JP2021048792A - Oil and fat composition for frozen bread after baking and frozen bread after baking - Google Patents

Oil and fat composition for frozen bread after baking and frozen bread after baking Download PDF

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JP2021048792A
JP2021048792A JP2019174110A JP2019174110A JP2021048792A JP 2021048792 A JP2021048792 A JP 2021048792A JP 2019174110 A JP2019174110 A JP 2019174110A JP 2019174110 A JP2019174110 A JP 2019174110A JP 2021048792 A JP2021048792 A JP 2021048792A
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bread
baking
frozen
oil
frozen bread
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美華 神並
Mika Shinnami
美華 神並
彩希 大橋
Saki Ohashi
彩希 大橋
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NOF Corp
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Abstract

To provide an oil and fat composition for frozen bread after baking, which prevents crust removal and shrinkage of bread during the storage of the frozen bread, and gives such bread as to have sufficient volume even after thawing of the stored frozen bread and have excellent chewy feeling.SOLUTION: There is provided an oil and fat composition for frozen bread after baking, the composition comprising L-cystine in edible oil and fat. Preferably, there is provided an oil and fat composition for frozen bread after baking, the composition further comprising glucoamylase in edible oil and fat. By using the oil and fat composition for frozen bread after baking of the present invention, it is possible to prevent crust removal and shrinkage of bread during the storage of the frozen bread and give such bread as to have sufficient volume even after thawing of the stored frozen bread and have excellent chewy feeling.SELECTED DRAWING: None

Description

本発明は、冷凍保存中に皮剥がれがなく、冷凍保存解凍後もパンの縮みがなく、十分なボリューム、腰持ちが良いパンが得られる、焼成後冷凍パン用油脂組成物に関する。 The present invention relates to an oil / fat composition for frozen bread after baking, which does not peel off during frozen storage, does not shrink even after thawing in frozen storage, and can obtain bread having sufficient volume and firmness.

本発明における焼成後冷凍パンとは、イーストを用いて醗酵した生地を成型し、焼成したのち急速冷凍したパンである。
焼成後冷凍パンは、消費者のタイミングに合わせて室温解凍またはリベイク(再焼成)することにより食することが可能である。また小売店やリテールベーカリーにおいて常温状態で販売されているパンと比較すると、焼成後冷凍パンは保存可能期限が長い利点がある。そのため家庭から飲食店と幅広く使用されており、今後の市場においても需要は増加していくと予想される。
しかし焼成後冷凍パンには、冷凍保存中に皮剥がれが生じ、冷凍保存解凍後にパンの縮みが生じ、ボリュームや腰持ちが低下するという課題がある。これは冷凍保存中に、特に水分含有量の少ないクラスト部分において乾燥が進むためである。皮剥がれおよび縮みが生じたパンは外観が損なわれ、また食感の低下にもつながり、商品価値が低下してしまう。
以上のことから焼成後冷凍パンにおいて、冷凍保存中に皮剥がれが防止され、冷凍保存解凍時にパンの縮みが防止され、ボリュームおよび腰持ちが良好である焼成後冷凍パンが求められている。
The baked frozen bread in the present invention is a bread obtained by molding a dough fermented with yeast, baking it, and then quick-freezing it.
After baking, the frozen bread can be eaten by thawing or rebaking at room temperature according to the consumer's timing. In addition, compared to bread sold at room temperature in retail stores and retail bakeries, frozen bread after baking has the advantage of having a longer shelf life. Therefore, it is widely used from homes to restaurants, and demand is expected to increase in the future market.
However, the frozen bread after baking has a problem that the skin peels off during the frozen storage, the bread shrinks after the frozen storage and thaw, and the volume and the firmness are reduced. This is because drying proceeds during frozen storage, especially in the crust portion having a low water content. Bread that has peeled and shrunk has a poor appearance, and also has a deteriorated texture, resulting in a decrease in commercial value.
From the above, in the post-baking frozen bread, there is a demand for a post-baking frozen bread that prevents peeling during frozen storage, prevents the bread from shrinking during frozen storage and thawing, and has good volume and firmness.

焼成後冷凍パンの皮剥がれを抑制するために、グリシンおよび5単糖類および/または6単糖類を有効成分として生地に練りこむ品質改良剤が開示されている(特許文献1)。しかしこの技術では焼成後および冷凍保存解凍後においてパンのボリューム、腰持ちが悪く、満足のできる外観が得られない。また、パン製品のクラスト部分(焼成後パンの外側部分)の亀裂や皮剥がれを抑制するために、焼成前の生地表面に塗布するクラスト改質剤が開示されている(特許文献2)。しかしこの技術では焼成後および冷凍保存解凍後においてパンのボリューム、腰持ちが良くなく、また冷凍保存中に皮剥がれが生じる。さらに、冷凍パン生地の焼成後におけるボリュームおよび食感の改良技術として、蛋白質含量が14%以上の小麦粉にシスチン及び/またはステアリル乳酸カルシウムを添加した冷凍パン生地が開示されている(特許文献3)。しかしこの技術はシスチンを小麦粉に直接添加してパン生地を製造し、その焼成前のパン生地を冷凍する技術であり、シスチンを油に分散していないためシスチンと油の併用効果は得られず、シスチンの保水性により凍結中に冷凍パン生地内で氷結晶が生じてしまいグルテン形成に影響が出るため、冷凍したパン生地を焼成後、再度冷凍した場合、パンのボリューム、腰持ちが低下し、また冷凍保存中に皮剥がれが生じる。
以上のことから焼成後冷凍パンにおいて、冷凍保存中に皮剥がれが防止され、冷凍保存解凍時にパンの縮みが防止され、ボリュームおよび腰持ちが良好であるパンは従来の技術では得られていない。
A quality improver containing glycine and 5 monosaccharides and / or 6 monosaccharides as active ingredients in a dough is disclosed in order to suppress peeling of frozen bread after baking (Patent Document 1). However, with this technique, the volume and firmness of bread are poor after baking and after freezing and thawing, and a satisfactory appearance cannot be obtained. Further, a crust modifier applied to the surface of the dough before baking is disclosed in order to suppress cracks and peeling of the crust portion (outer portion of the bread after baking) of the bread product (Patent Document 2). However, with this technique, the volume and firmness of bread are not good after baking and after freezing and thawing, and peeling occurs during freezing and storage. Further, as a technique for improving the volume and texture of frozen bread dough after baking, a frozen bread dough in which cystine and / or calcium stearyl lactate is added to wheat flour having a protein content of 14% or more is disclosed (Patent Document 3). However, this technology is a technology that produces bread dough by adding cystine directly to wheat flour and freezes the bread dough before baking.Since cystine is not dispersed in oil, the combined effect of cystine and oil cannot be obtained, and cystine Due to the water retention of the dough, ice crystals are generated in the frozen bread dough during freezing, which affects the formation of gluten. Therefore, when the frozen bread dough is baked and then frozen again, the volume and firmness of the bread are reduced, and the bread is stored frozen. Peeling occurs inside.
From the above, in the frozen bread after baking, peeling is prevented during frozen storage, shrinkage of the bread is prevented during freezing storage and thawing, and bread having good volume and firmness has not been obtained by conventional techniques.

国際公開第2013/154030号International Publication No. 2013/154030 特開2018−143143号公報JP-A-2018-143143 特開平3−183431号公報Japanese Unexamined Patent Publication No. 3-183431

本発明は、冷凍保存中のパンの皮剥がれや縮みが抑制され、冷凍保存解凍後も十分なボリュームを有し、腰持ちが良いパンが得られる焼成後冷凍パン用油脂組成物を提供することである。 The present invention provides an oil / fat composition for frozen bread after baking, which suppresses peeling and shrinkage of bread during frozen storage, has a sufficient volume even after thawing in frozen storage, and can obtain bread with a good chewy texture. Is.

発明者は鋭意検討を重ねた結果、食用油脂、L−シスチンを組み合わせることによって上記課題を解決する知見を見出し、さらにグルコアミラーゼを組み合わせることにその効果が増強されることを見出し、本発明を完成するに至った。
すなわち、本発明は以下の発明である。
〔1〕(A)食用油脂中に(B)L−シスチンを含有する焼成後冷凍パン用油脂組成物。
〔2〕食用油脂中に(C)グルコアミラーゼを含有する〔1〕記載の焼成後冷凍パン用油脂組成物。
〔3〕穀粉100質量部に対して、〔1〕又は〔2〕記載の焼成後冷凍パン用油脂組成物を0.5〜2.0質量部含有する焼成後後冷凍パン。
As a result of diligent studies, the inventor has found that the combination of edible oils and fats and L-cystine solves the above-mentioned problems, and further finds that the combination of glucoamylase enhances the effect, and completes the present invention. I came to do it.
That is, the present invention is the following invention.
[1] An oil / fat composition for frozen bread after baking containing (B) L-cystine in (A) edible oil / fat.
[2] The oil / fat composition for frozen bread after baking according to [1], which contains (C) glucoamylase in edible oil / fat.
[3] A post-baking frozen bread containing 0.5 to 2.0 parts by mass of the oil / fat composition for a post-baking frozen bread according to [1] or [2] with respect to 100 parts by mass of flour.

本発明によれば、冷凍保存中のパンの皮剥がれや縮みが抑制され、冷凍保存解凍後も十分なボリュームを有し、腰持ちが良いパンが得られる焼成後冷凍パン用油脂組成物を提供することができる。 According to the present invention, there is provided an oil / fat composition for frozen bread after baking, which suppresses peeling and shrinkage of bread during frozen storage, has a sufficient volume even after frozen storage and thawing, and can obtain bread with a good chewy texture. can do.

〔焼成後冷凍パン用油脂組成物〕
本発明の焼成後冷凍パン用油脂組成物は、(A)食用油脂、(B)L−シスチンを含有することを特徴とし、さらに、(C)グルコアミラーゼを含有することができる。なお、本発明の焼成後冷凍パン用油脂組成物はショートニング、油中水型乳化物または水中油型乳化物のいずれの形態においてもその効果を発揮することが出来る。
以下、本発明をさらに詳細に説明する。
[Fat composition for frozen bread after baking]
The oil / fat composition for frozen bread after baking of the present invention is characterized by containing (A) edible oil / fat and (B) L-cystine, and can further contain (C) glucoamylase. The oil-and-fat composition for frozen bread after baking of the present invention can exert its effect in any form of shortening, water-in-oil emulsion or oil-in-water emulsion.
Hereinafter, the present invention will be described in more detail.

((A)食用油脂)
(A)食用油脂としては、食用に適する油脂が使用でき、具体的には、牛脂、豚脂、魚油、パーム油、パーム核油、菜種油、大豆油、コーン油等の天然の動植物油脂、及びこれらの硬化油、極度硬化油、エステル交換油等が挙げられ、これらを目的に応じて適宜選択され、1種類又は2種類以上組み合わせて用いられる。(A)食用油脂に(B)L−シスチン、(C)グルコアミラーゼを含有することで、パン生地中にこれら素材を均一に分散させることができ、効果を十分に発揮させることが出来る。反対に、これら素材を(A)食用油脂に含有させず、パン生地にそれぞれ単体で添加した場合は、本発明の効果を十分に得ることは期待できない。
((A) Edible oils and fats)
(A) As edible fats and oils, edible fats and oils can be used. Specifically, natural animal and vegetable fats and oils such as beef fat, pork fat, fish oil, palm oil, palm kernel oil, rapeseed oil, soybean oil, and corn oil, and fats and oils. Examples thereof include these hydrogenated oils, extremely hydrogenated oils, ester exchange oils and the like, and these are appropriately selected according to the purpose and used alone or in combination of two or more. By containing (B) L-cystine and (C) glucoamylase in (A) edible oil and fat, these materials can be uniformly dispersed in the bread dough, and the effect can be fully exerted. On the contrary, when these materials are not contained in (A) edible oils and fats and are added individually to bread dough, it cannot be expected that the effects of the present invention can be sufficiently obtained.

((B)L−シスチン)
本発明において使用される(B)L−シスチンは、アミノ酸の1種であり、2つのシステイン分子がジスルフィド結合によって繋がった構造を有することを特徴とする。L−シスチンは、グルテンと結合することでグルテンを補強するため、焼成時のパンのボリュームが向上し、さらに冷凍保存解凍後のパンの縮みを防止する。一般的にボリュームが向上したパンは、焼成後、下に縮みやすく、横に広がった形状の、いわゆる腰持ちが低下したパンになるが、L−シスチンのグルテン補強効果により腰持ちが低下せず、結果として、パンのボリュームと腰持ちが良好になる。
((B) L-cystine)
The (B) L-cystine used in the present invention is one of the amino acids, and is characterized by having a structure in which two cysteine molecules are connected by a disulfide bond. Since L-cystine reinforces gluten by binding to gluten, the volume of bread during baking is improved, and the shrinkage of bread after freezing, storage and thawing is prevented. In general, bread with improved volume tends to shrink downward after baking and becomes a bread with a shape that spreads horizontally, so-called bread with reduced waist retention, but the gluten reinforcement effect of L-cystine does not reduce waist retention. As a result, the volume and waist of the bread are improved.

またL−シスチンを油脂中に分散することにより、L−シスチンと油脂の併用効果によりパン生地中に良好な水和状態が形成され、水分を生地内により多く保持することができ、焼成時の水分蒸発を防止する効果がある。そのため、焼成後冷凍パンにおいて、乾燥が原因となる冷凍保存中の皮剥がれを抑制することができる。 Further, by dispersing L-cystine in the fat and oil, a good hydration state is formed in the bread dough due to the combined effect of L-cystine and the fat and oil, and more water can be retained in the dough, and the water content at the time of baking can be maintained. It has the effect of preventing evaporation. Therefore, in the frozen pan after baking, peeling during frozen storage due to drying can be suppressed.

(B)L−シスチンの平均粒子径は、特に制限されないが、好ましくは100μm以下であり、より好ましくは50μm以下であり、特に好ましくは30μm以下である。L−シスチンの平均粒子径は細かい方が、パン生地中のグルテン内部へ作用するため、グルテンを補強するという効果をより一層発揮する。また、平均粒子径を小さくすることにより、食用油脂中の分散性に優れるため、L−シスチンのグルテン補強効果をより安定的に発揮することが可能となる。
なお、本発明におけるL−シスチンの平均粒子径とは、レーザー回折式粒度分布測定器(SALD−2100:(株)島津製作所製)を用いて測定した。
The average particle size of (B) L-cystine is not particularly limited, but is preferably 100 μm or less, more preferably 50 μm or less, and particularly preferably 30 μm or less. The finer the average particle size of L-cystine, the more it acts on the inside of gluten in the bread dough, so that the effect of reinforcing gluten is further exerted. Further, by reducing the average particle size, the dispersibility in edible oils and fats is excellent, so that the gluten reinforcing effect of L-cystine can be more stably exhibited.
The average particle size of L-cystine in the present invention was measured using a laser diffraction type particle size distribution measuring device (SALD-2100: manufactured by Shimadzu Corporation).

(B)L−シスチンの含有量は(A)食用油脂100質量部に対し0.01〜1質量部であり、より好ましくは0.03〜0.5質量部であり、さらに好ましくは0.03〜0.3質量部である。この範囲の含有量において、シスチンのパンに対する効果がより発揮できる。 The content of (B) L-cystine is 0.01 to 1 part by mass, more preferably 0.03 to 0.5 part by mass, and further preferably 0. It is 03 to 0.3 parts by mass. At a content in this range, the effect of cystine on bread can be more exerted.

本発明において使用できるL−シスチンはその形態や由来に限定されない。L−シスチンは、市販されており、例えば(株)トープロの「L−シスチン」等が例示できる。 The L-cystine that can be used in the present invention is not limited to its form or origin. L-cystine is commercially available, and examples thereof include "L-cystine" of Topro Co., Ltd.

((C)グルコアミラーゼ)
本発明において使用される(C)グルコアミラーゼは、アミログルコシダーゼやエキソ−1,4−α−D−グルコシダーゼとも称され、澱粉分解酵素(アミラーゼ)の1種である。グルコアミラーゼは、エキソ型酵素であるため、デンプンの構成要素であるアミロースおよびアミロペクチンのα−1,4グルコシド鎖を非還元性末端からグルコース単位で切断することができる。本発明において使用できるグルコアミラーゼはその形態や由来を限定しない。
グルコアミラーゼはデンプンを分解してグルコースを生成し、それらが水と結合するため、パン生地全体に水を保持しやすくなる。加えてL−シスチンとの併用により、L−シスチンのグルテン補強効果がグルコースと結合した水を外に放出しにくくなり、水分保持効果がさらに向上する。よって冷凍保存中の皮剥がれや、冷凍保存解凍後のパンの縮みやボリュームおよび腰持ちの低下をさらに防止することができる。
((C) Glucoamylase)
The (C) glucosidase used in the present invention is also called amyloglucosidase or exo-1,4-α-D-glucosidase, and is a kind of starch-degrading enzyme (amylase). Since glucoamylase is an exo-type enzyme, the α-1,4 glucoside chains of amylose and amylopectin, which are constituents of starch, can be cleaved from the non-reducing end in glucose units. The glucoamylase that can be used in the present invention does not limit its form or origin.
Glucoamylase breaks down starch to produce glucose, which binds to water, making it easier to retain water throughout the dough. In addition, when used in combination with L-cystine, the gluten-reinforcing effect of L-cystine makes it difficult for water bound to glucose to be released to the outside, further improving the water retention effect. Therefore, it is possible to further prevent peeling during frozen storage, shrinkage of bread after freezing and thawing, and reduction in volume and waist retention.

(C)グルコアミラーゼの含有量は、食用油脂100質量部に対して活性量1275u/gを基準で0.1〜2質量部であり、好ましくは0.4〜1.5質量部であり、より好ましくは0.6〜1質量部である。この範囲の含有量において、グルコアミラーゼのパンに対する効果がより発揮できる。
なお、例えば、食品油脂100質量部に対して活性量1275u/g基準で0.1〜2質量部との意味は、食用油脂100gに対して活性量127.5u〜2550uに換算できるものである。
このようなグルコアミラーゼとして、例えばダニスコ製「GRINDAMYL AG 1500/C」やノボザイムズ製「AMG 1100 BG」などが提示できる。なお、上記酵素の名称は商品名である。
The content of (C) glucoamylase is 0.1 to 2 parts by mass, preferably 0.4 to 1.5 parts by mass, based on an active amount of 1275 u / g with respect to 100 parts by mass of edible fats and oils. More preferably, it is 0.6 to 1 part by mass. At a content in this range, the effect of glucoamylase on bread can be more exerted.
For example, the meaning of 0.1 to 2 parts by mass based on the activity amount of 1275 u / g with respect to 100 parts by mass of food fat and oil can be converted into an activity amount of 127.5u to 2550u with respect to 100 g of edible fat and oil. ..
As such glucoamylase, for example, "GRINDAMYL AG 1500 / C" manufactured by Danisco and "AMG 1100 BG" manufactured by Novozymes can be presented. The name of the enzyme is a trade name.

(C)グルコアミラーゼの活性量は、澱粉をグルコアミラーゼによって分解し、生成するグルコースの量をグルコースオキシダーゼ法によって定量することによって測定する。そして、1分間に1μmolのグルコースを産生する酵素量を1uとして表す。 (C) The amount of activity of glucoamylase is measured by decomposing starch with glucoamylase and quantifying the amount of glucose produced by the glucose oxidase method. The amount of enzyme that produces 1 μmol of glucose per minute is represented as 1u.

具体的には、(C)グルコアミラーゼの活性量は以下の手順により測定する。
・2%可溶性澱粉1mlと0.2M酢酸緩衝液0.2mlを混合して基質溶液を作製し、40℃で5分間インキュベートする。
・次に試料酵素溶液[試料酵素1000mgを蒸留水100mlに正確に溶解した酵素溶液]0.1mlを基質溶液に添加し、良く混和したのち40℃でインキュベートする。
・20分経過後に、1N−NaOH水溶液0.1mlを添加混合して反応を停止させる(30分間放置)。
・次に1N−HCl水溶液0.1mlを添加し、グルコース濃度測定用の試料とする。
・グルコース濃度測定用の試料を0.1ml採取し、ブドウ糖定量試薬3.0mlを添加し、40℃で40分間反応させる。
・反応終了後、505nmにおける吸光度を分光光度計にて測定する。
・試料酵素溶液の代わりに蒸留水を用いたものをブランクとして、予めグルコース標準液より作成した検量線より、前記グルコース濃度測定用の試料中のグルコース濃度T(μmol/ml)を求める。(このときブランク中のグルコース濃度をT0とする)
・上記の反応によって1分間に1μmolのグルコースを産生する酵素量を1uとして以下の数式にしたがって算出する。そして、下記の数式によって算出される試料酵素溶液の酵素活性から、試料酵素溶液を調製する際の試料酵素の濃度に応じて試料酵素中の酵素活性を求める(なお下記の数式における希釈倍率は通常100である)。
試料酵素溶液の酵素活性(u/ml)={(T−T0)×1.5}/(20×0.1)
試料酵素1gの酵素活性(u)=(試料酵素溶液の酵素活性)×(希釈倍率)
Specifically, the amount of activity of (C) glucoamylase is measured by the following procedure.
-Mix 1 ml of 2% soluble starch and 0.2 ml of 0.2 M acetate buffer to prepare a substrate solution, and incubate at 40 ° C. for 5 minutes.
-Next, 0.1 ml of the sample enzyme solution [enzyme solution in which 1000 mg of the sample enzyme is accurately dissolved in 100 ml of distilled water] is added to the substrate solution, mixed well, and then incubated at 40 ° C.
-After 20 minutes, 0.1 ml of 1N-NaOH aqueous solution is added and mixed to stop the reaction (leave for 30 minutes).
-Next, 0.1 ml of a 1N-HCl aqueous solution is added to prepare a sample for measuring glucose concentration.
-Take 0.1 ml of a sample for measuring glucose concentration, add 3.0 ml of glucose quantification reagent, and react at 40 ° C. for 40 minutes.
-After completion of the reaction, the absorbance at 505 nm is measured with a spectrophotometer.
-The glucose concentration T (μmol / ml) in the sample for measuring the glucose concentration is obtained from a calibration curve prepared in advance from a glucose standard solution using distilled water instead of the sample enzyme solution as a blank. (At this time, the glucose concentration in the blank is T0)
-Calculate according to the following formula, assuming that the amount of enzyme that produces 1 μmol of glucose per minute by the above reaction is 1u. Then, from the enzyme activity of the sample enzyme solution calculated by the following formula, the enzyme activity in the sample enzyme is obtained according to the concentration of the sample enzyme when preparing the sample enzyme solution (note that the dilution ratio in the following formula is usually 100).
Enzyme activity of sample enzyme solution (u / ml) = {(T-T0) x 1.5} / (20 x 0.1)
Enzyme activity of 1 g of sample enzyme (u) = (enzyme activity of sample enzyme solution) × (dilution ratio)

本発明における焼成後冷凍パン用油脂組成物には、本願の発明の効果を損なわない限りにおいて、パン用油脂組成物に一般的に使用される添加物である加工澱粉、その他酵素、乳化剤、保存料、pH調整剤、色素、香料等を適宜使用してもよい。 The oil-and-fat composition for frozen bread after baking in the present invention includes modified starch, other enzymes, emulsifiers, and storage, which are additives generally used in the oil-and-fat composition for bread, as long as the effects of the present invention are not impaired. Agents, pH adjusters, pigments, fragrances and the like may be used as appropriate.

〔焼成後冷凍パン用油脂組成物の製造方法〕
本発明における焼成後冷凍パン用油脂組成物の製造方法は、通常のマーガリン、ショートニングの製造方法を用いることができ、特にグルコアミラーゼを失活しない温度で添加することが好ましい。例えば以下の製法が挙げられる。
まず油脂および油溶成分を融点温度以上の温度(70〜80℃)まで加熱し、均一溶解後、加温した水および水に十分に溶解した水溶成分を添加し、50〜55℃まで降温する。次に、プロペラ攪拌等を用いて均一に混合撹拌しながら酵素を添加し、さらに急冷可塑化し、30℃以下まで冷却することにより、目的の焼成後冷凍パン用油脂組成物を得る。上記製造において、高温状態にある均一混合物を冷却する際には均一混合物を入れている容器自身を外部から冷却しても良いが、一般的にショートニング、マーガリン製造に用いられるチラー、ボテーター、コンビネーター等を用いて急冷する方が性能上好ましい。
[Manufacturing method of oil and fat composition for frozen bread after baking]
As a method for producing an oil / fat composition for frozen bread after baking in the present invention, a usual method for producing margarine and shortening can be used, and it is particularly preferable to add glucoamylase at a temperature at which it is not inactivated. For example, the following manufacturing method can be mentioned.
First, the fat and oil-soluble components are heated to a temperature equal to or higher than the melting point temperature (70 to 80 ° C.), and after uniform dissolution, sufficiently dissolved water-soluble components are added to the heated water and water, and the temperature is lowered to 50 to 55 ° C. .. Next, the enzyme is added while uniformly mixing and stirring using propeller stirring or the like, and the mixture is further rapidly cooled and plasticized and cooled to 30 ° C. or lower to obtain the desired oil / fat composition for frozen bread after baking. In the above production, when cooling the homogeneous mixture in a high temperature state, the container itself containing the homogeneous mixture may be cooled from the outside, but a chiller, a botator, and a combinator generally used for shortening and margarine production. It is preferable in terms of performance to quench the mixture by using or the like.

〔焼成後冷凍パン〕
本発明の焼成後冷凍パンは、穀粉に、本発明の焼成後冷凍パン用油脂組成物を含むことを特徴とする。焼成後冷凍パンとは、イーストを用いて醗酵した生地を成型し、焼成したのち急速冷凍したパン、あるいは完全に焼成する前(通常焼成の7〜9割の時間で焼成)にオーブンから取り出し急速冷凍したパンである。
焼成後冷凍パンは、消費者のタイミングに合わせて室温解凍またはリベイク(再焼成)することにより食することが可能である。また小売店やリテールベーカリーにおいて常温状態で販売されているパンと比較すると、焼成後冷凍パンは保存可能期限が長い利点がある。
[Frozen bread after baking]
The post-baked frozen bread of the present invention is characterized in that the flour contains the oil / fat composition for the post-baked frozen bread of the present invention. After baking, frozen bread is made by molding a dough that has been fermented with yeast, baking it, and then quickly freezing it, or taking it out of the oven before it is completely baked (normally baked in 70 to 90% of the time it takes to bake). Frozen bread.
After baking, the frozen bread can be eaten by thawing or rebaking at room temperature according to the consumer's timing. In addition, compared to bread sold at room temperature in retail stores and retail bakeries, frozen bread after baking has the advantage of having a longer shelf life.

焼成後冷凍パンに添加する本発明の焼成後冷凍パン用油脂組成物の量は、穀粉100質量部に対して、0.5〜20質量部であり、好ましくは2〜10質量部である。焼成後冷凍パン用油脂組成物の量をこの範囲とすることによって、冷凍保存中の皮剥がれがなく、冷凍保存解凍後もパンの縮み、十分なボリューム、腰持ちが良いパンが得られる。添加する本発明の焼成後冷凍パン用油脂組成物の量が0.5質量部未満、あるいは20質量部を超えて添加した場合、冷凍保存中の皮剥がれや冷凍保存解凍後のパン縮み、ボリューム、腰持ちに対する効果が得られない。 The amount of the oil / fat composition for frozen bread after baking of the present invention to be added to the frozen bread after baking is 0.5 to 20 parts by mass, preferably 2 to 10 parts by mass with respect to 100 parts by mass of flour. By setting the amount of the oil / fat composition for frozen bread after baking within this range, it is possible to obtain bread that does not peel off during frozen storage, shrinks the bread even after freezing storage and thawing, has sufficient volume, and has a good chewy texture. When the amount of the oil / fat composition for frozen bread after baking of the present invention to be added is less than 0.5 parts by mass or more than 20 parts by mass, peeling during frozen storage, bread shrinkage after freezing storage and thawing, and volume. , The effect on the waist is not obtained.

穀粉としては、小麦粉、米粉、大麦粉、ライ麦粉等が挙げられる。また、本発明の焼成後冷凍パンに用いるその他の原料としては、主原料の穀粉の他にイースト、イーストフード、乳化剤、油脂類(ショートニング、ラード、マーガリン、バター、液状油等)、水、加工澱粉、乳製品、食塩、糖類、調味料(グルタミン酸ソーダ類や核酸類)、保存料、ビタミン、カルシウム等の強化剤、蛋白質、アミノ酸、化学膨張剤、フレーバー等が挙げられる。さらにレーズン等の乾燥果実、小麦粉ふすま、全粒粉等を使用できる。 Examples of the flour include wheat flour, rice flour, barley flour, rye flour and the like. Other raw materials used in the baked frozen bread of the present invention include yeast, yeast food, emulsifiers, fats and oils (shortening, lard, margarine, butter, liquid oil, etc.), water, and processing, in addition to the main raw material, grain flour. Examples include starch, dairy products, salt, sugars, seasonings (sodium glutamate and nucleic acids), preservatives, fortifiers such as vitamins and calcium, proteins, amino acids, chemical leavening agents, flavors and the like. Further, dried fruits such as raisins, wheat bran, whole grain flour and the like can be used.

〔焼成後冷凍パンの製造方法〕
本発明の焼成後冷凍パンの製造方法は、以下の工程(I)〜工程(IV)を備えることを特徴とする。
工程(I):食用油脂中にL−シスチンを含有する焼成後冷凍パン用油脂組成物を準備する工程。
工程(II):穀粉に対して、本発明の焼成後冷凍パン用油脂組成物を添加し、パン生地を得る工程。
工程(III):パン生地を焼成する工程。
工程(IV):焼成したパンを急速冷凍する工程。
[Manufacturing method of frozen bread after baking]
The method for producing a frozen bread after baking of the present invention is characterized by including the following steps (I) to (IV).
Step (I): A step of preparing a fat composition for frozen bread after baking, which contains L-cystine in edible fats and oils.
Step (II): A step of adding the oil / fat composition for frozen bread of the present invention to flour to obtain bread dough.
Step (III): A step of baking bread dough.
Step (IV): A step of quick freezing the baked bread.

工程(I)は、本発明の焼成後冷凍パン用油脂組成物を準備する工程である。焼成後冷凍パン用油脂組成物及びその製造方法については、上述したとおりであり、詳細は省略する。 Step (I) is a step of preparing the oil / fat composition for frozen bread after baking of the present invention. The fat composition for frozen bread after baking and the method for producing the same are as described above, and details thereof will be omitted.

工程(II)は、穀粉に対して、本発明の焼成後冷凍パン用油脂組成物を添加し、パン生地を得る工程である。工程(II)のパン生地を得る工程では、公知の製パン法により得ることができる。例えば、焼成後冷凍パン用油脂組成物と穀粉との混練は、ストレート法、中種法、ノータイム法等いずれの製パン法を用いてもよく、具体的には、ミキサーボウルなとの練り上げ装置で混練することができる。練り上げの方法は、装置によって異なるが、適度な撹拌条件、温度、時間で設定することができる。例えば、中種法では、中種作製時に低速2分、中速2分で混練し、中種発酵後、発酵したパン生地を砂糖などの副原料と共に低速2分、中速4分混練後、製パン用油脂組成物を加え、さらに低速3分、中速4分で混練するなどの条件を挙げることができる。 Step (II) is a step of adding the oil / fat composition for frozen bread of the present invention to the flour to obtain bread dough. In the step (II) of obtaining the bread dough, it can be obtained by a known bread making method. For example, as the kneading of the oil and fat composition for frozen bread after baking and the flour, any bread making method such as a straight method, a medium seed method, or a no-time method may be used. Specifically, a kneading device for a mixer bowl. Can be kneaded with. The kneading method differs depending on the apparatus, but can be set with appropriate stirring conditions, temperature, and time. For example, in the medium-seed method, the dough is kneaded at a low speed of 2 minutes and a medium speed of 2 minutes at the time of producing the medium seed, and after the medium-seed fermentation, the fermented bread dough is kneaded with auxiliary ingredients such as sugar for a low speed of 2 minutes and a medium speed of 4 minutes. Conditions such as adding a bread fat composition and further kneading at a low speed of 3 minutes and a medium speed of 4 minutes can be mentioned.

工程(II)において、パン生地を保存してもよい。パン生地の保存時の温度は、0℃以上に保持することが好ましい。生地を冷凍保存することにより、L−シスチンの保水性により凍結中に冷凍パン生地内で氷結晶が生じてしまいグルテン形成に影響が出るため、冷凍したパン生地を焼成後、再度冷凍した場合、パンのボリューム、腰持ちが低下し、また冷凍保存中に皮剥がれが生じるおそれがある。 Bread dough may be preserved in step (II). The storage temperature of the bread dough is preferably maintained at 0 ° C. or higher. By storing the dough in a freezer, the water retention of L-cystine causes ice crystals to form in the frozen bread dough during freezing, which affects gluten formation. Volume and waist retention may decrease, and peeling may occur during frozen storage.

工程(III)は、焼成したパンを急速冷凍する工程である。工程(III)のパン生地を焼成する工程において、焼成方法は、特に限定されず、例えば、工程(II)で得られたパン生地を、デバイダー等で分割し、モルダー等を通して成形後、型となる容器もしくは鉄板に並びに入れ、発酵や焼成を行う。焼成条件は、例えば190〜230℃の温度のオーブンの中で6〜12分間加熱することにより行うことができる。 Step (III) is a step of quick freezing the baked bread. In the step of baking the bread dough in the step (III), the baking method is not particularly limited. For example, the bread dough obtained in the step (II) is divided by a divider or the like, molded through a moulder or the like, and then used as a mold. Alternatively, they are placed on an iron plate and fermented or fired. The firing conditions can be achieved, for example, by heating in an oven at a temperature of 190 to 230 ° C. for 6 to 12 minutes.

工程(IV)は、焼成したパンを急速冷凍する工程である。工程(IV)において、冷凍方法は、急速冷凍を実現できる方法であれば特に限定されない。例えば、上記パン生地を焼成した後、あるいは完全に焼成する前にオーブンから取り出し、室温(例えば15〜30℃)まで放冷し、急速冷凍することにより製造することができる。ここで、物が凍る時に、水が氷になる温度帯−1〜−5℃を最大氷結晶生成帯と言い、急速冷凍とはこの生成帯を30分以内で通過させる様な冷凍方法を言う。例えば−30℃に設定した急速冷凍機で冷凍することができる。 Step (IV) is a step of quick freezing the baked bread. In step (IV), the freezing method is not particularly limited as long as it can realize quick freezing. For example, the bread dough can be produced by taking it out of the oven after baking or before baking it completely, allowing it to cool to room temperature (for example, 15 to 30 ° C.), and quick freezing it. Here, the temperature range of -1 to -5 ° C at which water turns into ice when an object freezes is called the maximum ice crystal formation zone, and quick freezing is a freezing method in which this formation zone is passed within 30 minutes. .. For example, it can be frozen in a quick freezer set at −30 ° C.

焼成後冷凍パンは、常温に放置する方法、電子レンジにて解凍する方法、冷凍したまま再度オーブンで再焼成(リベイク)することにより食することが可能である。 After baking, the frozen bread can be eaten by leaving it at room temperature, thawing it in a microwave oven, or re-baking it in an oven while it is frozen.

次に実施例を挙げて本発明を具体的に説明するが、これらの実施例は本発明を制限するものではない。 Next, the present invention will be specifically described with reference to examples, but these examples do not limit the present invention.

[焼成後冷凍パン用油脂組成物の製造]
表1の配合組成で、実施例1の焼成後冷凍パン用油脂組成物を製造した。すなわち食用油脂(パーム硬化油(融点42℃)5kg、パーム油30kg、菜種硬化油(融点36℃)35kg、および菜種油30kg)をプロペラ撹拌にて攪拌しながら、L−シスチン100g(平均粒子径29μm)を配合し80℃まで加熱したのち、50〜55℃に降温し、グルコアミラーゼ800gを添加後、ショートニング製造機を用いて急冷練り上げすることで実施例1の焼成後冷凍パン用油脂組成物を製造した。
同様にして、表1の配合組成で実施例2〜9、比較例1〜4の焼成後冷凍パン用油脂組成物を製造した。なお、比較例4は、(A)食用油脂と(B)L−シスチンを、別々に穀粉に添加した例である。
[Manufacturing of oil and fat composition for frozen bread after baking]
The oil and fat composition for frozen bread after baking of Example 1 was produced with the compounding composition shown in Table 1. That is, 100 g of L-cystine (average particle size 29 μm) while stirring edible oils and fats (hydrogenated palm oil (melting point 42 ° C.) 5 kg, palm oil 30 kg, hydrogenated rapeseed oil (melting point 36 ° C.) 35 kg, and rapeseed oil 30 kg) with propeller stirring. ), Heated to 80 ° C, lowered to 50-55 ° C, added 800 g of glucoamylase, and then rapidly cooled and kneaded using a shortening manufacturing machine to obtain the oil and fat composition for frozen bread after baking in Example 1. Manufactured.
Similarly, the oil and fat compositions for frozen bread after baking of Examples 2 to 9 and Comparative Examples 1 to 4 were produced with the compounding compositions shown in Table 1. Comparative Example 4 is an example in which (A) edible oil and fat and (B) L-cystine were separately added to the flour.

[焼成後冷凍パンの製造]
実施例1〜9、比較例1〜4の焼成後冷凍パン用油脂組成物を使用して、焼成後冷凍パンを製造した。すなわち、強力粉1000g、イーストフード1g、イースト20g、上白糖30g、食塩18g、水640gと焼成後冷凍パン用油脂組成物30gをミキサーボウルに投入し、低速4分間中速4分間捏ね上げ、捏ね上げ温度27℃の生地を得た。28℃で醗酵をさせ、開始から70分のときにパンチをいれガス抜きをし、さらに30分間醗酵させた。その後55gに分割し、次いでベンチタイムを25分間取った後、ラグビーボール状に成型した。鉄板に並べた生地を温度35℃、湿度75%のホイロに55分間入れて最終発酵を行った。最終発酵後10分間表面を乾燥させ、パン表面に切れ目(クープ)を入れた後、230℃のオーブンにて9分間焼成(再焼成用)、または11分間焼成した。焼成後、室温にて20分間放冷し、ビニールの袋に入れて封をした後、コマジャパン(株)社製急速冷凍庫にて−30℃まで冷却した。急速冷凍されたパンは、−20℃の冷凍庫にて保存した。焼成後冷凍パンは、皮剥がれの評価に用いた。
比較例3の焼成後冷凍パン用油脂組成物を使用した焼成後冷凍パンは、焼成工程の前に生地を急速冷凍し、−20℃で3日間保存した。そして、冷凍保存した生地を室温(20℃)に2時間放置して解凍した後に、ホイロに55分間入れて最終発酵を行った後に、230℃のオーブンにて11分間焼成し、実施例1と同様に急速冷凍した。
比較例4の焼成後冷凍パン用油脂組成物を使用した焼成後冷凍パンは、穀粉に対して焼成後冷凍パン用油脂組成物30gとL−シスチン0.03gを同時に添加し、得られた生地を実施例1と同様に焼成および急速冷凍した。
[Manufacturing of frozen bread after baking]
The post-baked frozen bread was produced using the oil and fat compositions for the post-baked frozen bread of Examples 1 to 9 and Comparative Examples 1 to 4. That is, 1000 g of strong flour, 1 g of yeast food, 20 g of yeast, 30 g of white sugar, 18 g of salt, 640 g of water and 30 g of oil and fat composition for frozen bread after baking are put into a mixer bowl and kneaded for 4 minutes at low speed and 4 minutes at medium speed. A dough having a temperature of 27 ° C. was obtained. Fermentation was carried out at 28 ° C., punched and degassed 70 minutes after the start, and further fermented for 30 minutes. After that, it was divided into 55 g, and then after taking a bench time of 25 minutes, it was molded into a rugby ball shape. The dough arranged on the iron plate was placed in a proofer having a temperature of 35 ° C. and a humidity of 75% for 55 minutes for final fermentation. After the final fermentation, the surface was dried for 10 minutes, a cut (coup) was made on the surface of the bread, and then the bread was baked in an oven at 230 ° C. for 9 minutes (for re-baking) or for 11 minutes. After firing, it was allowed to cool at room temperature for 20 minutes, put in a vinyl bag and sealed, and then cooled to −30 ° C. in a rapid freezer manufactured by Koma Japan Co., Ltd. The quick-frozen bread was stored in a freezer at −20 ° C. After baking, the frozen bread was used for evaluation of peeling.
In the post-baking frozen bread using the oil-and-fat composition for post-baking frozen bread of Comparative Example 3, the dough was rapidly frozen before the baking step and stored at −20 ° C. for 3 days. Then, the dough stored frozen was left at room temperature (20 ° C.) for 2 hours to thaw, then placed in a proofer for 55 minutes for final fermentation, and then baked in an oven at 230 ° C. for 11 minutes. It was also quick frozen.
In the post-baked frozen bread using the post-baked frozen bread oil / fat composition of Comparative Example 4, 30 g of the post-baked frozen bread oil / fat composition and 0.03 g of L-cystine were simultaneously added to the flour to obtain the dough. Was fired and quick frozen in the same manner as in Example 1.

[焼成後冷凍パンの解凍]
焼成後冷凍パンを室温(20℃)に2時間放置し、冷凍パン内部温度が20℃にまで上昇していることを確認した。11分間焼成したパンは、解凍後そのまま、9分間焼成したパンは、トースターにて220℃、2分再焼成したのち室温にて20分間放冷してから、パンの縮み、ボリューム、腰持ちの評価に用いた。
[Thawing frozen bread after baking]
After baking, the frozen pan was left at room temperature (20 ° C.) for 2 hours, and it was confirmed that the internal temperature of the frozen pan had risen to 20 ° C. Bread baked for 11 minutes is left as it is after thawing. Bread baked for 9 minutes is rebaked at 220 ° C for 2 minutes in a toaster and then allowed to cool at room temperature for 20 minutes. Used for evaluation.

[評価]
焼成後冷凍パン及び未焼成の冷凍パンの「冷凍保存中の皮剥がれ」、冷凍保存解凍後の「パンの縮み」、「ボリューム」、「腰持ち」について評価した。
[Evaluation]
"Peeling during frozen storage" of frozen bread after baking and unbaked frozen bread, "shrinkage of bread", "volume", and "holding" after thawing in frozen storage were evaluated.

〔皮剥がれの評価方法〕
冷凍保存中の焼成後冷凍パン(11分焼成品、9分焼成品)のクラスト部分を冷凍90日目と180日目に目視で観察した。クラスト部分に損傷が全く見られない場合を「5」とし、クラスト部分において剥がれている総面積が1センチ四方未満の場合を「4」、1センチ四方以上1.7センチ四方未満の場合を「3」、1.7センチ四方以上2.5センチ四方未満の場合を「2」、2.5センチ四方以上の場合を「1」として評価を行った。各焼成後冷凍パンについて、10個ずつに点数をつけ、その平均値が3以上の場合を合格とした。
[Evaluation method for peeling]
The crust portion of the frozen pan (11-minute baked product, 9-minute baked product) after baking during freezing storage was visually observed on the 90th and 180th days of freezing. "5" is when there is no damage to the crust part, "4" is when the total area peeled off in the crust part is less than 1 cm square, and "4" is when it is 1 cm square or more and less than 1.7 cm square. 3 ”, the case of 1.7 cm square or more and less than 2.5 cm square was evaluated as“ 2 ”, and the case of 2.5 cm square or more was evaluated as“ 1 ”. For each frozen bread after baking, a score was given to 10 pieces each, and a case where the average value was 3 or more was regarded as a pass.

〔パンの縮みの評価方法〕
冷凍90日目と180日目の焼成後冷凍パン(11分焼成品)を解凍したもの、焼成後冷凍パン(9分焼成品)を再焼成したもの、生のパン生地を冷凍後に焼成したものを用いて比容積を測定し、パンの縮みの指標とした。比容積は、アステックス(株)製3Dレーザー体積計を用いて測定した。パンの縮みは、焼成後冷凍前のパンの比容積をA、焼成後冷凍90日目もしくは冷凍180日目に解凍したパンの比容積をBとした際に下記(式1)にて表される値である。
縮み=A/B(式1)
上記式1により算出される縮みの値が、比較例1の油脂組成物を使用して焼成した焼成後冷凍パンの冷凍90日目における値を基準として、0.95倍未満の場合を「5」、0.97倍未満0.95倍以上の場合を「4」、0.99倍未満0.97以上の場合を「3」、1.10倍未満0.99以上の場合を「2」、1.10倍以上の場合を「1」として評価を行った。各焼成後冷凍パンについて、10個ずつに点数をつけ、その平均値が3以上の場合を合格とした。
[Evaluation method of bread shrinkage]
Thawed frozen bread (11-minute baked product) after baking on the 90th and 180th days of freezing, re-baked frozen bread (9-minute baked product) after baking, and baked raw bread dough after freezing. The specific volume was measured using this and used as an index of bread shrinkage. The specific volume was measured using a 3D laser volume meter manufactured by Astex Co., Ltd. The shrinkage of bread is represented by the following (formula 1) when the specific volume of bread after baking and before freezing is A, and the specific volume of bread thawed on the 90th day after freezing or 180 days after freezing is B. Value.
Shrinkage = A / B (Equation 1)
The case where the shrinkage value calculated by the above formula 1 is less than 0.95 times based on the value on the 90th day of freezing of the baked frozen pan baked using the fat and oil composition of Comparative Example 1 is "5". , Less than 0.97 times 0.95 times or more is "4", less than 0.99 times 0.97 or more is "3", less than 1.10 times 0.99 or more is "2" , 1.10 times or more was evaluated as "1". For each frozen bread after baking, a score was given to 10 pieces each, and a case where the average value was 3 or more was regarded as a pass.

〔ボリュームの評価方法〕
冷凍90日目と180日目の焼成後および半焼成後冷凍パンを解凍したものを用いて比容積を測定し、ボリューム評価の指標とした。比容積は、アステックス(株)製3Dレーザー体積計を用いて測定した。
比較例1の焼成後冷凍パン用油脂組成物を使用して焼成した焼成後又は半焼成後冷凍パンの焼成直後を基準として、ボリュームが1.10倍以上の場合を「5」、1.06倍以上1.10倍未満の場合を「4」、1.02倍以上1.06倍未満の場合を「3」、0.98倍以上1.02倍未満の場合を「2」、0.98倍未満の場合を「1」として評価を行った。なお、評価の基準は、同じ焼成工程のものを用いて評価した。各焼成後冷凍パンについて、10個ずつに点数をつけ、その平均値が3以上の場合を合格とした。
[Volume evaluation method]
The specific volume was measured by thawing the frozen bread after baking and semi-baking on the 90th and 180th days of freezing, and used as an index for volume evaluation. The specific volume was measured using a 3D laser volume meter manufactured by Astex Co., Ltd.
After baking using the oil / fat composition for frozen bread after baking in Comparative Example 1, after baking or after semi-baking and immediately after baking of the frozen bread, the case where the volume is 1.10 times or more is "5", 1.06. "4" for times of times or more and less than 1.10 times, "3" for cases of 1.02 times or more and less than 1.06 times, "2" for cases of 0.98 times or more and less than 1.02 times, 0. The case of less than 98 times was evaluated as "1". The evaluation criteria used were those of the same firing process. For each frozen bread after baking, a score was given to 10 pieces each, and a case where the average value was 3 or more was regarded as a pass.

〔腰持ちの評価方法〕
冷凍90日目と180日目の焼成後および半焼成後冷凍パンを解凍したものを用いて腰持ちを測定した。腰持ちは、アステックス(株)製3Dレーザー体積計を用いて測定した。腰持ちは、パンの最大高をH、短辺の横幅をWとした際に下記の(式2)にて表される値である。
腰持ち=H/W(式2)
比較例1の焼成後冷凍パン用油脂組成物を使用して焼成した焼成後又は半焼成後冷凍パンの焼成直後を基準として、腰持ちが1.05倍以上の場合を「5」、1.03倍以上1.05倍未満の場合を「4」、1.01倍以上1.03倍未満の場合を「3」、0.98倍以上1.01倍未満の場合を「2」、0.98倍以下の場合を「1」として評価を行った。なお、評価の基準は、同じ焼成工程のものを用いて評価した。各焼成後冷凍パンについて、10個ずつに点数をつけ、その平均値が3以上の場合を合格とした。
[Evaluation method of waist holding]
After baking and semi-baking on the 90th and 180th days of freezing, the thawed frozen bread was used to measure the waist retention. The waist holding was measured using a 3D laser volume meter manufactured by Astex Co., Ltd. The waist holding is a value expressed by the following (Equation 2) when the maximum height of the bread is H and the width of the short side is W.
Waist holding = H / W (formula 2)
After baking using the oil / fat composition for frozen bread after baking in Comparative Example 1, after baking or after semi-baking and immediately after baking of the frozen bread, the case where the waist holding is 1.05 times or more is "5". "4" for 03 times or more and less than 1.05 times, "3" for 1.01 times or more and less than 1.03 times, "2" for 0.98 times or more and less than 1.01 times, 0 The case of .98 times or less was evaluated as "1". The evaluation criteria used were those of the same firing process. For each frozen bread after baking, a score was given to 10 pieces each, and a case where the average value was 3 or more was regarded as a pass.

Figure 2021048792
Figure 2021048792

Figure 2021048792
Figure 2021048792

〔使用酵素〕
1.(商品名)「GRINDAMYL AG1500C」(グルコアミラーゼ)ダニスコジャパン(株)製、活性量1275u/g
[Enzyme used]
1. 1. (Product name) "GRINDAMYL AG1500C" (glucoamylase) manufactured by Danisco Japan Co., Ltd., active amount 1275u / g

表1及び表2の結果より、焼成後冷凍パンでは(B)L−シスチンが配合されない場合、(比較例1、2)、生地を冷凍させた場合(比較例3)、L−シスチンを穀粉に添加した場合(比較例4)には、冷凍保存中の皮剥がれ、冷凍保存解凍後のパン縮み、ボリューム、腰持ちにおいて満足のいく効果が得られないことが分かる。また、(B)L−シスチンと(C)グルコアミラーゼを併用することで(実施例1、3〜9)、冷凍保存中の皮剥がれ、冷凍保存解凍後のパン縮み、ボリューム、腰持ちにおいてより高い効果を得ることができる。

From the results of Tables 1 and 2, when (B) L-cystine is not blended in the frozen bread after baking (Comparative Examples 1 and 2), when the dough is frozen (Comparative Example 3), L-cystine is floured. When added to (Comparative Example 4), it can be seen that a satisfactory effect cannot be obtained in peeling during frozen storage, shrinkage of bread after freezing and thawing, volume, and firmness. In addition, by using (B) L-cystine and (C) glucoamylase in combination (Examples 1, 3 to 9), peeling during frozen storage, bread shrinkage after freezing and thawing, volume, and waist retention can be improved. A high effect can be obtained.

Claims (3)

食用油脂中にL−シスチンを含有する焼成後冷凍パン用油脂組成物。 A fat composition for frozen bread after baking, which contains L-cystine in edible fats and oils. 食用油脂中にグルコアミラーゼを含有する請求項1記載の焼成後冷凍パン用油脂組成物。 The oil / fat composition for frozen bread after baking according to claim 1, which contains glucoamylase in the edible oil / fat. 穀粉100質量部に対して、請求項1又は2記載の焼成後冷凍パン用油脂組成物を0.5〜20質量部含有する焼成後冷凍パン。


A post-baked frozen bread containing 0.5 to 20 parts by mass of the oil / fat composition for a post-baked frozen bread according to claim 1 or 2 with respect to 100 parts by mass of flour.


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