JP2021109902A - Longitudinal seal tape used in paper container, and paper container longitudinally sealed by longitudinal seal tape - Google Patents

Longitudinal seal tape used in paper container, and paper container longitudinally sealed by longitudinal seal tape Download PDF

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JP2021109902A
JP2021109902A JP2020001757A JP2020001757A JP2021109902A JP 2021109902 A JP2021109902 A JP 2021109902A JP 2020001757 A JP2020001757 A JP 2020001757A JP 2020001757 A JP2020001757 A JP 2020001757A JP 2021109902 A JP2021109902 A JP 2021109902A
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resin layer
paper container
packaging material
heat
sealing
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JP7372843B2 (en
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和彦 佐瀬
Kazuhiko Sase
和彦 佐瀬
茂和 宮川
Shigekazu Miyagawa
茂和 宮川
幸治 古市
Koji Furuichi
幸治 古市
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Nippon Paper Industries Co Ltd
Jujo Paper Co Ltd
Toyo Heisei KK
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Nippon Paper Industries Co Ltd
Jujo Paper Co Ltd
Toyo Heisei KK
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Priority to JP2020001757A priority Critical patent/JP7372843B2/en
Priority to PCT/JP2021/000490 priority patent/WO2021141111A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/35Heat-activated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Wrappers (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Cartons (AREA)

Abstract

To provide a longitudinal seal tape that is used in a paper container which can be laterally sealed without causing leakage by sealing with ultrasonic vibration oscillated with high output, and a paper container that is longitudinally sealed by a longitudinal seal tape.SOLUTION: A longitudinal seal tape 1, which is used to cover a joint in a longitudinal direction of a paper container molded and be longitudinally sealed through a step of heat fusing a belt-like packaging material 8 with paper board as a base layer and heat fusible synthetic resin layers as outermost layers of both front and rear surfaces so that both edge parts are made to overlap each other, and form a packaging material tube, has such a laminated structure that a gas barrier resin layer 8 is used as a core layer, and heat fusible synthetic resin layers 11 and 12 are laminated on both surfaces of the gas barrier resin layer 8 through adhesive resin layers 9 and 10, and a vibration absorption material is added to an adhesive resin forming the adhesive resin layers 9 and 10 and/or the heat fusible synthetic resin layers 11 and 12.SELECTED DRAWING: Figure 1

Description

本発明は、板紙をベース層とし、熱融着性合成樹脂層を表裏両面の最外層とする帯状の包材の長手方向(縦方向)の両縁部を重ね合わせて熱融着することにより包材チューブを形成する工程を経て成形される紙容器の内面に露出ずる縦方向の継ぎ目を被覆するために使用する縦シールテープ、及びこの縦シールテープで縦シールした紙容器に関する。 In the present invention, both edges in the longitudinal direction (longitudinal direction) of the strip-shaped packaging material having the paperboard as the base layer and the heat-sealing synthetic resin layer as the outermost layers on both the front and back surfaces are overlapped and heat-sealed. The present invention relates to a vertical sealing tape used for covering a vertical seam exposed on the inner surface of a paper container formed through a step of forming a packaging material tube, and a paper container vertically sealed with the vertical sealing tape.

飲料等を収容する紙容器の技術分野において、シール部に用いられ、その継ぎ目を被覆するためのシールテープとしては、低密度ポリエチレン(以下、LDPEと称する。)樹脂を単独に、或いはLDPE樹脂と直鎖状低密度ポリエチレン(以下、LLDPEと称する。)樹脂とのブレンド品、又はLDPE樹脂と高密度ポリエチレン(以下、HDPEと称する。)樹脂とのブレンド品を用いたLDPE樹脂を主体とするポリエチレン樹脂層を表裏両面の最外層とし、HDPE樹脂、延伸ポリエチレン・テレフタレート(以下、PETと称する。)樹脂、エチレンビニルアルコール共重合体ケン化物(以下、EVOHと称する。)樹脂或いは非晶性コポリエステル樹脂等の材料を用いたガスバリアー性樹脂層を芯層として、芯層と表裏両面の最外層とを、ドライラミネーション法又は押出しラミネーション法によって貼り合わせた3層テープ等が知られている(例えば、特許文献1参照。)。 In the technical field of paper containers for accommodating beverages and the like, low-density polyethylene (hereinafter referred to as LDPE) resin is used alone or as LDPE resin as a sealing tape used for a sealing portion and for covering the seam thereof. Polyethylene mainly composed of LDPE resin using a blended product of linear low density polyethylene (hereinafter referred to as LLDPE) resin or a blended product of LDPE resin and high density polyethylene (hereinafter referred to as HDPE) resin. The resin layer is the outermost layer on both the front and back sides, and HDPE resin, stretched polyethylene / terephthalate (hereinafter referred to as PET) resin, ethylene vinyl alcohol copolymer saponified (hereinafter referred to as EVOH) resin or amorphous copolyester. A three-layer tape or the like is known in which a gas barrier resin layer using a material such as resin is used as a core layer, and the core layer and the outermost layers on both the front and back surfaces are bonded by a dry lamination method or an extrusion lamination method (for example). , Patent Document 1).

こうしたシールテープを、板紙をベース層とし、表裏両面の少なくとも最外層が熱融着性合成樹脂層からなる帯状の包装材料素材(以下、包材と称する。)の長手方向両縁部同士を重ね合わせて縦シールする縦シールテープとして用い、できた包材チューブを紙容器1個分の距離をおいて一定幅を横シールしつつ中身の飲料等を充填し、該横シール領域の中間部を切断して分離して、煉瓦型等の最終形態にしてなるものがある。
上記した包材の長手方向両縁部同士の縦シールと包材チューブの横シールにあって、包材チューブの横シールは、その殆どが高周波溶着によって行われているが、一部超音波溶着や熱シール等によって行われている。
With such a sealing tape, both edges in the longitudinal direction of a strip-shaped packaging material (hereinafter referred to as a packaging material) in which a paperboard is used as a base layer and at least the outermost layers on both the front and back surfaces are composed of a heat-sealing synthetic resin layer are overlapped with each other. It is also used as a vertical sealing tape that vertically seals together, and the packaging material tube that is made is filled with beverages, etc., while horizontally sealing a certain width at a distance of one paper container, and the middle part of the horizontal sealing area is filled. Some are cut and separated to form the final form such as a brick mold.
In the above-mentioned vertical sealing between both edges of the packaging material in the longitudinal direction and the horizontal sealing of the packaging material tube, most of the horizontal sealing of the packaging material tube is performed by high-frequency welding, but some ultrasonic welding is performed. It is done by heat sealing.

特開2001−354916号公報Japanese Unexamined Patent Publication No. 2001-354916

超音波溶着によるシールは、溶着時間と超音波振動と加圧力によって左右され、発振器の出力を上げ振動回数を高めることにより溶着時間を短縮できる。このため、紙容器の製造効率を高めるためには包材チューブの横シールを行う発振器の出力を上げればよい。
しかし、発振器の出力を上げると、振動が中央部に集中し、包材の長手方向両縁部を重ね合わせた継ぎ目を被覆している縦シールテープは、包材の長手方向両縁部の内面側の端部で強い振動を受けることになり、この振動でガスバリアー性樹脂層が薄くなり破断してしまう場合がある。ガスバリアー性樹脂層が破断すると、破断部が経路となって内容液が漏れてしまうおそれがある。
The sealing by ultrasonic welding depends on the welding time, ultrasonic vibration, and pressing force, and the welding time can be shortened by increasing the output of the oscillator and increasing the number of vibrations. Therefore, in order to improve the manufacturing efficiency of the paper container, the output of the oscillator that laterally seals the packaging material tube may be increased.
However, when the output of the oscillator is increased, the vibration is concentrated in the central part, and the vertical sealing tape covering the seam in which both longitudinal edges of the packaging material are overlapped is the inner surface of both longitudinal edges of the packaging material. A strong vibration is received at the end on the side, and this vibration may cause the gas barrier resin layer to become thin and break. When the gas barrier resin layer is broken, the content liquid may leak through the broken portion as a path.

このような事態を解決する手段として、ガスバリアー性樹脂層の両面に、例えば、ナイロンフィルムを積層して縦シールテープの強度をアップさせ、ガスバリアー性樹脂層の破断を防ぐことが考えられる。
しかし、縦シールテープの強度をアップさせると、超音波溶着による横シール時に縦シールテープの両側端部を十分に加圧できなくなり、縦シールテープの両側端部と包材との間に微細な空隙が発生してしまい、この空隙が経路となって内容液が漏れてしまうおそれがある。
As a means for solving such a situation, it is conceivable to laminate, for example, a nylon film on both sides of the gas barrier resin layer to increase the strength of the vertical sealing tape and prevent the gas barrier resin layer from breaking.
However, if the strength of the vertical sealing tape is increased, it becomes impossible to sufficiently pressurize both end portions of the vertical sealing tape during horizontal sealing by ultrasonic welding, and fine particles are formed between the both end portions of the vertical sealing tape and the packaging material. A void may be generated, and the content liquid may leak through the void as a path.

本発明者等は、高出力で発振した超音波振動によるシールで、漏れが生じないように横シールすることができるようにするために、試験、研究を重ねた結果、縦シールテープに振動を吸収し減衰させる作用を持たせることに着眼し、本発明を完成するに至った。 As a result of repeated tests and research, the present inventors have conducted tests and studies to enable the sealing by ultrasonic vibration oscillated at high output to prevent leakage, and as a result, the vertical sealing tape is vibrated. Focusing on having the action of absorbing and attenuating, the present invention has been completed.

本発明の目的は、高出力で発振した超音波振動によるシールで、漏れの生じないように横シールすることができるようにした紙容器で使用される縦シールテープ及び縦シールテープで縦シールした紙容器を提供することにある。 An object of the present invention is a seal by ultrasonic vibration oscillated at high output, and the seal is vertically sealed with a vertical sealing tape and a vertical sealing tape used in a paper container that can be horizontally sealed so as not to cause leakage. To provide paper containers.

上記の目的を達成するために、請求項1に記載の発明は、板紙をベース層とし、熱融着性合成樹脂層を表裏両面の最外層とする帯状の包材の長手方向(縦方向)の両縁部を重ね合わせて熱融着することにより包材チューブを形成する工程を経て成形される紙容器の縦方向の継ぎ目を被覆して縦シールするために使用される縦シールテープであって、ガスバリアー性樹脂層を芯層とし、ガスバリアー性樹脂層の両面に接着樹脂層を介して熱融着性合成樹脂層を積層した積層構造を有し、前記接着樹脂層および/または熱融着性合成樹脂層を形成する接着樹脂に振動吸収材が添加されていることを特徴とする。 In order to achieve the above object, the invention according to claim 1 has a strip-shaped packaging material having a paperboard as a base layer and a heat-sealing synthetic resin layer as the outermost layers on both the front and back surfaces in the longitudinal direction (longitudinal direction). A vertical sealing tape used to cover and vertically seal the vertical seams of a paper container that is formed through the process of forming a packaging material tube by overlapping and heat-sealing both edges of the plastic container. The gas barrier resin layer is used as a core layer, and the gas barrier resin layer has a laminated structure in which a heat-sealing synthetic resin layer is laminated on both sides of the gas barrier resin layer via an adhesive resin layer. It is characterized in that a vibration absorber is added to the adhesive resin forming the fusible synthetic resin layer.

請求項2に記載の発明は、請求項1に記載の、前記振動吸収材は、エラストマーであることを特徴とする。 The invention according to claim 2 is characterized in that the vibration absorber according to claim 1 is an elastomer.

請求項3に記載の発明は、請求項2に記載の、前記エラストマーは、オレフィン系エラストマーまたはスチレン系エラストマーであることを特徴とする。 The invention according to claim 3 is characterized in that the elastomer according to claim 2 is an olefin-based elastomer or a styrene-based elastomer.

請求項4に記載の発明は、請求項1から3のいずれか1項に記載の、前記接着樹脂層を形成する接着樹脂は、ポリエチレン樹脂またはポリプロピレン樹脂であることを特徴とする。 The invention according to claim 4 is characterized in that the adhesive resin forming the adhesive resin layer according to any one of claims 1 to 3 is a polyethylene resin or a polypropylene resin.

請求項5に記載の発明は、請求項1から4のいずれか1項に記載の、前記ガスバリアー性樹脂層を形成するガスバリアー性樹脂は、エチレン−ビニルアルコール共重合体であることを特徴とする。 The invention according to claim 5 is characterized in that the gas barrier resin forming the gas barrier resin layer according to any one of claims 1 to 4 is an ethylene-vinyl alcohol copolymer. And.

請求項6に記載の発明は、板紙をベース層とし、熱融着性合成樹脂層を表裏両面の最外層とする帯状の包材の長手方向(縦方向)の両縁部を重ね合わせて熱融着することにより包材チューブを形成する工程を経て成形される紙容器であって、前記包材チューブ内面の前記包装材料素材の両縁部の縦方向継ぎ目が、ガスバリアー性樹脂層を芯層とし、ガスバリアー性樹脂層の両面に接着樹脂層を介して熱融着性合成樹脂層を積層した積層構造を有し、前記接着樹脂層および/または熱融着性合成樹脂層を形成する接着樹脂に振動吸収材が添加されている縦シールテープによって被覆されて縦シールが施されていることを特徴とする。 In the invention according to claim 6, both edges in the longitudinal direction (longitudinal direction) of the strip-shaped packaging material having the paperboard as the base layer and the heat-sealing synthetic resin layer as the outermost layers on both the front and back surfaces are superposed to heat. A paper container that is formed through a process of forming a packaging material tube by fusing, and the vertical seams of both edges of the packaging material on the inner surface of the packaging material tube are centered on a gas barrier resin layer. As a layer, it has a laminated structure in which a heat-sealing synthetic resin layer is laminated on both sides of a gas barrier resin layer via an adhesive resin layer, and forms the adhesive resin layer and / or the heat-sealing synthetic resin layer. It is characterized in that it is covered with a vertical sealing tape to which a vibration absorbing material is added to an adhesive resin to provide a vertical sealing.

本発明に係る紙容器に使用される縦シールテープによれば、ガスバリアー性樹脂層を芯層とし、ガスバリアー性樹脂層の両面に接着樹脂層を介して熱融着性合成樹脂層を積層した積層構造を有し、接着樹脂層および/または熱融着性合成樹脂層を形成する接着樹脂に振動吸収材が添加されているので、包材チューブの横シールが発振器から高出力で発振された超音波による溶着によるシールであっても、発振器から高出力で発振された超音波振動が振動吸収材で吸収されて減衰し、ガスバリアー性樹脂層の破断を発生させることなくシールすることができることになり、これにより紙容器の製造効率の向上を図ることができる。 According to the vertical sealing tape used for the paper container according to the present invention, the gas barrier resin layer is used as the core layer, and the heat-sealing synthetic resin layer is laminated on both sides of the gas barrier resin layer via the adhesive resin layer. Since the vibration absorber is added to the adhesive resin that forms the adhesive resin layer and / or the heat-sealing synthetic resin layer, the horizontal seal of the packaging material tube is oscillated from the oscillator at high output. Even if the seal is made by welding with ultrasonic waves, the ultrasonic vibration oscillated from the oscillator at high output is absorbed by the vibration absorber and attenuated, so that the seal can be made without causing breakage of the gas barrier resin layer. This makes it possible to improve the manufacturing efficiency of the paper container.

そして、振動吸収材が添加された接着樹脂で形成された接着樹脂層および/または熱融着性合成樹脂層による縦シールテープの強度のアップは僅かであり、超音波溶着による横シール時に縦シールテープの両側端部を十分に加圧でき、縦シールテープの両側端部と包材との間を埋めることができるのでシールの完全性を得ることができる。 The strength of the vertical sealing tape is slightly increased by the adhesive resin layer and / or the heat-sealing synthetic resin layer formed of the adhesive resin to which the vibration absorber is added, and the vertical sealing is performed during the horizontal sealing by ultrasonic welding. Since both side ends of the tape can be sufficiently pressurized and the space between the both side ends of the vertical sealing tape and the packaging material can be filled, the completeness of the seal can be obtained.

また、上記の縦シールテープで縦シールした紙容器によれば、縦シールテープのガスバリアー性樹脂層が破断していないので、液漏れの無い縦シールテープ付紙容器を得ることができる。 Further, according to the paper container vertically sealed with the above-mentioned vertical sealing tape, since the gas barrier resin layer of the vertical sealing tape is not broken, a paper container with a vertical sealing tape without liquid leakage can be obtained.

本発明に係る紙容器で使用される縦シールテープの実施の形態の一例を示す拡大断面図である。It is an enlarged cross-sectional view which shows an example of embodiment of the vertical sealing tape used in the paper container which concerns on this invention. 図1に示す縦シールテープで縦シールして形成した包材チューブを横シールした包材チューブを示す説明図である。It is explanatory drawing which shows the packaging material tube which horizontally sealed the packaging material tube formed by vertical sealing with the vertical sealing tape shown in FIG. 図2のX−X線一部拡大断面説明図である。FIG. 2 is an explanatory view of a partially enlarged cross section of X-ray in FIG.

以下、本発明の実施の形態について説明する。
図1乃至図3は、本発明に係る紙容器で使用される縦シールテープの実施の形態の一例を示すものであり、図1は本例の縦シールテープを示す拡大断面図、図2は図1に示す縦シールテープで縦シールして形成した包材チューブを横シールした包材チューブを示す説明図、図3は図2のX−X線一部拡大断面説明図である。
Hereinafter, embodiments of the present invention will be described.
1 to 3 show an example of an embodiment of the vertical sealing tape used in the paper container according to the present invention, FIG. 1 is an enlarged cross-sectional view showing the vertical sealing tape of this example, and FIG. 2 is an enlarged cross-sectional view. An explanatory view showing a packaging material tube formed by vertically sealing with the vertical sealing tape shown in FIG. 1 and horizontally sealing the packaging material tube, and FIG. 3 is an explanatory view of a partially enlarged cross section taken along line XX of FIG.

本例の縦シールテープ1は、板紙をベース層2とし、熱融着性合成樹脂層3,4を表裏両面の最外層とする帯状の包材5の長手方向(縦方向)の両縁部5a、5bを重ね合わせて熱融着することにより包材チューブ6を形成する工程を経て成形される紙容器7の縦方向の継ぎ目を被覆して縦シールするために使用されるものであり、ガスバリアー性樹脂層8を芯層とし、ガスバリアー性樹脂層8の両面に接着樹脂層9,10を介して熱融着性合成樹脂層11,12を積層した積層構造を有し、接着樹脂層9,10および/または熱融着性合成樹脂層11,12を形成する接着樹脂には振動吸収材が添加されている。 In the vertical seal tape 1 of this example, both edges in the longitudinal direction (longitudinal direction) of the strip-shaped packaging material 5 having the paperboard as the base layer 2 and the heat-sealing synthetic resin layers 3 and 4 as the outermost layers on both the front and back surfaces. It is used to cover and vertically seal the vertical seam of the paper container 7 formed through the step of forming the packaging material tube 6 by superimposing 5a and 5b and heat-sealing them. It has a laminated structure in which the gas barrier resin layer 8 is used as a core layer and the heat-sealing synthetic resin layers 11 and 12 are laminated on both sides of the gas barrier resin layer 8 via the adhesive resin layers 9 and 10. A vibration absorber is added to the adhesive resin forming the layers 9, 10 and / or the heat-sealing synthetic resin layers 11, 12.

芯層となるガスバリアー性樹脂層8は、エチレン−ビニル共重合体(以下、EVOH樹脂という。)、延伸ポリエチレン・テレフタレート樹脂(以下、PET樹脂と言う。)、非晶性コポリエステル樹脂等によって形成することができる。 本例では、EVOH樹脂を使用している。また、ガスバリアー性樹脂層2の厚みは、必要とされるガスバリアー性を発揮できるだけの厚みとすればよい。本例では25μmとなっている。 The gas barrier resin layer 8 serving as the core layer is made of an ethylene-vinyl copolymer (hereinafter referred to as EVOH resin), a stretched polyethylene terephthalate resin (hereinafter referred to as PET resin), an amorphous copolyester resin or the like. Can be formed. In this example, EVOH resin is used. Further, the thickness of the gas barrier resin layer 2 may be such that the required gas barrier property can be exhibited. In this example, it is 25 μm.

ガスバリアー性樹脂層8の両面に接着樹脂層9,10を介して積層した熱融着性合成樹脂層11,12は、低密度ポリエチレン樹脂(以下、LDPE樹脂という。)や直鎖状低密度ポリエチレン樹脂(以下、LLDPE樹脂という。)、またはLDPE樹脂とLLDPE樹脂とのブレンド品、もしくはLDPE樹脂と高密度ポリエチレン樹脂(以下、HDPE樹脂という。)とのブレンド品を用いたLDPE樹脂を主体とするポリエチレン樹脂によって形成することが好ましい。 The heat-sealing synthetic resin layers 11 and 12 laminated on both sides of the gas barrier resin layer 8 via the adhesive resin layers 9 and 10 are a low-density polyethylene resin (hereinafter referred to as LDPE resin) or a linear low-density resin. Mainly LDPE resin using polyethylene resin (hereinafter referred to as LLDPE resin), a blended product of LDPE resin and LLDPE resin, or a blended product of LDPE resin and high-density polyethylene resin (hereinafter referred to as HDPE resin). It is preferably formed of a polyethylene resin to be used.

この熱融着性合成樹脂層11,12の厚みにあては、特に規定しないが、薄すぎるとシール不良が生じたり、厚すぎると経済性を損ねたり、機械適正が損なわれたりするので、20μm〜60μm程度の厚みが好ましい。 The thickness of the heat-sealing synthetic resin layers 11 and 12 is not particularly specified, but if it is too thin, sealing defects will occur, and if it is too thick, economic efficiency will be impaired and mechanical suitability will be impaired. A thickness of about 60 μm is preferable.

ガスバリアー性樹脂層8と熱融着性合成樹脂層11,12の間に積層される接着樹脂層9,10は、ポリエチレン樹脂またはポリプロピレン樹脂で形成されおり、特にHDPE樹脂が好ましい。本例では、HDPE樹脂によって形成されている。 The adhesive resin layers 9 and 10 laminated between the gas barrier resin layer 8 and the heat-sealing synthetic resin layers 11 and 12 are made of polyethylene resin or polypropylene resin, and HDPE resin is particularly preferable. In this example, it is made of HDPE resin.

そして、接着樹脂層9,10および/または熱融着性合成樹脂層11,12を形成する接着樹脂には振動吸収材が添加されている。振動吸収材としては、接着樹脂層9,10および/または熱融着性合成樹脂層11,12に海島状に微分散するゴム成分であれば特に限定されない。
接着樹脂層9,10や熱融着性合成樹脂層11,12を形成するポリエチレン樹脂またはポリプロピレン樹脂に微分散するゴム成分としては、熱可塑性エラストマーであるオレフィン系エラストマー、スチレン系エラストマーが使いやすい。
また、臭気や味、溶出などの内容物適性、安全性の点からもオレフィン系エラストマー、スチレン系エラストマーが好適である。
本例では、接着樹脂層9,10を形成する接着樹脂に振動吸収材が添加されているが、熱融着性合成樹脂層11,12を形成する接着樹脂に振動吸収材が添加されていてもよく、また、接着樹脂層9,10および熱融着性合成樹脂層11,12を形成するそれぞれの接着樹脂に振動吸収材が添加されていてもよい。
る。
A vibration absorber is added to the adhesive resin forming the adhesive resin layers 9, 10 and / or the heat-sealing synthetic resin layers 11, 12. The vibration absorbing material is not particularly limited as long as it is a rubber component that is finely dispersed in the adhesive resin layers 9 and 10 and / or the heat-sealing synthetic resin layers 11 and 12 in a sea-island shape.
As the rubber component finely dispersed in the polyethylene resin or polypropylene resin forming the adhesive resin layers 9 and 10 and the heat-sealing synthetic resin layers 11 and 12, olefin-based elastomers and styrene-based elastomers, which are thermoplastic elastomers, are easy to use.
In addition, olefin-based elastomers and styrene-based elastomers are preferable from the viewpoints of content suitability such as odor, taste, and elution, and safety.
In this example, the vibration absorber is added to the adhesive resin forming the adhesive resin layers 9 and 10, but the vibration absorber is added to the adhesive resin forming the heat-sealing synthetic resin layers 11 and 12. Further, a vibration absorber may be added to each of the adhesive resins forming the adhesive resin layers 9 and 10 and the heat-sealing synthetic resin layers 11 and 12.
NS.

接着樹脂層9,10の厚みについては特に規定しないが、薄すぎると部分的な膜抜けが起こったり、厚すぎると経済性を損ねたりするので、3μm〜20μm程度の厚みが好ましい。 The thickness of the adhesive resin layers 9 and 10 is not particularly specified, but if it is too thin, partial film loss will occur, and if it is too thick, economic efficiency will be impaired. Therefore, a thickness of about 3 μm to 20 μm is preferable.

このように構成された本発明に係る紙容器に使用される縦シールテープによれば、ガスバリアー性樹脂層8を芯層とし、ガスバリアー性樹脂層8の両面に接着樹脂層9,10を介して熱融着性合成樹脂層11,12を積層した積層構造を有し、接着樹脂層9,10および/または熱融着性合成樹脂層11,12を形成する接着樹脂には振動吸収材が添加されているので、包材チューブ6の横シールAが発振器から高出力で発振された超音波による溶着によるシールであっても、発振器から高出力で発振された超音波振動が振動吸収材で吸収されて減衰し、ガスバリアー性樹脂層8の破断を発生させることなくシールすることができる。 According to the vertical sealing tape used for the paper container according to the present invention configured as described above, the gas barrier resin layer 8 is used as the core layer, and the adhesive resin layers 9 and 10 are provided on both sides of the gas barrier resin layer 8. The adhesive resin having a laminated structure in which the heat-sealing synthetic resin layers 11 and 12 are laminated and forming the adhesive resin layers 9 and 10 and / or the heat-sealing synthetic resin layers 11 and 12 is a vibration absorber. Is added, so even if the horizontal seal A of the packaging material tube 6 is a seal made by welding with ultrasonic waves oscillated from the oscillator at high output, the ultrasonic vibration oscillated from the oscillator at high output is the vibration absorber. The gas barrier resin layer 8 can be sealed without causing breakage.

本例では、接着樹脂層9,10および/または熱融着性合成樹脂層11,12を形成する接着樹脂に添加する振動吸収材として、接着樹脂内での微分散性がよいエラストマーが使用されているので、接着樹脂層9,10に均一した振動吸収性が備わるものとなる。 In this example, an elastomer having good fine dispersibility in the adhesive resin is used as the vibration absorber to be added to the adhesive resin forming the adhesive resin layers 9, 10 and / or the heat-sealing synthetic resin layers 11, 12. Therefore, the adhesive resin layers 9 and 10 are provided with uniform vibration absorption.

また、振動吸収材が添加された接着樹脂で形成された接着樹脂層9,10および/または熱融着性合成樹脂層11,12による縦シールテープ1の強度のアップは僅かであり、超音波溶着による横シール時に縦シールテープ1の両側端部1a、1bを十分に加圧でき、縦シールテープ1の両側端部1a、1bと包材5との間を埋めることができるのでシールの完全性を得ることができる。 Further, the strength of the vertical sealing tape 1 is slightly increased by the adhesive resin layers 9 and 10 and / or the heat-sealing synthetic resin layers 11 and 12 formed of the adhesive resin to which the vibration absorber is added, and the ultrasonic waves are generated. At the time of horizontal sealing by welding, both side end portions 1a and 1b of the vertical sealing tape 1 can be sufficiently pressurized, and the space between the both side end portions 1a and 1b of the vertical sealing tape 1 and the packaging material 5 can be filled, so that the sealing is complete. You can get sex.

また、上記の縦シールテープ1で縦シールBをした紙容器7によれば、縦シールテープ1のガスバリアー性樹脂層8が破断していないので、液漏れの無い縦シールテープ付紙容器を得ることができる。 Further, according to the paper container 7 in which the vertical seal B is formed with the vertical seal tape 1, the gas barrier resin layer 8 of the vertical seal tape 1 is not broken, so that the paper container with the vertical seal tape without liquid leakage is used. Obtainable.

1 縦シールテープ
1a、1b 縦シールテープの側端部
2 ベース層
3,4 熱融着性合成樹脂層
5 包材
5a,5b 縁部
6 包材チューブ
8 ガスバリアー性樹脂層
9,10 接着樹脂層
11,12 熱融着性合成樹脂層
A 横シール
B 縦シール
1 Vertical sealing tape 1a, 1b Side end of vertical sealing tape 2 Base layer 3, 4 Heat-sealing synthetic resin layer 5 Packaging material 5a, 5b Edge 6 Packaging material tube 8 Gas barrier resin layer 9,10 Adhesive resin Layers 11 and 12 Heat-sealing synthetic resin layer A Horizontal seal B Vertical seal

Claims (6)

板紙をベース層とし、熱融着性合成樹脂層を表裏両面の最外層とする帯状の包材の長手方向(縦方向)の両縁部を重ね合わせて熱融着することにより包材チューブを形成する工程を経て成形される紙容器の縦方向の継ぎ目を被覆して縦シールするために使用される縦シールテープであって、
ガスバリアー性樹脂層を芯層とし、ガスバリアー性樹脂層の両面に接着樹脂層を介して熱融着性合成樹脂層を積層した積層構造を有し、前記接着樹脂層および/または熱融着性合成樹脂層を形成する接着樹脂に振動吸収材が添加されていることを特徴とする紙容器で使用される縦シールテープ。
The packaging material tube is formed by superimposing both longitudinal (longitudinal) edges of the band-shaped packaging material, which uses paperboard as the base layer and the heat-sealing synthetic resin layer as the outermost layers on both the front and back sides, and heat-sealing the packaging material tube. A vertical sealing tape used to cover and vertically seal the vertical seams of a paper container that is formed through the forming process.
It has a laminated structure in which a gas barrier resin layer is used as a core layer and a heat-sealing synthetic resin layer is laminated on both sides of the gas barrier resin layer via an adhesive resin layer, and the adhesive resin layer and / or heat fusion is provided. A vertical sealing tape used in paper containers, characterized in that a vibration absorber is added to the adhesive resin that forms the sex synthetic resin layer.
前記振動吸収材は、エラストマーであることを特徴とする請求項1に記載の紙容器で使用される縦シールテープ。 The vertical sealing tape used in the paper container according to claim 1, wherein the vibration absorber is an elastomer. 前記エラストマーは、オレフィン系エラストマーまたはスチレン系エラストマーであることを特徴とする請求項2に記載の紙容器で使用される縦シールテープ。 The vertical sealing tape used in the paper container according to claim 2, wherein the elastomer is an olefin-based elastomer or a styrene-based elastomer. 前記接着樹脂層を形成する接着樹脂は、ポリエチレン樹脂またはポリプロピレン樹脂であることを特徴とする請求項1から3のいずれか1項に記載の紙容器で使用される縦シールテープ。 The vertical sealing tape used in the paper container according to any one of claims 1 to 3, wherein the adhesive resin forming the adhesive resin layer is a polyethylene resin or a polypropylene resin. 前記ガスバリアー性樹脂層を形成するガスバリアー性樹脂は、エチレン−ビニルアルコール共重合体であることを特徴とする請求項1から4のいずれか1項に記載の紙容器で使用される縦シールテープ。 The vertical seal used in the paper container according to any one of claims 1 to 4, wherein the gas barrier resin forming the gas barrier resin layer is an ethylene-vinyl alcohol copolymer. tape. 板紙をベース層とし、熱融着性合成樹脂層を表裏両面の最外層とする帯状の包材の長手方向(縦方向)の両縁部を重ね合わせて熱融着することにより包材チューブを形成する工程を経て成形される紙容器であって、
前記包材チューブ内面の前記包装材料素材の両縁部の縦方向継ぎ目が、ガスバリアー性樹脂層を芯層とし、ガスバリアー性樹脂層の両面に接着樹脂層を介して熱有着性合成樹脂層を積層した積層構造を有し、前記接着樹脂層および/または熱融着性合成樹脂層を形成する接着樹脂に振動吸収材が添加されている縦シールテープによって被覆されて縦シールが施されていることを特徴とする紙容器。
The packaging material tube is formed by superimposing both longitudinal (longitudinal) edges of the strip-shaped packaging material with the paperboard as the base layer and the heat-sealing synthetic resin layer as the outermost layers on both the front and back sides. A paper container that is molded through the forming process.
The vertical seams of both edges of the packaging material on the inner surface of the packaging material tube have a gas barrier resin layer as a core layer, and a heat-adhesive synthetic resin layer is provided on both sides of the gas barrier resin layer via an adhesive resin layer. The adhesive resin that forms the adhesive resin layer and / or the heat-sealing synthetic resin layer is covered with a vertical seal tape to which a vibration absorber is added to provide a vertical seal. A paper container characterized by being present.
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JPH11235768A (en) * 1997-12-18 1999-08-31 Dainippon Printing Co Ltd Liquid paper container, body sticking sleeve, and method and apparatus for its manufacture
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