JP2021068622A - Method for manufacturing gas diffusion layer integrated gasket - Google Patents

Method for manufacturing gas diffusion layer integrated gasket Download PDF

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JP2021068622A
JP2021068622A JP2019193926A JP2019193926A JP2021068622A JP 2021068622 A JP2021068622 A JP 2021068622A JP 2019193926 A JP2019193926 A JP 2019193926A JP 2019193926 A JP2019193926 A JP 2019193926A JP 2021068622 A JP2021068622 A JP 2021068622A
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gasket
diffusion layer
gas diffusion
gap
mounting member
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JP7280166B2 (en
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元 由井
Hajime Yui
元 由井
健一 大場
Kenichi Oba
健一 大場
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Nok Corp
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Nok Corp
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Gasket Seals (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)

Abstract

To provide a method for manufacturing a gas diffusion layer integrated gasket in which no gap remains between a gasket mounting member and a gas diffusion layer, so that it is possible to prevent an electrolyte membrane from entering the gap and thus being damaged.SOLUTION: As a step, first, a gasket mounting member 51 and a gas diffusion layer 41A in a fuel battery cell are arranged on the same plane with a gap c being set between them. Next, a screen mask 82 including a printing portion 82a for forming a gasket main body 61 and a printing portion 82b for forming a gap filling member 71 which fills the gap c and integrates the gasket mounting member 51 and the gas diffusion layer 41A is covered on the plane of the gasket mounting member 51, a molding material G for forming the gasket main body 61 is coated, the molding material G for forming the gap filling member 71 is filled, and the molding material G is solidified.SELECTED DRAWING: Figure 4

Description

本発明は、ガス拡散層一体ガスケット（ＧＤＬ一体ガスケット）の製造方法に関する。 The present invention relates to a method for manufacturing a gas diffusion layer integrated gasket (GDL integrated gasket).

燃料電池では、セル内部の燃料ガスが外部へ漏洩しないよう、またセル外部の異物が内部へ侵入しないようにガスケットが装着される。 In the fuel cell, a gasket is attached so that the fuel gas inside the cell does not leak to the outside and foreign matter outside the cell does not enter the inside.

図５（Ａ）はその一例を示すもので、一対のセパレータ１１１Ａ，１１１Ｂの間に内部積層体１２１が挟み込まれ、そのセル外側（図では左方）に位置してガスケット１３１が同じく一対のセパレータ１１１Ａ，１１１Ｂの間に挟み込まれる。 FIG. 5A shows an example thereof, in which the internal laminate 121 is sandwiched between the pair of separators 111A and 111B, and the gasket 131 is located on the outside of the cell (left side in the drawing) and the gasket 131 is also a pair of separators. It is sandwiched between 111A and 111B.

内部積層体１２１は、電解質膜１２３および一対の電極１２４Ａ，１２４Ｂよりなる膜電極複合体（ＭＥＡ）１２２を一対のガス拡散層（ＧＤＬ）１２５Ａ，１２５Ｂによって挟み込んだ構造とされ、これらの構成要素のうちで電解質膜１２３だけがその平面積を大きく形成されてガスケット１３１のほうへ突出している。 The inner laminate 121 has a structure in which a membrane electrode composite (MEA) 122 composed of an electrolyte membrane 123 and a pair of electrodes 124A and 124B is sandwiched between a pair of gas diffusion layers (GDL) 125A and 125B, and is composed of these components. Of these, only the electrolyte membrane 123 has a large flat area formed and protrudes toward the gasket 131.

ガスケット１３１は、ゴム状弾性体よりなるガスケット本体１３２を有し、これ単独では取り扱い性に難点があることから、ガスケット本体１３２をシート状のガスケット取付部材１３３によって保持する構造とされている。ガスケット本体１３２は、ガスケット取付部材１３３に接着固定されるガスケット基部１３２ａと、断面三角形状のシールリップ１３２ｂとを一体に備えている。 The gasket 131 has a gasket body 132 made of a rubber-like elastic body, and since it is difficult to handle by itself, the gasket body 132 is held by a sheet-shaped gasket mounting member 133. The gasket main body 132 integrally includes a gasket base 132a that is adhesively fixed to the gasket mounting member 133, and a seal lip 132b having a triangular cross section.

内部積層体１２１とガスケット１３１は、燃料電池のスタッキング時に電解質膜１２３とガスケット取付部材１３３とを接着剤１４１によって接着することにより一体化される。 The internal laminate 121 and the gasket 131 are integrated by adhering the electrolyte membrane 123 and the gasket mounting member 133 with an adhesive 141 when stacking the fuel cell.

特開２０１７−１５２２８１号公報JP-A-2017-152281

しかしながら上記構造によるとスタッキング時、同一平面上に配置される一方のガス拡散層１２５Ａとガスケット取付部材１３３との間に所定の幅ｗ０を備える隙間ｃが形成されるため、図５（Ｂ）に示すように接着剤硬化時の熱によって線膨張する電解質膜１２３がこの隙間ｃに入り込んで破損することが懸念される。 However, since the time of stacking according to the above structure, a gap c with a predetermined width w 0 between one gas diffusion layer 125A disposed on the same plane as the gasket mounting member 133 is formed, and FIG. 5 (B) As shown in the above, there is a concern that the electrolyte membrane 123, which linearly expands due to the heat generated when the adhesive is cured, enters the gap c and is damaged.

本発明は、ガス拡散層とガスケット取付部材との間に隙間が残らず、よって電解質膜が隙間に入り込んで破損するのを防止することができるガス拡散層一体ガスケットの製造方法を提供することを課題とする。 The present invention provides a method for manufacturing a gas diffusion layer integrated gasket in which no gap remains between the gas diffusion layer and the gasket mounting member, and thus the electrolyte membrane can be prevented from entering the gap and being damaged. Make it an issue.

本発明のガス拡散層一体ガスケットの製造方法は、燃料電池セルにおけるシート状のガスケット取付部材とガス拡散層とを前記両者の間に隙間を設定した状態で同一平面上に並べる工程と、前記ガスケット取付部材の平面上にガスケット本体を形成する印刷部ならびに前記隙間を埋め前記ガスケット取付部材および前記ガス拡散層を一体化する隙間埋め部材を形成する印刷部を備えるスクリーン印刷用のスクリーンを前記ガスケット取付部材および前記ガス拡散層に被せる工程と、前記スクリーンを被せた前記ガスケット取付部材に対し前記ガスケット本体を形成する成形材料を塗布する工程と、前記スクリーンを被せた前記隙間に対し前記隙間埋め部材を形成する成形材料を充填する工程と、前記塗布または充填した成形材料を固化させる工程と、を備える。 The method for manufacturing a gasket integrated gasket with a gas diffusion layer of the present invention includes a step of arranging a sheet-shaped gasket mounting member and a gas diffusion layer in a fuel cell on the same plane with a gap set between them, and the gasket. The gasket mounts a screen for screen printing including a printing portion that forms a gasket body on a flat surface of the mounting member and a printing portion that fills the gap and forms a gap filling member that integrates the gasket mounting member and the gas diffusion layer. A step of covering the member and the gas diffusion layer, a step of applying a molding material for forming the gasket body to the gasket mounting member covered with the screen, and a step of applying the gap filling member to the gap covered with the screen. It includes a step of filling the molding material to be formed and a step of solidifying the coated or filled molding material.

本発明によれば、ガス拡散層とシート状ガスケット取付部材との間に隙間が残らず、よって電解質膜が隙間に入り込んで破損するのを防止することができる。 According to the present invention, no gap remains between the gas diffusion layer and the sheet-shaped gasket mounting member, and thus it is possible to prevent the electrolyte membrane from entering the gap and being damaged.

実施の形態の製造方法によって製造するガス拡散層一体ガスケットの平面図Top view of the gas diffusion layer integrated gasket manufactured by the manufacturing method of the embodiment. 同ガス拡散層一体ガスケットの一部拡大断面図であって図１におけるＥ−Ｅ線拡大断面図A partially enlarged cross-sectional view of the gas diffusion layer integrated gasket, which is an enlarged cross-sectional view taken along line EE in FIG. 同ガス拡散層一体ガスケットを組み込んだ燃料電池セルの一部断面図Partial cross-sectional view of a fuel cell that incorporates the same gas diffusion layer integrated gasket 同製造方法の工程説明図Process explanatory diagram of the same manufacturing method （Ａ）は背景技術で説明した燃料電池セルの要部断面図、（Ｂ）はその不具合発生状態を示す燃料電池セルの要部断面図(A) is a cross-sectional view of a main part of the fuel cell described in the background technology, and (B) is a cross-sectional view of the main part of the fuel cell showing the state of occurrence of the defect.

図１および図２は、実施の形態の製造方法によって製造するガス拡散層一体ガスケット３１を単体で示し、図３はこのガス拡散層一体ガスケット３１を燃料電池セルに組み込んだ状態を示している。 1 and 2 show a single gas diffusion layer integrated gasket 31 manufactured by the manufacturing method of the embodiment, and FIG. 3 shows a state in which the gas diffusion layer integrated gasket 31 is incorporated in a fuel cell.

図１および図２に示すように、ガス拡散層一体ガスケット３１は、一対のガス拡散層４１Ａ，４１Ｂ（図３）のうちの一方のガス拡散層４１Ａと、このガス拡散層４１Ａと同一平面上に配置され、ガス拡散層４１Ａの周囲を囲むよう枠状に形成され、ガス拡散層４１Ａとの間に所定の幅ｗ１の隙間ｃを形成するシート状のガスケット取付部材５１と、ガスケット取付部材５１の平面上に接着固定され、ガス拡散層４１Ａの周囲を囲むよう枠状に形成されたガスケット本体６１と、前記隙間ｃを埋めるようガスケット取付部材５１およびガス拡散層４１Ａ間に配置され、両者５１，４１Ａに接着固定され両者５１，４１Ａを一体化した隙間埋め部材７１とを一体的に備えている。 As shown in FIGS. 1 and 2, the gas diffusion layer integrated gasket 31 is on the same plane as the gas diffusion layer 41A of one of the pair of gas diffusion layers 41A and 41B (FIG. 3) and the gas diffusion layer 41A. disposed, is formed in a frame shape so as to surround the periphery of the gas diffusion layer 41A, a sheet-shaped gasket mounting member 51 to form a predetermined gap c in width w 1 between the gas diffusion layer 41A, a gasket mounting member A gasket body 61 which is adhesively fixed on the plane of 51 and formed in a frame shape so as to surround the periphery of the gas diffusion layer 41A, and is arranged between the gasket mounting member 51 and the gas diffusion layer 41A so as to fill the gap c, both of which. It is integrally provided with a gap filling member 71 which is adhesively fixed to 51 and 41A and integrates both 51 and 41A.

ガス拡散層４１Ａは、所定の厚みを備える平板状に形成され、図１に示すように平面長方形状に形成されている。ガス拡散層４１Ａは、カーボンペーパー等によって形成されている。 The gas diffusion layer 41A is formed in a flat plate shape having a predetermined thickness, and is formed in a flat rectangular shape as shown in FIG. The gas diffusion layer 41A is formed of carbon paper or the like.

ガスケット取付部材５１は、これも所定の厚みを備える平板状に形成され、上記したようにガス拡散層４１Ａの周囲を囲むように枠状に形成されている。また、その四隅それぞれに、スタック組立て時にマニホールド穴とされる厚み方向に貫通する透孔５２が設けられている。ガスケット取付部材５１は、ＰＰ、ＰＥＮ、ＰＩ、ＰＰＳ、ＰＳＰまたはＰＥＮ等よりなるフィルム材によって形成されている。ガスケット取付部材５１はガスケット本体６１を保持しその取り扱い性を向上させることからフィルム状ガスケット保持部材とも称され、或いはガスケット基材または単に基材とも称される。 The gasket mounting member 51 is also formed in a flat plate shape having a predetermined thickness, and is formed in a frame shape so as to surround the periphery of the gas diffusion layer 41A as described above. Further, each of the four corners is provided with a through hole 52 penetrating in the thickness direction, which is a manifold hole at the time of stack assembly. The gasket mounting member 51 is formed of a film material made of PP, PEN, PI, PPS, PSP, PEN, or the like. The gasket mounting member 51 is also referred to as a film-shaped gasket holding member because it holds the gasket body 61 and improves its handleability, or is also referred to as a gasket base material or simply a base material.

ガスケット本体６１は、これも所定の厚みを備える平板状に形成され、上記したようにガス拡散層４１Ａの周囲を囲むように枠状に形成されている。また、前記各透孔５２の周囲を囲むようにしてマニホールド用シール部６２が一体に設けられている。ガスケット本体６１は上記図５（Ａ）（Ｂ）に示したガスケット本体１３２と異なり断面三角形状のシールリップ１３２ｂを備えておらず、その代わりとして平面状のシール面６３を備えている。ガスケット本体６１は、ＶＭＱ、ＥＰＤＭまたはＦＫＭ等よりなるゴム状弾性材によって形成されている。 The gasket body 61 is also formed in a flat plate shape having a predetermined thickness, and is formed in a frame shape so as to surround the periphery of the gas diffusion layer 41A as described above. Further, a manifold seal portion 62 is integrally provided so as to surround the periphery of each of the through holes 52. Unlike the gasket main body 132 shown in FIGS. 5 (A) and 5 (B) above, the gasket main body 61 does not have a seal lip 132b having a triangular cross section, and instead has a flat seal surface 63. The gasket body 61 is formed of a rubber-like elastic material made of VMQ, EPDM, FKM or the like.

隙間埋め部材７１は、前記隙間ｃを埋め、かつガスケット取付部材５１およびガス拡散層４１Ａに対しそれぞれ接着固定されてガス拡散層４１Ａとガスケット取付部材５１とをこの隙間埋め部材７１を介して一体化するために設けられており、隙間ｃがガス拡散層４１Ａの周囲の全周に亙って設けられているので、この隙間埋め部材７１もガス拡散層４１Ａの周囲の全周に亙って設けられている。 The gap filling member 71 fills the gap c and is adhesively fixed to the gasket mounting member 51 and the gas diffusion layer 41A, respectively, and the gas diffusion layer 41A and the gasket mounting member 51 are integrated via the gap filling member 71. Since the gap c is provided over the entire circumference of the gas diffusion layer 41A, the gap filling member 71 is also provided over the entire circumference of the gas diffusion layer 41A. Has been done.

また、隙間埋め部材７１は図２に示すように、隙間ｃ内に充填される隙間充填部７２と、この隙間充填部７２の厚み方向一方（図では上方）に重ねられ、隙間充填部７２の幅ｗ１（隙間ｃの幅ｗ１と同じ）よりも大きな幅ｗ２を備え、幅方向一方の端部７３ａをシート状ガスケット取付部材５１の平面上に重ねられ、他方の端部７３ｂをガス拡散層４１Ａの平面上に重ねられた隙間被覆部７３とを一体に備える形状とされ、これによりガスケット取付部材５１およびガス拡散層４１Ａに対する接着面積が拡大されている。ガス拡散層４１Ａの厚みとガスケット取付部材５１の厚みが同じまたは略同じである場合、隙間被覆部７３の厚みｔ１はガスケット本体６１の厚みｔ２と同じまたは略同じに形成されても良い。隙間埋め部材７１全体としての厚みｔ３はガスケット取付部材５１の厚みおよびガスケット本体６１の厚みの和ｔ４と同じまたは略同じに形成されても良い。隙間埋め部材７１は、ＶＭＱ、ＥＰＤＭまたはＦＫＭ等よりなるゴム状弾性材によって形成されている。隙間埋め部材７１はガスケット本体６１と同一種類の成形材料によって形成されているが、ガスケット本体６１と異なる種類の成形材料によって形成されても良い。 Further, as shown in FIG. 2, the gap filling member 71 is overlapped with the gap filling portion 72 filled in the gap c and the gap filling portion 72 in one of the thickness directions (upper in the figure) of the gap filling portion 72. It has a width w 2 larger than the width w 1 (the same as the width w 1 of the gap c), one end 73a in the width direction is overlapped on the plane of the sheet gasket mounting member 51, and the other end 73b is gas. The shape is such that the gap covering portion 73 stacked on the plane of the diffusion layer 41A is integrally provided, whereby the adhesion area to the gasket mounting member 51 and the gas diffusion layer 41A is expanded. When the thickness of the gas diffusion layer 41A and the thickness of the gasket mounting member 51 are the same or substantially the same, the thickness t 1 of the gap covering portion 73 may be formed to be the same as or substantially the same as the thickness t 2 of the gasket body 61. The thickness t 3 of the gap filling member 71 as a whole may be formed to be the same as or substantially the same as the sum t 4 of the thickness of the gasket mounting member 51 and the thickness of the gasket body 61. The gap filling member 71 is formed of a rubber-like elastic material made of VMQ, EPDM, FKM, or the like. The gap filling member 71 is formed of the same type of molding material as the gasket body 61, but may be formed of a different type of molding material from the gasket body 61.

上記構成のガス拡散層一体ガスケット３１は図３に示すように、電解質膜２２および一対の電極２３Ａ，２３Ｂよりなる膜電極複合体２１や他方のガス拡散層４１Ｂとともに一対のセパレータ１１Ａ，１１Ｂの間に挟み込まれる。一対のセパレータ１１Ａ，１１Ｂのうち一方のセパレータ１１Ａはガス拡散層一体ガスケット３１と全面的に接触し、これを保持する。他方のセパレータ１１Ｂには、この他方のセパレータ１１Ｂに対しガスケット本体６１を接触させるため、ガスケット本体６１のほうへ向けて屈曲した屈曲部１２が設けられている。セパレータ１１Ｂが金属セパレータである場合、屈曲部１２はプレス加工によって容易に形成される。 As shown in FIG. 3, the gas diffusion layer integrated gasket 31 having the above configuration is between the pair of separators 11A and 11B together with the membrane electrode composite 21 composed of the electrolyte membrane 22 and the pair of electrodes 23A and 23B and the other gas diffusion layer 41B. It is sandwiched between. One of the pair of separators 11A and 11B, the separator 11A, comes into full contact with the gas diffusion layer integrated gasket 31 and holds it. The other separator 11B is provided with a bent portion 12 that is bent toward the gasket body 61 in order to bring the gasket body 61 into contact with the other separator 11B. When the separator 11B is a metal separator, the bent portion 12 is easily formed by press working.

つぎに、上記ガス拡散層一体ガスケット３１の製造方法を説明する。製造に際してはスクリーン印刷法を実施し、スクリーン印刷機を使用し、すなわちガスケット取付部材５１およびガス拡散層４１Ａをスクリーン印刷機にセットし、隙間埋め部材７１を形成するゴム材料にて両者５１，４１Ａを接合する。工程としては、以下のようになる。 Next, a method of manufacturing the gas diffusion layer integrated gasket 31 will be described. In the production, a screen printing method is carried out, and a screen printing machine is used, that is, the gasket mounting member 51 and the gas diffusion layer 41A are set in the screen printing machine, and both 51 and 41A are made of a rubber material forming the gap filling member 71. To join. The process is as follows.

すなわち先ず、図４（Ａ）に示すように、あらかじめ製品形状に形成したシート状のガスケット取付部材５１およびガス拡散層４１Ａを両者５１，４１Ａの間に隙間ｃを設定した状態で同一平面上（作業台８１上）に並べて配置する。これにより枠状を呈するガスケット取付部材５１の内側（内周側）に隙間ｃを介してガス拡散層４１Ａが配置され、ガス拡散層４１Ａの外側（外周側）に隙間ｃを介してガスケット取付部材５１が配置されることになる。 That is, first, as shown in FIG. 4A, the sheet-shaped gasket mounting member 51 and the gas diffusion layer 41A formed in advance in the product shape are placed on the same plane with a gap c set between both 51 and 41A. Arrange them side by side on the workbench 81). As a result, the gas diffusion layer 41A is arranged inside (inner peripheral side) of the gasket mounting member 51 having a frame shape via the gap c, and the gasket mounting member is placed on the outside (outer peripheral side) of the gas diffusion layer 41A via the gap c. 51 will be placed.

次いで、図４（Ｂ）に示すように、ガスケット取付部材５１およびガス拡散層４１Ａにスクリーン印刷用のスクリーン（マスク）８２を被せる。スクリーン８２にはあらかじめ、ガスケット本体６１を形成すべく成形材料を透過させる印刷部（ガスケット取付部材５１の平面上にガスケット本体６１を形成する印刷部）８２ａと、隙間埋め部材７１を形成すべく成形材料を透過させる印刷部（隙間ｃを埋めガスケット取付部材５１およびガス拡散層４１Ａを一体化する隙間埋め部材７１を形成する印刷部）８２ｂが設けられている。 Next, as shown in FIG. 4B, the gasket mounting member 51 and the gas diffusion layer 41A are covered with a screen (mask) 82 for screen printing. The screen 82 is formed in advance to form a printing portion (printing portion that forms the gasket body 61 on the plane of the gasket mounting member 51) 82a that allows the molding material to pass through to form the gasket body 61, and a gap filling member 71. A printing portion (a printing portion that fills the gap c and forms a gap filling member 71 that integrates the gasket mounting member 51 and the gas diffusion layer 41A) is provided to allow the material to pass through.

次いで、図４（Ｃ）に示すように、スクリーン８２を被せたガスケット取付部材５１およびガス拡散層４１Ａに対しスクレーパ８３等を作動させてペースト状の成形材料Ｇを塗布し、固化させる。尚、ここでは、ガスケット本体６１と隙間埋め部材７１とを同一種類の成形材料によって形成することを前提としているため、スクリーン８２を被せたガスケット取付部材５１に対しガスケット本体６１を形成する成形材料Ｇを塗布する工程とスクリーン８２を被せた隙間ｃに対し隙間埋め部材７１を形成する成形材料Ｇを充填する工程とを一度の塗布作業で行っている。これに対しガスケット本体６１と隙間埋め部材７１とを異なる種類の成形材料によって形成する場合には、スクリーン８２を被せたガスケット取付部材５１に対しガスケット本体６１を形成する成形材料Ｇを塗布する工程とスクリーン８２を被せた隙間ｃに対し隙間埋め部材７１を形成する成形材料Ｇを充填する工程とを個別に行うことも考えられる。 Next, as shown in FIG. 4C, a scraper 83 or the like is operated on the gasket mounting member 51 and the gas diffusion layer 41A covered with the screen 82 to apply the paste-like molding material G and solidify it. Since it is assumed here that the gasket body 61 and the gap filling member 71 are formed of the same type of molding material, the molding material G for forming the gasket body 61 with respect to the gasket mounting member 51 covered with the screen 82. And the step of filling the molding material G for forming the gap filling member 71 with respect to the gap c covered with the screen 82 are performed in one coating operation. On the other hand, when the gasket body 61 and the gap filling member 71 are formed of different types of molding materials, a step of applying the molding material G forming the gasket body 61 to the gasket mounting member 51 covered with the screen 82. It is also conceivable to individually fill the gap c covered with the screen 82 with the molding material G for forming the gap filling member 71.

次いで、スクリーン８１を取り外すと図４（Ｃ）に示すように、ガスケット取付部材５１の平面上にガスケット本体６１が形成され、ガスケット取付部材５１とガス拡散層４１Ａとの間に隙間埋め部材７１が形成される。接着剤は事前に塗布され、よってガスケット取付部材５１の平面上にガスケット本体６１が接着固定されるとともに、ガスケット取付部材５１とガス拡散層４１Ａの双方に対し隙間埋め部材７１が接着固定され、両者５１，４１Ａが一体化される。 Next, when the screen 81 is removed, as shown in FIG. 4C, the gasket body 61 is formed on the flat surface of the gasket mounting member 51, and the gap filling member 71 is formed between the gasket mounting member 51 and the gas diffusion layer 41A. It is formed. The adhesive is applied in advance, so that the gasket body 61 is adhesively fixed on the flat surface of the gasket mounting member 51, and the gap filling member 71 is adhesively fixed to both the gasket mounting member 51 and the gas diffusion layer 41A. 51 and 41A are integrated.

上記構成のガス拡散層一体ガスケット３１およびその製造方法によれば、ガスケット取付部材５１およびガス拡散層４１Ａ間に形成される隙間ｃが隙間埋め部材７１によって埋められ、結果、隙間ｃが消失して隙間ｃが残されないことになる。したがって電解質膜２２が隙間ｃに入り込んで破損したり変形したりするのを未然に防止することが可能とされる。 According to the gas diffusion layer integrated gasket 31 having the above configuration and the manufacturing method thereof, the gap c formed between the gasket mounting member 51 and the gas diffusion layer 41A is filled by the gap filling member 71, and as a result, the gap c disappears. No gap c is left. Therefore, it is possible to prevent the electrolyte membrane 22 from entering the gap c and being damaged or deformed.

また、上記製造方法によれば、ガスケット本体６１および隙間埋め部材７１を同時に成形することが可能とされる。ガスケット本体６１および隙間埋め部材７１はこれらを一体に形成することにしても良い。 Further, according to the above manufacturing method, the gasket main body 61 and the gap filling member 71 can be molded at the same time. The gasket body 61 and the gap filling member 71 may be integrally formed of these.

１１Ａ，１１Ｂ セパレータ
１２ 屈曲部
２１ 膜電極複合体
２２ 電解質膜
２３Ａ，２３Ｂ 電極
３１ ガス拡散層一体ガスケット
４１Ａ，４１Ｂ ガス拡散層
５１ ガスケット取付部材
５２ 透孔
６１ ガスケット本体
６２ マニホールド用シール部
６３ シール面
７１ 隙間埋め部材
７２ 隙間充填部
７３ 隙間被覆部
７３ａ，７３ｂ 端部
８１ 作業台
８２ スクリーン
８２ａ，８２ｂ 印刷部
８３ スクレーパ
ｃ 隙間
Ｇ 成形材料
11A, 11B Separator 12 Bending part 21 Membrane electrode composite 22 Electrolyte film 23A, 23B Electrode 31 Gas diffusion layer integrated gasket 41A, 41B Gas diffusion layer 51 Gasket mounting member 52 Through hole 61 Gasket body 62 Manifold sealing part 63 Sealing surface 71 Gap filling member 72 Gap filling part 73 Gap covering part 73a, 73b End part 81 Worktable 82 Screen 82a, 82b Printing part 83 Scraper c Gap G Molding material

Claims (4)

燃料電池セルにおけるシート状のガスケット取付部材とガス拡散層とを前記両者の間に隙間を設定した状態で同一平面上に並べる工程と、
前記ガスケット取付部材の平面上にガスケット本体を形成する印刷部ならびに前記隙間を埋め前記ガスケット取付部材および前記ガス拡散層を一体化する隙間埋め部材を形成する印刷部を備えるスクリーン印刷用のスクリーンを前記ガスケット取付部材および前記ガス拡散層に被せる工程と、
前記スクリーンを被せた前記ガスケット取付部材に対し前記ガスケット本体を形成する成形材料を塗布する工程と、
前記スクリーンを被せた前記隙間に対し前記隙間埋め部材を形成する成形材料を充填する工程と、
前記塗布または充填した成形材料を固化させる工程と、
を備えることを特徴とするガス拡散層一体ガスケットの製造方法。 A step of arranging a sheet-shaped gasket mounting member and a gas diffusion layer in a fuel cell on the same plane with a gap set between them.
A screen for screen printing comprising a printing portion for forming a gasket body on a flat surface of the gasket mounting member and a printing portion for filling the gap and forming a gap filling member for integrating the gasket mounting member and the gas diffusion layer. The process of covering the gasket mounting member and the gas diffusion layer,
A step of applying a molding material for forming the gasket body to the gasket mounting member covered with the screen, and
A step of filling the gap covered with the screen with a molding material for forming the gap filling member, and
The step of solidifying the coated or filled molding material and
A method for manufacturing a gas diffusion layer integrated gasket. 請求項１記載の製造方法において、
前記ガスケット本体と前記隙間埋め部材とを同一種類の成形材料によって形成することを特徴とするガス拡散層一体ガスケットの製造方法。 In the manufacturing method according to claim 1,
A method for manufacturing a gas diffusion layer integrated gasket, wherein the gasket body and the gap filling member are formed of the same type of molding material. 請求項１記載の製造方法において、
前記スクリーンを被せた前記ガスケット取付部材に対し前記ガスケット本体を形成する成形材料を塗布する工程と前記スクリーンを被せた前記隙間に対し前記隙間埋め部材を形成する成形材料を充填する工程とを一度の塗布作業で行うことを特徴とするガス拡散層一体ガスケットの製造方法。 In the manufacturing method according to claim 1,
The step of applying the molding material forming the gasket body to the gasket mounting member covered with the screen and the step of filling the gap covered with the screen with the molding material forming the gap filling member are performed once. A method for manufacturing a gas diffusion layer integrated gasket, which is characterized by performing a coating operation. 請求項１、２または３記載の製造方法において、
前記隙間埋め部材は、前記隙間内に充填される隙間充填部と、前記隙間充填部の厚み方向一方に重ねられ、前記隙間充填部よりも大きな幅を備え、幅方向一方の端部を前記シート状ガスケット取付部材に重ね、他方の端部を前記ガス拡散層に重ねる隙間被覆部とを一体に備えることを特徴とするガス拡散層一体ガスケットの製造方法。
In the manufacturing method according to claim 1, 2 or 3,
The gap filling member is overlapped with a gap filling portion filled in the gap and one end in the thickness direction of the gap filling portion, has a width larger than that of the gap filling portion, and has one end in the width direction as the sheet. A method for manufacturing a gas diffusion layer integrated gasket, which is integrally provided with a gap covering portion which is overlapped with a shaped gasket mounting member and whose other end is overlapped with the gas diffusion layer.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017004671A (en) * 2015-06-08 2017-01-05 Nok株式会社 Method for manufacturing substrate integrated gasket
JP2019009098A (en) * 2017-06-29 2019-01-17 株式会社Ｓｏｋｅｎ Fuel cell
JP2019140027A (en) * 2018-02-14 2019-08-22 Nok株式会社 Gas diffusion layer-integrated gasket and member for fuel battery cell
JP2019140028A (en) * 2018-02-14 2019-08-22 Nok株式会社 Gas diffusion layer-integrated gasket and member for fuel battery cell

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017004671A (en) * 2015-06-08 2017-01-05 Nok株式会社 Method for manufacturing substrate integrated gasket
JP2019009098A (en) * 2017-06-29 2019-01-17 株式会社Ｓｏｋｅｎ Fuel cell
JP2019140027A (en) * 2018-02-14 2019-08-22 Nok株式会社 Gas diffusion layer-integrated gasket and member for fuel battery cell
JP2019140028A (en) * 2018-02-14 2019-08-22 Nok株式会社 Gas diffusion layer-integrated gasket and member for fuel battery cell

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