JP2021011304A - Manufacture method of gas-containing food - Google Patents

Manufacture method of gas-containing food Download PDF

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JP2021011304A
JP2021011304A JP2019127625A JP2019127625A JP2021011304A JP 2021011304 A JP2021011304 A JP 2021011304A JP 2019127625 A JP2019127625 A JP 2019127625A JP 2019127625 A JP2019127625 A JP 2019127625A JP 2021011304 A JP2021011304 A JP 2021011304A
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gas
container
inner container
food
lid
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信也 菅原
Shinya Sugawara
信也 菅原
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Daizo Corp
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Daizo Corp
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Priority to JP2019127625A priority Critical patent/JP2021011304A/en
Priority to CN201980047765.1A priority patent/CN112424088B/en
Priority to EP19837693.1A priority patent/EP3825254A4/en
Priority to US17/260,685 priority patent/US11603257B2/en
Priority to PCT/JP2019/028376 priority patent/WO2020017617A1/en
Publication of JP2021011304A publication Critical patent/JP2021011304A/en
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Abstract

To provide a manufacture method for obtaining a food in which gas is dissolved while performing ultrasonic welding.SOLUTION: A container body 16 containing a gas-permeable inner container 14 in an outer container 13, a lid body 15 having no valve, which is made of the same material as the container body 16 and closes the opening of the container body 16, a food C having a dissolution amount of gas of 0.05 or less, and gas P for dissolving the food are provided. After filling one of the inner container 14 or the outer container 13 and the inner container 14 with food C and filling the other with gas P, the lid body 15 is ultrasonically welded to the container body 16, the outer container 13 and the inner container 14 are sealed, and the gas P is permeated and contained in the food C.SELECTED DRAWING: Figure 5

Description

本発明は、ガス含有食品の製造方法に関し、特に超音波溶着により封をする場合のガス含有食品の製造方法に関する。 The present invention relates to a method for producing a gas-containing food, and particularly to a method for producing a gas-containing food when the food is sealed by ultrasonic welding.

外ボトル内に内ボトルを収容した容器の開口を塞ぐにあたり、蓋体を容器に超音波溶着することは、例えば特許文献1に記載されているように従来から行われている。 In closing the opening of the container containing the inner bottle in the outer bottle, ultrasonic welding of the lid to the container has been conventionally performed as described in, for example, Patent Document 1.

特開2019−006457号公報Japanese Unexamined Patent Publication No. 2019-006457

近年、環境負荷を減らすために、リサイクルしやすい包装容器が求められている。その1つの方法として包装容器を単一素材にすることが考えられるが、特許文献1の吐出容器はバルブを備えているため、シール材を省略することができない。そこで、開封可能な蓋体を同じ材質の容器本体に溶着して密封し、バルブ付きの吐出部材を取り付けることが考えられるが、低温状態にしてガスを飽和溶解させた食品(炭酸飲料等)を容器内に充填した状態で蓋体を超音波溶着しようとすると、超音波振動によって食品内に溶解していたガスが急激に気化して発泡し抜けてしまう。そのため、発泡した食品により溶着部分が冷やされて容器に蓋体を溶着させることが困難となる。また、仮に溶着できたとしても食品中のガス含有量が少なくなってしまうといった問題がある。 In recent years, in order to reduce the environmental load, packaging containers that are easy to recycle have been required. One method is to use a single material for the packaging container, but since the discharge container of Patent Document 1 is provided with a valve, the sealing material cannot be omitted. Therefore, it is conceivable to weld an openable lid to a container body made of the same material and seal it, and attach a discharge member with a valve. However, foods (carbonated beverages, etc.) in which gas is saturated and dissolved in a low temperature state are used. When an attempt is made to ultrasonically weld the lid while the container is filled, the gas dissolved in the food is rapidly vaporized by ultrasonic vibration and foams out. Therefore, the welded portion is cooled by the foamed food, and it becomes difficult to weld the lid to the container. Further, even if welding is possible, there is a problem that the gas content in the food is reduced.

そこで本発明は、超音波溶着しつつも、ガスが溶解した食品が得られる製造方法の提供を目的とする。 Therefore, an object of the present invention is to provide a production method for obtaining a food in which gas is dissolved while ultrasonically welding.

本発明のガス含有食品の製造方法は、外部容器13内に、ガス透過性の内部容器14を収容した容器本体16と、前記容器本体16と同一素材で構成され、容器本体16の開口を閉じる、バルブを有しない蓋体15と、ガスの溶解量が0.05以下である食品Cと、食品溶解用のガスPとを備え、前記内部容器14又は前記外部容器13と前記内部容器14との間のいずれか一方に前記食品Cを充填し、他方に前記ガスPを充填した後、前記蓋体15を前記容器本体16に超音波溶着して前記外部容器13と前記内部容器14とを密閉し、前記ガスPを透過させて前記食品Cに含有させることを特徴としている。 The method for producing a gas-containing food of the present invention comprises a container body 16 containing a gas-permeable inner container 14 in an outer container 13 and the same material as the container body 16, and closes the opening of the container body 16. The inner container 14 or the outer container 13 and the inner container 14 are provided with a lid 15 having no valve, a food C having a gas dissolution amount of 0.05 or less, and a food dissolution gas P. After filling one of the spaces with the food C and filling the other with the gas P, the lid 15 is ultrasonically welded to the container body 16 to form the outer container 13 and the inner container 14. It is characterized in that it is sealed and the gas P is permeated and contained in the food C.

上記製造方法において、前記内部容器14に前記食品Cを充填し、前記外部容器13と前記内部容器14との間に前記ガスPを充填することが好ましい。また、前記内部容器14に前記食品Cを充填した後、前記内部容器14内の気体と前記ガスPとを入れ替えることが好ましい。また、前記ガスPが25℃での水への溶解度が0.05以上の圧縮ガスであることが好ましい。 In the above manufacturing method, it is preferable that the food C is filled in the inner container 14 and the gas P is filled between the outer container 13 and the inner container 14. Further, it is preferable to replace the gas in the inner container 14 with the gas P after filling the inner container 14 with the food C. Further, it is preferable that the gas P is a compressed gas having a solubility in water at 25 ° C. of 0.05 or more.

本発明のガス含有食品の製造方法は、ガスの溶解量が0.05以下である食品を充填するため、蓋体を容器本体に超音波溶着するときに食品からガスが気化することがほとんどなく、確実に溶着することができる。また、ガスは内部容器を透過して食品に溶解するため、ガスが溶解した食品が得られる。容器本体と蓋体が同一素材で構成されているため、食品を吐出した後はリサイクルしやすい。 In the method for producing a gas-containing food of the present invention, since the food in which the dissolved amount of gas is 0.05 or less is filled, the gas is hardly vaporized from the food when the lid is ultrasonically welded to the container body. , Can be reliably welded. Further, since the gas permeates the inner container and dissolves in the food, the food in which the gas is dissolved can be obtained. Since the container body and lid are made of the same material, it is easy to recycle after discharging food.

内部容器に食品を充填し、外部容器と内部容器との間にガスを充填する場合、内部容器内の食品に外部からの熱が伝わりにくく、予め冷却した食品を内部容器内に充填すると、外部容器と内部容器との間のガスが速く溶解しやすい。内部容器内の気体とガスとを入れ替えれば、食品にガスを溶解させやすくなる。外部容器と内部容器との間に充填されるガスが25℃での水への溶解度が0.05以上の圧縮ガスであれば、食品へのガスの溶解量が多く、摂食時に溶解したガスの効果が得られやすい。また、原液を充填した直後に内部容器内に空間(ヘッドスペース)があっても、ガスが内部容器を透過して原液に多く溶解し、内部容器が収縮してヘッドスペースをなくすことができる。そのため蓋体を開封した時の原液の飛び散りを防止することができる。また、ガスの溶解により圧力が大きく低下するため、容器本体を薄くすることができる。 When the inner container is filled with food and gas is filled between the outer container and the inner container, heat from the outside is not easily transferred to the food in the inner container, and when the pre-cooled food is filled in the inner container, the outside The gas between the container and the inner container dissolves quickly and easily. Replacing the gas in the inner container makes it easier to dissolve the gas in the food. If the gas filled between the outer container and the inner container is a compressed gas having a solubility in water at 25 ° C. of 0.05 or more, the amount of gas dissolved in food is large, and the gas dissolved during feeding. The effect of is easy to obtain. Further, even if there is a space (head space) in the inner container immediately after filling the stock solution, the gas permeates the inner container and dissolves in a large amount in the stock solution, and the inner container contracts to eliminate the head space. Therefore, it is possible to prevent the undiluted solution from splashing when the lid is opened. Further, since the pressure is greatly reduced by the dissolution of the gas, the container body can be made thinner.

図1Aは本発明の製造方法で得られたガス含有食品を用いた吐出装置の一実施形態を示す断面図、図1Bは加圧容器の組み立て前の断面図である。FIG. 1A is a cross-sectional view showing an embodiment of a discharge device using the gas-containing food obtained by the production method of the present invention, and FIG. 1B is a cross-sectional view before assembling the pressurized container. 図2Aは本発明に関わる蓋体の溶着工程の一実施形態を示す要部断面図、図2Bは溶着後の断面図である。FIG. 2A is a cross-sectional view of a main part showing an embodiment of a lid welding step according to the present invention, and FIG. 2B is a cross-sectional view after welding. 図3は図1Aの吐出部材の拡大断面図である。FIG. 3 is an enlarged cross-sectional view of the discharge member of FIG. 1A. 本発明の製造方法に用いる加圧剤充填装置の一部断面正面図である。It is a partial cross-sectional front view of the pressurizing agent filling device used in the manufacturing method of this invention. 本発明のガス含有食品の製造方法の一実施形態を示す概略工程図である。It is a schematic process diagram which shows one Embodiment of the manufacturing method of the gas-containing food of this invention.

図1Aに示す吐出装置10は、加圧容器(二重加圧容器)11と、その加圧容器11に装着される吐出部材12と、加圧容器11に充填された原液(食品)Cおよび加圧剤(食品溶解用のガス)Pとからなる。加圧容器11に原液Cと加圧剤Pを充填したものがガス含有食品11aである。ガス含有食品11aと吐出部材12は組み立て前のセット品として、あるいは吐出部材12をガス含有食品11aの上端にいくらかねじ込んだ、しかも未開封の半結合状態で販売される。ガス含有食品11aは吐出部材12と共に販売されるほか、交換用として単独でも販売される。その場合は、吐出部材12は繰り返し使用するので、省資源に資する。吐出部材12も単独で販売されることがある。 The discharge device 10 shown in FIG. 1A includes a pressure container (double pressure container) 11, a discharge member 12 mounted on the pressure container 11, and a stock solution (food) C filled in the pressure container 11. It is composed of a pressurizing agent (gas for dissolving food) P. The gas-containing food 11a is a pressure container 11 filled with the stock solution C and the pressure agent P. The gas-containing food 11a and the discharge member 12 are sold as a set before assembly, or in a semi-bonded state in which the discharge member 12 is somewhat screwed into the upper end of the gas-containing food 11a and is unopened. The gas-containing food 11a is sold together with the discharge member 12, and is also sold alone as a replacement. In that case, since the discharge member 12 is used repeatedly, it contributes to resource saving. The discharge member 12 may also be sold independently.

図1Bに示す加圧容器11は、外部容器13と、その内部に収容されている可撓性を有する内部容器14と、外部容器13と内部容器14を封止するための蓋体(封盤)15とからなる。バルブやポンプは備えていない。また、外部容器13と、内部容器14と、蓋体15は同一素材からなる。従って、加圧容器11は単一素材からなる。外部容器13と内部容器14を組み合わせたものは容器本体16である。内部容器14の内部は原液Cを充填する原液収容室Scであり、外部容器13と内部容器14の隙間の空間は加圧剤Pを充填する加圧剤収容室Spである(図1A参照)。それらは蓋体15によって封止されるが、図1Bの状態では原液Cも加圧剤Pも充填されておらず、蓋体15も溶着されていない。この実施形態では、内部容器14で原液Cと加圧剤Pを分離して収容し、吐出部材12を装着することにより原液Cを吐出させることができるようにしている。 The pressure container 11 shown in FIG. 1B is a lid (sealing panel) for sealing the outer container 13, the flexible inner container 14 housed inside the outer container 13, and the outer container 13 and the inner container 14. ) Consists of 15. It does not have valves or pumps. Further, the outer container 13, the inner container 14, and the lid 15 are made of the same material. Therefore, the pressure vessel 11 is made of a single material. The combination of the outer container 13 and the inner container 14 is the container body 16. The inside of the inner container 14 is a stock solution storage chamber Sc filled with the stock solution C, and the space between the outer container 13 and the inner container 14 is a pressure agent storage chamber Sp filled with the pressurizing agent P (see FIG. 1A). .. They are sealed by the lid 15, but in the state of FIG. 1B, neither the stock solution C nor the pressurizing agent P is filled, and neither the lid 15 is welded. In this embodiment, the undiluted solution C and the pressurizing agent P are separately contained in the inner container 14, and the undiluted solution C can be discharged by attaching the discharge member 12.

図1Bは蓋体15を容器本体16に被せる前の状態で示している。外部容器13は底部13aと、円筒状の胴部13bと、肩部13cと、円筒状の首部13dとからなる。首部13dの外周には雄ねじ13eが形成されている。首部13dは上端で開口しており、首部13dの上端面13fは蓋体15を安定して支持し、溶着できるように略平坦にしている。 FIG. 1B shows the state before the lid 15 is put on the container body 16. The outer container 13 includes a bottom portion 13a, a cylindrical body portion 13b, a shoulder portion 13c, and a cylindrical neck portion 13d. A male screw 13e is formed on the outer circumference of the neck portion 13d. The neck portion 13d is open at the upper end, and the upper end surface 13f of the neck portion 13d stably supports the lid body 15 and is substantially flat so that it can be welded.

内部容器14も外部容器13と同様に、底部14a、胴部14b、肩部14cおよび首部14dからなる。首部14dの上端近辺が口部である。内部容器14の首部14dの外面は外部容器13の首部13dの内面との間にわずかな隙間を有するように嵌合されている。内部容器14の底部14aは外部容器13の底部13aと当接しており、加圧剤Pを充填するときや蓋体15を固着するときなど、内部容器14が下がらないように支持される。 Like the outer container 13, the inner container 14 also includes a bottom portion 14a, a body portion 14b, a shoulder portion 14c, and a neck portion 14d. The vicinity of the upper end of the neck portion 14d is the mouth portion. The outer surface of the neck portion 14d of the inner container 14 is fitted so as to have a slight gap with the inner surface of the neck portion 13d of the outer container 13. The bottom portion 14a of the inner container 14 is in contact with the bottom portion 13a of the outer container 13, and is supported so that the inner container 14 does not lower when the pressurizing agent P is filled or when the lid 15 is fixed.

図2Aは容器本体16に蓋体15を被せた状態である。蓋体15の天面17cには超音波溶着用のホーンHが当接されている。蓋体15の溶着はまだ行われていない。このとき原液収容室Scに原液Cは充填されているが、加圧剤収容室Spに加圧剤Pは充填されていない。外部容器13の首部13dの上端面13fには、超音波溶着のときに蓋体15との当接圧を高くして溶解しやすくし、蓋体15と一体にするための溶着部(図2BのY2)をつくる環状突起13gが形成されている。環状突起13gは断面略三角形で、とくに二等辺三角形ないし正三角形である。 FIG. 2A shows a state in which the container body 16 is covered with the lid body 15. A horn H worn by ultrasonic welding is in contact with the top surface 17c of the lid 15. Welding of the lid 15 has not been performed yet. At this time, the stock solution C is filled in the stock solution storage chamber Sc, but the pressure agent P is not filled in the pressure agent storage chamber Sp. On the upper end surface 13f of the neck portion 13d of the outer container 13, the contact pressure with the lid body 15 is increased during ultrasonic welding to facilitate dissolution, and a welding portion for integrating with the lid body 15 (FIG. 2B). 13 g of annular protrusions forming Y2) of the above are formed. The annular protrusion 13g has a substantially triangular cross section, and is particularly an isosceles triangle or an equilateral triangle.

この実施形態では環状突起13gは首部13dの厚みの範囲の略中央に設けている。蓋体15側に環状突起を設け、首部13dの上端面13fは平坦とすることもできる。上端面13fの内部側には傾斜部13hが複数個設けられており、超音波溶着のときに溶けた樹脂が冷やされてできた樹脂片(溶着くず)がはみ出ないように収容するための空間としている。 In this embodiment, the annular protrusion 13g is provided substantially in the center of the thickness range of the neck portion 13d. An annular protrusion may be provided on the lid 15 side, and the upper end surface 13f of the neck portion 13d may be flat. A plurality of inclined portions 13h are provided on the inner side of the upper end surface 13f, and a space for accommodating resin pieces (welding debris) formed by cooling the resin melted during ultrasonic welding so as not to protrude. It is said.

図2Aに示すように、内部容器14の首部14dの上部は外部容器13の上端面13fより突出しており、その突出している部位に外部容器13の上端面13fと係合するフランジ14fが形成されている。フランジ14fの厚さ(半径方向の寸法)は、外部容器13の首部13dの厚さの1/3〜1/2程度である。そのため、フランジ14fを外部容器13の首部13dの上端面13fに係止させたとき、外部容器13の首部13dの上端面13fは外側の部分が覆われずに残る。前記外部容器13の上端の環状突起13gは、その外側の部分に設けられている。内部容器14の首部14dの上端面14eにも、超音波溶着のときに蓋体15との当接圧を高くして蓋体15との溶着部(図2BのY1)をつくるための環状突起14gが形成されている。この実施形態ではこの環状突起14gも断面略三角形、とくに二等辺三角形ないし正三角形としている。 As shown in FIG. 2A, the upper portion of the neck portion 14d of the inner container 14 protrudes from the upper end surface 13f of the outer container 13, and a flange 14f that engages with the upper end surface 13f of the outer container 13 is formed at the protruding portion. ing. The thickness (radial dimension) of the flange 14f is about 1/3 to 1/2 of the thickness of the neck portion 13d of the outer container 13. Therefore, when the flange 14f is locked to the upper end surface 13f of the neck portion 13d of the outer container 13, the upper end surface 13f of the neck portion 13d of the outer container 13 remains without covering the outer portion. The annular protrusion 13g at the upper end of the outer container 13 is provided on the outer portion thereof. An annular protrusion on the upper end surface 14e of the neck portion 14d of the inner container 14 for forming a welded portion (Y1 in FIG. 2B) with the lid body 15 by increasing the contact pressure with the lid body 15 at the time of ultrasonic welding. 14 g is formed. In this embodiment, the annular protrusion 14g is also a substantially triangular cross section, particularly an isosceles triangle or an equilateral triangle.

内部容器14のフランジ14fの下面には、半径方向に延びる加圧剤充填用の横溝14hが等間隔で4カ所に形成されている。さらに内部容器14の首部14dの外周面には、その横溝14hと連通する縦溝14iが形成されている。縦溝14iは横溝14hから肩部14cの上端まで延びており、それにより加圧剤Pを加圧剤収容室Sp内に充填しやすい。 On the lower surface of the flange 14f of the inner container 14, lateral grooves 14h for filling the pressurizing agent extending in the radial direction are formed at four positions at equal intervals. Further, a vertical groove 14i communicating with the lateral groove 14h is formed on the outer peripheral surface of the neck portion 14d of the inner container 14. The vertical groove 14i extends from the lateral groove 14h to the upper end of the shoulder portion 14c, whereby the pressurizing agent P can be easily filled in the pressurizing agent accommodating chamber Sp.

外部容器13および内部容器14はいずれも合成樹脂製、とくにポリエチレンテレフタレート、ポリエチレンナフタレート、ポリエチレン、ポリプロピレンなどの熱可塑性樹脂製である。これらは、たとえば外部容器用のプリフォームの中に内部容器用のプリフォームを入れ、首部13d、14dの下端より下側を同時にブロー成形することにより製造することができる。とくに所定形状のプリフォームをインジェクション成形し、ついでブロー成形するインジェクション・ブロー成形法が好ましい。
内部容器14はブロー成形により胴部14bの肉厚を0.05〜0.3mmと薄くすることで加圧剤Pが透過しやすくなる。一方、外部容器13はブロー成形により胴部13bの肉厚を0.35mm以上と厚くすることで充填直後の圧力(加圧剤Pが原液Cに溶解する前の状態)でも大きく変形しない強度が得られる。このように外部容器13の胴部13bの肉厚を、内部容器14の胴部14bの肉厚よりも厚くすることが好ましい。
Both the outer container 13 and the inner container 14 are made of a synthetic resin, particularly a thermoplastic resin such as polyethylene terephthalate, polyethylene naphthalate, polyethylene, and polypropylene. These can be manufactured, for example, by putting the preform for the inner container in the preform for the outer container and blow molding the lower side of the neck portions 13d and 14d at the same time. In particular, an injection blow molding method in which a preform having a predetermined shape is injection molded and then blow molded is preferable.
The inner container 14 is blow-molded to reduce the wall thickness of the body portion 14b to 0.05 to 0.3 mm so that the pressurizing agent P can easily permeate. On the other hand, the outer container 13 is blow-molded to increase the wall thickness of the body 13b to 0.35 mm or more so that the outer container 13 has a strength that does not significantly deform even under the pressure immediately after filling (the state before the pressurizing agent P is dissolved in the stock solution C). can get. As described above, it is preferable that the wall thickness of the body portion 13b of the outer container 13 is thicker than the wall thickness of the body portion 14b of the inner container 14.

前記蓋体15は、内部容器14の首部14d内に挿入される有底筒状の封止部15aと、その上端に連続する環状のフランジ15bとからなる。封止部15aの上部は内部容器14の首部14dの内面と隙間をもって嵌合する内筒部15a1であり、下部は吐出部材12のバルブ21を着脱自在に収容し、シール材(図1の符号28)を介して嵌合するバルブ収容部(嵌合筒部)15a2である。バルブ収容部15a2は内筒部15a1より小径である。 The lid 15 is composed of a bottomed tubular sealing portion 15a inserted into the neck portion 14d of the inner container 14 and an annular flange 15b continuous with the upper end thereof. The upper portion of the sealing portion 15a is an inner cylinder portion 15a1 that fits with the inner surface of the neck portion 14d of the inner container 14 with a gap, and the lower portion accommodates the valve 21 of the discharge member 12 in a detachable manner and is a sealing material (reference numeral in FIG. 1). It is a valve accommodating portion (fitting cylinder portion) 15a2 that is fitted via 28). The valve accommodating portion 15a2 has a smaller diameter than the inner cylinder portion 15a1.

蓋体15のフランジ15bは、封止部15aの上端から半径方向外向きに拡がる平板部17と、その平板部17の外縁から下向きに延びる外筒部17aとからなる。平板部17の下面17bは内部容器14の首部14dの上端面14e、とくに環状突起14gと当接して溶着部(図2Bの符号Y1)を形成しシールする部位で、外筒部17aの下面17a1は外部容器13の首部13dの上端面13f、とくに環状突起13gと当接して溶着部(図2Bの符号Y2)を形成しシールする部位である。内部容器14の溶着部Y1は、原液収容室Scと加圧剤収容室Spの間をシールする。外部容器13の溶着部Y2は、加圧剤収容部Spと外部の間をシールする。平板部17の天面17c(フランジ15bの天面)は超音波溶着機の超音波振動を発振するホーンHとの当接面である。ホーンHは円柱状で、下面H1は平坦である。この下面H1の直径Dは、環状突起13gの直径と等しい。 The flange 15b of the lid 15 includes a flat plate portion 17 extending outward in the radial direction from the upper end of the sealing portion 15a, and an outer cylinder portion 17a extending downward from the outer edge of the flat plate portion 17. The lower surface 17b of the flat plate portion 17 is a portion that abuts on the upper end surface 14e of the neck portion 14d of the inner container 14, particularly the annular protrusion 14g, to form a welded portion (reference numeral Y1 in FIG. 2B) and seal the lower surface 17a1 of the outer cylinder portion 17a. Is a portion that abuts on the upper end surface 13f of the neck portion 13d of the outer container 13, particularly the annular protrusion 13g, to form a welded portion (reference numeral Y2 in FIG. 2B) and seal it. The welded portion Y1 of the inner container 14 seals between the stock solution accommodating chamber Sc and the pressurizing agent accommodating chamber Sp. The welded portion Y2 of the outer container 13 seals between the pressurizing agent accommodating portion Sp and the outside. The top surface 17c (top surface of the flange 15b) of the flat plate portion 17 is a contact surface with the horn H that oscillates the ultrasonic vibration of the ultrasonic welding machine. The horn H is cylindrical and the lower surface H1 is flat. The diameter D of the lower surface H1 is equal to the diameter of the annular protrusion 13g.

蓋体15の超音波溶着は、内部容器14内の原液収容室Scに原液Cを充填し、容器本体16の開口に蓋体15を被せた後、溶着用のホーンHを組み込んだ加圧剤充填装置(図4の符号30参照)によって行うことができる。超音波溶着は、図2Aの外部容器13と内部容器14の間の加圧剤収容室Spに加圧剤Pをアンダーカップ充填した後に行う。 For ultrasonic welding of the lid body 15, the stock solution C is filled in the stock solution storage chamber Sc in the inner container 14, the opening of the container body 16 is covered with the lid body 15, and then a pressurizing agent incorporating a horn H for welding. This can be done by a filling device (see reference numeral 30 in FIG. 4). Ultrasonic welding is performed after the pressure agent P is undercup-filled in the pressure agent storage chamber Sp between the outer container 13 and the inner container 14 in FIG. 2A.

溶着した後は、図2Bに示すように、外筒部17aの下面17a1が外部容器13の上端面13fと溶着され、平板部17の下面17bが内部容器14の上端面14eと溶着され、加圧剤Pが内部容器14を透過し、原液Cに加圧剤Pが溶け込むことによりガス含有食品11aとなる。原液Cに加圧剤Pを必要量溶け込ませるには、例えば5℃の雰囲気中において(冷蔵庫、倉庫、輸送コンテナなど)、3時間以上保存(冷蔵)しておけばよい。ただ、必ずしも冷蔵する必要はない。そして前述のように、溶融した樹脂が両者の隙間から外部にはみ出すことがない。また、2つの溶着部Y1、Y2は連続的に充分に溶着形成されるので、長期間にわたり加圧剤Pが加圧剤収容室Spから漏れ出すことがなく、また原液Cが原液収容室Scから漏れ出すことがない。溶着時に内側へはみ出した樹脂は、傾斜部(傾斜溝)13hに蓄えられ、加圧剤収容室Spに流れ込むことはない。 After welding, as shown in FIG. 2B, the lower surface 17a1 of the outer cylinder portion 17a is welded to the upper end surface 13f of the outer container 13, and the lower surface 17b of the flat plate portion 17 is welded to the upper end surface 14e of the inner container 14. The pressure agent P permeates the inner container 14, and the pressure agent P is dissolved in the stock solution C to form a gas-containing food 11a. In order to dissolve the required amount of the pressurizing agent P in the stock solution C, for example, it may be stored (refrigerated) for 3 hours or more in an atmosphere of 5 ° C. (refrigerator, warehouse, transportation container, etc.). However, it does not necessarily have to be refrigerated. Then, as described above, the molten resin does not protrude to the outside through the gap between the two. Further, since the two welded portions Y1 and Y2 are continuously and sufficiently welded, the pressurizing agent P does not leak from the pressurizing agent accommodating chamber Sp for a long period of time, and the undiluted solution C is used as the undiluted solution accommodating chamber Sc. Does not leak from. The resin that protrudes inward during welding is stored in the inclined portion (inclined groove) 13h and does not flow into the pressurizing agent accommodating chamber Sp.

なお、前記封止部15aの底部、すなわちバルブ収容部15a2の底部15cには、周囲に比して厚肉にされた受圧部15d1を備えた被開封部15dが設けられている。被開封部15dの周囲は、一部(連続部)15eを除き、環状溝などの弱め線15fで囲まれている。前記受圧部15d1は被開封部15dの上面全体に設けられ、弱め線15fは受圧部15d1の周囲を囲むように、底部15cの上面に形成されている。弱め線15fはたとえばV溝からなる。被開封部15dの連続部15eには、補強部(補強リブ)15gが半径方向外向きに延びるように設けられている。 The bottom portion of the sealing portion 15a, that is, the bottom portion 15c of the valve accommodating portion 15a2 is provided with an opened portion 15d provided with a pressure receiving portion 15d1 which is thicker than the surroundings. The circumference of the opened portion 15d is surrounded by a weakening line 15f such as an annular groove, except for a part (continuous portion) 15e. The pressure receiving portion 15d1 is provided on the entire upper surface of the opened portion 15d, and the weakening line 15f is formed on the upper surface of the bottom portion 15c so as to surround the circumference of the pressure receiving portion 15d1. The weakening line 15f is composed of, for example, a V groove. The continuous portion 15e of the opened portion 15d is provided with a reinforcing portion (reinforcing rib) 15 g extending outward in the radial direction.

蓋体15の材料は外部容器13や内部容器14との熱接合性が高い熱可塑性樹脂が用いられ、外部容器13や内部容器14と同じ材料を用いる。図2Bに示すように、蓋体15で原液収容室Scと加圧剤収容室Spを封止すると共に、内部容器14および外部容器13の両方に固着することにより、内容物(原液C、加圧剤P)を長期間安全に、漏れないように保管しておくことができる。原液を吐出した後の加圧容器は単一素材であるためリサイクルしやすい。 As the material of the lid 15, a thermoplastic resin having high thermal bondability with the outer container 13 and the inner container 14 is used, and the same material as the outer container 13 and the inner container 14 is used. As shown in FIG. 2B, the contents (stock solution C, addition) are formed by sealing the stock solution storage chamber Sc and the pressurizing agent storage chamber Sp with the lid 15 and fixing them to both the inner container 14 and the outer container 13. The pressure agent P) can be safely stored for a long period of time so as not to leak. Since the pressurized container after discharging the undiluted solution is a single material, it is easy to recycle.

内部容器14内の気体(特に後述するヘッドスペースHsの気体)Gを別の気体に置換する場合、この置換気体Rとしては原液Cと以下の関係が成り立つものを選択する。25℃、1気圧における原液1mlに対する溶解度が空気よりも高いもの、たとえば、溶解性圧縮ガス(炭酸ガス、亜酸化窒素)または溶解性圧縮ガスと低溶解性ガス(圧縮空気、酸素、窒素、水素)の混合ガスがあげられ、0.02ml以上となるもの、特に0.05ml以上となるものが好ましい。溶解度が高ければ、内部容器14内の気体Gである置換気体Rが速く原液Cに溶解して気相部がなくなりやすく、ガス含有食品11aの圧力を短時間で安定させることができる。 When the gas (particularly the gas of headspace Hs described later) G in the inner container 14 is replaced with another gas, a gas having the following relationship with the stock solution C is selected as the replacement gas R. Soluble compressed gas (carbon dioxide, nitrogen phosphite) or soluble compressed gas and low soluble gas (compressed air, oxygen, nitrogen, hydrogen) having higher solubility in 1 ml of undiluted solution at 25 ° C. and 1 atm. ), Which is 0.02 ml or more, and more preferably 0.05 ml or more. If the solubility is high, the substitution gas R, which is the gas G in the inner container 14, is rapidly dissolved in the stock solution C, and the gas phase portion is likely to disappear, so that the pressure of the gas-containing food 11a can be stabilized in a short time.

原液Cとしては、清涼飲料、アルコール飲料、デザート、調味料、栄養補助食品、ホィップクリームなどの液状、ゼリー状、ゲル状の食品などがあげられる。但し、これらの用途に限られるわけではない。原液Cに予め空気やガスが溶解されていてもよい。ただしガスの溶解量は0.05以下とする。ガスの溶解量が0.05を超えると、超音波溶着の際、ガスが大量に抜け出て超音波溶着に支障をきたす。なお、ガスの溶解量とは、原液1mlあたりに溶解しているガスの体積(ml)である。 Examples of the undiluted solution C include soft drinks, alcoholic beverages, desserts, seasonings, dietary supplements, liquid foods such as whip cream, jelly-like foods, and gel-like foods. However, it is not limited to these uses. Air or gas may be dissolved in the stock solution C in advance. However, the amount of gas dissolved shall be 0.05 or less. If the amount of dissolved gas exceeds 0.05, a large amount of gas escapes during ultrasonic welding, which hinders ultrasonic welding. The dissolved amount of gas is the volume (ml) of the gas dissolved in 1 ml of the stock solution.

原液Cは被開封部15dの内面側と接触させるのが好ましい。それにより蓋体15と容器本体16との溶着時に被開封部15dが原液Cで冷やされ、被開封部15dが熱で溶ける問題を解消できる。 The undiluted solution C is preferably brought into contact with the inner surface side of the opened portion 15d. As a result, the problem that the opened portion 15d is cooled by the undiluted solution C when the lid body 15 and the container body 16 are welded and the opened portion 15d is melted by heat can be solved.

加圧剤Pとしては炭酸ガス(0.76)、亜酸化窒素(0.059)などの溶解性圧縮ガスや、溶解性圧縮ガスと低溶解性ガス(空気(0.017)、酸素(0.028)、窒素(0.014)、水素(0.018))の混合ガスであり、内部容器14内の気体G、特に空気よりも溶解度が高いものを用いることが好ましい。なお、カッコ内は25℃での水への溶解度を示す。具体的には、25℃、1気圧における原液1mlに対する溶解度が0.02ml以上、好ましくは0.05ml以上となるものを用いる。また、加圧剤Pは飽和溶解状態での圧力が0.2〜0.6MPa(25℃、ゲージ圧)、好ましくは炭酸飲料と同程度の圧力0.3〜0.5MPa(25℃、ゲージ圧)となるように充填する。 As the pressurizing agent P, a soluble compressed gas such as carbon dioxide gas (0.76) and nitrous oxide (0.059), and a soluble compressed gas and a low soluble gas (air (0.017), oxygen (0) It is a mixed gas of .028), nitrogen (0.014), and hydrogen (0.018)), and it is preferable to use the gas G in the inner container 14, particularly one having a higher solubility than air. The numbers in parentheses indicate the solubility in water at 25 ° C. Specifically, those having a solubility in 1 ml of the undiluted solution at 25 ° C. and 1 atm of 0.02 ml or more, preferably 0.05 ml or more are used. The pressure of the pressurizing agent P in a saturated dissolved state is 0.2 to 0.6 MPa (25 ° C., gauge pressure), preferably 0.3 to 0.5 MPa (25 ° C., gauge pressure) similar to that of a carbonated drink. It is filled so that it becomes pressure).

外部容器13の容量は30〜500mlであることが好ましい。内部容器(原液収容室Sc)14の容量は20〜300ml程度が好ましい。加圧剤収容室Spの容量は10〜200ml程度が好ましい。 The capacity of the outer container 13 is preferably 30 to 500 ml. The capacity of the inner container (stock solution storage chamber Sc) 14 is preferably about 20 to 300 ml. The capacity of the pressurizing agent storage chamber Sp is preferably about 10 to 200 ml.

上記のように、加圧容器11を用いたガス含有食品11aは部品数が少なく、バルブを備えていないので、安価に製造することができ、加圧容器11を単一素材にすることができリサイクルしやすい。また、消費者が持ち運んだり、流通業者が配送したりするときに、万一、外部容器13にひびが入っても、加圧剤Pが漏れるだけで内部容器14内の原液Cは漏れないため、安全である。また、消費者が家庭の冷蔵庫で冷やしてから持ち運ぶ際には、外部容器13と内部容器14との間にある空間が保冷剤の役割をして外気温が食品Cに伝わりにくいため、長く冷えた状態で摂取することができる。 As described above, the gas-containing food 11a using the pressurized container 11 has a small number of parts and does not have a valve, so that it can be manufactured at low cost and the pressurized container 11 can be made of a single material. Easy to recycle. Further, even if the outer container 13 is cracked when the consumer carries it or the distributor delivers it, the pressurizing agent P only leaks and the undiluted solution C in the inner container 14 does not leak. , Safe. In addition, when a consumer carries it after cooling it in a refrigerator at home, the space between the outer container 13 and the inner container 14 acts as an ice pack and the outside air temperature is not easily transmitted to the food C, so that it is cooled for a long time. It can be taken in a free state.

つぎに図3を参照して、図1Aの吐出部材12を説明する。前記吐出部材12は、外部容器13の首部13dの雄ねじ13eと螺合するキャップ(装着部)20と、そのキャップ20によって保持されるバルブ21と、バルブ21のステム22に装着される操作ボタン(操作部、アクチュエータ)23とからなる。キャップ20は有底筒状で、内周面に雌ねじが形成されている。そして上底20aの下側に、バルブ21のハウジング24の上部を保持する筒状のバルブ保持部18aを備えたバルブホルダ18が取り付けられている。 Next, the discharge member 12 of FIG. 1A will be described with reference to FIG. The discharge member 12 includes a cap (mounting portion) 20 screwed with the male screw 13e of the neck portion 13d of the outer container 13, a valve 21 held by the cap 20, and an operation button (mounted on the stem 22 of the valve 21). It is composed of an operation unit and an actuator) 23. The cap 20 has a bottomed tubular shape, and a female screw is formed on the inner peripheral surface. A valve holder 18 provided with a tubular valve holding portion 18a for holding the upper portion of the housing 24 of the valve 21 is attached to the lower side of the upper bottom 20a.

バルブ21は、有底筒状のハウジング24と、その内部に上下移動自在に収容される前述のステム22と、そのステム22を上向きに付勢するバネ25と、ハウジング24の上端とバルブホルダ18のラバー押さえ18bの間に介在されるステムラバー26とからなる公知の基本構造を有する。さらにこの実施形態では、ハウジング24の下端に下向きに突出する略円柱状の開封部27が設けられている。開封部27は蓋体15の下部に設けられる被開封部15d(図2B参照)を破断して開封する部分である。ハウジング24の下部外周にOリングなどのシール部材28が装着されている。 The valve 21 includes a bottomed tubular housing 24, the above-mentioned stem 22 movably housed inside the housing 24, a spring 25 for urging the stem 22 upward, an upper end of the housing 24, and a valve holder 18. It has a known basic structure including a stem rubber 26 interposed between the rubber retainers 18b. Further, in this embodiment, a substantially columnar opening portion 27 projecting downward is provided at the lower end of the housing 24. The opening portion 27 is a portion for breaking and opening the opened portion 15d (see FIG. 2B) provided at the lower part of the lid body 15. A sealing member 28 such as an O-ring is attached to the lower outer periphery of the housing 24.

シール部材28は、開封時および開封後に蓋体15のバルブ収容部15a2の内周面とハウジング24の間をシールするものである。ハウジング24の内部と内部容器14内の原液収容室Scとを連通する通路は、ハウジング24を上下に貫通する縦孔24aとしている。 The sealing member 28 seals between the inner peripheral surface of the valve accommodating portion 15a2 of the lid 15 and the housing 24 at the time of opening and after opening. The passage connecting the inside of the housing 24 and the stock solution accommodating chamber Sc in the inner container 14 is a vertical hole 24a penetrating the housing 24 up and down.

開封部27の底面27aの高さ方向の位置は、キャップ20を外部容器13の雄ねじに1〜2回程度螺合させたときに受圧部15d1(図2B参照)と当接する位置である。したがって出荷時および流通時にはキャップ20を緩く螺合させて被開封部15dを破断せず、シール状態のまま吐出部材12と加圧容器11とを仮結合させておくことができる。そのため、購入した消費者はキャップ20を数回回してねじ込むだけで容易に開封することができる。 The position of the bottom surface 27a of the opening portion 27 in the height direction is a position where the cap 20 comes into contact with the pressure receiving portion 15d1 (see FIG. 2B) when the cap 20 is screwed into the male screw of the outer container 13 about once or twice. Therefore, at the time of shipment and distribution, the cap 20 can be loosely screwed so that the opened portion 15d is not broken, and the discharge member 12 and the pressure container 11 can be temporarily connected in the sealed state. Therefore, the purchased consumer can easily open the cap 20 by simply turning the cap 20 several times and screwing it in.

使用者が購入した吐出装置10を使用する場合、まずキャップ20を外部容器13の雄ねじ13eにねじ込む。それによりキャップ20全体およびバルブ21が下降し、開封部27の底面27aが被開封部15dを押し下げる。それにより被開封部15dは弱め線15fで破断され、バルブ収容部15a2の底部15cを突き破り、ハウジング24内と原液収容室Scとを連通する。その後は操作ボタン23を押し下げることにより、加圧剤Pの圧力によって原液Cを吐出することができる。 When using the discharge device 10 purchased by the user, first, the cap 20 is screwed into the male screw 13e of the outer container 13. As a result, the entire cap 20 and the valve 21 are lowered, and the bottom surface 27a of the opening portion 27 pushes down the opened portion 15d. As a result, the opened portion 15d is broken at the weakening line 15f, penetrates the bottom portion 15c of the valve accommodating portion 15a2, and communicates the inside of the housing 24 with the undiluted solution accommodating chamber Sc. After that, by pressing the operation button 23, the undiluted solution C can be discharged by the pressure of the pressurizing agent P.

原液Cがなくなると、キャップ20を逆に回してガス含有食品11aから吐出部材12を外す。原液Cが空になった加圧容器11は単一素材で構成されているためリサイクルしやすい。また、内部容器13は薄肉であるため、原液Cがなくなったことで加圧剤Pが透過しやすくなり、加圧剤Pは開封された被開封部15dから徐々に外部に放出される。さらに、吐出部材12は原液Cと接触するバルブ21や操作ボタン23を交換することで衛生的に繰り返し使用することができる。 When the undiluted solution C runs out, the cap 20 is turned in the reverse direction to remove the discharge member 12 from the gas-containing food 11a. Since the pressurized container 11 in which the undiluted solution C is emptied is made of a single material, it is easy to recycle. Further, since the inner container 13 is thin, the pressurizing agent P easily permeates because the stock solution C is exhausted, and the pressurizing agent P is gradually discharged to the outside from the opened portion 15d to be opened. Further, the discharge member 12 can be used hygienically and repeatedly by replacing the valve 21 and the operation button 23 that come into contact with the stock solution C.

つぎに図4を参照して前述の加圧剤Pの充填と溶着に用いられる加圧剤充填装置の一例を説明する。図4の加圧剤充填装置30は、ベース31と、そのベース31に設けられる昇降台32と、その昇降台32の上方に配置される筒状の充填具33と、その充填具33の上部開口を閉じ、充填具33内に昇降自在に設けられる超音波溶着用のホーンHとからなる。充填具33はベース31から立ち上がる2本の支柱35によって高さ調節自在に支持されている。充填具33の下端にはシール材36が設けられ、外部容器13の肩部13cに気密に当接する。ホーンHは流体シリンダまたはモータなどの駆動源を備えた昇降機構を介して超音波発振器に取り付けられている。昇降台32についても昇降装置37によって高さ調整自在に支持されている。 Next, an example of the pressurizing agent filling device used for filling and welding the pressurizing agent P described above will be described with reference to FIG. The pressurizing agent filling device 30 of FIG. 4 has a base 31, an elevating table 32 provided on the base 31, a tubular filler 33 arranged above the elevating table 32, and an upper portion of the filler 33. It is composed of a horn H for ultrasonic welding, which is provided in the filler 33 so as to be able to move up and down with the opening closed. The filler 33 is height-adjustably supported by two columns 35 rising from the base 31. A sealing material 36 is provided at the lower end of the filler 33 and airtightly contacts the shoulder portion 13c of the outer container 13. The horn H is attached to the ultrasonic oscillator via an elevating mechanism including a drive source such as a fluid cylinder or a motor. The elevating table 32 is also supported by the elevating device 37 so that the height can be adjusted.

ホーンHは、前述のように充填具33内をシールしながら上下に摺動できるように中部Hmが充填具33の内径に合わせられている。また、ホーンHは超音波発振器から振動エネルギーを下側に向けて増幅できるように、上部Huから中部Hmにかけて縮径し、さらに中部Hmから下部Hbにかけて縮径している。従って、下端近辺38が最も小径とされている。 As described above, the horn H has a central portion Hm adjusted to the inner diameter of the filler 33 so that it can slide up and down while sealing the inside of the filler 33. Further, the horn H is reduced in diameter from the upper Hu to the middle Hm and further reduced in diameter from the middle Hm to the lower Hb so that the vibration energy can be amplified downward from the ultrasonic oscillator. Therefore, the diameter near the lower end 38 is the smallest.

図5に示すガス含有食品11aの製造方法は、原液充填工程S1と、内部容器14内の気体Gを置換気体Rにする置換工程S2と、蓋体15を装着して置換気体Rを閉じ込める蓋体装着工程S3と、加圧剤充填・蓋体溶着工程S4と、内部容器収縮工程S5を備える。ただし、置換工程S2は必ずしも行う必要はない。この製造方法では、始めに外部容器13に内部容器14を装着した容器本体16を準備しておく。二重の容器本体16は二重ブロー成形などによって製造することができる。そして内部容器14内に、ガスを意図的に溶解させていない原液(ガス未溶解の食品)Cを充填する。原液Cは予め減圧して飽和溶解している空気を脱気して溶解量を減らしてもよい。また、原液Cは予め5℃以下に冷やしておくことが好ましい。この原液充填工程S1のとき、内部容器14の上部に原液Cを充填しない空所(ヘッドスペース)Hsを残しておく。 The method for producing the gas-containing food 11a shown in FIG. 5 includes a stock solution filling step S1, a replacement step S2 for converting the gas G in the inner container 14 into a replacement gas R, and a lid for which the lid 15 is attached to confine the replacement gas R. The body mounting step S3, the pressurizing agent filling / lid welding step S4, and the internal container shrinking step S5 are provided. However, the replacement step S2 does not necessarily have to be performed. In this manufacturing method, first, a container body 16 in which the inner container 14 is mounted on the outer container 13 is prepared. The double container body 16 can be manufactured by double blow molding or the like. Then, the inner container 14 is filled with the undiluted solution (food in which gas is not dissolved) C in which the gas is not intentionally dissolved. The stock solution C may be depressurized in advance to degas saturated and dissolved air to reduce the amount of dissolution. Further, the stock solution C is preferably cooled to 5 ° C. or lower in advance. At the time of this stock solution filling step S1, an empty space (head space) Hs that is not filled with the stock solution C is left in the upper part of the inner container 14.

次の置換工程S2では、原液収容室Scへのガスの出入りが可能な状態で蓋体15を保持し、内部容器14の開口と蓋体15との隙間から原液Cへの溶解度の高い置換気体Rを充填し、内部容器14内のヘッドスペースHsの空気を外部に排出して、内部容器14内の気体Gを置換気体Rにする(置換工程)。とくに、原液Cに溶解させたい気体に入れ変えることが好ましい。 In the next replacement step S2, the lid 15 is held in a state where gas can enter and exit the stock solution storage chamber Sc, and the replacement gas having high solubility in the stock solution C through the gap between the opening of the inner container 14 and the lid 15. R is filled, the air in the head space Hs in the inner container 14 is discharged to the outside, and the gas G in the inner container 14 is changed to the replacement gas R (replacement step). In particular, it is preferable to replace it with the gas to be dissolved in the stock solution C.

ついで蓋体装着工程S3において蓋体15を容器本体16の開口に被せ、置換した気体をヘッドスペースHs内に閉じ込める。密度(分子量)が空気よりも大きい気体を用いることでヘッドスペースHs内に閉じ込めやすい。 Then, in the lid mounting step S3, the lid 15 is placed over the opening of the container body 16 and the replaced gas is confined in the head space Hs. By using a gas having a density (molecular weight) higher than that of air, it is easy to confine it in the headspace Hs.

蓋体装着工程S3についで、内部容器14と外部容器13との間の加圧剤収容室Spに加圧剤Pを充填する加圧剤充填・蓋体15を内部容器14の開口および外部容器13の開口に溶着固定する蓋体溶着工程S4を行う。この工程では蓋体15と外部容器13の隙間を通して加圧剤収容室Spに加圧剤Pを充填する(アンダーカップ充填)。その後、蓋体15を外部容器13と内部容器14に溶着して密封する。この工程では、たとえば図4の加圧剤充填装置30などを使用することができ、図2Aの溶着方法を採用することができる。それにより溶着くずが外部に出にくく、蓋体15と外部容器13の密着性が高くなり、漏れが少なく、外観に優れたガス含有食品11aを得ることができる。 Following the lid mounting step S3, the pressurizing agent filling chamber Sp between the inner container 14 and the outer container 13 is filled with the pressurizing agent P. The lid 15 is opened in the inner container 14 and the outer container is opened. The lid welding step S4 for welding and fixing to the opening of 13 is performed. In this step, the pressurizing agent P is filled in the pressurizing agent accommodating chamber Sp through the gap between the lid 15 and the outer container 13 (undercup filling). After that, the lid 15 is welded to the outer container 13 and the inner container 14 and sealed. In this step, for example, the pressurizing agent filling device 30 of FIG. 4 can be used, and the welding method of FIG. 2A can be adopted. As a result, welded debris is less likely to come out, the adhesion between the lid 15 and the outer container 13 is increased, leakage is small, and a gas-containing food 11a having an excellent appearance can be obtained.

なお、ヘッドスペースHs内の空気よりも加圧剤Pのほうが原液Cへの溶解度が高い場合は、加圧剤Pが内部容器14を透過して原液Cに溶解しやすいため、置換工程S2は不要である。 When the pressurizing agent P has a higher solubility in the stock solution C than the air in the headspace Hs, the pressurizing agent P permeates the inner container 14 and easily dissolves in the stock solution C, so that the replacement step S2 is performed. Not needed.

また、加圧剤Pを充填する際にヘッドスペースHs内にも加圧剤Pを充填してもよい。すなわち、この工程でもヘッドスペースHs内の空気と加圧剤Pとを入れ換えることができる(置換工程S4a)。この場合、置換気体Rは加圧剤Pであって、内部容器14内の気体Gは加圧剤Pとなる。 Further, when the pressurizing agent P is filled, the pressurizing agent P may also be filled in the head space Hs. That is, even in this step, the air in the head space Hs and the pressurizing agent P can be replaced (replacement step S4a). In this case, the substitution gas R is the pressurizing agent P, and the gas G in the inner container 14 is the pressurizing agent P.

なお、原液充填工程S1にて加温した原液Cを充填して内部容器14を熱収縮させたり、原液充填工程S1の前に内部容器14に熱風を吹き付けて熱収縮させてから原液Cを充填することもできる。また、内部容器14内の空気をバキュームして内部容器14を収縮させてもよく、外部容器13と内部容器14の間の加圧剤収容室Spに加圧剤や圧縮空気を充填して内部容器14を外部から加圧し収縮させてもよい。内部容器14と外部容器13を二重ブロー成形などによって製造したときは、内部容器14と外部容器13が密着しており、加圧剤収容室Spが小さく充填しにくい。このように加圧剤Pを充填する前に、内部容器14を収縮させて加圧剤収容室Spを形成することにより、加圧剤Pを充填しやすくなる。また、後述する気体の溶解により内部容器14が収縮しやすくなる。 The inner container 14 is heat-shrinked by filling the stock solution C heated in the stock solution filling step S1, or the inner container 14 is heat-shrinked by blowing hot air before the stock solution filling step S1 and then the stock solution C is filled. You can also do it. Further, the air in the inner container 14 may be vacuumed to contract the inner container 14, and the pressurizing agent storage chamber Sp between the outer container 13 and the inner container 14 may be filled with a pressurizing agent or compressed air inside. The container 14 may be pressurized and contracted from the outside. When the inner container 14 and the outer container 13 are manufactured by double blow molding or the like, the inner container 14 and the outer container 13 are in close contact with each other, and the pressurizing agent storage chamber Sp is small and difficult to fill. By shrinking the internal container 14 to form the pressurizing agent accommodating chamber Sp before filling the pressurizing agent P in this way, the pressurizing agent P can be easily filled. In addition, the inner container 14 tends to shrink due to the dissolution of the gas described later.

蓋体溶着工程S4が完了すると、容器本体16内の圧力が高くなるためヘッドスペースHs内の気体Gは圧縮され、さらに原液Cに溶解していく。もしくは、加圧剤収容室Spの加圧剤Pが内部容器14内に透過し原液Cに溶解することで、溶解しきれなかったヘッドスペースHs内の空気(気体)Gが内部容器14外に押し出され、気相部が小さくなる、もしくは消滅する。そのため、内部容器14は徐々に収縮していくことになる。これが内部容器収縮工程S5である。この内部容器収縮工程S5は、冷蔵状態で行われることが好ましい。 When the lid welding step S4 is completed, the pressure inside the container body 16 increases, so that the gas G in the headspace Hs is compressed and further dissolved in the stock solution C. Alternatively, the pressurizing agent P in the pressurizing agent accommodating chamber Sp permeates into the inner container 14 and dissolves in the stock solution C, so that the air (gas) G in the headspace Hs that could not be completely dissolved is removed from the inner container 14. It is extruded and the gas phase part becomes smaller or disappears. Therefore, the inner container 14 gradually shrinks. This is the internal container shrinkage step S5. The internal container shrinkage step S5 is preferably performed in a refrigerated state.

このように、本発明のガス含有食品11aの製造方法によれば、内部容器14内の気体Gを原液Cに溶解させる、もしくは内部容器14外へ押し出すことができるため、内部容器14内での気相部の形成を抑制することができる。とくに、蓋体15を超音波溶着する場合、溶着部付近に原液Cがあると、原液Cが超音波振動により霧化して溶着部の溶解を阻害し、溶着が不十分になることがある。そのため、内部容器14内に気相部を設け、溶着部から原液Cの液面を離す必要があり、どうしても内部容器14に気相部が生じてしまうが、内部容器収縮工程S5を備えることで、気相部を小さく、もしくは消滅させることができ、原液Cの安定した吐出を実現できる。 As described above, according to the method for producing the gas-containing food 11a of the present invention, the gas G in the inner container 14 can be dissolved in the stock solution C or pushed out of the inner container 14, so that the gas G in the inner container 14 can be pushed out. The formation of the gas phase part can be suppressed. In particular, when the lid 15 is ultrasonically welded, if the undiluted solution C is present near the welded portion, the undiluted solution C may be atomized by ultrasonic vibration to inhibit the dissolution of the welded portion, resulting in insufficient welding. Therefore, it is necessary to provide a gas phase portion in the inner container 14 and separate the liquid level of the undiluted solution C from the welded portion, and the gas phase portion is inevitably generated in the inner container 14, but by providing the inner container shrinking step S5, , The gas phase part can be made small or extinguished, and stable discharge of the undiluted solution C can be realized.

また、加圧剤Pとして炭酸ガスを用いれば、原液Cに炭酸ガスを溶解させることができ、炭酸ガスを含有した食品(炭酸水、炭酸飲料等)を製造することができる。 Further, if carbon dioxide gas is used as the pressurizing agent P, carbon dioxide gas can be dissolved in the undiluted solution C, and foods containing carbon dioxide gas (carbonated water, carbonated drinks, etc.) can be produced.

(実施例1)
外部容器、内部容器共にポリエチレンテレフタレート製の加圧容器11(外部容器の満注量250ml)を用い、内部容器内に原液Cとして、25℃に調整し、空気が飽和溶解している水(溶解量0.017)を150g充填した。次いで容器本体にポリエチレンテレフタレート製の蓋体を被せた。さらに、外部容器と蓋体の間から加圧剤収容室Spに加圧剤Pとして炭酸ガス(水への溶解度:0.76(25℃,1atm))を充填し、蓋体を容器本体に超音波溶着により固定した。内部容器内のヘッドスペースHsの気体Gは空気である。製造直後の圧力は0.55MPaであった。その後、5℃の冷蔵庫にて保管したところ、6時間後には内部容器が収縮して気相部はほとんど消滅し、圧力は0.4MPaに低下した。そのため、実施例1では置換工程S2、S4aは不要である。出来上がったガス含有食品11aを、吐出部材12を用いて開封して原液Cを吐出させると、ペットボトルに充填されている市販の炭酸飲料と同程度の刺激が得られ、原液Cに十分な量の加圧剤Pが溶解していることが分かった。また、原液Cをほとんど全量吐出した後で吐出部材を外し、室温で3日間静置したところ、加圧剤収容室Sp内の加圧剤が内部容器を透過し、さらに被開封部を通じて外部に放出され、容器本体を握ると容易に変形させることができた。
(Example 1)
A pressurized container 11 made of polyethylene terephthalate (full injection amount of 250 ml of the outer container) was used for both the outer container and the inner container, and the stock solution C was adjusted to 25 ° C. in the inner container, and water in which air was saturated and dissolved (dissolved). Amount 0.017) was filled in 150 g. Next, the container body was covered with a lid made of polyethylene terephthalate. Further, carbon dioxide gas (solubility in water: 0.76 (25 ° C., 1 atm)) is filled as the pressurizing agent P from between the outer container and the lid to fill the pressurizing agent storage chamber Sp, and the lid is placed in the container body. It was fixed by ultrasonic welding. The gas G in the headspace Hs in the inner container is air. The pressure immediately after production was 0.55 MPa. Then, when it was stored in a refrigerator at 5 ° C., the internal container contracted after 6 hours, the gas phase part almost disappeared, and the pressure dropped to 0.4 MPa. Therefore, in the first embodiment, the replacement steps S2 and S4a are unnecessary. When the finished gas-containing food 11a is opened using the discharge member 12 and the undiluted solution C is discharged, the same stimulus as that of a commercially available carbonated beverage filled in a PET bottle is obtained, and a sufficient amount of the undiluted solution C is obtained. It was found that the pressurizing agent P of was dissolved. Further, when the discharge member was removed after almost all of the undiluted solution C was discharged and the mixture was allowed to stand at room temperature for 3 days, the pressure agent in the pressure agent storage chamber Sp permeated the inner container and further to the outside through the opened portion. It was released and could be easily deformed by grasping the container body.

(比較例1)
外部容器、内部容器共にポリエチレンテレフタレート製の加圧容器11(外部容器の満注量250ml)を用い、内部容器内に原液Cとして、25℃に調整し、炭酸ガスが飽和溶解している炭酸水(溶解量0.76)を150g充填した。次いで容器本体にポリエチレンテレフタレート製の蓋体を被せた。さらに、外部容器と蓋体の間から加圧剤収容室Spに加圧剤Pとして炭酸ガスを充填し、蓋体を容器本体に超音波溶着したところ、炭酸水があふれ出し、溶着できなかった。
(Comparative Example 1)
A pressurized container 11 made of polyethylene terephthalate (full injection amount of 250 ml of the outer container) was used for both the outer container and the inner container, and the stock solution C was adjusted to 25 ° C. in the inner container, and carbonated water in which carbon dioxide gas was saturated and dissolved was dissolved. (Dissolved amount 0.76) was filled with 150 g. Next, the container body was covered with a lid made of polyethylene terephthalate. Further, when carbon dioxide gas was filled as the pressurizing agent P from between the outer container and the lid body and the lid body was ultrasonically welded to the container body, the carbonated water overflowed and could not be welded. ..

以上、本発明の好ましい実施形態について説明したが、本発明はこれらの実施形態に限定されるものではなく、発明の範囲内で種々の変形を行うことができる。たとえば、大気中ではなく、炭酸ガス等の原液Cに溶解させたい雰囲気中でガス含有食品11aを製造してもよい。この場合、置換工程S2、S4aは不要である。また、内部容器14に加圧剤Pを充填し、外部容器13と内部容器14との間に原液Cを充填してもよい。この場合であっても、内部容器14を透過した加圧剤Pが原液Cに溶解するため、ガス含有食品が得られる。また、吐出部材12によって蓋体15を開封する以外にも、被開封部15dと連続するつまみ部を設け、プルトップのように、つまみ部を摘まんで引っ張るなどして被開封部15dをちぎり取るようにしてもよい。 Although the preferred embodiments of the present invention have been described above, the present invention is not limited to these embodiments, and various modifications can be made within the scope of the invention. For example, the gas-containing food 11a may be produced not in the air but in an atmosphere that is desired to be dissolved in the stock solution C such as carbon dioxide. In this case, the replacement steps S2 and S4a are unnecessary. Further, the inner container 14 may be filled with the pressurizing agent P, and the stock solution C may be filled between the outer container 13 and the inner container 14. Even in this case, since the pressurizing agent P that has passed through the inner container 14 dissolves in the stock solution C, a gas-containing food can be obtained. In addition to opening the lid 15 with the discharge member 12, a knob portion continuous with the opened portion 15d is provided, and the knob portion is picked up and pulled like a pull top to tear off the opened portion 15d. It may be.

10 吐出装置
11 加圧容器
11a ガス含有食品
12 吐出部材
C 原液
P 加圧剤
13 外部容器
13a 底部
13b 胴部
13c 肩部
13d 首部
13e 雄ねじ
13f 首部の上端面
13g 環状突起
13h 傾斜部
14 内部容器
Sc 原液収容室
Sp 加圧剤収容室
14a 底部
14b 胴部
14c 肩部
14d 首部
14e 上端面
14f フランジ
14g 環状突起
14h 横溝
14i 縦溝
15 蓋体
15a 封止部
15a1 内筒部
15a2 バルブ収容部(嵌合筒部)
15b フランジ
15c 底部
15d 被開封部
15d1 受圧部
15e 連続部
15f 弱め線
15g 補強部(補強リブ)
16 容器本体
17 平板部
17a 外筒部
17a1 外筒部の下面
17b 平板部の下面
17c 平板部の天面
18 バルブホルダ
18a バルブ保持部
18b ラバー押さえ
20 キャップ(装着部)
20a 上底
21 バルブ
22 ステム
23 操作ボタン
24 ハウジング
25 バネ
26 ステムラバー
27 開封部
27a (開封部の)底面
27b 深穴
27c 横孔
28 シール部材
H ホーン
H1 ホーンの下面
30 加圧剤充填装置
31 ベース
32 昇降台
33 充填具
35 支柱
36 シール材
37 昇降装置
38 ホーンの下端近辺
Hu ホーンの上部
Hm ホーンの中部
Hb ホーンの下部
S1 原液充填工程
S2 置換工程
S3 蓋体装着工程
S4 加圧剤充填・蓋体溶着工程
S4a 置換工程
S5 内部容器収縮工程
Hs ヘッドスペース
G 内部容器内の気体
R 置換気体
10 Discharge device 11 Pressurized container 11a Gas-containing food 12 Discharge member C Undiluted solution P Pressurizing agent 13 External container 13a Bottom 13b Body 13c Shoulder 13d Neck 13e Male screw 13f Top surface of neck 13g Circular protrusion 13h Inclined portion 14 Internal container Sc Undiluted solution storage chamber Sp Pressurizer storage chamber 14a Bottom 14b Body 14c Shoulder 14d Neck 14e Top surface 14f Flange 14g Circular protrusion 14h Horizontal groove 14i Vertical groove 15 Lid 15a Sealing part 15a1 Inner cylinder part 15a2 Valve housing part (fitting) Cylinder)
15b Flange 15c Bottom 15d Opened part 15d1 Pressure receiving part 15e Continuous part 15f Weakening line 15g Reinforcing part (reinforcing rib)
16 Container body 17 Flat plate 17a Outer cylinder 17a1 Lower surface of outer cylinder 17b Lower surface of flat plate 17c Top surface of flat plate 18 Valve holder 18a Valve holding 18b Rubber retainer 20 Cap (mounting part)
20a Upper bottom 21 Valve 22 Stem 23 Operation button 24 Housing 25 Spring 26 Stem rubber 27 Opening part 27a (Opening part) Bottom surface 27b Deep hole 27c Side hole 28 Sealing member H Horn H1 Horn bottom surface 30 Pressurizer filling device 31 Base 32 Lifting platform 33 Filling tool 35 Support 36 Sealing material 37 Lifting device 38 Near the lower end of the horn Hu Near the lower end of the horn Hm Upper part of the horn Hb Lower part of the horn S1 Stock solution filling process S2 Replacement process S3 Lid mounting process S4 Pressurizer filling / lid Body welding step S4a Substitution step S5 Inner container shrinkage step Hs Headspace G Gas in inner container R Substitute gas

Claims (4)

外部容器内に、ガス透過性の内部容器を収容した容器本体と、
前記容器本体と同一素材で構成され、容器本体の開口を閉じる、バルブを有しない蓋体と、
ガスの溶解量が0.05以下である食品と、
食品溶解用のガスとを準備し、
前記内部容器又は前記外部容器と前記内部容器との間のいずれか一方に前記食品を充填し、他方に前記ガスを充填した後、前記蓋体を前記容器本体に超音波溶着して前記外部容器と前記内部容器とを密閉し、前記ガスを透過させて前記食品に含有させる、ガス含有食品の製造方法。
A container body containing a gas-permeable inner container inside the outer container,
A lid that is made of the same material as the container body, closes the opening of the container body, and does not have a valve.
Foods with a dissolved amount of gas of 0.05 or less and
Prepare with gas for food dissolution,
After filling either one of the inner container or between the outer container and the inner container with the food and filling the other with the gas, the lid is ultrasonically welded to the container body to the outer container. A method for producing a gas-containing food, wherein the inner container is sealed and the gas is permeated and contained in the food.
前記内部容器に前記食品を充填し、前記外部容器と前記内部容器との間に前記ガスを充填する、請求項1記載のガス含有食品の製造方法。 The method for producing a gas-containing food according to claim 1, wherein the inner container is filled with the food, and the gas is filled between the outer container and the inner container. 前記内部容器に前記食品を充填した後、前記内部容器内の気体と前記ガスとを入れ替える、請求項2記載のガス含有食品の製造方法。 The method for producing a gas-containing food according to claim 2, wherein the gas in the inner container is replaced with the gas after the food is filled in the inner container. 前記ガスが、25℃での水への溶解度が0.05以上の圧縮ガスである、請求項1〜3のいずれか記載のガス含有食品の製造方法。


The method for producing a gas-containing food according to any one of claims 1 to 3, wherein the gas is a compressed gas having a solubility in water at 25 ° C. of 0.05 or more.


JP2019127625A 2018-07-18 2019-07-09 Manufacture method of gas-containing food Pending JP2021011304A (en)

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JP2019127625A JP2021011304A (en) 2019-07-09 2019-07-09 Manufacture method of gas-containing food
CN201980047765.1A CN112424088B (en) 2018-07-18 2019-07-18 Dual pressurized container, dispensing product, dispensing member, dispenser system, and method for manufacturing dispensing product
EP19837693.1A EP3825254A4 (en) 2018-07-18 2019-07-18 Double pressurized container, discharge product, discharge member, dispenser system and manufacturing method for discharge product
US17/260,685 US11603257B2 (en) 2018-07-18 2019-07-18 Double pressurized container, discharge product, discharge member, dispenser system and manufacturing method for discharge product
PCT/JP2019/028376 WO2020017617A1 (en) 2018-07-18 2019-07-18 Double pressurized container, discharge product, discharge member, dispenser system and manufacturing method for discharge product

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JPH1133444A (en) * 1997-07-15 1999-02-09 Osaka Ship Building Co Ltd Aerosol product
JP2002225937A (en) * 2001-01-25 2002-08-14 Kashiwagi Mold:Kk Packaging container
WO2005085077A1 (en) * 2004-03-03 2005-09-15 Kirin Brewery Company, Limited Sealed vessel and method of producing the same
JP2011105317A (en) * 2009-11-13 2011-06-02 Toppan Printing Co Ltd Packaging container and method for manufacturing food package using this packaging container
JP2014231357A (en) * 2013-05-02 2014-12-11 株式会社ダイゾー Discharge container
JP2015030493A (en) * 2013-07-31 2015-02-16 株式会社三谷バルブ Discharge container
WO2015151299A1 (en) * 2014-04-03 2015-10-08 株式会社テクノクラーツ Cap, pouring container comprising said cap, and production method for said cap
JP2016033038A (en) * 2014-07-31 2016-03-10 株式会社ダイゾー Discharge container and manufacturing method of discharge product
JP2016203988A (en) * 2015-04-15 2016-12-08 フジテクノ株式会社 Beverage container, beverage filling method, and beverage pouring method
JP2019006457A (en) * 2017-06-26 2019-01-17 株式会社ダイゾー Discharge container

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1133444A (en) * 1997-07-15 1999-02-09 Osaka Ship Building Co Ltd Aerosol product
JP2002225937A (en) * 2001-01-25 2002-08-14 Kashiwagi Mold:Kk Packaging container
WO2005085077A1 (en) * 2004-03-03 2005-09-15 Kirin Brewery Company, Limited Sealed vessel and method of producing the same
JP2011105317A (en) * 2009-11-13 2011-06-02 Toppan Printing Co Ltd Packaging container and method for manufacturing food package using this packaging container
JP2014231357A (en) * 2013-05-02 2014-12-11 株式会社ダイゾー Discharge container
JP2015030493A (en) * 2013-07-31 2015-02-16 株式会社三谷バルブ Discharge container
WO2015151299A1 (en) * 2014-04-03 2015-10-08 株式会社テクノクラーツ Cap, pouring container comprising said cap, and production method for said cap
JP2016033038A (en) * 2014-07-31 2016-03-10 株式会社ダイゾー Discharge container and manufacturing method of discharge product
JP2016203988A (en) * 2015-04-15 2016-12-08 フジテクノ株式会社 Beverage container, beverage filling method, and beverage pouring method
JP2019006457A (en) * 2017-06-26 2019-01-17 株式会社ダイゾー Discharge container

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