JP2020171202A - Scratch-frozen dough dual use improving agent and method of producing sweetened sponge bread using the agent - Google Patents

Scratch-frozen dough dual use improving agent and method of producing sweetened sponge bread using the agent Download PDF

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JP2020171202A
JP2020171202A JP2019073603A JP2019073603A JP2020171202A JP 2020171202 A JP2020171202 A JP 2020171202A JP 2019073603 A JP2019073603 A JP 2019073603A JP 2019073603 A JP2019073603 A JP 2019073603A JP 2020171202 A JP2020171202 A JP 2020171202A
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JP7316825B2 (en
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啓輔 高橋
Hirosuke Takahashi
啓輔 高橋
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Mitsubishi Corp Life Sciences Ltd
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Abstract

To provide a scratch-frozen dough dual use improving agent added to sweetened sponge dough which contains materials at the same ratio as the scratch process, the sweetened sponge dough being made by applying kneading and primary fermentation (floor time), and capable of being preserved by freezing after division and shaping, and the improving agent capable of keeping chewy texture and volume.SOLUTION: There is provided a method of producing bread using frozen and defrosted bread dough, the method comprising making sponge dough which includes a total gas quantity of 0.3-0.7 mL/g two hours later after fermentation, and comprising a composition obtained by thermally treating a solution for 30 minutes or longer at 65°C or more, the solution containing, in bread dough made by kneading the sponge dough with kneading dough, gluten and an organic acid which includes, in the same molecule, 0.5 pt.wt. or more of two or more carbonyl groups relative to 100 pts.wt. of gluten.EFFECT: According to the present invention, regarding the composition obtained by thermally treating gluten with the organic acid which includes, in the same molecule, two or more carbonyl groups, when it is added to bread dough made by the sweetened sponge process, it is effective for keeping particularly chewy texture and volume even after being preserved by freezing, and it further improves coarse of inner phase.SELECTED DRAWING: None

Description

本発明は、加糖中種製法で作製したパン生地を冷凍保存しても、冷凍障害を軽減することの出来るパン生地改良剤と当該剤を使用した加糖中種製法のパンの製造方法に関する。 The present invention relates to a bread dough improving agent capable of reducing freezing damage even when the bread dough produced by the sweetened medium seed production method is stored frozen, and a method for producing bread by the sweetened medium seed production method using the agent.

食事にパンを食べる習慣は高齢者世代にも根付き、一世帯あたりのパン消費量は近年増加傾向にある。さらに、パン食の習慣が根付いた結果、消費者にパンを提供するスタイルも多様化し、従来通りのスーパー、コンビニ、リテイルベーカリーに加えて、カフェやホテルなど他業種のサービスでもパンを提供するシーンが増えている。一方で、人口減少、少子高齢化が進行し、就労人口の減少が問題視される中で、製パン業界においても、人手不足は深刻な問題であり、人手不足と未熟な製パン技術を穴埋めするための製造方法や原材料が開発、改良されている。 The habit of eating bread as a meal has taken root in the elderly generation, and the consumption of bread per household has been on the rise in recent years. Furthermore, as a result of the habit of eating bread taking root, the style of providing bread to consumers has diversified, and in addition to the conventional supermarkets, convenience stores, and retail bakeries, the scene of providing bread at services of other industries such as cafes and hotels. Is increasing. On the other hand, as the population declines, the birthrate declines and the population ages, and the declining working population is seen as a problem, labor shortages are also a serious problem in the bakery industry, filling in the labor shortage and immature bread making technology. Manufacturing methods and raw materials have been developed and improved.

パンを製造する工程は、仕込み、混捏、フロアタイム(一次発酵)、分割、ベンチタイム、成型、ホイロ(二次発酵)、焼成に大きく分けられ、仕込みから焼成までの工程を連続的に行う製法はスクラッチ法または単にスクラッチと呼ばれている。一方で、上記の工程に冷凍保存の工程を挟み、作業を分割して製造者やパン職人の負担を軽減する冷凍生地製法があり、人手不足を解決する方法として取り組まれている。冷凍生地製法は、冷凍するタイミングによって、板生地冷凍法、生地玉冷凍法、成型後冷凍法、ホイロ後冷凍法、焼成後冷凍法などに分けられるが、最も代表的に行われる方法は成型後冷凍法である。 The process of manufacturing bread is roughly divided into preparation, kneading, floor time (primary fermentation), division, bench time, molding, proof (secondary fermentation), and baking, and the process from preparation to baking is continuously performed. Is called the scratch method or simply scratch. On the other hand, there is a frozen dough manufacturing method that reduces the burden on manufacturers and baker by sandwiching the frozen storage process in the above process and dividing the work, and is being tackled as a method for solving the labor shortage. The frozen dough manufacturing method is divided into a plate dough freezing method, a dough ball freezing method, a post-molding freezing method, a post-whisker freezing method, a post-baking freezing method, etc., depending on the timing of freezing, but the most typical method is after molding. It is a freezing method.

冷凍生地製法は、製造途中の生地または完成したパンを冷凍保存出来るため、製造または販売スケジュールに合わせて大量製造も可能であり、同時に製造ロスや販売ロスも軽減することが出来る。成型後冷凍法においては、セントラルベーカリーで成型して冷凍した後、冷凍保存してホイロとオーブンを備えたチェーンベーカリーに配送することで、少量、多品種のパンを複数のチェーンベーカリーで販売することが出来る。また、製パン技術の習得度が低い従業員でも焼き立てのパンを店舗に出すことが出来るため、人材雇用がしやすく、人手不足の問題を解決しやすい等の長所がある。 In the frozen dough manufacturing method, since the dough in the middle of production or the finished bread can be stored frozen, mass production can be performed according to the production or sales schedule, and at the same time, production loss and sales loss can be reduced. In the post-mold freezing method, after molding and freezing in a central bakery, it is stored frozen and delivered to a chain bakery equipped with a proofer and an oven, so that small quantities and various types of bread can be sold at multiple chain bakeries. Can be done. In addition, even employees with low mastery of bread making technology can put out freshly baked bread in stores, so it is easy to hire human resources and solve the problem of labor shortage.

一方で、冷凍生地製法に生じやすい外観、内相及び食感の品質的低下は、冷凍障害と呼ばれ、成型後冷凍法でも改善の難しい短所として挙げられる。冷凍障害が発生するメカニズムは完全には解明されていないが、冷凍保存中に形成される氷結晶とイースト菌体からの還元型グルタチオンの漏洩が主な要因とされている。パン生地中の氷結晶は冷凍保管中に成長し、パン生地の骨格を損傷させる。また、フロア工程を経過したイーストは、生育・増殖のためにエネルギーを消費した状態で凍結されるため、細胞破壊を起こしやすく、菌体内から還元型グルタチオンを漏洩させる。還元型グルタチオンはグルテンのS−S結合の一部を開裂させるため、パン生地を軟化または弱化させる。これらの変化を受けたパンは、解凍後のイーストによる発酵が不十分になり、さらに発酵や焼成で発生するガスを保持できないため、ボリューム低下、ロール成型時に見られる腰落ち、クラム部の内相の荒れ、硬くパサついた食感等、品質の悪化が目立つようになる。 On the other hand, the deterioration in quality of appearance, internal phase and texture that tends to occur in the frozen dough manufacturing method is called a freezing disorder, and is mentioned as a disadvantage that is difficult to improve even in the post-molding freezing method. The mechanism by which freezing disorders occur has not been completely elucidated, but the main cause is the leakage of reduced glutathione from ice crystals and yeast cells formed during freezing storage. Ice crystals in the dough grow during freezing and damage the dough skeleton. In addition, since the yeast that has passed the floor process is frozen in a state of consuming energy for growth and proliferation, it is liable to cause cell destruction and leak reduced glutathione from the cells. Reduced glutathione cleaves some of the SS bonds in gluten, thus softening or weakening the dough. Bread that has undergone these changes is insufficiently fermented with yeast after thawing, and cannot retain the gas generated during fermentation and baking, resulting in volume reduction, waist drop seen during roll molding, and the internal phase of the crumb part. Deterioration of quality such as rough texture and hard and dry texture becomes noticeable.

上記の冷凍障害を軽減するために冷凍生地製法で最も行われる改良方法としては、グルテンやイーストの添加量を多くしたり、水の添加量を少なくするなど、冷凍障害が発生しにくい配合を組むことである。また、冷凍保存前のイーストの生育・増殖を抑制するため、捏上温度を低くしたり、フロアタイムをスクラッチ法の場合より短時間にするなど、工程条件も変える必要があった。 The most common improvement method in the frozen dough manufacturing method to reduce the above freezing damage is to make a formulation that is less likely to cause freezing damage, such as increasing the amount of gluten or yeast added or decreasing the amount of water added. That is. In addition, in order to suppress the growth and proliferation of yeast before freezing and storage, it was necessary to change the process conditions such as lowering the kneading temperature and shortening the floor time compared to the scratch method.

そのため、パンに使用する小麦粉の一部をイーストと水で予めしっかりと発酵し、発酵後の生地を残りの原材料と混捏して、さらにフロアタイムをとってから分割する中種法は、冷凍障害を受けやすいポイントが複数あるため、冷凍生地にすることが技術的に難しいと考えられてきた。特に、配合する糖が多ければ多いほどパン生地は軟化してだれやすいため、ロール成型で冷凍保存すると腰落ちが顕著に目立つ等の課題が残されていた。 Therefore, the medium-sized method, in which a part of the flour used for bread is thoroughly fermented with yeast and water in advance, the fermented dough is mixed with the remaining raw materials, and the dough is further divided after taking floor time, is a freezing disorder. It has been considered technically difficult to make frozen dough because there are several points that are susceptible to it. In particular, the more sugar is mixed, the softer the dough becomes and the easier it is for the dough to drip. Therefore, when the dough is frozen and stored by roll molding, there remains a problem that the waist drop is noticeable.

上記のような特徴から、スクラッチと冷凍生地製法は、配合と工程が初めから異なるため、仕込み段階から別々の製造スケジュールを立てる必要があり、リテイルベーカリー等で両方の製法を行う場合には、冷凍生地製法は必ずしも労力削減に繋がらず、依然として従業員の負担は軽減出来なかった。また、スクラッチの中種法で作製したパンは、他の製法で作製したパンよりもソフト性が高く、老化抑制にも優れているため、冷凍生地工場を持つ大手製パンメーカーは、スクラッチの中種法で得たパン生地を、工程の途中で冷凍保存出来るような原材料の開発、改良が従来より求められていた。 Due to the above characteristics, the scratch and frozen dough manufacturing methods have different formulations and processes from the beginning, so it is necessary to set up separate manufacturing schedules from the preparation stage, and when both manufacturing methods are performed at retail bakery etc., freezing The dough manufacturing method did not necessarily lead to labor reduction, and the burden on employees could not be reduced. In addition, bread made by the medium-sized scratch method is softer than bread made by other methods and is also excellent in suppressing aging, so a major bread maker with a frozen dough factory is in scratch. Conventionally, there has been a demand for the development and improvement of raw materials that enable the bread dough obtained by the seed method to be frozen and stored in the middle of the process.

先行技術文献では中種法で作製した生地を冷凍保存する技術が開示されている。特許文献1では、イーストドーナツの中種生地に多量の酸化剤を添加することで、やわらかさとボリュームが維持され、吸油低減にも高い効果があることを開示している。当該文献のように、還元型グルタチオンによる影響を酸化剤で抑制することは幅広く行われているが、酸化剤の過剰添加は、機械耐性を低下させたり、成型の巻きを剥がす要因にもなるため、他の乳化剤や酵素と合わせて適度に伸展性を持たせながら使用することが好ましく、複数の素材を適した配合で組み合さなければならなかった。そのため、特許文献2および特許文献3では、冷凍生地パンのボリューム低下や腰落ちを酸化剤で抑制しているが、パンの種類に合わせて酸化剤以外の物質を選択し、配合検討する必要があることを示唆しており、より汎用性の高いパン生地物性改良剤が求められている。また、従来の技術においては、生地だれしやすい条件がそろい、ボリューム低下や腰落ちが発生しやすい加糖中種製法に対しては、冷凍障害を抑制する報告は開示されていなかった。 Prior art documents disclose a technique for freezing and preserving dough produced by the medium seed method. Patent Document 1 discloses that by adding a large amount of an oxidizing agent to a medium-sized dough of yeast donut, softness and volume are maintained, and it is highly effective in reducing oil absorption. As in the above document, it is widely practiced to suppress the influence of reduced glutathione with an oxidant, but excessive addition of the oxidant may reduce mechanical resistance or cause the molding to be unwound. , It is preferable to use it in combination with other emulsifiers and enzymes while maintaining appropriate extensibility, and a plurality of materials must be combined in an appropriate formulation. Therefore, in Patent Documents 2 and 3, the decrease in volume and the looseness of the frozen dough bread are suppressed by the oxidizing agent, but it is necessary to select a substance other than the oxidizing agent according to the type of bread and examine the composition. It is suggested that there is, and a more versatile bread dough physical property improving agent is required. In addition, in the conventional technique, there has been no disclosure of a report that suppresses freezing damage for a sweetened medium-sized production method in which the conditions for the dough to easily drip are met and the volume and waist drop are likely to occur.

特開平5−219877号公報Japanese Unexamined Patent Publication No. 5-21987 特開平8−106200号公報Japanese Unexamined Patent Publication No. 8-106200 特許公報第3632723号公報Patent Gazette No. 3632723

本発明が解決しようとする課題は、スクラッチ法と同様の配合で、混捏、フロアタイムを取り、分割、成型後に冷凍保存できる加糖中種生地を作製し、腰持ちとボリューム維持の出来るパン生地改良剤を提供することである。 The problem to be solved by the present invention is a bread dough improving agent capable of maintaining a firmness and volume by producing a sweetened medium-sized dough that can be kneaded, taken floor time, divided, and stored frozen after molding by the same composition as the scratch method. Is to provide.

仕込み時からスクラッチで配合を組んだパン生地は、スクラッチの工程条件で製造しており、途中で冷凍保存すると高品質のパンを得ることが出来なかった。同様に、冷凍生地製法で配合を組んだパン生地は、いずれかの工程で冷凍保存することを想定しており、仕込みから焼成まで連続してパンを作製しても、本来のスクラッチのパンより硬くパサついた食感であり、発酵時間も十分に取らないことから発酵風味も弱かった。そのため、スクラッチ法と冷凍生地製法は、別々のスケジュールを立てる必要があり、リテイルベーカリー等では依然として従業員の負担は軽減出来なかった。また、冷凍生地工場を持つ大手製パンメーカーにとっても、冷凍生地パンをスクラッチの中種法で作製したパンのような品質にまで高めることが出来なかった。
また、冷凍生地製法における冷凍障害に対して、ビタミンCなどの酸化剤が用いられてきたが、酸化剤は添加量が過剰になると機械耐性を低下させたり、成型を困難にすることから、生地状態を調節するために他の素材との配合検討が必要あり、使い方が限られていた。
The bread dough that was blended by scratch from the time of preparation was manufactured under the scratch process conditions, and if it was frozen and stored in the middle, high quality bread could not be obtained. Similarly, bread dough that has been blended by the frozen dough manufacturing method is assumed to be stored frozen in any process, and even if bread is made continuously from preparation to baking, it will be harder than the original scratch bread. The texture was dry and the fermentation flavor was weak because the fermentation time was not sufficient. Therefore, it is necessary to set separate schedules for the scratch method and the frozen dough manufacturing method, and the burden on employees could not be reduced at retail bakeries and the like. Also, even for a major bread maker with a frozen dough factory, it was not possible to improve the quality of frozen dough bread to the quality of bread made by the scratch medium method.
In addition, oxidizing agents such as vitamin C have been used for freezing disorders in the freezing dough manufacturing method. However, if the amount of the oxidizing agent added is excessive, the mechanical resistance is lowered and molding becomes difficult. In order to adjust the condition, it was necessary to consider the combination with other materials, and the usage was limited.

本発明者らは、上記課題の解決につき鋭意研究を重ねた結果、カルボニル基を同一分子内に2つ以上有する有機酸でグルテンを加熱処理した組成物は、加糖中種製法で作製したパン生地に添加すると、冷凍保存しても、とりわけ腰持ちとボリュームの維持に効果的であり、さらに、内相の荒れを改善することを見出し、本発明に至った。 As a result of diligent research on solving the above problems, the present inventors have obtained a composition obtained by heat-treating gluten with an organic acid having two or more carbonyl groups in the same molecule into a bread dough prepared by a sweetened medium-sized production method. It was found that when added, it is particularly effective in maintaining the firmness and volume even when stored frozen, and further, it improves the roughness of the internal phase, leading to the present invention.

すなわち本発明は、
(1)冷凍・解凍したパン生地を用いるパンの製造方法において、発酵開始2時間後におけるトータルガス発生量が0.3mL/g以上0.7mL/g未満である中種生地を作製し、該中種生地を本捏生地と混捏したパン生地中に、グルテンと、該グルテン100重量部に対して0.5重量部以上のカルボニル基を同一分子内に2つ以上有する有機酸とを含有する溶液を、65℃以上で30分以上加熱処理して得られる組成物を含有させる方法。
(2)パン生地が高糖生地である、上記(1)の方法。
を提供するものである。
That is, the present invention
(1) In the method for producing bread using frozen and thawed bread dough, a medium-sized dough having a total gas generation amount of 0.3 mL / g or more and less than 0.7 mL / g 2 hours after the start of fermentation is prepared. A solution containing gluten and an organic acid having two or more carbonyl groups of 0.5 parts by weight or more in the same molecule with respect to 100 parts by weight of the gluten is prepared in a bread dough obtained by kneading the seed dough with the main dough. , A method for containing a composition obtained by heat-treating at 65 ° C. or higher for 30 minutes or longer.
(2) The method of (1) above, wherein the bread dough is a high sugar dough.
Is to provide.

本発明のパン生地改良剤を加糖中種製法の生地に添加すると、加糖中種製法の配合と工程で仕込んだ生地を冷凍保存しても、冷凍障害を軽減することが出来る。特に軽減されやすい冷凍障害としては、腰持ちとボリュームの維持であり、さらに、内相の荒れを改善することが出来る。 When the bread dough improving agent of the present invention is added to the dough of the sweetened medium seed manufacturing method, the freezing disorder can be alleviated even if the dough prepared in the formulation and process of the sweetened medium seed manufacturing method is stored frozen. Freezing disorders that are particularly easy to alleviate are the maintenance of waist and volume, and can also improve the roughness of the internal phase.

従来は冷凍生地製法を用いる場合には、スクラッチ法の配合と比較して、水の添加量や発酵時間を減らし、イーストの添加量を増やすことで、冷凍障害を軽減する方法が取られてきたが、本発明のパン生地改良剤を用いると、加糖中種製法と同様に仕込んで、発酵させたパン生地を板生地冷凍法、生地玉冷凍法、成型後冷凍法、ホイロ後冷凍法、焼成後冷凍法へ途中の工程から切り替えることが出来る。 Conventionally, when the frozen dough manufacturing method is used, a method of reducing the freezing disorder by reducing the amount of water added and the fermentation time and increasing the amount of yeast added has been adopted as compared with the blending of the scratch method. However, when the bread dough improving agent of the present invention is used, the bread dough prepared and fermented in the same manner as the sweetened medium seed manufacturing method is frozen by the plate dough freezing method, the dough ball freezing method, the post-molding freezing method, the post-whisker freezing method, and the post-baking freezing. You can switch to the law from the middle process.

実施例1における腰もち度の測定方法Method for measuring waist retention in Example 1 糖濃度の異なる中種生地におけるトータルガス発生量Total amount of gas generated in medium-sized dough with different sugar concentrations 実施例1におけるパンの高さの継時的変化Changes in bread height over time in Example 1 実施例1におけるパンの腰もちの継時的変化Changes over time in the chewy texture of bread in Example 1 実施例1におけるパンの底面のホワイトラインWhite line on the bottom of the pan in Example 1 実施例1におけるパンの切断面の内相Internal phase of the cut surface of the bread in Example 1

以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.

本発明に用いられる中種生地は、常法の作製方法に従ってよく、表1及び表3に記載される原材料及び工程により作製することが出来る。強力粉、イーストフード、グルコース、イースト、水を秤量し、ミキサーで混捏後、発酵温度を管理した発酵槽または発酵室で一定時間発酵させる。発酵時間は作製するパンの種類によって適宜調整してもよく、15分‐6時間、好ましくは0.5−4時間、より好ましくは1−3時間である。発酵温度は使用するイーストの特性に合わせてよく、20−30℃が望ましい。 The medium-sized dough used in the present invention may be produced according to a conventional production method, and can be produced by the raw materials and processes shown in Tables 1 and 3. Weigh flour, yeast food, glucose, yeast, and water, knead them with a mixer, and ferment them in a fermentation tank or fermentation room where the fermentation temperature is controlled for a certain period of time. The fermentation time may be appropriately adjusted depending on the type of bread to be produced, and is 15 minutes to 6 hours, preferably 0.5 to 4 hours, and more preferably 1-3 hours. The fermentation temperature may be adjusted to the characteristics of the yeast used, preferably 20-30 ° C.

本発明に用いられる本捏生地は、常法の作製方法に従ってよく、表2に記載される原材料及び工程により作製することが出来る。中種生地、強力粉、砂糖、食塩、脱脂粉乳、油脂、水、品質改良剤より構成され、ミキサーで混捏後、発酵温度を管理した発酵槽または発酵室で一定時間発酵させる。砂糖の添加量は適宜調整してもよく、対粉0−30%、好ましくは5−25%、より好ましくは10−20%である。 The kneaded dough used in the present invention may be produced according to a conventional production method, and can be produced by the raw materials and processes shown in Table 2. It is composed of medium-sized dough, strong flour, sugar, salt, skim milk powder, fats and oils, water, and quality improver. After kneading with a mixer, it is fermented for a certain period of time in a fermenter or fermentation room where the fermentation temperature is controlled. The amount of sugar added may be adjusted as appropriate, and is 0-30%, preferably 5-25%, and more preferably 10-20% with respect to the flour.

本発明におけるトータルガス発生量は、中種生地中のイーストが一定時間で生成した二酸化炭素を主要とするガス全量であり、イーストの活性が高いほど、トータルガス発生量は高い。活性が高いイーストはフロア工程で対数増殖期から定常期に移行した後、冷凍障害を受けると、グルタチオンを漏出しやすい。 The total gas generation amount in the present invention is the total amount of gas mainly composed of carbon dioxide produced by yeast in the middle seed dough in a certain period of time, and the higher the yeast activity, the higher the total gas generation amount. Highly active yeast tends to leak glutathione when it undergoes freezing damage after shifting from the logarithmic growth phase to the stationary phase in the floor process.

本発明におけるパン生地改良剤は、グルテンと、該グルテン100重量部に対して1重量部以上のカルボニル基を同一分子内に2つ以上有する有機酸とを含有する溶液を、70℃以上で30分以上加熱処理する工程により得られる組成物である。 The bread dough improving agent in the present invention is prepared by mixing a solution containing gluten and an organic acid having two or more carbonyl groups in the same molecule with respect to 100 parts by weight of the gluten at 70 ° C. or higher for 30 minutes. This is the composition obtained by the above heat treatment step.

本発明において用いられるグルテンは、由来となる穀物も分離方法も特に限定されないが、小麦由来のグルテンが好ましい。また、分離されたグルテンは、分離したままのウェットタイプ(生グルテン)であっても、また、気流乾燥法(フラッシュドライ法)、噴霧乾燥法(スプレードライ法)、真空乾燥法、凍結乾燥法(フリーズドライ法)などの各種乾燥方法を用いて乾燥させて粉末状にした活性グルテンのいずれであってもよいが、活性グルテンが好ましい。活性グルテンを用いる場合、その水分含量は、好ましくは10%未満、より好ましくは9%未満、さらに好ましくは8%未満、最も好ましくは6%未満である。 The gluten used in the present invention is not particularly limited in terms of the grain from which it is derived and the method of separation, but gluten derived from wheat is preferable. Further, the separated gluten may be a wet type (raw gluten) as it is separated, or may be an air flow drying method (flash drying method), a spray drying method (spray drying method), a vacuum drying method, or a freeze drying method (a vacuum drying method). It may be any active gluten that has been dried and powdered using various drying methods such as freeze-drying method), but active gluten is preferable. When active gluten is used, its water content is preferably less than 10%, more preferably less than 9%, even more preferably less than 8%, most preferably less than 6%.

本発明において用いられる有機酸は、カルボニル基を同一分子内に2つ以上、好ましくは、カルボキシル基を2つ以上有する有機酸で、異性体はシス体であってもトランス体であってもよく、ラセミ体であってもよい。カルボニル基を2つ以上、同一分子内に有する有機酸としては、コハク酸、リンゴ酸、マロン酸、グルタル酸、アジピン酸が好ましく、コハク酸またはリンゴ酸がより好ましく、コハク酸がさらに好ましい。また、有機酸は1種を用いてもよく、2種以上を併用してもよい。 The organic acid used in the present invention is an organic acid having two or more carbonyl groups, preferably two or more carboxyl groups in the same molecule, and the isomer may be a cis form or a trans form. , May be racemic. As the organic acid having two or more carbonyl groups in the same molecule, succinic acid, malic acid, malonic acid, glutaric acid, and adipic acid are preferable, succinic acid or malic acid is more preferable, and succinic acid is further preferable. In addition, one type of organic acid may be used, or two or more types may be used in combination.

本発明において、グルテンと、カルボニル基を同一分子内に2つ以上有する有機酸(以下、単に有機酸という)とを含有する溶液を加熱処理する際、グルテンに対する有機酸の量は、例えばグルテン100重量部に対し、0.5重量部以上、好ましくは1.0重量部以上、より好ましくは2.0重量部以上、さらに好ましくは4.0重量部以上である。また、グルテンに対する有機酸の量の上限は、特に限定されないが、グルテンと有機酸が十分に反応し、最終製品に有機酸の味が残らないようにするために、例えば、グルテン100重量部に対し、100重量部未満、好ましくは50重量部未満、より好ましくは15重量部未満、さらに好ましくは13.5重量部未満、さらにより好ましくは12重量部未満、最も好ましくは10重量部以下である。 In the present invention, when a solution containing gluten and an organic acid having two or more carbonyl groups in the same molecule (hereinafter, simply referred to as organic acid) is heat-treated, the amount of the organic acid relative to gluten is, for example, gluten 100. It is 0.5 parts by weight or more, preferably 1.0 part by weight or more, more preferably 2.0 parts by weight or more, and further preferably 4.0 parts by weight or more with respect to parts by weight. The upper limit of the amount of the organic acid with respect to gluten is not particularly limited, but in order to prevent the gluten and the organic acid from reacting sufficiently and leaving the taste of the organic acid in the final product, for example, 100 parts by weight of gluten. On the other hand, it is less than 100 parts by weight, preferably less than 50 parts by weight, more preferably less than 15 parts by weight, further preferably less than 13.5 parts by weight, still more preferably less than 12 parts by weight, and most preferably 10 parts by weight or less. ..

上記加熱処理は、有機酸を液体の媒体に溶解させた状態で用いることが好ましく、その媒体となる液体は、水が好ましい。グルテンと有機酸を含む溶液の調製方法は、グルテンを液体に分散させた後、有機酸や有機酸の溶解液を添加する方法、グルテンに対して、有機酸の溶解液を添加する方法、グルテンと有機酸を混合したものに、液体を添加する方法、グルテンと有機酸を混合したものを、液体に添加する方法のいずれであってもよい。 The heat treatment is preferably used in a state where the organic acid is dissolved in a liquid medium, and the liquid used as the medium is preferably water. The method for preparing a solution containing gluten and an organic acid is a method of dispersing gluten in a liquid and then adding an organic acid or a solution of the organic acid, a method of adding a solution of an organic acid to gluten, and a method of adding a solution of an organic acid to gluten. It may be either a method of adding a liquid to a mixture of and an organic acid, or a method of adding a mixture of gluten and an organic acid to a liquid.

上記加熱処理の温度は、65℃以上が好ましく、70℃以上がより好ましく、80℃以上がさらに好ましい。40℃では、グルテン等がダマになり、50℃〜60℃では、ダマにはならないが、目的の改良されたグルテンを得ることができない。また、加熱処理の温度の上限は特にないが、水溶液での反応であり、反応物が熱変性を受けるタンパク質ということを考慮すると、100℃以下、好ましくは100℃未満、より好ましくは95℃未満、さらに好ましくは90℃以下である。 The temperature of the heat treatment is preferably 65 ° C. or higher, more preferably 70 ° C. or higher, and even more preferably 80 ° C. or higher. At 40 ° C, gluten and the like become lumps, and at 50 ° C to 60 ° C, gluten and the like do not become lumps, but the desired improved gluten cannot be obtained. There is no particular upper limit to the temperature of the heat treatment, but considering that the reaction is an aqueous solution and the reaction product is a protein that undergoes heat denaturation, the temperature is 100 ° C. or lower, preferably less than 100 ° C., more preferably less than 95 ° C. , More preferably 90 ° C. or lower.

上記加熱処理より得られたグルテンと有機酸の反応物(以下、「パン生地改良剤」とする)は、そのまま、または、乾燥させて、固形化や粉末化し、本発明のパン生地改良剤として用いることができる。乾燥方法は特に限定されず、気流乾燥法(フラッシュドライ法)、噴霧乾燥法(スプレードライ法)、ドラム乾燥法(ドラムドライ法)、真空乾燥法、凍結乾燥法(フリーズドライ法)などの各種乾燥方法を用いることができる。 The reaction product of gluten and organic acid (hereinafter referred to as "bread dough improving agent") obtained by the above heat treatment is used as it is or after being dried to solidify or powder and used as the bread dough improving agent of the present invention. Can be done. The drying method is not particularly limited, and various methods such as air flow drying method (flash drying method), spray drying method (spray drying method), drum drying method (drum drying method), vacuum drying method, freeze drying method (freeze drying method), etc. A drying method can be used.

本発明におけるパン生地改良剤は、単独で用いることもできるが、パンを製造する際に一般的に使用する、他の食品材料や、添加物、香料、色素などを混合して、製剤化してもよい。例えば、当該加糖中種生地用改良剤には、各種食用油脂、乳製品、果汁、穀物粉等や、モノグリセリド、コハク酸モノグリセリド、ジアセチル酒石酸モノグリセリド、ショ糖脂肪酸エステル、レシチン、酵素分解レシチン、ステアロイル乳酸ナトリウムやステアロイル乳酸カルシウム等の乳化剤、α-アミラーゼ、β-アミラーゼ、グルコアミラーゼ、ヘミセルラーゼ(ペントサナーゼ)、セルラーゼ、グルコースオキシダーゼ、プロテアーゼ等の酵素、システイン、シスチン、メチオニン、アラニン、アスパラギン酸、グリシン等のアミノ酸、コラーゲンや大豆タンパクやペプチド等、塩化ナトリウム、塩化カリウム、塩化アンモニウム、硫酸カルシウム、炭酸カルシウム、リン酸2水素カルシウム等の無機塩、イノシン酸ナトリウム、グアニル酸ナトリウム等の核酸、ビタミンB1、ビタミンB2、ビタミンC(L−アスコルビン酸)、ビタミンE等のビタミン、エタノール、グリセロール等のアルコール、ショ糖、ブドウ糖、麦芽糖、乳糖等の糖類、アラビアガム、アルギン酸、カラギナン、キサンタンガム、グァーガム、タマリンドガム、ペクチン等の増粘多糖類、デキストリン、各種澱粉等の賦形剤等を含有させてもよい。また、パン生地改良剤の形態は特に限定されず、液状、顆粒状、ペースト状、乳液状のいずれの形状であってもよい。 The bread dough improving agent in the present invention can be used alone, but it can also be formulated by mixing other food materials, additives, flavors, pigments, etc. that are generally used in the production of bread. Good. For example, the improved agent for sweetened medium-sized dough includes various edible fats and oils, dairy products, fruit juice, grain flour, etc., monoglyceride, succinic acid monoglyceride, diacetyl tartrate monoglyceride, sucrose fatty acid ester, lecithin, enzymatically decomposed lecithin, stearoyl lactic acid. Emulsifiers such as sodium and stearoyl calcium lactate, enzymes such as α-amylase, β-amylase, glucoamylase, hemicellase (pentosanase), cellulase, glucose oxidase, protease, cysteine, cystine, methionine, alanine, aspartic acid, glycine, etc. Amino acids, collagen, soybean protein, peptides, etc., inorganic salts such as sodium chloride, potassium chloride, ammonium chloride, calcium sulfate, calcium carbonate, calcium dihydrogen phosphate, nucleic acids such as sodium inosinate, sodium guanylate, vitamin B1, vitamins B2, vitamin C (L-ascorbic acid), vitamins such as vitamin E, alcohols such as ethanol and glycerol, sugars such as sucrose, glucose, malt sugar and lactose, arabic gum, alginic acid, caraginan, xanthan gum, guar gum, tamarind gum, Thickening polysaccharides such as pectin, dextrin, excipients such as various starches and the like may be contained. The form of the bread dough improving agent is not particularly limited, and may be in any of liquid, granular, paste, and milky forms.

本発明におけるパン生地改良剤は、穀物粉を原材料とするパン及びパン生地に用いることができ、当該改良剤を他の原材料に添加する以外は、従来の配合及び工程と同様に用いることができる。本発明のパン生地改良剤の穀物粉に対する添加量は、穀粉100重量部に対して通常0.1〜10重量部、好ましくは0.1〜5重量部、より好ましくは1〜5重量部である。 The bread dough improving agent in the present invention can be used for bread and bread dough using grain flour as a raw material, and can be used in the same manner as in the conventional formulation and process except that the improving agent is added to other raw materials. The amount of the bread dough improving agent of the present invention added to the flour is usually 0.1 to 10 parts by weight, preferably 0.1 to 5 parts by weight, and more preferably 1 to 5 parts by weight with respect to 100 parts by weight of the flour. ..

本発明において、パン及びパン生地に用いられる穀物粉には、小麦、米、大麦、ライ麦等の穀類から得られる穀粉があげられ、好ましくは小麦粉が用いられる。小麦粉としては、強力粉、準強力粉、中力粉および薄力粉のいずれの種類ならびに等級のものを用いてもよい。 In the present invention, examples of the flour used for bread and bread dough include flour obtained from grains such as wheat, rice, barley, and rye, and wheat flour is preferably used. As the wheat flour, any kind and grade of strong flour, semi-strong flour, medium-strength flour and weak flour may be used.

本発明において、パン及びパン生地に用いられる穀物粉以外の原材料には、主原料として穀粉(小麦粉、ライ麦粉、米粉、トウモロコシ粉等)、副材料として水、酵母(イースト)、食塩、糖類、油脂(ショートニング、ラード、マーガリン、バターなど)、乳製品(牛乳、脱脂粉乳、全粉乳、練乳等)、卵、イーストフードなどが含まれる。 In the present invention, raw materials other than grain flour used for bread and bread dough include flour (wheat flour, rye flour, rice flour, corn flour, etc.) as the main raw material, and water, yeast (yeast), salt, sugar, oil and fat as auxiliary materials. Includes (shortening, lard, margarine, butter, etc.), dairy products (milk, non-fat dry milk, whole milk powder, condensed milk, etc.), eggs, yeast foods, etc.

本発明において製造されるパンの種類は、限定されず、穀粉、イースト、食塩および水を主原料として、混捏、一次発酵、分割、成型、二次発酵、焼成などの工程により製出される加工食品であり、各工程間で冷凍保存しても良い。具体的な種類としては、食パン、ライ麦パン、フランスパン、バライティブレッド、ロールパン、クロワッサン、ホットドッグ、ハンバーガー、サンドイッチ、ジャムパン、あんぱん、クリームパン、レーズンパン、メロンパン、スイートロール、ブリオッシュ、コロネ等、が挙げられるが、加糖中種生地を用いたパンが好ましい。 The type of bread produced in the present invention is not limited, and processed foods produced by kneading, primary fermentation, division, molding, secondary fermentation, baking and the like using flour, yeast, salt and water as main raw materials. Therefore, it may be stored frozen between each step. Specific types include bread, rye bread, French bread, variety red, roll bread, croissant, hot dog, hamburger, sandwich, jam bread, anpan, cream bun, raisin bread, melon bread, sweet roll, brioche, corone, etc. Although it can be mentioned, bread using a sweetened medium-sized dough is preferable.

本発明におけるパン生地改良剤は、スクラッチ法で作製したパン生地を適宜途中の工程で冷凍保存することを可能とする。スクラッチ法とは、混捏、フロアタイム(一次発酵)、分割、ベンチタイム、成型、ホイロ(二次発酵)、焼成からなる工程を連続的に行う製パン法であり、代表的な製パン法としてはストレート法、2度捏法、ノーパンチ法、70%中種法、フル・フレーバー法、短時間中種法、長時間中種法(S780法)、オーバーナイト中種法(宵種法)、100%中種法、加糖中種法、が挙げられる。当該スクラッチ法で作製したパン生地を冷凍するタイミングは、従来の冷凍生地製法で知られるタイミングに倣って良く、混捏直後に生地を冷凍する板生地冷凍法、分割・丸め後に成型せずに生地を冷凍する生地玉冷凍法、成型後に生地を冷凍する成型後冷凍法、ホイロ後に生地を冷凍するホイロ後冷凍法、焼成した後に冷凍する焼成後冷凍法のいずれかの製法と同様の工程で保存することが出来る。 The bread dough improving agent in the present invention makes it possible to freeze and store the bread dough produced by the scratch method in an appropriate intermediate step. The scratch method is a bread making method in which a process consisting of kneading, floor time (primary fermentation), division, bench time, molding, proof (secondary fermentation), and baking is continuously performed, and is a typical bread making method. Is a straight method, double kneading method, no punch method, 70% medium seed method, full flavor method, short-time medium seed method, long-time medium seed method (S780 method), overnight medium seed method (evening seed method), Examples include the 100% medium seed method and the sweetened medium seed method. The timing of freezing the bread dough produced by the scratch method may follow the timing known in the conventional frozen dough manufacturing method. The plate dough freezing method in which the dough is frozen immediately after kneading, and the dough is frozen without being molded after being divided and rolled. Dough ball freezing method, dough after molding, freezing after molding, freezing after proofing, freezing after proofing, freezing after baking, freezing after baking, which is the same process as any of the manufacturing methods. Can be done.

本発明において腰落ちとは、パン生地を冷凍し、一定期間冷凍保存した後、解凍して焼成した際に、パン生地がだれて底面が広がる状態をいう。
本発明において腰もちとは、パン生地を冷凍し、一定期間冷凍保存した後、解凍して焼成した際に、パン生地がだれることなく高さがあり、パンの側面は丸みを帯びて持ちあがって底面が小さく保たれる状態をいう。
In the present invention, the “looseness” refers to a state in which the dough drips and the bottom surface expands when the dough is frozen, stored frozen for a certain period of time, then thawed and baked.
In the present invention, the waist mochi means that when the bread dough is frozen, stored frozen for a certain period of time, then thawed and baked, the bread dough has a height without sagging, and the side surface of the bread is rounded and lifted. A state in which the bottom surface is kept small.

本発明において、冷凍生地製法とは、混捏、フロアタイム(一次発酵)、分割、ベンチタイム、成型、ホイロ(二次発酵)、焼成からなる工程に、冷凍保存工程を挿入することによって、製パン作業を中断し、切り離すことが出来る製パン法である。冷凍保存工程をどの工程間に挿入するかによって、板生地冷凍法、生地玉冷凍法、成型後冷凍法、ホイロ後冷凍法、焼成後冷凍法に分けられる。 In the present invention, the frozen dough manufacturing method refers to bread making by inserting a freezing storage step into a step consisting of kneading, floor time (primary fermentation), division, bench time, molding, proofing (secondary fermentation), and baking. It is a bread making method that can interrupt the work and separate it. It is divided into a plate dough freezing method, a dough ball freezing method, a post-molding freezing method, a post-whisker freezing method, and a post-baking freezing method depending on which step the freezing storage step is inserted between.

以下に、本発明の内容について実施例を用いて説明する。ただし、本発明の技術範囲はこれらの実施例に限定されるものではない。 Hereinafter, the contents of the present invention will be described with reference to examples. However, the technical scope of the present invention is not limited to these examples.

以下の実施例で作製するパンの原材料の配合比は、強力粉を100重量部としてベイカーズ%(重量部)で記載した。冷凍生地用イーストは、ダイヤイーストFRZ(MCフードスペシャリティーズ)を用いた。当該イーストは、スクラッチ用としても用いることが出来る。また、イーストフードにはパンダイヤN(MCフードスペシャリティーズ)を用いた。 The blending ratio of the raw materials for bread prepared in the following examples is described in Bakers% (parts by weight) with 100 parts by weight of strong flour. Diamond yeast FRZ (MC Food Specialties) was used as the yeast for frozen dough. The yeast can also be used for scratching. In addition, Pandia N (MC Food Specialties) was used as the yeast food.

(発酵力の測定)
本発明におけるトータルガス発生量は、ファーモグラフを用いて測定した。表1に記載される原材料を秤量し、ピンミキサーで混捏後、20gずつに分割し、ファーモグラフのサンプル瓶にセットした。発酵温度は28℃とし、5分間の予備加温を終了した後、120分間発酵させ、トータルガス発生量を得た。
(Measurement of fermentative power)
The total amount of gas generated in the present invention was measured using a pharmacograph. The raw materials listed in Table 1 were weighed, kneaded with a pin mixer, divided into 20 g portions, and set in a thermograph sample bottle. The fermentation temperature was set to 28 ° C., and after the preliminary heating for 5 minutes was completed, fermentation was performed for 120 minutes to obtain the total amount of gas generated.

本発明におけるパン生地改良剤について、当該剤の添加効果は、加糖中種製法の生地を成型後冷凍することで評価した。加糖中種製法の生地は糖濃度が高く、かつ、フロアタイムとして十分な発酵時間が設けられた生地であることから、成型後冷凍した場合には、イーストからのグルタチオン漏洩等により冷凍障害を起こしやすい。また、当該実施例においては、水の配合比もスクラッチ法で仕込む場合と同じ配合比で仕込み、冷凍保存中の氷結晶の形成が生じやすい条件として評価した。 Regarding the bread dough improving agent in the present invention, the effect of adding the agent was evaluated by freezing the dough produced by the sweetened medium seed production method after molding. Since the dough produced by the sugar-sweetened medium-seed method has a high sugar concentration and has a sufficient fermentation time as a floor time, if it is frozen after molding, glutathione leakage from yeast may cause freezing problems. Cheap. Further, in the example, the mixing ratio of water was also prepared at the same mixing ratio as in the case of charging by the scratch method, and the condition was evaluated as a condition in which the formation of ice crystals during frozen storage was likely to occur.

(試料の作製方法)
パン生地改良剤は、蒸留水500mLに、コハク酸4.00g(0.034mol)を添加して混合し、混合液を得た。得られた混合液に、活性グルテン(水分量5.8W/W%)100gを添加し、十分に撹拌しながら、ウォーターバスを用いて80℃まで加熱した。80℃達温後、300分間、さらに撹拌を行い、活性グルテンとコハク酸を反応させた。得られた反応液に対してホモジナイザーを用いて、120秒間、乳化処理を行った。乳化処理液をバットに広げ、凍結乾燥機を用いて乾燥し、乾燥物(水分量7.0W/W%)を得た。フードプロセッサーを用いて、当該乾燥物を粉砕し、本発明におけるパン生地改良剤とした。
(Sample preparation method)
As the bread dough improving agent, 4.00 g (0.034 mol) of succinic acid was added to 500 mL of distilled water and mixed to obtain a mixed solution. 100 g of active gluten (water content 5.8 W / W%) was added to the obtained mixed solution, and the mixture was heated to 80 ° C. using a water bath with sufficient stirring. After reaching 80 ° C., the mixture was further stirred for 300 minutes to react active gluten with succinic acid. The obtained reaction solution was emulsified for 120 seconds using a homogenizer. The emulsified liquid was spread on a vat and dried using a freeze-dryer to obtain a dried product (water content 7.0 W / W%). The dried product was crushed using a food processor to obtain a bread dough improving agent in the present invention.

(製パン方法)
表1にパンの原材料の配合比を、表2に製パン工程及び各工程における条件を示した。
中種生地は全試験区とも同じ配合と工程で作製した。具体的には、強力粉、イーストフード、グルコース、イースト、水をそれぞれ秤量し、縦型ミキサーで混捏後、恒温槽で発酵した。
本捏生地には、何も加えない比較区1とグルテンを改良剤として添加した比較区2、および本発明のパン生地改良剤を添加した実施区1を用いて比較評価した。具体的には、強力粉、グラニュー糖、食塩、脱脂粉乳、水、発酵を終了した中種生地、グルテンまたはパン生地改良剤、をそれぞれ秤量し、縦型ミキサーで混捏した。ミキサーの撹拌速度を適宜調整し、生地内にグルテンが形成されたことを確認した後、ショートニングを添加し、再度混捏した。生地とショートニングが十分に混ざり合い、生地内にグルテンが再度形成させたことを確認してミキシングを終了し、この時の生地温度を捏上温度とした。また、ミキシング中に生地を適宜冷却することによって、捏上温度を28±0.5℃以内に調節した。捏ね上げた生地は恒温槽で一次発酵させた(フロアタイム)。フロアタイム終了後、生地を分割し、丸めて、ベンチタイムで生地を休ませた。ベンチタイム終了後、丸めた生地をモルダーでロール成型し、冷凍保存した。
冷凍期間は最長1ヶ月間とし、冷凍保存1日後、1週間後、2週間後、1ヶ月後について添加効果を比較した。
冷凍庫から取り出した加糖中種生地は、ドウコンディショナーで解凍し、ホイロで二次発酵した後、焼成した。
焼成したパンは室温冷却し、粗熱が取れた後、恒温槽で一晩保管し、翌日評価した。
(Bread making method)
Table 1 shows the mixing ratio of the raw materials for bread, and Table 2 shows the bread making process and the conditions in each process.
The medium seed dough was prepared by the same composition and process in all test plots. Specifically, strong flour, yeast food, glucose, yeast, and water were weighed, kneaded with a vertical mixer, and then fermented in a constant temperature bath.
The kneaded dough was comparatively evaluated using Comparative Group 1 in which nothing was added, Comparative Group 2 in which gluten was added as an improving agent, and Implementation Group 1 in which the bread dough improving agent of the present invention was added. Specifically, strong flour, granulated sugar, salt, skim milk powder, water, fermented medium-sized dough, gluten or bread dough improver were weighed and kneaded with a vertical mixer. The stirring speed of the mixer was adjusted appropriately, and after confirming that gluten was formed in the dough, shortening was added and the mixture was kneaded again. After confirming that the dough and shortening were sufficiently mixed and gluten was formed again in the dough, mixing was completed, and the dough temperature at this time was set as the kneading temperature. In addition, the kneading temperature was adjusted within 28 ± 0.5 ° C. by appropriately cooling the dough during mixing. The kneaded dough was first fermented in a constant temperature bath (floor time). After the floor time was over, the dough was split, rolled and rested on the bench time. After the bench time was over, the rolled dough was rolled with a mulder and stored frozen.
The freezing period was set to a maximum of 1 month, and the effects of addition were compared after 1 day, 1 week, 2 weeks, and 1 month of frozen storage.
The sweetened dough taken out of the freezer was thawed with a dough conditioner, secondarily fermented with a proofer, and then baked.
The baked bread was cooled to room temperature, and after the rough heat was removed, it was stored overnight in a constant temperature bath and evaluated the next day.

(添加効果の評価方法)
添加効果はパンの高さと腰もち度の測定、及び内相の外観について比較した。
<パンの高さ>
本発明においてロールパンは、ロール成型時の綴じ目線と並行した一辺を長辺とし、生地が巻かれて渦巻き状を示す一辺を短辺と定義した。ロールパンの高さは、長辺の長さ1/2の位置から長辺に対し前後2cmの部位で最も底部からの高さがある位置をロールパンの高さと定義した。
<パンの腰もち度>
ロールパンの高さとして測定した位置を長辺に対して垂直または短辺に対して平行にカットしたときの切断面を図1に示した。図1中のγはロールパンの底面と切断面が付着する短辺の長さを示し、αは切断面において最も長い短辺の長さを示した。腰もち度は、αに対するγの短さ、またはαからγを引いたロールパンが底面と接していない短辺の長さをαに対して比較した数値とした。腰もち度は1からγ/αを減じた値と定義し、0に近いほど腰もちは悪く、1に近いほど腰もちが良いことを示すが、1未満の数値とする。
腰もち度は目視での官能評価も可能である。腰もちの良いロールパンの底面は、底面の周囲にホワイトラインが残り、中心部より白い色調を呈する。一方、腰もちの悪いロールパンはホワイトラインがなく、底面全体が焼き色を呈するため、腰もちの良し悪しを識別することが可能である。
<内相>
内相は、上記の切断面について、切断面内側の気泡の細かさを比較することにより評価した。冷凍障害によるダメージが大きい内相は気泡の大きさが大きく、切断面全体で気泡の入り方が荒い様相を呈する。一方、冷凍障害によるダメージが少ない場合には、気泡の大きさが小さく、入り方が細かく均一な様相を呈する。
(Evaluation method of addition effect)
The effect of addition was compared with the measurement of bread height and chewyness, and the appearance of the internal phase.
<Bread height>
In the present invention, in the roll pan, one side parallel to the binding line at the time of roll molding is defined as a long side, and one side in which the dough is rolled and shows a spiral shape is defined as a short side. The height of the roll pan was defined as the height of the roll pan from the position where the length of the long side was 1/2 to the position where the height from the bottom was the highest at the portion 2 cm in the front-rear direction with respect to the long side.
<Bread waistiness>
FIG. 1 shows a cut surface when the position measured as the height of the roll pan is cut perpendicular to the long side or parallel to the short side. In FIG. 1, γ indicates the length of the short side to which the bottom surface of the roll pan and the cut surface adhere, and α indicates the length of the longest short side on the cut surface. The waist retention was defined as a value obtained by comparing the shortness of γ with respect to α or the length of the short side of the roll pan obtained by subtracting γ from α with respect to α. The degree of waist retention is defined as a value obtained by subtracting γ / α from 1, and the closer to 0, the worse the waist, and the closer to 1, the better the waist, but the value is less than 1.
The degree of waist retention can be visually evaluated. The bottom of the bread roll, which is chewy, has a white line around the bottom and is whiter than the center. On the other hand, rolls with poor chewyness do not have white lines and the entire bottom surface is browned, so it is possible to distinguish between good and bad chewyness.
<Internal phase>
The internal phase was evaluated by comparing the fineness of air bubbles inside the cut surface with respect to the above-mentioned cut surface. The internal phase, which is heavily damaged by freezing damage, has a large bubble size, and the bubble enters the entire cut surface in a rough manner. On the other hand, when the damage due to the freezing disorder is small, the size of the bubbles is small, and the way of entering is fine and uniform.

(結果)
<トータルガス発生量>
糖濃度3−20%の中種生地におけるイースト(ダイヤイーストFRZ)のトータルガス発生量を図2に示した。28℃で120分発酵させた後のトータルガス発生量は、濃度依存的に減少し、糖濃度3%から20%において0.3mL/g以上0.7mL/g未満だった。糖濃度3%はイーストの活性が最も高いため、冷凍障害を受けやすく、グルタチオン漏洩量も多いことが示唆された。
ロールパンの高さと腰もち度における継時的変化を図3及び図4に示した。
図3及び図4において、冷凍保存1日後を「冷凍1D」、冷凍保存1週間後を「冷凍1W」、冷凍保存2週間後を「冷凍2W」、冷凍保存1か月後を「冷凍1M」と記した。
ロールパンの高さについて比較すると、冷凍保存1日後から冷凍保存1ヶ月後まで実施区1の値が最も大きく、パン生地改良剤を添加することによって、ロールパンの高さが維持されることが示された。
ロールパンの腰もち度について比較すると、高さと同様に、冷凍保存1日後から冷凍保存1ヶ月後まで実施区1の値が最も大きく、パン生地改良剤を添加することによって、ロールパンの腰もちが維持されることが示された。
実施区1は高さと腰もち度が共に大きい値を示したことから、ボリュームも3つの試験区の中で最も大きいことが示唆された。
ロールパンの高さと腰もち度について冷凍1ヵ月間で継時的変化を比較すると、3試験区とも同様に減退したが、実施区1の冷凍保存1ヶ月後の値は、比較区1及び比較区2の冷凍保存1日後の数値よりも著しく高かった。実施区1は、比較区1および比較区2と比較すると、従来の冷凍生地製法で行ってきた水の配合量を減らしたり、発酵時間を短くするなどの変更を必要とせず、糖濃度が高く、発酵時間を長く取って作製しても、十分に冷凍障害を抑制出来ることを示した。
ロールパンの底面の様相を図5に示した。図5では、左から順に比較区1、比較区2、実施区1とした。比較区1の底面にホワイトラインが見当たらないのに対し、比較区2及び実施区1にはホワイトラインを確認することが出来た。実施区1のホワイトラインは比較区2よりも太く、底面において広い面積を占めていたことから、比較区2よりも腰もちが改善されていることが示唆された。
ロールパンの切断面の様相を図6に示した。図6では、左から順に比較区1、比較区2、実施区1とした。比較区1及び比較区2の内相は外側から中央部に向かって大きな気泡が増加するのに対し、実施区1は外側と中央部の気泡の大きさはほぼ同じであり、均一な内相を示した。このことから、本発明におけるパン生地改良剤は氷結晶によるパン生地の骨格の破壊を防ぎ、内相を均一に維持するのに有効であることが示された。
(result)
<Total gas generation>
The total amount of gas generated by yeast (diaeast FRZ) in the medium-sized dough having a sugar concentration of 3 to 20% is shown in FIG. The total amount of gas generated after fermentation at 28 ° C. for 120 minutes decreased in a concentration-dependent manner, and was 0.3 mL / g or more and less than 0.7 mL / g at a sugar concentration of 3% to 20%. It was suggested that the sugar concentration of 3% has the highest yeast activity, so that it is susceptible to freezing damage and the amount of glutathione leaked is large.
The changes over time in the height and stiffness of the rolls are shown in FIGS. 3 and 4.
In FIGS. 3 and 4, 1 day after freezing storage is "frozen 1D", 1 week after frozen storage is "freezing 1W", 2 weeks after frozen storage is "freezing 2W", and 1 month after frozen storage is "freezing 1M". I wrote.
Comparing the heights of bread rolls, the value of Implementation Group 1 was the largest from 1 day after freezing storage to 1 month after freezing storage, indicating that the height of bread rolls was maintained by adding a bread dough improving agent. ..
Comparing the chewyness of the bread rolls, the value of the implementation group 1 was the largest from 1 day after the frozen storage to 1 month after the frozen storage, and the chewyness of the bread rolls was maintained by adding the bread dough improving agent. Rukoto has been shown.
Since the height and the degree of stiffness of the test group 1 were large, it was suggested that the volume was also the largest among the three test groups.
Comparing the changes over time in the height and firmness of the bread rolls during one month of freezing, the changes were similarly reduced in all three test plots, but the values after one month of freezing storage in the implementation plot 1 were in the comparison plot 1 and the comparison plot. It was significantly higher than the value after 1 day of freezing storage of 2. Compared with Comparative Group 1 and Comparative Group 2, Implementation Group 1 does not require changes such as reducing the amount of water blended or shortening the fermentation time, which has been performed by the conventional frozen dough manufacturing method, and has a higher sugar concentration. It was shown that freezing damage can be sufficiently suppressed even if the fermentation time is long.
The appearance of the bottom surface of the roll pan is shown in FIG. In FIG. 5, the comparison zone 1, the comparison zone 2, and the implementation zone 1 are set in order from the left. While the white line was not found on the bottom surface of the comparison group 1, the white line could be confirmed in the comparison group 2 and the implementation area 1. Since the white line of the implementation group 1 was thicker than that of the comparison group 2 and occupied a large area on the bottom surface, it was suggested that the waistiness was improved as compared with the comparison group 2.
The appearance of the cut surface of the roll pan is shown in FIG. In FIG. 6, the comparison zone 1, the comparison zone 2, and the implementation zone 1 are set in order from the left. In the internal phase of Comparative Group 1 and Comparative Group 2, large bubbles increase from the outside toward the center, whereas in Implementation Group 1, the sizes of the bubbles in the outside and the center are almost the same, and the internal phase is uniform. showed that. From this, it was shown that the bread dough improving agent in the present invention is effective in preventing the destruction of the bread dough skeleton by ice crystals and maintaining the internal phase uniformly.

以上説明してきたように、本発明のパン生地改良剤をスクラッチの加糖中種製法の生地に添加すると、製造工程の途中から冷凍保存しても、冷凍障害を軽減することが出来る。特に軽減されやすい冷凍障害としては、腰持ちとボリュームの維持であり、さらに、内相の荒れを改善することが出来る。従来は冷凍生地製法を用いる場合には、スクラッチ法の配合と比較して、水の添加量や発酵時間を減らし、イーストの添加量を増やすことで、冷凍障害を軽減する方法が取られてきたが、本発明のパン生地改良剤を用いると、加糖中種製法と同様に仕込んで、発酵させて、分割、成型したパン生地を冷凍保存することができる。さらに、焼成されたパンは、発酵時間を十分に取っているため、冷凍生地パンでは高められなかった発酵風味を高めることも可能である。本発明においては、冷凍障害が最も起こりやすい評価系で効果を確認した。そのため、パン生地改良剤を用いれば、その他のスクラッチ法に分類される製パン法でも、途中の工程から適宜冷凍保存した場合にも、高品質のパンが作製できると考えられた。当該改良剤の使用により、より冷凍生地製法の利用が広がり、製パン業界における人手不足を解消する一助となると考えられる。 As described above, when the bread dough improving agent of the present invention is added to the dough of the scratch-sweetened medium-sized manufacturing method, freezing damage can be reduced even if the dough is stored frozen in the middle of the manufacturing process. Freezing disorders that are particularly easy to alleviate are the maintenance of waist and volume, and can also improve the roughness of the internal phase. Conventionally, when the frozen dough manufacturing method is used, a method of reducing the freezing disorder by reducing the amount of water added and the fermentation time and increasing the amount of yeast added has been adopted as compared with the blending of the scratch method. However, when the bread dough improving agent of the present invention is used, the bread dough that has been charged, fermented, divided, and molded can be stored frozen in the same manner as in the sweetened medium-sized production method. Furthermore, since the baked bread has a sufficient fermentation time, it is possible to enhance the fermentation flavor that could not be enhanced by the frozen dough bread. In the present invention, the effect was confirmed in the evaluation system in which freezing damage is most likely to occur. Therefore, it is considered that if a bread dough improving agent is used, high-quality bread can be produced even in the bread-making method classified into other scratch methods, even when the bread is appropriately frozen and stored from the middle step. It is thought that the use of the improver will further expand the use of the frozen dough manufacturing method and help solve the labor shortage in the bakery industry.

Claims (2)

冷凍・解凍したパン生地を用いるパンの製造方法において、発酵開始2時間後におけるトータルガス発生量が0.3mL/g以上0.7mL/g未満である中種生地を作製し、該中種生地を本捏生地と混捏したパン生地中に、グルテンと、該グルテン100重量部に対して0.5重量部以上のカルボニル基を同一分子内に2つ以上有する有機酸とを含有する溶液を、65℃以上で30分以上加熱処理して得られる組成物を含有させる方法。 In the bread manufacturing method using frozen and thawed bread dough, a medium-sized dough having a total gas generation amount of 0.3 mL / g or more and less than 0.7 mL / g 2 hours after the start of fermentation is prepared, and the medium-sized dough is used. A solution containing gluten and an organic acid having two or more carbonyl groups of 0.5 parts by weight or more in the same molecule with respect to 100 parts by weight of the gluten in a bread dough mixed with the main kneaded dough at 65 ° C. The method for containing the composition obtained by heat-treating for 30 minutes or more. パン生地が高糖生地である、請求項1の方法。 The method of claim 1, wherein the bread dough is a high sugar dough.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08256674A (en) * 1995-03-27 1996-10-08 Nippon Flour Mills Co Ltd Frozen dough of bread containing large amount of sugar and its production
JP2003052301A (en) * 2001-08-14 2003-02-25 Kanegafuchi Chem Ind Co Ltd Method for ultra-high sugar containing bun production
WO2017141702A1 (en) * 2016-02-19 2017-08-24 Mcフードスペシャリティーズ株式会社 Method for manufacturing modified gluten

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08256674A (en) * 1995-03-27 1996-10-08 Nippon Flour Mills Co Ltd Frozen dough of bread containing large amount of sugar and its production
JP2003052301A (en) * 2001-08-14 2003-02-25 Kanegafuchi Chem Ind Co Ltd Method for ultra-high sugar containing bun production
WO2017141702A1 (en) * 2016-02-19 2017-08-24 Mcフードスペシャリティーズ株式会社 Method for manufacturing modified gluten

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