JP2021052015A - battery - Google Patents

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JP2021052015A
JP2021052015A JP2020212879A JP2020212879A JP2021052015A JP 2021052015 A JP2021052015 A JP 2021052015A JP 2020212879 A JP2020212879 A JP 2020212879A JP 2020212879 A JP2020212879 A JP 2020212879A JP 2021052015 A JP2021052015 A JP 2021052015A
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Japan
Prior art keywords
recess
housing
external connection
connection terminal
electrode terminal
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Japanese (ja)
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直樹 岩村
Naoki Iwamura
直樹 岩村
信保 根岸
Nobuyasu Negishi
信保 根岸
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Toshiba Corp
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Toshiba Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

To provide a battery with a novel configuration which is improved to cause less inconvenience.SOLUTION: A battery in an embodiment comprises, for example, a housing, a penetration part, an external connection terminal, a recess, a seal member, and an insulation member. The housing houses an electrode body. The penetration part is provided on the housing and penetrates the housing from the outside to the inside. The external connection terminal is inserted into the penetration part so as to be electrically connected to the electrode body. On an outer surface of the housing, the recess is formed further on the outer side than an outer edge of the external connection terminal. The seal member is interposed between the external connection terminal and an inner peripheral surface of the penetration part in a compressed state around the entire periphery of the inner peripheral surface. The insulation member has: a contact part which comes into contact with an end of the seal member; and a protrusion part which is spaced away from the contact part and protrudes into the recess.SELECTED DRAWING: Figure 2

Description

本発明の実施形態は、電池に関する。 Embodiments of the present invention relate to batteries.

従来、表面側に開放された凹部と当該凹部の底部を貫通する貫通孔とが設けられた壁部を含む筐体と、貫通孔に挿入された外部接続端子と、外部接続端子と貫通孔との間に介在されたシール部材と、外部接続端子と壁部との間に介在された絶縁部材と、を備えた電池が、知られている。 Conventionally, a housing including a recess provided on the surface side and a wall portion having a through hole penetrating the bottom of the recess, an external connection terminal inserted into the through hole, an external connection terminal, and a through hole. A battery including a seal member interposed between the two, and an insulating member interposed between the external connection terminal and the wall portion is known.

特開2008−305644号公報Japanese Unexamined Patent Publication No. 2008-305644

この種の電池では、例えば、より不都合が少なく改善された新規な構成が得られれば、好ましい。 In this type of battery, for example, it is preferable to obtain a new configuration with less inconvenience and improved.

実施形態の電池は、例えば、筐体と、貫通部と、外部接続端子と、凹部と、シール部材と、絶縁部材と、を備える。筐体は、電極体が収容される。貫通部は、筐体に設けられ、筐体の外部と内部とを貫通する。外部接続端子は、貫通部に挿入され、電極体と電気的に接続される。凹部は、筐体の外部表面であって、外部接続端子の外縁よりも外側に形成される。シール部材は、外部接続端子と貫通部の内周面との間に、内周面の全周に亘り圧縮された状態で介在される。絶縁部材は、シール部材の端部に当接する当接部と、当接部から離間し凹部内に突出した突出部と、を有する。 The battery of the embodiment includes, for example, a housing, a penetrating portion, an external connection terminal, a recess, a sealing member, and an insulating member. The housing contains an electrode body. The penetrating portion is provided in the housing and penetrates the outside and the inside of the housing. The external connection terminal is inserted into the penetrating portion and is electrically connected to the electrode body. The recess is the outer surface of the housing and is formed outside the outer edge of the external connection terminal. The seal member is interposed between the external connection terminal and the inner peripheral surface of the penetrating portion in a compressed state over the entire circumference of the inner peripheral surface. The insulating member has a contact portion that comes into contact with the end portion of the seal member, and a protrusion portion that is separated from the contact portion and protrudes into the recess.

図1は、第1実施形態の電池の例示的かつ模式的な分解斜視図である。FIG. 1 is an exemplary and schematic exploded perspective view of the battery of the first embodiment. 図2は、第1実施形態の電池の一部の例示的かつ模式的な断面図である。FIG. 2 is an exemplary and schematic cross-sectional view of a portion of the battery of the first embodiment. 図3は、第1実施形態の電池の第一の壁部の例示的かつ模式的な断面図である。FIG. 3 is an exemplary and schematic cross-sectional view of the first wall portion of the battery of the first embodiment. 図4は、第1実施形態の電池の第一の壁部の例示的かつ模式的な平面図である。FIG. 4 is an exemplary and schematic plan view of the first wall portion of the battery of the first embodiment. 図5は、第1実施形態の第1変形例の電池の第一の壁部の例示的かつ模式的な平面図である。FIG. 5 is an exemplary and schematic plan view of the first wall portion of the battery of the first modification of the first embodiment. 図6は、第1実施形態の第2変形例の電池の第一の壁部の例示的かつ模式的な平面図である。FIG. 6 is an exemplary and schematic plan view of the first wall portion of the battery of the second modification of the first embodiment.

以下、本発明の例示的な実施形態が開示される。以下に示される実施形態の構成、ならびに当該構成によってもたらされる作用および結果(効果)は、一例である。 Hereinafter, exemplary embodiments of the present invention will be disclosed. The configurations of the embodiments shown below, as well as the actions and results (effects) brought about by the configurations, are examples.

また、以下に開示される複数の実施形態には、同様の構成要素が含まれる。よって、以下では、それら同様の構成要素には共通の符号が付与されるとともに、重複する説明が省略される。なお、以下の各図では、便宜上、方向が定義されている。X方向は、電池1の厚さ方向に沿うとともに、壁部20f(第一の壁部)の短手方向に沿う。Y方向は、電池1の幅方向に沿うとともに、壁部20fの長手方向に沿う。Z方向は、電池1の高さ方向に沿うとともに、壁部20fの厚さ方向に沿う。X方向、Y方向、およびZ方向は、互いに直交している。 Also, the plurality of embodiments disclosed below include similar components. Therefore, in the following, common reference numerals will be given to these similar components, and duplicate explanations will be omitted. In each of the following figures, the direction is defined for convenience. The X direction is along the thickness direction of the battery 1 and along the short side direction of the wall portion 20f (first wall portion). The Y direction is along the width direction of the battery 1 and along the longitudinal direction of the wall portion 20f. The Z direction is along the height direction of the battery 1 and along the thickness direction of the wall portion 20f. The X, Y, and Z directions are orthogonal to each other.

<第1実施形態>
図1,2に示されるように、電池1は、例えば、二次電池(蓄電池、充電式電池)として構成されており、筐体2と、電極体3と、導電部材4と、シール部材5(図2参照)と、絶縁部材6と、外部接続端子7と、を備えている。電池1は、単電池や、電池セル、缶セル等とも称され、電極体3は、電極群や、蓄電部、コイル部、充放電部等とも称されうる。また、導電部材4は、リード部材や、接続部材、端子部材等とも称されうる。なお、図2では、便宜上、電極体3は図示省略されている。
<First Embodiment>
As shown in FIGS. 1 and 2, the battery 1 is configured as, for example, a secondary battery (storage battery, rechargeable battery), and includes a housing 2, an electrode body 3, a conductive member 4, and a seal member 5. (See FIG. 2), an insulating member 6, and an external connection terminal 7. The battery 1 may be referred to as a cell, a battery cell, a can cell, or the like, and the electrode body 3 may also be referred to as an electrode group, a power storage unit, a coil unit, a charge / discharge unit, or the like. Further, the conductive member 4 can also be referred to as a lead member, a connecting member, a terminal member, or the like. In FIG. 2, the electrode body 3 is not shown for convenience.

電池1は、例えば、リチウムイオン二次電池等で構成されうる。なお、電池1は、ニッケル水素電池や、ニッケルカドミウム電池、鉛蓄電池等、他の二次電池であってもよい。リチウムイオン二次電池は、非水電解質二次電池の一種であり、電解質中のリチウムイオンが電気伝導を担う。正極材料としては、例えば、リチウムマンガン複合酸化物や、リチウムニッケル複合酸化物、リチウムコバルト複合酸化物、リチウムニッケルコバルト複合酸化物、リチウムマンガンコバルト複合酸化物、スピネル型リチウムマンガンニッケル複合酸化物、オリビン構造を有するリチウムリン酸化物等が用いられ、負極材料としては、例えば、チタン酸リチウム(LTO)等の酸化物系材料や、ニオブ複合酸化物等の酸化物材料等が用いられる。また、電解質(例えば、電解液)としては、フッ素系錯塩(例えばLiBF4、LiPF6)等のリチウム塩が配合された、例えば、炭酸エチレンや、炭酸プロピレン、炭酸ジエチル、炭酸エチルメチル、炭酸ジメチル等の有機溶媒等が単独であるいは複数混合されて用いられる。 The battery 1 may be composed of, for example, a lithium ion secondary battery or the like. The battery 1 may be another secondary battery such as a nickel hydrogen battery, a nickel cadmium battery, or a lead storage battery. A lithium ion secondary battery is a type of non-aqueous electrolyte secondary battery, and lithium ions in the electrolyte are responsible for electrical conduction. Examples of the positive electrode material include lithium manganese composite oxide, lithium nickel composite oxide, lithium cobalt composite oxide, lithium nickel cobalt composite oxide, lithium manganese cobalt composite oxide, spinel type lithium manganese nickel composite oxide, and olivine. A lithium phosphorus oxide having a structure or the like is used, and as the negative electrode material, for example, an oxide-based material such as lithium titanate (LTO), an oxide material such as a niobium composite oxide, or the like is used. Further, as the electrolyte (for example, the electrolytic solution), a lithium salt such as a fluorine-based complex salt (for example, LiBF4, LiPF6) is blended, for example, ethylene carbonate, propylene carbonate, diethyl carbonate, ethylmethyl carbonate, dimethyl carbonate and the like. Organic solvents and the like are used alone or in admixture.

図1に示されるように、筐体2は、X方向に薄い扁平な直方体状に構成されている。筐体2は、例えば、複数の壁部20a〜20fを有する。壁部20aおよび壁部20cは、いずれも、X方向と直交する方向(YZ平面)に沿って延びており、X方向に間隔をあけて互いに平行に設けられている。また、壁部20bおよび壁部20dは、いずれも、Y方向と直交する方向(XZ平面)に沿って延びており、Y方向に間隔をあけて互いに平行に設けられている。壁部20a〜20dは、側壁部や周壁部等と称されうる。 As shown in FIG. 1, the housing 2 is formed in a flat rectangular parallelepiped shape thin in the X direction. The housing 2 has, for example, a plurality of wall portions 20a to 20f. Both the wall portion 20a and the wall portion 20c extend along a direction (YZ plane) orthogonal to the X direction, and are provided parallel to each other at intervals in the X direction. Further, both the wall portion 20b and the wall portion 20d extend along a direction (XZ plane) orthogonal to the Y direction, and are provided in parallel with each other at intervals in the Y direction. The wall portions 20a to 20d may be referred to as a side wall portion, a peripheral wall portion, or the like.

また、壁部20eおよび壁部20fは、いずれも、Z方向と直交する方向(XY平面)に沿って延びており、Z方向に間隔をあけて互いに平行に設けられている。壁部20eは、底壁部や下壁部等と称され、壁部20fは、天壁部や上壁部等と称されうる。壁部20fは、第一の壁部の一例である。 Further, both the wall portion 20e and the wall portion 20f extend along a direction (XY plane) orthogonal to the Z direction, and are provided in parallel with each other at intervals in the Z direction. The wall portion 20e may be referred to as a bottom wall portion, a lower wall portion, or the like, and the wall portion 20f may be referred to as a top wall portion, an upper wall portion, or the like. The wall portion 20f is an example of the first wall portion.

また、筐体2は、複数の部品(分割体)が組み合わせられて構成されている。具体的には、筐体2は、例えば、ケース21と、蓋22と、を有する。ケース21は、少なくとも、壁部20a〜20eを有する。ケース21には、壁部20a〜20eによって囲まれ、上方(Z方向)に向けて開放された収容部20rが設けられている。収容部20rは、開口部や、凹部、室等とも称されうる。なお、壁部20a〜20eの内面20iには、ケース21と導電部材4とを絶縁する絶縁シート等の絶縁層が設けられうる。 Further, the housing 2 is configured by combining a plurality of parts (divided bodies). Specifically, the housing 2 has, for example, a case 21 and a lid 22. The case 21 has at least wall portions 20a to 20e. The case 21 is provided with a housing portion 20r surrounded by wall portions 20a to 20e and opened upward (Z direction). The accommodating portion 20r may also be referred to as an opening, a recess, a chamber, or the like. An insulating layer such as an insulating sheet that insulates the case 21 and the conductive member 4 may be provided on the inner surface 20i of the wall portions 20a to 20e.

また、蓋22は、少なくとも、壁部20fを有する。蓋22は、収容部20rに電極体3および導電部材4が収容された状態で、ケース21と一体化される。ケース21と蓋22とは、例えば、溶接等によって互いに結合され、結合された部分から液体や気体等が漏れるのが抑制されている。ケース21は、第一筐体部材や、下ケース等とも称され、蓋22は、第二筐体部材や、上ケース、カバー等とも称されうる。筐体2は、例えば、アルミニウム等の金属材料によって構成されている。 Further, the lid 22 has at least a wall portion 20f. The lid 22 is integrated with the case 21 in a state where the electrode body 3 and the conductive member 4 are housed in the housing portion 20r. The case 21 and the lid 22 are connected to each other by, for example, welding, and leakage of liquid, gas, or the like from the combined portion is suppressed. The case 21 may also be referred to as a first housing member, a lower case, or the like, and the lid 22 may also be referred to as a second housing member, an upper case, a cover, or the like. The housing 2 is made of, for example, a metal material such as aluminum.

また、蓋22、すなわち壁部20fは、収容部20r側を向いた裏面20f2と、収容部20rとは反対側を向いた表面20f1と、を有する。表面20f1には、外部接続端子7としての正極端子23および負極端子24が露出している。正極端子23および負極端子24は、互いにY方向に間隔をあけて位置されている。Y方向は、表面20f1に沿う方向の一例である。 Further, the lid 22, that is, the wall portion 20f has a back surface 20f2 facing the accommodating portion 20r side and a front surface 20f1 facing the side opposite to the accommodating portion 20r. The positive electrode terminal 23 and the negative electrode terminal 24 as the external connection terminal 7 are exposed on the surface 20f1. The positive electrode terminal 23 and the negative electrode terminal 24 are positioned at intervals in the Y direction from each other. The Y direction is an example of a direction along the surface 20f1.

また、図2〜4に示されるように、壁部20fには、表面20f1に開放された複数の有底の凹部26,28が設けられている。凹部26は、Z方向、すなわち壁部20fの厚さ方向(図4)の視線では、四角形状に構成されている。本実施形態では、正極端子23および負極端子24に対応して、二つの凹部26がY方向に互いに間隔をあけて設けられている。凹部26は、第一の凹部の一例である。 Further, as shown in FIGS. 2 to 4, the wall portion 20f is provided with a plurality of bottomed recesses 26 and 28 opened on the surface 20f1. The recess 26 is formed in a quadrangular shape in the Z direction, that is, in the line of sight in the thickness direction of the wall portion 20f (FIG. 4). In the present embodiment, two recesses 26 are provided at intervals in the Y direction corresponding to the positive electrode terminal 23 and the negative electrode terminal 24. The recess 26 is an example of the first recess.

また、凹部28は、凹部26の四つの縁部26e(図4参照)のうち壁部20fの中間位置C側およびその反対側の縁部26e1,26e2に沿ってX方向に細長く延びている。本実施形態では、凹部26のそれぞれに、二つの凹部28が隣接して設けられている。凹部26は、二つの凹部28の間に位置され、凹部26と二つの凹部28とは、Y方向に並んでいる。凹部28は、第二の凹部の一例である。また、縁部26eは、辺部や、端部等とも称されうる。 Further, the recess 28 extends in the X direction along the edge portions 26e1, 26e2 on the intermediate position C side of the wall portion 20f and the opposite side of the four edge portions 26e (see FIG. 4) of the recess 26. In the present embodiment, two recesses 28 are provided adjacent to each of the recesses 26. The recess 26 is located between the two recesses 28, and the recess 26 and the two recesses 28 are aligned in the Y direction. The recess 28 is an example of the second recess. Further, the edge portion 26e may also be referred to as a side portion, an end portion, or the like.

また、凹部26の底面26aには、貫通孔27が設けられている。図3に示されるように、貫通孔27は、底面26aと裏面20f2との間で壁部20fを貫通している。貫通孔27は、Z方向(図4)の視線では、円形状に構成されている。図2に示されるように、貫通孔27には、外部接続端子7のうちの軸部7bが挿入される。 Further, a through hole 27 is provided in the bottom surface 26a of the recess 26. As shown in FIG. 3, the through hole 27 penetrates the wall portion 20f between the bottom surface 26a and the back surface 20f2. The through hole 27 is formed in a circular shape in the line of sight in the Z direction (FIG. 4). As shown in FIG. 2, the shaft portion 7b of the external connection terminals 7 is inserted into the through hole 27.

外部接続端子7は、例えば、頭部7aと、軸部7bと、結合部7cと、を有する。頭部7aは、貫通孔27の表面20f1側で軸部7bと接続され、結合部7cは、貫通孔27の裏面20f2側で軸部7bと接続されている。図1,2に示されるように、頭部7aは、凹部26の縁部26e(図4参照)に沿った四角形状の板状に構成されている。頭部7aの径方向(XY平面)に沿った幅は、貫通孔27の開口幅(直径)よりも大きい。また、軸部7bは、貫通孔27の内周面27aに沿った円柱状に構成されている。 The external connection terminal 7 has, for example, a head portion 7a, a shaft portion 7b, and a coupling portion 7c. The head portion 7a is connected to the shaft portion 7b on the front surface 20f1 side of the through hole 27, and the connecting portion 7c is connected to the shaft portion 7b on the back surface 20f2 side of the through hole 27. As shown in FIGS. 1 and 2, the head portion 7a is formed in a rectangular plate shape along the edge portion 26e (see FIG. 4) of the recess 26. The width of the head 7a along the radial direction (XY plane) is larger than the opening width (diameter) of the through hole 27. Further, the shaft portion 7b is formed in a columnar shape along the inner peripheral surface 27a of the through hole 27.

結合部7cは、例えば、外部接続端子7と導電部材4とがカシメによって互いに結合された場合に、軸部7bの端部から径方向(XY平面)に沿って張り出した部分である。結合部7cは、導電部材4とZ方向に重なり、結合部7cと頭部7aとの間には、導電部材4とシール部材5とが挟まれている。図2に示されるように、外部接続端子7と導電部材4とが互いに結合された状態では、頭部7aの少なくとも一部が凹部26内に位置されている。これにより、頭部7aの表面20f1からの突出量が抑えられ、ひいては電池1がZ方向により小型に構成されうる。また、頭部7aと導電部材4との間にシール部材5が弾性的に圧縮された状態で挟まれることにより、シール性が高められている。結合部7cは、カシメ部や、フランジ部、張出部、引掛部等とも称されうる。 The coupling portion 7c is, for example, a portion that projects along the radial direction (XY plane) from the end portion of the shaft portion 7b when the external connection terminal 7 and the conductive member 4 are coupled to each other by caulking. The connecting portion 7c overlaps the conductive member 4 in the Z direction, and the conductive member 4 and the sealing member 5 are sandwiched between the connecting portion 7c and the head portion 7a. As shown in FIG. 2, when the external connection terminal 7 and the conductive member 4 are connected to each other, at least a part of the head portion 7a is located in the recess 26. As a result, the amount of protrusion of the head 7a from the surface 20f1 can be suppressed, and the battery 1 can be made smaller in the Z direction. Further, the sealing property is enhanced by sandwiching the sealing member 5 between the head portion 7a and the conductive member 4 in an elastically compressed state. The connecting portion 7c may also be referred to as a caulking portion, a flange portion, an overhanging portion, a hooking portion, or the like.

図1に示されるように、外部接続端子7の一方である正極端子23は、壁部20fを貫通した状態で設けられ、壁部20fの内側で導電部材4の一方である正極リード4Rと結合される。また、図2に示されるように、外部接続端子7の他方である負極端子24は、壁部20fを貫通した状態で設けられ、壁部20fの内側で導電部材4の他方である負極リード4Lと結合される。なお、壁部20fの裏面20f2には、蓋22と導電部材4とを絶縁する絶縁シート等の絶縁層8が設けられている。 As shown in FIG. 1, the positive electrode terminal 23, which is one of the external connection terminals 7, is provided so as to penetrate the wall portion 20f, and is coupled to the positive electrode lead 4R, which is one of the conductive members 4, inside the wall portion 20f. Will be done. Further, as shown in FIG. 2, the negative electrode terminal 24, which is the other side of the external connection terminal 7, is provided so as to penetrate the wall portion 20f, and the negative electrode lead 4L, which is the other side of the conductive member 4 inside the wall portion 20f. Combined with. The back surface 20f2 of the wall portion 20f is provided with an insulating layer 8 such as an insulating sheet that insulates the lid 22 and the conductive member 4.

図1に示されるように、電極体3は、例えば、正極31と、負極32と、絶縁層33(セパレータ)と、を有する。正極31、負極32、および絶縁層33は、それぞれ、シート状に構成されている。そして、電極体3は、シート状の正極31、負極32、および絶縁層33がY方向に沿った軸回りに巻回されて、あるいは折り畳まれて、扁平形状に構成されている。電極体3は、電極群であって発電要素として機能する。 As shown in FIG. 1, the electrode body 3 has, for example, a positive electrode 31, a negative electrode 32, and an insulating layer 33 (separator). The positive electrode 31, the negative electrode 32, and the insulating layer 33 are each formed in a sheet shape. The electrode body 3 is formed into a flat shape by winding or folding the sheet-shaped positive electrode 31, the negative electrode 32, and the insulating layer 33 around the axis along the Y direction. The electrode body 3 is a group of electrodes and functions as a power generation element.

また、正極31および負極32は、それぞれ、集電体や、集電体を覆う活物質層、集電体から突出した集電タブ等を有する。正極31の集電タブは、電極体3のY方向の反対方向の端部に位置され、図1に示される正極バックアップリード35と接続されている。また、負極32の集電タブは、電極体3のY方向の端部に位置され、図1に示される負極バックアップリード36と接続されている。正極バックアップリード35および負極バックアップリード36は、リード部材や、導電部材、接続部材、端子部材等とも称されうる。 Further, the positive electrode 31 and the negative electrode 32 each have a current collector, an active material layer covering the current collector, a current collector tab protruding from the current collector, and the like. The current collecting tab of the positive electrode 31 is located at the end of the electrode body 3 in the direction opposite to the Y direction, and is connected to the positive electrode backup lead 35 shown in FIG. The current collecting tab of the negative electrode 32 is located at the end of the electrode body 3 in the Y direction and is connected to the negative electrode backup lead 36 shown in FIG. The positive electrode backup lead 35 and the negative electrode backup lead 36 can also be referred to as a lead member, a conductive member, a connecting member, a terminal member, and the like.

導電部材4の一方である正極リード4Rは、正極バックアップリード35を介して、正極31と正極端子23とを電気的に接続している。正極リード4Rと正極端子23とは、カシメによって互いに結合され、正極リード4Rと正極バックアップリード35とは、例えば、超音波溶接等によって互いに結合されている。 The positive electrode lead 4R, which is one of the conductive members 4, electrically connects the positive electrode 31 and the positive electrode terminal 23 via the positive electrode backup lead 35. The positive electrode lead 4R and the positive electrode terminal 23 are bonded to each other by caulking, and the positive electrode lead 4R and the positive electrode backup lead 35 are bonded to each other by, for example, ultrasonic welding.

また、導電部材4の他方である負極リード4Lは、負極バックアップリード36を介して、負極32と負極端子24とを電気的に接続している。負極リード4Lと負極端子24とは、カシメによって互いに結合され、負極リード4Lと負極バックアップリード36とは、例えば、超音波溶接等によって互いに結合されている。 Further, the negative electrode lead 4L, which is the other side of the conductive member 4, electrically connects the negative electrode 32 and the negative electrode terminal 24 via the negative electrode backup lead 36. The negative electrode lead 4L and the negative electrode terminal 24 are bonded to each other by caulking, and the negative electrode lead 4L and the negative electrode backup lead 36 are bonded to each other by, for example, ultrasonic welding.

図1に示されるように、導電部材4は、例えば、ベース部4aと、アーム部4bと、を有する。導電部材4は、例えば、一枚の板状の部材が、二箇所(アーム部4bの根元部分)で屈曲されて構成されている。なお、導電部材4は、ベース部4aとアーム部4bとが、例えば、溶接等によって互いに結合されて構成されてもよい。 As shown in FIG. 1, the conductive member 4 has, for example, a base portion 4a and an arm portion 4b. The conductive member 4 is composed of, for example, a single plate-shaped member bent at two locations (the root portion of the arm portion 4b). The conductive member 4 may be formed by connecting the base portion 4a and the arm portion 4b to each other by, for example, welding.

ベース部4aは、壁部20f(XY平面)に沿って延びた四角形状の板状に構成されている。ベース部4aは、壁部20fの内側(収容部20r側)で絶縁層8(図2参照)を間に挟んだ状態で壁部20fと重ねられる。また、ベース部4aには、外部接続端子7(正極端子23または負極端子24)が挿入される貫通孔4a1が設けられている。 The base portion 4a is formed in a rectangular plate shape extending along the wall portion 20f (XY plane). The base portion 4a is overlapped with the wall portion 20f with the insulating layer 8 (see FIG. 2) sandwiched inside the wall portion 20f (on the side of the accommodating portion 20r). Further, the base portion 4a is provided with a through hole 4a1 into which an external connection terminal 7 (positive electrode terminal 23 or negative electrode terminal 24) is inserted.

図1に示されるように、アーム部4bは、ベース部4aから壁部20e(底壁部)側へ向けてベース部4aと交差する方向に延びている。アーム部4bは、壁部20a,20c(YZ平面)に沿った四角形状の板状に構成されている。 As shown in FIG. 1, the arm portion 4b extends from the base portion 4a toward the wall portion 20e (bottom wall portion) side in a direction intersecting with the base portion 4a. The arm portion 4b is formed in a rectangular plate shape along the wall portions 20a and 20c (YZ plane).

また、アーム部4bは、第一のアーム部4b1と、第二のアーム部4b2と、を有する。第一のアーム部4b1および第二のアーム部4b2は、X方向、すなわち電極体3の厚さ方向に間隔をあけて互いに平行に設けられている。導電部材4は、第一のアーム部4b1と第二のアーム部4b2との間に電極体3の端部(集電タブ)を挟んだ状態で、電極体3の正極バックアップリード35または負極バックアップリード36と結合される。 Further, the arm portion 4b has a first arm portion 4b1 and a second arm portion 4b2. The first arm portion 4b1 and the second arm portion 4b2 are provided parallel to each other at intervals in the X direction, that is, in the thickness direction of the electrode body 3. The conductive member 4 has a positive electrode backup lead 35 or a negative electrode backup of the electrode body 3 with an end portion (current collection tab) of the electrode body 3 sandwiched between the first arm portion 4b1 and the second arm portion 4b2. Combined with lead 36.

導電部材4は、電極体3および蓋22と一体化された状態で、ケース21の収容部20r内に挿入される。そして、蓋22が、収容部20rを塞いだ状態で、ケース21の上方(Z方向)の端部20jと結合される。その後、電解液が、蓋22に設けられる不図示の注液口から筐体2内に所定量、例えば、電極体3が電解液によって十分に浸される量だけ注入される。そして、注液口が溶接等によって封止される。なお、蓋22の正極端子23と負極端子24との間には、不図示の弁部が設けられうる。弁部は、筐体2内の圧力が閾値よりも高くなった場合に開放され、当該筐体2内の圧力を低下させる。弁部は、例えば、正極端子23と負極端子24との中間位置C(図3,4参照)に設けられる。 The conductive member 4 is inserted into the accommodating portion 20r of the case 21 in a state of being integrated with the electrode body 3 and the lid 22. Then, the lid 22 is joined to the upper end portion 20j of the case 21 in a state of closing the accommodating portion 20r. After that, the electrolytic solution is injected into the housing 2 from a liquid injection port (not shown) provided on the lid 22 by a predetermined amount, for example, an amount by which the electrode body 3 is sufficiently immersed by the electrolytic solution. Then, the liquid injection port is sealed by welding or the like. A valve portion (not shown) may be provided between the positive electrode terminal 23 and the negative electrode terminal 24 of the lid 22. The valve portion is opened when the pressure in the housing 2 becomes higher than the threshold value, and the pressure in the housing 2 is reduced. The valve portion is provided, for example, at an intermediate position C (see FIGS. 3 and 4) between the positive electrode terminal 23 and the negative electrode terminal 24.

図2に示されるように、シール部材5は、例えば、筒状部5aと、第一のフランジ部5bと、第二のフランジ部5cと、を有する。筒状部5aは、貫通孔27の内周面27aと軸部7bの外周面との間に介在している。本実施形態では、例えば、外部接続端子7のカシメ時に当該外部接続端子7がZ方向に圧縮されることによって、軸部7bが径方向(XY平面)に沿って膨らむ。これにより、軸部7bの外周面と貫通孔27の内周面27aとの間に筒状部5aが弾性的に圧縮された状態で挟まれ、ひいては貫通孔27のシール性が向上しうる。 As shown in FIG. 2, the sealing member 5 has, for example, a tubular portion 5a, a first flange portion 5b, and a second flange portion 5c. The tubular portion 5a is interposed between the inner peripheral surface 27a of the through hole 27 and the outer peripheral surface of the shaft portion 7b. In the present embodiment, for example, when the external connection terminal 7 is crimped, the external connection terminal 7 is compressed in the Z direction, so that the shaft portion 7b swells along the radial direction (XY plane). As a result, the tubular portion 5a is sandwiched between the outer peripheral surface of the shaft portion 7b and the inner peripheral surface 27a of the through hole 27 in an elastically compressed state, and thus the sealing property of the through hole 27 can be improved.

また、第一のフランジ部5bは、筒状部5aのZ方向の端部から底面26aに沿って軸部7bとは反対側に延び、第二のフランジ部5cは、筒状部5aのZ方向の反対方向の端部から裏面20f2に沿って軸部7bとは反対側に延びている。第一のフランジ部5bは、頭部7aと底面26aとの間に介在し、第二のフランジ部5cは、ベース部4aと裏面20f2との間に介在している。第一のフランジ部5bおよび第二のフランジ部5cは、頭部7aとベース部4aとの間に弾性的に圧縮された状態で挟まれることにより、シール性が高められている。シール部材5は、例えば、合成樹脂材料等の絶縁体(弾性体)で構成されている。シール部材5は、ガスケットや、パッキン、介在物等とも称されうる。 Further, the first flange portion 5b extends from the end portion of the tubular portion 5a in the Z direction along the bottom surface 26a to the side opposite to the shaft portion 7b, and the second flange portion 5c is the Z of the tubular portion 5a. It extends from the end in the opposite direction along the back surface 20f2 to the side opposite to the shaft portion 7b. The first flange portion 5b is interposed between the head portion 7a and the bottom surface 26a, and the second flange portion 5c is interposed between the base portion 4a and the back surface 20f2. The first flange portion 5b and the second flange portion 5c are sandwiched between the head portion 7a and the base portion 4a in an elastically compressed state, so that the sealing property is enhanced. The seal member 5 is made of, for example, an insulator (elastic body) such as a synthetic resin material. The sealing member 5 may also be referred to as a gasket, packing, inclusions, or the like.

図2に示されるように、絶縁部材6は、例えば、第一の部分6aと、第二の部分6bと、第三の部分6cと、を有する。第一の部分6aは、例えば、凹部26の縁部26e(図4参照)に沿った角筒状に構成されている。第一の部分6aは、凹部26内に位置され、シール部材5および頭部7aと凹部26の側面26bとの間に介在している。第一の部分6aは、筒状部等とも称されうる。 As shown in FIG. 2, the insulating member 6 has, for example, a first portion 6a, a second portion 6b, and a third portion 6c. The first portion 6a is formed in a square tubular shape along the edge portion 26e (see FIG. 4) of the recess 26, for example. The first portion 6a is located in the recess 26 and is interposed between the sealing member 5 and the head 7a and the side surface 26b of the recess 26. The first portion 6a may also be referred to as a tubular portion or the like.

第二の部分6bは、第一の部分6aのZ方向の端部から表面20f1に沿って頭部7aとは反対側に延びている。図1に示されるように、第二の部分6bは、Z方向の視線では、四角形状の枠状に構成されている。第一の部分6aおよび第二の部分6bは、外部接続端子7と壁部20fとの間に介在し、外部接続端子7の周囲を覆っている。絶縁部材6は、例えば、合成樹脂材料等の絶縁体(弾性体)で構成されている。絶縁部材6は、ガスケットや、パッキン、介在物等とも称されうる。また、第二の部分6bは、フランジ部や、張出部等とも称されうる。 The second portion 6b extends from the end of the first portion 6a in the Z direction along the surface 20f1 to the side opposite to the head 7a. As shown in FIG. 1, the second portion 6b is formed in a rectangular frame shape in the line of sight in the Z direction. The first portion 6a and the second portion 6b are interposed between the external connection terminal 7 and the wall portion 20f and cover the periphery of the external connection terminal 7. The insulating member 6 is made of, for example, an insulator (elastic body) such as a synthetic resin material. The insulating member 6 may also be referred to as a gasket, packing, inclusions, or the like. Further, the second portion 6b may also be referred to as a flange portion, an overhanging portion, or the like.

図2に示されるように、第三の部分6cは、第二の部分6bから凹部28内に突出している。第三の部分6cは、図4に示される凹部28に沿ってX方向に細長く延びている。そして、本実施形態では、例えば、第三の部分6cが凹部28内に圧入されること等によって、第三の部分6cと凹部28とが機械的に接合されている。すなわち、第三の部分6cと凹部28とは、互いにY方向およびX方向に引っ掛かっている。第三の部分6cは、凸部や、突出部、嵌部、引掛部等とも称されうる。 As shown in FIG. 2, the third portion 6c projects from the second portion 6b into the recess 28. The third portion 6c is elongated in the X direction along the recess 28 shown in FIG. Then, in the present embodiment, for example, the third portion 6c is mechanically joined to the recess 28 by press-fitting the third portion 6c into the recess 28. That is, the third portion 6c and the recess 28 are hooked on each other in the Y direction and the X direction. The third portion 6c may also be referred to as a convex portion, a protruding portion, a fitting portion, a hooking portion, or the like.

上述したように、本実施形態では、外部接続端子7のカシメ時に当該外部接続端子7がZ方向に圧縮されることによって、軸部7bが径方向(XY平面)に沿って膨らむ。このため、軸部7bの外周面と凹部26の側面26bとの間にシール部材5および絶縁部材6が弾性的に圧縮された状態で挟まれると、絶縁部材6が第一の部分6aを支点として変形し、第二の部分6bの先端部6b1と表面20f1との間に隙間が生じてしまう虞がある。その点、本実施形態によれば、例えば、第三の部分6cと凹部28とが互いに引っ掛かっているため、絶縁部材6の第一の部分6aを支点とした変形(傾倒、反り)を抑制することができる。よって、例えば、第二の部分6bの先端部6b1と表面20f1との間に隙間が生じるのが抑制されやすく、ひいては当該隙間を介した貫通孔27側への塵芥や水滴等の侵入を抑制することができる。 As described above, in the present embodiment, when the external connection terminal 7 is crimped, the external connection terminal 7 is compressed in the Z direction, so that the shaft portion 7b swells along the radial direction (XY plane). Therefore, when the seal member 5 and the insulating member 6 are sandwiched between the outer peripheral surface of the shaft portion 7b and the side surface 26b of the recess 26 in an elastically compressed state, the insulating member 6 serves as a fulcrum of the first portion 6a. There is a possibility that a gap may be formed between the tip portion 6b1 of the second portion 6b and the surface 20f1. In that respect, according to the present embodiment, for example, since the third portion 6c and the recess 28 are caught by each other, deformation (tilting, warpage) with the first portion 6a of the insulating member 6 as a fulcrum is suppressed. be able to. Therefore, for example, it is easy to suppress the formation of a gap between the tip portion 6b1 of the second portion 6b and the surface 20f1, and by extension, the invasion of dust, water droplets, etc. into the through hole 27 side through the gap is suppressed. be able to.

以上のように、本実施形態では、例えば、絶縁部材6は、凹部26(第一の凹部)内に位置された第一の部分6aと、表面20f1に沿った第二の部分6bと、第二の部分6bから凹部28(第二の凹部)内に突出した第三の部分6cと、を有する。よって、本実施形態によれば、例えば、凹部28と第三の部分6cとによって、絶縁部材6の第一の部分6aを支点とした変形(傾倒、反り)を抑制することができる。よって、例えば、第二の部分6bの先端部6b1と表面20f1との間に隙間が生じるのが抑制されやすく、ひいては当該隙間を介した貫通孔27側への塵芥や水滴等の侵入を抑制することができる。 As described above, in the present embodiment, for example, the insulating member 6 has a first portion 6a located in the recess 26 (first recess), a second portion 6b along the surface 20f1, and a second portion. It has a third portion 6c protruding from the second portion 6b into the recess 28 (second recess). Therefore, according to the present embodiment, for example, the recess 28 and the third portion 6c can suppress deformation (tilting, warping) with the first portion 6a of the insulating member 6 as a fulcrum. Therefore, for example, it is easy to suppress the formation of a gap between the tip portion 6b1 of the second portion 6b and the surface 20f1, and by extension, the invasion of dust, water droplets, etc. into the through hole 27 side through the gap is suppressed. be able to.

また、本実施形態によれば、壁部20fに凹部28が設けられているため、例えば、コイニング(圧印加工)等による凹部26,28の成形時に、凹部26の底面26aと側面26bとの間の角部26cに角丸(角R)形状の所謂ダレが生じ難くなるという利点もある。仮に、凹部26の角部26cに角丸(角R)形状のダレが生じると、軸部7bの外周面と凹部26の側面26bとの間にシール部材5および絶縁部材6が挟まれた場合に、絶縁部材6の第一の部分6aが凹部26から抜け出す方向に浮き上がってしまう虞がある。その点、本実施形態によれば、例えば、凹部28によって、凹部26の角部26cがより精度よく成形されやすくなる。よって、例えば、絶縁部材6の凹部26から抜け出す方向への変形が抑制されやすく、ひいては第二の部分6bと表面20f1との間に隙間が生じるのがより一層抑制されやすい。 Further, according to the present embodiment, since the recess 28 is provided in the wall portion 20f, for example, when the recesses 26 and 28 are formed by coining (imprinting) or the like, between the bottom surface 26a and the side surface 26b of the recess 26. There is also an advantage that so-called sagging of a rounded corner (corner R) shape is less likely to occur at the corner portion 26c of the above. If the corner portion 26c of the recess 26 is sagging in a rounded (cornered R) shape, the seal member 5 and the insulating member 6 are sandwiched between the outer peripheral surface of the shaft portion 7b and the side surface 26b of the recess 26. In addition, there is a risk that the first portion 6a of the insulating member 6 will rise in the direction of coming out of the recess 26. In that respect, according to the present embodiment, for example, the concave portion 28 makes it easier to form the corner portion 26c of the concave portion 26 with higher accuracy. Therefore, for example, the deformation of the insulating member 6 in the direction of coming out of the recess 26 is easily suppressed, and the formation of a gap between the second portion 6b and the surface 20f1 is more likely to be suppressed.

また、本実施形態では、例えば、外部接続端子7は、表面20f1に沿うY方向に互いに間隔をあけて位置された正極端子23および負極端子24を含み、凹部28は、正極端子23と負極端子24との間に設けられている。よって、本実施形態によれば、例えば、凹部28によって、凹部26の四つの縁部26e(図4参照)のうち最も角丸(角R)形状のダレが生じやすい中間位置C側の縁部26e1の角部26cにダレが生じるのを効果的に抑制することができる。 Further, in the present embodiment, for example, the external connection terminal 7 includes a positive electrode terminal 23 and a negative electrode terminal 24 located at intervals in the Y direction along the surface 20f1, and the recess 28 is a positive electrode terminal 23 and a negative electrode terminal. It is provided between 24 and 24. Therefore, according to the present embodiment, for example, the edge portion on the intermediate position C side where the concave portion 28 is most likely to cause sagging of the rounded corner (corner R) shape among the four edge portions 26e (see FIG. 4) of the concave portion 26. It is possible to effectively suppress the occurrence of sagging at the corner portion 26c of 26e1.

また、本実施形態では、例えば、凹部28は、正極端子23と負極端子24との中間位置C(弁部)よりも正極端子23または負極端子24の近くに位置されている。よって、本実施形態によれば、例えば、凹部26の縁部26eと凹部28とが互いにより近づいて配置されやすくなり、ひいては角部26cがより精度よく成形されたり、絶縁部材6がより小型に構成されたりしうる。 Further, in the present embodiment, for example, the recess 28 is located closer to the positive electrode terminal 23 or the negative electrode terminal 24 than the intermediate position C (valve portion) between the positive electrode terminal 23 and the negative electrode terminal 24. Therefore, according to the present embodiment, for example, the edge portion 26e and the recessed portion 28 of the recessed portion 26 are more likely to be arranged closer to each other, the corner portion 26c is formed more accurately, and the insulating member 6 is made smaller. It can be configured.

また、本実施形態では、例えば、凹部28は、表面20f1における凹部26の縁部26eに沿って延びている。よって、本実施形態によれば、例えば、凹部28によって、凹部26の角部26cが縁部26eに沿ってより一層精度よく成形されやすい。 Further, in the present embodiment, for example, the recess 28 extends along the edge 26e of the recess 26 on the surface 20f1. Therefore, according to the present embodiment, for example, the concave portion 28 makes it easier for the corner portion 26c of the concave portion 26 to be formed more accurately along the edge portion 26e.

なお、本実施形態では、凹部28が凹部26の両側のそれぞれに設けられた場合が例示されたが、これには限定されず、例えば、図5に示される第1変形例の電池1Aのように、凹部28Aは、凹部26の縁部26e1側のみに設けられてもよい。凹部26の四つの縁部26eのうち中間位置Cとは反対側の縁部26e2は、縁部26e1と比べて、コイニング(圧印加工)による凹部26,28Aの成形時に金型の抑えとの距離が近くなる。よって、凹部26の縁部26e2側の角部26cには、縁部26e1側の角部26cと比べて、角丸(角R)形状のダレが生じ難い。よって、第1変形例のように、凹部28Aは、凹部26の縁部26e1側のみに設けられてもよい。 In the present embodiment, the case where the recesses 28 are provided on both sides of the recesses 26 has been exemplified, but the present invention is not limited to this, and for example, the battery 1A of the first modification shown in FIG. In addition, the recess 28A may be provided only on the edge 26e1 side of the recess 26. Of the four edge portions 26e of the recess 26, the edge portion 26e2 on the side opposite to the intermediate position C is the distance from the mold retainer when the recesses 26 and 28A are formed by coining (imprinting) as compared with the edge portion 26e1. Becomes closer. Therefore, the corner portion 26c on the edge portion 26e2 side of the recess 26 is less likely to have a rounded (corner R) shape than the corner portion 26c on the edge portion 26e1 side. Therefore, as in the first modification, the recess 28A may be provided only on the edge 26e1 side of the recess 26.

また、図6に示される第2変形例の電池1Bのように、凹部28Bは、四つの縁部26eに沿った四角形状の枠状に構成されてもよい。第2変形例によれば、凹部28Bと第三の部分6cとの接触面積が増大するため、絶縁部材6の変形をより一層抑制することができる。 Further, as in the battery 1B of the second modification shown in FIG. 6, the recess 28B may be formed in a rectangular frame shape along the four edge portions 26e. According to the second modification, since the contact area between the recess 28B and the third portion 6c is increased, the deformation of the insulating member 6 can be further suppressed.

以上、本発明の実施形態を例示したが、上記実施形態はあくまで一例であって、発明の範囲を限定することは意図していない。上記実施形態は、その他の様々な形態で実施されることが可能であり、発明の要旨を逸脱しない範囲で、種々の省略、置き換え、組み合わせ、変更を行うことができる。上記実施形態は、発明の範囲や要旨に含まれるとともに、特許請求の範囲に記載された発明とその均等の範囲に含まれる。本発明は、上記実施形態に開示される構成以外によっても実現可能であるとともに、基本的な構成(技術的特徴)によって得られる種々の効果(派生的な効果も含む)を得ることが可能である。また、各構成要素のスペック(構造や、種類、方向、形状、大きさ、長さ、幅、厚さ、高さ、数、配置、位置、材質等)は、適宜に変更して実施することができる。 Although the embodiments of the present invention have been illustrated above, the above embodiments are merely examples and are not intended to limit the scope of the invention. The above-described embodiment can be implemented in various other forms, and various omissions, replacements, combinations, and changes can be made without departing from the gist of the invention. The above-described embodiment is included in the scope and gist of the invention, and is also included in the scope of the invention described in the claims and the equivalent scope thereof. The present invention can be realized by a configuration other than the configuration disclosed in the above embodiment, and various effects (including derivative effects) obtained by the basic configuration (technical features) can be obtained. is there. In addition, the specifications of each component (structure, type, direction, shape, size, length, width, thickness, height, number, arrangement, position, material, etc.) should be changed as appropriate. Can be done.

1,1A,1B…電池、2…筐体、3…電極体、5…シール部材、6…絶縁部材、6a…第一の部分、6b…第二の部分、6c…第三の部分、7…外部接続端子、20f…壁部(第一の壁部)、20f1…表面、20f2…裏面、23…正極端子、24…負極端子、26…凹部(第一の凹部)、26a…底面、26e…縁部、27…貫通孔、27a…内周面、28,28A,28B…凹部(第二の凹部)、C…中間位置、Y…表面に沿う方向。 1,1A, 1B ... Battery, 2 ... Housing, 3 ... Electrode body, 5 ... Seal member, 6 ... Insulation member, 6a ... First part, 6b ... Second part, 6c ... Third part, 7 ... External connection terminal, 20f ... Wall (first wall), 20f1 ... Front surface, 20f2 ... Back surface, 23 ... Positive terminal, 24 ... Negative terminal, 26 ... Recess (first recess), 26a ... Bottom, 26e ... edge, 27 ... through hole, 27a ... inner peripheral surface, 28, 28A, 28B ... recess (second recess), C ... intermediate position, Y ... direction along the surface.

Claims (3)

電極体が収容された筐体と、
前記筐体に設けられ、前記筐体の外部と内部とを貫通する貫通部と、
前記貫通部に挿入され、前記電極体と電気的に接続された外部接続端子と、
前記筐体の外部表面であって、前記外部接続端子の外縁よりも外側に形成された凹部と、
前記外部接続端子と前記貫通部の内周面との間に、前記内周面の全周に亘り圧縮された状態で介在されたシール部材と、
前記シール部材の端部に当接する当接部と、前記当接部から離間し前記凹部内に突出した突出部と、を有する絶縁部材と、
を備えた電池。
The housing in which the electrode body is housed and
A penetrating portion provided in the housing and penetrating the outside and the inside of the housing,
An external connection terminal inserted into the penetration portion and electrically connected to the electrode body,
A recess formed on the outer surface of the housing and outside the outer edge of the external connection terminal,
A seal member interposed between the external connection terminal and the inner peripheral surface of the penetrating portion in a compressed state over the entire circumference of the inner peripheral surface.
An insulating member having a contact portion that comes into contact with the end portion of the seal member and a protrusion portion that is separated from the contact portion and protrudes into the recess.
Batteries with.
前記外部接続端子は、前記筐体の外部表面に沿う方向に互いに間隔をあけて位置された正極端子および負極端子を含み、
前記凹部は、前記正極端子と前記負極端子との間に設けられた、請求項1に記載の電池。
The external connection terminal includes a positive electrode terminal and a negative electrode terminal located at intervals along the outer surface of the housing.
The battery according to claim 1, wherein the recess is provided between the positive electrode terminal and the negative electrode terminal.
前記凹部は、前記正極端子と前記負極端子との中間位置よりも前記正極端子または前記負極端子の近くに位置された、請求項2に記載の電池。 The battery according to claim 2, wherein the recess is located closer to the positive electrode terminal or the negative electrode terminal than the intermediate position between the positive electrode terminal and the negative electrode terminal.
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