JP2020171719A - Washing towel cloth - Google Patents

Washing towel cloth Download PDF

Info

Publication number
JP2020171719A
JP2020171719A JP2020105736A JP2020105736A JP2020171719A JP 2020171719 A JP2020171719 A JP 2020171719A JP 2020105736 A JP2020105736 A JP 2020105736A JP 2020105736 A JP2020105736 A JP 2020105736A JP 2020171719 A JP2020171719 A JP 2020171719A
Authority
JP
Japan
Prior art keywords
yarn
washing
fabric
towel cloth
decitex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2020105736A
Other languages
Japanese (ja)
Other versions
JP7164214B2 (en
Inventor
正司 伊澤
Seiji Izawa
正司 伊澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Izawa Towel Co Ltd
Original Assignee
Izawa Towel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Izawa Towel Co Ltd filed Critical Izawa Towel Co Ltd
Priority to JP2020105736A priority Critical patent/JP7164214B2/en
Publication of JP2020171719A publication Critical patent/JP2020171719A/en
Application granted granted Critical
Publication of JP7164214B2 publication Critical patent/JP7164214B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Body Washing Hand Wipes And Brushes (AREA)
  • Woven Fabrics (AREA)

Abstract

To provide a washing towel cloth which has a soft texture because a cloth surface is smooth, which makes a soap lather up well, which makes even a tiny stain washed out efficiently, and which is excellent in draining property and quick-drying property.SOLUTION: A washing towel cloth is made of a napped cloth in which cut pile yarn is composed of synthetic fiber filament yarn with at least a total fineness of 10-500 dtex and a single fiber fineness of 0.1-10 dtex.SELECTED DRAWING: Figure 1

Description

本発明は、洗浄タオル地に関わり、より詳しくは、織物の表面が滑らかでソフトな風合いを持ち、泡立ちが良く、細部の汚れまでも効率よく落とし、且つ水切り性、速乾性に優れた洗浄タオル地に関する。 The present invention relates to a washing towel cloth, and more particularly, to a washing towel cloth having a smooth and soft texture on the surface of a woven fabric, having good foaming, efficiently removing even fine stains, and having excellent drainage and quick-drying properties. ..

近年、新型コロナウィルス感染症(COVID−19)やインフルエンザ等に対する感染リスクを軽減する目的で手洗いの励行が推奨されている。一般に洗剤を使って素手で手洗いする方法は指や爪の間の汚れはなかなか落ちずに時間がかかる。また、スポンジを使う方法は泡立ちが良くて使い易い反面、スポンジでは指や爪の細かい所まで洗えない。また、破れ易いという欠点がある。綿100%のタオルは風合いが硬く、また、表面がループパイル糸であり、洗ったときに毛倒れして同様に細かい汚れまで洗えない。また、洗濯した後は水切れが悪く、乾燥が遅い。 In recent years, it has been recommended to wash hands for the purpose of reducing the risk of infection with the new coronavirus infection (COVID-19) and influenza. In general, the method of washing hands with bare hands using detergent does not easily remove dirt between fingers and nails and takes time. Also, while the method using a sponge has good foaming and is easy to use, the sponge cannot wash even the finest parts of fingers and nails. It also has the drawback of being easily torn. The 100% cotton towel has a hard texture, and the surface is a loop pile yarn, so when it is washed, the hair falls down and even fine stains cannot be washed. In addition, after washing, the drainage is poor and the drying is slow.

かかる課題に対して、ループパイル糸構造を有するタオル地であり、ループパイル長はベース部から0.3〜10mmであり、かつループパイル糸および/または地糸中に0.7デニール〜0.00001デニールの超極細合成繊維を少なくともタオル地全重量に対し5重量%以上含んでなることを特徴とするタオル地に関する公報開示の技術が存在する(特許文献1)。 To solve this problem, it is a towel cloth having a loop pile yarn structure, the loop pile length is 0.3 to 10 mm from the base portion, and 0.7 denier to 0.00001 in the loop pile yarn and / or the ground yarn. There is a technique for disclosing a publication regarding a towel cloth, which comprises at least 5% by weight or more of denyl ultrafine synthetic fiber with respect to the total weight of the towel cloth (Patent Document 1).

また、良好な泡立ち性と触感を併せもち、かつ軽量,乾燥性に優れ、敏感肌の人にも適合できるボディタオル,洗顔パフ,介護手袋などの洗浄用製品に好適な布帛を提供することを課題として、グランド糸に繊度10〜150dtexの合成繊維を用い、地組織緯糸挿入糸に合成繊維フィラメントを芯糸とし、天然繊維の大ループと合成繊維の小ループの少なくとも大小2種のループ(花糸)を含み有するブークレ糸を用いて布帛を構成し、天然繊維の大ループのみが肌面に触れ合成繊維の小ループがその根元に位置して泡立ち性を良好ならしめるようにした公報開示の技術が存在する(特許文献2)。 In addition, we hope to provide fabrics suitable for cleaning products such as body towels, face wash puffs, and nursing gloves, which have good foaming and tactile sensations, are lightweight, and have excellent dryness, and are suitable for people with sensitive skin. As a task, synthetic fibers with a fineness of 10 to 150 dtex are used for the ground yarn, synthetic fiber filaments are used as the core yarn for the ground structure weft insertion yarn, and at least two types of loops (flowers), a large loop of natural fiber and a small loop of synthetic fiber, are used. The woven fabric is made of bouclé yarn containing (thread), and only the large loops of natural fibers touch the skin surface, and the small loops of synthetic fibers are located at the roots of the fabrics to improve foaming properties. Technology exists (Patent Document 2).

更に、優れた泡立ち性、汚れ落ち性及び乾燥性を具備し、ボディタオル等に好適な洗浄用布帛及びその洗浄用布帛を用いて形成した洗浄用タオルを提供することを課題として、浴用ボディタオルに使用する洗浄用布帛が経糸と緯糸により編成した基布からなり、経糸と緯糸の交点間に洗浄用の柄糸5を弛みを持たせてラウンド状に編成し、柄糸が0.9デシテックスの単繊維からなる極細繊維と柄糸繊維を混成した混成繊維を3本、撚成して構成され、柄糸の極細繊維の撚り回数が4回/インチであり、柄糸繊維には、2dtexの繊度のポリ乳酸繊維からなり、繊度が150dtexの撚糸を使用し、極細繊維が柄糸繊維に対して60%混成させる公報開示の技術が存在する(特許文献3)。 Further, it is an object of the present invention to provide a cleaning cloth having excellent foaming property, stain removing property and drying property, which is suitable for a body towel or the like, and a cleaning cloth formed by using the cleaning cloth, and a bath body towel. The cleaning cloth used in is composed of a base cloth knitted with warp and weft, and the pattern thread 5 for cleaning is knitted in a round shape with a slack between the intersections of the warp and the weft, and the pattern thread is 0.9 decitex. It is composed of three mixed fibers, which are a mixture of ultrafine fibers made of single fibers and pattern yarn fibers, twisted, and the number of twists of the ultrafine fibers of the pattern yarn is 4 times / inch, and the pattern yarn fibers have 2dtex. There is a technique disclosed in Gazette Disclosure that uses twisted yarn having a fineness of 150 dtex and mixing 60% of ultrafine fibers with stalk fibers (Patent Document 3).

更にまた、超極細繊維を表面に有する靴みがき用具に関する公報開示の技術が存在する(特許文献4)。 Furthermore, there is a technique for disclosing a publication regarding a shoe polishing tool having ultrafine fibers on the surface (Patent Document 4).

更にまた、単繊維デニールが1.0以下の極細合成繊維を40重量%以上含有する起毛布帛に、親水加工を施して得られる吸水性起毛布帛に関する公報開示の技術が存在する(特許文献5)。 Furthermore, there is a technique for disclosing a publication regarding a water-absorbent brushed fabric obtained by subjecting a brushed fabric containing 40% by weight or more of ultrafine synthetic fibers having a single fiber denier of 1.0 or less to a hydrophilic treatment (Patent Document 5). ..

更にまた、加工工程負荷の低減、生地への有害物質残存による皮膚障害その他諸問題を改善すると共に、ソフト風合いや拭取性、コンパクトな収納性に優れたワイピングクロス、めがね拭き、フェイスタオル等に代表される生活繊維資材に好適な布帛の提供することを課題として、単繊維繊度が0.2〜0.5デシテックスのポリエステルマルチフィラメント糸を80重量%以上使用してなる繊維資材であり、アルカリ減量率が5%以下、パージ・トラップ法によるガスクロマトグラフ質量分析法にて検出される有機溶剤成分が0.05ppm未満であるポリエステル極細繊維よりなる繊維資材に関する公報開示の技術が存在する(特許文献6)。 Furthermore, it reduces the load on the processing process, improves skin disorders and other problems caused by residual harmful substances on the fabric, and is used for wiping cloths, eyeglass wipes, face towels, etc., which have excellent soft texture, wiping properties, and compact storability. It is a fiber material made by using 80% by weight or more of polyester multifilament yarn having a single fiber fineness of 0.2 to 0.5 decitex, with an object of providing a cloth suitable for a typical daily fiber material, and is alkaline. There is a technique for disclosing a publication regarding a fiber material made of polyester ultrafine fibers having a weight loss rate of 5% or less and an organic solvent component detected by a gas chromatograph mass analysis method by a purge trap method of less than 0.05 ppm (Patent Documents). 6).

特開平3−27149号公報Japanese Unexamined Patent Publication No. 3-27149 特開2004−337380号公報Japanese Unexamined Patent Publication No. 2004-337380 特開2012−70954号公報Japanese Unexamined Patent Publication No. 2012-70954 特開平2−299628号公報Japanese Unexamined Patent Publication No. 2-299628 特開昭59−1772号公報JP-A-59-1772 特開2005−179846号公報Japanese Unexamined Patent Publication No. 2005-179846

Yahoo、[体毛の太さ]の検索、画像Yahoo, [hair thickness] search, images

ところで、細かい汚れ落ちについて毛穴のサイズを調べた結果、日本人の体毛の太さが15〜17μmと言われている(非特許文献1)。この体毛の太さ(直径)を毛穴の直径と同一と仮定し、この毛穴に入るポリエステルマルチフィラメント糸の単繊維繊度を試算すると、2.4〜2.8デシテックスの単繊維繊度に相当する。つまり、毛穴の汚れを落とすにはこの程度の糸の細さが好適である。 By the way, as a result of investigating the size of pores for fine dirt removal, it is said that the thickness of Japanese body hair is 15 to 17 μm (Non-Patent Document 1). Assuming that the thickness (diameter) of the body hair is the same as the diameter of the pores, the single fiber fineness of the polyester multifilament yarn entering the pores is estimated to correspond to the single fiber fineness of 2.4 to 2.8 decitex. That is, this level of fineness of thread is suitable for removing dirt from pores.

しかし、ループパイル糸構造を有し、ループパイル長がベース部から0.3〜10mmであり、かつループパイル糸および/または地糸中に0.7デニール〜0.00001デニールの超極細合成繊維を少なくともタオル地全重量に対し5重量%以上含むタオル地に係る発明は、綿糸に替えて極細の合成繊維を用い、洗浄性、吸水性、乾燥性等を改善したものであるが、織物構造は従来の綿タオルと同様のループパイル織物、布帛であり、かかる織物のパイル糸は洗ったときに毛倒れして全体の汚れのみならず、特に細かい汚れは効率よく洗えない、という課題があった。 However, it has a loop pile yarn structure, a loop pile length of 0.3 to 10 mm from the base, and an ultrafine synthetic fiber of 0.7 denier to 0.00001 denier in the loop pile yarn and / or the ground yarn. The invention relating to a towel cloth containing at least 5% by weight based on the total weight of the towel cloth is to use ultrafine synthetic fibers instead of cotton threads to improve cleanability, water absorption, dryness, etc. It is a loop pile woven fabric and cloth similar to the cotton towel of the above, and there is a problem that the pile yarn of such a woven fabric falls down when washed and not only the whole stain but also particularly fine stain cannot be washed efficiently.

また、グランド糸に繊度10〜150dtexの合成繊維を用い、地組織緯糸挿入糸に合成繊維フィラメントを芯糸とし、天然繊維の大ループと合成繊維の小ループの少なくとも大小2種のループ(花糸)を含み有するブークレ糸を用いて布帛を構成し、天然繊維の大ループのみが肌面に触れ合成繊維の小ループがその根元に位置して泡立ち性を良好ならしめるようにした洗浄用布帛に係る発明も、綿糸に替えて極細の合成繊維を用い、洗浄性、吸水性、乾燥性等を改善したものであるが、織物構造は従来の綿タオルと同様のループパイル織物、布帛であり、かかる織物のパイル糸は洗ったときに毛倒れして全体の汚れのみならず、特に細かい汚れは効率よく洗えない、という課題があった。 In addition, synthetic fibers with a fineness of 10 to 150 dtex are used for the ground yarn, and synthetic fiber filaments are used as the core yarn for the ground weaving yarn insertion yarn, and at least two types of loops (flower yarn), a large loop of natural fiber and a small loop of synthetic fiber, are used. ) Is used to compose the fabric, and only the large loops of natural fibers touch the skin surface, and the small loops of synthetic fibers are located at the roots of the fabric to improve the foaming property. The present invention also uses ultrafine synthetic fibers instead of cotton threads to improve cleanability, water absorption, dryness, etc., but the woven structure is a loop pile woven fabric and fabric similar to conventional cotton towels. There is a problem that the pile yarn of such a woven fabric falls down when washed and not only the entire stain but also particularly fine stain cannot be washed efficiently.

更に、浴用ボディタオルに使用する洗浄用布帛が経糸と緯糸により編成した基布からなり、経糸と緯糸の交点間に洗浄用の柄糸5を弛みを持たせてラウンド状に編成し、柄糸が0.9デシテックスの単繊維からなる極細繊維と柄糸繊維を混成した混成繊維を3本、撚成して構成され、柄糸の極細繊維の撚り回数が4回/インチであり、柄糸繊維には、2dtexの繊度のポリ乳酸繊維からなり、繊度が150dtexの撚糸を使用し、極細繊維が柄糸繊維に対して60%混成させる、洗浄用布帛を用いた洗浄用タオルに係る発明も、綿糸に替えて極細の合成繊維を用い、洗浄性、吸水性、乾燥性等を改善したものであるが、織物構造は従来の綿タオルと同様のループパイル織物、布帛であり、かかる織物のパイル糸は洗ったときに毛倒れして全体の汚れのみならず、特に細かい汚れは効率よく洗えない、という課題があった。 Further, the cleaning cloth used for the bath body towel is composed of a base cloth knitted with warp threads and weft threads, and the pattern thread 5 for cleaning is knitted in a round shape with a slack between the intersections of the warp threads and the weft threads. It is composed of three mixed fibers, which are a mixture of ultrafine fibers made of 0.9 decitex single fibers and pattern yarn fibers, twisted, and the number of twists of the ultrafine fibers of the pattern yarn is 4 times / inch. There is also an invention relating to a cleaning towel using a cleaning cloth, which is composed of a polylactic acid fiber having a fineness of 2 dtex, a twisted yarn having a fineness of 150 dtex is used, and the ultrafine fiber is mixed with the pattern yarn fiber by 60%. , Ultra-fine synthetic fiber is used instead of cotton thread to improve cleanability, water absorption, dryness, etc., but the woven structure is the same loop pile woven fabric and cloth as the conventional cotton towel, and the woven fabric has the same structure. There was a problem that the pile yarn fell down when washed and not only the entire stain but also fine stains could not be washed efficiently.

更にまた、靴みがき用具に係る発明は、極細繊維を用いたものであるが汚れを効率よく洗浄する方法としては十分ではなかった。 Furthermore, although the invention relating to the shoe polishing tool uses ultrafine fibers, it is not sufficient as a method for efficiently cleaning dirt.

更にまた、単繊維デニールが1.0以下の極細合成繊維を40重量%以上含有する起毛布帛に、親水加工を施して得られる吸水性起毛布帛に係る技術も、極細繊維を用いたものであるが汚れを効率よく洗浄する方法としては十分ではなかった。 Furthermore, a technique relating to a water-absorbent brushed fabric obtained by subjecting a brushed fabric containing 40% by weight or more of ultrafine synthetic fibers having a single fiber denier of 1.0 or less to a hydrophilic treatment also uses ultrafine fibers. However, it was not sufficient as a method for efficiently cleaning dirt.

更にまた、単繊維繊度が0.2〜0.5デシテックスのポリエステルマルチフィラメント糸を80重量%以上使用してなる繊維資材であり、アルカリ減量率が5%以下、パージ・トラップ法によるガスクロマトグラフ質量分析法にて検出される有機溶剤成分が0.05ppm未満であるポリエステル極細繊維よりなる繊維資材の技術は、加工工程負荷の低減、生地への有害物質残存による皮膚障害その他諸問題を改善すると共に、ソフト風合いや拭取性、コンパクトな収納性に優れたワイピングクロス、めがね拭き、フェイスタオル等に代表される生活繊維資材に好適な布帛の提供することを目的とするものの、極細繊維を用いたものであるが汚れを効率よく洗浄する方法としては十分ではなかった。 Furthermore, it is a fiber material made of 80% by weight or more of polyester multifilament yarn having a single fiber fineness of 0.2 to 0.5 decitex, an alkali weight loss rate of 5% or less, and a gas chromatograph mass by the purge trap method. The technology of fiber materials made of polyester ultrafine fibers with an organic solvent component of less than 0.05 ppm detected by the analysis method reduces the processing load, improves skin disorders due to residual harmful substances on the fabric, and other problems. Although the purpose is to provide a cloth suitable for daily fiber materials such as wiping cloths, eyeglass wipes, face towels, etc., which are excellent in soft texture, wiping property, and compact storability, ultrafine fibers are used. However, it was not sufficient as a method for efficiently cleaning dirt.

本発明では、上記課題を解決し、織物の表面が滑らかでソフトな風合いを持ち、泡立ちが良く、細部の汚れまでも効率よく落とし、且つ水切り性、速乾性に優れた洗浄タオル地を提供することを目的とする。 The present invention solves the above problems and provides a washing towel cloth having a smooth and soft texture on the surface of a woven fabric, having good foaming, efficiently removing even fine stains, and having excellent drainage and quick-drying properties. With the goal.

上記課題を解決するために、請求項1に記載の洗浄タオル地は、
カットパイル糸が少なくとも総繊度10〜500デシテックス、単繊維繊度が0.1〜10デシテックスの合成繊維フィラメント糸で構成された立毛織物で構成される、ことを特徴とする。
In order to solve the above problem, the washing towel cloth according to claim 1 is used.
The cut pile yarn is characterized by being composed of a napped fabric composed of synthetic fiber filament yarn having a total fineness of at least 10 to 500 decitex and a single fiber fineness of 0.1 to 10 decitex.

請求項2に記載の洗浄タオル地は、請求項1に記載の洗浄タオル地において、
前記合成繊維フィラメント糸は、ポリエステル系繊維であることが好ましい。
The washing towel cloth according to claim 2 is the washing towel cloth according to claim 1.
The synthetic fiber filament yarn is preferably a polyester fiber.

請求項3に記載の洗浄タオル地は、請求項1又は2に記載の洗浄タオル地において、
前記立毛織物は、前記合成繊維フィラメント糸を少なくとも30重量%以上含むことが好ましい。
The washing towel cloth according to claim 3 is the washing towel cloth according to claim 1 or 2.
The fluffy fabric preferably contains at least 30% by weight of the synthetic fiber filament yarn.

請求項4に記載の洗浄タオル地は、請求項1乃至3のいずれか1項に記載の洗浄タオル地において、
前記立毛織物は、タテパイル織物であることが好ましい。
The washing towel cloth according to claim 4 is the washing towel cloth according to any one of claims 1 to 3.
The fluffy fabric is preferably a vertical pile fabric.

請求項5に記載の洗浄タオル地は、請求項1乃至4のいずれか1項に記載の洗浄タオル地において、
前記立毛織物のカットパイル糸のカットパイル長は、0.5〜10mmであることが好ましい。
The washing towel cloth according to claim 5 is the washing towel cloth according to any one of claims 1 to 4.
The cut pile length of the cut pile yarn of the fluffy fabric is preferably 0.5 to 10 mm.

請求項6に記載の洗浄タオル地は、請求項1乃至5のいずれか1項に記載の洗浄タオル地において、
前記立毛織物の目付は、50〜500g/mであることが好ましい。
The washing towel cloth according to claim 6 is the washing towel cloth according to any one of claims 1 to 5.
The basis weight of the woolen fabric is preferably 50 to 500 g / m 2 .

請求項7に記載の洗浄タオル地は、請求項1乃至6のいずれか1項に記載の洗浄タオル地において、
用途が手洗い用であることが好ましい。
The washing towel cloth according to claim 7 is the washing towel cloth according to any one of claims 1 to 6.
It is preferably used for hand washing.

本発明によれば、織物の表面が滑らかでソフトな風合いを持ち、泡立ちが良く、細部の汚れまでも効率よく落とし、且つ水切り性、速乾性に優れた洗浄タオル地を提供できる。 According to the present invention, it is possible to provide a washing towel cloth having a smooth and soft texture on the surface of a woven fabric, having good foaming, efficiently removing even fine stains, and having excellent drainage and quick-drying properties.

立毛織物の一例としてのタテパイル織物の断面図である。It is sectional drawing of the vertical pile fabric as an example of a fluffy fabric. 図1に示されたタテパイル織物の構造を示す拡大図である。It is an enlarged view which shows the structure of the vertical pile woven fabric shown in FIG.

以下、本発明の一実施形態に係る洗浄タオル地を詳細に説明する。図1は、立毛織物の一例としてのタテパイル織物の断面図であり、図2は、図1に示されたタテパイル織物の構造を示す拡大図である。図1中の1はカットパイル糸、2は地糸である。地糸はウラ面であり平坦な面である。なお、2の地糸は1のカットパイル糸を強固に把持しており、立毛の直立性及び毛倒れを防止している。また、図2中の1はカットパイル糸、2−1はタテ糸地糸、2−2はヨコ糸地糸である。 Hereinafter, the washing towel cloth according to the embodiment of the present invention will be described in detail. FIG. 1 is a cross-sectional view of a vertical pile fabric as an example of a fluffy fabric, and FIG. 2 is an enlarged view showing a structure of the vertical pile fabric shown in FIG. In FIG. 1, 1 is a cut pile yarn and 2 is a ground yarn. The ground thread is a back surface and a flat surface. It should be noted that the ground yarn of 2 firmly grips the cut pile yarn of 1, and prevents the uprightness of the standing hair and the falling of the hair. Further, in FIG. 2, 1 is a cut pile yarn, 2-1 is a warp yarn, and 2-2 is a weft yarn.

本実施形態は、合成繊維マルチフィラメント糸の極細繊維で構成された三次元構造の立毛織物である。これを手洗いタオルとして使用した場合を手洗い手順に沿って効果を説明する。まず、生地がソフトなので、手洗い時に肌によくなじみ、全体の汚れをまんべんなく落とす。また、立毛が密集しているので、抱水性が高いため泡立ちが良く、洗剤の表面張力で汚れを浮かび上がらせる。次いで手を洗った時に立毛している極細フィラメント糸が、柔らかなブラシ効果が発揮されて毛穴や爪先までの細かな汚れを落とす(ミクロブラッシング効果)。洗った後は織物の立毛の先端から水滴がしたたり落ちるので、水切り性が良い。これを繊維表面積の高い極細繊維で、且つ疎水性を有する合成繊維を用いることで速乾性が一層高まり、清潔感も得られる。 The present embodiment is a fluffy fabric having a three-dimensional structure composed of ultrafine fibers of synthetic fiber multifilament yarn. The effect of using this as a hand-washing towel will be explained according to the hand-washing procedure. First of all, since the fabric is soft, it fits well on the skin when washing hands and removes all dirt evenly. In addition, since the naps are densely packed, the water holding property is high, so that the foaming is good, and the surface tension of the detergent makes the dirt stand out. Next, when you wash your hands, the extra-fine filament yarn that is fluffy exerts a soft brush effect and removes fine dirt to the pores and toes (micro brushing effect). After washing, water droplets dripping from the tips of the naps of the woven fabric, so drainage is good. By using an ultrafine fiber having a high fiber surface area and a synthetic fiber having hydrophobicity, quick-drying property is further enhanced and a feeling of cleanliness can be obtained.

ここで、本実施形態で言う「立毛織物」は、糸(毛)が直立している織物であれば特に限定するものではないが、タテパイル織物(通称ベルベット)、ヨコパイル織物(通称別珍)等が挙げられる。タテパイル織物とは図1(後述)のように、タテ糸のパイルをカットした立毛密度の高い立毛織物である。ヨコパイル織物とはヨコ糸のパイルをカットした立毛織物で立毛密度はやや低い。本実施形態はソフトな風合いで、立毛密度が高く、毛倒れしにくく、汚れを効率的に落とすことから、タテパイル織物が特に好ましい。 Here, the "standing woolen fabric" referred to in the present embodiment is not particularly limited as long as it is a woven fabric in which threads (hairs) are upright, but vertical pile fabrics (commonly known as velvet), horizontal pile fabrics (commonly known as velveteen), and the like are used. Can be mentioned. As shown in FIG. 1 (described later), the vertical pile fabric is a fluff fabric having a high nap density by cutting the pile of the warp yarn. The weft pile fabric is a fluffy fabric in which the pile of weft yarn is cut, and the nap density is rather low. In this embodiment, a vertical pile fabric is particularly preferable because it has a soft texture, a high nap density, is hard to fall down, and efficiently removes stains.

(製造方法)
タテ二重組織織物を、製織時に織物の中層に両外層を接合しているパイル糸(タテ糸)をナイフ刃でカットする。カットされると織物の中層からスライスされ、めくられるように開かれて、2枚の織物が得られる。この2枚の織物はそれぞれオモテ面にパイルがカットされた立毛面を有する(図1)。立毛されたカットパイル糸Aをタテ糸地糸Bとヨコ糸地糸Cで強固に把持しており、着用での糸抜けを防止している(図2)。洗浄タオル地として風合い、汚れ落とし性として好ましい織物形態をなしている。このように本実施形態でいう立毛織物は、通常の両面が平面な織物とは全く異なる、特徴ある三次元立体構造織物であり、洗浄タオル地として極めて好ましい織物形態をなしている。
(Production method)
When weaving a vertical double-structured woven fabric, the pile yarn (vertical yarn) that joins both outer layers to the middle layer of the woven fabric is cut with a knife blade. When cut, it is sliced from the middle layer of the fabric and opened to be turned over to obtain two fabrics. Each of these two fabrics has a napped surface with a pile cut on the front surface (Fig. 1). The raised cut pile yarn A is firmly gripped by the warp yarn B and the weft yarn C to prevent the yarn from coming off during wearing (FIG. 2). It has a woven fabric shape that is preferable for its texture as a washing towel cloth and for removing stains. As described above, the fluffy woven fabric referred to in the present embodiment is a characteristic three-dimensional three-dimensional woven fabric that is completely different from the usual woven fabric having both sides flat, and has an extremely preferable woven fabric form as a washing towel cloth.

(合成繊維フィラメント糸)
ここで、毛穴のサイズを調べた結果、白色人種の体毛の太さは約44μm、黒色人種は24μm、黄色人種の体毛の太さは15〜17μmとグラフに示している(非特許文献1)。この体毛の太さ(直径)と毛穴の直径を同一と仮定し、この毛穴に入るポリエステルマルチフィラメント糸の単繊維繊度を試算すると、白色人種は21.3デシテックス、黒色人種は6.3デシテックス、黄色人種は2.4〜2.8デシテックスであった。例えばかかるマルチフィラメント糸の単繊維繊度を0.5デシテックスとすると、白色人種では42本、黒色人種は12本、黄色人種は5本程度、毛穴に入ることになる。
(Synthetic fiber filament yarn)
Here, as a result of examining the size of the pores, the thickness of the hair of the Caucasian race is about 44 μm, the thickness of the hair of the black race is 24 μm, and the thickness of the hair of the yellow race is 15 to 17 μm (non-patented). Document 1). Assuming that the thickness (diameter) of the hair and the diameter of the pores are the same, the single fiber fineness of the polyester multifilament yarn that enters the pores is calculated to be 21.3 decitex for Caucasians and 6.3 for blacks. Decitex, the yellow race was 2.4-2.8 decitex. For example, assuming that the single fiber fineness of the multifilament yarn is 0.5 decitex, 42 yarns for Caucasians, 12 yarns for black races, and about 5 yarns for yellow races will enter the pores.

つまり、毛穴のよごれを落とすには少なくとも単繊維繊度が21.3デシテックス以下の糸の細さが必要であり、本実施形態は単繊維繊度が0.1〜10デシテックスなので、毛穴に立毛されているマルチフィラメントの単繊維が十分に入る糸の細さである。 That is, in order to remove dirt from the pores, it is necessary to have a fineness of at least a single fiber fineness of 21.3 decitex or less, and since the single fiber fineness of this embodiment is 0.1 to 10 decitex, the hair is raised in the pores. It is the fineness of the thread that allows the single fibers of the multifilament to enter sufficiently.

ポリエステルのマルチフィラメントの単繊維繊度の直径(μm)は次式(簡便式)より求めた。
簡便式:Fd=10√d、
d=1.1×dt
ここで、Fdはポリエステルの単繊維繊度の直径(μm)、10は係数、dはデニール、dtはデシテックスで表し、1デニールは9000mで1グラムであり、ポリエステルの比重は1.38で求めた簡便式である。
The diameter (μm) of the single fiber fineness of the polyester multifilament was obtained from the following formula (simple formula).
Simple formula: Fd = 10√d,
d = 1.1 × dt
Here, Fd is the diameter of the single fiber fineness of polyester (μm), 10 is a coefficient, d is denier, and dt is decitex. 1 denier is 9000 m and 1 gram, and the specific gravity of polyester is 1.38. It is a simple formula.

次いで本実施形態で言う合成繊維マルチフィラメント糸とはポリマーで重合、合成され、繊維糸状に製造された合成繊維であれば、特に制限されるものではないが、ポリエステルフィラメント、ポリアミドフィラメント、ポリアクリルフィラメント、ポリプロピレンフィラメント、ポリ乳酸フィラメント等の合成繊維の長繊維マルチフィラメントで構成されたものが好ましく挙げられる。なお、マルチフィラメントとは例えば、糸表示が総繊度84デシテックス、36フィラメントの糸は、単繊維繊度が2.3デシテックスの1本の細いフィラメントが36本で構成された糸で、総繊度は84デシテックスの長繊維糸を言う。 Next, the synthetic fiber multifilament yarn referred to in the present embodiment is not particularly limited as long as it is a synthetic fiber polymerized and synthesized with a polymer and produced in the form of a fibrous yarn, but is not particularly limited, but is a polyester filament, a polyamide filament, or a polyacrylic filament. , Polypropylene filaments, polylactic acid filaments and other synthetic long-fiber multifilaments are preferable. The multifilament is, for example, a yarn having a total fineness of 84 decitex and a 36-filament yarn having a single fiber fineness of 2.3 decitex, which is composed of 36 fine filaments and has a total fineness of 84. Decitex long fiber yarn.

かかる合成繊維マルチフィラメント糸は洗浄性を高めることから、タテパイル糸に100%用いられることが好ましい。なお、少量であればレーヨンやキュプラ、綿等をかかる合成繊維に混繊や合撚して混用しても構わない。また、かかる合成繊維をタテパイル糸だけではなく、地糸に用いても良い。速乾性を高める場合はタテパイル糸と地糸の両方にかかる合成繊維を用いることが好ましい。 Since such synthetic fiber multifilament yarn enhances detergency, it is preferable to use 100% for vertical pile yarn. In addition, if it is a small amount, rayon, cupra, cotton or the like may be mixed or twisted with the synthetic fiber. Further, the synthetic fiber may be used not only for the vertical pile yarn but also for the ground yarn. When improving quick-drying, it is preferable to use synthetic fibers that are applied to both the vertical pile yarn and the ground yarn.

ここで、本実施形態の効果を好適に発揮できるものとして立毛部のタテパイル糸にポリエステルフィラメント糸を用いることが特に好ましい。この理由は、ポリエステルは単繊維繊度が細い糸から太い糸まで幅広く製糸できること、糸が細いにも関わらず繊維強度、剛性が高いので、立毛糸がソフトながら、弾力性、反発性があるので、洗浄で毛倒れしにくいこと、疎水性が高いので、乾燥速度が速いからである。 Here, it is particularly preferable to use a polyester filament yarn as the vertical pile yarn of the napped portion so that the effect of the present embodiment can be suitably exhibited. The reason for this is that polyester can produce a wide range of yarns from fine to thick single-fiber yarns, and despite the thin yarns, the fiber strength and rigidity are high, so the fluffy yarns are soft but elastic and repulsive. This is because the hair does not easily fall over during washing and the drying speed is high because it is highly hydrophobic.

本実施形態ではポリエステル系繊維は、例えばポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、或いはスルフォイソフタル酸やイソフタル酸、ポリエチレングリコール等を共重合させた共重合ポリエステル等である。これらをタテパイル糸だけでなく、地糸にも用いても構わない。 In the present embodiment, the polyester fiber is, for example, polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, or a copolymerized polyester obtained by copolymerizing sulfoisophthalic acid, isophthalic acid, polyethylene glycol, or the like. These may be used not only for the vertical pile yarn but also for the ground yarn.

本実施形態はかかるポリエステル系繊維を用いることであれば、その糸種や糸断面やポリエステルボマーを複数に複合した複合繊維でも良い等、特別な制限はない。好ましい具体例を挙げる。 In the present embodiment, as long as such polyester-based fibers are used, there are no particular restrictions such as a composite fiber in which a plurality of yarn types, yarn cross sections, and polyester bombers are compounded. Preferred specific examples are given.

まず、原糸形態はカットパイル糸が毛倒れしにくいことから、延伸糸(ナマ糸)及び弱仮より加工糸が好ましい。また、ソフトで腰のある立毛糸を得るため、単繊維の繊度をミックスした混繊糸を用いることも好ましい。また、糸の断面は通常の丸断面を適用できるが、マイルドな絹様光沢を求める場合は三角断面〜八角断面糸が好ましい。光沢の艶を調整する場合は艶消し剤の酸化チタンの量を加減した原糸を用いる(フルダル糸〜セミダル糸〜ブライト糸)。色の濃淡効果を得るにはシック&シン糸を用いる。異色効果を得る場合はスルフォイソフタル酸を共重合したカチオン染料可染型ポリエステルをレギュラーポリエステルに交織し、カチオン染料と分散染料で染め分けして、異色織物にすることも好ましい。また、環境対応素材のリサイクルポリエステル糸を用いることも好ましい。また、アルカリ易溶解成分の共重合ポリエステルポリマーとレギュラーポリエステルポリマーを接合したポリエステル複合繊維を用いて織物を作る。次いでこれを、アルカリ液でかかる易溶解成分を溶解することで、レギュラーポリエステルからなる超極細糸を得る、分割繊維や海島型繊維を使うことも好ましい。なお、一般的に活用している風合いをソフト化する、アルカリ減量加工も適用することも好ましい方法である。 First, as the raw yarn form, the cut pile yarn is less likely to fall down, so that the drawn yarn (raw yarn) and the processed yarn are preferable to the weak temporary yarn. Further, in order to obtain a soft and chewy standing yarn, it is also preferable to use a mixed yarn in which the fineness of a single fiber is mixed. A normal round cross section can be applied to the cross section of the yarn, but when a mild silky luster is desired, a triangular cross section to an octagonal cross section yarn is preferable. When adjusting the luster of luster, use a raw yarn in which the amount of titanium oxide as a matting agent is adjusted (full dull yarn-semi-dull yarn-bright yarn). Thick and thin threads are used to obtain the color shading effect. In order to obtain a different color effect, it is also preferable to mix a cationic dye dyeable polyester copolymerized with sulfoisophthalic acid with a regular polyester and dye it separately with a cationic dye and a disperse dye to obtain a different color woven fabric. It is also preferable to use recycled polyester yarn, which is an environmentally friendly material. In addition, a woven fabric is made using a polyester composite fiber in which a copolymerized polyester polymer having an easily soluble alkali component and a regular polyester polymer are bonded. Next, it is also preferable to use split fibers or sea-island type fibers that obtain ultrafine yarns made of regular polyester by dissolving the easily soluble component in an alkaline solution. It is also a preferable method to apply an alkali weight loss process that softens the texture that is generally used.

更には、ポリトリメチレンテレフタレートやポリブチレンテレフタレートは、レギュラーポリエステルに対して剛性が低いのでこれを地糸に使い、織物全体をよりソフトな風合いを作ることも好ましいことである。 Furthermore, since polytrimethylene terephthalate and polybutylene terephthalate have lower rigidity than regular polyester, it is also preferable to use this as the ground yarn to make the entire woven fabric have a softer texture.

なお、ポリエステル以外のポリアミドフィラメントではナイロン6やナイロン66に代表されるように、ナイロン特有の吸湿性や酸性染料による鮮明色が得られる特長があり、好ましい。ポリアクリルフィラメントでは常圧で染色できることから、綿やレーヨン、ウールとの混用織物が得られるので、好ましい。ポリプロピレンフィラメントは比重が小さいので、軽量織物が得られる。ポリ乳酸フィラメントは環境対応繊維として好ましく使える。 Polyamide filaments other than polyester are preferable because they have the characteristics of being hygroscopic and vivid colors due to acid dyes, as typified by nylon 6 and nylon 66. Since the polyacrylic filament can be dyed at normal pressure, a woven fabric mixed with cotton, rayon, or wool can be obtained, which is preferable. Since polypropylene filament has a low specific gravity, a lightweight woven fabric can be obtained. Polylactic acid filaments can be preferably used as environmentally friendly fibers.

本実施形態の立毛織物のカットパイル糸は、総繊度10〜500デシテックス、単繊維繊度が0.1〜10デシテックスの合成繊維マルチフィラメント糸である。洗浄時の手持ち感、洗いやすさ、泡立ち性から、特に50〜400デシテックスが好ましい。10デシテックス未満の物は薄べったく、洗いにくく、好ましくない。また、500デシテックスを超えるものは地厚で重く洗いにくく、また、乾燥しにくいので好ましくない。 The cut pile yarn of the fluffy fabric of the present embodiment is a synthetic fiber multifilament yarn having a total fineness of 10 to 500 decitex and a single fiber fineness of 0.1 to 10 decitex. 50 to 400 decitex is particularly preferable from the viewpoint of hand-held feeling during washing, ease of washing, and foaming property. Items less than 10 decitex are thin and difficult to wash, which is not preferable. In addition, those exceeding 500 decitex are not preferable because they are thick and heavy and difficult to wash, and also difficult to dry.

本実施形態のカットパイル糸の単繊維繊度は、織物のソフトさ、弾力性の風合いと、細かい汚れを落とすことと速乾性から、単繊維繊度は0.1〜10デシテックスのものが良い。特に0.5〜8デシテックスが風合いと汚れ落とし性、速乾性のバランスから好ましい。0.1デシテックス未満の物は風合いがたらたらして腰がなく、汚れが落ちにくく、好ましくない。また、10デシテックスを超えるものは風合いが粗硬で洗いにくく、好ましくない。 The single fiber fineness of the cut pile yarn of the present embodiment is preferably 0.1 to 10 decitex because of the softness and elasticity of the woven fabric, the removal of fine stains and the quick-drying property. In particular, 0.5 to 8 decitex is preferable from the viewpoint of balance of texture, stain removal property, and quick-drying property. Items with less than 0.1 decitex are not preferable because they have a rough texture and are not stiff and stains are difficult to remove. Further, those exceeding 10 decitex are not preferable because the texture is rough and hard to wash.

本実施形態は立毛織物の合成繊維マルチフィラメント糸が織物に少なくとも30重量%以上含むものである。特に汚れの落としやすさと速乾性から、60〜100重量%に含有させることが好ましい。30重量%未満のものはかかる性能が低下するので、好ましくない。なお、織物に30重量%未満の範囲で、例えば地糸に綿糸、レーヨン糸、ウール糸等を用いて吸湿性や風合い、或いは暖かみを得る方法等は好ましいことである。 In the present embodiment, the synthetic fiber multifilament yarn of the fluffy woven fabric is contained in the woven fabric in an amount of at least 30% by weight or more. In particular, it is preferably contained in an amount of 60 to 100% by weight because it is easy to remove stains and dries quickly. If it is less than 30% by weight, the performance is deteriorated, which is not preferable. It should be noted that a method of obtaining hygroscopicity, texture, or warmth by using cotton yarn, rayon yarn, wool yarn, or the like as the ground yarn in the range of less than 30% by weight is preferable for the woven fabric.

本実施形態は立毛織物のカットパイル長が0.5〜10mmである。特に汚れの落としやすさ、ミクロブラッシング効果を最大に発揮させるために1.0〜7.0mmの範囲のものが特に好ましい。0.5mm未満のものは立毛が短すぎて該ブラッシング効果が出にくいので好ましくない。また、10mmを越えるものは長すぎて毛倒れして細かい汚れが取れず、好ましくない。 In this embodiment, the cut pile length of the fluffy fabric is 0.5 to 10 mm. In particular, those in the range of 1.0 to 7.0 mm are particularly preferable in order to maximize the ease of removing dirt and the micro brushing effect. Those with a thickness of less than 0.5 mm are not preferable because the naps are too short and the brushing effect is difficult to obtain. Further, the one exceeding 10 mm is not preferable because it is too long and the hair falls down and fine stains cannot be removed.

また、本実施形態は前記立毛織物の目付は50〜500g/mであることが好ましい。洗浄時の手持ち感、洗いやすさ、泡立ち性から100〜400g/mのものが特に好ましい。50g/m未満の物は薄べったく、洗いにくく、好ましくない。また、500デシテックスを超えるものは速乾性が乏しくなるので好ましくない。 Further, in the present embodiment, the basis weight of the raised woolen fabric is preferably 50 to 500 g / m 2 . 100 to 400 g / m 2 is particularly preferable from the viewpoint of hand-held feeling at the time of washing, ease of washing, and foaming property. Items less than 50 g / m 2 are thin and difficult to wash, which is not preferable. In addition, those exceeding 500 decitex are not preferable because they have poor quick-drying properties.

(用途)
本実施形態の洗浄タオル地の用途は手洗い用として特に好ましい。前述したように、ソフトな風合いで、泡立ち性、水切り性、細部の汚れを効率よく落とし、且つ速乾性が得られる。なお、手洗い用途以外には特に限定するものではないが、洗車、窓ふき、家具、置物の清掃、電子機器のクリーナー、精密機器の研磨等の用途として幅広く適用することができる。
(Use)
The use of the washing towel cloth of the present embodiment is particularly preferable for hand washing. As described above, it has a soft texture, efficiently removes foaming property, draining property, and stains on details, and quick-drying property can be obtained. The application is not particularly limited to applications other than hand washing, but can be widely applied to applications such as car washing, window cleaning, furniture, cleaning of figurines, cleaners for electronic devices, and polishing of precision devices.

また、本実施形態の織物の仕上げ方法については特に制限するものではないが、吸水加工、撥水加工、消臭加工、抗菌加工等を適用することも好ましい方法である。また、無地染めの他に、プリント染色や先染め(糸染め)することも可能である。このように本実施形態は風合い加工、機能加工など幅広い加工も適用できるので、多様な好ましい商品が得られる特長がある。 The method for finishing the woven fabric of the present embodiment is not particularly limited, but it is also preferable to apply water absorption processing, water repellent processing, deodorant processing, antibacterial processing and the like. In addition to plain dyeing, print dyeing and yarn dyeing (yarn dyeing) are also possible. As described above, since this embodiment can be applied to a wide range of processing such as texture processing and functional processing, it has a feature that various preferable products can be obtained.

以下に、実施例に基づいて本実施形態を詳細に説明するが、本実施形態は必ずしもこれらに限定されるものではない。 Hereinafter, the present embodiment will be described in detail based on the examples, but the present embodiment is not necessarily limited to these.

[測定方法]
本実施例における特性の測定・評価は、以下に記載の方法を用いた。なお、評価する洗浄タオル地は実施例、比較例を含めて一定の重さで評価したこと、また、評価者は10名でその平均値を用いて評価した。手洗いの順で説明する。
(1)洗浄タオル地の風合いの評価は次の4段階で官能感触テストで評価した。表面が滑らかでソフトな風合いのものが、優れている(◎)、良い(〇)、普通(△)、劣る(×)で評価した。
(2)洗浄タオル地の泡立ち性の評価は、一定量の重さの生地を秤量し、下記洗剤をポンピングしながら3回生地に付けて、泡立ち性が優れているものから、次の4段階に視覚官能で評価した。泡立ち性が優れている(◎)、良い(〇)、普通(△)、劣る(×)。洗剤の明細は泡立ちソープタイプ、商品名:キレイキレイ、メーカ:LION、成分:イソプロピルメチルフェノール等。容器:ポンピング方式を用いた。
(3)洗浄タオル地の汚れの落ちやすさの評価は、疑似汚れを手に付け、泡立ちした洗浄タオルでその汚れが落ちたときの速度:汚れ落ち速度(秒)で評価した。疑似汚れは下記の油性のマジックペン(黒)と口紅(赤)であり、手の甲、手のひら、爪の間に汚れを付けた。左手の手の甲と手のひらにはそれぞれ幅5mm、長さ50mmのサイズで2本ずつ線を書き、汚れを付けた。爪には人差し指、中指、薬指の3本の爪の間に汚れを差し込んで付けた。次いで、前記泡立たせたタオル地で、手の甲、手のひら、爪の間のそれぞれ汚れが落ちる時間(秒)を測った。時間が短いほど、汚れを落とす性能が高く、洗浄効率に優れているタオル地である。なお、疑似汚れの明細は次のとおりである。[1]油性のボールペン(黒)、商品名:油性マジックペン、メーカ:ZEBURA、成分:プロピレングリコールメチルエーテル等のアルコール類と樹脂、染料など。[2]口紅(赤)、メーカ:DAISO、成分:トリメリト酸デシルパルミチン酸エチルヘキシルセレシン等及び合成ワックス、ヤシ油、顔料など。
(4)洗浄タオル地の水切り性の評価は手洗いが終わり、生地を水洗し、脱水後の生地の残留水分率(%)で評価する。評価は残留水分率が少ないほど、水切り性が優れている。評価はまず、生地(原布)を12.0gの重さに裁断、秤量する。ついで生地を室温の水に10分浸漬し、片手で生地の中央を把持し10回振り、脱水する。更にこの生地を丸めて両手で握りしめて脱水、これを3回繰り返す(合計10回振り+3回握り脱水)。これで固く絞られ、余分な水分が脱水される状態となる。この生地の重さを測り、次式で生地の残留水分率(%)を求める。

Figure 2020171719
(5)洗浄タオル地の速乾性の評価は上記脱水した生地の乾燥時間(分)で評価する。評価は乾燥時間が短いほど、速乾性に優れている。評価方法は上記脱水した生地を秤量し、20℃×湿度65%の室内にハンガーで吊り下げる。この生地が原布の重量になるまでの、完全に乾燥した時の時間(分)を測定する。 [Measuring method]
The method described below was used for the measurement and evaluation of the characteristics in this example. The washing towel cloth to be evaluated was evaluated with a constant weight including the examples and comparative examples, and 10 evaluators were evaluated using the average value. The explanation will be given in the order of hand washing.
(1) The texture of the washed towel cloth was evaluated by a sensory feel test in the following four stages. Those with a smooth and soft surface were evaluated as excellent (⊚), good (〇), normal (Δ), and inferior (×).
(2) To evaluate the foaming property of the washing towel cloth, weigh a certain amount of dough and apply it to the cloth three times while pumping the following detergent, and from the one with excellent foaming property to the next four stages. It was evaluated by visual sensuality. Excellent foaming (◎), good (〇), normal (△), inferior (×). The details of the detergent are foaming soap type, product name: beautiful, manufacturer: LION, ingredient: isopropylmethylphenol, etc. Container: A pumping method was used.
(3) The ease of removing stains on the washing towel cloth was evaluated by the speed at which the stains were removed with the foamed washing towel after applying the pseudo stains to the hands: the stain removing speed (seconds). The pseudo stains were the following oil-based marker pen (black) and lipstick (red), and stains were applied between the back of the hand, palm, and nails. Two lines were drawn on the back of the left hand and the palm of the hand with a width of 5 mm and a length of 50 mm, respectively, to make stains. Dirt was inserted between the index finger, middle finger, and ring finger to attach the nail. Next, on the foamed towel cloth, the time (seconds) for removing dirt between the back of the hand, the palm, and the nails was measured. The shorter the time, the higher the performance of removing dirt and the better the cleaning efficiency of the towel cloth. The details of the pseudo-dirt are as follows. [1] Oil-based ballpoint pen (black), trade name: oil-based marker pen, manufacturer: ZEBURA, component: alcohols such as propylene glycol methyl ether, resins, dyes, etc. [2] Lipstick (red), manufacturer: DAISO, ingredients: ethylhexyl selecin decyl palmitate, etc., synthetic wax, coconut oil, pigments, etc.
(4) The drainage property of the washing towel cloth is evaluated by the residual moisture content (%) of the cloth after hand washing, washing the cloth with water, and dehydrating the cloth. In the evaluation, the smaller the residual water content, the better the drainability. First, the dough (raw cloth) is cut to a weight of 12.0 g and weighed. Then, soak the dough in water at room temperature for 10 minutes, grasp the center of the dough with one hand, shake it 10 times, and dehydrate it. Furthermore, this dough is rolled and squeezed with both hands to dehydrate, and this is repeated 3 times (10 times in total + 3 times squeezed and dehydrated). This will squeeze it tightly and dehydrate excess water. The weight of this dough is measured, and the residual moisture content (%) of the dough is calculated by the following formula.
Figure 2020171719
(5) The quick-drying property of the washing towel cloth is evaluated by the drying time (minutes) of the dehydrated dough. As for the evaluation, the shorter the drying time, the better the quick-drying property. The evaluation method is to weigh the dehydrated dough and hang it in a room at 20 ° C. and 65% humidity with a hanger. Measure the time (minutes) when the dough is completely dried until it reaches the weight of the original fabric.

(実施例1)
(1)立毛織物の製造方法と評価方法
カットパイル糸に総繊度84デシテックス、36フィラメント、単繊維繊度が2.3デシテックスのポリエステルのマルチフィラメント糸の延伸糸を用いた(丸断面、セミダル糸)。タテ地糸およびヨコ地糸には54デシテックス、24フィラメントのポリエステルのマルチフィラメント糸の延伸糸を用いて(丸断面、セミダル糸)、カットパイル長が1.3mmのポリエステル100%のタテパイル立毛織物を製織した。次いでこれを精練し、分散染料でベージュに染色し、仕上げた。仕上品の目付は197g/m、幅114cm、長さ30mである。この織物を25.0×24.3cmに裁断し、12.0gのタオル地にした。これを手洗い用の洗浄タオルとして性能評価を行った。評価は前記測定方法に従って、生地の風合い、泡立ち性、油性マジックペン(黒)と口紅(赤)による汚れ落ちの速さ、残留水分率、乾燥時間を評価した。評価結果を表1に示す。
(Example 1)
(1) Manufacturing method and evaluation method of napped fabric A stretched yarn of a polyester multifilament yarn having a total fineness of 84 decitex, 36 filaments and a single fiber fineness of 2.3 decitex was used as the cut pile yarn (round cross section, semi-dull yarn). .. For the warp and weft yarns, use a drawn yarn of 54 decitex, 24-filament polyester multifilament yarn (round cross section, semi-dull yarn), and use a 100% polyester vertical pile fluff fabric with a cut pile length of 1.3 mm. Weaved. This was then refined and dyed beige with a disperse dye to finish. The basis weight of the finished product is 197 g / m 2 , width 114 cm, and length 30 m. This woven fabric was cut into 25.0 × 24.3 cm to make 12.0 g of towel cloth. The performance was evaluated using this as a washing towel for hand washing. In the evaluation, the texture, foaming property, speed of stain removal by oil-based marker pen (black) and lipstick (red), residual moisture content, and drying time were evaluated according to the above-mentioned measurement method. The evaluation results are shown in Table 1.

(実施例2)
カットパイル糸に総繊度168デシテックス、96フィラメント、単繊維繊度が1.75デシテックスのポリエステルのマルチフィラメント糸の(丸断面、フルダル糸)の延伸糸を用い、カットパイル長が1.5mmのポリエステル100%のタテパイル立毛織物を製織し、分散染料でブルーに染色し、仕上品の目付は230g/mで、この織物を22.8×22.7cmに裁断し、12.0gの洗浄タオル地にした以外は実施例1に従って評価した。
(Example 2)
A polyester 100 with a cut pile length of 1.5 mm is used as the cut pile yarn, which is a drawn yarn of a polyester multifilament yarn (round cross section, full dull yarn) having a total fineness of 168 decitex, 96 filaments and a single fiber fineness of 1.75 decitex. % Vertical pile fluffed fabric was woven and dyed blue with a disperse dye, and the finished product had a texture of 230 g / m 2 , and this fabric was cut into 22.8 x 22.7 cm to make 12.0 g of wash towel cloth. Other than that, it was evaluated according to Example 1.

(実施例3)
カットパイル糸に総繊度84デシテックス、72フィラメント、単繊維繊度が1.2デシテックスのカチオン染料可染型ポリエステルのマルチフィラメント糸の延伸糸を用い、タテ、ヨコ地糸に80番の綿糸を用い、カットパイル長が2.0mmのポリエステル78重量%、綿22重量%の交織したタテパイル立毛織物を製織した。次いでカットパイル糸をカチオン染料で濃紺に、綿地糸をイェローに反応染料で異色に染色し、仕上げた。仕上品の目付は278g/mで、この織物を20.7×22.6cmに裁断し、12.0gの洗浄タオル地にした以外は実施例1に従って評価した。
(Example 3)
For the cut pile yarn, a drawn yarn of a cationic dye dyeable polyester multifilament yarn having a total fineness of 84 decitex, 72 filaments and a single fiber fineness of 1.2 decitex was used, and a cotton yarn of No. 80 was used for the warp and weft ground yarns. A vertical pile fluffy fabric having a cut pile length of 2.0 mm, which was 78% by weight of polyester and 22% by weight of cotton, was woven. Next, the cut pile yarn was dyed in dark blue with a cationic dye, and the cotton yarn was dyed in yellow with a reactive dye to finish it. The basis weight of the finished product was 278 g / m 2 , and this woven fabric was cut into 20.7 × 22.6 cm and evaluated according to Example 1 except that it was made into a 12.0 g wash towel cloth.

(比較例1)
洗浄タオル地を通常の綿100%のパイルタオル(ノーカットパイル品、パイル糸および地糸とも30番綿糸使い)の目付320g/mを用い、これを22.0×17.0cmに裁断し、12.0gのタオル地にした以外は、実施例1に従って手洗い用の洗浄タオルとしての性能評価を行った。評価結果を表1に併記した。
(Comparative Example 1)
For the washing towel cloth, use a normal 100% cotton pile towel (uncut pile product, pile thread and ground thread both use No. 30 cotton thread) with a mesh size of 320 g / m 2 , and cut this into 22.0 x 17.0 cm. Performance evaluation as a washing towel for hand washing was performed according to Example 1 except that the towel cloth was made of 0.0 g. The evaluation results are also shown in Table 1.

(比較例2)
洗浄タオル地を使わずに素手で手洗いを行った以外は、実施例1に従って手洗いの評価を行った。但し、素手のため、生地の風合い、残留水分率、乾燥速度は評価せず、泡立ち性、汚れ落ちの速さのみ評価した。評価結果を表1に併記した。

Figure 2020171719
(Comparative Example 2)
The hand washing was evaluated according to Example 1, except that the hand washing was performed with bare hands without using the washing towel cloth. However, since the hands were bare hands, the texture of the fabric, the residual moisture content, and the drying speed were not evaluated, but only the foaming property and the speed of removing stains were evaluated. The evaluation results are also shown in Table 1.
Figure 2020171719

(2)評価結果
表1から明らかなように、実施例1の洗浄タオル地は、表面が滑らかで、ソフトな風合いで、泡立ち性に優れている。また、手の隅々までの汚れが速く落ち、水切り性もよく、乾燥が速い。詳細には実施例1は、手の甲と手のひらの汚れ落ちの速さが比較例1に対して2.3〜2.7倍速い。比較例2に対しては3.4〜21.0倍速い。爪の間の汚れが比較例1に対して2.2〜3.6倍速く、比較例2に対しては2.6〜8.3倍速く、効率よく汚れが落ちる洗浄タオル地であった。また、生地の乾燥時間が比較例1に対して2.4倍速く、速乾性に優れ、清潔感に富むベージュの洗浄タオル地であった。
(2) Evaluation Results As is clear from Table 1, the washing towel cloth of Example 1 has a smooth surface, a soft texture, and excellent foaming property. In addition, dirt on every corner of the hand is quickly removed, draining is good, and drying is quick. Specifically, in Example 1, the speed of removing stains on the back and palm of the hand is 2.3 to 2.7 times faster than that of Comparative Example 1. It is 3.4 to 21.0 times faster than Comparative Example 2. The dirt between the nails was 2.2 to 3.6 times faster than that of Comparative Example 1, and 2.6 to 8.3 times faster than that of Comparative Example 2, and the dirt was removed efficiently. In addition, the drying time of the dough was 2.4 times faster than that of Comparative Example 1, the quick-drying property was excellent, and the beige washing towel cloth was rich in cleanliness.

実施例2は、汚れの落ちやすさが実施例1よりも更に優れており、滑らかでソフトな風合いを持つ、素晴らしいブルーの洗浄タオル地であった。実施例3は、綿の風合いを持ちながら、汚れの洗浄性に優れる、濃紺とイェローに異色染色された特徴ある色感に富む洗浄タオル地であった。一方、比較例1の綿100%のタオル地は生地の風合い、泡立ち性が乏しく汚れ落ちの速さも劣るものであった。また、水切り性、乾燥速度が遅い、平凡なタオル地であった。比較例2の素手で洗ったものは汚れが落ちにくく、洗浄効率は劣るものであった。 Example 2 was a wonderful blue wash towel cloth with a smooth and soft texture, which was even easier to remove stains than Example 1. Example 3 was a washing towel cloth having a cotton texture and excellent stain cleaning property, which was dyed in different colors in dark blue and yellow and was rich in characteristic color. On the other hand, the 100% cotton towel cloth of Comparative Example 1 had poor texture and foaming property, and the speed of removing stains was also inferior. In addition, it was a mediocre towel cloth with draining properties and slow drying speed. Those washed with bare hands in Comparative Example 2 were difficult to remove stains, and the cleaning efficiency was inferior.

以上のように、本実施形態の立毛織物の洗浄タオルを用いると、従来技術では得られなかった、織物の表面が滑らかで、ソフトな風合いを持ち、泡立ちが良く、細部の汚れまでも効率よく落とし、且つ水切り性、速乾性に優れた洗浄タオル地を得ることができる。 As described above, when the fluffy woven fabric washing towel of the present embodiment is used, the surface of the woven fabric is smooth, has a soft texture, has good foaming, and efficiently even stains in details, which could not be obtained by the conventional technique. It is possible to obtain a washing towel cloth that can be dropped and has excellent drainage and quick-drying properties.

(実施例4)
カットパイル糸に総繊度84デシテックス、24フィラメント、単繊維繊度が3.5デシテックス糸と総繊度66デシテックス、204フィラメント、単繊維繊度が0.32デシテックス糸をエアー混繊した総繊度150デシテックス、228フィラメントのポリエステルのマルチフィラメント糸(丸断面、セミダル糸)を用いた。タテ地糸には84デシテックス、36フィラメントの延伸糸とヨコ地糸に54デシテックス、24フィラメントのポリエステルを用い、カットパイル長が2.0mmのポリエステル100%のタテパイル立毛織物を製織し、精練し、仕上げた。次いで裏の地糸面にプリント加工した。仕上げ品の目付は330g/mで、この織物を実施例1に従って評価した。
(Example 4)
Cut pile yarn with total fineness of 84 decitex, 24 filaments, single fiber fineness of 3.5 decitex yarn and total fineness of 66 decitex, 204 filament, single fiber fineness of 0.32 decitex yarn mixed with air, total fineness of 150 decitex, 228 Polyester multifilament yarn (round cross section, semi-dull yarn) of filament was used. 84 decitex, 36 filament stretched yarn and 54 decitex, 24 filament polyester are used for the warp yarn, and 100% polyester vertical woolen fabric with a cut pile length of 2.0 mm is woven and refined. I finished it. Next, the back yarn surface was printed. The basis weight of the finished product was 330 g / m 2 , and this woven fabric was evaluated according to Example 1.

評価の結果、単繊維繊度が太細にミックスされており、立毛部がソフトながら、弾力性がある風合いであった。また、爪の間のマジック汚れ落ちの速さは120秒であり、非常に優れていた。乾燥時間も305分であり、従来の綿100%タオルでは到達できない高いレベルのプリントされた洗浄タオルであった。 As a result of the evaluation, the fineness of the single fibers was finely mixed, and the napped part had a soft but elastic texture. In addition, the speed of removing magic stains between the nails was 120 seconds, which was very excellent. The drying time was 305 minutes, which was a high level of printed cleaning towel that could not be reached with conventional 100% cotton towels.

(実施例5)
カットパイル糸に総繊度156デシテックス、104フィラメント、単繊維繊度が1.5デシテックスのナイロン6のマルチフィラメント糸(丸断面、セミダル糸)を用いた。タテ地糸とヨコ地糸には70デシテックス、24フィラメントのポリプロピレンのマルチフィラメント糸を用い、カットパイル長が1.5mmのナイロン6とポリプロピレンの交織のタテパイル立毛織物を製織した。これを精練し、ナイロンを濃紺に染色し、仕上げた。仕上げ品の目付は205g/mで、この織物を実施例1に従って評価した。
(Example 5)
A nylon 6 multifilament yarn (round cross section, semi-dull yarn) having a total fineness of 156 decitex, 104 filaments and a single fiber fineness of 1.5 decitex was used as the cut pile yarn. 70 decitex, 24-filament polypropylene multifilament yarn was used as the warp and weft yarns, and a vertical pile woolen fabric of a mixed weave of nylon 6 and polypropylene having a cut pile length of 1.5 mm was woven. This was smelted, nylon was dyed dark blue, and finished. The basis weight of the finished product was 205 g / m 2 , and this woven fabric was evaluated according to Example 1.

評価の結果、通常のポリエステル立毛織物(目付250g/m)に対して目付が205g/mであり、約18%軽かった。軽量なので手洗いの取り扱いに優れ、軽快に洗浄できるものであった。また、口紅の爪の間の汚れ落ちの速さは12秒で、乾燥時間も320分であり、高いレベルの濃紺の軽い洗浄タオルであった。 As a result of the evaluation, the basis weight was 205 g / m 2 with respect to the normal polyester woolen fabric (basis weight 250 g / m 2 ), which was about 18% lighter. Because it is lightweight, it is easy to handle by hand and can be washed lightly. In addition, the speed of removing stains between the lipstick nails was 12 seconds, the drying time was 320 minutes, and it was a high-level dark blue light cleaning towel.

以上のように、本実施形態の洗浄タオルを用いると、従来技術では得られなかった、織物の表面が滑らかで、ソフトな風合いを持ち、泡立ちが良く、細部の汚れまでも効率よく落とし、且つ水切り性、速乾性に優れた洗浄タオル地を得ることができた。 As described above, when the washing towel of the present embodiment is used, the surface of the woven fabric is smooth, has a soft texture, has good foaming, and efficiently removes even fine stains, which cannot be obtained by the conventional technique. We were able to obtain a washing towel cloth with excellent drainage and quick-drying properties.

Skin Pharmacology and Physiology,(米),2006;19,p.159−167、(特にFig.5のCalf)Skin Pharmacology and Physiology, (US), 2006; 19, p. 159-167, (especially Fig. 5 Calf)

Claims (7)

カットパイル糸が少なくとも総繊度10〜500デシテックス、単繊維繊度が0.1〜10デシテックスの合成繊維フィラメント糸で構成された立毛織物で構成される、洗浄タオル地。 A wash towel cloth in which the cut pile yarn is composed of a napped fabric composed of synthetic fiber filament yarn having a total fineness of at least 10 to 500 decitex and a single fiber fineness of 0.1 to 10 decitex. 前記合成繊維フィラメント糸は、ポリエステル系繊維である、請求項1に記載の洗浄タオル地。 The washing towel cloth according to claim 1, wherein the synthetic fiber filament yarn is a polyester fiber. 前記立毛織物は、前記合成繊維フィラメント糸を少なくとも30重量%以上含む、請求項1又は2に記載の洗浄タオル地。 The washing towel cloth according to claim 1 or 2, wherein the woolen fabric contains at least 30% by weight of the synthetic fiber filament yarn. 前記立毛織物は、タテパイル織物である、請求項1乃至3のいずれか1項に記載の洗浄タオル地。 The washing towel cloth according to any one of claims 1 to 3, wherein the woolen fabric is a vertical pile fabric. 前記立毛織物のカットパイル糸のカットパイル長は、0.5〜10mmである、請求項1乃至4のいずれか1項に記載の洗浄タオル地。 The washing towel cloth according to any one of claims 1 to 4, wherein the cut pile length of the cut pile yarn of the fluffy fabric is 0.5 to 10 mm. 前記立毛織物の目付は、50〜500g/mである、請求項1乃至5のいずれか1項に記載の洗浄タオル地。 The washing towel cloth according to any one of claims 1 to 5, wherein the basis weight of the woolen fabric is 50 to 500 g / m 2 . 用途が手洗い用である、請求項1乃至6のいずれか1項に記載の洗浄タオル地。 The washing towel cloth according to any one of claims 1 to 6, which is used for hand washing.
JP2020105736A 2020-06-19 2020-06-19 washed toweling Active JP7164214B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2020105736A JP7164214B2 (en) 2020-06-19 2020-06-19 washed toweling

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2020105736A JP7164214B2 (en) 2020-06-19 2020-06-19 washed toweling

Publications (2)

Publication Number Publication Date
JP2020171719A true JP2020171719A (en) 2020-10-22
JP7164214B2 JP7164214B2 (en) 2022-11-01

Family

ID=72829840

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2020105736A Active JP7164214B2 (en) 2020-06-19 2020-06-19 washed toweling

Country Status (1)

Country Link
JP (1) JP7164214B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112095208A (en) * 2020-07-30 2020-12-18 张健 Warm-keeping velvet sportswear fabric with high water absorption rate and low water retention rate and manufacturing method thereof
JP7080380B1 (en) 2021-05-31 2022-06-03 株式会社ファーストリテイリング fabric
KR20220146778A (en) * 2021-04-26 2022-11-02 주식회사 나경 Manufacturing method of textile blinds using waste PET resin

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0327149A (en) * 1989-06-20 1991-02-05 Toray Ind Inc Toweling piece and production thereof
JPH04125792U (en) * 1991-04-27 1992-11-17 教行 山内 towel
JP3077541U (en) * 2000-07-15 2001-05-25 河野新素材開発株式会社 Facial cleansing supplies
US20010017168A1 (en) * 2000-02-25 2001-08-30 Andre Dewispelaere Loop pile fabric and method for weaving it
JP2004027438A (en) * 2002-06-27 2004-01-29 Tamai Towel:Kk Towel fabric and method for producing the same
JP2009013529A (en) * 2007-07-04 2009-01-22 Kenji Kita Moquette fabric
JP2009150027A (en) * 2007-12-22 2009-07-09 Gp:Kk Double-sided towel and method for producing the same
JP2010209476A (en) * 2009-03-06 2010-09-24 Teijin Fibers Ltd Napped fabric, supporter, and fiber product
JP2011006806A (en) * 2009-06-24 2011-01-13 Teijin Fibers Ltd Sebum-removing cloth and method for producing the same

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0327149A (en) * 1989-06-20 1991-02-05 Toray Ind Inc Toweling piece and production thereof
JPH04125792U (en) * 1991-04-27 1992-11-17 教行 山内 towel
US20010017168A1 (en) * 2000-02-25 2001-08-30 Andre Dewispelaere Loop pile fabric and method for weaving it
JP3077541U (en) * 2000-07-15 2001-05-25 河野新素材開発株式会社 Facial cleansing supplies
JP2004027438A (en) * 2002-06-27 2004-01-29 Tamai Towel:Kk Towel fabric and method for producing the same
JP2009013529A (en) * 2007-07-04 2009-01-22 Kenji Kita Moquette fabric
JP2009150027A (en) * 2007-12-22 2009-07-09 Gp:Kk Double-sided towel and method for producing the same
JP2010209476A (en) * 2009-03-06 2010-09-24 Teijin Fibers Ltd Napped fabric, supporter, and fiber product
JP2011006806A (en) * 2009-06-24 2011-01-13 Teijin Fibers Ltd Sebum-removing cloth and method for producing the same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112095208A (en) * 2020-07-30 2020-12-18 张健 Warm-keeping velvet sportswear fabric with high water absorption rate and low water retention rate and manufacturing method thereof
KR20220146778A (en) * 2021-04-26 2022-11-02 주식회사 나경 Manufacturing method of textile blinds using waste PET resin
KR102468940B1 (en) 2021-04-26 2022-11-21 주식회사 나경 Manufacturing method of textile blinds using waste PET resin
JP7080380B1 (en) 2021-05-31 2022-06-03 株式会社ファーストリテイリング fabric
WO2022255101A1 (en) * 2021-05-31 2022-12-08 株式会社ファーストリテイリング Woven fabric
JP2022183574A (en) * 2021-05-31 2022-12-13 株式会社ファーストリテイリング Woven fabric

Also Published As

Publication number Publication date
JP7164214B2 (en) 2022-11-01

Similar Documents

Publication Publication Date Title
JP7164214B2 (en) washed toweling
US20140317866A1 (en) Microfiber Cosmetic Textile and Methods of Use
EP2992796B1 (en) Towel product
CN102747530A (en) Preparation method of polyester-cotton combined ultrafine fiber towel cloth and towel cloth thereof
JP6246505B2 (en) Wiper and manufacturing method thereof
JPH0327149A (en) Toweling piece and production thereof
JP6145432B2 (en) Pile cloth
JP5186276B2 (en) Sebum removing fabric and sebum removing product
JP2013256736A (en) Method for producing polyester-polyamide composite microfiber towel cloth and the towel cloth
US20130189473A1 (en) Towels of micro fibers of polyester/polyamide bi-components and the method of making
JP4258247B2 (en) Sebum removing fabric and method for producing the same
PL239664B1 (en) Textile cleaning device, in particular for removing make-up
US11441246B2 (en) Towel product
US20030008588A1 (en) Textile skin cleaning device
US20140093676A1 (en) Towels of Micro fibers of Polyester/Polyamide Bi-components and the Method of Making
JP2005052201A (en) Towel handkerchief
JP3233409U (en) Cleaning tool
KR101189753B1 (en) Manufacturing method of a mat and the mat manufactured therdfrom
JP3206216U (en) Towel fabric body with excellent dirt removal
JP7264552B2 (en) toweling
JP3244365U (en) towel
JP2019097869A (en) Pile cloth, pile cloth-attached tool, and production method of pile cloth
JP3160179U (en) Body wash towel
JPH0420596Y2 (en)
JPH0745585Y2 (en) Napped knitted fabric

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20200619

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20200730

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20210420

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20210423

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210603

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20211027

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20211223

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A712

Effective date: 20220421

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20220428

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20220524

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20221007

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20221013

R150 Certificate of patent or registration of utility model

Ref document number: 7164214

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150