JP2021155281A - Cold resistant inorganic anchor material and fixing method of anchor member using the anchor material - Google Patents
Cold resistant inorganic anchor material and fixing method of anchor member using the anchor material Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 94
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 31
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims abstract description 24
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 7
- 239000011707 mineral Substances 0.000 claims abstract description 7
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 7
- 239000007924 injection Substances 0.000 claims description 7
- IDNHOWMYUQKKTI-UHFFFAOYSA-M lithium nitrite Chemical compound [Li+].[O-]N=O IDNHOWMYUQKKTI-UHFFFAOYSA-M 0.000 claims description 5
- 235000010288 sodium nitrite Nutrition 0.000 claims description 5
- RAFRTSDUWORDLA-UHFFFAOYSA-N phenyl 3-chloropropanoate Chemical compound ClCCC(=O)OC1=CC=CC=C1 RAFRTSDUWORDLA-UHFFFAOYSA-N 0.000 claims description 4
- 238000010998 test method Methods 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 2
- 230000001070 adhesive effect Effects 0.000 claims description 2
- 238000007665 sagging Methods 0.000 abstract description 11
- 238000007710 freezing Methods 0.000 abstract description 10
- 230000008014 freezing Effects 0.000 abstract description 9
- 238000004873 anchoring Methods 0.000 abstract description 2
- 238000011156 evaluation Methods 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000004568 cement Substances 0.000 description 13
- 210000003205 muscle Anatomy 0.000 description 11
- 238000010276 construction Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000007798 antifreeze agent Substances 0.000 description 8
- 238000004898 kneading Methods 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000011398 Portland cement Substances 0.000 description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000002528 anti-freeze Effects 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- -1 alkali metal nitrite Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003340 retarding agent Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- AZFNGPAYDKGCRB-XCPIVNJJSA-M [(1s,2s)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;chlororuthenium(1+);1-methyl-4-propan-2-ylbenzene Chemical compound [Ru+]Cl.CC(C)C1=CC=C(C)C=C1.C1=CC(C)=CC=C1S(=O)(=O)[N-][C@@H](C=1C=CC=CC=1)[C@@H](N)C1=CC=CC=C1 AZFNGPAYDKGCRB-XCPIVNJJSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000010289 potassium nitrite Nutrition 0.000 description 1
- 239000004304 potassium nitrite Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- Bridges Or Land Bridges (AREA)
- Joining Of Building Structures In Genera (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
本発明は、耐寒用無機系アンカー材料及び該アンカー材料を用いたアンカー部材の固定方法に関し、特に低温下、例えば氷点下の環境においても有効に使用できる耐寒用注入式無機系あと施工アンカー材料及び当該アンカー材料を用いたアンカー部材の固定方法に関する。 The present invention relates to a cold-resistant inorganic anchor material and a method of fixing an anchor member using the anchor material, and a cold-resistant injection-type inorganic post-installed anchor material that can be effectively used even in an environment of low temperature, for example, below freezing point. The present invention relates to a method of fixing an anchor member using an anchor material.
建築物や舗装道路等の構造物の表面から所定の深さで形成される孔に、アンカー筋を収容し、アンカー筋と孔との間に充填材を充填することで、アンカー筋を構造物に固定する方法が知られている。
かかる建築・土木構造物であるコンクリート構造物に設けられた孔に注入するアンカー材料としては、無機系と有機系とに大別することができ、また施工形態として、カプセルタイプと注入タイプとがある。
Anchor bars are housed in holes formed at a predetermined depth from the surface of structures such as buildings and paved roads, and a filler is filled between the anchor bars and the holes to form the anchor bars. There is a known method of fixing to.
The anchor material to be injected into the hole provided in the concrete structure which is such a building / civil engineering structure can be roughly classified into an inorganic type and an organic type, and the construction form includes a capsule type and an injection type. be.
無機系アンカー材料は、セメントを主成分とし、水と混練されて、孔とアンカー筋との間に充填された後、硬化することで硬化層を形成する。そして、該硬化層が構造物およびアンカー筋と結合し、アンカー筋に対して孔から引き抜く方向に力が加わった際に、高い付着性能を有することで、アンカー筋が引き抜かれないように維持することが所望される。 The inorganic anchor material contains cement as a main component, is kneaded with water, is filled between the pores and the anchor streaks, and then hardened to form a hardened layer. Then, when the hardened layer is combined with the structure and the anchor muscle and a force is applied to the anchor muscle in the direction of pulling out from the hole, the anchor muscle is maintained so as not to be pulled out by having high adhesion performance. Is desired.
例えば、建築構造物では、手すり、看板等の取り付け、ブレス工法等の耐震補強工事、土木構造物では、橋梁の落橋防止、トンネル内設備の取り付け、固定等に採用されているのが一般的である。 For example, in building structures, it is generally used for installation of handrails, signs, etc., seismic reinforcement work such as breath construction method, and in civil engineering structures, it is generally used for bridge collapse prevention, installation of equipment in tunnels, fixing, etc. be.
通常、コンクリートやモルタル等のセメント系材料は、寒冷地における氷点下で使用する場合には、練り混ぜに使用する水が凍結するため、初期凍害を受けてしまい、耐久性、水密性等が著しく劣ることが知られている。
そこで、冬季の施工においては、特に氷点下の環境では、亜硝酸塩、硝酸塩、尿素、エチレングリコール等の防凍剤を添加して混練水の凝固点を降下させ、凍結を防止して施工を実施している。
また、無機系アンカー材料も、氷点下の場合には、初期凍害を受けてアンカー筋との付着性能に大きな影響を及ぼすことも懸念されている。
Normally, when cement-based materials such as concrete and mortar are used below freezing in cold regions, the water used for kneading freezes, resulting in initial frost damage, and the durability and watertightness are significantly inferior. It is known.
Therefore, in winter construction, especially in a sub-zero environment, antifreeze agents such as nitrite, nitrate, urea, and ethylene glycol are added to lower the freezing point of the kneaded water to prevent freezing. ..
Inorganic anchor materials are also concerned that when they are below freezing point, they are damaged by initial frost and have a great influence on the adhesion performance with anchor muscles.
低温でのセメント材料用付着保持材として、特許第5740909号(特許文献1)には、コンクリート構造体をセメント系材料で補修するための下地処理材として温度5℃以下の環境下で使用するセメント材料用付着保持材であって、亜硝酸ナトリウム、亜硝酸リチウム、硝酸カルシウム、亜硝酸カルシウムからなる群より選ばれる物質が固形分濃度5〜50質量%で溶解している水溶液であることを特徴とする、セメント材料用付着保持材が記載されている。 As an adhesion-retaining material for cement materials at low temperatures, Patent No. 5740909 (Patent Document 1) states that cement used in an environment with a temperature of 5 ° C. or lower as a base treatment material for repairing a concrete structure with a cement-based material. It is an adhesion-retaining material for materials, and is characterized by being an aqueous solution in which a substance selected from the group consisting of sodium nitrite, lithium nitrite, calcium nitrate, and calcium nitrite is dissolved at a solid content concentration of 5 to 50% by mass. The adhesion-retaining material for cement materials is described.
また、特開昭62−235239号公報(特許文献2)には、セメント質物質とアルカリ金属硝酸塩、アルカリ土類金属硝酸塩、アルカリ金属亜硝酸塩及びアルカリ土類金属亜硝酸塩の群から選ばれた1種以上とを主成分とする素子の定着組成物であって、セメント質物質は、ポルトランド系セメント、アルミナセメント、スラグ系セメント及びこれらのセメントにCa0−Al203系の化合物を混合したものが開示されている。
さらに特開2018−080092号公報(特許文献3)には、水との接触により最高で10℃の作業温度及び/又は周辺温度で硬化する寒冷地用の水硬性組成物であって、ポルトランドセメント、アルミナセメント、及び急結剤を含有する水硬成分と、カオリンを主成分とする強度増進剤と、流動化剤と、凝結調整剤とを含み、前記ポルトランドセメントを20〜40質量部、前記アルミナセメントを30〜50質量部、前記急結剤を10〜30質量部、前記カオリンを1〜10質量部、前記凝結調整剤を0.1〜1質量部、前記流動化剤を0.1〜1質量部とする水硬性組成物が開示されている。
Further, in Japanese Patent Application Laid-Open No. 62-235239 (Patent Document 2), a cementy substance and an alkali metal nitrate, an alkaline earth metal nitrate, an alkali metal nitrite, and an alkaline earth metal nitrite selected from the group 1 a fixing composition of elements as a main component and seeds above, cementitious material was Portland cement, alumina cement, slag cement and Ca0-Al 2 0 3 based compounds in these cements were mixed Things are disclosed.
Further, Japanese Patent Application Laid-Open No. 2018-080092 (Patent Document 3) describes a hydraulic composition for cold regions that cures at a working temperature of up to 10 ° C. and / or an ambient temperature upon contact with water, and is Portland cement. , Alumina cement, a hydraulic component containing a quick-setting agent, a strength enhancer containing kaolin as a main component, a fluidizing agent, and a coagulation adjuster, and 20 to 40 parts by mass of the Portland cement. 30 to 50 parts by mass of alumina cement, 10 to 30 parts by mass of the quick-setting agent, 1 to 10 parts by mass of the kaolin, 0.1 to 1 part by mass of the coagulation adjuster, 0.1 part by mass of the fluidizing agent. A hydraulic composition having up to 1 part by mass is disclosed.
しかし、従来の無機系アンカー材料では、上記防凍剤を使用した場合に、圧縮強度の改善は得られるが、防凍剤の添加により流動性が悪くなり、また収縮率が増加して、アンカー材料に所望される施工性能(上向き施工時のダレ性)や力学特性(圧縮強度や引張強度)が低下してしまう。 However, in the conventional inorganic anchor material, when the above antifreeze is used, the compressive strength can be improved, but the addition of the antifreeze deteriorates the fluidity and increases the shrinkage rate, so that the anchor material can be used. The desired construction performance (sagging property during upward construction) and mechanical properties (compressive strength and tensile strength) are reduced.
そこで、氷点下の環境でも、可使時間を確保でき、ダレ性が少ない良好な施工性能を有するとともに、アンカー部材との付着性能に優れ、十分な圧縮強度を有する耐寒用無機系アンカー材料が所望されている。 Therefore, a cold-resistant inorganic anchor material that can secure the pot life even in a sub-zero environment, has good construction performance with little sagging property, has excellent adhesion performance to an anchor member, and has sufficient compressive strength is desired. ing.
本発明の目的は、上記課題を解決し、氷点下の環境でも適切な可使時間を確保でき、ダレ性が少ない良好な施工性能を有するとともに、アンカー筋等のアンカー部材との付着性能に優れ、当該アンカー材料とコンクリート構造物との付着強度を良好に維持することができる耐寒用無機系アンカー材料、特にあと施工アンカー材料を提供することである。
また、本発明の他の目的は、本発明の耐寒用無機系アンカー材料を用いて、寒冷環境下においてもアンカー部材を簡易に且つ有効に定着することができる、アンカー部材の固定方法を提供することである。
An object of the present invention is to solve the above problems, secure an appropriate pot life even in a sub-zero environment, have good construction performance with little sagging, and have excellent adhesion performance to anchor members such as anchor bars. It is an object of the present invention to provide an inorganic anchor material for cold resistance, particularly a post-installed anchor material, which can maintain good adhesion strength between the anchor material and a concrete structure.
Another object of the present invention is to provide a method for fixing an anchor member, which can easily and effectively fix the anchor member even in a cold environment by using the cold-resistant inorganic anchor material of the present invention. That is.
本発明は、氷点下の条件においても、特定のセメントと特定の防凍剤とを含み、防凍剤の含有量を特定することで、上記課題を解決することを見出し、本発明に到った。 The present invention has been found to solve the above problems by including a specific cement and a specific antifreeze agent even under sub-zero conditions and specifying the content of the antifreeze agent, and has arrived at the present invention.
請求項1記載の耐寒用無機系アンカー材料は、超速硬性バインダー及び亜硝酸塩を含み、超速硬性バインダーは、超速硬性鉱物としてのCA(CaO・Al2O3)を10〜50質量%及びC2AS(2CaO・Al2O3・SiO2)を3〜40質量%含み、C12A7(12CaO・7Al2O3)は実質的に含有せず、亜硝酸塩は、超速硬性バインダー100質量部に対して3〜13質量部で含有されることを特徴とする、耐寒用無機系アンカー材料である。
The cold-resistant inorganic anchor material according to
請求項2記載の耐寒用無機系アンカー材料は、上記耐寒用無機系アンカー材料において、亜硝酸塩は、亜硝酸リチウム、亜硝酸カルシウム及び亜硝酸ナトリウムから成る群より選ばれる少なくとも1種であることを特徴とする、耐寒用無機系アンカー材料である。
The cold-resistant inorganic anchor material according to
請求項3記載の耐寒用無機系アンカー材料は、上記いずれかの耐寒用無機系アンカー材料において、−10℃における圧縮強度がJIS A 1108の「コンクリート圧縮強さ試験」に準拠して測定して29.4N/mm2以上で、―10℃におけるアンカー部材の付着強度がJCAAの「あと施工アンカー試験方法」に準拠して測定して10.9N/mm2以上であることを特徴とする、耐寒用無機系アンカー材料である。 The cold-resistant inorganic anchor material according to claim 3 has a compressive strength at −10 ° C. measured in accordance with JIS A 1108 “Concrete Compressive Strength Test” in any of the above cold-resistant inorganic anchor materials. 29.4 N / mm 2 or more, and the adhesive strength of the anchor member at −10 ° C. is 10.9 N / mm 2 or more as measured in accordance with JCAA's “Post-installed Anchor Test Method”. It is an inorganic anchor material for cold resistance.
請求項4記載のアンカー部材の固定方法は、上記いずれかの耐寒用無機系アンカー材料を、カートリッジに内包し、該カートリッジを注入ガンに取り付けて、当該耐寒用無機系アンカー材料をコンクリート構造物の孔に充填して硬化させてアンカー部材を固定することを特徴とする、アンカー部材の固定方法である。 The method for fixing the anchor member according to claim 4 is to enclose any of the above-mentioned cold-resistant inorganic anchor materials in a cartridge, attach the cartridge to an injection gun, and attach the cold-resistant inorganic anchor material to a concrete structure. It is a method of fixing an anchor member, which comprises filling a hole and hardening the anchor member to fix the anchor member.
本発明の耐寒用無機系アンカー材料は、超速硬性バインダーと亜硝酸塩とを組み合わせることにより、氷点下の環境においても適切な可使時間を有し、ダレ性等の施工性に優れるため、上向き施工においても有効に使用でき、高い圧縮強度を有し、アンカー部材との優れた付着強度を保持することが可能となる。
また本発明のアンカー部材の固定方法は、寒冷環境下においても、コンクリート構造物の孔に充填した該無機系アンカー材料が垂れることなく、効率よく簡単に施工することができる。
また特に、アンカー用カートリッジ等の注入容器を用いることで、耐寒用無機系アンカー材料の撹拌混合作業と充填作業を同一の容器で行うこともでき、撹拌混合作業中の粉塵の発生をほぼゼロに抑えられ、孔内充填、特に上向き充填を簡便に行うことが可能となる。
The cold-resistant inorganic anchor material of the present invention has an appropriate pot life even in a sub-zero environment by combining an ultrafast-hardening binder and a nitrite, and has excellent workability such as sagging property. Can be effectively used, has high compressive strength, and can maintain excellent adhesion strength with the anchor member.
Further, the method for fixing the anchor member of the present invention can be efficiently and easily applied even in a cold environment without the inorganic anchor material filled in the holes of the concrete structure dripping.
In particular, by using an injection container such as an anchor cartridge, it is possible to perform the stirring and mixing work and the filling work of the cold-resistant inorganic anchor material in the same container, and the generation of dust during the stirring and mixing work is almost zero. It is suppressed, and it becomes possible to easily perform filling in the hole, particularly upward filling.
本発明を次の形態により説明するが、これらに限定されるものではない。
本発明の耐寒用無機系アンカー材料は、超速硬性バインダー及び亜硝酸塩を含み、前記超速硬性バインダーは、超速硬性鉱物としてのCAを10〜50質量%、C2ASを3〜40質量%含み、C12A7は実質的に含有せず、亜硝酸塩は、超速硬性バインダー100質量部に対して3〜13質量部で含有される、耐寒用無機系アンカー材料である。
The present invention will be described in the following form, but the present invention is not limited thereto.
The cold-resistant inorganic anchor material of the present invention contains an ultrafast-hardening binder and a nitrite, and the ultrafast-hardening binder contains 10 to 50% by mass of CA as an ultrafast-hardening mineral, 3 to 40% by mass of C2AS, and C12A7. Nitrite is a cold-resistant inorganic anchor material that is substantially free and is contained in an amount of 3 to 13 parts by mass with respect to 100 parts by mass of the ultrafast-hardening binder.
通常、超速硬性鉱物としては、CA、C2AS及びC12A7が該当するが、本発明においては、超速硬性バインダー中にはCA及びC2ASが含まれ、C12A7は実質的に含まれない。超速硬性バインダー中に含まれるCA及びC2ASの含有量は、CAが10〜50質量%、C2ASが3〜40質量%である。
かかる範囲でCA及びC2ASを含有し、更にC12A7を実質的に含有しないことにより、本発明の上記効果を有効に発現することができる。
ここでC12A7を実質的に含有しないとは、仮に含まれたとしても1質量%未満であることを意味し、好ましくは0%である。
C12A7を1質量%以上で含むと、適切な可使時間を確保できず、施工性は十分ではなくなる場合があり望ましくない。
Usually, CA, C2AS and C12A7 correspond to the ultrafast-hardening mineral, but in the present invention, CA and C2AS are contained in the ultrafast-hardening binder, and C12A7 is substantially not contained. The contents of CA and C2AS contained in the ultrafast-hardening binder are 10 to 50% by mass for CA and 3 to 40% by mass for C2AS.
By containing CA and C2AS in such a range and substantially not containing C12A7, the above-mentioned effect of the present invention can be effectively exhibited.
Here, the fact that C12A7 is substantially not contained means that even if it is contained, it is less than 1% by mass, and is preferably 0%.
If C12A7 is contained in an amount of 1% by mass or more, an appropriate pot life cannot be secured, and workability may not be sufficient, which is not desirable.
また、超速硬性バインダー中には、CAが10〜50質量%含まれるとともにC2ASが3〜40質量%含まれる。かかる含有範囲を逸脱すると、氷点下の環境でのコンクリート構造物との付着性が劣り、適切な可使時間が得られず施工性が劣ることとなる。 Further, the ultrafast-hardening binder contains 10 to 50% by mass of CA and 3 to 40% by mass of C2AS. If it deviates from such a content range, the adhesiveness to the concrete structure in the environment below the freezing point is inferior, the appropriate pot life cannot be obtained, and the workability is inferior.
かかる超速硬性バインダーとして、CAが10〜50質量%、C2ASが3〜40質量%含まれ、C12A7は実質的に含有されない超速硬性バインダーが得られるのであれば、超速硬セメントを超速硬性バインダーとして含むこともできる。 As such an ultrafast-hardening binder, if an ultrafast-hardening binder containing 10 to 50% by mass of CA and 3 to 40% by mass of C2AS and substantially not containing C12A7 can be obtained, ultrafast-hardening cement is contained as the ultrafast-hardening binder. You can also do it.
一例としての従来のポルトランドセメントを用いるアンカー材料は、凝結時間が長く、特に横向きや上向きの孔に充填する場合には、時間の経過とともに、アンカー材料が孔から垂れてきたり、次工程までの移行時間が長くなっていたが、本発明においては、氷点下の環境においても適切な可使時間を確保するとともにダレ性に優れるため、このような問題は生じない。 Anchor materials using conventional Portland cement as an example have a long setting time, and especially when filling sideways or upward holes, the anchor material may hang down from the holes or shift to the next process over time. Although the time has been long, in the present invention, such a problem does not occur because an appropriate pot life is secured even in a sub-zero environment and the sagging property is excellent.
また本発明の耐寒用無機系アンカー材料には、前記超速硬性バインダーと組み合わせて、亜硝酸塩を必須成分として含有する。
本発明の耐寒用無機系アンカー材料に用いる亜硝酸塩としては、特に限定されず、任意の亜硝酸塩を含むことができるが、好ましくは、亜硝酸リチウム、亜硝酸カルシウム及び亜硝酸ナトリウムから成る群より選ばれる少なくとも1種の亜硝酸塩を用いることが、本発明の上記効果を更に有効に発現するために望ましい。
また、亜硝酸塩の粒度は特に限定されず、またその配合量は、上記超速硬性バインダー100質量部に対して3〜13質量部であり、好ましくは3.5〜12.5質量部である。
かかる範囲で超速硬性バインダーと亜硝酸塩とを組み合わせて用いることにより、氷点下における環境においても、施工性に優れ、圧縮強度や付着(引張)強度を良好に保持することが可能となる。
なお、かかる亜硝酸塩は、混練水に予め配合して溶解させておくことが望ましい。
Further, the cold-resistant inorganic anchor material of the present invention contains nitrite as an essential component in combination with the ultrafast-hardening binder.
The nitrite used in the cold-resistant inorganic anchor material of the present invention is not particularly limited and may contain any nitrite, but is preferably from the group consisting of lithium nitrite, calcium nitrite and sodium nitrite. It is desirable to use at least one selected nitrite in order to more effectively exhibit the above-mentioned effects of the present invention.
The particle size of the nitrite is not particularly limited, and the blending amount thereof is 3 to 13 parts by mass, preferably 3.5 to 12.5 parts by mass with respect to 100 parts by mass of the ultrafast-hardening binder.
By using the ultrafast-hardening binder and the nitrite in combination within such a range, it is possible to have excellent workability even in an environment below freezing point, and to maintain good compressive strength and adhesion (tensile) strength.
It is desirable that the nitrite is previously mixed and dissolved in kneading water.
従来は、防凍剤として、尿素、エチレングリコール、硝酸カルシウム等を用いていたが、本発明においては、これらの防凍剤は含まれない。 Conventionally, urea, ethylene glycol, calcium nitrate and the like have been used as the antifreeze agent, but in the present invention, these antifreeze agents are not included.
本発明の耐寒用無機系アンカー材料には、骨材が含有されるが、骨材としては特に限定されず、コンクリートやモルタルに用いられる一般的な細骨材を好適に用いることができる。
細骨材としては、川砂、海砂、山砂、砕砂等の天然細骨材、再生細骨材、人工細骨材を例示することができる。
細骨材の配合割合は、特に限定されず、現場での所望する要求に応じて、任意に配合することができるが、好適には、超速硬性バインダー100質量部に対して、好ましくは30〜200質量部、より好ましくは40〜100質量部であり、細骨材の最大寸法は1.2mmであることが望ましい。
The cold-resistant inorganic anchor material of the present invention contains an aggregate, but the aggregate is not particularly limited, and a general fine aggregate used for concrete or mortar can be preferably used.
Examples of the fine aggregate include natural fine aggregates such as river sand, sea sand, mountain sand, and crushed sand, recycled fine aggregates, and artificial fine aggregates.
The blending ratio of the fine aggregate is not particularly limited and can be arbitrarily blended according to the desired requirements in the field, but preferably, it is preferably 30 to 30 parts by mass with respect to 100 parts by mass of the ultrafast-hardening binder. It is preferably 200 parts by mass, more preferably 40 to 100 parts by mass, and the maximum size of the fine aggregate is 1.2 mm.
更に、水を配合して本発明の耐寒用無機系アンカー材料を得るが、水は、水/超速硬性バインダー質量比で好ましくは30〜50、より好ましくは35〜45である。30未満であるとバインダー粉体と水とが不均一となりノズルからの排出が困難となり、50を超えると充填した材料が孔から流出したり、ダレ性や付着強度が低下するため好ましくない。 Further, water is blended to obtain the cold-resistant inorganic anchor material of the present invention. Water is preferably 30 to 50, more preferably 35 to 45 in terms of water / ultrafast-hardening binder mass ratio. If it is less than 30, the binder powder and water become non-uniform and it becomes difficult to discharge from the nozzle, and if it exceeds 50, the filled material flows out from the pores, and the sagging property and the adhesion strength are lowered, which is not preferable.
本発明の耐寒用無機系アンカー材料には、必要に応じて、公知の混和剤や添加剤、例えば減水剤、遅延剤、ポリマー、防錆剤、凝結遅延剤等を、本発明の効果を害さない範囲で添加することができる。 For the cold-resistant inorganic anchor material of the present invention, if necessary, known admixtures and additives such as water reducing agents, retarding agents, polymers, rust preventives, coagulation retarding agents, etc. are used to impair the effects of the present invention. It can be added in a range that does not exist.
本発明の耐寒用無機系アンカー材料は、予め、超速硬性バインダーと亜硝酸塩等の粉末体を配合し、それに細骨材や水を配合して均一に混練することで製造することもできるが、好ましくは予め亜硝酸塩を混練水に溶解し、超速硬性バインダーと、亜硝酸塩水溶液と、骨材等の各材料を現場で配合して、任意のミキサーを用いて混練することで製造することも可能であり、均一な材料が調製できればその方法は限定されない。 The cold-resistant inorganic anchor material of the present invention can also be produced by preliminarily blending an ultrafast-hardening binder and a powder such as nitrite, and then blending fine aggregate and water and kneading them uniformly. It is also possible to preferably manufacture by dissolving nitrite in kneading water in advance, blending an ultrafast-hardening binder, an aqueous solution of nitrite, and each material such as aggregate on site, and kneading them using an arbitrary mixer. The method is not limited as long as a uniform material can be prepared.
本発明の耐寒用無機系アンカー材料は、特に氷点下の環境で、例えば、既設のコンクリート構造物にアンカー部材を固定するのに用いられる。
具体的には、コンクリート構造物に表面より穿孔し、該孔に本発明の耐寒用無機系アンカー材料を充填し、アンカー筋を挿入して、該耐寒用無機系アンカー材料を硬化させて、アンカー部材を固定させる。
孔への耐寒用無機系アンカー材料の充填方法は、特に限定されず、公知の方法を適用することができるが、施工の容易性より、例えば、カートリッジに当該アンカー材料を充填し、該カートリッジを注入ガンと称される吐出機に取り付けて、ノズルから当該アンカー材料を孔の奥に注入して硬化させる方法を好適に用いることができる。
また、アンカー材料として本発明の耐寒用無機系アンカー材料を用いているため、氷点下の環境でも、適切な可使時間を保持し、注入した当該アンカー材料が垂れてくることがなく、迅速にアンカー部材を固定することができる。
The cold-resistant inorganic anchor material of the present invention is used, for example, for fixing an anchor member to an existing concrete structure in a sub-zero environment.
Specifically, a concrete structure is perforated from the surface, the hole is filled with the cold-resistant inorganic anchor material of the present invention, an anchor streak is inserted, and the cold-resistant inorganic anchor material is cured to anchor. Fix the member.
The method for filling the holes with the cold-resistant inorganic anchor material is not particularly limited, and a known method can be applied. However, for ease of construction, for example, the cartridge is filled with the anchor material, and the cartridge is filled. A method of mounting the anchor material on a discharger called an injection gun and injecting the anchor material into the hole to cure the anchor material can be preferably used.
In addition, since the cold-resistant inorganic anchor material of the present invention is used as the anchor material, an appropriate pot life is maintained even in a sub-zero environment, and the injected anchor material does not drip and is quickly anchored. The member can be fixed.
カートリッジや注入ガンは、任意の公知のものを用いることができ、例えば、シーリングガンまたはコーキングガンは、カートリッジを装着するカートリッジ用ガンとして使用することができる。 Any known cartridge or injection gun can be used, and for example, a sealing gun or a caulking gun can be used as a cartridge gun for mounting a cartridge.
本発明の耐寒用無機系アンカー材料は、下記試験例に記載したように、氷点下、例えば−10℃の温度下において、JASS15 M103(セルフレベリング材の品質基準試験)に準じて測定したダレ性のフロー試験値が70mm以下であり、可使時間も下記試験例の方法で測定して31〜80分と適切であり、またJIS A 1108「コンクリート圧縮強さ試験」に準じて測定した圧縮強度が29.4N/mm2以上であり、また、JCAAの「あと施工アンカー試験方法」に準拠して測定したアンカー筋の引張強度が10.9N/mm2以上とすることが可能となる。
本発明のアンカー部材の固定方法は、氷点下の環境においても、適切な可使時間を有し、材料ダレすることなく施工性に優れ、初期凍害を受けることなく強度を発現し、アンカー部材の付着性能を著しく向上させることができる。
As described in the following test example, the cold-resistant inorganic anchor material of the present invention has a sagging property measured according to JASS15 M103 (quality standard test of self-leveling material) at a temperature below freezing point, for example, -10 ° C. The flow test value is 70 mm or less, the pot life is also appropriate as 31 to 80 minutes measured by the method of the following test example, and the compressive strength measured according to JIS A 1108 "Concrete compressive strength test" is is at 29.4N / mm 2 or more, and it is possible that the tensile strength of the anchor muscle was measured according to "post-installed anchor test method" of JCAA is to 10.9N / mm 2 or more.
The method for fixing an anchor member of the present invention has an appropriate pot life even in a sub-zero environment, has excellent workability without material sagging, exhibits strength without being subjected to initial frost damage, and adheres to the anchor member. Performance can be significantly improved.
本発明を次の実施例、比較例及び試験例に基づき説明する。
(1)原材料
無機系アンカー材料を調製するにあたり、以下の各原材料を用いた。
・超速硬性バインダー:表1及び表2に示す超速硬性鉱物組成を有するもの
・普通ポルトランドセメント:住友大阪セメント(株)製
・早強ポルトランドセメント:住友大阪セメント(株)製
・防凍剤:亜硝酸リチウム(日産化学工業(株)製)
亜硝酸カリウム(関東化学(株)製)
亜硝酸ナトリウム(関東化学(株)製)
尿素:(関東化学(株)製)
硝酸カルシウム:(関東化学(株)製)
・細骨材(B):6号砂
・混練水(W):水道水
・増粘剤:メチルセルロース系増粘剤(2%水溶液、粘度:4000mPa・s) ハイメトローズ90:(信越化学工業(株)製)
The present invention will be described with reference to the following examples, comparative examples and test examples.
(1) Raw materials In preparing the inorganic anchor material, the following raw materials were used.
・ Ultra-fast-hardening binder: Those having the ultra-fast-hardening mineral composition shown in Tables 1 and 2. ・ Ordinary Portland cement: manufactured by Sumitomo Osaka Cement Co., Ltd. ・ Early-strength Portland cement: manufactured by Sumitomo Osaka Cement Co., Ltd. ・ Antifreeze: nitrite Lithium (manufactured by Nissan Chemical Industry Co., Ltd.)
Potassium nitrite (manufactured by Kanto Chemical Co., Inc.)
Sodium nitrite (manufactured by Kanto Chemical Co., Inc.)
Urea: (manufactured by Kanto Chemical Co., Inc.)
Calcium nitrate: (manufactured by Kanto Chemical Co., Inc.)
-Fine aggregate (B): No. 6 sand-Kneading water (W): Tap water-Thickening agent: Methyl cellulose-based thickener (2% aqueous solution, viscosity: 4000 mPa · s) Himetro's 90: (Shin-Etsu Chemical Co., Ltd.) ) Made)
(2)実施例1〜15及び比較例1〜16
上記各原材料を用いて、表1及び表2に示す配合比で各原材料を配合して、各無機系アンカー材料を調製した。
具体的には、混練水に予め上記各防凍剤を溶解して各水溶液を調製した。
表1及び2に示す超速硬性バインダーと、骨材と、増粘剤と、調製した上記各水溶液とを、表1及び表2に示す配合割合で混錬して、各無機系アンカー材料を調製した。
(2) Examples 1 to 15 and Comparative Examples 1 to 16
Using each of the above raw materials, each raw material was blended at the blending ratios shown in Tables 1 and 2, and each inorganic anchor material was prepared.
Specifically, each aqueous solution was prepared by dissolving each of the above antifreeze agents in kneaded water in advance.
The ultrafast-hardening binder shown in Tables 1 and 2, the aggregate, the thickener, and each of the prepared aqueous solutions are kneaded at the blending ratios shown in Tables 1 and 2 to prepare each inorganic anchor material. bottom.
(3)試験例
以下の試験は、−10℃、−5℃、0℃の寒冷温度下で実施した。
(試験例1)施工性/ダレ性
上記各実施例及び比較例で得られた練り混ぜ直後の各無機系アンカー材料を用いて、JASS15 M103「セルフレベリング材の品質基準試験」に準じ、図1に示すようにしてφ50mm×h51mmフロー試験により評価した。
その結果を、表1及び表2に示す。
なお、以下の評価基準で評価した。
〇:70mm以下
△:71〜75mm
×:76mm以上
(3) Test example The following tests were carried out under cold temperatures of -10 ° C, -5 ° C, and 0 ° C.
(Test Example 1) Workability / Dripping property Using each inorganic anchor material immediately after kneading obtained in each of the above Examples and Comparative Examples, according to JASS15 M103 “Quality standard test of self-leveling material”, FIG. It was evaluated by a φ50 mm × h51 mm flow test as shown in.
The results are shown in Tables 1 and 2.
The evaluation was based on the following evaluation criteria.
〇: 70 mm or less Δ: 71-75 mm
×: 76 mm or more
(試験例2)施工性/可使時間
上記各実施例及び比較例で得られた練り混ぜ直後の各無機系アンカー材料を用いて、市販のシーリングガン用のカートリッジ樹脂製注入器(330mlタイプ:エーディーワイ(株)製)に充填し、前記カートリッジに注入用ノズル(φ12mm)を取付けて、当該注入器からの排出可能時間を評価した。
その結果を、表1及び表2に示す。
なお、以下の評価基準で評価した。・
〇:30〜80分(適切)
△:20分〜30分未満
×:20分未満または80分を超える
(Test Example 2) Workability / Potability Time A commercially available cartridge resin injector for a sealing gun (330 ml type:) using each inorganic anchor material immediately after kneading obtained in each of the above Examples and Comparative Examples. It was filled in ADY Co., Ltd., and an injection nozzle (φ12 mm) was attached to the cartridge, and the discharge possible time from the injector was evaluated.
The results are shown in Tables 1 and 2.
The evaluation was based on the following evaluation criteria.・
〇: 30-80 minutes (appropriate)
Δ: 20 minutes to less than 30 minutes ×: Less than 20 minutes or more than 80 minutes
(試験例3)機械的強度/圧縮強度
JIS A 1108「コンクリート圧縮強さ試験」に準拠して圧縮強度試験を実施した。
具体的には、φ50×100mmに各無機系アンカー材料を成形し、上記の各温度で養生し、材齢28日における圧縮強度を測定した、
その結果を、表1及び表2に示す。
なお、以下の評価基準で評価した。
〇:29.4N/mm2以上
×:29.4N/mm2未満
(Test Example 3) Mechanical Strength / Compressive Strength A compressive strength test was carried out in accordance with JIS A 1108 “Concrete Compressive Strength Test”.
Specifically, each inorganic anchor material was molded into φ50 × 100 mm, cured at each of the above temperatures, and the compressive strength at the age of 28 days was measured.
The results are shown in Tables 1 and 2.
The evaluation was based on the following evaluation criteria.
〇: 29.4N / mm 2 or more ×: 29.4N / mm less than 2
(試験例4)機械的強度/引張強度(アンカー筋との付着性)
鋼管に打設したコンクリートに、φ16mmの孔を形成し、各無機系アンカー材料を注入して、全ねじボルトM12(材質SNB7)を定着させて、JCAAの「あと施工アンカー試験」に準じて、引張(付着)強度試験を実施した。
付着試験におけるアンカー筋等の条件は以下のとおりである。
・アンカー筋:M12
・種類:SNB7
・埋め込み長さ:84mm(7da)
・アンカー筋直径:12mm
・穿孔径:φ16mm
・母材コンクリート:鋼管打ち込みコンクリート(σB=25N/mm2)
(Test Example 4) Mechanical strength / tensile strength (adhesion with anchor muscle)
A hole of φ16 mm is formed in the concrete placed in the steel pipe, each inorganic anchor material is injected, and all screw bolts M12 (material SNB7) are fixed, and according to JCAA's "Post-installed anchor test", A tensile (adhesion) strength test was carried out.
The conditions such as anchor muscles in the adhesion test are as follows.
・ Anchor muscle: M12
・ Type: SNB7
-Embedding length: 84 mm (7 da)
・ Anchor muscle diameter: 12 mm
・ Drilling diameter: φ16 mm
・ Base concrete: Steel pipe driven concrete (σB = 25N / mm 2 )
具体的には、図2に示すような試験装置を用い、上記各実施例及び比較例で得られた無機系アンカー材料を、φ16mmの孔に注入して前記全ねじボルトM12で定着させたものを上記の各温度の恒温槽に28日間入れて、その後引張強度試験を実施した。
アンカー筋である全ねじボルトM12を孔から引き抜く際の最大荷重Aを測定した。
次いで、最大荷重Aと付着面積Bとから引張(付着)強度Cを算出した。
なお、付着面積B及び引張(付着)強度Cは、下記式(1)及び(2)により算出した。
付着面積B=アンカー筋の直径D×π×定着長(埋め込み深さ)L・・・(1)
引張強度C=最大荷重A/付着面積B・・・(2)
その結果を、表1及び表2に示す。
また、以下の評価基準で評価した。
〇:10.9N/mm2以上
×:10.9N/mm2未満
Specifically, using a test device as shown in FIG. 2, the inorganic anchor materials obtained in the above Examples and Comparative Examples were injected into a hole having a diameter of 16 mm and fixed with the full screw bolt M12. Was placed in a constant temperature bath at each of the above temperatures for 28 days, and then a tensile strength test was carried out.
The maximum load A when the full-thread bolt M12, which is the anchor bar, was pulled out from the hole was measured.
Next, the tensile (adhesion) strength C was calculated from the maximum load A and the adhesion area B.
The adhesion area B and the tensile (adhesion) strength C were calculated by the following formulas (1) and (2).
Adhesion area B = Anchor muscle diameter D x π x anchoring length (embedding depth) L ... (1)
Tensile strength C = maximum load A / adhesion area B ... (2)
The results are shown in Tables 1 and 2.
In addition, the evaluation was made according to the following evaluation criteria.
〇: 10.9N / mm 2 or more ×: 10.9N / mm Less than 2
(総合評価)
上記試験例1〜4の評価の中で、すべての評価が〇のものを総合評価〇とし、評価の少なくとも一つが×のものは総合評価×とし、×の評価はないが△の評価が一つあり他の評価結果は〇のものを総合評価△として、その総合評価の結果も表1及表2に示す。
(comprehensive evaluation)
Among the evaluations of Test Examples 1 to 4, those with all evaluations of 〇 are evaluated as overall evaluation 〇, those with at least one evaluation of × are evaluated as overall evaluation ×, and there is no evaluation of ×, but evaluation of △ is one. As for the other evaluation results, those with ◯ are designated as comprehensive evaluation Δ, and the results of the comprehensive evaluation are also shown in Tables 1 and 2.
上記表1及び2より、本発明の実施例の無機系アンカー材料は、氷点下の環境においてもダレ性は良好で、適切な可使時間を有し、アンカー筋の引張強度等を良好に保持することが可能であることがわかる。
一方、無機系アンカー材料に含まれる超速硬性バインダー中の超速硬性鉱物組成が、本発明の範囲外の比較例1〜5では、氷点下の環境においては、適切な可使時間を有することができないか、機械的強度が十分でないことが明らかである。
From Tables 1 and 2 above, the inorganic anchor material of the embodiment of the present invention has good sagging property even in a sub-zero environment, has an appropriate pot life, and maintains good tensile strength and the like of the anchor muscle. It turns out that it is possible.
On the other hand, in Comparative Examples 1 to 5 in which the composition of the ultrafast-hardening mineral in the ultrafast-hardening binder contained in the inorganic anchor material is outside the scope of the present invention, is it possible to have an appropriate pot life in a sub-zero environment? It is clear that the mechanical strength is not sufficient.
また、亜硝酸塩の含有割合が本発明の範囲外の比較例6〜7、本発明の亜硝酸塩以外の防凍剤を含む8〜13、防凍剤を含まない比較例14、本発明の超速硬性バインダーを含まない比較例15〜16のアンカー材料は、氷点下の環境においては、施工性が悪いか、機械的強度が十分でないことが明らかである。 Further, Comparative Examples 6 to 7 in which the content ratio of the nitrite is outside the range of the present invention, 8 to 13 containing an antifreeze agent other than the nitrite of the present invention, Comparative Example 14 not containing the antifreeze agent, and the ultrafast-hardening binder of the present invention. It is clear that the anchor materials of Comparative Examples 15 to 16 not containing the above-mentioned materials have poor workability or insufficient mechanical strength in a sub-freezing environment.
本発明の耐寒用無機系アンカー材料は、寒冷場所における建築・土木分野におけるコンクリート構造物に設けた孔に、アンカー筋等のアンカー部材を強固に付着させることができ、適切な可使時間を有するため施工の作業効率が高く、特に寒冷地における構造物に有効に適用することができる。
The cold-resistant inorganic anchor material of the present invention can firmly attach an anchor member such as an anchor bar to a hole provided in a concrete structure in the field of construction / civil engineering in a cold place, and has an appropriate pot life. Therefore, the work efficiency of construction is high, and it can be effectively applied to structures especially in cold regions.
Claims (4)
The cold-resistant inorganic anchor material according to any one of claims 1 to 3 is encapsulated in a cartridge, the cartridge is attached to an injection gun, and the cold-resistant inorganic anchor material is filled in a hole of a concrete structure. A method for fixing an anchor member, which comprises curing and fixing the anchor member.
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