JP2021007516A5 - - Google Patents
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- JP2021007516A5 JP2021007516A5 JP2019122080A JP2019122080A JP2021007516A5 JP 2021007516 A5 JP2021007516 A5 JP 2021007516A5 JP 2019122080 A JP2019122080 A JP 2019122080A JP 2019122080 A JP2019122080 A JP 2019122080A JP 2021007516 A5 JP2021007516 A5 JP 2021007516A5
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- absorbent
- surface side
- skin surface
- core
- absorbent core
- Prior art date
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- 239000002250 absorbent Substances 0.000 claims description 74
- 230000002745 absorbent Effects 0.000 claims description 73
- 229920000642 polymer Polymers 0.000 claims description 26
- 239000000835 fiber Substances 0.000 claims description 12
- 239000006096 absorbing agent Substances 0.000 claims 3
- 239000003086 colorant Substances 0.000 claims 1
- 230000000295 complement effect Effects 0.000 claims 1
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- -1 sericite Chemical compound 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920000247 superabsorbent polymer Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229910052900 illite Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910021426 porous silicon Inorganic materials 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Description
本発明は、吸収性コアと該吸収性コアの肌面側及び非肌面側を覆うコアラップシートとを有する吸収体を備えた吸収性物品であって、前記吸収性コアの肌面側及び非肌面側の少なくとも一方に、L*a*b*表色系でL*値:40以上100以下、a*値:-12以上3以下、b*値:-24以上3以下の範囲の色を有する部材があり、前記吸収性コアが、高吸収性ポリマーとパルプ繊維との集合体であり、前記吸収性コアの肌面側に前記高吸収性ポリマーが配されており、前記吸収性コアの肌面側には、前記吸収性コアと前記コアラップシートとの接合部が配されており、前記吸収性コアの肌面側の少なくとも一部において、前記接合部によって前記高吸収性ポリマーを囲む部屋が配置され、前記高吸収性ポリマーの配された領域が区画されている吸収性物品を提供する。
The present invention is an absorbent article comprising an absorbent body having an absorbent core and a core wrap sheet covering the skin surface side and the non-skin surface side of the absorbent core, the skin surface side of the absorbent core and the skin surface side of the absorbent core. On at least one of the non-skin side, L * a * b * color system L * value: 40 or more and 100 or less, a * value: -12 or more and 3 or less, b * value: -24 or more and 3 or less There is a member having a color, the absorbent core is an aggregate of a highly absorbent polymer and a pulp fiber, and the highly absorbent polymer is arranged on the skin surface side of the absorbent core, and the absorbent core is arranged. A joint portion between the absorbent core and the core wrap sheet is arranged on the skin surface side of the core, and at least a part of the skin surface side of the absorbent core has the high absorbency due to the joint portion. An absorbent article is provided in which a room surrounding the polymer is arranged and the area in which the highly absorbent polymer is arranged is partitioned.
(吸収性コア6にける高吸収性ポリマー67の坪量の測定方法)
まず、吸収性コア6の測定対象部分の断面をマイクロスコープで観察しながら厚み方向に2等分して、表面部61及び裏面部62の各部位を採取する。
採取した各部位について、特許第4225821号公報に記載の繊維及び/又は吸水性ポリマーの定量方法に基づき、高吸収性ポリマー67とパルプ繊維68の混合物のそれぞれを定量化し、高吸収性ポリマー67の質量を算出する。
具体的には、採取した各部位の質量を測定した後、各部位において、高吸収性ポリマー67を低分子量化する。高吸収性ポリマー67の低分子量化は紫外線照射によって行うことができる。その際、採取した各部位の高吸収性ポリマー67とパルプ繊維68の混合物をメッシュ袋などに入れた状態で、アスコルビン酸及びリボフラビンを含む水溶液中に浸漬する。浸漬によって高吸収性ポリマーを膨潤させた後、前記メッシュ袋を水溶液から取り出して、上記の紫外線照射を行い、高吸収性ポリマー67の低分子量化を行う。次いで、低分子量化により生じた成分を水洗いによって除去する。除去したメッシュ袋を充分に水洗いした後、脱水及び乾燥して質量を測定する。測定した質量からメッシュ袋単体の質量を差し引いてパルプ繊維68の質量を算出し、最初に測定した各部位の質量からパルプ繊維68の質量を差し引いて高吸収性ポリマー67の質量を得る。これらを基に、各部位の面積で除して、各部位における高吸収性ポリマー67の坪量を得る。上記の測定を3回行い得た平均値を、表面部61及び裏面部62の各部位における高吸収性ポリマー67の坪量とする。
(Method for measuring the basis weight of the highly
First, the cross section of the measurement target portion of the
For each of the collected sites, each of the mixture of the
Specifically, after measuring the mass of each of the collected sites, the highly
上記のようなスリット部8は、吸収性コア6に対して切込みを加える方法の他、回転ドラムの外周面に配された集積用凹部において、スッリト部8となるべき部位に非通気性の凸部を設けることで製造できる。
In addition to the method of making a notch in the
色調変化剤の具体例として、表面シート3の構成繊維の成分とは屈折率の異なる無機紛体、有機紛体などが挙げられる。
無機紛体としては、例えば、酸化チタン、多孔質酸化ケイ素(シリカ)、多孔質シリカ、酸化アルミニウム(アルミナ)、石灰、粘土鉱物が挙げられる。粘土鉱物としては、スメクタイト、モンモリナイト、ベントナイト、カオリナイト、セリサイト、イライト、グローコナイト、クロライト、ゼオライト、タルク、ミズカナイト、等が挙げられる。
有機紛体としては、ポリエチレン紛体、ポリエステル紛体、ポリプロピレン紛体、ポリアクリル紛体、ポリアクリレート紛体、セルロース紛体、ビスコース紛体、シルク紛体、シリコーン化合物紛体、フッ素化合物紛体、等が挙げられる。またこれらの有機紛体を色素によって着色したものが挙げられる。中でも、色調変化剤として酸化チタンを用いることが好ましい。
色調変化剤の配合量は、表面シート3の構成繊維全体を100質量%として、0.1質量%以上が好ましく、1質量%以上がより好ましく、3質量%以上が更に好ましい。酸化チタンを表面シート3の構成繊維に一定量以上配合することで、効果的に光を散乱させることができる。一方、表面シート3の構成繊維への酸化チタンの配合量の上限値は、本発明の効果を奏するものであれば特に限定されないが、10質量%以下が実際的である。
Specific examples of the color tone changing agent include inorganic powders and organic powders having a refractive index different from that of the constituent fibers of the
Examples of the inorganic powder include titanium oxide, porous silicon oxide (silica), porous silica, aluminum oxide (alumina), lime, and clay minerals. Examples of clay minerals include smectite, montmorillonite, bentonite, kaolinite, sericite, illite, gloconite, chlorite, zeolite, talc, and mizukanite.
Examples of the organic powder include polyethylene powder, polyester powder, polypropylene powder, polyacrylic powder, polyacrylate powder, cellulose powder, viscose powder, silk powder, silicone compound powder, fluorine compound powder and the like. Further, examples thereof include those obtained by coloring these organic powders with a dye. Above all, it is preferable to use titanium oxide as a color tone changing agent .
The blending amount of the color tone changing agent is preferably 0.1% by mass or more, more preferably 1% by mass or more, still more preferably 3% by mass or more, assuming that the entire constituent fibers of the
<1>
吸収性コアと該吸収性コアの肌面側及び非肌面側を覆うコアラップシートとを有する吸収体を備えた吸収性物品であって、
前記吸収性コアの肌面側及び非肌面側の少なくとも一方に、L*a*b*表色系でL*値:40以上100以下、a*値:-12以上3以下、b*値:-24以上3以下の範囲の色を有する部材があり、
前記吸収性コアが、高吸収性ポリマーとパルプ繊維との集合体であり、前記吸収性コアの肌面側に前記高吸収性ポリマーが配されており、
前記吸収性コアの肌面側には、前記吸収性コアと前記コアラップシートとの接合部が配されており、前記吸収性コアの肌面側の少なくとも一部において、前記接合部によって前記高吸収性ポリマーを囲む部屋が配置され、前記高吸収性ポリマーの配された領域が区画されている吸収性物品。
<1>
An absorbent article comprising an absorbent body having an absorbent core and a core wrap sheet covering the skin and non-skin sides of the absorbent core.
L * a * b * color system L * value: 40 or more and 100 or less, a * value: -12 or more and 3 or less, b * value on at least one of the skin surface side and the non-skin surface side of the absorbent core. : There is a member with a color in the range of -24 or more and 3 or less.
The absorbent core is an aggregate of a highly absorbent polymer and pulp fibers, and the highly absorbent polymer is arranged on the skin surface side of the absorbent core.
A joint portion between the absorbent core and the core wrap sheet is arranged on the skin surface side of the absorbent core, and at least a part of the absorbent core on the skin surface side is described by the joint portion. An absorbent article in which a room surrounding the highly absorbent polymer is arranged and an area in which the highly absorbent polymer is arranged is partitioned.
Claims (8)
前記吸収性コアの肌面側及び非肌面側の少なくとも一方に、L*a*b*表色系でL*値:40以上100以下、a*値:-12以上3以下、b*値:-24以上3以下の範囲の色を有する部材があり、
前記吸収性コアが、高吸収性ポリマーとパルプ繊維との集合体であり、前記吸収性コアの肌面側に前記高吸収性ポリマーが配されており、
前記吸収性コアの肌面側には、前記吸収性コアと前記コアラップシートとの接合部が配されており、前記吸収性コアの肌面側の少なくとも一部において、前記接合部によって前記高吸収性ポリマーを囲む部屋が配置され、前記高吸収性ポリマーの配された領域が区画されており、
前記色が、前記高吸収性ポリマーの変色後の色と補色の関係の範囲にある色である、吸収性物品。 An absorbent article comprising an absorbent body having an absorbent core and a core wrap sheet covering the skin and non-skin sides of the absorbent core.
L * a * b * color system L * value: 40 or more and 100 or less, a * value: -12 or more and 3 or less, b * value on at least one of the skin surface side and the non-skin surface side of the absorbent core. : There is a member with a color in the range of -24 or more and 3 or less.
The absorbent core is an aggregate of a highly absorbent polymer and pulp fibers, and the highly absorbent polymer is arranged on the skin surface side of the absorbent core.
A joint portion between the absorbent core and the core wrap sheet is arranged on the skin surface side of the absorbent core, and at least a part of the absorbent core on the skin surface side is described by the joint portion. A room surrounding the highly absorbent polymer is arranged, and the area where the highly absorbent polymer is arranged is partitioned .
An absorbent article , wherein the color is within the range of complementary colors to the discolored color of the highly absorbent polymer .
前記高吸収性ポリマーを囲む部屋が前記長手方向に列をなしており、該列が前記幅方向に3列以上配置されている請求項1記載の吸収性物品。 The absorbent core has a longitudinal direction corresponding to the direction in which the front side, the inseam and the rear side of the wearer are connected and a width direction orthogonal to the longitudinal direction.
The absorbent article according to claim 1, wherein the chambers surrounding the highly absorbent polymer are arranged in a row in the longitudinal direction, and the rows are arranged in three or more rows in the width direction.
Claims 1 to 7 in which a slit portion is arranged in the absorbent core, and the core wrap sheets arranged on the skin surface side and the non-skin surface side of the absorbent core are adhered to each other by the slit portion. The absorbent article according to any one of the above .
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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JP2019122080A JP7351657B2 (en) | 2019-06-28 | 2019-06-28 | absorbent articles |
PCT/JP2020/018859 WO2020261780A1 (en) | 2019-06-28 | 2020-05-11 | Absorbent article |
CN202080046274.8A CN114040737B (en) | 2019-06-28 | 2020-05-11 | Absorbent article |
Applications Claiming Priority (1)
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JP2019122080A JP7351657B2 (en) | 2019-06-28 | 2019-06-28 | absorbent articles |
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JP2021007516A JP2021007516A (en) | 2021-01-28 |
JP2021007516A5 true JP2021007516A5 (en) | 2022-03-18 |
JP7351657B2 JP7351657B2 (en) | 2023-09-27 |
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CN (1) | CN114040737B (en) |
WO (1) | WO2020261780A1 (en) |
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Publication number | Priority date | Publication date | Assignee | Title |
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JP4124938B2 (en) * | 2000-02-01 | 2008-07-23 | 株式会社日本吸収体技術研究所 | Water-disintegrating superabsorbent composite and absorbent article |
JP3737335B2 (en) | 2000-03-22 | 2006-01-18 | 花王株式会社 | Absorbent articles |
HU2762U (en) * | 2002-12-20 | 2004-06-28 | Procter & Gamble | Disposable absorbent article |
JP4477430B2 (en) | 2004-06-28 | 2010-06-09 | 大王製紙株式会社 | Absorber manufacturing equipment and absorber manufacturing method |
JP4724499B2 (en) * | 2005-08-31 | 2011-07-13 | 大王製紙株式会社 | Absorbent articles |
JP2007202576A (en) | 2006-01-30 | 2007-08-16 | Livedo Corporation | Absorbent laminate and disposable absorbent article |
JP4693125B2 (en) | 2006-10-11 | 2011-06-01 | 大阪シーリング印刷株式会社 | Sheet member with liquid crystal and method for producing the same |
JP5709398B2 (en) | 2010-03-31 | 2015-04-30 | ユニ・チャーム株式会社 | Absorbent articles |
EP2399557B2 (en) | 2010-06-25 | 2017-03-29 | The Procter and Gamble Company | Disposable diaper with reduced bulk |
JP6231868B2 (en) | 2013-12-12 | 2017-11-15 | 花王株式会社 | Absorbent article surface sheet and absorbent article provided with the same |
JP6479520B2 (en) | 2015-03-20 | 2019-03-06 | 大王製紙株式会社 | Absorbent articles |
JP6158872B2 (en) | 2015-08-25 | 2017-07-05 | 大王製紙株式会社 | Absorbent articles |
JP6381588B2 (en) | 2016-07-07 | 2018-08-29 | ユニ・チャーム株式会社 | Absorbent articles |
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- 2020-05-11 CN CN202080046274.8A patent/CN114040737B/en active Active
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