JP2021132701A - Nonwoven fabric for absorbent article and absorbent article - Google Patents
Nonwoven fabric for absorbent article and absorbent article Download PDFInfo
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- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 137
- 230000002745 absorbent Effects 0.000 title claims abstract description 53
- 239000002250 absorbent Substances 0.000 title claims abstract description 53
- 239000000835 fiber Substances 0.000 claims abstract description 196
- 239000000470 constituent Substances 0.000 claims abstract description 37
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000004698 Polyethylene Substances 0.000 claims abstract description 13
- 229920000573 polyethylene Polymers 0.000 claims abstract description 13
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 12
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 12
- -1 polyethylene Polymers 0.000 claims abstract description 11
- 239000004743 Polypropylene Substances 0.000 claims abstract description 6
- 229920001155 polypropylene Polymers 0.000 claims abstract description 6
- 230000006835 compression Effects 0.000 abstract description 11
- 238000007906 compression Methods 0.000 abstract description 11
- 238000000034 method Methods 0.000 description 29
- 238000010438 heat treatment Methods 0.000 description 23
- 238000011084 recovery Methods 0.000 description 20
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- 238000002844 melting Methods 0.000 description 11
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- 239000004416 thermosoftening plastic Substances 0.000 description 11
- 239000002131 composite material Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002994 raw material Substances 0.000 description 7
- 238000001878 scanning electron micrograph Methods 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 6
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- 239000008358 core component Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 238000007664 blowing Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 3
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- 238000012546 transfer Methods 0.000 description 3
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229920000433 Lyocell Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 2
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- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- 125000003821 2-(trimethylsilyl)ethoxymethyl group Chemical group [H]C([H])([H])[Si](C([H])([H])[H])(C([H])([H])[H])C([H])([H])C(OC([H])([H])[*])([H])[H] 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- IDCBOTIENDVCBQ-UHFFFAOYSA-N TEPP Chemical compound CCOP(=O)(OCC)OP(=O)(OCC)OCC IDCBOTIENDVCBQ-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000002175 menstrual effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Nonwoven Fabrics (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Abstract
Description
本発明は、吸収性物品用不織布及びこれを備える吸収性物品に関する。 The present invention relates to a non-woven fabric for an absorbent article and an absorbent article comprising the same.
使い捨ておむつ等の吸収性物品は、一般的に、圧縮された包装形態で流通されている。包装形態から開封された後において柔らかさやクッション感を得る観点から、吸収性物品は、その嵩が回復することが望まれている。そのため、吸収性物品に用いられる不織布として、嵩高性及び嵩回復性に優れるものが検討されている。例えば、特許文献1には、所定の芯成分及び鞘成分を有し、且つスパイラル状に捲縮された偏心芯鞘型複合繊維ウェブからなる不織布であって、繊維間相互が熱接着されてなる比容積、及び24時間圧縮直後の厚さ回復率それぞれが所定の範囲である、嵩回復性に優れたシートが開示されている。 Absorbent articles such as disposable diapers are generally distributed in compressed packaging. From the viewpoint of obtaining softness and cushioning feeling after being opened from the package form, it is desired that the bulk of the absorbent article is restored. Therefore, as a non-woven fabric used for an absorbent article, a non-woven fabric having excellent bulkiness and bulk recovery property has been studied. For example, Patent Document 1 describes a non-woven fabric having a predetermined core component and sheath component and made of an eccentric core-sheath composite fiber web that is spirally crimped, and the fibers are heat-bonded to each other. A sheet having excellent bulk recovery is disclosed in which the specific volume and the thickness recovery rate immediately after compression for 24 hours are each within a predetermined range.
また、本出願人は、先に、エラストマー成分を所定量含む繊維集合体、又は規則的に配列された多数の凸部が形成されている繊維集合体からなり、坪量が15〜100g/m2であり、無荷重厚みが1〜10mmであり、圧縮回復率が60%以上である圧縮回復性シートを提案している(特許文献2、3)。 Further, the applicant is composed of a fiber aggregate containing a predetermined amount of an elastomer component or a fiber aggregate in which a large number of regularly arranged convex portions are formed, and has a basis weight of 15 to 100 g / m. No. 2 , a compression recovery sheet having a no-load thickness of 1 to 10 mm and a compression recovery rate of 60% or more has been proposed (Patent Documents 2 and 3).
空気などの熱風や水蒸気を繊維ウエブに吹き付けることで製造されたエアスルー不織布は、製造直後では、ふっくらとしたクッション感を有している。しかしながら、エアスルー不織布を吸収性物品の構成部材に用いた場合、前述した包装形態で封入されると、圧縮により本来のクッション感を生じ難い傾向にある。特許文献1〜3に記載の各シートは、厚み(嵩)の回復性が考慮されているものの、当該厚みの回復性について更なる改善の余地があった。 The air-through non-woven fabric produced by blowing hot air such as air or water vapor onto the fiber web has a fluffy cushioning feeling immediately after production. However, when the air-through non-woven fabric is used as a constituent member of the absorbent article, when it is sealed in the above-mentioned packaging form, it tends to be difficult to generate the original cushioning feeling by compression. Although the recoverability of the thickness (bulk) of each of the sheets described in Patent Documents 1 to 3 is taken into consideration, there is room for further improvement in the recoverability of the thickness.
本発明の課題は、圧縮に対する厚みの回復性に優れ、クッション性が良好な吸収性物品用不織布及びこれを備える吸収性物品を提供することに関する。 An object of the present invention is to provide a non-woven fabric for an absorbent article having excellent thickness recovery with respect to compression and good cushioning property, and an absorbent article having the same.
本発明は、エアスルー不織布からなる吸収性物品用不織布であって、
非伸縮性繊維からなり、該非伸縮性繊維が、繊維径が15μm以下である細繊維を含んでおり、
全ての構成繊維に対する、前記細繊維の割合が30%以上であり、
坪量が30g/m2以下であり、両面が平坦であり、30cN/cm2の荷重を24時間印加後の厚みが1.6mm以上である、吸収性物品用不織布を提供するものである。
The present invention is a non-woven fabric for absorbent articles made of an air-through non-woven fabric.
It is composed of non-stretchable fibers, and the non-stretchable fibers contain fine fibers having a fiber diameter of 15 μm or less.
The ratio of the fine fibers to all the constituent fibers is 30% or more.
Provided is a non-woven fabric for absorbent articles having a basis weight of 30 g / m 2 or less, flat surfaces on both sides, and a thickness of 1.6 mm or more after applying a load of 30 cN / cm 2 for 24 hours.
また本発明は、前記吸収性物品用不織布を構成部材として備える、吸収性物品を提供するものである。 The present invention also provides an absorbent article comprising the non-woven fabric for the absorbent article as a constituent member.
本発明によれば、圧縮に対する厚みの回復性に優れ、クッション性が良好な吸収性物品用不織布及びこれを備える吸収性物品が提供される。 According to the present invention, there is provided a non-woven fabric for an absorbent article having excellent thickness recovery with respect to compression and good cushioning property, and an absorbent article having the same.
以下本発明を、その好ましい実施形態に基づき図面を参照しながら説明する。
本実施形態の吸収性物品用不織布(以下、単に「不織布」ともいう)は、エアスルー不織布である。「エアスルー不織布」とは、所定温度以上の流体、例えば気体や水蒸気を、不織布の前駆体である繊維ウエブ又は不織布に吹き付ける工程(エアスルー工程)を経て製造された不織布をいう。斯かる流体の吹き付けは、熱風等の流体が繊維ウエブ又は不織布を貫通する、いわゆるエアスルー方式(貫通方式)で行われる。本発明のエアスルー不織布には、斯かるエアスルー方式による熱処理工程のみで製造される不織布のみならず、他の方法で作製された不織布に該熱処理工程を付加して製造した不織布、あるいはエアスルー工程の後に何らかの工程を行って製造した不織布が包含される。
Hereinafter, the present invention will be described based on the preferred embodiment with reference to the drawings.
The non-woven fabric for absorbent articles of the present embodiment (hereinafter, also simply referred to as “nonwoven fabric”) is an air-through non-woven fabric. The "air-through non-woven fabric" refers to a non-woven fabric produced through a step (air-through step) of spraying a fluid having a temperature equal to or higher than a predetermined temperature, for example, gas or water vapor, onto a fiber web or a non-woven fabric which is a precursor of the non-woven fabric. The spraying of such a fluid is performed by a so-called air-through method (penetration method) in which a fluid such as hot air penetrates the fiber web or the non-woven fabric. The air-through non-woven fabric of the present invention includes not only the non-woven fabric produced only by the heat treatment step by the air-through method, but also the non-woven fabric manufactured by adding the heat treatment step to the non-woven fabric produced by another method, or after the air-through step. Nonwoven fabrics manufactured by performing some process are included.
本実施形態の不織布は、構成繊維どうしの交点が熱融着した熱融着部を複数有している。斯かる熱融着部は、構成繊維どうしが接する部分に形成されており、不織布内に三次元的に分散して配置されている。 The non-woven fabric of the present embodiment has a plurality of heat-sealed portions in which the intersections of the constituent fibers are heat-sealed. Such a heat-sealed portion is formed in a portion where the constituent fibers are in contact with each other, and is three-dimensionally dispersed and arranged in the non-woven fabric.
本実施形態の不織布は、該不織布の厚み方向と直交する方向に沿い、該厚み方向に離間した2つの面を有している。本実施形態の不織布が吸収性物品の構成部材として使用された場合、該不織布の表面は通常、吸収性物品の着用者の肌に向けられる面(肌対向面)となるか、又は着用者の肌とは反対側に向けられる面(非肌対向面)若しくはショーツ等の着衣に向けられる面(着衣対向面)となる。 The non-woven fabric of the present embodiment has two surfaces separated in the thickness direction along a direction orthogonal to the thickness direction of the non-woven fabric. When the nonwoven fabric of the present embodiment is used as a constituent member of the absorbent article, the surface of the nonwoven fabric is usually a surface of the absorbent article that faces the skin of the wearer (skin facing surface) or that of the wearer. It is a surface facing the opposite side of the skin (non-skin facing surface) or a surface facing clothing such as shorts (clothing facing surface).
本実施形態の不織布は、非伸縮性繊維からなる。非伸縮性繊維は、非弾性の構成成分からなる繊維である。「非伸縮性繊維」は、「伸ばすことができ、かつ元の長さに対して50%伸ばした状態(元の長さの150%の長さになる)から力を解放したときに、元の長さの3%以下の長さまで戻る性質」を有さない繊維を意味する。
上述した熱融着部を形成する観点から、本実施形態の不織布は、非伸縮性繊維として、熱可塑性繊維を含むことが好ましい。即ち、本実施形態の不織布は、非伸縮性且つ熱可塑性の繊維を含むことが好ましい。斯かる繊維としては、例えば、ポリエチレン(PE)、ポリプロピレン(PP)等のポリオレフィン;ポリエチレンテレフタレート(PET)等のポリエステル;ナイロン6、ナイロン66等のポリアミド;ポリアクリル酸、ポリメタクリル酸アルキルエステル、ポリ塩化ビニル、ポリ塩化ビニリデン等の熱可塑性樹脂からなる繊維が挙げられ、これらの1種を単独で又は2種以上を組み合わせて用いることができる。
The non-woven fabric of the present embodiment is made of non-stretchable fibers. Non-stretchable fibers are fibers composed of non-elastic constituents. "Non-stretchable fibers" are "stretchable" and when released from a state where they are stretched 50% of their original length (which is 150% of their original length). It means a fiber that does not have the property of returning to a length of 3% or less of the length of the fiber.
From the viewpoint of forming the heat-sealed portion described above, the nonwoven fabric of the present embodiment preferably contains thermoplastic fibers as non-stretchable fibers. That is, the non-woven fabric of the present embodiment preferably contains non-stretchable and thermoplastic fibers. Examples of such fibers include polyolefins such as polyethylene (PE) and polypropylene (PP); polyesters such as polyethylene terephthalate (PET); polyamides such as nylon 6 and nylon 66; polyacrylic acid, polymethacrylic acid alkyl esters, and poly. Examples thereof include fibers made of a thermoplastic resin such as vinyl chloride and polyvinylidene chloride, and one of these fibers can be used alone or in combination of two or more.
本実施形態の不織布に用いられる非伸縮性且つ熱可塑性の繊維は、1種類の合成樹脂又は2種類以上の合成樹脂を混合したブレンドポリマーからなる単一繊維でもよく、あるいは複合繊維でもよい。ここでいう複合繊維は、成分の異なる2種類以上の合成樹脂を紡糸口金で複合し、同時に紡糸して得られる合成繊維で、複数の成分がそれぞれ繊維の長さ方向に連続した構造で、単繊維内で相互接着しているものをいう。複合繊維の形態には、芯部と鞘部とからなる芯鞘構造を備える芯鞘型や、サイドバイサイド型等が挙げられる。 The non-stretchable and thermoplastic fiber used for the non-woven fabric of the present embodiment may be a single fiber made of one kind of synthetic resin or a blend polymer obtained by mixing two or more kinds of synthetic resins, or may be a composite fiber. The composite fiber referred to here is a synthetic fiber obtained by combining two or more kinds of synthetic resins having different components with a spinneret and spinning them at the same time, and has a structure in which a plurality of components are continuous in the length direction of the fiber. Those that are mutually bonded in the fiber. Examples of the form of the composite fiber include a core-sheath type having a core-sheath structure composed of a core portion and a sheath portion, a side-by-side type, and the like.
生産コストの観点から、非伸縮性且つ熱可塑性の繊維は、PE、PP、及びPETからなる群から選択される1種又は2種以上の樹脂成分を含むことが好ましい。
非伸縮性繊維は、構成樹脂としてPEを含むことが好ましく、少なくとも表面にPEを含むことがより好ましく、PEからなることが更に好ましい。
例えば、非伸縮性繊維として芯鞘構造を備える繊維を含む場合、芯部の樹脂成分(以下、「芯成分」ともいう)がPETであり、前記鞘部の樹脂成分(以下、「鞘成分」ともいう)がポリエチレンであることが好ましい。
From the viewpoint of production cost, the non-stretchable and thermoplastic fiber preferably contains one or more resin components selected from the group consisting of PE, PP, and PET.
The non-stretchable fiber preferably contains PE as a constituent resin, more preferably contains PE at least on the surface, and further preferably consists of PE.
For example, when a fiber having a core-sheath structure is included as a non-stretchable fiber, the resin component of the core portion (hereinafter, also referred to as “core component”) is PET, and the resin component of the sheath portion (hereinafter, “sheath component””. Also referred to as) is preferably polyethylene.
非伸縮性且つ熱可塑性の繊維の好ましい一例として、芯鞘型複合繊維からなる熱可塑性繊維であって、芯成分がPET及びPPからなる群から選択される1種以上であり、鞘成分がPEであるものが挙げられる。 A preferable example of the non-stretchable and thermoplastic fiber is a thermoplastic fiber composed of a core-sheath type composite fiber, in which the core component is one or more selected from the group consisting of PET and PP, and the sheath component is PE. There is one that is.
本実施形態の不織布は、非伸縮性且つ熱可塑性の繊維に加えて、他の非伸縮性繊維を含有していてもよい。斯かる他の非伸縮性繊維としては、例えば、パルプやコットン等の天然繊維、レーヨン、リヨセル及びテンセル等のセルロース系繊維等が挙げられ、これらの1種を単独で又は2種以上を混合して用いることができる。
特に不織布が、芯成分がPETであり、鞘成分がPEである芯鞘型複合繊維を含む場合、コットンを混綿して用いることが好ましい。
The non-woven fabric of the present embodiment may contain other non-stretchable fibers in addition to the non-stretchable and thermoplastic fibers. Examples of such other non-stretchable fibers include natural fibers such as pulp and cotton, cellulosic fibers such as rayon, lyocell and tencel, and one of these fibers alone or in combination of two or more. Can be used.
In particular, when the non-woven fabric contains a core-sheath type composite fiber in which the core component is PET and the sheath component is PE, it is preferable to use cotton mixed.
上述した熱融着部を形成する観点から、全構成繊維に占める他の非伸縮性繊維の割合は、好ましくは95質量%以上、より好ましくは99質量%以上であり、また好ましくは100質量%以下である。 From the viewpoint of forming the heat-sealed portion described above, the ratio of the other non-stretchable fibers to the total constituent fibers is preferably 95% by mass or more, more preferably 99% by mass or more, and preferably 100% by mass. It is as follows.
上述した非伸縮性繊維は非弾性の樹脂からなる繊維であるが、これと相反する特性を有する繊維に伸縮性繊維がある。伸縮性繊維は、弾性樹脂からなる繊維である。斯かる繊維の構成樹脂としては、例えば、SBS(スチレン−ブタジエン−スチレン)、SIS(スチレン−イソプレン−スチレン)、SEBS(スチレン−エチレン−ブタジエン−スチレン)、SEPS(スチレン−エチレン−プロピレン−スチレン)等のスチレン系エラストマー、オレフィン系エラストマー(エチレン系のα−オレフィンエラストマー、エチレン・ブテン・オクテン等を共重合したプロピレン系エラストマー)、ポリエステル系エラストマー、ポリウレタン系エラストマー等が挙げられる。本実施形態の不織布は、このような伸縮性繊維を含んでいない。 The above-mentioned non-stretchable fiber is a fiber made of a non-elastic resin, and a fiber having properties contradictory to this is a stretchable fiber. Elastic fibers are fibers made of elastic resin. Examples of the constituent resins of such fibers include SBS (styrene-butadiene-styrene), SIS (styrene-isoprene-styrene), SEBS (styrene-ethylene-butadiene-styrene), and SEPS (styrene-ethylene-propylene-styrene). Styrene-based elastomers such as, olefin-based elastomers (ethylene-based α-olefin elastomers, propylene-based elastomers obtained by copolymerizing ethylene, butene, octene, etc.), polyester-based elastomers, polyurethane-based elastomers, and the like can be mentioned. The non-woven fabric of the present embodiment does not contain such elastic fibers.
本実施形態の不織布において、非伸縮性繊維は、繊維径が15μm以下の繊維(以下、「細繊維」ともいう。)を含んでいる。本実施形態の不織布は、全構成繊維に対する細繊維の割合が30%以上である。斯かる割合を、以下「細繊維率」ともいう。不織布の柔軟性を向上させる観点から、細繊維率は、好ましくは20%以上、より好ましくは30%以上であり、また好ましくは100%以下である。細繊維率は、不織布を構成する全構成繊維の質量に対する、細繊維の質量の割合(%)であり、不織布を製造するときに用いた繊維の質量に基づいて求めることができる。また、不織布の細繊維率は、以下の表面観察による方法により求めことができる。細繊維の使用量(質量)の割合から求める方法、及び以下の表面観察による方法の少なくとも一方の方法により求めた細繊維率が30%以上であれば、本発明における「全ての構成繊維に対する、前記細繊維の割合が30%以上である」という条件を満たす。本実施形態の不織布は、後述するように、坪量が30g/m2以下であり且つ両面が平坦な不織布であるため、以下の表面観察により大部分の繊維を観察することができる。そのために細繊維率は以下のように定義してよい。 In the nonwoven fabric of the present embodiment, the non-stretchable fibers include fibers having a fiber diameter of 15 μm or less (hereinafter, also referred to as “fine fibers”). The non-woven fabric of the present embodiment has a ratio of fine fibers to all constituent fibers of 30% or more. Such a ratio is also referred to as a "fine fiber ratio" below. From the viewpoint of improving the flexibility of the non-woven fabric, the fine fiber ratio is preferably 20% or more, more preferably 30% or more, and preferably 100% or less. The fine fiber ratio is a ratio (%) of the mass of the fine fibers to the mass of all the constituent fibers constituting the non-woven fabric, and can be obtained based on the mass of the fibers used when producing the non-woven fabric. In addition, the fine fiber ratio of the non-woven fabric can be determined by the following method of surface observation. If the fine fiber ratio obtained by at least one of the method obtained from the ratio of the amount of fine fibers used (mass) and the method by the following surface observation is 30% or more, the "for all constituent fibers" in the present invention. The condition that the ratio of the fine fibers is 30% or more is satisfied. As will be described later, the non-woven fabric of the present embodiment has a basis weight of 30 g / m 2 or less and is a non-woven fabric having flat surfaces on both sides. Therefore, most of the fibers can be observed by the following surface observation. Therefore, the fine fiber ratio may be defined as follows.
測定対象の不織布について、鋭利なかみそりを用いて、10mm×10mmの領域を厚み方向の全体に亘って切り出し、これを測定サンプルとする。測定サンプルの何れか一方の面を走査型電子顕微鏡(Scanning Electron Microscope:SEM、JCM−6000 商品名、日本電子株式会社製。本明細書におけるSEMは全てこれである。)を用いて表面観察する。この際、倍率200倍で500μm×400μmの領域(観察領域)を撮影する。このSEMによる撮影では、測定サンプルの被撮影面において最表に位置する繊維に焦点を合わせる。1枚の測定サンプルにつき、互いに位置が異なる5箇所を撮影し、計5枚のSEM画像を得る。次いで、各SEM画像において、焦点の合った繊維を選択する。焦点の合った繊維それぞれについて、熱融着部以外の任意の部分を選択し、その選択した部分における繊維の長手方向と直交する線を引く。この直交する線に沿う前記繊維の差し渡し長さを繊維径として測定する。斯かる測定は、前記焦点の合った繊維において、前記差し渡し長さを示す差し渡し線、即ち繊維の長手方向と直交する線と、繊維の輪郭を示す線とが互いに直交する位置で測定する。前記「焦点の合った繊維」とは、SEM画像において繊維の輪郭が500μm×400μmの領域内でぼやけていない繊維である。測定した繊維径が15μm以下の繊維の本数を細繊維の本数としてカウントし、SEM画像における前記焦点の合った繊維の本数に対する該細繊維の本数の割合、即ち「細繊維の本数/焦点の合った繊維の本数」の百分率(%)を求める。斯かる割合を、測定サンプルから取得した計5枚のSEM画像ごとに求め、これらの平均を、「片面細繊維率」とする。次いで、前記「片面細繊維率」の測定を、該不織布の両面それぞれについて行い、これらの平均を、細繊維率とする。 With respect to the non-woven fabric to be measured, a region of 10 mm × 10 mm is cut out over the entire thickness direction using a sharp razor, and this is used as a measurement sample. Surface observation is performed on one surface of the measurement sample using a scanning electron microscope (Scanning Electron Microscope: SEM, JCM-6000, trade name, manufactured by JEOL Ltd. All SEMs in the present specification are this). .. At this time, a region (observation region) of 500 μm × 400 μm is photographed at a magnification of 200 times. In this SEM imaging, the fibers located on the outermost surface of the surface to be photographed of the measurement sample are focused. For one measurement sample, 5 points having different positions from each other are photographed to obtain a total of 5 SEM images. Then, in each SEM image, the focused fibers are selected. For each of the focused fibers, select any portion other than the heat-sealed portion and draw a line orthogonal to the longitudinal direction of the fiber at the selected portion. The transfer length of the fibers along the orthogonal lines is measured as the fiber diameter. In such a measurement, in the focused fiber, the transfer line indicating the transfer length, that is, the line orthogonal to the longitudinal direction of the fiber and the line indicating the contour of the fiber are measured at positions orthogonal to each other. The "focused fiber" is a fiber whose contour is not blurred within a region of 500 μm × 400 μm in the SEM image. The number of fibers having a measured fiber diameter of 15 μm or less is counted as the number of fine fibers, and the ratio of the number of the fine fibers to the number of the focused fibers in the SEM image, that is, “number of fine fibers / focusing) Calculate the percentage (%) of "the number of fibers". Such a ratio is obtained for each of a total of five SEM images obtained from the measurement sample, and the average of these is defined as the "single-sided fine fiber ratio". Next, the measurement of the "single-sided fine fiber ratio" is performed for each of both sides of the non-woven fabric, and the average of these is taken as the fine fiber ratio.
本実施形態の不織布の坪量は、30g/m2以下である。クッション性をより確実に奏させるとともに、生産コストを抑制する観点から、本実施形態の不織布の坪量は、好ましくは8g/m2以上、より好ましくは10g/m2以上であり、また好ましくは28g/m2以下、より好ましくは26g/m2以下である。 The basis weight of the non-woven fabric of this embodiment is 30 g / m 2 or less. From the viewpoint of more reliably achieving cushioning properties and suppressing production costs, the basis weight of the non-woven fabric of the present embodiment is preferably 8 g / m 2 or more, more preferably 10 g / m 2 or more, and preferably 10 g / m 2 or more. It is 28 g / m 2 or less, more preferably 26 g / m 2 or less.
本実施形態の不織布は、両面が平坦である。換言すれば、本実施形態の不織布は、両面に凹凸形状を有していない。前記「凹凸形状」は、例えば平面方向に複数の凸部又は凹部が形成されたものや、一方向に延びる凸条部と溝部とが交互に形成されたものが含まれる。即ち、本実施形態の不織布は、両面にこれら凸部、凹部、凸条部、及び溝部を有しない。 The non-woven fabric of the present embodiment is flat on both sides. In other words, the non-woven fabric of the present embodiment does not have an uneven shape on both sides. The "concavo-convex shape" includes, for example, a shape in which a plurality of convex portions or concave portions are formed in a plane direction, and a shape in which convex portions and grooves extending in one direction are alternately formed. That is, the non-woven fabric of the present embodiment does not have these protrusions, recesses, ridges, and grooves on both sides.
本実施形態の不織布は、30cN/cm2の荷重を24時間印加後の厚みが1.6mm以上である。斯かる厚みを、以下「回復厚み」ともいう。後述する厚みの回復性をより確実に奏させる観点から、回復厚みは、好ましくは1.7mm以上、より好ましくは1.8mm以上であり、また好ましくは8mm以下、より好ましくは5mm以下である。回復厚みに関し、「30cN/cm2の荷重」は、包装体内に圧縮された状態で封入された吸収性物品に印加される荷重の1.1倍の荷重として設定されたものである。回復厚みは、以下の測定方法により測定される。 The non-woven fabric of the present embodiment has a thickness of 1.6 mm or more after applying a load of 30 cN / cm 2 for 24 hours. Such a thickness is also hereinafter referred to as "recovery thickness". From the viewpoint of more reliably achieving the recovery of the thickness described later, the recovery thickness is preferably 1.7 mm or more, more preferably 1.8 mm or more, and preferably 8 mm or less, more preferably 5 mm or less. Regarding the recovery thickness, the " load of 30 cN / cm 2 " is set as a load 1.1 times the load applied to the absorbent article enclosed in the package in a compressed state. The recovery thickness is measured by the following measuring method.
〔回復厚みの測定方法〕
測定対象の不織布について、鋭利なかみそりを用いて、100mm×140mmの領域を厚み方向の全体に亘って切り出し、これを測定サンプルとする。次いで、測定サンプルを、サンプル以上の面積を有する2枚の加圧板であって、アクリル板若しくはPET板(厚みは3mm以内)からなるものに挟み、これの上に10kgの錘を載せて、30cN/cm2の荷重を測定サンプルに対し印加する。このように、測定サンプルを24時間圧縮状態にした後、加圧板と錘とを外してから30秒以内に、0.5g荷重下における該測定サンプルの厚みを、オムロン株式会社製レーザー厚み計ZSLD−80を用いて測定する。以上の測定を各測定サンプルについて行い、これらの平均を回復厚みとする。
[Measurement method of recovery thickness]
With respect to the non-woven fabric to be measured, a region of 100 mm × 140 mm is cut out over the entire thickness direction using a sharp razor, and this is used as a measurement sample. Next, the measurement sample is sandwiched between two pressure plates having an area larger than the sample and made of an acrylic plate or a PET plate (thickness is within 3 mm), and a weight of 10 kg is placed on the pressure plate to 30 cN. A load of / cm 2 is applied to the measurement sample. In this way, after compressing the measurement sample for 24 hours, within 30 seconds after removing the pressure plate and the weight, the thickness of the measurement sample under a load of 0.5 g is measured by the laser thickness gauge ZSLD manufactured by OMRON Corporation. Measure using -80. The above measurement is performed for each measurement sample, and the average of these is taken as the recovery thickness.
吸収性物品は、一般的に包装体内に圧縮された状態で流通される。本実施形態の不織布を吸収性物品の構成部材に用いた場合、包装体が開封されて圧縮状態が解除されると、当該不織布は、回復厚みが1.6mm以上であるので、厚みが良好に回復する。斯かる厚みの回復性は以下の理由によるものと考えられる。本実施形態の不織布の両面が平坦であり、全ての構成繊維に対する細繊維の割合、及び該不織布の坪量が前述した範囲であるので、不織布全体の柔軟性が高く、包装形態において構成繊維が高密度化し易い。また当該不織布を形成する非伸縮性繊維は、非弾性であることから、圧縮に対する変形が生じ難いので、圧縮に対する反発力が作用し易い。斯かる不織布を、圧縮状態から圧縮が解除された開放状態にすると、非伸縮性繊維の反発力により構成繊維間の隙間が元に近い状態に戻る。即ち構成繊維の密度が包装前の密度に戻り易くなるので、該不織布の厚みが良好に回復するとともに、これに起因して良好なクッション性が得られる。 The absorbent article is generally distributed in a compressed state inside the package. When the non-woven fabric of the present embodiment is used as a constituent member of an absorbent article, when the package is opened and the compressed state is released, the non-woven fabric has a recovery thickness of 1.6 mm or more, so that the thickness is good. Recover. The recoverability of such thickness is considered to be due to the following reasons. Since both sides of the nonwoven fabric of the present embodiment are flat, the ratio of the fine fibers to all the constituent fibers, and the basis weight of the nonwoven fabric are within the above-mentioned ranges, the flexibility of the entire nonwoven fabric is high, and the constituent fibers are present in the packaging form. Easy to increase the density. Further, since the non-stretchable fibers forming the non-woven fabric are inelastic, they are unlikely to be deformed by compression, so that a repulsive force against compression is likely to act. When such a non-woven fabric is put into an open state in which compression is released from a compressed state, the gap between the constituent fibers returns to a state close to the original due to the repulsive force of the non-stretchable fibers. That is, since the density of the constituent fibers is likely to return to the density before packaging, the thickness of the non-woven fabric is satisfactorily restored, and due to this, good cushioning property can be obtained.
厚みの回復性をより向上させる観点から、本実施形態の不織布における構成繊維の平均繊維径は、好ましくは5μm以上、より好ましくは10μm以上であり、また好ましくは18μm以下、より好ましくは15μm以下である。
不織布は、繊維径が互いに異なる複数種類の繊維から構成されてもよいが、上記と同様の観点から、繊維径が20μm以下の構成繊維からなることが好ましく、繊維径が15μm以下の構成繊維からなることがより好ましい。不織布が、繊維径が互いに異なる複数種類の繊維を含んでいる場合、前記「平均繊維径」は、不織布全体における構成繊維の繊維径の平均である。
From the viewpoint of further improving the recoverability of the thickness, the average fiber diameter of the constituent fibers in the nonwoven fabric of the present embodiment is preferably 5 μm or more, more preferably 10 μm or more, and preferably 18 μm or less, more preferably 15 μm or less. be.
The non-woven fabric may be composed of a plurality of types of fibers having different fiber diameters, but from the same viewpoint as described above, the non-woven fabric is preferably composed of constituent fibers having a fiber diameter of 20 μm or less, and is composed of constituent fibers having a fiber diameter of 15 μm or less. Is more preferable. When the nonwoven fabric contains a plurality of types of fibers having different fiber diameters, the "average fiber diameter" is the average of the fiber diameters of the constituent fibers in the entire nonwoven fabric.
不織布の構成繊維の繊維径は、以下の方法により求められる。前述した〔細繊維率の測定方法〕と同様の方法によって不織布をSEM観察する。この不織布のSEM画像における前述した「焦点の合った繊維」を任意に10本選択する。次いで、これら10本の繊維それぞれについて、前述した繊維径を測定する。次いで、測定サンプルから取得した計5枚のSEM画像ごとに、前記10本の繊維について、繊維径の算術平均値を求める。斯かる算術平均値を、不織布の両面それぞれについて求め、これらの平均を平均繊維径とする。 The fiber diameter of the constituent fibers of the non-woven fabric is determined by the following method. The non-woven fabric is SEM-observed by the same method as the above-mentioned [Measuring method of fine fiber ratio]. Arbitrarily select 10 of the above-mentioned "focused fibers" in the SEM image of this non-woven fabric. Next, the fiber diameter described above is measured for each of these 10 fibers. Next, the arithmetic mean value of the fiber diameter is obtained for the 10 fibers for each of a total of 5 SEM images obtained from the measurement sample. Such an arithmetic mean value is obtained for each of both sides of the non-woven fabric, and the average of these values is taken as the average fiber diameter.
本実施形態の不織布は吸収性物品用であり、吸収性物品の構成部材として使用される。ここでいう「吸収性物品」には、人体から排出される体液(尿、軟便、経血、汗等)の吸収に用いられる物品が広く包含され、例えば、使い捨ておむつ、生理用ナプキン、生理用ショーツ、失禁パッド等が包含される。 The non-woven fabric of the present embodiment is for an absorbent article and is used as a constituent member of the absorbent article. The term "absorbable article" as used herein broadly includes articles used for absorbing body fluids (urine, loose stool, menstrual blood, sweat, etc.) discharged from the human body, and includes, for example, disposable diapers, sanitary napkins, and sanitary napkins. Includes shorts, incontinence pads, etc.
吸収性物品は、典型的には、着用者の肌から相対的に近い位置に配された液透過性の表面シートと、着用者の肌から相対的に遠い位置に配された液透過性又は液難透過性若しくは撥水性の裏面シートと、両シート間に介在配置された液保持性の吸収体とを具備する。吸収性物品は、その外面を形成する外装体を具備するものであってもよい。
本実施形態の不織布を吸収性物品に用いる場合、該吸収性物品は、該不織布を構成部材として備える。
Absorbent articles typically include a liquid permeable surface sheet located relatively close to the wearer's skin and a liquid permeable or liquid permeable material located relatively far from the wearer's skin. It is provided with a liquid-impermeable or water-repellent back sheet and a liquid-retaining absorber disposed between the two sheets. The absorbent article may include an exterior body that forms its outer surface.
When the non-woven fabric of the present embodiment is used as an absorbent article, the absorbent article includes the non-woven fabric as a constituent member.
本実施形態の不織布は、基本的には、エアスルー法で得られた不織布単層からなるものであるが、吸収性物品の構成部材として用いられる場合、他の不織布やフィルム等をはじめとする他のシート材料と積層された状態になっていてもよい。 The non-woven fabric of the present embodiment is basically composed of a single-layered non-woven fabric obtained by the air-through method, but when used as a constituent member of an absorbent article, other non-woven fabrics, films and the like are used. It may be in a state of being laminated with the sheet material of.
良好なクッション性により、吸収性物品の肌触りや装着感をより向上させる観点から、本実施形態の不織布が用いられた吸収性物品は、該不織布を、該吸収性物品の最外面を形成するシートに用いることが好ましい。具体的には、本実施形態の不織布を表面シート及び前記裏面シートの何れか一方又は双方として備えることが好ましく、該不織布を裏面シートとして備えることがより好ましい。防漏性をより確実に確保する観点から、斯かる裏面シートは、液難透過性シートと前記不織布との積層シートからなることが好ましい。
上記と同様の観点から、前記吸収性物品は、本実施形態の不織布を、該吸収性物品の外面を形成する外装体として備えることが好ましい。特に、本実施形態の不織布は、両面が平坦であるので、外装体に用いることにより滑らかな手触りが得られる。
From the viewpoint of further improving the feel and wearing feeling of the absorbent article by the good cushioning property, the absorbent article in which the nonwoven fabric of the present embodiment is used is a sheet forming the outermost surface of the absorbent article. It is preferable to use it for. Specifically, the non-woven fabric of the present embodiment is preferably provided as either one or both of the front surface sheet and the back surface sheet, and more preferably the non-woven fabric is provided as the back surface sheet. From the viewpoint of ensuring leak resistance more reliably, such a back surface sheet is preferably made of a laminated sheet of a liquid impervious sheet and the non-woven fabric.
From the same viewpoint as above, it is preferable that the absorbent article is provided with the non-woven fabric of the present embodiment as an exterior body forming the outer surface of the absorbent article. In particular, since the non-woven fabric of the present embodiment is flat on both sides, a smooth feel can be obtained by using it as an exterior body.
本実施形態の不織布が市販の吸収性物品等の製品に組み込まれている場合、該吸収性物品に対して、コールドスプレーを噴霧して、吸収性物品の構成部材を接着している接着剤を固化させ、表面シート、吸収性シート、裏面シートなどの各部材ごとに分解することで、不織布を取り出す。この取り出し方法は、特に断らない限り、本明細書における他の測定方法にも共通して適用可能である。 When the non-woven fabric of the present embodiment is incorporated in a product such as a commercially available absorbent article, a cold spray is sprayed on the absorbent article to apply an adhesive for adhering the constituent members of the absorbent article. The non-woven fabric is taken out by solidifying and disassembling each member such as a front sheet, an absorbent sheet, and a back sheet. Unless otherwise specified, this extraction method can be commonly applied to other measurement methods in the present specification.
次に、上述した実施形態の不織布の製造方法について説明する。本製造方法は、熱可塑性繊維を含む繊維ウエブにエアスルー方式で熱風を吹き付ける熱処理工程を有する。前記熱処理工程は、繊維ウエブの構成繊維どうしの交点を融着させて熱融着部を形成することで不織布化する工程である。 Next, the method for producing the nonwoven fabric of the above-described embodiment will be described. This manufacturing method includes a heat treatment step of blowing hot air into a fiber web containing thermoplastic fibers by an air-through method. The heat treatment step is a step of forming a non-woven fabric by fusing the intersections of the constituent fibers of the fiber web to form a heat-sealed portion.
繊維ウエブは、典型的には、熱可塑性繊維等の原料繊維を開繊機で開繊し、開繊された原料繊維をカード機でウエブ化することで製造される。繊維ウエブは不織布に形成される前の段階のシート状物であり、繊維ウエブ中では繊維同士は熱融着していない。原料繊維すなわち繊維ウエブの構成繊維としては、前述した不織布の構成繊維と同じものを用いることが好ましい。また、繊維ウエブの坪量は、上述した不織布の坪量の範囲に合わせることが好ましい。
繊維ウエブは、繊維径が互いに異なった複数種類の繊維を積層してなる積層ウエブ又は混合してなる混合ウエブであってもよい。
三層以上の積層ウエブを用いる場合、該積層ウエブの表面を形成する層は熱可塑性の繊維を含んで構成され、且つ該表面を形成する層間に介在する中間層はコットン等の非熱可塑性の繊維を含んで構成されてもよい。
The fiber web is typically produced by opening a raw material fiber such as a thermoplastic fiber with a fiber opening machine and converting the opened raw material fiber into a web with a card machine. The fiber web is a sheet-like material before it is formed into a non-woven fabric, and the fibers are not heat-sealed in the fiber web. As the raw material fiber, that is, the constituent fiber of the fiber web, it is preferable to use the same one as the constituent fiber of the non-woven fabric described above. Further, it is preferable that the basis weight of the fiber web is adjusted to the range of the basis weight of the above-mentioned non-woven fabric.
The fiber web may be a laminated web made by laminating a plurality of types of fibers having different fiber diameters or a mixed web made by mixing them.
When three or more laminated webs are used, the layer forming the surface of the laminated web is composed of thermoplastic fibers, and the intermediate layer interposed between the layers forming the surface is a non-thermoplastic material such as cotton. It may be composed of fibers.
得られた繊維ウエブに対して熱処理工程を行う。より具体的には、例えば樹脂製のメッシュベルトや、ワイヤーメッシュからなる金属製の無端縁ネット、通気孔が開いた金属製プレート、又は通気孔が開いていない金属製プレート等の上に載置して、該繊維ウエブ側から熱風又は水蒸気を吹き付けることで、繊維どうしの交点を熱融着させる。これにより、得られる不織布には、プレート又はネットと対向する面(以下、非吹き付け面ともいう)と、熱風の吹き付け面(以下、吹き付け面ともいう)との2つの面が形成される。 A heat treatment step is performed on the obtained fiber web. More specifically, it is placed on, for example, a resin mesh belt, a metal endless net made of wire mesh, a metal plate with vents, or a metal plate without vents. Then, hot air or steam is blown from the fiber web side to heat-fuse the intersections of the fibers. As a result, the obtained non-woven fabric is formed with two surfaces, a surface facing the plate or net (hereinafter, also referred to as a non-sprayed surface) and a surface for which hot air is sprayed (hereinafter, also referred to as a sprayed surface).
通常のエアスルー処理における熱風の温度は、繊維ウエブの構成繊維の融点のうち最も低い最低融点(例えば芯鞘型複合繊維の鞘部における融点)よりも10℃程度高い範囲に設定されるが、不織布化をより容易にする観点から、熱風の温度と構成繊維の融点との温度差は、好ましくは5℃以上、より好ましくは10℃以上であり、また好ましくは70℃以下、より好ましくは50℃以下である。
なお、構成繊維の最低融点とは、芯鞘型複合繊維のように複数種類の樹脂を繊維が有する場合、それらの樹脂の中で最も融点が低いものの融点を指す。明確な融点が存在しない樹脂の場合は軟化点を指す。
The temperature of the hot air in the normal air-through treatment is set in a range about 10 ° C. higher than the lowest melting point of the constituent fibers of the fiber web (for example, the melting point in the sheath portion of the core-sheath type composite fiber), but the non-woven fabric From the viewpoint of facilitating the conversion, the temperature difference between the temperature of the hot air and the melting point of the constituent fibers is preferably 5 ° C. or higher, more preferably 10 ° C. or higher, and preferably 70 ° C. or lower, more preferably 50 ° C. It is as follows.
The lowest melting point of the constituent fibers refers to the melting point of the lowest melting point among the resins when the fibers have a plurality of types of resins such as core-sheath type composite fibers. In the case of a resin that does not have a definite melting point, it refers to the softening point.
不織布の厚みを大きくして、クッション性をより確実に奏させる観点から、熱処理工程において繊維ウエブに吹き付けられる熱風の風速は、0.3m/秒以上、好ましくは0.5m/秒以上、より好ましくは0.8m/秒以上、そして、10m/秒以下、好ましくは5m/秒以下、より好ましくは3m/秒以下である。 From the viewpoint of increasing the thickness of the non-woven fabric and ensuring cushioning, the air velocity of the hot air blown to the fiber web in the heat treatment step is 0.3 m / sec or more, preferably 0.5 m / sec or more, more preferably. Is 0.8 m / sec or more, and 10 m / sec or less, preferably 5 m / sec or less, and more preferably 3 m / sec or less.
熱処理工程において、繊維ウエブに熱風を吹き付ける時間(熱処理時間)は、従来のエアスルー不織布の製造方法と同程度であってもよいが、上記と同様の観点から、熱処理時間は、好ましくは1秒以上、より好ましくは3秒以上であり、また製造スピードをできるだけ早くし製造コストを下げる観点から好ましくは60秒以下、より好ましくは30秒以下である。 In the heat treatment step, the time for blowing hot air onto the fiber web (heat treatment time) may be about the same as that of the conventional air-through non-woven fabric manufacturing method, but from the same viewpoint as above, the heat treatment time is preferably 1 second or more. , More preferably 3 seconds or more, and preferably 60 seconds or less, more preferably 30 seconds or less from the viewpoint of increasing the production speed as much as possible and reducing the production cost.
不織布の厚みをより大きくする観点から、本製造方法は、繊維ウエブ内部に別体のシートを介在させた状態で熱処理工程を行うことが好ましい。斯かる構成により、熱風を吹き付けて不織布化しても、嵩高な状態を容易に維持することができる。前記別体のシートは、繊維材料を含む各種のシートを用いることができる。例えば湿式抄造紙や乾式抄造紙などの紙、織布、不織布若しくは編み物地又はそれらの複合シートなどが挙げられる。コストを下げる観点から、紙や不織布を用いることが好ましい。
以下、繊維ウエブ内部に介在される別体のシートであって、該繊維ウエブを不織布化した後、その不織布から取り除かれるシートを「介在シート」という。なお、三層以上の積層ウエブにおいて、該積層ウエブの表面を形成する層間に介在する中間層を形成し、且つ不織布化した後に、その不織布から取り除かれないシートは、介在シートではない。
From the viewpoint of increasing the thickness of the non-woven fabric, it is preferable that the heat treatment step is performed in this manufacturing method with a separate sheet interposed inside the fiber web. With such a configuration, even if hot air is blown to form a non-woven fabric, the bulky state can be easily maintained. As the separate sheet, various sheets containing a fiber material can be used. Examples thereof include papers such as wet papers and dry papers, woven fabrics, non-woven fabrics, knitted fabrics, and composite sheets thereof. From the viewpoint of reducing the cost, it is preferable to use paper or non-woven fabric.
Hereinafter, a separate sheet interposed inside the fiber web, in which the fiber web is made into a non-woven fabric and then removed from the non-woven fabric, is referred to as an "intervening sheet". In a laminated web having three or more layers, a sheet that is not removed from the non-woven fabric after forming an intermediate layer between layers forming the surface of the laminated web and forming a non-woven fabric is not an interwoven sheet.
繊維ウエブ内部に介在シートを配置する方法としては、間に介在シートを挟んで積層した積層ウエブを形成する方法、具体的には、間にPET等のPEの溶融温度よりもはるかに高い高溶融温度を有する繊維シートを挟む方法や、該高溶融温度を有する繊維を混綿させる方法等が挙げられる。 As a method of arranging the interposition sheet inside the fiber web, a method of forming a laminated web in which the interposition sheet is sandwiched between them, specifically, a method of forming a laminated web in which the interposition sheet is sandwiched between them, specifically, a high melting temperature much higher than the melting temperature of PE such as PET. Examples thereof include a method of sandwiching a fiber sheet having a temperature and a method of mixing fibers having a high melting temperature.
繊維ウエブ内部に介在シートを配置した状態で熱処理工程を行った後、該介在シートは得られた不織布から除かれる。例えば、間に介在シートを挟んで積層した積層ウエブに熱処理(エアスルー処理)を施した後、得られた不織布から介在シートを引き抜いて取り除く。 After performing the heat treatment step with the interposition sheet arranged inside the fiber web, the interposition sheet is removed from the obtained non-woven fabric. For example, after heat treatment (air-through treatment) is performed on the laminated web laminated with the interposition sheet sandwiched between them, the interposition sheet is pulled out from the obtained non-woven fabric to remove it.
以上、本発明をその好ましい実施形態に基づき説明したが、本発明は前記実施形態に制限されず適宜変更可能である。また上述した各構成を適宜組み合わせてもよい。 Although the present invention has been described above based on the preferred embodiment, the present invention is not limited to the above embodiment and can be appropriately modified. Further, each of the above-described configurations may be combined as appropriate.
以下、本発明を実施例により更に具体的に説明するが、本発明は斯かる実施例に限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to such Examples.
〔実施例1〕
原料繊維として、芯成分がPET、鞘成分がPEからなる同心の芯鞘型複合繊維(芯鞘比50質量%:50質量%)からなる1.2dtexの熱可塑性繊維を用いた。斯かる原料繊維は、最低融点が120℃であった。公知のカード機を用い常法に従って、坪量が10g/m2となるように繊維ウエブを2枚製造した。次いで、介在シートとして1枚のキムワイプ(登録商標)(日本製紙クレシア株式会社製、S−200)を2枚の繊維ウエブの間に挟んで、積層ウエブを作製した。この積層ウエブを樹脂製のメッシュベルトに載置した状態で、エアスルー方式により熱風を吹き付ける熱処理工程を行い不織布化した後、キムワイプを引き抜いて不織布を製造した。熱処理工程(エアスルー処理)における熱処理条件は表1に示すとおりであった。
[Example 1]
As the raw material fiber, a 1.2 dtex thermoplastic fiber composed of a concentric core-sheath type composite fiber having a core component of PET and a sheath component of PE (core-sheath ratio 50% by mass: 50% by mass) was used. Such raw material fibers had a minimum melting point of 120 ° C. Two fiber webs were produced using a known card machine according to a conventional method so that the basis weight was 10 g / m 2. Next, one Kimwipe (registered trademark) (manufactured by Nippon Paper Crecia Co., Ltd., S-200) was sandwiched between two fiber webs as an intervening sheet to prepare a laminated web. With this laminated web placed on a resin mesh belt, a heat treatment step of blowing hot air was performed by an air-through method to form a non-woven fabric, and then Kimwipe was pulled out to produce a non-woven fabric. The heat treatment conditions in the heat treatment step (air-through treatment) are as shown in Table 1.
〔実施例2〕
2枚の繊維ウエブの間に中間層を挟んで作製した積層ウエブを用いた点以外は、実施例1と同様の方法により、不織布を製造した。中間層は、PET繊維(帝人フロンティア株式会社製、商品名「テイジンテトロン 3.3dtex」)を用いて、坪量が2g/m2となるように作製した繊維ウエブであった。実施例2では、中間層は引き抜かずに不織布を製造した。
[Example 2]
A non-woven fabric was produced by the same method as in Example 1 except that a laminated web prepared by sandwiching an intermediate layer between two fiber webs was used. The intermediate layer was a fiber web produced using PET fiber (manufactured by Teijin Frontier Co., Ltd., trade name "Teijin Tetron 3.3dtex") so as to have a basis weight of 2 g / m 2. In Example 2, the non-woven fabric was produced without pulling out the intermediate layer.
〔実施例3〕
実施例1の原料繊維を用いて、坪量が12g/m2となるように繊維ウエブを2枚製造した。同様の方法で丸三産業製コットンを原料繊維として坪量が4g/m2となるように繊維ウエブを1枚製造し、これを真ん中の層(中間層)にした積層ウエブを製造した。この積層ウエブを用いた点、及び実施例1と熱処理工程(エアスルー処理)における熱処理条件を異ならせた点以外は、実施例1と同様の方法により不織布を製造した。実施例3では、中間層は引き抜かずに不織布を製造した。
[Example 3]
Using the raw material fibers of Example 1, two fiber webs were produced so as to have a basis weight of 12 g / m 2. In the same manner, one fiber web was manufactured using Marusan Sangyo cotton as a raw material fiber so as to have a basis weight of 4 g / m 2, and a laminated web was manufactured by using this as a middle layer (intermediate layer). A non-woven fabric was produced by the same method as in Example 1 except that the laminated web was used and the heat treatment conditions in the heat treatment step (air-through treatment) were different from those in Example 1. In Example 3, the non-woven fabric was produced without pulling out the intermediate layer.
〔比較例1〕
2枚の繊維ウエブの間に介在シートを挟まないで、積層ウエブを作製した点以外は、実施例1と同様の方法により不織布を製造した。
[Comparative Example 1]
A non-woven fabric was produced by the same method as in Example 1 except that a laminated web was produced without sandwiching an intervening sheet between the two fiber webs.
〔比較例2〕
坪量及び熱処理工程(エアスルー処理)における熱処理条件を異ならせた点以外は、比較例1と同様の方法により不織布を製造した。
[Comparative Example 2]
A non-woven fabric was produced by the same method as in Comparative Example 1 except that the basis weight and the heat treatment conditions in the heat treatment step (air-through treatment) were different.
〔比較例3〕
坪量を異ならせた点以外は、比較例2と同様の方法により不織布を製造した。熱処理工程(エアスルー処理)における熱処理条件は表1に示すとおりであった。
[Comparative Example 3]
A non-woven fabric was produced by the same method as in Comparative Example 2 except that the basis weights were different. The heat treatment conditions in the heat treatment step (air-through treatment) are as shown in Table 1.
〔比較例4〕
坪量を異ならせた点以外は、比較例2と同様の方法により不織布を製造した。熱処理工程(エアスルー処理)における熱処理条件は表1に示すとおりであった。
[Comparative Example 4]
A non-woven fabric was produced by the same method as in Comparative Example 2 except that the basis weights were different. The heat treatment conditions in the heat treatment step (air-through treatment) are as shown in Table 1.
〔厚みの測定〕
実施例及び比較例において得られた製造直後の不織布について、前述した方法により厚みを測定した。測定結果を表1に示す。
[Measurement of thickness]
The thickness of the immediately-produced nonwoven fabrics obtained in Examples and Comparative Examples was measured by the method described above. The measurement results are shown in Table 1.
〔回復厚みの測定〕
実施例及び比較例において得られた不織布について、前述した方法により回復厚みを測定した。測定結果を表1に示す。
[Measurement of recovery thickness]
The recovery thickness of the non-woven fabrics obtained in Examples and Comparative Examples was measured by the method described above. The measurement results are shown in Table 1.
〔クッション性の評価〕
実施例及び比較例の不織布について、クッション性を評価した。評価方法は以下のとおりである。不織布から、10cm×10cmの大きさで切り出したものを試験片として用い、パネラーとして3名のクッション性の評価に関して熟練した成人男性が、該試験片を触ることで、そのクッション性(ふっくらさ)を評価した。試験片の触り方は規定しておらず、パネラー各々が自由に試験片を触って評価した。斯かる評価は、市販のおむつから取り出した外層シートを触ったときのクッション性を評価基準とした。具体的には、市販のおむつ「メリーズ寵愛の抱擁」(花王株式会社、2019年製、中国販売品)の外層シートを3点とし、別の市販のおむつ「メリーズさらさらエアスルーMサイズ」(花王株式会社、2019年製、日本販売品)の外層シートを1点とした。外層シートは、おむつの外面を形成するシートである。前記評価基準において、評価点が高いほど試験片がふっくらしており、クッション性が高いと評価した。また、評価基準が3点のおむつよりもクッション性が高いと評価した場合、評価点を3点より高い点数とし、最高評価を5点とした。評価点は、パネラー3人の平均値を整数桁に四捨五入して算出した。評価結果を表1に示す。
[Evaluation of cushioning]
The cushioning properties of the non-woven fabrics of Examples and Comparative Examples were evaluated. The evaluation method is as follows. A non-woven fabric cut out in a size of 10 cm x 10 cm is used as a test piece, and three adult men who are skilled in evaluating the cushioning property as panelists touch the test piece to obtain the cushioning property (fluffiness). Was evaluated. The method of touching the test piece was not specified, and each panelist freely touched the test piece for evaluation. In such an evaluation, the cushioning property when the outer layer sheet taken out from a commercially available diaper was touched was used as an evaluation standard. Specifically, the outer layer sheet of the commercially available diaper "Mary's Love Embrace" (Kao Corporation, made in 2019, sold in China) is set to 3 points, and another commercially available diaper "Mary's Sarasara Air Through M size" (Kao Corporation) The outer layer sheet of the company, made in 2019, sold in Japan) was set as one point. The outer layer sheet is a sheet that forms the outer surface of the diaper. In the above evaluation criteria, it was evaluated that the higher the evaluation score, the more fluffy the test piece and the higher the cushioning property. In addition, when it was evaluated that the cushioning property was higher than that of the diaper having the evaluation standard of 3 points, the evaluation point was set to higher than 3 points and the highest evaluation was set to 5 points. The evaluation points were calculated by rounding the average value of the three panelists to an integer digit. The evaluation results are shown in Table 1.
表1に示すとおり、実施例1〜3の不織布は、回復厚みが1.6mm以上であった。斯かる不織布は、比較例1〜4よりも、回復厚みが大きく、クッション性が高い評価となった。表1の結果より、各実施例における不織布は、比較例における不織布に比して、圧縮に対する嵩の回復性に優れ、クッション性が良好であることが判る。
As shown in Table 1, the non-woven fabrics of Examples 1 to 3 had a recovery thickness of 1.6 mm or more. Such a non-woven fabric was evaluated to have a larger recovery thickness and a higher cushioning property than Comparative Examples 1 to 4. From the results in Table 1, it can be seen that the non-woven fabrics in each example are superior in bulk recovery to compression and have good cushioning properties as compared with the non-woven fabrics in the comparative examples.
Claims (6)
非伸縮性繊維からなり、該非伸縮性繊維が、繊維径が15μm以下である細繊維を含んでおり、
全ての構成繊維に対する、前記細繊維の割合が30%以上であり、
坪量が30g/m2以下であり、両面が平坦であり、30cN/cm2の荷重を24時間印加後の厚みが1.6mm以上である、吸収性物品用不織布。 A non-woven fabric for absorbent articles made of an air-through non-woven fabric.
It is composed of non-stretchable fibers, and the non-stretchable fibers contain fine fibers having a fiber diameter of 15 μm or less.
The ratio of the fine fibers to all the constituent fibers is 30% or more.
A non-woven fabric for absorbent articles having a basis weight of 30 g / m 2 or less, flat surfaces on both sides, and a thickness of 1.6 mm or more after applying a load of 30 cN / cm 2 for 24 hours.
The absorbent article according to claim 5, wherein the constituent member is an exterior body forming an outer surface of the absorbent article.
Priority Applications (1)
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