation items described in the production of muffins and their evaluation. The results of each evaluation are shown in Table 14. In addition, Test Examples 8-2 to 8-4 correspond to Examples of the present invention, and Test Examples 8-1 correspond to Comparative Examples.

Figure 2022012611000015
Figure 2022012611000015

液状油であるサラダ油を添加した試験例8-1では、油染みの発生がみられた。試験例8-2~8-4では、特に油染みが少なく、評価が高かった。 In Test Example 8-1 to which salad oil, which is a liquid oil, was added, oil stains were observed. In Test Examples 8-2 to 8-4, the oil stain was particularly small and the evaluation was high.

また、栄養成分を調整する目的で、大豆粉や米粉を添加する場合、試験例8-5、8-6に示したとおり、しっとり感が損なわれることがある。小麦粉の一部を大豆粉あるいは米粉に置き換え、本発明の油脂ミックスを添加した試験例8-7、8-8は、表15に示すように小麦粉を100%とした試験例8-2と同等の良好なしっとり感であった。

Figure 2022012611000016
Further, when soybean flour or rice flour is added for the purpose of adjusting the nutritional component, the moist feeling may be impaired as shown in Test Examples 8-5 and 8-6. Test Examples 8-7 and 8-8 in which a part of wheat flour was replaced with soybean flour or rice flour and the oil and fat mix of the present invention was added are equivalent to Test Example 8-2 in which 100% wheat flour is used as shown in Table 15. It was a good moist feeling.
Figure 2022012611000016

本発明によれば、20℃で液体の油脂70質量%以上に対して、特定の乳化剤を5~30質量%配合するか、または、特定の乳化剤を3~12質量%と極度硬化油を2~10質量%(ただし、特定の乳化剤と極度硬化油との合計が6質量%以上)配合することにより製造した可塑性油脂組成物に、ベーカリー用品質改良材を添加混合してベーカリー用可塑性油脂組成物が得られる。
このようにして製造されたベーカリー用可塑性油脂組成物は、幅広い温度域で可塑性が良好で、作業性が非常に好適な物性をそなえており、また、飽和脂肪酸含有量が低減されており、ベーカリー製品の食感にしっとり感、ソフト感を付与することができる。
According to the present invention, 5 to 30% by mass of a specific emulsifier is blended with respect to 70% by mass or more of a liquid oil or fat at 20 ° C., or 3 to 12% by mass of a specific emulsifier and 2 extremely hydrogenated oils are added. Plastic oil and fat composition for bakery by adding and mixing a quality improving material for bakery to a plastic oil and fat composition produced by blending up to 10% by mass (however, the total of a specific emulsifier and extremely hydrogenated oil is 6% by mass or more). You can get things.
The plastic fat and oil composition for bakery produced in this manner has good plasticity in a wide temperature range, has very suitable physical properties for workability, and has a reduced saturated fatty acid content, so that the bakery can be used. It is possible to give a moist and soft feeling to the texture of the product.

また、ベーカリー用品質改良材が液体状または流動状(オリゴ糖、液体香料)である場合や吸湿性の高い粉体(粉あめ等)である場合、粉体であるベーカリー用ミックスに添加するとダマの発生や固結の要因になってしまうため、ベーカリー製品製造時にミックスとは別に計量して添加することが多く、作業が煩雑になっていた。本発明では、ベーカリー用品質改良材が混合されたベーカリー用可塑性油脂組成物を用いることにより、ミキシング時に生地がまとまりやすく、生地のべたつきを抑制することができるので、作業性が良好になる。 If the quality improving material for bakery is liquid or fluid (oligosaccharide, liquid fragrance) or powder with high hygroscopicity (powder candy, etc.), adding it to the powder bakery mix will cause lumps. In many cases, the bakery product is weighed and added separately from the mix when manufacturing the bakery product, which makes the work complicated. In the present invention, by using the plastic oil / fat composition for bakery mixed with the quality improving material for bakery, the dough is easily organized during mixing and the stickiness of the dough can be suppressed, so that the workability is improved.

Claims (6)

20℃で液体である油脂を70質量%以上と、(A)ポリグリセリン脂肪酸エステルを5~30質量%、または(B)ポリグリセリン脂肪酸エステルを3~12質量%および極度硬化油を2~10質量%含有し、かつポリグリセリン脂肪酸エステルと極度硬化油との合計が6質量%以上、
とを含有する可塑性油脂組成物に、ベーカリー用品質改良材が添加混合されているベーカリー用可塑性油脂組成物であって、
前記ポリグリセリン脂肪酸エステルが、構成脂肪酸100%中、炭素数が16~18の飽和脂肪酸の含有量が90%以上であり、
前記可塑性油脂組成物が、該可塑性油脂組成物の全構成脂肪酸の質量に対して、40質量%以下の飽和脂肪酸を含有する、ベーカリー用可塑性油脂組成物。
70% by mass or more of fats and oils that are liquid at 20 ° C., 5 to 30% by mass of (A) polyglycerin fatty acid ester, 3 to 12% by mass of (B) polyglycerin fatty acid ester, and 2 to 10 extremely hydrogenated oils. Contains% by mass, and the total of polyglycerin fatty acid ester and extremely hydrogenated oil is 6% by mass or more.
A plastic oil / fat composition for bakery in which a quality improving material for bakery is added and mixed with a plastic oil / fat composition containing
The polyglycerin fatty acid ester contains 90% or more of saturated fatty acids having 16 to 18 carbon atoms in 100% of constituent fatty acids.
A plastic fat or oil composition for bakery, wherein the plastic fat or oil composition contains 40% by mass or less of saturated fatty acids with respect to the mass of all constituent fatty acids of the plastic fat or oil composition.
前記可塑性油脂組成物は、動的粘弾性測定における10℃と30℃の貯蔵弾性率の常用対数の数値の差が、1.0未満である、請求項1に記載のベーカリー用可塑性油脂組成物。 The plastic fat composition for bakery according to claim 1, wherein the difference between the common logarithm values of the storage elastic modulus at 10 ° C. and 30 ° C. in the dynamic viscoelasticity measurement is less than 1.0. .. 前記ベーカリー用品質改良材が、ベーカリー用可塑性油脂組成物中に50質量%以下添加されている、請求項1または2に記載のベーカリー用可塑性油脂組成物。 The plastic oil / fat composition for bakery according to claim 1 or 2, wherein the quality improving material for bakery is added in an amount of 50% by mass or less in the plastic oil / fat composition for bakery. 請求項1ないし3のいずれかに記載のベーカリー用可塑性油脂組成物を含んでなる、ベーカリー生地。 A bakery dough comprising the plastic oil / fat composition for bakery according to any one of claims 1 to 3. 請求項4に記載のベーカリー生地が加熱調理されたベーカリー製品。 A bakery product in which the bakery dough according to claim 4 is cooked. 20℃で液体である油脂70質量%以上に対して、
(A)ポリグリセリン脂肪酸エステル5~30質量%、または(B)ポリグリセリン脂肪酸エステルを3~12質量%および極度硬化油を2~10質量%含有し、かつポリグリセリン脂肪酸エステルと極度硬化油との合計が6質量%以上、を混合し、加熱して融解させた後急冷捏和し、ベーカリー用品質改良材を添加混合し、ベーカリー用可塑性油脂組成物を製造する方法であって、
ポリグリセリン脂肪酸エステルが、構成脂肪酸100%中、炭素数が16~18の飽和脂肪酸の含有量が90%以上であり、
可塑性油脂組成物の全構成脂肪酸の質量に対して40質量%以下の飽和脂肪酸を含有する可塑性油脂組成物を製造する、ベーカリー用可塑性油脂組成物の製造方法。
For 70% by mass or more of fats and oils that are liquid at 20 ° C
(A) Polyglycerin fatty acid ester 5 to 30% by mass, or (B) Polyglycerin fatty acid ester 3 to 12% by mass and extremely hydrogenated oil 2 to 10% by mass, and polyglycerin fatty acid ester and extremely hydrogenated oil. A method for producing a plastic oil / fat composition for bakery by mixing 6% by mass or more of the above, heating and melting, quenching and kneading, adding and mixing a quality improving material for bakery.
The polyglycerin fatty acid ester contains 90% or more of saturated fatty acids having 16 to 18 carbon atoms in 100% of constituent fatty acids.
A method for producing a plastic fat or oil composition for bakery, which comprises producing a plastic fat or oil composition containing 40% by mass or less of saturated fatty acids with respect to the mass of all constituent fatty acids of the plastic fat or oil composition.
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