JP2020165011A - Nonwoven fabric and absorbent article using the same - Google Patents

Nonwoven fabric and absorbent article using the same Download PDF

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Publication number
JP2020165011A
JP2020165011A JP2019064344A JP2019064344A JP2020165011A JP 2020165011 A JP2020165011 A JP 2020165011A JP 2019064344 A JP2019064344 A JP 2019064344A JP 2019064344 A JP2019064344 A JP 2019064344A JP 2020165011 A JP2020165011 A JP 2020165011A
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Prior art keywords
woven fabric
load
fiber
air
under
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JP2019064344A
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Japanese (ja)
Inventor
正志 青野
Masashi Aono
正志 青野
康志 松田
Koji Matsuda
康志 松田
卓 小島
Taku Kojima
卓 小島
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JNC Corp
JNC Fibers Corp
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JNC Corp
JNC Fibers Corp
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Priority to JP2019064344A priority Critical patent/JP2020165011A/en
Priority to CN202010212881.9A priority patent/CN111748910A/en
Publication of JP2020165011A publication Critical patent/JP2020165011A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/47Sanitary towels, incontinence pads or napkins
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15203Properties of the article, e.g. stiffness or absorbency
    • A61F2013/15284Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
    • A61F2013/15463Absorbency

Abstract

To provide a nonwoven fabric capable of maintaining its form under high load while suppressing a basis weight of the nonwoven fabric, and thereby suppressing liquid return.SOLUTION: There is provided a through-air nonwoven fabric in which a ratio of a thickness under a load of 50 gf/cm2 to a thickness under a load of 3.5 gf/cm2 is 0.5-0.8, and a fiber surface area per volume under the load of 50 gf/cm2 is 70-120 cm2/cm3.SELECTED DRAWING: None

Description

本発明は、吸収性物品の部材として用いられる不織布及びそれを用いた吸収性物品に関する。 The present invention relates to a non-woven fabric used as a member of an absorbent article and an absorbent article using the same.

従来、使い捨ておむつ等の吸収性物品には、肌と直に接し、尿等の排泄液を透過するトップシートと、その裏側にあり排泄液を保持する吸収体と、それらの間にあり排泄液を吸収体全体に拡散させるセカンドシートと、を備えたものが汎用されている。吸収性物品において、排泄液は吸収体で保持されるが、荷重がかかると排泄液が肌側に逆流してしまうことがある。このように排泄液が吸収体から肌側へ逆流する現象を液戻りと呼び、液戻りは、ジメジメした不快感や水分による肌のかぶれを引き起こす要因になる。そこで、吸収性物品には、吸収体が保持した排泄液を肌側に液戻りさせないことが求められ、この要求に対応するセカンドシートの構成が検討されてきた。 Conventionally, absorbent articles such as disposable diapers have a top sheet that is in direct contact with the skin and allows excrement fluid such as urine to permeate, an absorber that holds the excretory fluid on the back side, and an excretory fluid that is between them. A second sheet that diffuses urine throughout the absorber is widely used. In an absorbent article, the excrement is held by the absorber, but when a load is applied, the excrement may flow back to the skin side. The phenomenon in which the excrement fluid flows back from the absorber to the skin side in this way is called liquid return, and the liquid return causes damp discomfort and skin irritation due to water. Therefore, the absorbent article is required not to return the excrement liquid held by the absorber to the skin side, and the configuration of the second sheet corresponding to this demand has been studied.

吸収性物品のセカンドシートは、スルーエア不織布から構成されるものが主流である。スルーエア不織布は、サーマルボンド不織布に分類され、エアスルー不織布と称されることもある不織布であって、例えば、融点の異なる少なくとも2種類の熱可塑性樹脂で構成された複合繊維のウェブを熱処理することで得られる。ウェブを熱処理する方法としては、例えば、ウェブを支持搬送する搬送支持体を備えた熱処理装置(例えば、熱風貫通式熱処理機、熱風吹き付け式熱処理機)によって繊維同士を熱接着させ、不織布化する方法が知られている。 The second sheet of the absorbent article is mainly composed of a through-air non-woven fabric. The through-air non-woven fabric is a non-woven fabric that is classified as a thermal bonded non-woven fabric and is sometimes called an air-through non-woven fabric. For example, by heat-treating a web of composite fibers composed of at least two types of thermoplastic resins having different melting points. can get. As a method of heat-treating the web, for example, a method of heat-bonding the fibers to each other by a heat treatment apparatus (for example, a hot air penetration type heat treatment machine, a hot air blowing type heat treatment machine) provided with a transport support for supporting and transporting the web to form a non-woven fabric. It has been known.

セカンドシートについて、例えば、特許文献1は、おむつ表面における吸収速度を高めるとともに、体液の逆戻り防止及びおむつ表面の濡れ・カブレ防止を図る効果があるとともに、おむつの表面部が柔軟性に富むものを提供することを課題としており、圧縮硬さを規定したセカンドシートを備える吸収性物品が提案されている。特許文献1のセカンドシートは、特定範囲の繊度を有する熱接着性複合繊維を、エアスルー型熱処理機で熱接着した後、圧密処理して得られることが開示されている。また、0.5gf/cm荷重時のセカンドシートの厚みが0.7〜0.9mmであることが開示されている。特許文献1のセカンドシートは、密度が高く、かつ、柔軟性に富むことを特徴としている。 Regarding the second sheet, for example, Patent Document 1 has an effect of increasing the absorption rate on the surface of the diaper, preventing the reversion of body fluids, preventing the surface of the diaper from getting wet and fogging, and the surface of the diaper is highly flexible. It is an object to provide, and an absorbent article having a second sheet having a defined compressive hardness has been proposed. It is disclosed that the second sheet of Patent Document 1 is obtained by heat-bonding heat-adhesive composite fibers having a specific range of fineness with an air-through type heat treatment machine and then consolidating them. Further, it is disclosed that the thickness of the second sheet under a load of 0.5 gf / cm 2 is 0.7 to 0.9 mm. The second sheet of Patent Document 1 is characterized by having a high density and abundant flexibility.

また、荷重がかかった時の厚みを確保することで、液戻りを抑制する不織布が提案されている。例えば、特許文献2は、セカンドシートとして、坪量が30g/m以上、50gf/cm荷重下の厚みが0.35mm〜1mmであるエアスルー又はエアレイド不織布を開示している。特許文献2の発明は、大量の尿を吸収させた場合にも液戻りが生じにくい使い捨ておむつを提供することを課題としており、この課題に対して、おむつ着用中に着用者の体重によって加わる荷重を想定した高荷重(50gf/cm)下においても、所要の厚みが維持されることによって、優れた液戻り低減効果が奏されるものと考えられている。 In addition, a non-woven fabric that suppresses liquid return by ensuring the thickness when a load is applied has been proposed. For example, Patent Document 2 discloses an air-through or air-laid nonwoven fabric having a basis weight of 30 g / m 2 or more and a thickness of 0.35 mm to 1 mm under a load of 50 gf / cm 2 as a second sheet. An object of the invention of Patent Document 2 is to provide a disposable diaper that does not easily return to liquid even when a large amount of urine is absorbed, and to this problem, a load applied by the weight of the wearer while wearing the diaper. It is considered that an excellent liquid return reducing effect can be achieved by maintaining the required thickness even under a high load (50 gf / cm 2 ) assuming the above.

また、例えば、特許文献3には、繊維表面が親水化処理されてなる単繊維繊度が2〜8dtexのポリエステル系繊維からなる、目付が40〜60g/mのスパンレース不織布であって、ノンバインダーで形成されてなることを特徴とするセカンドシートが提案されている。 Further, for example, Patent Document 3 describes a spunlace non-woven fabric having a basis weight of 40 to 60 g / m 2 and made of a polyester fiber having a single fiber fineness of 2 to 8 dtex and having a fiber surface hydrolyzed. A second sheet has been proposed, which is characterized by being formed of a binder.

特開2005−52186号公報Japanese Unexamined Patent Publication No. 2005-52186 特開2007−159943号公報Japanese Unexamined Patent Publication No. 2007-159943 特開2017−148284号公報JP-A-2017-148284

特許文献1のセカンドシートは、液戻りの防止に加えて、おむつの表面部が柔軟性に富む等の効果を得るために、密度が高くかつ柔らかいシートを構成するものである。しかしながら、この柔らかさのため、荷重時の厚みが小さくなり、液戻り防止性が十分に発揮されない場合もあった。また、特許文献2のセカンドシートは、荷重下での厚みを確保するために、低荷重下(49Pa=0.5gf/cm)の厚みを1.4〜1.9mm程度とすることが記載されており、低荷重下での厚みが大きな不織布であった。また、特許文献3の不織布は、スパンレース不織布であるため、柔軟性に優れる一方で圧縮耐性が弱く、液戻り防止性を確保するためには目付を高くする必要があり、具体的には、目付を40〜60g/mとすることが好ましいことが開示されている。 The second sheet of Patent Document 1 constitutes a sheet having a high density and a softness in order to obtain effects such as a highly flexible surface portion of the diaper in addition to preventing liquid return. However, due to this softness, the thickness under load becomes small, and the liquid return prevention property may not be sufficiently exhibited. Further, it is described that the thickness of the second sheet of Patent Document 2 is about 1.4 to 1.9 mm under a low load (49 Pa = 0.5 gf / cm 2 ) in order to secure the thickness under a load. It was a non-woven fabric with a large thickness under a low load. Further, since the non-woven fabric of Patent Document 3 is a spunlace non-woven fabric, it has excellent flexibility but weak compression resistance, and it is necessary to increase the basis weight in order to secure the liquid return prevention property. It is disclosed that the basis weight is preferably 40 to 60 g / m 2 .

このような状況に鑑み、本発明は、不織布の目付を低く抑えつつ、高荷重時にも一定の厚みを維持し、それにより液戻りを抑制する不織布を提供することである。 In view of such a situation, the present invention provides a non-woven fabric that keeps the basis weight of the non-woven fabric low and maintains a constant thickness even under a high load, thereby suppressing liquid return.

発明者らは上述の課題を解決するために検討を重ね、その結果、低荷重時には比較的薄く、かつ、高荷重下においても一定の厚みを維持できる不織布を作製することに想到した。そして、不織布の潰れやすさを把握するにあたり、低加重時(3.5gf/cm荷重下)での厚みと高荷重時(50gf/cm荷重下)での厚みに注目し、その厚みの比率と、50gf/cm荷重下における体積当たりの繊維表面積を制御することによって、液戻りを低減でき、低目付かつ液戻り性を備えた不織布が得られるという知見を得て、本発明を完成した。 The inventors have made repeated studies to solve the above-mentioned problems, and as a result, have come up with the idea of producing a non-woven fabric that is relatively thin under a low load and can maintain a constant thickness even under a high load. Then, in grasping the fragility of the non-woven fabric, pay attention to the thickness at low load (3.5 gf / cm 2 load) and the thickness at high load (50 gf / cm 2 load), and consider the thickness. The present invention was completed with the finding that by controlling the ratio and the surface area of the fiber per volume under a load of 50 gf / cm 2 , liquid return can be reduced, and a non-woven fabric having low graininess and liquid return property can be obtained. did.

本発明は以下の構成を有する。
[1]3.5gf/cm荷重下での厚みに対する、50gf/cm荷重下での厚みの比が0.5〜0.8であり、かつ、50gf/cm荷重下での体積当たりの繊維表面積が70〜120cm/cmである、スルーエア不織布。
[2]目付が20〜35g/mである、[1]に記載のスルーエア不織布。
[3]ポリエチレンテレフタレートとポリエチレンとからなり、並列型複合繊維、偏心鞘芯型複合繊維及び同心鞘芯型複合繊維からなる群から選ばれるいずれかである複合繊維から構成される、[1]又は[2]に記載のスルーエア不織布。
[4]ポリエチレンテレフタレートとポリエチレンとからなり、並列型複合繊維、偏心鞘芯型複合繊維及び同心鞘芯型複合繊維からなる群から選ばれるいずれかである複合繊維のウェブを作製する工程、前記工程で得られたウェブをスルーエア法によって熱処理する工程、及び、前記熱処理工程の直後に前記ウェブを圧密する工程、を含む、[1]〜[3]のいずれか1項に記載のスルーエア不織布の製造方法。
[5][1]〜[3]のいずれかに記載のスルーエア不織布を含む、吸収性物品。
The present invention has the following configurations.
[1] for 3.5 gf / cm 2 Thickness under load, the ratio of the thickness of the under 50 gf / cm 2 load is 0.5 to 0.8, and, 50 gf / cm 2 per volume under load Through-air non-woven fabric having a fiber surface area of 70 to 120 cm 2 / cm 3 .
[2] The through-air non-woven fabric according to [1], which has a basis weight of 20 to 35 g / m 2 .
[3] It is composed of polyethylene terephthalate and polyethylene, and is composed of a composite fiber which is one selected from the group consisting of a parallel type composite fiber, an eccentric sheath core type composite fiber and a concentric sheath core type composite fiber, [1] or The through-air non-woven fabric according to [2].
[4] A step of producing a web of a composite fiber which is composed of polyethylene terephthalate and polyethylene and is selected from the group consisting of a parallel type composite fiber, an eccentric sheath core type composite fiber and a concentric sheath core type composite fiber. The production of the through-air nonwoven fabric according to any one of [1] to [3], which comprises a step of heat-treating the web obtained in 1) by a through-air method and a step of compacting the web immediately after the heat treatment step. Method.
[5] An absorbent article comprising the through-air nonwoven fabric according to any one of [1] to [3].

3.5gf/cm荷重下での厚みと50gf/cm荷重下での厚みの比を0.5〜0.8とすることにより不織布の形状を保持し、一旦吸収体に吸収された排泄液の肌側への戻りを抑制できる。また、体積あたりの繊維表面積を70〜120cm/cmとすることにより、毛細管現象による液拡散を抑制することができ、これにより液戻りを低減できる。このように、上述の構成を有する本発明によれば、排泄液に対し十分な吸収性を有し、且つ荷重下でも液戻りが抑制される。 The ratio of the thickness of the thickness and 50 gf / cm under a 2 weight under 3.5 gf / cm 2 load to maintain the shape of the nonwoven fabric by a 0.5 to 0.8, it is once absorbed into the absorbent body excretion The return of the liquid to the skin side can be suppressed. Further, by setting the fiber surface area per volume to 70 to 120 cm 2 / cm 3 , it is possible to suppress the liquid diffusion due to the capillary phenomenon, and thereby the liquid return can be reduced. As described above, according to the present invention having the above-mentioned configuration, it has sufficient absorbency to the excreted liquid and the liquid return is suppressed even under a load.

本発明の不織布は、3.5gf/cm荷重下での厚みに対する、50gf/cm荷重下での厚みの比が0.5〜0.8であり、かつ、50gf/cm荷重下での体積当たりの繊維表面積が70〜120cm/cmであるスルーエア不織布であり、吸収性物品のセカンドシートとして好適に用いられる。 Non-woven fabric of the present invention, to the thickness of the under 3.5 gf / cm 2 load, a ratio of the thickness of the under 50 gf / cm 2 load is 0.5 to 0.8, and, 50 gf / cm under 2 Load at It is a through-air non-woven fabric having a fiber surface area of 70 to 120 cm 2 / cm 3 per volume, and is suitably used as a second sheet of an absorbent article.

本発明の不織布は、スルーエア不織布であって、その原料としては、繊維同士を熱によって接着できる、熱接着性繊維を含むものを使用できる。例えば、単一又は複数種類の熱接着性複合繊維であってもよいし、複数の種類の熱接着性繊維を混合(混繊)して用いてもよい。好ましくは、融点の異なる複数の樹脂が複合された、熱接着性を有する複合繊維が挙げられる。複合繊維の熱接着性成分は、その繊維からなるウェブに熱風を通すことによって熱溶融し、接着点を形成する熱可塑性樹脂成分であればよい。繊維同士の熱接着点は、融点の低い熱可塑性樹脂成分が熱風処理で溶融することにより形成される。熱接着性繊維を構成する樹脂成分としては、ポリオレフィン系(例えば、ポリプロピレン、プロピレン共重合体[プロピレンを主成分とし、これと他のα−オレフィンとの共重合体;例えば、エチレン−プロピレン二元共重合体、プロピレン−ブテン−1二元共重合体、プロピレン−ヘキセン−1二元共重合体等]、ポリエチレン等)、ポリエステル系(例えば、ポリエチレンテレフタレート)、ポリアミド系(例えば、ナイロン6等)が例示できる。複合繊維における低融点成分と高融点成分の具体的な組み合わせとしては、ポリエチレン(低融点成分)とポリプロピレン(高融点成分)、ポリエチレン(低融点成分)とポリエチレンテレフタレート(高融点成分)等が例示でき、特に嵩高性、不織布強力の点で好ましいのは、ポリエチレン(低融点成分)とポリエチレンテレフタレート(高融点成分)からなる複合繊維である。 The non-woven fabric of the present invention is a through-air non-woven fabric, and as a raw material thereof, a non-woven fabric containing heat-adhesive fibers capable of adhering fibers to each other by heat can be used. For example, it may be a single type or a plurality of types of heat-adhesive composite fibers, or a plurality of types of heat-adhesive fibers may be mixed (mixed) and used. Preferably, a composite fiber having heat adhesiveness, in which a plurality of resins having different melting points are composited, can be mentioned. The heat-adhesive component of the composite fiber may be a thermoplastic resin component that heat-melts by passing hot air through the web made of the fiber to form an adhesive point. The thermal adhesion points between the fibers are formed by melting the thermoplastic resin component having a low melting point by hot air treatment. The resin component constituting the heat-adhesive fiber is a polyolefin-based (for example, polypropylene, propylene copolymer [a copolymer containing propylene as a main component and another α-olefin; for example, ethylene-propylene binary; Copolymer, propylene-butene-1 binary copolymer, propylene-hexene-1 binary copolymer, etc.], polyethylene, etc.), polyester-based (for example, polyethylene terephthalate), polyamide-based (for example, nylon 6, etc.) Can be exemplified. Specific combinations of the low melting point component and the high melting point component in the composite fiber include polyethylene (low melting point component) and polypropylene (high melting point component), polyethylene (low melting point component) and polyethylene terephthalate (high melting point component), and the like. Particularly, a composite fiber composed of polyethylene (low melting point component) and polyethylene terephthalate (high melting point component) is preferable in terms of bulkiness and strength of the non-woven fabric.

また、スルーエア不織布を製造するためのウェブには、前記の熱接着性を有する複合繊維に加えて、天然繊維(木質繊維等)、再生繊維(レーヨン等)、半合成繊維(アセテート等)や化学繊維、合成繊維(ポリエステル、アクリル、ナイロン、塩化ビニル等)等のいわゆる熱接着性繊維でない繊維(以下、「非熱接着性繊維」と言う)を含んでもよい。「非熱接着性繊維」とは、不織布を製造する際に行われる熱接着において、熱接着に関与するような熱的変化(溶融又は軟化)を生じない繊維をいう。非熱接着性繊維が含まれる場合、ウェブの全重量に対する非熱接着性繊維の割合は、発明の効果を阻害しない限り制限されないが、例えば、1〜30重量%とすることができ、好ましくは3〜15重量%である。 In addition to the above-mentioned heat-adhesive composite fibers, natural fibers (wooden fibers, etc.), recycled fibers (rayons, etc.), semi-synthetic fibers (acetates, etc.) and chemical fibers are used on the web for producing through-air non-woven fabrics. Fibers that are not so-called heat-adhesive fibers such as fibers and synthetic fibers (polyester, acrylic, nylon, vinyl chloride, etc.) (hereinafter referred to as "non-heat-adhesive fibers") may be included. The "non-thermally adhesive fiber" refers to a fiber that does not undergo a thermal change (melting or softening) that is involved in thermal bonding in the thermal bonding performed when manufacturing a non-woven fabric. When non-heat-adhesive fibers are included, the proportion of non-heat-adhesive fibers to the total weight of the web is not limited as long as it does not interfere with the effects of the invention, but can be, for example, 1-30% by weight, preferably 1-30% by weight. It is 3 to 15% by weight.

複合繊維の形状は、その長手方向に垂直な断面において、同心鞘芯型、偏心鞘芯型、並列型を例示できる。同心鞘芯型複合繊維や偏心鞘芯型複合繊維の場合、低融点成分が鞘成分を構成し、高融点成分が芯成分を構成する複合繊維であることが好ましい。 The shape of the composite fiber can be exemplified by a concentric sheath core type, an eccentric sheath core type, and a parallel type in a cross section perpendicular to the longitudinal direction thereof. In the case of concentric sheath-core type composite fibers and eccentric sheath-core type composite fibers, it is preferable that the low melting point component constitutes the sheath component and the high melting point component constitutes the core component.

複合繊維を原料として、カード機によりウェブを作製する場合、複合繊維は捲縮を有することが必要である。同心鞘芯型複合繊維の場合、クリンパーでジグザグ形状の機械捲縮を付与することができる。また、偏心鞘芯型複合繊維の場合、クリンパーでジグザグ形状の機械捲縮を付与することや、延伸や乾燥工程で三次元捲縮を付与することができる。捲縮数は、7.0〜20.0山/2.54cmであれば、カード機の通過性が良好であり、11.0〜16.0山/2.54cmであれば、得られるウェブの地合が良好となる。 When the web is produced by a card machine using the composite fiber as a raw material, the composite fiber needs to have crimping. In the case of concentric sheath-core type composite fibers, a crimper can be used to impart a zigzag-shaped mechanical crimp. Further, in the case of the eccentric sheath core type composite fiber, a zigzag-shaped mechanical crimp can be imparted by a crimper, and a three-dimensional crimp can be imparted by a stretching or drying step. If the number of crimps is 7.0 to 20.0 ridges / 2.54 cm, the passability of the card machine is good, and if it is 11.0-16.0 ridges / 2.54 cm, the obtained web The condition of is good.

本発明のスルーエア不織布は、3.5gf/cm荷重下での厚みに対する50gf/cm荷重下での厚みの比が0.5〜0.8であるという特徴を有する。低荷重下と高荷重下で厚みが大きく変化しない、「潰れにくい」不織布であることによって、吸収体とトップシートの間を充分に隔てることができ、優れた液戻り防止性を有するものと考えられている。従来のセカンドシートでは、低荷重下では比較的厚みがあり(例えば1mm以上等)、かつ、高荷重時には、低荷重の厚みの大部分が潰れてもなお一定の厚みを保持できるものが検討されてきた。しかしながら、本願発明では、低荷重時から比較的厚みが薄くかつ高荷重下でも潰れにくい不織布とすることによって、吸収性物品に搭載された場合に吸水性物品自体の厚みを低減でき、また吸収性物品表面部分のゴワつきを抑制することができる。厚みの比が0.5〜0.8であることが肝要であり、0.6〜0.7であれば好ましい。 Through-air nonwoven fabric of the present invention, the ratio of the thickness of the under 50 gf / cm 2 load to the thickness under 3.5 gf / cm 2 load has a characteristic of being 0.5 to 0.8. It is considered that the non-woven fabric that does not change significantly in thickness under low load and high load and is "hard to crush" can sufficiently separate the absorber from the top sheet and has excellent liquid return prevention properties. Has been done. A conventional second sheet that is relatively thick under a low load (for example, 1 mm or more) and that can maintain a constant thickness even if most of the thickness of the low load is crushed under a high load has been studied. I came. However, in the present invention, by using a non-woven fabric that is relatively thin from a low load and is not easily crushed even under a high load, the thickness of the water-absorbent article itself can be reduced when mounted on the absorbent article, and the absorbency is also reduced. It is possible to suppress the stiffness of the surface portion of the article. It is important that the thickness ratio is 0.5 to 0.8, preferably 0.6 to 0.7.

また、本願発明のスルーエア不織布は、50gf/cm荷重下での体積当たりの繊維表面積が70〜120cm/cmであるという特徴を有する。ここで、体積当たりの繊維表面積とは、不織布の1cm(1cc)に含まれる繊維の表面積の総和であり、構成する繊維の表面積と不織布の繊維密度とから算出される値である。繊維表面積及び体積当たりの繊維表面積は次式(1)及び(2)によって算出される。 Further, the through-air nonwoven fabric of the present invention is characterized in that the fiber surface area per volume under a load of 50 gf / cm 2 is 70 to 120 cm 2 / cm 3 . Here, the fiber surface area per volume is the total surface area of the fibers contained in 1 cm 3 (1 cc) of the non-woven fabric, and is a value calculated from the surface area of the constituent fibers and the fiber density of the non-woven fabric. The fiber surface area and the fiber surface area per volume are calculated by the following equations (1) and (2).

(1)繊維表面積(cm/g)=繊維径(μm)÷10000(μm/cm)×π×10000(m)×100(cm/m)÷繊維10000mの重量(g) (1) Fiber surface area (cm 2 / g) = fiber diameter (μm) ÷ 10000 (μm / cm) × π × 10000 (m) × 100 (cm / m) ÷ fiber 10000 m weight (g)

(2)体積当たりの繊維表面積(cm/cm)=繊維表面積(cm/g)×不織布の繊維密度(g/cm(2) Fiber surface area per volume (cm 2 / cm 3 ) = Fiber surface area (cm 2 / g) x Fiber density of non-woven fabric (g / cm 3 )

特に理論に拘束されるものではないが、本発明において、荷重下での不織布の体積当たりの繊維表面積は、不織布に生じる毛細管現象と関連するものと考えられており、50gf/cm荷重下での体積当たりの繊維表面積が70〜120cm/cmである範囲では、尿等の排泄液の吸収体への優れた透過性を得ることができ、液戻りを抑制できる。本発明のスルーエア不織布は特に、前述の「潰れにくさ」が一定の範囲であり、かつ、不織布の体積当たりの繊維表面積が一定の範囲であるときに、優れた液通過性かつ優れた液戻り防止性が得られると考えられている。 Although not particularly bound by theory, in the present invention, the fiber surface area per volume of the nonwoven fabric under load is considered to be related to the capillary phenomenon occurring in the nonwoven fabric, and under a load of 50 gf / cm 2 . In the range where the fiber surface area per volume is 70 to 120 cm 2 / cm 3 , excellent permeability of excrement liquid such as urine to the absorber can be obtained, and liquid return can be suppressed. The through-air non-woven fabric of the present invention has excellent liquid permeability and excellent liquid return, particularly when the above-mentioned "difficulty of crushing" is within a certain range and the fiber surface area per volume of the non-woven fabric is within a certain range. It is believed that preventive properties can be obtained.

本願発明のスルーエア不織布の目付は、上記の構成を満たし、本願発明の効果を得られる限り制限されないが、例えば、20〜35g/mとすることができ、25〜33g/mであることがより好ましい。本願発明のスルーエア不織布は、セカンドシートとして比較的低目付ながらも、優れた液戻り防止性を有するため、吸収性物品全体の軽量化、コンパクト化を図ることもできる。 The basis weight of the through-air nonwoven fabric of the present invention is not limited as long as it satisfies the above constitution and the effect of the present invention can be obtained, but it can be, for example, 20 to 35 g / m 2 and 25 to 33 g / m 2. Is more preferable. The through-air non-woven fabric of the present invention has a relatively low basis weight as a second sheet, but has excellent liquid return prevention properties, so that the weight and compactness of the entire absorbent article can be reduced.

本願発明のスルーエア不織布を構成する繊維の繊度は、上記の構成を満たし、本願発明の効果を得られる限り制限されないが、例えば2.0〜20dtexとすることができ、好ましくは3〜15dtexであり、さらに好ましくは5〜10dtexの範囲である。繊度が20dtex以上である繊維を用いると触感の硬い不織布となり、吸収性物品に搭載した際、表面の触感に悪影響を及ぼすこととなり、また、繊度が2.0dtex以下である繊維を用いることによって高荷重時に厚みを維持できなくなるとともに液戻りが促進されると考えられている。 The fineness of the fibers constituting the through-air nonwoven fabric of the present invention is not limited as long as it satisfies the above constitution and the effect of the present invention can be obtained, but can be, for example, 2.0 to 20 dtex, preferably 3 to 15 dtex. , More preferably in the range of 5-10 dtex. If a fiber having a fineness of 20 dtex or more is used, it becomes a non-woven fabric having a hard tactile sensation, which adversely affects the tactile sensation of the surface when mounted on an absorbent article, and is high by using a fiber having a fineness of 2.0 dtex or less. It is thought that the thickness cannot be maintained under load and the liquid return is promoted.

本発明の不織布には、本発明の効果を妨げない範囲で、消臭成分、抗アレルゲン成分、抗菌成分、湿潤成分、保湿成分等を添加することができる。これらの成分は、不織布に噴霧等により付着させる方法や、不織布を構成する複合繊維の少なくとも一方の熱可塑性複合繊維の内部に練り込む方法、または、繊維表面に付着させる方法等によって、付与することができる。 To the non-woven fabric of the present invention, a deodorant component, an anti-allergen component, an antibacterial component, a wetting component, a moisturizing component and the like can be added as long as the effects of the present invention are not impaired. These components are added by a method of adhering to the non-woven fabric by spraying or the like, a method of kneading into at least one of the thermoplastic composite fibers of the non-woven fabric, or a method of adhering to the fiber surface. Can be done.

本発明の不織布をセカンドシートとして用いた吸収性物品は、例えば、使い捨ておむつ等のおむつ、尿パッド、経血吸収パッド等として使用される。本発明の不織布をセカンドシートして用いた吸収性物品は、セカンドシートとして上述のスルーエア不織布を用いるほかは、従来公知の構成とすることができるが、具体的には、例えば、次の構成とすることができる。 The absorbent article using the non-woven fabric of the present invention as a second sheet is used, for example, as a diaper such as a disposable diaper, a urine pad, a menstrual blood absorbing pad, and the like. The absorbent article using the nonwoven fabric of the present invention as a second sheet may have a conventionally known configuration other than using the above-mentioned through-air nonwoven fabric as the second sheet. Specifically, for example, the following configuration is used. can do.

吸収性物品は、トップシートと、セカンドシートと、吸収体と、防水性のバックシートとを含む。トップシートは、例えばスルーエア不織布単層もしくは積層したものを用いることができる。吸収体は、典型的には吸収性材料によって構成される。吸収性材料としては、使い捨ておむつ等の吸収性物品に使用可能な公知の吸収性材料を用いることができる。具体的には、フラッフパルプ、高吸水性ポリマー(Super Absorbent Polymer、SAP)、親水性シート等を挙げることができ、これらのうちの1種以上を使用できる。 Absorbent articles include a top sheet, a second sheet, an absorber, and a waterproof back sheet. As the top sheet, for example, a through-air non-woven fabric single layer or laminated can be used. The absorber is typically composed of an absorbent material. As the absorbent material, a known absorbent material that can be used for an absorbent article such as a disposable diaper can be used. Specific examples thereof include fluff pulp, super absorbent polymer (SAP), hydrophilic sheet and the like, and one or more of these can be used.

フラッフパルプとしては、木材パルプや非木材パルプを綿状に解繊したものが好ましい。SAPとしては、ポリアクリル酸ナトリウムが好ましい。親水性シートとしては、ティシュペーパー、吸収紙の他、不織布を使用できる。不織布を用いる場合には、親水化処理したものが好ましい。また、型崩れ対策として、熱融着繊維等の合成繊維を含んだものであってもよい。これらの材料は単独で用いてもよいし、組み合わせで用いてもよく、例えば、好ましい吸収性材料として、フラッフパルプ100質量部に対して、10〜500質量部程度のSAPを併用したものが挙げられる。 As the fluff pulp, wood pulp or non-wood pulp defibrated into cotton is preferable. As the SAP, sodium polyacrylate is preferable. As the hydrophilic sheet, non-woven fabric can be used in addition to tissue paper and absorbent paper. When a non-woven fabric is used, it is preferably hydrophilized. Further, as a measure against shape loss, synthetic fibers such as heat-sealed fibers may be included. These materials may be used alone or in combination. For example, as a preferable absorbent material, a material in which about 10 to 500 parts by mass of SAP is used in combination with 100 parts by mass of fluff pulp can be mentioned. Be done.

吸収体は、通常、単層ないしは複層のマット状で用いられる。フラッフパルプとSAPが併用される場合、SAPはフラッフパルプのマット中に均一に混合されていてもよいし、複層のフラッフパルプの層間に層状に配置されていてもよい。また、吸収体として、このようにSAPが用いられる場合、吸収体層からのSAPの漏洩を防止し、また、吸収体層に形状安定性を付与するために、吸収体層の全体を親水性シートで被覆することが好ましい。 The absorber is usually used in the form of a single-layer or multi-layer mat. When the fluff pulp and the SAP are used together, the SAP may be uniformly mixed in the mat of the fluff pulp, or may be arranged in layers between the layers of the multi-layered fluff pulp. Further, when SAP is used as the absorber in this way, the entire absorber layer is made hydrophilic in order to prevent leakage of SAP from the absorber layer and to impart shape stability to the absorber layer. It is preferable to cover with a sheet.

吸収体の下面側には、吸収対象物が吸収性物品の外部に漏れることを防止するために、防水性を有するバックシートが設けられる。バックシートは、吸収性物品の最外層を形成するものであって、吸収性物品を着用者が装着した際には、着用者の着衣側に位置する層である。バックシートを構成する材料としては、例えば、ポリエチレン等の樹脂からなる液不透過性フィルム等を挙げることができ、中でも、微多孔性ポリエチレンフィルムを用いることが好ましい。微多孔性ポリエチレンフィルムは、0.1〜数μmの微細な孔が多数形成されたものであって、液不透過性ではあるが透湿性を有するため、これを用いることによって、吸収性物品の内部の蒸れを防止できる。 A waterproof back sheet is provided on the lower surface side of the absorber in order to prevent the object to be absorbed from leaking to the outside of the absorbent article. The back sheet forms the outermost layer of the absorbent article, and is a layer located on the clothing side of the wearer when the absorbent article is worn by the wearer. Examples of the material constituting the back sheet include a liquid-impermeable film made of a resin such as polyethylene, and among them, a microporous polyethylene film is preferably used. The microporous polyethylene film has a large number of fine pores of 0.1 to several μm formed, and is impermeable to liquid but has moisture permeability. Therefore, by using this, an absorbent article can be obtained. Can prevent internal stuffiness.

なお、バックシートの最外面には、さらに防水性フィルムを設けて補強したり、使用時の手触りを向上させたりするために、紙クロス、織布、スパンレース不織布、スパンボンド不織布等からなるカバーシートを設けてもよい。なかでも、スパンボンド不織布が、強度やコスト面で好適に用いられる。 A cover made of paper cloth, woven fabric, spunlace non-woven fabric, spunbond non-woven fabric, etc. is provided on the outermost surface of the back sheet to further reinforce it and improve the feel during use. A sheet may be provided. Among them, spunbonded non-woven fabric is preferably used in terms of strength and cost.

また、吸収性物品は、吸収性物品のズレを防止するための固定手段を有していてもよい。固定手段としては、例えば、粘着テープ等が挙げられ、吸収性物品の最外面に1箇所以上設けられる。その他、例えば、伸縮帯や伸縮テープ、立体形状を形成させるためのギャザー等、目的に応じて任意の各種の構成を有することができる。 Further, the absorbent article may have a fixing means for preventing the absorbent article from being displaced. Examples of the fixing means include an adhesive tape and the like, which are provided at one or more places on the outermost surface of the absorbent article. In addition, for example, an elastic band, an elastic tape, gathers for forming a three-dimensional shape, and the like can have any various configurations depending on the purpose.

(製造方法)
本発明の不織布はスルーエア不織布であり、ウェブの製造方法は公知の方法及び条件を適切に選択することによって得られる。前述のとおり、融点の異なる複数の樹脂が複合された、熱接着性を有する複合繊維を用いてウェブを作製することが好ましい。得られたウェブは、搬送支持体(ベルトコンベア)に載置されて熱処理装置中に送入される。熱処理装置の中で、複合繊維の低融点樹脂のみが溶融する温度まで加熱が行われ、溶融した低融点樹脂が互いに接着(熱接着)することによって、繊維の交点が融着し、その後冷却することで立体構造を有するスルーエア不織布が製造される。さらに、本発明では熱処理機で繊維の低融点樹脂が溶融した状態で、例えばロールやプレートでウェブを圧密し、繊維同士を強制的に接触させ熱接着させることが好ましい。圧密は、熱処理の後であればよいが、熱処理に引き続いて、熱処理の直後に行うことが好ましい。この工程により、不織布中の接着点が増加し、高荷重時に潰れにくい不織布が得られる。
(Production method)
The non-woven fabric of the present invention is a through-air non-woven fabric, and a method for producing a web can be obtained by appropriately selecting known methods and conditions. As described above, it is preferable to prepare a web using a composite fiber having heat adhesiveness in which a plurality of resins having different melting points are composited. The obtained web is placed on a transport support (belt conveyor) and fed into the heat treatment apparatus. In the heat treatment device, heating is performed to a temperature at which only the low melting point resin of the composite fiber melts, and the melted low melting point resins adhere to each other (heat adhesion), so that the intersections of the fibers are fused and then cooled. As a result, a through-air non-woven fabric having a three-dimensional structure is manufactured. Further, in the present invention, it is preferable that the web is compacted by, for example, a roll or a plate in a state where the low melting point resin of the fiber is melted by a heat treatment machine, and the fibers are forcibly brought into contact with each other to be thermally bonded. Consolidation may be performed after the heat treatment, but is preferably performed immediately after the heat treatment following the heat treatment. By this step, the adhesive points in the non-woven fabric are increased, and a non-woven fabric that is not easily crushed under a high load can be obtained.

以下、実施例によって本発明をより詳細に説明するが、以下の実施例は例示を目的としたものに過ぎない。本発明の範囲は、本実施例に限定されない。 Hereinafter, the present invention will be described in more detail by way of examples, but the following examples are for purposes of illustration only. The scope of the present invention is not limited to this embodiment.

実施例、比較例で用いた物性値の測定方法及び定義を以下に示す。 The measurement method and definition of the physical property values used in the examples and comparative examples are shown below.

<不織布の目付>
10cm×10cmの正方形に不織布を切り出し、その重量を測定し、単位面積当たりに換算し、小数点以下第一位を四捨五入して求めた。
<Metsuke of non-woven fabric>
A non-woven fabric was cut into a square of 10 cm × 10 cm, the weight of the non-woven fabric was measured, converted per unit area, and rounded off to the first decimal place.

<不織布の厚み>
10cm×10cmの正方形に不織布を切り出し、カトーテック製『ハンディ―圧縮機KES−G5』(商品名)を用いて、2cmの加圧板で不織布を圧縮し、3.5gf/cm、50gf/cmそれぞれでの厚みを測定した。
<Thickness of non-woven fabric>
Cut out the non-woven fabric into a square of 10 cm x 10 cm, and compress the non-woven fabric with a 2 cm 2 pressure plate using "Handy-Compressor KES-G5" (trade name) manufactured by Katou Tech, and 3.5 gf / cm 2 , 50 gf /. The thickness at each cm 2 was measured.

<不織布の厚み比>
3.5gf/cm荷重時の厚みに対する、50gf/cm荷重時の厚みの比であり、下記式で表される。
厚み比=50gf/cm荷重時の厚み÷3.5gf/cm荷重時の厚み
<Thickness ratio of non-woven fabric>
For 3.5 gf / cm 2 load at a thickness, a ratio of the thickness at 50 gf / cm 2 load, represented by the following formula.
Thickness ratio = 50 gf / cm Thickness under 2 loads ÷ 3.5 gf / cm Thickness under 2 loads

<50gf/cm荷重下での不織布体積当たりの繊維表面積>
不織布を構成する複合繊維の繊維径から繊維表面積を算出した。繊維径は走査型電子顕微鏡(SEM)を用いて、不織布表面の拡大写真を撮影し、20本の繊維の直径を測定し、その算術平均値を用いた。繊維表面積及び体積当たりの繊維表面積は次式(1)及び(2)によって算出した。
(1)繊維表面積(cm/g)=繊維径(μm)÷10000(μm/cm)×π×10000(m)×100(cm/m)÷繊維10000mの重量(g)
(2)体積当たりの繊維表面積(cm/cm)=繊維表面積(cm/g)×不織布の繊維密度(g/cm
繊維表面積に50gf/cm荷重下の不織布密度を掛けることで、50gf/cm荷重下での不織布体積当たりの繊維表面積(cm/cm)を算出した。
<Fiber surface area per volume of non-woven fabric under 50 gf / cm 2 load>
The fiber surface area was calculated from the fiber diameter of the composite fiber constituting the non-woven fabric. For the fiber diameter, a magnified photograph of the surface of the non-woven fabric was taken using a scanning electron microscope (SEM), the diameters of 20 fibers were measured, and the arithmetic mean value was used. The fiber surface area and the fiber surface area per volume were calculated by the following equations (1) and (2).
(1) Fiber surface area (cm 2 / g) = fiber diameter (μm) ÷ 10000 (μm / cm) × π × 10000 (m) × 100 (cm / m) ÷ fiber 10000 m weight (g)
(2) Fiber surface area per volume (cm 2 / cm 3 ) = Fiber surface area (cm 2 / g) x Fiber density of non-woven fabric (g / cm 3 )
By multiplying the nonwoven density under 50 gf / cm 2 load to fiber surface area was calculated fiber surface area per nonwoven volume under 50 gf / cm 2 load (cm 2 / cm 3).

<液戻り試験>
EDANA−ERT 151.1−96に準じた方法により評価した。なお、使用した吸収紙は(株)クレシア製キムタオル(商品名)を約90mm×90mm(5.00〜5.05gになるように調整)に裁断したものを用い、生理食塩水15mlを透水、吸収させた。液戻り量を以下の基準で判定した。液戻り量が少ないほど良好な不織布と判断した。
○:2.0g未満
△:2.0g以上、3.0g未満
×:3.0g以上
<Liquid return test>
It was evaluated by a method according to EDANA-ERT 151.1-96. The absorbent paper used was Kim Towel (trade name) manufactured by Crecia Co., Ltd. cut into approximately 90 mm x 90 mm (adjusted to 5.00 to 5.05 g), and 15 ml of physiological saline was permeable. Absorbed. The amount of liquid return was determined according to the following criteria. It was judged that the smaller the amount of liquid returned, the better the non-woven fabric.
◯: less than 2.0 g Δ: 2.0 g or more, less than 3.0 g ×: 3.0 g or more

[実施例1]
繊度5.6dtex、鞘成分がポリエチレン、芯成分がポリエチレンテレフタレートの鞘芯型複合繊維からなる目付31g/mの不織布を作製した。まず、前記の複合繊維をカーディング法にてウェブとした。138℃の熱風循環式サクションバンドドライヤーを用いて、得られたウェブに熱風を通過させることにより、ウェブを構成する繊維間交絡点を接着させ、その直後に金属ローラーを用いてウェブを圧縮し、強制的に繊維間の熱接着を促進させることで作製した。
この不織布は不織布厚み比=0.69、50gf/cm荷重時の体積当たりの繊維表面積が95cm/cmであり、液戻りは1.6gと良好な結果が得られた。
[Example 1]
A non-woven fabric having a basis weight of 31 g / m 2 was produced, which consisted of a sheath-core type composite fiber having a fineness of 5.6 dtex, a sheath component of polyethylene, and a core component of polyethylene terephthalate. First, the composite fiber was made into a web by a carding method. A hot air circulation type suction band dryer at 138 ° C. was used to pass hot air through the obtained web to bond the interfiber confounding points constituting the web, and immediately after that, the web was compressed using a metal roller. It was produced by forcibly promoting thermal adhesion between fibers.
The nonwoven fabric fiber surface area per volume during nonwoven thickness ratio = 0.69,50gf / cm 2 load is 95cm 2 / cm 3, liquid return was obtained good results with 1.6 g.

[実施例2〜3]
表1に記載の同心鞘芯型熱接着性複合繊維を用い、実施例1と同様にして、表1に記載の不織布を作製した。実施例1と同様に評価した結果を表1に示す。なお、原料繊維として、実施例2では9.0dtex、実施例3では20dtexの、鞘成分がポリエチレン、芯成分がポリエチレンテレフタレートである鞘芯型複合繊維を不織布の原料として用いた。
いずれも液戻りは抑制されており良好な結果が得られた。
[Examples 2 to 3]
The non-woven fabric shown in Table 1 was prepared in the same manner as in Example 1 using the concentric sheath core type heat-adhesive composite fibers shown in Table 1. Table 1 shows the results of evaluation in the same manner as in Example 1. As the raw material fiber, a sheath-core type composite fiber having a sheath component of polyethylene and a core component of polyethylene terephthalate having 9.0 dtex in Example 2 and 20 dtex in Example 3 was used as a raw material for the non-woven fabric.
In all cases, liquid return was suppressed and good results were obtained.

[比較例1]
繊度5.6dtex、鞘成分がポリエチレン、芯成分がポリエチレンテレフタレートの鞘芯型複合繊維からなる目付30g/mの不織布を作製した。まず、前記の複合繊維をカーディング法にてウェブとした。138℃の熱風循環式サクションバンドドライヤーを用いて、得られたウェブに熱風を通過させることにより、ウェブを構成する繊維間交絡点を接着させた。その後、金属ローラーを用いたウェブの圧縮は行わず不織布を作製した。この不織布は不織布厚み比0.12、50gf/cm荷重時の体積当たりの繊維表面積が555cm/cmであり、液戻りは2.6gと不良な結果が得られた。
[Comparative Example 1]
A non-woven fabric having a basis weight of 30 g / m 2 was produced, which consisted of a sheath-core type composite fiber having a fineness of 5.6 dtex, a sheath component of polyethylene, and a core component of polyethylene terephthalate. First, the composite fiber was made into a web by a carding method. The interfiber entanglement points constituting the web were adhered by passing hot air through the obtained web using a hot air circulation type suction band dryer at 138 ° C. Then, the non-woven fabric was produced without compressing the web using a metal roller. The nonwoven fabric fiber surface area per volume during nonwoven thickness ratio 0.12,50gf / cm 2 load was 555cm 2 / cm 3, liquid return was obtained 2.6g and poor outcome.

[比較例2〜3]
表1に記載の同心鞘芯型熱接着性複合繊維を用い、比較例1と同様にして、表1に記載の不織布を作製した。比較例1と同様に評価した結果を表1に示す。なお、原料繊維として、比較例2では5.6dtex、比較例3では9.0dtexの、鞘成分がポリエチレン、芯成分がポリエチレンテレフタレートである鞘芯型複合繊維を不織布の原料として用いた。いずれも液戻りは抑制できておらず不良な結果が得られた。
[Comparative Examples 2-3]
The non-woven fabric shown in Table 1 was prepared in the same manner as in Comparative Example 1 using the concentric sheath core type heat-adhesive composite fibers shown in Table 1. Table 1 shows the results of evaluation in the same manner as in Comparative Example 1. As the raw material fiber, a sheath-core type composite fiber having a sheath component of polyethylene and a core component of polyethylene terephthalate having 5.6 dtex in Comparative Example 2 and 9.0 dtex in Comparative Example 3 was used as a raw material for the non-woven fabric. In each case, the liquid return could not be suppressed and poor results were obtained.

Figure 2020165011
Figure 2020165011

実施例1と比較例1、実施例2と比較例3はそれぞれ、不織布を構成する繊維が同じで、スルーエア不織布の作製後の圧密処理の有無のみが異なる例である。表1に示されるとおり、実施例1と比較例1、実施例2と比較例3はそれぞれ、3.5gf/cm荷重下での厚みはほぼ同じであるが、50gf/cm荷重下での厚みが大きく異なり、実施例1,2の不織布は荷重下でも潰れにくく、荷重下でも体積当たりの繊維表面積が一定範囲に維持されることがわかる。表1に示されるとおり、スルーエア不織布の不織布厚み比、及び、50gf/cm荷重時の体積当たりの繊維表面積を、規定の範囲にコントロールすることで液戻りを大幅に抑制できた。 Example 1 and Comparative Example 1 and Example 2 and Comparative Example 3 are examples in which the fibers constituting the non-woven fabric are the same, and only the presence or absence of consolidation treatment after the production of the through-air non-woven fabric is different. As shown in Table 1, Example 1 and Comparative Example 1, respectively Comparative Example 3 and Example 2, the thickness of the under 3.5 gf / cm 2 load is almost the same, 50 gf / cm under 2 Load at It can be seen that the non-woven fabrics of Examples 1 and 2 are not easily crushed even under a load, and the fiber surface area per volume is maintained within a certain range even under a load. As shown in Table 1, by controlling the non-woven fabric thickness ratio of the through-air non-woven fabric and the fiber surface area per volume under a load of 50 gf / cm 2 within a specified range, liquid return could be significantly suppressed.

本発明のスルーエア不織布は、使い捨ておむつ等のおむつ、尿パッド、経血吸収パッド等に搭載されるセカンドシートとして使用することができる。 The through-air non-woven fabric of the present invention can be used as a second sheet mounted on diapers such as disposable diapers, urine pads, menstrual blood absorption pads and the like.

Claims (5)

3.5gf/cm荷重下での厚みに対する、50gf/cm荷重下での厚みの比が0.5〜0.8であり、かつ、50gf/cm荷重下での体積当たりの繊維表面積が70〜120cm/cmである、スルーエア不織布。 For 3.5 gf / cm 2 Thickness under load, the ratio of the thickness of the under 50 gf / cm 2 load is 0.5 to 0.8, and fiber surface area per volume under 50 gf / cm 2 load A through-air non-woven fabric having a surface area of 70 to 120 cm 2 / cm 3 . 目付が20〜35g/mである、請求項1に記載のスルーエア不織布。 The through-air nonwoven fabric according to claim 1, which has a basis weight of 20 to 35 g / m 2 . ポリエチレンテレフタレートとポリエチレンとからなり、並列型複合繊維、偏心鞘芯型複合繊維及び同心鞘芯型複合繊維からなる群から選ばれるいずれかである複合繊維から構成される、請求項1又は2に記載のスルーエア不織布。 The first or second claim, wherein the polyethylene terephthalate and polyethylene are composed of a composite fiber which is one of the group consisting of a parallel type composite fiber, an eccentric sheath core type composite fiber and a concentric sheath core type composite fiber. Through-air non-woven fabric. ポリエチレンテレフタレートとポリエチレンとからなり、並列型複合繊維、偏心鞘芯型複合繊維及び同心鞘芯型複合繊維からなる群から選ばれるいずれかである複合繊維のウェブを作製する工程、
前記工程で得られたウェブをスルーエア法によって熱処理する工程、及び、
前記熱処理工程の直後に前記ウェブを圧密する工程、を含む、
請求項1〜3のいずれか1項に記載のスルーエア不織布の製造方法。
A step of producing a web of composite fibers, which is composed of polyethylene terephthalate and polyethylene and is selected from the group consisting of parallel type composite fibers, eccentric sheath core type composite fibers and concentric sheath core type composite fibers.
A step of heat-treating the web obtained in the above step by the through-air method, and
A step of compacting the web immediately after the heat treatment step is included.
The method for producing a through-air nonwoven fabric according to any one of claims 1 to 3.
請求項1〜3のいずれかに記載のスルーエア不織布を含む、吸収性物品。 An absorbent article comprising the through-air nonwoven fabric according to any one of claims 1-3.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021215492A1 (en) * 2020-04-22 2021-10-28 花王株式会社 Non-woven fabric for hygiene, hygienic product and absorbent article provided with same, and method for manufacturing non-woven fabric for hygiene

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