JP2020514547A - Flat steel semi-finished products, method of manufacturing components and their use - Google Patents

Flat steel semi-finished products, method of manufacturing components and their use Download PDF

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JP2020514547A
JP2020514547A JP2019547458A JP2019547458A JP2020514547A JP 2020514547 A JP2020514547 A JP 2020514547A JP 2019547458 A JP2019547458 A JP 2019547458A JP 2019547458 A JP2019547458 A JP 2019547458A JP 2020514547 A JP2020514547 A JP 2020514547A
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マッセイ,クリスティーナ
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ThyssenKrupp Steel Europe AG
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B21D53/00Making other particular articles
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
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    • B60N2/00Seats specially adapted for vehicles; Arrangement or mounting of seats in vehicles
    • B60N2/02Seats specially adapted for vehicles; Arrangement or mounting of seats in vehicles the seat or part thereof being movable, e.g. adjustable
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    • B60N2/06Seats specially adapted for vehicles; Arrangement or mounting of seats in vehicles the seat or part thereof being movable, e.g. adjustable the whole seat being movable slidable
    • B60N2/07Slide construction
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/10Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
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    • C22C38/008Ferrous alloys, e.g. steel alloys containing tin
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    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/08Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes

Abstract

本発明は、1200MPaを超える引張強度及び/又は370HV10を超える硬度を有し、マルテンサイト相鋼から作製される第1層(1.1)と、600MPaより小さい引張強度及び/又は190HV10より小さい硬度を有し、表面積全体で、かつ材料と材料が結合される方法で第1層(1.1)に結合される、軟鋼合金から作製される、少なくとも1つの第2層(1.2、1.2‘)と、を含む、平鋼半仕上げ製品(1)に関する。本発明はさらに平鋼半仕上げ製品から構成要素を製造する方法及びそれらに関連する使用に関する。【選択図】図1The present invention has a tensile strength of more than 1200 MPa and/or a hardness of more than 370 HV10 and a first layer (1.1) made of martensitic phase steel and a tensile strength of less than 600 MPa and/or a hardness of less than 190 HV10. At least one second layer (1.2, 1) made of a mild steel alloy having an .2') and a flat steel semi-finished product (1). The invention further relates to methods of making components from flat steel semi-finished products and their associated uses. [Selection diagram] Figure 1

Description

本発明は、第1層と、第1層に完全にかつ凝集力で結合する少なくとも1つの第2層と、を含む半仕上げ平鋼製品に関する。本発明は、さらに半仕上げ平鋼製品から構成要素を製造するプロセスと、それらに関連する使用に関する。   The present invention relates to a semi-finished flat steel product comprising a first layer and at least one second layer which is completely and cohesively bonded to the first layer. The invention further relates to processes for manufacturing components from semi-finished flat steel products and their associated uses.

自動車業界において、自動車の軽量化及び軽量化に伴う燃料消費の低減のための、新たな解決策が模索されている。自動車重量の低減を可能にするためには、ここでは軽量構造が重要な手段である。軽量構造体を得る1つの方法は、強度が増強された材料を使用することである。材料の強度が増すにつれて、これらの材料の曲げ性能は通常低下する。事故の衝突に関連する構成要素の場合にも求められるが、乗員の確実な保護のためには、使用される材料は、軽量構造体を実施するために強度が高められたにもかかわらず、衝突で導入されたエネルギーを、材料自身の変形により確実に変換させることができなければならない。そのためには、特に車両構造又はシート機構の衝突関連部品に高い成形性能が求められる。重量を削減する1つの方法は、特に電気自動車及び/又はハイブリッド自動車の場合に、例えば、自動車の車体構造、フレーム、シート機構及び/又はシャーシや、例えば、電気走行のためのバッテリーモジュールを収容するバッテリーハウジングさえ、従来使用される材料と比較してよりいっそう軽い形態で、軽量かつ刷新的な材料を用いて、構成する又は組み立てることである。例えば、従来の材料は、構成要素特有の方法で、同等の性質を有するより軽い材料に置き換えることができる。例えば、自動車業界では、2種以上の異なる材料から構成されるハイブリッド材料又は材料複合体の使用が増えている。それぞれ個別の材料は特有の性質を有しているが、個別の、一体構造の材料と比較して材料複合体が改善された性質を達成するために、これらの特有の性質が複合体で組み合わされて本質的に相反する性質を与える。特に異なる合金鋼から調製される材料複合体は、例えば、ドイツ語で公表されているドイツ特許第DE102008022709A1号の先行技術において既知である。   In the automotive industry, new solutions are being sought to reduce the weight of automobiles and the fuel consumption associated with the weight reduction. Lightweight construction is an important measure here in order to enable the reduction of vehicle weight. One way to obtain a lightweight structure is to use materials with increased strength. As the strength of materials increases, the bending performance of these materials usually decreases. As required in the case of components involved in accidental crashes, for reliable protection of the occupants, the materials used are, despite their increased strength to implement a lightweight structure. The energy introduced in the collision must be able to be reliably converted by the deformation of the material itself. For that purpose, high molding performance is particularly required for collision-related parts of a vehicle structure or a seat mechanism. One way to reduce the weight is, for example, in the case of electric and / or hybrid vehicles, to accommodate, for example, the bodywork of the vehicle, the frame, the seat mechanism and / or the chassis and, for example, the battery module for electric driving. Even the battery housing is constructed or assembled using light weight and innovative materials in a much lighter form compared to the materials conventionally used. For example, conventional materials can be replaced in a component-specific manner with lighter materials of comparable properties. For example, the automotive industry is increasingly using hybrid materials or material composites composed of two or more different materials. Although each individual material has unique properties, these unique properties are combined in the composite to achieve improved properties in the material composite as compared to individual, monolithic materials. Being given an essentially contradictory property. Material composites prepared in particular from different alloy steels are known, for example, in the prior art of German patent DE 102008022709A1 published in German.

特にマルテンサイト微細構造を有する合金鋼は、高い(引張り)強度(R)を有し有利な性質を備え、冷間形成される衝突関連部品(構成部品)の製造に特に好適である。このような合金鋼は、本出願人からマルテンサイト相鋼として、「MS−WR(登録商標)」の商標名で市販されている。この合金鋼は上記と同一の性質を伴い、材料の厚みの観点から、従来の合金鋼と比較して、より薄く調製することができ、材料の厚みの削減が、構成要素(構成部品)の重量又は自動車全体の重量に良い影響を及ぼし得る。それゆえこのような合金鋼は、自動車業界に優れた適合性を示す。 In particular, an alloy steel having a martensitic microstructure has a high (tensile) strength (R m ) and advantageous properties and is particularly suitable for the production of cold-formed collision-related parts (components). Such an alloy steel is commercially available from the applicant as a martensitic phase steel under the trade name of "MS-WR (registered trademark)". This alloy steel has the same properties as the above, and from the viewpoint of material thickness, it can be prepared thinner than the conventional alloy steel, and the reduction of material thickness is It can have a positive effect on the weight or the overall weight of the vehicle. Therefore, such alloy steels show excellent compatibility with the automotive industry.

マルテンサイト相鋼の強度を増大させることに関する可能性は決して研究し尽されておらず、そのため適切な合金概念を用いて又は別の方法若しくは追加の方法として、製造ルートの最適化により、マルテンサイト相鋼における、最大2000MPa以上の引張強度を達成する又は確立することができる可能性がある。しかしながら、本質的にマルテンサイト微細構造を有する合金鋼(マルテンサイト相鋼)は、化学的性質及び物理的性質のために、塗装性、特に耐食性コーティングが制限される。材料の強度が増加すると成形性能は低下し、特に曲げ角度が犠牲になるので、形成作業における鋼材料の表面又は表面近くの領域で、確立される形状又は複雑性に応じて微細亀裂/亀裂が発生する可能性があり、これらは最悪の場合、構成要素の初期破損につながり得る。   The possibilities relating to increasing the strength of martensitic phase steels have never been exhausted, so that with the appropriate alloying concept or alternatively or additionally, by optimizing the manufacturing route, martensite It may be possible to achieve or establish tensile strengths of up to 2000 MPa or more in phase steels. However, alloy steels having an essentially martensitic microstructure (martensitic phase steels) have limited paintability, especially corrosion resistant coatings, due to their chemical and physical properties. As the strength of the material increases, the forming performance decreases and, in particular, the bending angle is sacrificed, so that microcracks / cracks are formed in the surface or near the surface of the steel material in the forming operation, depending on the shape or complexity established. This can occur and, in the worst case, can lead to initial failure of the component.

本発明の目的は、本質的に改善された性質を有する半仕上げ平鋼製品であって、容易にコーティング可能で、かつ特に形成作業中に亀裂が入る傾向があったとしても低く、特に高い曲げ角度を有する平鋼製品を提供することと、また構成要素を製造するためのプロセス及びそれらに関連する使用を特定することである。   The object of the present invention is a semi-finished flat steel product with essentially improved properties, which is easily coatable and which is particularly low, even if it tends to crack during the forming operation, and especially high bending. Providing angled flat steel products and also identifying processes and associated uses for making components.

この目的は、請求項1の特徴を有する半仕上げ平鋼製品によって達成される。   This object is achieved by a semi-finished flat steel product having the features of claim 1.

本発明の発明者は、マルテンサイト微細構造を有し、かつ1200MPaを超える引張強度及び/又は370HV10を超える硬度、特に1300MPaを超える引張強度及び/又は400HV10を超える硬度、好ましくは1400MPaを超える引張強度及び/又は435HV10を超える硬度、さらに好ましくは1500MPaを超える引張強度及び/又は465HV10を超える硬度、特に好ましくは1600MPaを超える引張強度及び/又は490HV10を超える硬度を有する、合金鋼の第1層の、少なくとも片面に、完全にかつ凝集力で結合する少なくとも1つの、軟鋼合金の第2層を提供することで、軟鋼合金の第2層が一種の機能層として作用するため、第1層の少なくとも片面は、確実に直接的な接触が生じないようにすることが可能であると見出した。本発明との関係において、軟鋼合金は600MPaより小さい引張強度及び/又は190HV10より小さい硬度、特に550MPaより小さい引張強度及び/又は175HV10より小さい硬度、好ましくは450MPaより小さい引張強度及び/又は140HV10より小さい硬度、より好ましくは380MPaより小さい引張強度及び/又は120HV10より小さい硬度を有する。第2層、すなわち軟鋼合金は、コーティング及び/又は成形性能に関して特に良い影響を与える性質を有する。本発明の半仕上げ平鋼製品は、それゆえ既存の標準的なプロセス、例えば、圧延プロファイルなどに、一連のプロセスを変更する必要なく統合され得る。コーティング及び/又は成形性能の傾向は、本発明に従う機能層としての第2層によって決定される、半仕上げ平鋼製品の表面の性質によって決定される度合いが、非常に大きい。   The inventor of the present invention has a martensitic microstructure and has a tensile strength above 1200 MPa and / or a hardness above 370 HV10, in particular a tensile strength above 1300 MPa and / or a hardness above 400 HV10, preferably a tensile strength above 1400 MPa. And / or a hardness of more than 435 HV10, more preferably a tensile strength of more than 1500 MPa and / or a hardness of more than 465 HV10, particularly preferably a tensile strength of more than 1600 MPa and / or a hardness of more than 490 HV10, of a first layer of alloy steel, By providing at least one second layer of mild steel alloy, which is completely and cohesively bonded on at least one side, the second layer of mild steel alloy acts as a kind of functional layer, so that at least one side of the first layer Found that it is possible to ensure that no direct contact occurs. In the context of the present invention, mild steel alloys have a tensile strength of less than 600 MPa and / or a hardness of less than 190 HV10, in particular less than 550 MPa and / or a hardness of less than 175 HV10, preferably less than 450 MPa and / or less than 140 HV10. It has a hardness, more preferably a tensile strength of less than 380 MPa and / or a hardness of less than 120 HV10. The second layer, the mild steel alloy, has properties that have a particularly positive influence on the coating and / or forming performance. The semi-finished flat steel product of the present invention can therefore be integrated into existing standard processes, such as rolling profiles, without the need to modify the sequence of processes. The tendency of the coating and / or forming performance is determined to a great extent by the surface properties of the semifinished flat steel product, which is determined by the second layer as a functional layer according to the invention.

半仕上げ平鋼製品は、実施されてもよく、又は、鋼帯、鋼板若しくは薄鋼板の形態の半仕上げ製品として、さらなるプロセス過程に提供されてよい。本発明によれば、半仕上げ平鋼製品は、少なくとも2つの異なる合金鋼の層を有する。   The semi-finished flat steel product may be embodied or may be provided to further process steps as a semi-finished product in the form of strip, steel plate or sheet steel. According to the invention, the semi-finished flat steel product has at least two layers of different alloy steels.

本発明によれば、半仕上げ平鋼製品の第1層は、Fe及び調製に関連した不可避の不純物に加えて、C:0.15〜0.6重量%、Si:0.05〜0.9重量%、Mn:0.3〜2.0重量%、Al:0.01〜2.0重量%、Cr+Mo:最大1.5重量%、Nb+Ti:最大0.2重量%、B:最大0.02重量%、V:最大0.25重量%、Cu:最大0.2重量%、Ni:最大0.3重量%、Sn:最大0.05重量%、Ca:最大0.01重量%、As:最大0.02重量%、N:最大0.01重量%、P:最大0.06重量%、S:最大0.03重量%からなる。   According to the invention, the first layer of the semi-finished flat steel product comprises, in addition to Fe and unavoidable impurities related to the preparation, C: 0.15-0.6% by weight, Si: 0.05-0. 9% by weight, Mn: 0.3 to 2.0% by weight, Al: 0.01 to 2.0% by weight, Cr + Mo: maximum 1.5% by weight, Nb + Ti: maximum 0.2% by weight, B: maximum 0. 0.02% by weight, V: maximum 0.25% by weight, Cu: maximum 0.2% by weight, Ni: maximum 0.3% by weight, Sn: maximum 0.05% by weight, Ca: maximum 0.01% by weight, As: maximum 0.02% by weight, N: maximum 0.01% by weight, P: maximum 0.06% by weight, S: maximum 0.03% by weight.

Cは強度を増大させる合金元素であり、含有量が増すにつれて強度の増大に寄与し、それゆえ所望の強度を達成又は確立するために、少なくとも0.15重量%の含有量、好ましくは少なくとも0.2重量%の含有量で存在する。材料の強度が高くなるにつれて、脆性もまた増大するので、材料特性に悪影響を及ぼさないように、また十分な溶接性を確保するために、Cの含有量はまた、0.6重量%以下、特に0.55重量%以下、好ましくは0.5重量%以下、さらに好ましくは0.45重量%以下、特に好ましくは0.4重量%以下に制限される。   C is an alloying element that increases the strength and contributes to the increase of the strength as the content increases and therefore a content of at least 0.15% by weight, preferably at least 0, in order to achieve or establish the desired strength. Present in a content of 0.2% by weight. Since the brittleness also increases as the strength of the material increases, the C content is also 0.6 wt% or less so as not to adversely affect the material properties and to ensure sufficient weldability. In particular, it is limited to 0.55% by weight or less, preferably 0.5% by weight or less, more preferably 0.45% by weight or less, and particularly preferably 0.4% by weight or less.

Siは固溶体の硬化に寄与する合金元素であり、その含有量によっては強度の増大に良い影響を有し、それゆえ少なくとも0.05重量%の含有量で存在する。上記合金元素は、十分な圧延性を確保するために、0.9重量%以下、特に0.7重量%以下、好ましくは0.5重量%以下に制限される。   Si is an alloying element that contributes to the hardening of the solid solution and, depending on its content, has a positive effect on the increase in strength and is therefore present in a content of at least 0.05% by weight. The above alloying elements are limited to 0.9% by weight or less, particularly 0.7% by weight or less, and preferably 0.5% by weight or less in order to secure sufficient rolling property.

Mnは焼入れ性に寄与する合金元素であり、特にSと結合してMnSを得るために引張強度に良い影響を有し、それゆえ少なくとも0.3重量%の含有量で存在する。上記合金元素は、十分な溶接性を確保するために、2.0重量%以下、特に1.7重量%以下、好ましくは1.5重量%以下に制限される。   Mn is an alloying element that contributes to hardenability and has a positive effect on tensile strength, especially because it combines with S to give MnS and is therefore present in a content of at least 0.3% by weight. The above alloying elements are limited to 2.0% by weight or less, particularly 1.7% by weight or less, preferably 1.5% by weight or less in order to secure sufficient weldability.

合金元素のAlは脱酸に寄与し、少なくとも0.01重量%、特に0.015重量%の含有量で存在する。上記合金元素は、材料中への析出物、特に材料特性に悪影響を及ぼし得る非金属の酸化介在物を本質的に低減させる及び/又は避けるために、2.0重量%以下、特に1.0重量%以下、好ましくは0.5重量%以下、より好ましくは0.1重量%以下に制限される。例えば、含有量は0.02重量%〜0.06重量%の間で設定される。   The alloying element Al contributes to deoxidation and is present in a content of at least 0.01% by weight, in particular 0.015% by weight. The alloying elements are not more than 2.0% by weight, in particular 1.0%, in order to essentially reduce and / or avoid precipitates in the material, in particular non-metallic oxidic inclusions which can adversely affect the material properties. The amount is limited to not more than 0.5% by weight, preferably not more than 0.5% by weight, more preferably not more than 0.1% by weight. For example, the content is set between 0.02% by weight and 0.06% by weight.

合金元素のCrは、その含有量によって、特に少なくとも0.05重量%の含有量で、強度を確立するために寄与する、特に焼入れ性に寄与する可能性がある。上記合金元素は、適切な溶接性を確保するために、1.5重量%以下、特に1.2重量%以下、好ましくは1.0重量%以下に制限される。   The alloying element Cr may contribute, depending on its content, in particular at least 0.05% by weight, to establishing strength, in particular to hardenability. The above alloying elements are limited to 1.5% by weight or less, particularly 1.2% by weight or less, preferably 1.0% by weight or less, in order to ensure proper weldability.

合金元素のBは、特にNと結合したときに焼入れ性に寄与することができ、特に少なくとも0.001重量%の含有量で存在する。上記合金元素は、含有量が高いと材料特性に悪影響を及ぼし、その結果、材料の硬度及び/又は強度が低下する可能性があるため、0.02重量%以下、特に0.015重量%以下に制限される。   The alloying element B can contribute to the hardenability, especially when combined with N, and is particularly present in a content of at least 0.001% by weight. If the content of the above alloying elements is high, the material properties are adversely affected, and as a result, the hardness and / or the strength of the material may be reduced. Therefore, 0.02 wt% or less, particularly 0.015 wt% or less. Limited to.

合金元素のTi及びNbは、結晶粒微細化のため及び/又はNと結合するために、特にTiが少なくとも0.005重量%の含有量で、合金中において個別に又は組み合わせて含まれ得る。例えば完全にNと結合するためには、Tiの含有量は少なくとも3.42*Nで提供される必要があるだろう。上記元素の含有量が高いと材料特性に悪影響を及ぼし、特に材料の強靭性に悪影響を及ぼすため、組み合わせた合金元素は、0.2重量%以下、特に0.15重量%以下、好ましくは0.1重量%以下に制限される。   The alloying elements Ti and Nb may be included individually or in combination in the alloy, for the purpose of grain refinement and / or for bonding with N, in particular with a content of Ti of at least 0.005% by weight. For example, in order to be fully N bound, the Ti content would have to be provided at least 3.42 * N. If the content of the above elements is high, the material properties are adversely affected, and particularly, the toughness of the material is adversely affected. Therefore, the combined alloy elements are 0.2 wt% or less, particularly 0.15 wt% or less, preferably 0 wt% or less. It is limited to 1% by weight or less.

Mo、V、Cu、Ni、Sn、Ca、As、N、P又はSは、個別に又は組み合わせて、とりわけこれらの元素が、特定の性質を確立するために合金に含まれる場合でなければ、不純物として見なすことができる合金元素である。含有量は、0.3重量%以下のMo、0.25重量%以下のV、0.2重量%以下のCu、0.3重量%以下のNi、0.05重量%以下のSn、0.01重量%以下のCa、0.02重量%以下のAs、0.01重量%以下のN、0.06重量%以下のP、0.03重量%以下のSに制限される。   Mo, V, Cu, Ni, Sn, Ca, As, N, P or S may be used individually or in combination, especially if these elements are not included in the alloy to establish specific properties. It is an alloying element that can be regarded as an impurity. The content is 0.3 wt% or less Mo, 0.25 wt% or less V, 0.2 wt% or less Cu, 0.3 wt% or less Ni, 0.05 wt% or less Sn, 0 It is limited to 0.01 wt% or less of Ca, 0.02 wt% or less of As, 0.01 wt% or less of N, 0.06 wt% or less of P, and 0.03 wt% or less of S.

第1層の少なくとも片面に機能層を形成するための第2層は好ましくは、容易に、かつ通常困難なくコーティング及び/又は形成することができる、マイクロアロイ鋼又は2相の合金鋼からなる。本発明によれば、半仕上げ平鋼製品の第2層は、Fe及び調製に関連した不可避の不純物に加えて、C:最大0.2重量%、Si:0.01〜0.6重量%、Mn:0.1〜2.5重量%、Al:0.01〜2.0重量%、Cr+Mo:最大1.4重量%、Nb+Ti:最大0.25重量%、B:最大0.02重量%、V:最大0.05重量%、Cu:最大0.2重量%、Ni:最大0.2重量%、Sn:最大0.05重量%、Ca:最大0.01重量%、Co:最大0.02重量%、N:最大0.01重量%、P:最大0.1重量%、S:最大0.06重量%からなる。   The second layer for forming the functional layer on at least one side of the first layer preferably consists of a microalloy steel or a two-phase alloy steel, which can be easily and usually coated and / or formed without difficulty. According to the invention, the second layer of the semifinished flat steel product comprises, in addition to Fe and unavoidable impurities related to the preparation, C: max. 0.2% by weight, Si: 0.01-0.6% by weight. , Mn: 0.1 to 2.5% by weight, Al: 0.01 to 2.0% by weight, Cr + Mo: maximum 1.4% by weight, Nb + Ti: maximum 0.25% by weight, B: maximum 0.02% by weight. %, V: maximum 0.05% by weight, Cu: maximum 0.2% by weight, Ni: maximum 0.2% by weight, Sn: maximum 0.05% by weight, Ca: maximum 0.01% by weight, Co: maximum 0.02% by weight, N: maximum 0.01% by weight, P: maximum 0.1% by weight, S: maximum 0.06% by weight.

合金元素のCは、成形性及び/又は塗装性を増大させるために、少なくとも0.001重量%で存在する一方、0.2重量%以下、特に0.15重量%以下、好ましくは0.11重量%以下、より好ましくは0.09重量%以下に制限される。   The alloying element C is present in an amount of at least 0.001% by weight in order to increase the formability and / or coatability, while it is not more than 0.2% by weight, in particular not more than 0.15% by weight, preferably 0.11% by weight or less. It is limited to not more than wt%, more preferably not more than 0.09 wt%.

Siは固溶体の硬化に寄与する合金元素であり、強度の増大に良い影響を有し、それゆえ少なくとも0.01重量%の含有量で存在する。上記合金元素は、十分な圧延性及び/又は表面品質を確保するために、0.6重量%以下、特に0.5重量%以下、好ましくは0.4重量%以下に制限される。   Si is an alloying element that contributes to the hardening of the solid solution and has a positive effect on the increase in strength and is therefore present in a content of at least 0.01% by weight. The above alloying elements are limited to not more than 0.6% by weight, particularly not more than 0.5% by weight, preferably not more than 0.4% by weight, in order to secure sufficient rollability and / or surface quality.

Mnは焼入れ性に寄与する合金元素であり、特にSと結合してMnSを得るために引張強度に良い影響を有し、それゆえ少なくとも0.1重量%の含有量で存在する。上記合金元素は、十分な溶接性を確保するために、2.5重量%以下、特に2.0重量%以下、好ましくは1.5重量%以下に制限される。   Mn is an alloying element that contributes to the hardenability, has a positive effect on the tensile strength in particular because it combines with S to give MnS and is therefore present in a content of at least 0.1% by weight. The above alloying elements are limited to 2.5% by weight or less, particularly 2.0% by weight or less, preferably 1.5% by weight or less in order to secure sufficient weldability.

合金元素のAlは脱酸に寄与し、少なくとも0.01重量%、特に0.015重量%の含有量で存在する。特に2相域(オーステナイト/フェライト)で熱間圧延される、特に2相の合金鋼の場合、Alはより広い2相域をもたらすために高い含有量で合金に含まれるが、上記合金元素は材料中への析出物、特に材料特性に悪影響を及ぼし得る非金属の酸化介在物を本質的に低減させる及び/又は避けるために、2.0重量%以下、特に1.8重量%以下、好ましくは1.6重量%以下に制限される。特にマイクロアロイ鋼の場合、Al含有量は、本質的に上述の不利益を避けるために、1.0重量%以下、特に0.5重量%以下、好ましくは0.2重量%以下に制限される。   The alloying element Al contributes to deoxidation and is present in a content of at least 0.01% by weight, in particular 0.015% by weight. In particular, in the case of a two-phase alloy steel that is hot-rolled in the two-phase region (austenite / ferrite) in particular, Al is contained in the alloy in a high content to provide a wider two-phase region, but the above-mentioned alloying elements 2.0% by weight or less, especially 1.8% by weight or less, in order to essentially reduce and / or avoid deposits in the material, in particular non-metallic oxidative inclusions which can adversely affect the material properties. Is limited to 1.6% by weight or less. Especially in the case of microalloyed steel, the Al content is essentially limited to 1.0% by weight or less, in particular 0.5% by weight or less, preferably 0.2% by weight or less, in order to avoid the abovementioned disadvantages. It

合金元素のCrはまた、その含有量によっては、特に少なくとも0.1重量%の含有量で強度の確立に寄与し得るが、本質的に表面の完全な塗装性を確保することを可能にするために1.4重量%以下、特に1.2重量%以下、好ましくは1.0重量%以下、さらに好ましくは0.8重量%以下に制限される。   The alloying element Cr also makes it possible, depending on its content, to contribute to the establishment of strength, in particular at a content of at least 0.1% by weight, but essentially ensuring a complete paintability of the surface. Therefore, it is limited to 1.4% by weight or less, particularly 1.2% by weight or less, preferably 1.0% by weight or less, and more preferably 0.8% by weight or less.

合金元素のBは、特にNと結合したときに焼入れ性に寄与することができ、特に少なくとも0.0002重量%の含有量で存在する。上記合金元素は、含有量が高いと材料特性に悪影響を及ぼし、その結果、材料の硬度及び/又は強度が低下する可能性があるため、0.02重量%以下、特に0.015重量%以下、好ましくは0.01重量%以下、さらに好ましくは0.005重量%以下に制限される。   The alloying element B can contribute to the hardenability, especially when combined with N, and is particularly present in a content of at least 0.0002% by weight. If the content of the above alloying elements is high, the material properties are adversely affected, and as a result, the hardness and / or the strength of the material may be reduced. Therefore, 0.02 wt% or less, particularly 0.015 wt% or less. , Preferably 0.01% by weight or less, and more preferably 0.005% by weight or less.

合金元素のTi及びNbは、結晶粒微細化及び/又はNと結合するために、特にTiが少なくとも0.001重量%及び/又はNbが0.001重量%の含有量で、合金中において個別に又は組み合わせて含まれ得る。例えば完全にNと結合するためには、Tiの含有量は少なくとも3.42*Nで提供される必要があるだろう。上記元素の含有量が高いと材料特性に悪影響を及ぼし、特に材料の強靭性に悪影響を及ぼすため、組み合わせた合金元素は、0.25重量%以下、特に0.2重量%以下、好ましくは0.15重量%以下に制限される。   The alloying elements Ti and Nb are used in the alloy in an amount of at least 0.001% by weight of Ti and / or 0.001% by weight of Nb in order to be finely grained and / or combined with N. Or in combination. For example, in order to be fully N bound, the Ti content would have to be provided at least 3.42 * N. If the content of the above elements is high, the material properties are adversely affected, and particularly, the toughness of the material is adversely affected. Therefore, the combined alloy elements are 0.25% by weight or less, particularly 0.2% by weight or less, preferably 0% by weight or less. It is limited to 0.15% by weight or less.

Mo、V、Cu、Ni、Sn、Ca、Co、N、P又はSは、個別に又は組み合わせて、とりわけこれらの元素が、特定の性質を確立するために合金に含まれる場合でなければ、不純物として見なすことができる合金元素である。含有量は、0.2重量%以下のMo、0.05重量%以下のV、0.2重量%以下のCu、0.2重量%以下のNi、0.05重量%以下のSn、0.01重量%以下のCa、0.02重量%以下のCo、0.01重量%以下のN、0.1重量%以下のP、0.06重量%以下のSに制限される。   Mo, V, Cu, Ni, Sn, Ca, Co, N, P or S, individually or in combination, especially if these elements are not included in the alloy in order to establish specific properties, It is an alloying element that can be regarded as an impurity. Content is 0.2 wt% or less Mo, 0.05 wt% or less V, 0.2 wt% or less Cu, 0.2 wt% or less Ni, 0.05 wt% or less Sn, 0 It is limited to 0.01 wt% or less of Ca, 0.02 wt% or less of Co, 0.01 wt% or less of N, 0.1 wt% or less of P, and 0.06 wt% or less of S.

半仕上げ平鋼製品の1つの形状では、最も単純な実施で、第2層が片面に結合した第1層のみが提供される。第2層の自由表面は、亜鉛ベースの耐食性コーティングでコーティングされていることが好ましく、特に、代替的に又は追加的に第1層の自由表面も亜鉛ベースの耐食性層でコーティングされていることが好ましい。好ましくは、半仕上げ製品は、片面ずつ配設され、完全にかつ凝集力で第1層に結合する2つの第2層を含み、それゆえ、用途に従えば対称又は非対称の構造を有してもよいサンドウィッチ状の材料を提供することが可能である。第2層の両方の自由表面が、好ましくは亜鉛ベースの耐食性コーティングでコーティングされていてもよい。より好ましくは、半仕上げ平鋼製品は実施に従うと、片面又は両面に電気亜鉛コーティングが施されている。電気コーティングの実施には、例えば、特に溶融コーティング作業の実施で起こるような、特に第1層の性質が熱的作用の悪影響を受けないという利点がある。   One form of semi-finished flat steel product, in its simplest implementation, provides only the first layer with the second layer bonded to one side. The free surface of the second layer is preferably coated with a zinc-based corrosion resistant coating, in particular alternatively or additionally the free surface of the first layer is also coated with a zinc-based corrosion resistant layer. preferable. Preferably, the semi-finished product comprises two second layers, arranged one by one, bonded completely and cohesively to the first layer, and therefore has a symmetrical or asymmetrical structure according to the application. It is possible to provide a good sandwich-like material. Both free surfaces of the second layer may be coated with a corrosion resistant coating, preferably based on zinc. More preferably, the semi-finished flat steel product, according to practice, is electrozinc coated on one or both sides. The practice of electrocoating has the advantage that the properties of the first layer in particular are not adversely affected by the thermal action, as occurs, for example, in the practice of melt coating operations.

半仕上げ平鋼製品のさらなる形状では、軟鋼合金の第2層は、半仕上げ平鋼製品の材料における全体の厚みを基準として、2%〜30%、特に5%〜20%、好ましくは7.5%〜12%の材料の厚みを有する。機能層として提供される軟鋼合金は、次のような材料の厚みにならなければならない。第一に、第1層の好ましい性質が本質的に悪影響を受けないように、第2層(片面ごと)の材料の厚みは、半仕上げ製品の材料における全体の厚みを基準として、30%以下、特に20%以下、好ましくは12%以下に制限され、第二に、第1層が確実に半仕上げ平鋼製品の表面から一定の距離を有するために、欠陥を生じさせずにコーティング及び/又は成形が実施可能であるように、第2層(片面ごと)の材料の厚みは、半仕上げ製品の材料における全体の厚みを基準として、少なくとも2%、特に少なくとも5%、好ましくは少なくとも7.5%である。半仕上げ平鋼製品は、0.5〜6.0mm、特に0.8〜4.0mm、好ましくは1.2〜3.0mmの、全体の材料の厚みを有する。   In a further form of the semifinished flat steel product, the second layer of mild steel alloy is 2% to 30%, in particular 5% to 20%, preferably 7.%, based on the total thickness in the material of the semifinished flat steel product. It has a material thickness of 5% to 12%. The mild steel alloy provided as the functional layer must have the following material thicknesses. First, the thickness of the material of the second layer (on each side) is 30% or less, based on the total thickness of the material of the semi-finished product, so that the preferred properties of the first layer are not substantially adversely affected. Limited to 20% or less, preferably 12% or less, and secondly to ensure that the first layer has a certain distance from the surface of the semi-finished flat steel product, the coating and / or coating without defects. Alternatively, the thickness of the material of the second layer (one side) is at least 2%, in particular at least 5%, preferably at least 7.%, based on the total thickness in the material of the semifinished product, so that molding can be carried out. 5%. The semi-finished flat steel product has an overall material thickness of 0.5 to 6.0 mm, in particular 0.8 to 4.0 mm, preferably 1.2 to 3.0 mm.

半仕上げ平鋼製品のさらなる形状では、半仕上げ平鋼製品はクラッディング、特に圧延クラッディングを用いて又は鋳造を用いて製造されている。本発明の半仕上げ平鋼製品は、例えば、ドイツ特許第DE102005006606B3号明細書に開示されるように、好ましくは熱間圧延クラッディングを用いて製造されている。参照によりこの特許明細書の内容が本出願に組み込まれる。あるいは、本発明の半仕上げ平鋼製品は鋳造を用いて製造されてもよく、その場合、その製造の1つの選択肢が特開平3‐133630号公報に開示される。金属複合体の製造は通常、既知の技術である。   In a further form of the semi-finished flat steel product, the semi-finished flat steel product is produced using a cladding, in particular a rolling cladding or using casting. The semi-finished flat steel product according to the invention is preferably manufactured using hot-rolling cladding, as disclosed, for example, in DE 102005006606B3. The contents of this patent specification are incorporated into the present application by reference. Alternatively, the semi-finished flat steel product of the present invention may be produced using casting, in which case one option of its production is disclosed in JP-A-3-133630. The production of metal composites is usually a known technique.

第2の態様では、本発明は、路上走行車構造体、鉄道用車両構造体、造船又は航空機の構成要素を製造するためのプロセスに関し、この場合は本発明の半仕上げ平鋼製品が冷間形成される。本発明の半仕上げ平鋼製品の第2層は、特に良好な変形性を有し、例えば、マイクロアロイ鋼又は2相の合金鋼からなり、変形特性は最適であるため、本発明の半仕上げ平鋼製品は、本質的に亀裂が生じない方法で、従来と同一の組成のマルテンサイト相鋼と比較して、高い曲げ角度を伴って形成することができる。   In a second aspect, the invention relates to a process for manufacturing a road vehicle structure, a railway vehicle structure, a shipbuilding or aircraft component, in which case the semifinished flat steel product of the invention is cold. It is formed. The second layer of the semi-finished flat steel product of the invention has particularly good deformability, for example made of microalloyed steel or two-phase alloy steel, the deformation properties being optimal, so the semi-finished product of the invention The flat steel product can be formed in an essentially crack-free manner with a high bending angle compared to conventional martensitic phase steels of the same composition.

薄鋼板又は鋼板の形態で提供することができる本発明の半仕上げ平鋼製品の冷間形成は、例えば、曲げ加工又はUO成形による非連続プロセスにおいて、好ましくは従来型の成形型において実施することができる。別の方法として好ましくは、例えば、鋼帯の形状での半仕上げ平鋼製品の形成は、好ましくは従来のプロファイル設備上で圧延プロファイルにより費用をかけずに実施することができる。曲げ加工、UO成形又は圧延プロファイルによって、必要条件に従って、異なる断面形状を伴う、開いた又は閉じたプロファイルを製造することが可能である。製造されたプロファイルは、長手方向に一定の断面積又は長手方向に変化する断面積を有してよい。   The cold forming of the semifinished flat steel product according to the invention, which can be provided in the form of sheet steel or sheet steel, is carried out in a discontinuous process, for example by bending or UO forming, preferably in a conventional forming die. You can Alternatively and preferably, the forming of semifinished flat steel products, for example in the form of strips, can be carried out inexpensively, preferably by rolling profiles, on conventional profile equipment. By bending, UO forming or rolling profiles, it is possible to produce open or closed profiles with different cross-sectional shapes according to the requirements. The manufactured profile may have a constant cross-sectional area in the longitudinal direction or a cross-sectional area that varies in the longitudinal direction.

第3の態様では、本発明は本発明の半仕上げ平鋼製品から製造されたプロファイルの使用に関する。プロファイルは、自動車の衝突プロファイルとして、特に、自動車のバッテリーハウジングにおけるプロファイルとして使用することができ又はプロファイルは自動車座席のシートレールとして使用することができる。バッテリーハウジングは、組み立てられた少なくとも1つの底部、4つの壁及び蓋を含み、バッテリーモジュールを収容する役割を持つ。特に、上記の壁は、本発明の半仕上げ平鋼製品から製造されたプロファイルから形成される。バッテリーハウジングは、例えば自動車のフロア領域に、解放可能に車体構造に接着され、衝突の際は、仮に変形するとしても、わずかのみ変形し得る。本発明の半仕上げ平鋼製品は、その高い引張強度及び/又は硬度のために、特にこの用途に好適であり、特に自動車の湿った領域での使用のために、耐食性能を増大させる電気亜鉛コーティングとともに提供される場合に好適である。自動車は好ましくはハイブリッド自動車又は純粋に電気によって駆動される自動車であり、それらの自動車は個人の自動車、実用車又はバスである。   In a third aspect, the invention relates to the use of profiles made from the semi-finished flat steel product of the invention. The profile can be used as a crash profile for a motor vehicle, in particular as a profile in a battery housing of a motor vehicle, or the profile can be used as a seat rail for a motor vehicle seat. The battery housing includes at least one bottom, four walls and a lid that are assembled and serves to house the battery module. In particular, the wall is formed from a profile manufactured from the semi-finished flat steel product of the invention. The battery housing is releasably glued to the car body structure, for example in the floor area of a motor vehicle, and may only slightly deform, if at all, in the event of a collision. The semi-finished flat steel product of the present invention is particularly suitable for this application due to its high tensile strength and / or hardness, and electrolytic zinc which increases corrosion resistance performance, especially for use in wet areas of automobiles. Suitable when provided with a coating. The vehicles are preferably hybrid vehicles or vehicles driven purely by electricity, which vehicles are private vehicles, utility vehicles or buses.

本発明の半仕上げ平鋼製品から製造されたプロファイルはまた、モータービークルの横方向又は縦方向のビームとして、例えばプロファイルとして、特に衝突プロファイルとして、バンパー、ドアの敷居、サイドインパクトビームにおいて又は衝突時にゼロから低い変形性/押し込み性が求められる領域、例えば、バッテリーハウジング、シート機構、車体構造、シャーシ、ルーフ構造において使用されてもよい。   The profiles produced from the semi-finished flat steel products according to the invention are also used as transverse or longitudinal beams of motor vehicles, for example as profiles, in particular as collision profiles, at bumpers, door sills, side impact beams or during collisions. It may be used in areas where zero to low deformability / pushability is required, for example in battery housings, seat mechanisms, body structures, chassis, roof structures.

以下に、実施例に相当する図に関して、本発明の詳細の説明を記載する。   In the following, a detailed description of the invention will be given with respect to the figures corresponding to the examples.

図1は、本発明の半仕上げ平鋼製品の概略断面図を示す。FIG. 1 shows a schematic sectional view of a semi-finished flat steel product of the present invention.

1つの図は、本発明の半仕上げ平鋼製品(1)の概略断面図を示す。本発明の半仕上げ平鋼製品(1)は、合金鋼の第1層(1.1)であって、マルテンサイト微細構造(マルテンサイト相鋼)を有し、1200MPaを超える引張強度及び/又は370HV10を超える硬度、特に1300MPaを超える引張強度及び/又は400HV10を超える硬度、好ましくは1400MPaを超える引張強度及び/又は435HV10を超える硬度、さらに好ましくは1500MPaを超える引張強度及び/又は465HV10を超える硬度、特に好ましくは1600MPaを超える引張強度及び/又は490HV10を超える硬度を有する第1層と、軟鋼合金の第2層(1.2、1.2‘)であって、600MPaより小さい引張強度及び/又は190HV10より小さい硬度、特に550MPaより小さい引張強度及び/又は175HV10より小さい硬度、好ましくは450MPaより小さい引張強度及び/又は140HV10より小さい硬度、より好ましくは380MPaより小さい引張強度及び/又は120HV10より小さい硬度を有し、第1層(1.1)のいずれかの面に、完全にかつ凝集力で結合する第2層と、を含む。用途に従い、かつ最も単純な実施において、1つの第2層(1.2)のみが、第1層(1.1)に完全にかつ凝集力で結合することもまた可能であり、それゆえ第2層(1.2‘)は点線で表される。   One figure shows a schematic cross section of a semi-finished flat steel product (1) according to the invention. The semi-finished flat steel product (1) of the present invention is a first layer (1.1) of alloy steel, has a martensitic microstructure (martensitic phase steel), and has a tensile strength of more than 1200 MPa and / or A hardness of more than 370 HV10, in particular a tensile strength of more than 1300 MPa and / or a hardness of more than 400 HV10, preferably a tensile strength of more than 1400 MPa and / or a hardness of more than 435 HV10, more preferably a tensile strength of more than 1500 MPa and / or a hardness of more than 465 HV10, Particularly preferably, the first layer having a tensile strength of more than 1600 MPa and / or a hardness of more than 490 HV10 and the second layer (1.2, 1.2 ') of a mild steel alloy and having a tensile strength of less than 600 MPa and / or A hardness of less than 190 HV10, in particular less than 550 MPa and / or less than 175 HV10, preferably less than 450 MPa and / or less than 140 HV10, more preferably less than 380 MPa and / or less than 120 HV10. A first layer (1.1), and a second layer that is completely and cohesively bonded to either side of the first layer (1.1). Depending on the application and in the simplest implementation, it is also possible that only one second layer (1.2) is completely and cohesively bonded to the first layer (1.1), and therefore The two layers (1.2 ') are represented by dotted lines.

第1層(1.1)は、Fe及び調製に関連した不可避の不純物に加えて、C:0.15〜0.6重量%、Si:0.05〜0.9重量%、Mn:0.3〜2.0重量%、Al:0.01〜2.0重量%、Cr+Mo:最大1.5重量%、Nb+Ti:最大0.2重量%、B:最大0.02重量%、V:最大0.25重量%、Cu:最大0.2重量%、Ni:最大0.3重量%、Sn:最大0.05重量%、Ca:最大0.01重量%、As:最大0.02重量%、N:最大0.01重量%、P:最大0.06重量%、S:最大0.03重量%からなる。第2層(1.2、1.2‘)は、Fe及び調製に関連した不可避の不純物に加えて、C:最大0.2重量%、Si:0.01〜0.6重量%、Mn:0.1〜2.5重量%、Al:0.01〜2.0重量%、Cr+Mo:最大1.4重量%、Nb+Ti:最大0.25重量%、B:最大0.02重量%、V:最大0.05重量%、Cu:最大0.2重量%、Ni:最大0.2重量%、Sn:最大0.05重量%、Ca:最大0.01重量%、Co:最大0.02重量%、N:最大0.01重量%、P:最大0.1重量%、S:最大0.06重量%からなり、これらの層は好ましくはマイクロアロイ鋼から形成される。   The first layer (1.1) comprises, in addition to Fe and unavoidable impurities related to the preparation, C: 0.15-0.6% by weight, Si: 0.05-0.9% by weight, Mn: 0. 0.3 to 2.0% by weight, Al: 0.01 to 2.0% by weight, Cr + Mo: maximum 1.5% by weight, Nb + Ti: maximum 0.2% by weight, B: maximum 0.02% by weight, V: Maximum 0.25% by weight, Cu: maximum 0.2% by weight, Ni: maximum 0.3% by weight, Sn: maximum 0.05% by weight, Ca: maximum 0.01% by weight, As: maximum 0.02% by weight. %, N: maximum 0.01% by weight, P: maximum 0.06% by weight, S: maximum 0.03% by weight. The second layer (1.2, 1.2 ') contains, in addition to Fe and unavoidable impurities related to the preparation, C: max. 0.2% by weight, Si: 0.01-0.6% by weight, Mn. : 0.1 to 2.5% by weight, Al: 0.01 to 2.0% by weight, Cr + Mo: maximum 1.4% by weight, Nb + Ti: maximum 0.25% by weight, B: maximum 0.02% by weight, V: 0.05% by weight maximum, Cu: 0.2% by weight maximum, Ni: 0.2% by weight maximum, Sn: 0.05% by weight maximum, Ca: 0.01% by weight maximum, Co: 0.1% by weight maximum. 02% by weight, N: up to 0.01% by weight, P: up to 0.1% by weight, S: up to 0.06% by weight, these layers preferably being formed from microalloy steel.

第2層(1.2、1.2‘)の、特に片面ごとの材料の厚みは、第1層(1.1)の好ましい性質が本質的に悪影響を受けないような厚みであり、第2層(片面ごと)の材料の厚みは、半仕上げ平鋼製品(1)の材料における全体の厚みを基準として、少なくとも2%かつ最大30%、好ましくは少なくとも7.5%かつ最大12%であり、半仕上げ平鋼製品(1)は例えば、0.5〜6mmの材料全体の厚みを有してよい。第2層(1.2、1.2‘)は、半仕上げ平鋼製品の第1層(1.1)と比較してコーティングに好適であるため、第2層は自由表面に亜鉛ベースの耐食性コーティング、好ましくはいずれの表面にも電気亜鉛コーティング(1.3、1.3‘)を有する。コーティング(1.3‘)は、例えば半仕上げ平鋼製品(1)の最も単純な実施形態では、すでに上記に記載されるように、第2層(1.2‘)の不存在下では同様に存在しないため点線で表される。   The thickness of the material of the second layer (1.2, 1.2 '), in particular per side, is such that the preferred properties of the first layer (1.1) are not essentially adversely affected, The thickness of the material of the two layers (each side) is at least 2% and at most 30%, preferably at least 7.5% and at most 12%, based on the total thickness of the material of the semi-finished flat steel product (1). Yes, the semi-finished flat steel product (1) may have a total material thickness of, for example, 0.5-6 mm. The second layer (1.2, 1.2 ') is suitable for coating compared to the first layer (1.1) of semi-finished flat steel products, so that the second layer is zinc-based on the free surface. It has a corrosion resistant coating, preferably an electrozinc coating (1.3, 1.3 ') on either surface. The coating (1.3 ') is similar in the absence of the second layer (1.2'), as already described above, for example in the simplest embodiment of the semi-finished flat steel product (1). It is represented by a dotted line because it does not exist.

本発明は、図面に示される実施例及び一般的に説明される実施に限定されず、むしろ、本発明の半仕上げ平鋼製品はまた、テーラード製品、例えば、テーラードブランク及び/又はテーラードロールブランクから形成されてもよい。   The present invention is not limited to the embodiments shown in the drawings and the generally described implementations, but rather the semi-finished flat steel products of the present invention can also be made from tailored products, such as tailored blanks and / or tailored roll blanks. It may be formed.

Claims (9)

1200MPaを超える引張強度及び/又は370HV10を超える硬度を有するマルテンサイト鋼合金の第1層(1.1)と、600MPaより小さい引張強度及び/又は190HV10より小さい硬度を有し、前記第1層(1.1)に完全にかつ凝集力で結合する、少なくとも1つの軟鋼合金の第2層(1.2、1.2‘)と、を含み、
前記第1層(1.1)が、Fe及び調製に関連した不可避の不純物とともに、C:0.15〜0.6重量%、Si:0.05〜0.9重量%、Mn:0.3〜2.0重量%、Al:0.01〜2.0重量%、Cr+Mo:最大1.5重量%、Nb+Ti:最大0.2重量%、B:最大0.02重量%、V:最大0.25重量%、Cu:最大0.2重量%、Ni:最大0.3重量%、Sn:最大0.05重量%、Ca:最大0.01重量%、As:最大0.02重量%、N:最大0.01重量%、P:最大0.06重量%、S:最大0.03重量%からなり、
前記第2層(1.2、1.2‘)が、Fe及び調製に関連した不可避の不純物とともに、C:最大0.2重量%、Si:0.01〜0.6重量%、Mn:0.1〜2.5重量%、Al:0.01〜2.0重量%、Cr+Mo:最大1.4重量%、Nb+Ti:最大0.25重量%、B:最大0.02重量%、V:最大0.05重量%、Cu:最大0.2重量%、Ni:最大0.2重量%、Sn:最大0.05重量%、Ca:最大0.01重量%、Co:最大0.02重量%、N:最大0.01重量%、P:最大0.1重量%、S:最大0.06重量%からなる、半仕上げ平鋼製品(1)。
A first layer (1.1) of martensitic steel alloy having a tensile strength of more than 1200 MPa and / or a hardness of more than 370 HV10, and a first layer (1.1) having a tensile strength of less than 600 MPa and / or a hardness of less than 190 HV10. 1.1) a second layer (1.2, 1.2 ') of at least one mild steel alloy, which is completely and cohesively bonded.
The first layer (1.1), together with Fe and inevitable impurities related to the preparation, contained C: 0.15 to 0.6% by weight, Si: 0.05 to 0.9% by weight, Mn: 0. 3 to 2.0% by weight, Al: 0.01 to 2.0% by weight, Cr + Mo: maximum 1.5% by weight, Nb + Ti: maximum 0.2% by weight, B: maximum 0.02% by weight, V: maximum 0.25% by weight, Cu: maximum 0.2% by weight, Ni: maximum 0.3% by weight, Sn: maximum 0.05% by weight, Ca: maximum 0.01% by weight, As: maximum 0.02% by weight , N: maximum 0.01% by weight, P: maximum 0.06% by weight, S: maximum 0.03% by weight,
The second layer (1.2, 1.2 '), together with Fe and inevitable preparation-related impurities, C: max. 0.2% by weight, Si: 0.01-0.6% by weight, Mn: 0.1-2.5% by weight, Al: 0.01-2.0% by weight, Cr + Mo: maximum 1.4% by weight, Nb + Ti: maximum 0.25% by weight, B: maximum 0.02% by weight, V : Max 0.05 wt%, Cu: Max 0.2 wt%, Ni: Max 0.2 wt%, Sn: Max 0.05 wt%, Ca: Max 0.01 wt%, Co: Max 0.02 Semi-finished flat steel product (1) consisting of wt%, N: 0.01 wt% maximum, P: 0.1 wt% max, and S: 0.06 wt% max.
前記第1層(1.1)のいずれかの面に配置され該第1層に完全にかつ凝集力で結合する、2つの層(1.2、1.2‘)を有することを特徴とする、請求項1に記載の半仕上げ平鋼製品。   Characterized in that it comprises two layers (1.2, 1.2 ') arranged on either side of said first layer (1.1) and bonded to said first layer completely and cohesively. The semi-finished flat steel product according to claim 1. 前記第2層(1.2、1.2‘)が、前記半仕上げ平鋼製品の全材料の厚みを基準として、2%〜30%、特に5%〜20%の材料の厚みを有することを特徴とする、請求項1又は請求項2に記載の半仕上げ平鋼製品。   The second layer (1.2, 1.2 ') has a material thickness of 2% to 30%, especially 5% to 20%, based on the total material thickness of the semi-finished flat steel product. The semi-finished flat steel product according to claim 1 or 2, characterized in that. 電解により適用された亜鉛コーティング(1.3、1.3‘)を有することを特徴とする、請求項1から請求項3のいずれかに記載の半仕上げ平鋼製品。   Semi-finished flat steel product according to any of claims 1 to 3, characterized in that it has an electrolytically applied zinc coating (1.3, 1.3 '). クラッディングを用いて又は鋳造を用いて製造されることを特徴とする、請求項1から請求項4のいずれかに記載の半仕上げ平鋼製品。   Semi-finished flat steel product according to any of claims 1 to 4, characterized in that it is manufactured using cladding or using casting. 路上走行車構造体、鉄道用車両構造体、造船又は航空機の構成要素を製造するためのプロセスであって、請求項1から請求項5のいずれかに記載の半仕上げ平鋼製品が冷間形成される、プロセス。   A process for manufacturing a road vehicle structure, a railway vehicle structure, a shipbuilding or an aircraft component, wherein the semi-finished flat steel product according to any one of claims 1 to 5 is cold formed. Be a process. 冷間形成作業が、プロファイルを製造するための曲げ加工、UO成形又は圧延プロファイルによって実施されることを特徴とする、請求項6に記載のプロセス。   Process according to claim 6, characterized in that the cold forming operation is carried out by bending, UO forming or rolling profiles to produce the profile. 衝突プロファイルとして、特に自動車のバッテリーハウジングのプロファイルとして、請求項7に従って製造されるプロファイルの使用。   Use of a profile manufactured according to claim 7 as a collision profile, in particular as a profile of an automobile battery housing. 自動車座席のシートレールとして、請求項7に従って製造されるプロファイルの使用。   Use of a profile manufactured according to claim 7 as a seat rail of a motor vehicle seat.
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