JP2021024785A - Water-in-oil emulsified composition - Google Patents
Water-in-oil emulsified composition Download PDFInfo
- Publication number
- JP2021024785A JP2021024785A JP2019141187A JP2019141187A JP2021024785A JP 2021024785 A JP2021024785 A JP 2021024785A JP 2019141187 A JP2019141187 A JP 2019141187A JP 2019141187 A JP2019141187 A JP 2019141187A JP 2021024785 A JP2021024785 A JP 2021024785A
- Authority
- JP
- Japan
- Prior art keywords
- water
- oil
- composition
- repellent
- emulsified composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 103
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000005871 repellent Substances 0.000 claims abstract description 63
- 239000000843 powder Substances 0.000 claims abstract description 53
- 239000007787 solid Substances 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 17
- 239000012071 phase Substances 0.000 claims description 9
- 239000008346 aqueous phase Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 150000002222 fluorine compounds Chemical class 0.000 claims description 4
- 238000004945 emulsification Methods 0.000 claims description 2
- 239000012190 activator Substances 0.000 abstract description 4
- 238000009472 formulation Methods 0.000 abstract description 4
- 229920005573 silicon-containing polymer Polymers 0.000 abstract description 4
- 230000000717 retained effect Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 94
- 235000019198 oils Nutrition 0.000 description 71
- 238000002360 preparation method Methods 0.000 description 11
- -1 fatty acid esters Chemical class 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002537 cosmetic Substances 0.000 description 7
- 239000000454 talc Substances 0.000 description 7
- 229910052623 talc Inorganic materials 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000010445 mica Substances 0.000 description 6
- 229910052618 mica group Inorganic materials 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000010702 perfluoropolyether Substances 0.000 description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 235000013871 bee wax Nutrition 0.000 description 3
- 239000012166 beeswax Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 229960005323 phenoxyethanol Drugs 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 230000003578 releasing effect Effects 0.000 description 3
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004907 Macro-emulsion Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 2
- 241001135917 Vitellaria paradoxa Species 0.000 description 2
- 206010000496 acne Diseases 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229940043348 myristyl alcohol Drugs 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010016334 Feeling hot Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000004812 organic fluorine compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036555 skin type Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、製剤中に含まれる水が塗布時に放出され、水滴となって現れる油中水型乳化組成物に関する。 The present invention relates to a water-in-oil emulsified composition in which water contained in a preparation is released at the time of application and appears as water droplets.
化粧料は、外観を美しく、肌を健やかにすることを主な機能とするが、近年、使用時において、実感できる付加的な機能を備えたものも提案されている。付加的な機能を備えたものとして、例えば、使用の際に温感や冷感を生じさせる化粧料や、肌に塗布することによってエマルジョンが崩壊して水が放出される、いわゆるウォーター−ドロップクイックブレイク型の化粧料（特許文献１〜３）等が提案されている。 The main function of cosmetics is to make the appearance beautiful and to make the skin healthy, but in recent years, those having additional functions that can be felt when used have been proposed. As a product with additional functions, for example, cosmetics that give a feeling of warmth or coldness when used, or so-called water-drop quick, in which an emulsion disintegrates and water is released when applied to the skin. Break-type cosmetics (Patent Documents 1 to 3) and the like have been proposed.
特許文献１〜３に記載の乳化製剤はいずれも、製剤中に水分を保持するため、ネットワーク構造を形成するシリコーンポリマーを用いている。しかし、シリコーンポリマーのようなシリコーン成分は、使用者の肌質によっては、吹き出物やニキビなどのトラブルの原因となることがある。そこで、近年、シリコーンを配合しない、いわゆる「ノンシリコーン」タイプの化粧料が提案され、その認知度および需要が高まっている。このため、ノンシリコーンタイプとして処方を設計することは、化粧料の付加価値の向上につながるといえる。この点、ウォーター−ドロップクイックブレイク型の乳化組成物も同様である。
そこで、本発明は、シリコーンポリマーを用いることなく、製剤中に水分を保持することができ、組成物に含まれる水が塗布時に水滴となって現れる新たな油中水型乳化組成物を提供することを目的としている。
All of the emulsified preparations described in Patent Documents 1 to 3 use a silicone polymer that forms a network structure in order to retain water in the preparation. However, a silicone component such as a silicone polymer may cause troubles such as pimples and acne depending on the skin type of the user. Therefore, in recent years, so-called "non-silicone" type cosmetics that do not contain silicone have been proposed, and their recognition and demand are increasing. Therefore, it can be said that designing the prescription as a non-silicone type leads to an increase in the added value of cosmetics. In this respect, the same applies to the water-drop quick break type emulsified composition.
Therefore, the present invention provides a new water-in-oil emulsified composition which can retain water in a formulation without using a silicone polymer and in which water contained in the composition appears as water droplets at the time of application. The purpose is.
本発明は、固体油と撥水撥油性紛体とを配合することにより、水の含有量が高い油中水型乳化組成物を安定化し、肌に塗布する際、組成物から放出された水により水滴を生じさせることが可能となるという知見に基づいており、以下の構成を備えている。 The present invention stabilizes a water-in-oil emulsified composition having a high water content by blending a solid oil and a water-repellent oil-repellent powder, and when applied to the skin, the water released from the composition is used. Based on the finding that it is possible to generate water droplets, it has the following configuration.
［１］（Ａ）常温で液体の液体油、（Ｂ）常温で固体の固体油、（Ｃ）撥水撥油性紛体、（Ｄ）界面活性剤および（Ｅ）水を含有している油中水型乳化組成物。
［２］前記（Ａ）液体油の含有量が１．０〜１５重量％であり、前記（Ｂ）固体油の含有量が２．０〜１０重量％であり、前記（Ｃ）撥水撥油性紛体の含有量が０．１〜１．５重量％である［１］に記載の油中水型乳化組成物。
［３］前記（Ｅ）水の含有量が６０〜９０重量％である［１］に記載の油中水型乳化組成物。
[1] In an oil containing (A) a liquid oil that is liquid at room temperature, (B) a solid oil that is solid at room temperature, (C) a water-repellent oil-repellent powder, (D) a surfactant, and (E) water. Aqueous emulsified composition.
[2] The content of the liquid oil (A) is 1.0 to 15% by weight, the content of the solid oil (B) is 2.0 to 10% by weight, and the water repellency (C) is water repellent. The water-in-oil emulsified composition according to [1], wherein the content of the oily powder is 0.1 to 1.5% by weight.
[3] The water-in-oil emulsified composition according to [1], wherein the content of (E) water is 60 to 90% by weight.
［４］前記（Ｃ）撥水撥油性紛体は、フッ素化合物で表面処理された無機紛体である［１］に記載の油中水型乳化組成物。
［５］前記（Ｃ）撥水撥油性紛体の含有量が前記（Ｂ）固体油の含有量の１／１００〜１／２である［４］に記載の油中水型乳化組成物。
［６］前記（Ｄ）界面活性剤はＨＬＢが２〜１１である［１］に記載の油中水型乳化組成物。
[4] The water-in-oil emulsified composition according to [1], wherein the (C) water- and oil-repellent powder is an inorganic powder surface-treated with a fluorine compound.
[5] The water-in-oil emulsified composition according to [4], wherein the content of the (C) water- and oil-repellent powder is 1/100 to 1/2 of the content of the (B) solid oil.
[6] The water-in-oil emulsified composition according to [1], wherein the (D) surfactant has an HLB of 2 to 11.
［７］油相に分散する水相の平均粒子径が１〜１００μｍである［１］に記載の油中水型乳化組成物。
［８］（Ｆ）シリコーン成分を実質的に含有しない［１］に記載の油中水型乳化組成物。
[7] The water-in-oil emulsified composition according to [1], wherein the average particle size of the aqueous phase dispersed in the oil phase is 1 to 100 μm.
[8] The water-in-oil emulsified composition according to [1], which does not substantially contain the (F) silicone component.
［９］皮膚に塗布することにより、油相に分散する水相が放出される［１］〜［８］のいずれか１項に記載の油中水型乳化組成物。 [9] The water-in-oil emulsified composition according to any one of [1] to [8], wherein an aqueous phase dispersed in the oil phase is released when applied to the skin.
本発明の油中水型乳化組成物は、（Ｃ）撥水撥油性紛体が、油相と水相との界面を安定化するとともに、皮膚に塗布する際に加わる力により、乳化状態が破壊され、内包する水を放出する。このため、肌に塗布することにより、組成物に含まれる水が放出され、水滴となって現れる、新たなウォーター−ドロップクイックブレイク型の油中水型乳化組成物を提供できる。 In the water-in-oil emulsified composition of the present invention, the (C) water-repellent oil-repellent powder stabilizes the interface between the oil phase and the water phase, and the emulsified state is destroyed by the force applied when applied to the skin. And release the contained water. Therefore, it is possible to provide a new water-drop quick break type water-in-oil emulsified composition in which the water contained in the composition is released and appears as water droplets when applied to the skin.
本発明の油中水型乳化組成物（以下、適宜「組成物」ともいう）は、（Ａ）常温で液体の液体油、（Ｂ）常温で固体の固体油、（Ｃ）撥水撥油性紛体、（Ｄ）界面活性剤および（Ｅ）水を含有している。（Ｂ）固体油と（Ｃ）撥水撥油性紛体との併用により、水性成分の含有量を高くすることができるから、肌に塗布した際、水相の放出を十分に実感できる、水放出性のよい組成物となる。 The water-in-oil emulsified composition of the present invention (hereinafter, also appropriately referred to as “composition”) is (A) a liquid oil that is liquid at room temperature, (B) a solid oil that is solid at room temperature, and (C) water and oil repellency. It contains a powder, (D) a surfactant and (E) water. By using (B) solid oil and (C) water-repellent oil-repellent powder in combination, the content of aqueous components can be increased, so when applied to the skin, the release of the aqueous phase can be fully felt. The composition has good properties.
（Ａ）常温で液体の液体油
液体油とは、常温（２５℃）において液体である油性成分をいう。液体油は、常温で液体であるから、その融点は２５℃以下である。ベタツキが抑えられた良好な使用感とする観点から、融点が２０℃以下の液体油が好ましい。また、安定的に液体油として機能させる観点から、融点が０℃以下の液体油が好ましい。
(A) Liquid oil that is liquid at room temperature Liquid oil refers to an oily component that is liquid at room temperature (25 ° C.). Since liquid oil is liquid at room temperature, its melting point is 25 ° C. or lower. A liquid oil having a melting point of 20 ° C. or lower is preferable from the viewpoint of suppressing stickiness and providing a good usability. Further, from the viewpoint of stably functioning as a liquid oil, a liquid oil having a melting point of 0 ° C. or lower is preferable.
液体油としては、例えば、オリーブ油、ヒマワリ油、アボカド油などの植物由来の油脂；流動パラフィン、軽質イソパラフィン、流動イソパラフィン等の直鎖又は分岐の炭化水素油；ミリスチン酸イソプロピル、ミリスチン酸オクチルドデシル等の多価アルコール脂肪酸エステル等のエステル油；水添ポリイソブテンなど水素添加により酸化安定性を高めた油；ジメチルポリシロキサン、ジメチルシクロポリシロキサン、メチルフェニルポリシロキサン等のシリコーン油；フルオロポリエーテル、パーフルオロアルキルエーテルシリコーン等のフッ素油などが挙げられる。これらは、単独で用いても、二種以上を混合して用いてもよい。 Examples of the liquid oil include plant-derived fats and oils such as olive oil, sunflower oil, and avocado oil; linear or branched hydrocarbon oils such as liquid paraffin, light isoparaffin, and liquid isoparaffin; isopropyl myristate, octyldodecyl myristate, and the like. Ester oils such as polyhydric alcohol fatty acid esters; oils whose oxidative stability is enhanced by hydrogenation such as hydrogenated polyisobutene; silicone oils such as dimethylpolysiloxane, dimethylcyclopolysiloxane, methylphenylpolysiloxane; fluoropolyether, perfluoroalkyl Fluorooil such as ether silicone can be mentioned. These may be used alone or in combination of two or more.
組成物１００重量％中の液体油の含有量は、１．０〜１５重量％が好ましく、２．０〜１０重量％がより好ましく、３．０〜８．０重量％がさらに好ましい。なお、本発明において、数値範囲Ａ〜Ｂは、Ａ以上Ｂ以下を示す。 The content of the liquid oil in 100% by weight of the composition is preferably 1.0 to 15% by weight, more preferably 2.0 to 10% by weight, still more preferably 3.0 to 8.0% by weight. In the present invention, the numerical ranges A to B indicate A or more and B or less.
（Ｂ）常温で固体の固体油
固体油とは、常温において固体である油性成分をいう。固体油は、常温で固体であることから、その融点は２５℃よりも高い。
(B) Solid oil solid at room temperature Solid oil means an oily component that is solid at room temperature. Since solid oil is solid at room temperature, its melting point is higher than 25 ° C.
固体油としては、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸等の高級脂肪酸；イソステアリルアルコール、セタノール、ベヘニルアルコール、ミリスチルアルコール等の高級脂肪族アルコール；蜜蝋（ミツロウ）、羊毛蝋などの動物由来の油脂；シア油、カルバナワックス、キャンデリラワックス、ライスワックス等の植物由来ワックス；分岐炭化水素（イソパラフィン）、直鎖状炭化水素、飽和環状炭化水素、マイクロクリスタリンワックス、パラフィンワックスなどの石油由来の油などが挙げられる。これらは、単独で用いても、二種以上を混合して用いてもよい。 Solid oils include higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid; higher aliphatic alcohols such as isostearyl alcohol, cetanol, behenyl alcohol and myristyl alcohol; animal-derived beeswax, wool wax and the like. Oils and fats; plant-derived waxes such as shea oil, carbana wax, candelilla wax, and rice wax; petroleum-derived waxes such as branched hydrocarbons (isoparaffin), linear hydrocarbons, saturated cyclic hydrocarbons, microcrystallin wax, and paraffin wax. Examples include oil. These may be used alone or in combination of two or more.
組成物１００重量％中の固体油の含有量は、肌に塗布する際に水を放出して、組成物に含まれる水が水滴となって現れる作用（適宜「水放出性」という）を良好にする観点から、２．０〜１０重量％が好ましく、３．０〜８．０重量％がより好ましく、４．０〜６．０重量％がさらに好ましい。 The content of the solid oil in 100% by weight of the composition has a good action (appropriately referred to as "water release property") in which water is released when applied to the skin and the water contained in the composition appears as water droplets. From the viewpoint of the above, 2.0 to 10% by weight is preferable, 3.0 to 8.0% by weight is more preferable, and 4.0 to 6.0% by weight is further preferable.
組成物の安定性の観点から、組成物１００重量％中における（Ａ）液体油と（Ｂ）固体油との含有量の合計（Ａ＋Ｂ）は、５．０〜１５重量％が好ましく、７．０〜１４重量％がより好ましく、８．０〜１３重量％がさらに好ましい。また、組成物中の（Ｂ）固体油と（Ａ）液体油との含有量（重量％）の比（Ｂ／Ａ）は、組成物の安定性の観点から３／７以上が好ましく、２／３以上がより好ましく、１／１以上がさらに好ましい。また、組成物の水放出性を良好にする観点から、比（Ｂ／Ａ）は、４／１以下が好ましく、３／１以下がより好ましく、２／１以下がさらに好ましい。 From the viewpoint of the stability of the composition, the total content (A + B) of the liquid oil (A) and the solid oil (B) in 100% by weight of the composition is preferably 5.0 to 15% by weight. 0 to 14% by weight is more preferable, and 8.0 to 13% by weight is further preferable. The ratio (B / A) of the content (% by weight) of the (B) solid oil and the (A) liquid oil in the composition is preferably 3/7 or more from the viewpoint of the stability of the composition. / 3 or more is more preferable, and 1/1 or more is further preferable. Further, from the viewpoint of improving the water release property of the composition, the ratio (B / A) is preferably 4/1 or less, more preferably 3/1 or less, and further preferably 2/1 or less.
（Ｃ）撥水撥油性紛体
撥水撥油性紛体とは、撥水性および撥油性を備えた紛体をいう。紛体の表面を撥水撥油性化合物で処理し、撥水撥油性を備えた皮膜を形成することにより、撥水撥油性紛体となる。本発明において、「撥水撥油性」とは、水および油の両方と馴染まない性質をいう。
(C) Water-repellent and oil-repellent powder The water- and oil-repellent powder means a powder having water repellency and oil repellency. By treating the surface of the powder with a water- and oil-repellent compound to form a film having water- and oil-repellent properties, the powder becomes a water- and oil-repellent powder. In the present invention, "water and oil repellency" refers to a property that is incompatible with both water and oil.
撥水撥油性紛体は、例えば、紛体の表面をフッ素化合物で処理することによって得られる。フッ素化合物とは、フッ素原子を含む有機フッ素化合物をいい、化合物中の水素が完全にフッ素化されたパーフルオロ化合物が好ましい。パーフルオロ化合物としては、例えば、パーフルオロプロポキシ−９ジメチルアミノプロピルアミド等のパーフルオロポリエーテル基を有するパーフルオロポリエーテル誘導体が挙げられる。 The water- and oil-repellent powder is obtained, for example, by treating the surface of the powder with a fluorine compound. The fluorine compound refers to an organic fluorine compound containing a fluorine atom, and a perfluoro compound in which hydrogen in the compound is completely fluorinated is preferable. Examples of the perfluoro compound include a perfluoropolyether derivative having a perfluoropolyether group such as perfluoropropoxy-9 dimethylaminopropylamide.
撥水撥油性紛体を構成する紛体は、無機紛体および有機紛体のいずれでもよいが、組成物の安定性の観点から、無機紛体が好ましい。無機紛体としては、例えば、酸化チタン、マイカ、セリサイト、タルク、シリカ、酸化鉄、酸化スズ等が挙げられる。 The powder constituting the water- and oil-repellent powder may be either an inorganic powder or an organic powder, but an inorganic powder is preferable from the viewpoint of stability of the composition. Examples of the inorganic powder include titanium oxide, mica, sericite, talc, silica, iron oxide, tin oxide and the like.
表面がパーフルオロポリエーテル誘導体で処理された無機紛体としては、日光ケミカルズ（株）製、ＮＩＫＫＯＬＦＯＮＣＯＡＴシリーズ（酸化チタン：ＴＩ−１、マイカ：ＭＩ−１、セリサイト：ＳＥ−１、タルク：ＴＡ−１、黒酸化鉄：ＩＢ−１、赤酸化鉄：ＩＲ−１、黄酸化鉄：ＩＹ−１）が挙げられる。 As an inorganic powder whose surface has been treated with a perfluoropolyether derivative, NIKKOLFONCOAT series manufactured by Nikko Chemicals Co., Ltd. (titanium oxide: TI-1, mica: MI-1, sericite: SE-1, talc: TA- 1. Black iron oxide: IB-1, red iron oxide: IR-1, yellow iron oxide: IY-1).
（Ｃ）撥水撥油性紛体と（Ｂ）固体油とを併用することにより、油中水型乳化系の界面を安定化することができる。組成物の水放出性を良好にする観点から、組成物１００重量％中における撥水撥油性紛体の含有量は、０．１重量％以上が好ましく、０．２重量％以上がより好ましく、０．３重量％以上がさらに好ましい。また、組成物の安定性の観点から、紛体の含有量は２．０重量％以下が好ましく、１．５重量％以下がより好ましく、１．２重量％以下がさらに好ましい。 By using (C) a water-repellent oil-repellent powder and (B) a solid oil in combination, the interface of the water-in-oil emulsified system can be stabilized. From the viewpoint of improving the water release property of the composition, the content of the water-repellent oil-repellent powder in 100% by weight of the composition is preferably 0.1% by weight or more, more preferably 0.2% by weight or more, and 0. .3% by weight or more is more preferable. From the viewpoint of the stability of the composition, the content of the powder is preferably 2.0% by weight or less, more preferably 1.5% by weight or less, still more preferably 1.2% by weight or less.
組成物の水放出性を良好にする観点から、組成物中の（Ｃ）撥水撥油性紛体と（Ｂ）固体油との含有量（重量％）の比（Ｃ／Ｂ）は、１／１００以上が好ましく、１／５０以上がより好ましく、１／２０以上がさらに好ましい。組成物の経時的な安定性を良好にする観点から、上記の比（Ｃ／Ｂ）は、１／２以下が好ましく、１／３以下がより好ましく、１／５以下がさらに好ましい。 From the viewpoint of improving the water release property of the composition, the ratio (C / B) of the content (% by weight) of (C) water-repellent oil-repellent powder and (B) solid oil in the composition is 1 /. 100 or more is preferable, 1/50 or more is more preferable, and 1/20 or more is further preferable. From the viewpoint of improving the stability of the composition over time, the above ratio (C / B) is preferably 1/2 or less, more preferably 1/3 or less, and even more preferably 1/5 or less.
組成物の水放出性を良好にする観点から、組成物中の（Ｃ）撥水撥油性紛体と（Ａ）液体油および（Ｂ）固体油の含有量の合計（Ａ＋Ｂ）との比Ｃ／（Ａ＋Ｂ）は、１／１００以上が好ましく、１／２０以上がより好ましい。組成物の安定性を良好にする観点から、上記の比Ｃ／（Ａ＋Ｂ）は、１／４以下が好ましく、１／５以下がより好ましい。 From the viewpoint of improving the water release property of the composition, the ratio of (C) water-repellent oil-repellent powder to (A) the total content of liquid oil and (B) solid oil (A + B) in the composition C / (A + B) is preferably 1/100 or more, and more preferably 1/20 or more. From the viewpoint of improving the stability of the composition, the above ratio C / (A + B) is preferably 1/4 or less, more preferably 1/5 or less.
撥水撥油性紛体の形状は特に限定されるものではなく、例えば、球形状や紡錘形状の撥水撥油性紛体を用いることができる。 The shape of the water- and oil-repellent powder is not particularly limited, and for example, a spherical or spindle-shaped water- and oil-repellent powder can be used.
組成物の水放出性を良好にする観点から、（Ｂ）固体油および（Ｃ）撥水撥油性紛体の含含有量の合計（Ｂ＋Ｃ）と（Ａ）液体油の含有量との比（Ｂ＋Ｃ）／Ａは、０．７以上が好ましく、０．８以上がより好ましく、１．０以上がさらに好ましい。また、組成物の安定性を良好にする観点から、（Ｂ＋Ｃ）／Ａは２．０以下が好ましく、１．８以下がより好ましく、１．６以下がさらに好ましい。 From the viewpoint of improving the water release property of the composition, the ratio of the total content of (B) solid oil and (C) water-repellent oil-repellent powder (B + C) to the content of (A) liquid oil (B + C). ) / A is preferably 0.7 or more, more preferably 0.8 or more, and even more preferably 1.0 or more. Further, from the viewpoint of improving the stability of the composition, (B + C) / A is preferably 2.0 or less, more preferably 1.8 or less, and further preferably 1.6 or less.
（Ｄ）界面活性剤
本実施形態の組成物は、界面活性剤を含有している。界面活性剤としては、高級脂肪酸ＰＥＧグリセリル、高級脂肪酸グリセリル、高級脂肪酸ソルビタン、ＰＥＧ−水添ヒマシ油などの非イオン性界面活性剤が挙げられる。これらのうち、製剤の安定性の観点から、非イオン性界面活性剤は、ＨＬＢが２以上１２未満のものが好ましく、２以上１１以下のものがより好ましく、２以上１０以下のものがさらに好ましい。界面活性剤は、単独または複数を混合して用いることができる。非イオン性界面活性剤を複数用いた混合物の場合、各非イオン性界面活性剤のＨＬＢに混合物中で占める割合を乗じた値の合計を混合物のＨＬＢとする。本発明において、ＨＬＢは実測法により求めた値をいう。実測法は、標準となる界面活性剤とＨＬＢ未知の乳化剤との組合せを用いて、標準となる油（流動パラフィン）を乳化し、最も安定なエマルジョンが得られる組み合わせにおける乳化剤の比率から未知の乳化剤のＨＬＢの値を求める方法である。
(D) Surfactant The composition of the present embodiment contains a surfactant. Examples of the surfactant include nonionic surfactants such as higher fatty acid PEG glyceryl, higher fatty acid glyceryl, higher fatty acid sorbitan, and PEG-hydrogenated castor oil. Of these, from the viewpoint of formulation stability, the nonionic surfactant preferably has an HLB of 2 or more and less than 12, more preferably 2 or more and 11 or less, and further preferably 2 or more and 10 or less. .. The surfactant may be used alone or in combination of two or more. In the case of a mixture using a plurality of nonionic surfactants, the sum of the values obtained by multiplying the HLB of each nonionic surfactant by the ratio of each nonionic surfactant in the mixture is taken as the HLB of the mixture. In the present invention, HLB refers to a value obtained by an actual measurement method. In the actual measurement method, a standard oil (liquid paraffin) is emulsified using a combination of a standard surfactant and an emulsifier of unknown HLB, and an emulsifier unknown from the ratio of the emulsifier in the combination that gives the most stable emulsion. This is a method for obtaining the HLB value of.
水放出性と乳化安定性を良好にする観点から、組成物１００重量％中における界面活性剤の含有量は、０．１〜５重量％が好ましく、０．５〜４重量％がより好ましく、１〜３重量％がさらに好ましい。
界面活性剤を上述した（Ａ）液体油、（Ｂ）固体油および（Ｃ）撥水撥油性紛体と併用することにより、シリコーン系の界面活性剤を用いることなく、水放出性の良好な油中水型乳化組成物を提供することができる。
From the viewpoint of improving water release property and emulsion stability, the content of the surfactant in 100% by weight of the composition is preferably 0.1 to 5% by weight, more preferably 0.5 to 4% by weight. 1 to 3% by weight is more preferable.
By using the surfactant in combination with the above-mentioned (A) liquid oil, (B) solid oil and (C) water-repellent oil-repellent powder, an oil having good water release property without using a silicone-based surfactant. A medium-water emulsified composition can be provided.
（Ｂ）固体油および（Ｃ）撥水撥油性紛体の含有量の合計（Ｂ＋Ｃ）と（Ａ）液体油の含有量との比（Ｂ＋Ｃ）／Ａは、水放出性を良好にする観点から、０．７以上が好ましく、０．８以上がより好ましく、１．０以上がさらに好ましい。また、当該比（Ｂ＋Ｃ）／Ａは、組成物の安定性の観点から、４以下が好ましく、３以下がより好ましい。 The ratio of the total content of (B) solid oil and (C) water-repellent oil-repellent powder (B + C) to the content of (A) liquid oil (B + C) / A is from the viewpoint of improving water release. , 0.7 or more is preferable, 0.8 or more is more preferable, and 1.0 or more is further preferable. Further, the ratio (B + C) / A is preferably 4 or less, more preferably 3 or less, from the viewpoint of stability of the composition.
（Ｅ）水
水放出性が良好な組成物とする観点から、組成物１００重量％中における水の含有量は、６０重量％以上が好ましく、７０重量％以上がより好ましく、８０重量％以上がさらに好ましい。経時的な安定性の良い組成物とする観点から、組成物中の水の含有量は、９０重量％以下が好ましく、８８重量％以下がより好ましい。
(E) From the viewpoint of making a composition having good water release property, the content of water in 100% by weight of the composition is preferably 60% by weight or more, more preferably 70% by weight or more, and 80% by weight or more. More preferred. From the viewpoint of obtaining a composition having good stability over time, the content of water in the composition is preferably 90% by weight or less, more preferably 88% by weight or less.
（粘度）
本発明の油中水型乳化組成物の粘度は、２００００ｍＰａ・ｓ〜５００００ｍＰａ・ｓ程度になる。５００００ｍＰａ・ｓ以上の高粘度とすることで、水の含有量が高い油中水型乳化組成物を経時的な安定性を向上させることができる。なお、上記粘度は、Ｂ型粘度計を使用して、２５℃、５ｒｐｍで測定された値をいう。
(viscosity)
The viscosity of the water-in-oil emulsified composition of the present invention is about 20000 mPa · s to 50,000 mPa · s. By setting the viscosity to 50,000 mPa · s or more, the stability of the water-in-oil emulsified composition having a high water content over time can be improved. The viscosity is a value measured at 25 ° C. and 5 rpm using a B-type viscometer.
（乳化粒子）
本発明の油中水型乳化組成物は、平均粒子径（Ｄ５０、メジアン径）が１〜１００μｍ程度のマクロエマルジョンである。このため、塗布の際に体感できるほど高い割合で水を含有することが可能になり、組成物を皮膚に塗布した際、油の連続相から多量の水が放出される、水放出性の良好な組成物となる。
(Emulsified particles)
The water-in-oil emulsified composition of the present invention is a macroemulsion having an average particle size (D50, median diameter) of about 1 to 100 μm. Therefore, it is possible to contain water in a high proportion that can be felt at the time of application, and when the composition is applied to the skin, a large amount of water is released from the continuous phase of the oil, and the water release property is good. Composition.
固体油と撥水撥油性紛体とを併用することにより、水相と油相との界面に撥水撥油性紛体を位置させることにより界面が硬くなって、高濃度の水を内包する油中水型乳化組成物の安定性が向上すると推定される。界面の硬い乳化系とすることにより、肌への塗布の際に加わる力によって容易に乳化系が壊れる、水放出性の良好な組成物となる。 By using solid oil and water-repellent oil-repellent powder together, the interface becomes hard by locating the water-repellent oil-repellent powder at the interface between the aqueous phase and the oil phase, and the water in the oil contains a high concentration of water. It is presumed that the stability of the mold emulsified composition is improved. By using an emulsifying system having a hard interface, the composition has a good water release property, in which the emulsifying system is easily broken by the force applied at the time of application to the skin.
（Ｆ）シリコーン成分
本発明は、（Ｂ）固体油脂と（Ｃ）撥水撥油性紛体とを併用することで、シリコーン系の活性剤を用いることなく、水放出性が良好な、使用の際に水が湧き出るような印象を与える油中水型乳化組成物を実現している。本発明の組成物は、シリコーン系の活性剤を用いることなく、水放出性を実現しているから、組成物中に含まれるシリコーン成分を実質的に含有しない、いわゆる「ノンシリコーン」の組成物とすることも可能である。本発明においてはケイ素を含む有機化合物を「シリコーン成分」という。また、「実質的に含有しない」とは、その所期の機能を奏する量の「シリコーン成分」を含有しないことをいう。例えば、シリコーン系の活性剤の場合、組成物１００重量％中の含有量が０．１重量％以下であれば、「実質的に含有しない」にあたる。
(F) Silicone component In the present invention, by using (B) solid oil and fat and (C) water-repellent oil-repellent powder in combination, water release property is good without using a silicone-based activator. We have realized a water-in-oil emulsification composition that gives the impression that water springs out. Since the composition of the present invention realizes water release property without using a silicone-based activator, it is a so-called "non-silicone" composition that does not substantially contain the silicone component contained in the composition. It is also possible to. In the present invention, an organic compound containing silicon is referred to as a "silicone component". In addition, "substantially free" means that the amount of "silicone component" that exerts the intended function is not contained. For example, in the case of a silicone-based activator, if the content in 100% by weight of the composition is 0.1% by weight or less, it corresponds to "substantially not contained".
本発明の組成物は、油性成分が連続相を構成しているから、使用の際、伸びの良さを実感しやすい。また、油性成分の皮膜を皮膚に形成して、水分蒸散を防止し潤いを保持するエモリエント効果に優れるという特長を備えている。 In the composition of the present invention, since the oily component constitutes a continuous phase, it is easy to realize the good elongation when used. In addition, it has the feature of forming a film of oily components on the skin and having an excellent emollient effect of preventing water evaporation and retaining moisture.
本実施形態の組成物は、上述した成分以外に、医薬品や化粧品の分野において一般に用いられている成分を含有してもよい。このような成分としては、クエン酸およびクエン酸ナトリウム等のｐＨ調整剤；フェノキシエタノール、安息香酸ナトリウムおよびパラベンなどの防腐剤；ビーズポリマー等の滑材；ピロリドンカルボン酸ナトリウム塩、グリセリン、１，３−ブチレングリコール（ＢＧ）などの保湿剤；ビタミン類；無機フィラー；香料；などが挙げられる。これら成分の含有量は、本実施形態の組成物の特性に悪い影響を与えない範囲とすればよい。 In addition to the above-mentioned ingredients, the composition of the present embodiment may contain ingredients generally used in the fields of pharmaceuticals and cosmetics. Such components include pH regulators such as citric acid and sodium citrate; preservatives such as phenoxyethanol, sodium benzoate and paraben; lubricants such as bead polymers; sodium pyrrolidone carboxylate, glycerin, 1,3- Moisturizers such as butylene glycol (BG); vitamins; inorganic fillers; fragrances; and the like. The content of these components may be in a range that does not adversely affect the characteristics of the composition of the present embodiment.
以下、実施例によって本発明をより具体的に説明するが、本発明はこれらに限定されるものではない。なお、以下の説明における％は重量％である。 Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto. In addition,% in the following description is weight%.
まず、実施例および比較例において用いた成分を以下に示す。
（Ａ）液体油
オリーブ油：ＮＩＫＫＯＬ オリーブ油（製品名、日光ケミカルズ（株）製）
ミリスチン酸イソプロピル：ＩＰＭ−Ｒ（製品名、日油（株）製）
水添ポリイソブテン：パールリーム１８（製品名、日油（株）製）
（Ｂ）固体油
ミツロウ：精製ミツロウ ＣＹ−１００（横関油脂工業（株）製）
ミリスチルアルコール：ＮＡＡ−４３（製品名、日油（株）製）
ステアリン酸：ＮＡＡ−１８０（製品名、日油（株）製）
シア脂 ：ビオデルマＳ−１９（製品名、一丸ファルコス（株）製）
（Ｃ）撥水撥油性紛体
パーフルオロポリエーテル誘導体（ＰＦＰＯＰ）処理タルク（タルク、パーフルオロプロポキシ（パーフルオロＰＰＧ）−９ジメチルアミノプロピルアミド、リン酸）：ＦＯＮＣＯＡＴ ＴＡ−１：（製品名、日光ケミカルズ（株）製）
ＰＦＰＯＰ処理マイカ（マイカ、パーフルオロプロポキシ（パーフルオロＰＰＧ）−９ジメチルアミノプロピルアミド、リン酸）：ＦＯＮＣＯＡＴ ＭＩ−１（製品名、日光ケミカルズ（株）製）
ＰＦＰＯＰ処理チタン（酸化チタン、パーフルオロプロポキシ（パーフルオロＰＰＧ）−９ジメチルアミノプロピルアミド、リン酸）：ＦＯＮＣＯＡＴ ＴＩ−１：（製品名、日光ケミカルズ（株）製）
ＰＦＰＯＰ処理セリサイト（セリサイト、パーフルオロプロポキシ（パーフルオロＰＰＧ）−９ジメチルアミノプロピルアミド、リン酸）：ＦＯＮＣＯＡＴ ＳＥ−１（製品名、日光ケミカルズ（株）製）
（Ｄ）界面活性剤
モノオレイン酸グリセリル：ＮＩＫＫＯＬ ＭＧＯ（製品名、日光ケミカルズ（株）製、ＨＬＢ２．５）
オレイン酸ソルビタン：ＮＩＫＫＯＬ ＳＯ−１０Ｖ（製品名、日光ケミカルズ（株）製、ＨＬＢ４．３）
ベヘネス−５：ＮＩＫＫＯＬ ＢＢ−５（製品名、日光ケミカルズ（株）製）（ＨＬＢ７．０）
ＰＰＧ−４セテス−１：ＮＩＫＫＯＬ ＰＢＣ−３１（日光ケミカルズ（株）製、ＨＬＢ９．５）
イソステアリン酸ポリグリセリル−１０：ＮＩＫＫＯＬ ＤＥＣＡＧＬＹＮ １−ＩＳＶ（製品名、日光ケミカルズ（株）製、ＨＬＢ１２．０）
（他の成分）
ＢＧ（１、３ブチレングリコール）：１３ＢＧ−ＵＫ（製品名、ダイセル化学（株）製）
フェノキシエタノール：Ｍｉｃｒｏｃａｒｅ ＰＥ（製品名、ソー・ジャパン（株）製）
タルク：タルク ＥＸ−１５（製品名、（株）ヤマグチマイカ製）
マイカ：マイカ ＦＡ−４５０（製品名、（株）ヤマグチマイカ製）
酸化チタン、酸化鉄：：ＰＨＯＴＯＬＩＴＥ ＬＹ−Ｓ（製品名、（株）ヤマグチマイカ製）
セリサイト：セリサイトＦＳＥ（製品名、三信鉱工（株）製）
ポリパーフルオロメチルイソプロピルエーテル：フォンブリン ＨＣ ＰＥＰＥ（製品名、ＳＯＬＢＡＹ社製）
First, the components used in Examples and Comparative Examples are shown below.
(A) Liquid oil Olive oil: NIKKOL olive oil (product name, manufactured by Nikko Chemicals Co., Ltd.)
Isopropyl myristate: IPM-R (product name, manufactured by NOF CORPORATION)
Hydrogenated polyisobutene: Pearl Dream 18 (product name, manufactured by NOF CORPORATION)
(B) Solid oil beeswax: Refined beeswax CY-100 (manufactured by Yokoseki Oil & Fat Industry Co., Ltd.)
Myristyl alcohol: NAA-43 (product name, manufactured by NOF CORPORATION)
Stearic acid: NAA-180 (product name, manufactured by NOF CORPORATION)
Shea butter: Bioderma S-19 (product name, manufactured by Ichimaru Falcos Co., Ltd.)
(C) Water- and oil-repellent powder Perfluoropolyether derivative (PFPOP) -treated talc (talc, perfluoropropoxy (perfluoroPPG) -9 dimethylaminopropylamide, phosphoric acid): FONCOAT TA-1: (product name, sunlight Made by Chemicals Co., Ltd.)
PFPOP-treated mica (mica, perfluoropropoxy (perfluoroPPG) -9 dimethylaminopropylamide, phosphoric acid): FONCOAT MI-1 (product name, manufactured by Nikko Chemicals Co., Ltd.)
PFPOP-treated titanium (titanium oxide, perfluoropropoxy (perfluoroPPG) -9 dimethylaminopropylamide, phosphoric acid): FONCOAT TI-1: (Product name, manufactured by Nikko Chemicals Co., Ltd.)
PFPOP-treated sericite (serisite, perfluoropropoxy (perfluoroPPG) -9 dimethylaminopropylamide, phosphoric acid): FONCOAT SE-1 (product name, manufactured by Nikko Chemicals Co., Ltd.)
(D) Surfactant Glyceryl monooleate: NIKKOL MGO (Product name, manufactured by Nikko Chemicals Co., Ltd., HLB2.5)
Sorbitan oleate: NIKKOL SO-10V (Product name, manufactured by Nikko Chemicals Co., Ltd., HLB 4.3)
Behenes-5: NIKKOL BB-5 (product name, manufactured by Nikko Chemicals Co., Ltd.) (HLB7.0)
PPG-4 Setes-1: NIKKOL PBC-31 (manufactured by Nikko Chemicals Co., Ltd., HLB 9.5)
Polyglyceryl isostearate-10: NIKKOL DECAGLYN 1-ISV (Product name, manufactured by Nikko Chemicals Co., Ltd., HLB 12.0)
(Other ingredients)
BG (1,3 butylene glycol): 13BG-UK (Product name, manufactured by Daicel Chemical Co., Ltd.)
Phenoxyethanol: Microcare PE (product name, manufactured by So Japan Co., Ltd.)
Talc: Talc EX-15 (product name, manufactured by Yamaguchi Mica Co., Ltd.)
Mica: Mica FA-450 (Product name, manufactured by Yamaguchi Mica Co., Ltd.)
Titanium oxide, iron oxide :: PHOTOLITE LY-S (product name, manufactured by Yamaguchi Mica Co., Ltd.)
Sericite: Sericite FSE (product name, manufactured by Sanshin Mining Co., Ltd.)
Polyperfluoromethylisopropyl ether: Fombulin HC PEPE (product name, manufactured by SOLBAY)
＜製造方法＞
以下の方法により、油中水型乳化組成物を製造した。なお、表１〜表６における各成分の数字は配合量（重量部）を示す。
（１）表１〜表６に示す（Ａ）液体油、（Ｂ）固体油、（Ｄ）界面活性剤およびＢＧを攪拌しながら８０℃まで加熱し、（Ｃ）撥水撥油性紛体（ＦＯＮＣＯＡＴ、実施例）または タルク、マイカ、酸化チタンと酸化鉄との混合紛体、セリサイト、ＨＣ ＰＥＰＥ：ポリパーフルオロメチルイソプロピルエーテル（比較例）を加えて均一に分散させた。
（２）（１）を１００ｒｐｍでプロペラ攪拌しながら、８０℃に加熱した（Ｅ）水を徐々に加えた。
（３）（２）を８０℃に保持したまま、１００ｒｐｍで３０分間プロペラ攪拌を行った。
（４）（３）にフェノキシエタノールを加えて、室温になるまで緩やかに攪拌冷却し、油中水型乳化組成物を調製した。
<Manufacturing method>
A water-in-oil emulsified composition was produced by the following method. The numbers of each component in Tables 1 to 6 indicate the blending amount (part by weight).
(1) Liquid oil, (B) solid oil, (D) surfactant and BG shown in Tables 1 to 6 are heated to 80 ° C. with stirring, and (C) water-repellent oil-repellent powder (FONCOAT). , Example) or talc, mica, a mixed powder of titanium oxide and iron oxide, cericite, HC PEPE: polyperfluoromethylisopropyl ether (comparative example) was added and uniformly dispersed.
(2) Water (E) heated to 80 ° C. was gradually added while stirring (1) with a propeller at 100 rpm.
(3) While maintaining (2) at 80 ° C., the propeller was stirred at 100 rpm for 30 minutes.
(4) Phenoxyethanol was added to (3), and the mixture was gently stirred and cooled until it reached room temperature to prepare a water-in-oil emulsified composition.
＜評価方法＞
水の放出度合い、使用感および安定性を、以下の方法に基づいて評価した。評価結果を表１〜表６に示す。
<Evaluation method>
The degree of water release, usability and stability were evaluated based on the following methods. The evaluation results are shown in Tables 1 to 6.
＜水の放出度合い（水放出性）＞
製剤約１ｇを手の甲に塗り広げたときに製剤中から水が放出されるか否かを目視で評価した。
○：製剤から水が放出される。
×：製剤から水が放出されない。
<Degree of water release (water release property)>
It was visually evaluated whether or not water was released from the preparation when about 1 g of the preparation was spread on the back of the hand.
◯: Water is released from the preparation.
X: No water is released from the preparation.
＜使用感（滑らかさ）＞
製剤約１ｇを手の甲に塗り広げたときの製剤の滑らかさを官能評価により三段階で評価した。
○：滑らかである
△：やや滑らかである
×：滑らかではない
<Usage (smoothness)>
The smoothness of the preparation when about 1 g of the preparation was spread on the back of the hand was evaluated on a three-point scale by sensory evaluation.
○: Smooth △: Slightly smooth ×: Not smooth
＜安定性＞
５０ｍＬ容量のポリエチレン（ＰＥ）製容器に実施例および比較例の組成物約４０ｇを投入して密封後、１ヶ月間室温（２５℃）で静置した後の製剤外観を目視評価した。
○：分離および沈殿のいずれも生じなかった
×：分離または沈殿が生じた
<Stability>
Approximately 40 g of the compositions of Examples and Comparative Examples were placed in a polyethylene (PE) container having a capacity of 50 mL, sealed, and then allowed to stand at room temperature (25 ° C.) for 1 month, and then the appearance of the preparation was visually evaluated.
◯: Neither separation nor precipitation occurred ×: Separation or precipitation occurred
表１、表２に示すように、（Ｃ）撥水撥油性紛体の含有量を大きくすることで、組成物の水放出性（内包性）が向上した。ただし、（Ｃ）撥水撥油性紛体の含有量が過剰になると、組成物の安定性が低下する傾向が認められた。
表面が撥水撥油処理された粉体を用いることで、無機紛体の種類に関わらず、同様の結果が得られた。
As shown in Tables 1 and 2, the water release property (encapsulation property) of the composition was improved by increasing the content of the (C) water-repellent oil-repellent powder. However, when the content of (C) water- and oil-repellent powder was excessive, the stability of the composition tended to decrease.
By using the powder whose surface was treated with water and oil repellency, the same result was obtained regardless of the type of inorganic powder.
（Ｂ）固体油の含有量により、製剤からの水放出性を調整することができた。また、（Ｂ）固体油の含有量が大きくなりすぎると、組成物の安定性が低下する傾向が認められた。
（Ｂ）固体油は、室温での固体の油であれば、高級アルコール、脂肪酸、植物油、鉱物油など種類を問わず、水放出性および安定性の良好な組成物が得られた。
(B) The water release property from the preparation could be adjusted by the content of the solid oil. Further, when the content of (B) solid oil becomes too large, the stability of the composition tends to decrease.
As long as the solid oil is a solid oil at room temperature, a composition having good water release property and stability was obtained regardless of the type such as higher alcohol, fatty acid, vegetable oil and mineral oil.
表４に示すように、種々の界面活性剤を用いて水の放出性を備えた製剤を調製することができた。安定性の観点から、ＨＬＢが１２よりも小さい界面活性剤を用いることが好ましいといえる。
As shown in Table 4, various surfactants could be used to prepare water-releasing formulations. From the viewpoint of stability, it can be said that it is preferable to use a surfactant having an HLB of less than 12.
表５の比較例１〜比較例６に示すように、（Ａ）液体油と（Ｂ）固体油とを併用することなく、一方のみを用いた場合、水放出性を備えた組成物を得ることができなかった。また、（Ａ）液体油と（Ｂ）固体油とを併用したとしても、（Ｃ）撥水撥油性紛体を用いなければ、水を放出する油中水型乳化組成物を得ることができなかった。
As shown in Comparative Examples 1 to 6 in Table 5, when only one of (A) liquid oil and (B) solid oil is used without being used in combination, a composition having water release property is obtained. I couldn't. Further, even if (A) liquid oil and (B) solid oil are used in combination, a water-in-oil emulsified composition that releases water cannot be obtained unless (C) a water-repellent oil-repellent powder is used. It was.
表６に示すように、（Ｃ）撥水撥油性紛体の代わりに、表面が撥水撥油処理されていない無機紛体を用いた場合、水放出性の良好な組成物を得ることができなかった。この結果から、水放出性を示す組成物を得るためには、紛体表面がＰＦＰＯＰ処理された撥水撥油性紛体を用いる必要があるといえる。 As shown in Table 6, when an inorganic powder whose surface is not treated with water-repellent oil-repellent treatment is used instead of the water-repellent oil-repellent powder (C), a composition having good water-releasing property cannot be obtained. It was. From this result, it can be said that it is necessary to use a water-repellent oil-repellent powder whose surface is treated with PFPOP in order to obtain a composition exhibiting water-releasing property.
図１および図２は、実施例２および比較例８の組成物の図面代用顕微鏡写真である。同図に示すように、実施例２の組成物は、粒子径が１０〜３０μｍ程度のマクロエマルジョンであったのに対し、比較例８の組成物は、粒子径が１μｍ以下のエマルジョンであった。本発明の組成物は、油相中に大きな粒径の水相が分散していることで、良好な水放出性を実現したと考えられる。 1 and 2 are drawing-substituting micrographs of the compositions of Example 2 and Comparative Example 8. As shown in the figure, the composition of Example 2 was a macroemulsion having a particle size of about 10 to 30 μm, whereas the composition of Comparative Example 8 was an emulsion having a particle size of 1 μm or less. .. It is considered that the composition of the present invention has achieved good water release property because the aqueous phase having a large particle size is dispersed in the oil phase.
本発明の油中水型乳化組成物は、ウォーター−ドロップクイックブレイク型の化粧料として有用である。 The water-in-oil emulsified composition of the present invention is useful as a water-drop quick break type cosmetic.
Claims (9)
油中水型乳化組成物。 Water-in-oil emulsification containing (A) liquid oil at room temperature, (B) solid oil at room temperature, (C) water-repellent oil-repellent powder, (D) surfactant and (E) water Composition.
前記（Ｂ）固体油の含有量が２．０〜１０重量％であり、
前記（Ｃ）撥水撥油性紛体の含有量が０．１〜１．５重量％である
請求項１に記載の油中水型乳化組成物。 The content of the liquid oil (A) is 1.0 to 15% by weight.
The content of the solid oil (B) is 2.0 to 10% by weight.
The water-in-oil emulsified composition according to claim 1, wherein the content of the water-repellent oil-repellent powder (C) is 0.1 to 1.5% by weight.
請求項１に記載の油中水型乳化組成物。 The water-in-oil emulsified composition according to claim 1, wherein the content of (E) water is 60 to 90% by weight.
請求項１に記載の油中水型乳化組成物。 The water-in-oil emulsified composition according to claim 1, wherein the (C) water- and oil-repellent powder is an inorganic powder surface-treated with a fluorine compound.
請求項４に記載の油中水型乳化組成物。 The water-in-oil emulsified composition according to claim 4, wherein the content of the (C) water-repellent oil-repellent powder is 1/100 to 1/2 of the content of the (B) solid oil.
請求項１に記載の油中水型乳化組成物。 The water-in-oil emulsified composition according to claim 1, wherein the surfactant (D) has an HLB of 2 to 11.
請求項１に記載の油中水型乳化組成物。 The water-in-oil emulsified composition according to claim 1, wherein the aqueous phase dispersed in the oil phase has an average particle size of 1 to 100 μm.
請求項１に記載の油中水型乳化組成物。 (F) The water-in-oil emulsified composition according to claim 1, which does not substantially contain a silicone component.
請求項１〜８のいずれか１項に記載の油中水型乳化組成物。 The water-in-oil emulsified composition according to any one of claims 1 to 8, wherein the aqueous phase is released when applied to the skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019141187A JP2021024785A (en) | 2019-07-31 | 2019-07-31 | Water-in-oil emulsified composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019141187A JP2021024785A (en) | 2019-07-31 | 2019-07-31 | Water-in-oil emulsified composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2021024785A true JP2021024785A (en) | 2021-02-22 |
Family
ID=74663605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019141187A Pending JP2021024785A (en) | 2019-07-31 | 2019-07-31 | Water-in-oil emulsified composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2021024785A (en) |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60184003A (en) * | 1984-03-01 | 1985-09-19 | Lion Corp | W/o-type emulsion cosmetic |
| JPH04279518A (en) * | 1991-03-06 | 1992-10-05 | Kanebo Ltd | Cosmetic |
| JPH04308520A (en) * | 1991-04-04 | 1992-10-30 | Kanebo Ltd | W/o-type make-up cosmetic |
| JPH11246354A (en) * | 1997-12-29 | 1999-09-14 | Kose Corp | Water-in-oil type cosmetic |
| JP2003226634A (en) * | 2001-11-30 | 2003-08-12 | Kose Corp | Water-in-oil emulsified cosmetic |
| JP2005008560A (en) * | 2003-06-19 | 2005-01-13 | Kao Corp | Water-in-oil type emulsified cosmetic |
| JP2008184399A (en) * | 2007-01-29 | 2008-08-14 | Shiseido Co Ltd | Powdery cosmetic |
| JP2012041202A (en) * | 2010-08-12 | 2012-03-01 | Tohoku Univ | Sheet-shaped cerium oxide and petal-shaped cerium oxide powder as aggregate of the sheet-shaped cerium oxide, process for production of the sheet-shaped cerium oxide and the petal-shaped cerium oxide powder, coated sheet-shaped cerium oxide and petal-shaped cerium oxide powder as aggregate of the coated sheet-shaped cerium oxide, and cosmetic |
| JP2013010744A (en) * | 2011-05-30 | 2013-01-17 | Dow Corning Toray Co Ltd | Novel organopolysiloxane elastomer and use of the same |
| JP2013227295A (en) * | 2012-03-26 | 2013-11-07 | Kose Corp | Water-in-oil type solid cosmetic |
| JP2018526386A (en) * | 2015-09-02 | 2018-09-13 | アモーレパシフィック コーポレーション | High internal phase oil-in-water cosmetic composition |
| WO2019004048A1 (en) * | 2017-06-29 | 2019-01-03 | 信越化学工業株式会社 | Water break-type sunscreen cosmetic product |
| JP2019099468A (en) * | 2017-11-29 | 2019-06-24 | 花王株式会社 | Water-in-oil emulsion cosmetic |
-
2019
- 2019-07-31 JP JP2019141187A patent/JP2021024785A/en active Pending
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60184003A (en) * | 1984-03-01 | 1985-09-19 | Lion Corp | W/o-type emulsion cosmetic |
| JPH04279518A (en) * | 1991-03-06 | 1992-10-05 | Kanebo Ltd | Cosmetic |
| JPH04308520A (en) * | 1991-04-04 | 1992-10-30 | Kanebo Ltd | W/o-type make-up cosmetic |
| JPH11246354A (en) * | 1997-12-29 | 1999-09-14 | Kose Corp | Water-in-oil type cosmetic |
| JP2003226634A (en) * | 2001-11-30 | 2003-08-12 | Kose Corp | Water-in-oil emulsified cosmetic |
| JP2005008560A (en) * | 2003-06-19 | 2005-01-13 | Kao Corp | Water-in-oil type emulsified cosmetic |
| JP2008184399A (en) * | 2007-01-29 | 2008-08-14 | Shiseido Co Ltd | Powdery cosmetic |
| JP2012041202A (en) * | 2010-08-12 | 2012-03-01 | Tohoku Univ | Sheet-shaped cerium oxide and petal-shaped cerium oxide powder as aggregate of the sheet-shaped cerium oxide, process for production of the sheet-shaped cerium oxide and the petal-shaped cerium oxide powder, coated sheet-shaped cerium oxide and petal-shaped cerium oxide powder as aggregate of the coated sheet-shaped cerium oxide, and cosmetic |
| JP2013010744A (en) * | 2011-05-30 | 2013-01-17 | Dow Corning Toray Co Ltd | Novel organopolysiloxane elastomer and use of the same |
| JP2013227295A (en) * | 2012-03-26 | 2013-11-07 | Kose Corp | Water-in-oil type solid cosmetic |
| JP2018526386A (en) * | 2015-09-02 | 2018-09-13 | アモーレパシフィック コーポレーション | High internal phase oil-in-water cosmetic composition |
| WO2019004048A1 (en) * | 2017-06-29 | 2019-01-03 | 信越化学工業株式会社 | Water break-type sunscreen cosmetic product |
| JP2019099468A (en) * | 2017-11-29 | 2019-06-24 | 花王株式会社 | Water-in-oil emulsion cosmetic |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4646269B2 (en) | Skin preparation | |
| JP5224740B2 (en) | Hair wax | |
| JP4860067B2 (en) | Solid oil-in-water cosmetics | |
| JP5117591B2 (en) | Water-in-oil emulsified cosmetic | |
| JP5722615B2 (en) | Gel-like composition | |
| JP2004175736A (en) | Composition for cleansing | |
| JP4812241B2 (en) | Emulsifying composition for hair | |
| JP2008297280A (en) | Emulsion cosmetic | |
| JPH09194331A (en) | Oil-in-water-type solid emulsified cosmetic | |
| JP2021024785A (en) | Water-in-oil emulsified composition | |
| JP5547123B2 (en) | Water-in-oil emulsified cosmetic | |
| JP2005255623A (en) | Water-in-oil type foundation | |
| JP2013189429A (en) | Water-in-oil-in-water type emulsified cosmetic | |
| JP2014162790A (en) | Oil-in-water type powder cosmetic | |
| JP2018043941A (en) | Oil-in-water type liquid bathing agent | |
| JP2018100239A (en) | Oil-in-water emulsion composition and skin external preparation | |
| JP2002308962A (en) | Emulsified composition | |
| JP4250545B2 (en) | Water-in-oil lip cosmetic | |
| JPH0794366B2 (en) | Method for producing O / W gel cosmetic | |
| JP6640556B2 (en) | Oil-in-water liquid bath agent and method for producing the same | |
| JP4188777B2 (en) | Emulsified composition | |
| JP6042628B2 (en) | Oil-in-water emulsified cosmetic | |
| JP2011126829A (en) | Emulsified composition for hair | |
| JP5038941B2 (en) | Oil-in-water emulsified cosmetic | |
| JP6753700B2 (en) | Oil-in-water emulsified composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220323 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230120 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20230131 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20230801 |