JP2020171438A - Paper straw and its manufacturing method - Google Patents

Paper straw and its manufacturing method Download PDF

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JP2020171438A
JP2020171438A JP2019074450A JP2019074450A JP2020171438A JP 2020171438 A JP2020171438 A JP 2020171438A JP 2019074450 A JP2019074450 A JP 2019074450A JP 2019074450 A JP2019074450 A JP 2019074450A JP 2020171438 A JP2020171438 A JP 2020171438A
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paper
base paper
straw
wax
coating agent
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知正 中村
Tomomasa Nakamura
知正 中村
宙迪 齋藤
Hiromichi Saito
宙迪 齋藤
勇太 青柳
Yuta Aoyagi
勇太 青柳
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Daishowa Paper Products Co Ltd
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Daishowa Paper Products Co Ltd
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Abstract

To provide a paper straw excellent in water proofness, rigidity and manufacturing efficiency without using plastic; and to provide its manufacturing method.SOLUTION: At least one surface side which is an outer surface 11A or an inner surface 11B of a paper straw 10 contains a base paper 11 coated beforehand with a waterproof coating agent such as naturally derived wax 15, and the base paper 11 is wound spirally in piles, while a margin 11C to adhere is shifted gradually as much as a prescribed amount in an oblique direction. and an overlapping part (margin 11C to adhere) of the base paper 11 is fixed mutually adhesively, to thereby form a tube body having both ends communicating with each other.SELECTED DRAWING: Figure 1

Description

本発明は、紙製ストロー及びその製造方法に関するものであり、特に、従来のプラスチック製ストローの代替が可能な紙製ストロー及びその製造方法に関するものである。 The present invention relates to a paper straw and a method for producing the same, and more particularly to a paper straw which can replace a conventional plastic straw and a method for producing the same.

一般に、現在普及しているストローは、熱溶融されたプラスチックを押し出し、それを冷却して形成されている。また、今日では、世界的に物質的な生活水準が高まり、どの国のどの食文化でも、飲料を飲むときにストローを使用することが極めて多くなっている。したがって、世界中で毎日消費しているストローの数量は非常に膨大である。 In general, straws that are currently in widespread use are formed by extruding heat-melted plastic and cooling it. Also, today, the standard of living material is rising worldwide, and in every food culture in any country, the use of straws when drinking beverages is extremely high. Therefore, the quantity of straws consumed daily around the world is enormous.

すなわち、プラスチックからなる1本のストローは、体積が大きくないものの、毎日累積される使用数は非常に大きくなる。 That is, although the volume of one straw made of plastic is not large, the number of used straws accumulated every day is very large.

また、プラスチック製ストローの体積は小さいがために、リサイクルされた後の再利用率と価値が高くなく、また処理もしにくい。そのため、再利用されずに、世界で毎日極めて膨大な数量のストロー廃棄物が生まれている。この大量のプラスチック廃棄物は環境及び生物に有害であり、大量の海洋ごみを発生し、それを処理するのに膨大な処理コストを必要とする。 Moreover, since the volume of the plastic straw is small, the reuse rate and value after recycling are not high, and it is difficult to process. As a result, an extremely large amount of straw waste is generated every day in the world without being reused. This large amount of plastic waste is harmful to the environment and living organisms, generates a large amount of marine debris, and requires enormous processing costs to dispose of it.

このほか、プラスチック製ストローには、さらに可塑剤の残留または熱い飲料・温かい食品の飲食時に可塑剤が析出する問題も存在し、人体の健康にも有害である。 In addition, plastic straws also have the problem of residual plasticizer or precipitation of plasticizer when eating and drinking hot beverages and hot foods, which is harmful to human health.

そこで、今日では、プラスチック製ストローに替えて、例えば特許文献1で知られるような螺旋状紙管製造の技術を応用して作られた、紙製のストローが販売され、使用されている。 Therefore, today, instead of plastic straws, paper straws made by applying, for example, a technique for manufacturing a spiral paper tube as known in Patent Document 1, are sold and used.

しかしながら、現在の紙製ストローは、耐水性が低く、飲み物に浸している中、含水し、フニャフニャに柔らかくなってしまう。特に、近年、カフェチエーン店や喫茶店、コンビニエンスストア等では、フラッペのような中身をかき混ぜる必要のある飲み物を提供する店舗が増えている。そのような商材に対応するためには、水分中である程度剛性を保つことができる紙製ストローを提供する必要がある。 However, current paper straws have low water resistance and become moist and soft to fluffy while immersed in drinks. In particular, in recent years, cafe chain stores, coffee shops, convenience stores, and the like are increasing in number of stores offering drinks such as frappe that need to be agitated. In order to deal with such products, it is necessary to provide a paper straw that can maintain rigidity to some extent in moisture.

紙製ストローに耐久性を付与する代表的な方法としては、ヒートシール性と撥水性を有するコーティング剤を塗布した紙材を形成する方法が知られている(例えば、特許文献2参照)。そのコーティング剤としては、ポリエチレン樹脂、ポリビニルアルコール樹脂等の熱可塑性樹脂の溶液で、パラフィン等に溶かしたものである。 As a typical method for imparting durability to a paper straw, a method of forming a paper material coated with a coating agent having heat-sealing property and water repellency is known (see, for example, Patent Document 2). The coating agent is a solution of a thermoplastic resin such as a polyethylene resin or a polyvinyl alcohol resin, which is dissolved in paraffin or the like.

また、他の方法としては、通常の紙製のストローを形成し、その後、ワックスが入れられた中に浸して浸透させ、ストローの表面にワックスを積層させる方法がある。 Further, as another method, there is a method of forming a normal paper straw, then immersing it in a wax and allowing it to permeate, and laminating the wax on the surface of the straw.

特許第2914934号公報Japanese Patent No. 2914934 特開平6−133840号公報Japanese Unexamined Patent Publication No. 6-133840

しかしながら、特許文献1に記載のストローのように、原紙にヒートシール性と撥水性を有するコーティング剤を塗布した従来の方法では、ポリエチレン樹脂、ポリビニルアルコール樹脂等の熱可塑性樹脂の溶液に浸けるので、完全な脱プラスチックを達成できないという問題点があった。 However, in the conventional method of applying a coating agent having heat-sealing property and water repellency to the base paper like the straw described in Patent Document 1, it is immersed in a solution of a thermoplastic resin such as a polyethylene resin or a polyvinyl alcohol resin. There was a problem that complete deplasticization could not be achieved.

また、通常の紙製のストローを形成し、その後、ワックスが入れられた中に浸して浸透させ、ストローの表面にワックスを積層させる従来の方法では、連続生産ができず、生産効率が悪く、大量生産に向かない、という問題点があった。 Further, in the conventional method of forming a normal paper straw, then immersing it in a straw and infiltrating it, and laminating the wax on the surface of the straw, continuous production is not possible and the production efficiency is poor. There was a problem that it was not suitable for mass production.

そこで、プラスチックを用いずに、耐水性と剛性、及び、生産効率の高い紙製ストロー及びその製造方法を提供するために解決すべき技術的課題が生じてくるのであり、本発明はこの課題を解決することを目的とする。 Therefore, there arises a technical problem to be solved in order to provide a paper straw having high water resistance, rigidity, and production efficiency and a method for manufacturing the same without using plastic, and the present invention solves this problem. The purpose is to solve it.

本発明は上記目的を達成するために提案されたものであり、請求項1に記載の発明は、紙製ストローであって、前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来の耐水塗工剤を塗工した原紙を含み、前記原紙が、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回され、前記原紙の重ね合わされた部分を相互に密接固定して両端が連通している管体として形成されている、紙製ストローを提供する。 The present invention has been proposed to achieve the above object, and the invention according to claim 1 is a paper straw, which is naturally formed on at least one surface side which is an inner surface or an outer surface of the paper straw. The base paper is wound with a water-resistant coating agent derived from the base paper in a spiral manner while shifting the side edges by a predetermined amount in an oblique direction, and the overlapped portions of the base paper are closely attached to each other. Provided is a paper straw that is formed as a tube that is fixed and has both ends communicating.

この構成によれば、紙製ストローの内面または外面となる少なくとも一面側に、例えば天然の粘土を用いた耐水塗工剤、食物繊維の抽出物を用いた耐水塗工剤、生物由来のワックス成分(例えば、蜜ロウ、米ぬかロウ、カルナバロウ等の天然由来のロウ)等の、天然由来の耐水塗工剤を予め塗工した原紙を用いてストローを成型することで、プラスチックを用いずに、耐水性と剛性に優れた紙製ストローが得られる。また、予め耐水塗工剤を塗工してある原紙を用いてストローを成型することで、従来のワックスの中に浸して浸透させる方法に比べて生産効率が格段に向上する。 According to this configuration, on at least one side, which is the inner surface or the outer surface of the paper straw, for example, a water resistant coating agent using natural clay, a water resistant coating agent using an extract of dietary fiber, and a wax component derived from a living body. By molding a straw using a base paper that has been pre-coated with a naturally-derived water-resistant coating agent such as (for example, naturally-derived wax such as beeswax, rice bran wax, and carnauba wax), water resistance is not used without using plastic. A paper straw with excellent properties and rigidity can be obtained. Further, by molding the straw using the base paper coated with the water resistant coating agent in advance, the production efficiency is remarkably improved as compared with the conventional method of immersing and permeating the straw.

請求項2に記載の発明は、請求項1に記載の構成において、前記原紙は、前記内面と前記外面の両方の面にそれぞれ耐水塗工剤を塗工してなる、紙製ストローを提供する。 The invention according to claim 2 provides a paper straw in which, in the configuration according to claim 1, the base paper is coated with a water resistant coating agent on both the inner surface and the outer surface, respectively. ..

この構成によれば、内面と外面の両方の面にそれぞれ耐水塗工剤を塗工してある原紙を螺旋状に巻回して紙製ストローを作っているので、更に耐水性と剛性に優れた紙製ストローが得られる。 According to this configuration, a base paper coated with a water-resistant coating agent on both the inner and outer surfaces is spirally wound to make a paper straw, which is further excellent in water resistance and rigidity. A paper straw is obtained.

請求項3に記載の発明は、請求項1又は2に記載の構成において、前記原紙の重ね合わされる部分の固定に自然由来の糊を用いてなる、紙製ストローを提供する。 The invention according to claim 3 provides a paper straw in the configuration according to claim 1 or 2, wherein a naturally occurring glue is used to fix the overlapped portion of the base paper.

この構成によれば、原紙の重ね合わされる部分の接着固定に、自然由来の糊、例えば澱粉糊等を使用することで、プラスチック等の石化材料を全く用いない紙製ストローが得られる。 According to this configuration, by using a naturally-derived glue such as starch glue for adhesively fixing the overlapped portion of the base paper, a paper straw that does not use any petrified material such as plastic can be obtained.

請求項4に記載の発明は、請求項1、2又は3に記載の構成において、前記原紙が、前記紙製ストローの前記外面側に配置される表面に前記耐水塗工剤を塗工した外面原紙と、内面と外面のいずれの面にも耐水塗工剤を塗工してない中間原紙と、前記紙製ストローの前記内面側に配置される表面に前記耐水塗工剤を塗工した内面原紙を順に積層して一体化された積層原紙でなり、前記外面原紙の裏面側と前記中間原紙の前記外面との間、及び、前記内面原紙の裏面側と前記中間原紙の前記内面との間を、それぞれ糊を用いて密接固定してなる、紙製ストローを提供する。 The invention according to claim 4 is the outer surface in which the water resistant coating agent is applied to the surface of the base paper arranged on the outer surface side of the paper straw in the configuration according to claim 1, 2 or 3. The base paper, the intermediate base paper on which neither the inner surface nor the outer surface is coated with the water resistant coating agent, and the inner surface of the paper straw coated with the water resistant coating agent on the surface arranged on the inner surface side. It is a laminated base paper in which base papers are laminated in order and integrated, and between the back surface side of the outer surface base paper and the outer surface of the intermediate base paper, and between the back surface side of the inner surface base paper and the inner surface of the intermediate base paper. Provided are paper straws, each of which is closely fixed with glue.

この構成によれば、紙製ストローの外面側に配置される表面に耐水塗工剤を塗工した外面原紙の上に、内面と外面のいずれの面にも耐水塗工剤を塗工してない中間原紙と、紙製ストローの内面側に配置される面に耐水塗工剤を塗工した内面原紙を、順に積層して一体化された積層原紙を使用し、この積層原紙の側縁部を斜め方向に所定量ずつずらして重ねて螺旋状に巻回されて、両端が連通した管体を形成し、原紙の重ね合わさる部分を相互に密接固定して耐水塗工剤を形成するので、プラスチックを用いずに、更に耐水性と剛性に優れた紙製ストローが得られる。また、予め耐水塗工剤を塗工してある原紙を用いてストローを成型することで、従来のワックスの中に浸して浸透させる方法に比べて生産効率が格段に向上する。 According to this configuration, the water resistant coating agent is applied to both the inner surface and the outer surface on the outer surface base paper in which the surface arranged on the outer surface side of the paper straw is coated with the water resistant coating agent. A laminated base paper in which no intermediate base paper and an inner base paper in which a water-resistant coating agent is applied to the surface arranged on the inner surface side of a paper straw are laminated in order and integrated is used, and the side edge portion of this laminated base paper is used. Are stacked by a predetermined amount in an oblique direction and wound in a spiral shape to form a tubular body with both ends communicating with each other, and the overlapping parts of the base paper are closely fixed to each other to form a water resistant coating agent. A paper straw with excellent water resistance and rigidity can be obtained without using plastic. Further, by molding the straw using the base paper coated with the water resistant coating agent in advance, the production efficiency is remarkably improved as compared with the conventional method of immersing and permeating the straw.

請求項5に記載の発明は、紙製ストローの製造方法であって、前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来の耐水塗工剤を塗工した原紙を用意し、前記原紙を、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回するとともに、前記原紙の重ね合わされた部分を自然由来の糊を介して相互に密接固定し、両端が連通した管体として形成する、紙製ストローの製造方法を提供する。 The invention according to claim 5 is a method for producing a paper straw, in which a base paper to which a naturally-derived water-resistant coating agent is previously applied is prepared on at least one side which is the inner surface or the outer surface of the paper straw. , The base paper is stacked and spirally wound while shifting the side edges in a predetermined amount in an oblique direction, and the overlapped portions of the base paper are closely fixed to each other via naturally-derived glue, and both ends are Provided is a method for manufacturing a paper straw, which is formed as a continuous tube.

この方法によれば、紙製ストローの内面または外面となる少なくとも一面側に、例えば天然の粘土を用いた耐水塗工剤、食物繊維の抽出物を用いた耐水塗工剤、生物由来のワックス成分(例えば、蜜ロウ、米ぬかロウ、カルナバロウ等の天然由来のロウ)等の、天然由来の耐水塗工剤を予め塗工した原紙を用意してストローを成型することで、プラスチックを用いずに、耐水性と剛性に優れた紙製ストローが得られる。また、予めワックスを塗工してある原紙を用いてストローを成型することで、従来のワックスの中に浸して浸透させる方法に比べて生産効率が格段に向上する。 According to this method, on at least one side, which is the inner surface or the outer surface of a paper straw, for example, a water resistant coating agent using natural clay, a water resistant coating agent using an extract of dietary fiber, and a wax component derived from a living body. By preparing a base paper pre-coated with a naturally-derived water-resistant coating agent such as (for example, naturally-derived wax such as beeswax, rice bran wax, and carnauba wax) and molding a straw, without using plastic, A paper straw with excellent water resistance and rigidity can be obtained. Further, by molding the straw using the base paper coated with wax in advance, the production efficiency is remarkably improved as compared with the conventional method of immersing and permeating the straw.

発明によれば、予め耐水塗工剤を塗工した原紙を用いてストローを成型することで、プラスチックを用いずに、耐水性と剛性に優れたストローが得られる。また、予め耐水塗工剤を塗工してある原紙を用いてストローを成型することで、従来のワックスの中に浸して浸透させる方法に比べて生産効率が格段に向上する。 According to the invention, by molding a straw using a base paper coated with a water resistant coating agent in advance, a straw having excellent water resistance and rigidity can be obtained without using plastic. Further, by molding the straw using the base paper coated with the water resistant coating agent in advance, the production efficiency is remarkably improved as compared with the conventional method of immersing and permeating the straw.

本発明に係る紙製ストローの一実施例を示すもので、(a)はその側面図、(b)は(a)のA−A線方向から見た正面図である。An embodiment of a paper straw according to the present invention is shown, where (a) is a side view thereof, and (b) is a front view of (a) seen from the direction of the AA line. 同上紙製ストローを形成する前のテープ状をし、かつ、一面にワックスを塗工した原紙を示すもので、(a)は原紙の平面図、(b)は原紙の側面図である。The same as above shows a base paper which is in the shape of a tape before forming a straw made of paper and has wax coated on one side. (A) is a plan view of the base paper, and (b) is a side view of the base paper. 同上紙製ストローを形成する途中の状態を概略的に示す斜視図である。It is a perspective view which shows roughly the state in the process of forming the straw made by the said paper. 同上紙製ストローを形成する、一面にワックスを塗工したテープ状の原紙を形成する装置の一例を模式的に示す構成配置図である。It is a configuration layout diagram schematically showing an example of an apparatus for forming a tape-shaped base paper coated with wax on one surface for forming a straw made of the same paper. 本発明に係る紙製ストローの他の実施例を説明するもので、(a)は同上紙製ストローを形成する前のテープ状をした原紙の側面図、(b)はその原紙の展開平面図、(c)はその原紙の展開側面図である。Another embodiment of the paper straw according to the present invention will be described, where (a) is a side view of a tape-shaped base paper before forming the same paper straw, and (b) is a developed plan view of the base paper. , (C) is a developed side view of the base paper. 紙製ストローの実験結果を示す図である。It is a figure which shows the experimental result of the paper straw.

本発明はプラスチックを用いずに、耐水性と剛性、及び、生産効率の高い紙製ストロー及び紙製ストローの製造方法を提供するという目的を達成するために、紙製ストローであって、前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来の耐水塗工剤を塗工した原紙を含み、前記原紙が、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回され、前記原紙の重ね合わされた部分を相互に密接固定して両端が連通している管体として形成されている、構成にしたことにより実現した。 The present invention is a paper straw according to the present invention, in order to achieve the object of providing a paper straw having high water resistance, rigidity, and production efficiency and a method for manufacturing a paper straw without using plastic. At least one surface, which is the inner surface or the outer surface of the straw, contains a base paper coated with a naturally-derived water-resistant coating agent in advance, and the base paper is stacked in a spiral shape while shifting the side edges in a predetermined amount in an oblique direction. This was achieved by winding the base paper and fixing the overlapped portions of the base paper closely to each other to form a tubular body in which both ends communicate with each other.

以下、本発明の実施形態に係る一実施例を添付図面に基づいて詳細に説明する。なお、以下の実施例において、構成要素等の形状、位置関係に言及するときは、特に明示した場合及び原理的に明らかにそうでないと考えられる場合等を除き、実質的にその形状等に近似又は類似するもの等を含む。 Hereinafter, an embodiment according to an embodiment of the present invention will be described in detail with reference to the accompanying drawings. In the following examples, when referring to the shape and positional relationship of the components, etc., they are substantially approximated to the shape, etc., except when explicitly stated or when it is considered that it is not apparent in principle. Or similar ones are included.

また、図面は、特徴を分かり易くするために特徴的な部分を拡大する等して誇張する場合があり、構成要素の寸法比率等が実際と同じであるとは限らない。また、実施例の説明の全体を通じて同じ要素には同じ符号を付している。 In addition, the drawings may be exaggerated by enlarging the characteristic parts in order to make the features easy to understand, and the dimensional ratios and the like of the components are not always the same as the actual ones. In addition, the same elements are designated by the same reference numerals throughout the description of the examples.

図1は本発明に係る紙製ストローの一実施例を示すもので、同図(a)はその外観斜視図、同図(b)は(a)のA−A線方向から見た正面図である。 FIG. 1 shows an embodiment of a paper straw according to the present invention, in which FIG. 1A is an external perspective view thereof, and FIG. 1B is a front view seen from the direction of AA in FIG. Is.

図1に示す紙製ストロー10は、耐水性を有し、かつ可燃ゴミとして廃棄できる原紙11によって構成されている。原紙11は、図2に示すようにテープ状に形成されており、紙製ストロー10の外面側となる外面11Aに、予め耐水塗工剤としてのワックス15が塗工されている。反対に、紙製ストローの内面側となる内面11Bには、内面11Bの全面に接着剤12が塗布される、なお、符号11Cで示す部分は、原紙11を重ね巻きして接着する接着しろである。 The paper straw 10 shown in FIG. 1 is made of a base paper 11 that has water resistance and can be disposed of as combustible waste. As shown in FIG. 2, the base paper 11 is formed in a tape shape, and the outer surface 11A on the outer surface side of the paper straw 10 is previously coated with wax 15 as a water resistant coating agent. On the contrary, the adhesive 12 is applied to the entire surface of the inner surface 11B, which is the inner surface side of the paper straw, and the portion indicated by the reference numeral 11C is an adhesive margin in which the base paper 11 is laminated and adhered. is there.

なお、原紙11の一面、すなわち外面11Aに塗工された耐水塗工剤としてのワックス15は、例えば蜜ロウ、米ぬかロウ、カルナバロウ等、天然由来のロウが使用される。本実施例では、耐水塗工剤としてワックス15を使用した一例を説明するが、このワックス15以外にも、耐水塗工剤として、例えば天然の粘土を用いた耐水塗工剤、食物繊維の抽出物を用いた耐水塗工剤、生物由来のワックス成分等を使用してもよい。
一方、接着剤12としては、デンプン糊等の自然由来の糊を使用する。これにより、プラスチック等の石化材料を全く用いない紙製ストロー10を目指す。
As the wax 15 as a water resistant coating agent coated on one surface of the base paper 11, that is, the outer surface 11A, naturally derived waxes such as beeswax, rice bran wax, and carnauba wax are used. In this embodiment, an example in which wax 15 is used as the water resistant coating agent will be described. In addition to the wax 15, for example, a water resistant coating agent using natural clay and extraction of dietary fiber are used as the water resistant coating agent. A water resistant coating agent using a material, a wax component derived from a living body, or the like may be used.
On the other hand, as the adhesive 12, a naturally derived glue such as starch glue is used. As a result, we aim to create a paper straw 10 that does not use any petrified material such as plastic.

次に、以上の材料で形成される紙製ストロー10の製造方法を説明する。 Next, a method for manufacturing the paper straw 10 formed of the above materials will be described.

まず、外面11Aにワックス15が塗工されて耐久性を有する、テープ状の原紙11を用意する。 First, a tape-shaped base paper 11 is prepared, in which the outer surface 11A is coated with wax 15 and has durability.

次いで、内面11Bの全面に接着剤12を塗布し、図3に示すように成型設備(図示しない)におけるロール軸13の中心軸線Oに沿って原紙11を、斜め方向に所定量(本実施例では接着しろ11Cの幅W1)ずつずらしながら螺旋状に巻回し、両端が連通した1つの螺旋管体14を形成する。この巻回時、原紙11の内面11B側に塗付されている接着剤12により、原紙11の重なり合う部分(接着しろ11Cの幅W1の箇所)が相互に接着固定される。 Next, the adhesive 12 is applied to the entire surface of the inner surface 11B, and as shown in FIG. 3, a predetermined amount of the base paper 11 is obliquely applied along the central axis O of the roll shaft 13 in the molding facility (not shown) (this embodiment). Then, the adhesive margin 11C is wound in a spiral shape while shifting by 1) to form one spiral tube body 14 in which both ends communicate with each other. At the time of this winding, the overlapping portion of the base paper 11 (the portion of the width W1 of the adhesive margin 11C) is adhered and fixed to each other by the adhesive 12 applied to the inner surface 11B side of the base paper 11.

また、一定長さに巻回したら切断すると、図1に示す両端が連通した紙製ストロー10の形成が完了する。 Further, when the straw is wound to a certain length and cut, the formation of the paper straw 10 having both ends communicating with each other as shown in FIG. 1 is completed.

このように形成された紙製ストロー10は、プラスチック等の石化材料を全く用いない紙製ストロー10として提供することができる。そして、紙製ストロー10では、原紙11の外面11Aにワックス15が塗工されているので、そのワックス15により耐水性と剛性を高め、耐水性と剛性に優れたストローが得られる。また、予めワックス15を塗工してある原紙11を用いて、両端が連通した管体であるストローを成型することで、従来のワックスの中に下して浸透させる方法に比べて生産効率も格段に向上する。 The paper straw 10 thus formed can be provided as a paper straw 10 that does not use any petrified material such as plastic. In the paper straw 10, since the wax 15 is coated on the outer surface 11A of the base paper 11, the wax 15 enhances the water resistance and rigidity, and a straw having excellent water resistance and rigidity can be obtained. In addition, by molding a straw, which is a tube body in which both ends communicate with each other, using a base paper 11 coated with wax 15 in advance, the production efficiency is higher than that of the conventional method of lowering and infiltrating into wax. It will improve dramatically.

なお、図1及び図2に、原紙11の幅を符号W0、重なる部分である接着しろ11Cの幅を符号W1で示すように、紙製ストロー10では、重ねられる部分である接着しろ11Cの幅W1は螺旋管体14の強度を決定できる。例えば、重なる部分となる接着しろ11Cの幅W1が大きいほど、より硬く、湾曲し難くなるが、逆に接着しろ11Cの幅W1が小さいほど、螺旋管体14は柔軟になり、湾曲し易くなる。 In addition, as shown in FIGS. 1 and 2 that the width of the base paper 11 is indicated by reference numeral W0 and the width of the overlapping portion of the adhesive margin 11C is indicated by the reference numeral W1, in the paper straw 10, the width of the adhesive margin 11C which is an overlapping portion is shown. W1 can determine the strength of the spiral tube 14. For example, the larger the width W1 of the adhesive margin 11C that is the overlapping portion, the harder it is and the more difficult it is to bend. On the contrary, the smaller the width W1 of the adhesive margin 11C, the more flexible the spiral tube 14 becomes and the easier it is to bend. ..

このため、巻回時に重なる部分(接着しろ11C)の幅W1を調整し、重なる部分の幅W1を原紙11の幅W0の約2分の1から4分の1の間で変化させると、硬さと、柔らかさを変化させることができ、紙製ストロー10に使用上の利便性と高品質を実現する。 Therefore, when the width W1 of the overlapping portion (adhesion margin 11C) is adjusted during winding and the width W1 of the overlapping portion is changed between about one-half to one-fourth of the width W0 of the base paper 11, it is hard. The softness can be changed, and the paper straw 10 realizes convenience and high quality in use.

図4は、予め紙製ストロー10の外周面となる外面11Aにワックス15を塗工するワックス塗工装置20の一構成例を模式的に示す構成配置図である。図4において、ワックス塗工装置20は、溶融されたワックス15を入れたワックス貯留槽21、一対の回動ローラ22A、22B、複数のガイドローラ23、原紙供給リール24、原紙巻取リール25等で構成されている。 FIG. 4 is a configuration layout diagram schematically showing a configuration example of a wax coating device 20 that previously coats the outer surface 11A, which is the outer peripheral surface of the paper straw 10, with the wax 15. In FIG. 4, the wax coating device 20 includes a wax storage tank 21 containing the molten wax 15, a pair of rotating rollers 22A and 22B, a plurality of guide rollers 23, a base paper supply reel 24, a base paper take-up reel 25, and the like. It is composed of.

一対の回動ローラ22A、22Bの中、回動ローラ22Aの外周面の一部はワックス貯留槽21内に浸され、外周面にワックス15を含ませた状態で回転するようにして配置されている。一方、回動ローラ22Bは、回動ローラ22Aと回動ローラ22Bとの間を通るテープ状の原紙11を回動ローラ22Aに圧着させるピンチローラである。また、図4にそれぞれ矢印で回転方向及び移動方向を示すように、回動ローラ22Aは時計回り方向に回転し、回動ローラ22Bは反時計回り方向に回転する。 Of the pair of rotating rollers 22A and 22B, a part of the outer peripheral surface of the rotating roller 22A is immersed in the wax storage tank 21, and is arranged so as to rotate with the wax 15 included in the outer peripheral surface. There is. On the other hand, the rotating roller 22B is a pinch roller that crimps the tape-shaped base paper 11 passing between the rotating roller 22A and the rotating roller 22B to the rotating roller 22A. Further, as shown by arrows in FIG. 4, the rotating roller 22A rotates in the clockwise direction, and the rotating roller 22B rotates in the counterclockwise direction.

原紙供給リール24は、ワックス塗工前の原紙11を巻回保持しているリールであり、原紙巻取リール25は、ワックス塗工後の原紙11を巻回保持するリールである。 The base paper supply reel 24 is a reel that winds and holds the base paper 11 before wax coating, and the base paper winding reel 25 is a reel that winds and holds the base paper 11 after wax coating.

複数のガイドローラ23は、原紙供給リール24から引き出された原紙11を一対の回動ローラ22A、22Bの間を通って原紙巻取リール25にガイドするためのローラである。 The plurality of guide rollers 23 are rollers for guiding the base paper 11 drawn from the base paper supply reel 24 to the base paper take-up reel 25 through between the pair of rotating rollers 22A and 22B.

原紙巻取リール25は、一対の回動ローラ22A、22Bの間を通ってワックス塗工の処理を終えた原紙11を巻き取るためのリールである。 The base paper take-up reel 25 is a reel for winding the base paper 11 which has been wax-coated by passing between the pair of rotating rollers 22A and 22B.

このように構成されたワックス塗工装置20では、原紙供給リール24から引き出された原紙11を、ガイドローラ23により一対の回動ローラ22A、22Bの間に導き、また、一対の回動ローラ22A、22Bの間を通った原紙11を、ガイドローラ23により原紙巻取リール25に導き、その原紙巻取リール25で原紙11を巻き取るようになっている。また、その原紙搬送の途中、ワックス貯留槽21内のワックス15が回動ローラ22Aによって原紙11の外面11Aに塗布される。これにより、紙製ストロー10の外周面となる原紙11の外面11Aに、予めワックス15を塗工してなる原紙11が完成する。なお、原紙11の内面11Bへの接着剤12の塗布は、原紙11を螺旋状に巻回処理する直前に行う。 In the wax coating device 20 configured in this way, the base paper 11 drawn from the base paper supply reel 24 is guided between the pair of rotating rollers 22A and 22B by the guide roller 23, and the pair of rotating rollers 22A. , The base paper 11 that has passed between 22B is guided to the base paper take-up reel 25 by the guide roller 23, and the base paper 11 is taken up by the base paper take-up reel 25. Further, during the transportation of the base paper, the wax 15 in the wax storage tank 21 is applied to the outer surface 11A of the base paper 11 by the rotating roller 22A. As a result, the base paper 11 formed by applying wax 15 in advance to the outer surface 11A of the base paper 11 which is the outer peripheral surface of the paper straw 10 is completed. The adhesive 12 is applied to the inner surface 11B of the base paper 11 immediately before the base paper 11 is spirally wound.

なお、上記実施例では、原紙11の外面11A側にだけワックス15を塗工した場合を説明したが、原紙11の外面11Aに替えて、原紙11の内面11B側にだけワックス15を塗工してなる原紙11を使用してもよく、また、原紙11の外面11Aと内面11Bの両方の面にワックス15を塗工した原紙11を使用して紙製ストロー10を形成してもよいものである。このように、外面11Aと内面11Bの両面にワックス15を塗工した原紙11を使用した場合では、更に耐水性と剛性に優れた紙製ストロー10が得られる。 In the above embodiment, the case where the wax 15 is applied only to the outer surface 11A side of the base paper 11 has been described, but instead of the outer surface 11A of the base paper 11, the wax 15 is applied only to the inner surface 11B side of the base paper 11. A base paper 11 made of wax may be used, or a paper straw 10 may be formed by using a base paper 11 coated with wax 15 on both the outer surface 11A and the inner surface 11B of the base paper 11. is there. As described above, when the base paper 11 in which the wax 15 is applied to both the outer surface 11A and the inner surface 11B is used, a paper straw 10 having further excellent water resistance and rigidity can be obtained.

また、例えば図5に示すように、成形時に、外面側に配置される外面11Aにワックス15を塗工した外面原紙111と、上下両面に自然由来の糊である接着剤12を塗布して、ワックス15は塗工してない中間原紙112と、内面側に配置される内面11Bにワックス15を塗工した内面原紙113、を積層して使用する原紙(積層原紙)11を用いてもストローを成形することができる。 Further, for example, as shown in FIG. 5, at the time of molding, the outer surface base paper 111 in which the wax 15 is applied to the outer surface 11A arranged on the outer surface side and the adhesive 12 which is a naturally derived glue are applied to both the upper and lower surfaces. The wax 15 can be straw even if the base paper (laminated base paper) 11 used by laminating the uncoated intermediate base paper 112 and the inner surface base paper 113 in which the wax 15 is coated on the inner surface 11B arranged on the inner surface side is used. Can be molded.

すなわち、図5に示す原紙(積層原紙)11を用いて紙製ストロー10を成形する場合は、例えば外面原紙111と中間原紙112と内面原紙113をそれぞれ別々の位置から設備のロール軸13に送り出す。また、送り出しの途中で、外面原紙111及び内面原紙113と重なる中間原紙112の部分に、接着剤12が塗布される。さらに、外面原紙111、中間原紙112、内面原紙113を、ロール軸13上でそれぞれ中心軸線Oに沿って少しずつ幅(例えば、接着しろ11Cに相当する幅W1)をずらしながら重ねて螺旋状に巻く。また、一定長さに巻回したら切断すると、図1に示す紙製ストロー10と同様に、両端が連通した紙製ストロー10の形成が完了する。 That is, when the paper straw 10 is molded using the base paper (laminated base paper) 11 shown in FIG. 5, for example, the outer base paper 111, the intermediate base paper 112, and the inner base paper 113 are sent from different positions to the roll shaft 13 of the equipment. .. Further, in the middle of feeding, the adhesive 12 is applied to the portion of the intermediate base paper 112 that overlaps the outer base paper 111 and the inner base paper 113. Further, the outer base paper 111, the intermediate base paper 112, and the inner base paper 113 are stacked on the roll axis 13 along the central axis O little by little (for example, the width W1 corresponding to the bonding margin 11C) to form a spiral. Roll. Further, when the straw is wound to a certain length and then cut, the formation of the paper straw 10 having both ends communicating with each other is completed as in the case of the paper straw 10 shown in FIG.

この図5に示した原紙11を使用した変形例の場合も、プラスチック等の石化材料を全く用いない紙製ストロー10として提供することができる。そして、紙製ストロー10では、原紙11の外面11A(外面原紙111の上面)と内面11B(内面原紙113の下面)とにそれぞれ、予めワックス15を塗工しているので、ワックス15により耐水性と剛性を高め、耐水性と剛性に優れたストローが得られる。また、予めワックス15を塗工してある原紙11を用いて両端が連通した管体であるストローを成型するので、従来のワックスの中に下して浸透させる方法に比べて生産効率も格段に向上する。 Also in the case of the modified example using the base paper 11 shown in FIG. 5, it can be provided as a paper straw 10 that does not use any petrified material such as plastic. In the paper straw 10, the wax 15 is previously applied to the outer surface 11A (upper surface of the outer base paper 111) and the inner surface 11B (lower surface of the inner base paper 113) of the base paper 11, so that the wax 15 is water resistant. A straw with excellent water resistance and rigidity can be obtained by increasing the rigidity. In addition, since the straw, which is a tube body in which both ends are communicated with each other, is molded using the base paper 11 coated with wax 15 in advance, the production efficiency is significantly higher than that of the conventional method of infiltrating the straw into the wax. improves.

図6は、各実施例毎の実験結果を示す。実験では、試料(イ)、試料(イ)、試料(ロ)、試料(ハ)、試料(ニ)の4つについて検証した。実験で使用した試料(イ)は、表裏両面共にワックス塗工をしていない晒のクラフト原紙を使用した紙製ストロー、試料(ロ)は、図1から図4に示した内面11Bのみワックス塗工をしてなる原紙11を使用した紙製ストロー、試料(ハ)は、外面11Aのみ、ワックス塗工をしてなる原紙11を使用した紙製ストロー、試料(ニ)は、図5に示した、外面11Aと内面11B共にワックス塗工をしてなる原紙11を使用した紙製ストローである。 FIG. 6 shows the experimental results for each example. In the experiment, four samples (a), sample (a), sample (b), sample (c), and sample (d) were verified. The sample (a) used in the experiment is a paper straw using bleached kraft base paper that has not been waxed on both the front and back sides, and the sample (b) is waxed only on the inner surface 11B shown in FIGS. 1 to 4. The paper straw and sample (c) using the processed base paper 11 are shown on the outer surface 11A only, and the paper straw and sample (d) using the wax-coated base paper 11 are shown in FIG. Further, it is a paper straw using a base paper 11 which is wax-coated on both the outer surface 11A and the inner surface 11B.

実験では、試料(イ)〜(ニ)で形成された各紙ストローを水中に、10分浸漬した場合、20分浸漬した場合、30分浸漬した場合、40分浸漬した場合、50分浸漬した場合、60分浸漬した場合において、それぞれの状態を検証した。 In the experiment, each paper straw formed from the samples (a) to (d) was immersed in water for 10 minutes, 20 minutes, 30 minutes, 40 minutes, and 50 minutes. , Each state was verified when immersed for 60 minutes.

その結果、試料(イ)の、表裏両面共にワックス塗工をしていない晒のクラフト原紙を使用した紙製ストローでは、水に10分浸漬しただけで含水し、軟化が見られた。また、20分では端部の剥がれや毛羽立ちの発生があり、さらにクラフト原紙に印刷されているインクの溶出もあった。 As a result, in the paper straw of the sample (a) using the bleached kraft base paper which was not wax-coated on both the front and back sides, the straw was moistened and softened only by immersing it in water for 10 minutes. In addition, in 20 minutes, the edges were peeled off and fluffing occurred, and the ink printed on the kraft base paper was also eluted.

一方、試料(ロ)の、内面11Bのみワックス塗工をしてなる原紙11を使用した紙製ストローでは、10分〜30分浸した場合では、若干の軟化があった程度であるが、40分〜60分浸すと軟化の進行及び含水が見られた。 On the other hand, in the paper straw of the sample (b) using the base paper 11 in which only the inner surface 11B is wax-coated, there was only a slight softening when soaked for 10 to 30 minutes. After soaking for 1 to 60 minutes, softening progress and water content were observed.

試料(ハ)の、外面11Aのみワックス塗工をしてなる原紙11を使用した紙製ストローでは、10分〜40分浸した場合では、若干の軟化があった程度であるが、50分〜60分浸すと軟化の進行及び含水が見られた。 In the paper straw of the sample (c) using the base paper 11 in which only the outer surface 11A is wax-coated, when soaked for 10 to 40 minutes, there was only a slight softening, but 50 minutes to After soaking for 60 minutes, progress of softening and water content were observed.

試料(ニ)の、外面11Aと内面11Bの両面にワックス塗工をしてなる原紙11を使用した紙製ストローでは、20分浸したまでは浸水もなく元のままで、30分〜60分浸すと若干の軟化及び含水が見られた。 In the paper straw of the sample (d), which uses the base paper 11 in which both the outer surface 11A and the inner surface 11B are wax-coated, the straw remains as it is without water immersion until it is soaked for 20 minutes, and remains as it is for 30 to 60 minutes. Some softening and water content were observed when soaked.

したがって、本発明を適用した試料(ロ)、(ハ)、(ニ)の紙製ストロー10の場合では、(イ)に示す従来の紙製ストローと比べると、耐水性と剛性が格段に向上していることが判った。 Therefore, in the case of the paper straws 10 of the samples (b), (c), and (d) to which the present invention is applied, the water resistance and rigidity are remarkably improved as compared with the conventional paper straws shown in (a). I found out that I was doing it.

なお、本発明は、本発明の精神を逸脱しない限り種々の改変を成すことができ、そして、本発明が該改変されたものに及ぶことは当然である。 It should be noted that the present invention can be modified in various ways as long as it does not deviate from the spirit of the present invention, and it is natural that the present invention extends to the modified ones.

10 :紙製ストロー
11 :原紙
11A :外面
11B :内面
12 :接着剤
13 :ロール軸
14 :螺旋管体
15 :ワックス(耐水塗工剤)
20 :ワックス塗工装置
21 :ワックス塗布ローラ槽
22A :回動ローラ
22B :回動ローラ
23 :ガイドローラ
24 :原紙供給リール
25 :原紙巻取リール
111 :外面原紙
112 :中間原紙
113 :内面原紙
O :中心軸線
W0 :原紙の幅
W1 :接着しろの幅(重なる部分)
10: Paper straw 11: Base paper 11A: Outer surface 11B: Inner surface 12: Adhesive 13: Roll shaft 14: Spiral tube 15: Wax (water resistant coating agent)
20: Wax coating device 21: Wax coating roller tank 22A: Rotating roller 22B: Rotating roller 23: Guide roller 24: Base paper supply reel 25: Base paper take-up reel 111: Outer surface base paper 112: Intermediate base paper 113: Inner surface base paper O : Central axis W0: Base paper width W1: Adhesion margin width (overlapping part)

本発明は上記目的を達成するために提案されたものであり、請求項1に記載の発明は、紙製ストローであって、前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来の耐水塗工剤を塗工した原紙を含み、前記原紙が、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回され、前記原紙の重ね合わされた部分を相互に密接固定して両端が連通している管体として形成され、前記耐水塗工剤は、天然由来のワックスである、紙製ストローを提供する。 The present invention has been proposed to achieve the above object, and the invention according to claim 1 is a paper straw, which is naturally formed on at least one surface side which is an inner surface or an outer surface of the paper straw. The base paper is wound with a water-resistant coating agent derived from the base paper in a spiral manner while shifting the side edges by a predetermined amount in an oblique direction, and the overlapped portions of the base paper are closely attached to each other. The water resistant coating agent, which is formed as a tubular body that is fixed and has both ends communicating with each other, provides a paper straw , which is a naturally occurring wax .

この構成によれば、紙製ストローの内面または外面となる少なくとも一面側に、生物由来のワックス成分(例えば、蜜ロウ、米ぬかロウ、カルナバロウ等の天然由来のロウ)等の、天然由来の耐水塗工剤を予め塗工した原紙を用いてストローを成型することで、プラスチックを用いずに、耐水性と剛性に優れた紙製ストローが得られる。また、予め耐水塗工剤を塗工してある原紙を用いてストローを成型することで、従来のワックスの中に浸して浸透させる方法に比べて生産効率が格段に向上する。 According to this configuration, at least on one side a paper straws inner or outer surface, a wax component derived from the raw material (e.g., beeswax, rice bran wax, wax of natural origin such as carnauba wax), such as, water of natural origin By molding the straw using a base paper coated with a coating agent in advance, a paper straw having excellent water resistance and rigidity can be obtained without using plastic. Further, by molding the straw using the base paper coated with the water resistant coating agent in advance, the production efficiency is remarkably improved as compared with the conventional method of immersing and permeating the straw.

請求項5に記載の発明は、紙製ストローの製造方法であって、前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来のワックスを塗工した原紙を用意し、前記原紙を、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回するとともに、前記原紙の重ね合わされた部分を自然由来の糊を介して相互に密接固定し、両端が連通した管体として形成する、紙製ストローの製造方法を提供する。 The invention according to claim 5 is a method for producing a paper straw, wherein a base paper coated with a naturally-derived wax in advance on at least one side which is an inner surface or an outer surface of the paper straw is prepared, and the base paper is prepared. , While shifting the side edges diagonally by a predetermined amount and winding them in a spiral shape, the overlapped parts of the base paper are closely fixed to each other via naturally derived glue, and both ends are communicated with each other. Provided is a method for producing a paper straw formed as a body.

この方法によれば、紙製ストローの内面または外面となる少なくとも一面側に、生物由来のワックス成分(例えば、蜜ロウ、米ぬかロウ、カルナバロウ等の天然由来のロウ)等の、天然由来の耐水塗工剤を予め塗工した原紙を用意してストローを成型することで、プラスチックを用いずに、耐水性と剛性に優れた紙製ストローが得られる。また、予めワックスを塗工してある原紙を用いてストローを成型することで、従来のワックスの中に浸して浸透させる方法に比べて生産効率が格段に向上する。 According to this method, at least on one side a paper straws inner or outer surface, a wax component derived from the raw material (e.g., beeswax, rice bran wax, wax of natural origin such as carnauba wax), such as, water of natural origin By preparing a base paper coated with a coating agent in advance and molding the straw, a paper straw having excellent water resistance and rigidity can be obtained without using plastic. Further, by molding the straw using the base paper coated with wax in advance, the production efficiency is remarkably improved as compared with the conventional method of immersing and permeating the straw.

Claims (5)

紙製ストローであって、
前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来の耐水塗工剤を塗工した原紙を含み、
前記原紙が、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回され、前記原紙の重ね合わされた部分を相互に密接固定して両端が連通している管体として形成されている、
ことを特徴とする紙製ストロー。
It ’s a paper straw,
At least one side, which is the inner surface or the outer surface of the paper straw, contains a base paper previously coated with a naturally-derived water-resistant coating agent.
The base paper is spirally wound by stacking the side edges while shifting the side edges by a predetermined amount, and the overlapped portions of the base paper are closely fixed to each other to form a tube body in which both ends communicate with each other. ing,
A paper straw that features that.
前記原紙は、前記内面と前記外面の両方の面にそれぞれ耐水塗工剤を塗工してなる、
ことを特徴とする請求項1に記載の紙製ストロー。
The base paper is formed by applying a water resistant coating agent to both the inner surface and the outer surface.
The paper straw according to claim 1, wherein the straw is made of paper.
前記原紙の重ね合わされる部分の固定に自然由来の糊を用いてなる、
ことを特徴とする請求項1又は2に記載の紙製ストロー。
Naturally-derived glue is used to fix the overlapped portion of the base paper.
The paper straw according to claim 1 or 2, wherein the straw is made of paper.
前記原紙が、前記紙製ストローの前記外面側に配置される表面に前記耐水塗工剤を塗工した外面原紙と、内面と外面のいずれの面にも耐水塗工剤を塗工してない中間原紙と、前記紙製ストローの前記内面側に配置される表面に前記耐水塗工剤を塗工した内面原紙を順に積層して一体化された積層原紙でなり、
前記外面原紙の裏面側と前記中間原紙の前記外面との間、及び、前記内面原紙の裏面側と前記中間原紙の前記内面との間を、それぞれ糊を用いて密接固定してなる、
ことを特徴とする請求項1、2又は3に記載の紙製ストロー。
The base paper is the outer base paper on which the water resistant coating agent is applied to the surface arranged on the outer surface side of the paper straw, and neither the inner surface nor the outer surface is coated with the water resistant coating agent. It is a laminated base paper in which an intermediate base paper and an inner base paper coated with the water resistant coating agent on the surface arranged on the inner surface side of the paper straw are laminated in order and integrated.
The back side of the outer base paper and the outer surface of the intermediate base paper, and the back side of the inner base paper and the inner surface of the intermediate base paper are closely fixed with glue, respectively.
The paper straw according to claim 1, 2 or 3, wherein the straw is made of paper.
紙製ストローの製造方法であって、
前記紙製ストローの内面または外面となる少なくとも一面側に、予め天然由来の耐水塗工剤を塗工した原紙を用意し、
前記原紙を、側縁部を斜め方向に所定量ずつずらしながら重ねて螺旋状に巻回するとともに、前記原紙の重ね合わされた部分を自然由来の糊を介して相互に密接固定し、両端が連通した管体として形成する、
ことを特徴とする紙製ストローの製造方法。
It ’s a method of manufacturing paper straws.
Prepare a base paper that has been previously coated with a naturally-derived water-resistant coating agent on at least one side that will be the inner or outer surface of the paper straw.
The base papers are stacked and spirally wound while shifting the side edges in a predetermined amount in an oblique direction, and the overlapped portions of the base papers are closely fixed to each other via naturally derived glue, and both ends communicate with each other. Form as a tubular body,
A method of manufacturing a paper straw, which is characterized by this.
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JP7465571B2 (en) 2022-06-22 2024-04-11 株式会社Ky7 Paper-based materials, lids, containers with lids, and combinations of lids and containers

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JPH10337790A (en) * 1997-06-06 1998-12-22 Mitsuya Tekko Kk Method and apparatus for manufacture of spiral paper tube
JP2003508309A (en) * 1999-09-01 2003-03-04 バイオガイア・エイビー Distribution tube
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JP2006068307A (en) * 2004-09-02 2006-03-16 Showa Marutsutsu Co Ltd Paper shaft, paper muddler, paper spoon and paper knife
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JP3216663U (en) * 2018-04-03 2018-06-14 ▲ユ▼▲ティン▼ 許 Drinking paper straws

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JPS56101088U (en) * 1979-11-28 1981-08-08
JPH02163058A (en) * 1988-12-14 1990-06-22 Toyo Ink Mfg Co Ltd Pressure-sensitive transfer material for food
JPH06133840A (en) * 1992-10-26 1994-05-17 Shigeru Nakagawa Paper tube
JPH10337790A (en) * 1997-06-06 1998-12-22 Mitsuya Tekko Kk Method and apparatus for manufacture of spiral paper tube
JP2003508309A (en) * 1999-09-01 2003-03-04 バイオガイア・エイビー Distribution tube
JP2003135241A (en) * 2001-11-08 2003-05-13 Hyozaemon:Kk Utensile for eating and drinking and sales method for the utensile for eating and drinking
JP2006068307A (en) * 2004-09-02 2006-03-16 Showa Marutsutsu Co Ltd Paper shaft, paper muddler, paper spoon and paper knife
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Publication number Priority date Publication date Assignee Title
JP7465571B2 (en) 2022-06-22 2024-04-11 株式会社Ky7 Paper-based materials, lids, containers with lids, and combinations of lids and containers

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