JP2020164422A - Hairdressing agent composition and hairdressing agent - Google Patents

Abstract

To provide a hairdressing agent composition excellent in hairdressing power for raising hair, arranging power and usability.SOLUTION: There is provided a hairdressing agent composition which is discharged and used from a container, which comprises a gel-like composition containing a polyoxyethylene oleyl ether (component A), a polyoxyethylene alkyl ether having an HLB value of 10.0 or more (component B), a film-forming polymer (component C), a thickener (component D) and water (component E) and a liquefied gas (component X) and is in a state of an emulsion composition where the component X exists as a dispersoid in the gel-like composition as a dispersant and can be changed into a foam state during discharging or after discharging from the container.SELECTED DRAWING: None

Description

The present invention relates to a hair styling composition that is discharged from a container and used. The present invention also relates to a hair styling product in which the above-mentioned hair styling product composition is filled in a container.

There are various hair styling properties that can be exhibited by the hair styling agent composition used for hair styling. For example, as hair styling characteristics, there are characteristics such as tying hair together (for example, tying hair tightly, tying hair together to form a hair bundle, etc.), and creating a flow of hair to form a hairstyle (for example, arranging power, etc.). , The property of hardening the hair, the property of raising the hair, the property of holding the hairstyle for a long time, the property of imparting luster to the hair, and the property of improving the slip between the hairs to give a silky feeling.

The hair styling product composition is designed to exhibit one or more of the above hair styling characteristics according to the target hair styling style, the hair quality to which the hair is applied, and the like. In addition, there are various properties of the hair styling product composition such as liquid, cream, wax, foam (foam), gel and grease, and each hair styling composition has various properties. Has different usability, usability and hair styling properties. Further, hair styling product compositions having different properties have different composition designs.

Patent Document 1 below contains (A) 35 to 50% by mass of a (meth) acrylate-based monomer having a specific structure and 50 to 65% by mass of an ethylene oxide group-containing (meth) acrylate-based monomer having a specific structure. A gel-like hair cosmetic (hair conditioner composition) containing a polymer obtained by copolymerizing a monomer component and (B) a thickener is disclosed.

Japanese Unexamined Patent Publication No. 2016-011269

The gel-like hair styling agent composition as described in Patent Document 1 is generally excellent in hair styling power and arranging power (hair styling characteristics for making hair flow and making hairstyle).

On the other hand, as a hair styling product composition having excellent usability such as coatability, an aerosol foam hair styling product composition used by discharging a hair styling product composition in a foam form (foam shape) from an aerosol container is known. The aerosol foam hair styling product is generally used by shaking the container immediately before use to mix the aerosol foam hair styling product composition and the propellant. Therefore, the viscosity of the aerosol foam hair styling product composition is set low. Therefore, it is difficult to enhance the arranging power with the conventional aerosol foam hair styling composition.

An object of the present invention is to provide a hair styling composition having excellent hair styling power, arranging power and usability.

The present invention is a hair styling composition used by being discharged from a container, wherein the following component (A), the following component (B), the following component (C), the following component (D), and the following component (E) are added. It is a state of an emulsified composition containing the gel-like composition containing the following component (X) and the component X as a dispersoid in the gel-like composition as a dispersion medium, and is in a state of being discharged from the container. Alternatively, a hair styling composition that can be transformed into a foam after ejection is provided.

Component (A): Polyoxyethylene oleyl ether Component (B): Polyoxyethylene alkyl ether having an HLB value of 10.0 or more Component (C): Film-forming polymer Component (D): Thickener Component (E): Water component (X): Liquefied gas

In the hair styling composition of the present invention, it is preferable that the gel-like composition further contains the following component (F) and the following component (G).

Component (F): Sorbitan fatty acid ester having an HLB value of less than 10.0 Component (G): Polyoxyethylene sorbitan fatty acid ester having an HLB value of 10.0 or more

In the hair styling composition of the present invention, the component (C) preferably contains the following component (C1).

Ingredient (C1): Acrylic resin A film-forming polymer selected from the group consisting of alkanolamine, polyvinylpyrrolidone, and N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer.

In the hair styling composition of the present invention, it is preferable that the component (D) contains the following component (D1) and the following component (D2).

Ingredient (D1): Clay mineral Ingredient (D2): Polysaccharide thickener

The present invention provides a hair styling agent comprising a container, the above-mentioned hair styling agent composition, and a propellant, and the container is filled with the hair styling agent composition and the propellant.

In the hair styling agent of the present invention, it is preferable that the hair styling agent composition and the propellant are not in contact with each other in the container.

The hair styling composition of the present invention contains a gel-like composition containing specific components (A) to (E) and a specific component (X), and is a dispersoid in the gel-like composition as a dispersion medium. Since it is in the state of an emulsified composition in which the component (X) is present as, it can be changed into a foam shape at the time of discharge from the container or after discharge. In the hair styling composition of the present invention, it is possible to achieve both the characteristics of the gel-like hair styling composition having excellent hair-raising power and arranging power and the characteristics of the foam-like hair styling composition having excellent usability. .. That is, the hair styling composition of the present invention is excellent in all of the hair styling power, the arranging power, and the usability to raise the hair.

Hereinafter, the present invention will be described in detail.

The hair styling product composition of the present invention is discharged from a container and used. The hair styling composition of the present invention can be discharged from a container. The hair styling composition of the present invention is a gel-like composition containing polyoxyethylene oleyl ether, polyoxyethylene alkyl ether having an HLB value of 10.0 or more, a film-forming polymer, a thickener, and water, and a liquefied gas. And include.

In the present specification, the above-mentioned "polyoxyethylene oleyl ether" may be referred to as "component (A)".

In the present specification, the above-mentioned "polyoxyethylene alkyl ether having an HLB value of 10.0 or more" may be referred to as "component (B)".

In the present specification, the above-mentioned "film-forming polymer" may be referred to as "component (C)".

In the present specification, the above-mentioned "thickener" may be referred to as "component (D)".

In the present specification, the above-mentioned "water" may be referred to as "component (E)".

In the present specification, the above "liquefied gas" may be referred to as "component (X)".

The hair styling composition of the present invention contains a gel-like composition containing the component (A), the component (B), the component (C), the component (D), and the component (E). The hair styling product composition of the present invention contains the above gel-like composition and the component (X). The hair styling composition of the present invention is an emulsified composition in which the component (X) is dispersed as a dispersoid in the gel-like composition as a dispersion medium. The properties of the hair styling product composition of the present invention, which is in the state of the emulsified composition, can be changed into a foam shape at the time of discharge from the container or after discharge.

Since the hair styling composition of the present invention has the above-mentioned constitution, it is excellent in hair styling power, arranging power and usability to raise hair.

The hair styling composition of the present invention is excellent in both hair styling ability to raise hair and arranging ability. The arranging power means a hair styling characteristic that creates a flow of hair and creates a hairstyle. Further, the hair styling composition of the present invention can be satisfactorily discharged from a container, foams satisfactorily at the time of discharge or after discharge, suppresses stickiness at the time of application, enhances the application feeling, and is excellent in usability. ..

In the hair conditioner composition of the present invention, the gel-like composition further contains a sorbitan fatty acid ester having an HLB value of less than 10.0 and a polyoxyethylene sorbitan fatty acid ester having an HLB value of 10.0 or more. You may.

In the present specification, the above-mentioned "sorbitan fatty acid ester having an HLB value of less than 10.0" may be referred to as "component (F)".

In the present specification, the above-mentioned "polyoxyethylene sorbitan fatty acid ester having an HLB value of 10.0 or more" may be referred to as "component (G)".

The HLB values of the components (B), (F), and (G) can be obtained by, for example, an actual measurement method.

As described above, the hair styling composition of the present invention contains at least the component (A), the component (B), the component (C), the component (D), the component (E), and the component (X). The hair styling product composition of the present invention may further contain a component (F) and a component (G).

The hair styling composition of the present invention contains components other than the components (A), (B), (C), (D), (E), (F), (G), and (X). May be good. The gel-like composition may contain components other than the components (A), (B), (C), (D), (E), (F), and (G).

The above components, for example, component (A), component (B), component (C), component (D), component (E), component (F), component (G), component (X) and other components , Only one type may be used, or two or more types may be used.

Hereinafter, details of each component used in the hair styling composition of the present invention will be described.

(Component (A))
The component (A) is polyoxyethylene oleyl ether. By using the component (A), the gel-like composition and the component (X) can be satisfactorily emulsified, and usability can be improved. When the component (A) is not used, the emulsification of the component (X) becomes insufficient, and after a certain period of time, the gel-like composition and the component (X) are separated and do not sufficiently foam. Further, by using the component (A), a gel-like composition having a good thickening can be obtained, so that the arranging power can be enhanced. As the component (A), only one kind may be used, or two or more kinds may be used in combination.

From the viewpoint of further enhancing the arranging power and usability, the average number of moles of the polyoxyethylene group of the component (A) (that is, the average number of moles of oxyethylene added) is preferably 5.0 or more, more preferably 10. It is 0.0 or more, preferably 60.0 or less, and more preferably 50.0 or less.

The content of the component (A) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 1.0% by mass or more. It is more preferably 2.0% by mass or more, preferably 10.0% by mass or less, and more preferably 8.0% by mass or less. When the content of the component (A) is at least the above lower limit, the emulsification stability of the component (X) in the gel-like composition is further improved, and the foamability (particularly the foamability after aging) is improved. Can be done. When the content of the component (A) is not more than the above upper limit, the stickiness can be further suppressed and the feeling of use can be further enhanced. The content of the component (A) is the total amount of the contents of all the components (A) in the gel-like composition.

(Component (B))
The component (B) is a polyoxyethylene alkyl ether having an HLB value of 10.0 or more. By using the component (B) in addition to the component (X), the foamability of the hair styling product composition is improved, and the properties can be changed into a foam shape at the time of discharge from the container or after discharge. The sustainability of the foam can be increased. When the component (B) is not used, the component (X) is removed from the hair styling product composition without sufficient foaming at the time of discharge from the container or after the discharge. As the component (B), only one kind may be used, or two or more kinds may be used in combination.

The HLB value of the component (B) is 10.0 or more. If the HLB value of the component (B) is less than 10.0, the properties may not be changed to a foam shape at the time of discharge from the container or after discharge, or the durability of the foam may be lowered.

From the viewpoint of further enhancing usability, the HLB value of the component (B) is preferably 12.0 or more, more preferably 13.0 or more, preferably 20.0 or less, and more preferably 18.0 or less.

Examples of the component (B) include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene myristel ether, polyoxyethylene octyldodecyl ether, polyoxyethylene behenyl ether and the like.

From the viewpoint of further improving usability, the average number of moles of polyoxyethylene group added to the component (B) (that is, the average number of moles of oxyethylene added) is preferably 4.0 or more, more preferably 6.0 or more. , Preferably 60.0 or less, more preferably 50.0 or less.

The content of the component (B) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 1.0% by mass or more. It is more preferably 1.5% by mass or more, preferably 10.0% by mass or less, and more preferably 8.0% by mass or less. When the content of the component (B) is at least the above lower limit, the foamability of the hair styling product composition can be further improved. When the content of the component (B) is not more than the above upper limit, the stickiness can be further suppressed and the feeling of use can be further enhanced. The content of the component (B) is the total amount of the contents of all the components (B) in the gel-like composition.

(Component (C))
The component (C) is a film-forming polymer. By using the component (C), the hair styling ability to raise the hair can be enhanced. As the component (C), only one kind may be used, or two or more kinds may be used in combination.

Examples of the component (C) include an anionic film-forming polymer, a cationic film-forming polymer, an amphoteric film-forming polymer, and a nonionic film-forming polymer.

Examples of the anionic film-forming polymer include (meth) alkyl acrylate copolymers, (meth) acrylic acid / (meth) alkyl acrylate copolymers, acrylic resin alkanolamines, methyl vinyl ether / maleic acid ester copolymers, and the like. Vinyl acetate / crotonic acid copolymer, vinyl acetate / crotonic acid / vinyl neodecanoate copolymer, vinyl acetate / crotonic acid / vinyl propionate copolymer, vinyl acetate / maleic acid monobutyl ester / isoborolyl acrylate copolymer Combined, acrylate / alkyl acrylate / alkylacrylamide copolymer, polyvinylpyrrolidone / acrylate / (meth) acrylate copolymer, (styrene / alkyl acrylate) copolymer, (styrene / acrylate amide) common weight Examples thereof include coalescence, urethane-acrylic copolymer, and sodium polystyrene sulfonate. In addition, "(meth) acrylic" means both "acrylic" and "methacryl".

Examples of the cationic film-forming polymer include vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose chloride, and vinyl imidazole. Rium trichloride / vinylpyrrolidone copolymer, hydroxyethylcellulose / dimethyldialylammonium chloride, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, methylvinylimidazolium chloride / vinylpyrrolidone copolymer, and (vinylpyrrolidone / dimethylamino) A propylmethacrylate / lauryldimethylaminopropylmethacrylate) copolymer and the like can be mentioned.

Examples of the amphoteric film-forming polymer include N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / alkyl methacrylate ester copolymer, and N, N dimethyl-N- (2-methacryloyloxyethyl). Monochloroacetic acid amphoteric products of amine = N-oxide / alkyl methacrylate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer, dialkylaminoethyl methacrylate / alkyl methacrylate copolymer , And (isobutylene / diethylaminopropyl maleimide / maleic acid) copolymers and the like.

Examples of the nonionic film-forming polymer include polyvinyl alcohol, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinylmethyl ether / ethyl maleate copolymer, polyvinylcaprolactam and the like.

From the viewpoint of further enhancing the hair conditioning and arranging power to raise the hair, the component (C) contains acrylic resin alkanolamine, polyvinylpyrrolidone, and N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxy. It is preferable to contain a film-forming polymer (at least one film-forming polymer) selected from the group consisting of betaine / methacrylic acid alkyl ester copolymers.

In the present specification, a film selected from the group consisting of "acrylic resin alkanolamine, polyvinylpyrrolidone, and N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer". The "forming polymer" may be referred to as "component (C1)".

Therefore, the component (C) preferably contains the component (C1).

From the viewpoint of further enhancing the hair styling ability and the arranging ability to raise the hair, the component (C) is preferably the component (C1).

The content of the component (C) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.1% by mass or more. It is more preferably 0.5% by mass or more, preferably 7.0% by mass or less, and more preferably 6.0% by mass or less. When the content of the component (C) is at least the above lower limit, the hair styling ability to raise the hair can be further enhanced. When the content of the component (C) is not more than the above upper limit, the stickiness can be further suppressed and the feeling of use can be further enhanced. The content of the component (C) is the total amount of the contents of all the components (C) in the gel-like composition.

The content of the component (C1) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.1% by mass or more. It is more preferably 0.5% by mass or more, preferably 7.0% by mass or less, and more preferably 6.0% by mass or less. When the content of the component (C1) is at least the above lower limit, the hair styling ability to raise the hair can be further enhanced. When the content of the component (C1) is not more than the above upper limit, the stickiness can be further suppressed and the feeling of use can be further enhanced. The content of the component (C1) is the total amount of the contents of all the components (C1) in the gel-like composition.

(Component (D))
Ingredient (D) is a thickener. By using the component (D), a gel-like composition having a good thickening can be obtained, so that the arranging power can be enhanced. As the component (D), only one kind may be used, or two or more kinds may be used in combination.

Examples of the component (D) include clay minerals, polysaccharide thickeners, acrylic thickeners and the like.

In the present specification, "clay mineral" may be referred to as "component (D1)".

In the present specification, the "polysaccharide-based thickener" may be referred to as "ingredient (D2)".

In the present specification, the "acrylic thickener" may be referred to as "ingredient (D3)".

From the viewpoint of further exerting the thickening effect and further enhancing the arranging power, the component (D) may contain the component (D1) and the component (D2), or may contain the component (D3). preferable. From the viewpoint of further exerting the thickening effect and further enhancing the arranging power, the component (D) more preferably contains the component (D1) and the component (D2).

As the component (D1), the component (D2), and the component (D3), only one type may be used, or two or more types may be used in combination.

The component (D1) may be a natural product or a synthetic product. Ingredients (D1) include kaolin clay minerals, antigolite clay minerals, pyrophyllite clay minerals, mica clay minerals, smectite clay minerals, vermiculite clay minerals, green mudstone clay minerals and organically modified clays. Examples include minerals.

Examples of the kaolin group clay minerals include kaolin, nacrite, dikite and halosite. Examples of the antigolite group clay minerals include antigolite, amesite, and cronsteadite. Examples of the pyrophyllite group clay mineral include pyrophyllite and talc (talc). Examples of the mica family clay minerals include illite, glauconite, ceradonite, sericite, mica (mica), muscovite, chrome muscovite and biotite. Examples of the smectite group clay minerals include bentonite, montmorillonite, biderite, nontonite, saponite, hectorite and lucentite. Examples of the vermiculite group clay mineral include vermiculite and the like. Examples of the chlorite group clay mineral include chlorite. Examples of the organically modified clay mineral include organically modified clay minerals obtained by organically modifying smectite group clay minerals or vermiculite group clay minerals. A quaternary ammonium salt-type cationic surfactant is preferably used for the organic modification treatment. Examples of the quaternary ammonium salt-type cationic surfactant include the above-mentioned alkyltrimethylammonium chloride, dialkyldimethylammonium chloride and benzalkonium chloride.

From the viewpoint of further improving the storage stability and usability of the hair styling product composition, the component (D1) is a clay mineral (at least one clay mineral) selected from the group consisting of synthetic silicates and derivatives thereof. Is preferable. The synthetic silicate and its derivatives are not silicate minerals whose main components are naturally occurring magnesium silicate and silicate (sodium / magnesium), which contain not a few impurities, but silicates obtained by synthesis. Refers to salts and silicate derivatives.

Examples of the synthetic silicate and its derivative include synthetic silicic acid (sodium / magnesium) represented by INCI name (International Nomenclature for Cosmetic Industries): SODIUM MAGNESIUM SILICATE, and INCI name: MAGNESIUM FLUOR. Magnesium acid, INCI name: SODIUM MAGNESIUM FLOUOROSILICATE, fluorosilicate (sodium / magnesium), INCI name: MAGNESIUM POTASSIUM FLOUROSILICATE, fluorosilicate (magnesium / potassium), INCI name: MAGNESI Fluorosilicate (magnesium / sodium), synthetic aluminum silicate represented by INCI name: ALUMINUM SILICATE and the like.

The component (D1) is particularly preferably a clay mineral (at least one clay mineral) selected from the group consisting of synthetic silicate (sodium / magnesium) and fluorosilicate (sodium / magnesium).

Examples of the component (D2) include methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, hydroxypropyl methyl cellulose, xanthan gum, guagam, carrageenan, pectin and locust bean gum.

From the viewpoint of further exerting the thickening effect and further enhancing the arranging power, the component (D2) is derived from methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, hydroxypropyl methyl cellulose, and xanthan gum. It is preferable that the polysaccharide thickener (at least one polysaccharide thickener) selected from the above group.

Ingredients (D3) include carboxyvinyl polymer, acrylate / alkyl methacrylate copolymer, alkyl acrylate / alkyl methacrylate / polyoxyethylene stearyl ether copolymer, and (Acrylates / steareth methacrylate-20) copolymer. , (Acrylates / Methacrylic Acid Steareth-20) Crosspolymers, (Acrylates / Behenez Methacrylate-25) Copolymers, (Acrylates / Vinyl Neodecanoate) Crosspolymers and the like.

From the viewpoint of further exerting the thickening effect and further enhancing the arranging power, the component (D3) is a group consisting of a carboxyvinyl polymer and an acrylic acid / alkyl methacrylate copolymer (alkyl-modified carboxyvinyl polymer). It is preferable that the acrylic thickener (at least one acrylic thickener) is more selected.

The content of the component (D) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.1% by mass or more. It is more preferably 0.3% by mass or more, preferably 10.0% by mass or less, and more preferably 8.0% by mass or less. When the content of the component (D) is at least the above lower limit, the thickening effect can be further exerted, and the arranging power can be further enhanced. When the content of the component (D) is not more than the above upper limit, the stickiness can be further suppressed and the feeling of use can be further enhanced. The content of the component (D) is the total amount of the contents of all the components (D) in the gel-like composition.

The content of the component (D1) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.5% by mass or more. It is more preferably 1.0% by mass or more, preferably 9.9% by mass or less, and more preferably 8.0% by mass or less. The content of the component (D1) is the total amount of the contents of all the components (D1) in the gel-like composition.

The content of the component (D2) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.01% by mass or more. It is more preferably 0.03% by mass or more, preferably 2.0% by mass or less, and more preferably 1.0% by mass or less. The content of the component (D2) is the total amount of the contents of all the components (D2) in the gel-like composition.

The total content of the component (D1) and the component (D2) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling product composition of the present invention) is preferable. Is 0.1% by mass or more, more preferably 0.51% by mass or more, preferably 10.0% by mass or less, and more preferably 8.0% by mass or less. When the total content of the component (D1) and the component (D2) is at least the above lower limit, the thickening effect can be further exerted, and the arranging power can be further enhanced. When the total content of the component (D1) and the component (D2) is not more than the above upper limit, the stickiness can be further suppressed and the feeling of use can be further enhanced.

The mass ratio of the content of the component (D1) to the content of the component (D2) (content of component (D1) / content of component (D2)) is preferably 5.0 or more, more preferably 10.0. As mentioned above, it is preferably 120.0 or less, more preferably 100.0 or less. When the mass ratio (content of component (D1) / content of component (D2)) is equal to or higher than the lower limit and lower than the upper limit, the thickening effect can be further exerted and the arranging power can be further enhanced. Can be enhanced.

The content of the component (D3) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.1% by mass or more. It is more preferably 0.2% by mass or more, preferably 3.0% by mass or less, and more preferably 1.5% by mass or less. When the content of the component (D3) is at least the above lower limit and at least the above upper limit, the thickening effect can be further exerted, and the arranging power can be further enhanced. The content of the component (D3) is the total amount of the contents of all the components (D3) in the gel-like composition.

(Component (E))
The component (E) is water. The component (E) is preferably purified water.

The content of the component (E) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 45.0% by mass or more. It is more preferably 50.0% by mass or more, preferably 95.8% by mass or less, and more preferably 90.0% by mass or less. When the content of the component (E) is at least the above lower limit and at least the above upper limit, a gel-like composition can be obtained satisfactorily.

(Component (F))
The component (F) is a sorbitan fatty acid ester having an HLB value of less than 10.0. The gel-like composition preferably contains the component (F). By using the component (F), the emulsification stability of the component (X) into the gel-like composition can be further improved, and the foamability (particularly, the foamability after aging) can be further improved. As the component (F), only one kind may be used, or two or more kinds may be used in combination.

The HLB value of component (F) is less than 10.0. From the viewpoint of further enhancing the emulsification stability of the component (X) into the gel-like composition, the HLB value of the component (F) is preferably 4.0 or more, more preferably 4.5 or more, preferably 9.5 or more. Hereinafter, it is more preferably 9.0 or less.

Ingredients (F) include sorbitan monocaprate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan distearate, sorbitan sesquistearate, sorbitan tristearate, sorbitan monoisostearate, sorbitan sesquiisostearate, Examples thereof include sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, and sorbitan coconut oil fatty acid.

From the viewpoint of further enhancing usability, the component (F) is a sorbitan fatty acid ester (at least one sorbitan fatty acid ester) selected from the group consisting of sorbitan monolaurate, sorbitan monopalmitate, and sorbitan coconut oil fatty acid. Is preferable.

The content of the component (F) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.1% by mass or more. It is more preferably 0.2% by mass or more, preferably 8.0% by mass or less, and more preferably 5.0% by mass or less. When the content of the component (F) is at least the above lower limit and at least the above upper limit, the emulsification stability of the component (X) in the gel-like composition can be further enhanced. The content of the component (F) is the total amount of the contents of all the components (F) in the gel-like composition.

(Component (G))
The component (G) is a polyoxyethylene sorbitan fatty acid ester having an HLB value of 10.0 or more. The gel-like composition preferably contains the component (G). By using the component (G), the emulsification stability of the component (X) into the gel-like composition can be further improved, and the foamability (particularly, the foamability after aging) can be further improved. In particular, by using both the component (F) and the component (G), the emulsion stability can be further enhanced. As the component (G), only one kind may be used, or two or more kinds may be used in combination.

The HLB value of the component (G) is 10.0 or more. From the viewpoint of further enhancing the emulsification stability of the component (X) in the gel-like composition, the HLB value of the component (G) is preferably 11.0 or more, more preferably 12.0 or more, preferably 18.0. Hereinafter, it is more preferably 17.0 or less.

Ingredients (G) include polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, polyoxyethylene sorbitan monolaurate, and monopalmitic acid. Examples thereof include polyoxyethylene sorbitan.

From the viewpoint of further enhancing usability, the component (G) is a group consisting of polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monolaurate, and polyoxyethylene sorbitan monopalmitate. More preferably, it is a polyoxyethylene sorbitan fatty acid ester (at least one polyoxyethylene sorbitan fatty acid ester).

From the viewpoint of further enhancing the emulsion stability of the component (X) in the gel-like composition, the average number of moles of polyoxyethylene groups added to the component (G) (that is, the average number of moles of oxyethylene added) is preferably set. It is 10.0 or more, more preferably 15.0 or more, preferably 50.0 or less, and more preferably 40.0 or less.

The content of the component (G) in 100% by mass of the gel-like composition (in 100% by mass of the component excluding the component (X) in the hair styling composition of the present invention) is preferably 0.1% by mass or more. It is more preferably 0.2% by mass or more, preferably 8.0% by mass or less, and more preferably 5.0% by mass or less. When the content of the component (G) is at least the above lower limit and at least the above upper limit, the emulsification stability of the component (X) in the gel-like composition can be further enhanced. The content of the component (G) is the total amount of the contents of all the components (G) in the gel-like composition.

From the viewpoint of further enhancing the emulsion stability of the component (X) in the gel-like composition, the total of the content of the component (F) and the content of the component (G) is preferably 0.2% by mass or more. , More preferably 0.4% by mass or more, preferably 16.0% by mass or less, and more preferably 10.0% by mass or less.

From the viewpoint of further enhancing the emulsification stability of the component (X) in the gel-like composition, the content of the component (F) is relative to the total of the content of the component (F) and the content of the component (G). The mass ratio (content of component (F) / (total of content of component (F) and content of component (G))) is preferably 0.2 or more, more preferably 0.3 or more, preferably 0.3 or more. Is 0.8 or less, more preferably 0.7 or less.

(Other ingredients)
The gel-like composition may contain components other than the components (A) to (G) described above. Ingredients other than the components (A) to (G) include, for example, surfactants such as nonionic surfactants, cationic surfactants, anionic surfactants, and amphoteric surfactants; waxes, hydrocarbon oils, higher alcohols, etc. , Ester oils, silicone oils, fats and oils, polyhydric alcohols, lower alcohols, preservatives, metal ion sequestering agents, antioxidants, plant extracts, dyes, pigments, pH adjusters, fragrances and the like.

Examples of the nonionic surfactant include polyglycerin fatty acid ester, polyoxyethylene cured castor oil and the like.

Examples of the polyglycerin fatty acid ester include polyglyceryl laurate, polyglyceryl myristate, polyglyceryl isostearate, and polyglyceryl diacetic acid.

Examples of the polyoxyethylene cured castor oil include polyoxyethylene cured castor oil in which the average number of moles of polyoxyethylene groups added is 30 to 80.

Examples of the amphoteric surfactant include N- [3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine hydrochloride (alkyl (C12, 14) oxyhydroxypropylarginine HCl) and the like. Be done.

Examples of the wax include carnauba wax, candelilla wax, beeswax, lanolin and the like.

Examples of the hydrocarbon oil include microcrystalline wax, paraffin wax, polyethylene wax, liquid paraffin, liquid isoparaffin, squalane, and petrolatum.

Examples of the higher alcohol include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, and oleyl alcohol.

Examples of the ester oil include isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, and cetyl 2-ethylhexanoate.

Examples of the silicone oil include methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, dimethiconol, methylhydrogenpolysiloxane, alcohol-modified silicone, alkyl-modified silicone, and amino-modified silicone.

Examples of the fats and oils include olive oil, rice bran oil, sunflower oil, coconut oil, camellia oil, macadamia nut oil, sunflower oil, grape seed oil, and avocado oil.

Examples of the polyhydric alcohol include glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, dipropylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, and 1, , 2-Ocanediol, 1,2-decanediol, polyoxypropylene methyl glucoside and the like.

Examples of the lower alcohol include ethanol and the like.

Examples of the preservative include methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, phenoxyethanol and the like.

(Component (X))
The component (X) is a liquefied gas. The hair styling composition of the present invention contains the component (X). After the component (X) is emulsified into the gel-like composition to obtain an emulsified composition, the component (X) is vaporized and the hair styling product composition foams by discharging the emulsified composition from the container. The properties can be changed into a foam. As the component (X), only one kind may be used, or two or more kinds may be used in combination.

Examples of the component (X) include isobutane and isopentane.

The content of the component (X) in 100% by mass of the hair styling composition of the present invention is preferably 1.0% by mass or more, more preferably 2.0% by mass or more, preferably 15.0% by mass or less. More preferably, it is 10.0% by mass or less. When the content of the component (X) is not less than the above lower limit and not more than the above upper limit, a foam having good fineness (foam density) is formed, and usability can be further improved. The content of the component (X) is the total amount of the contents of all the components (X) in the hair styling product composition of the present invention.

(Other details of hair styling composition)
The viscosity of the hair styling product composition of the present invention at 25 ° C. and the viscosity of the gel-like composition at 25 ° C. are preferably 800 mPa · s or more, more preferably 10,000 mPa · s or more, preferably 400,000 mPa · s or less, respectively. Is 100,000 mPa · s or less. When the viscosity is at least the above lower limit and at least the above upper limit, the discharge property and the foamability can be improved.

The above viscosity was determined by using a viscometer. 2 rotors, No. 3 rotor or No. It is measured using a 4-rotor under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute. As the viscometer, a TV-25 type viscometer manufactured by Toki Sangyo Co., Ltd. can be used.

The method for producing the hair styling product composition of the present invention is not particularly limited. The method for producing the hair styling composition is as follows: (1) Ingredient (A), Ingredient (B), Ingredient (C), Ingredient (D), Ingredient (E), if necessary. The step of mixing with other components to obtain a gel-like composition, and (2) mixing the obtained gel-like composition with the component (X) into the gel-like composition as a dispersion medium. It is preferable to include a step of allowing the component (X) to be present as a dispersoid to bring the hair styling product composition into an emulsified composition. A homo mixer, a discharge mixer, a paddle mixer and the like are used for the above mixing.

The hair styling product composition of the present invention is discharged from a container and used. The hair styling composition of the present invention is an emulsified composition in which the component (X) is dispersed as a dispersoid in a gel-like composition as a dispersion medium before being discharged from the container (in a state of being filled in the container). It is in a state. The hair styling composition, which is in the state of an emulsifying composition, is not a liquid but a gel.

In the hair styling composition of the present invention, the gel-like composition as a dispersion medium in the emulsified composition is not in liquid form but in gel form. Since the gel-like composition has fluidity, it serves as a dispersion medium in the same manner as the liquid composition.

The properties of the hair styling product composition of the present invention, which is in the state of an emulsified composition, foam by the action of the component (X) and the component (B) at the time of discharge from the container or after the discharge, and change into a foam shape. The properties of the hair styling product composition of the present invention may change into a foam shape at the time of discharge from the container, may change into a foam shape after discharge from the container, and may change into a foam shape at the time of discharge from the container and after discharge. It may change into a form.

When the properties of the hair styling product composition of the present invention change into a foam shape after ejection, the time from ejection to the start of the foam formation is preferably 1 minute or less, more preferably 30 seconds or less, still more preferably. Is 20 seconds or less, particularly preferably 10 seconds or less.

Examples of the container include a pressure-resistant container such as an aerosol container. The aerosol container may be an aerosol container having a structure in which the hair styling agent composition and the propellant are in contact with each other, or may be an aerosol container having a structure in which the hair styling product composition and the propellant are not in contact with each other.

The hair styling composition of the present invention is preferably an aerosol hair styling composition.

The hair styling product composition of the present invention is preferably used by being filled in the container together with the propellant. From the viewpoint of enhancing the stability of the hair styling product composition of the present invention, it is preferable that the hair styling product composition of the present invention is filled in the container so as not to come into contact with the propellant. The hair styling composition of the present invention is preferably used by being filled in the container so as to be separated from the propellant. The hair styling composition of the present invention is preferably used by being encapsulated in a bag container placed in the container (container body). It is preferable that the hair styling product composition of the present invention cannot be mixed with the propellant in the container (container body).

(Hair styling product)
The hair styling agent of the present invention includes a container, the hair styling agent composition described above, and a propellant, and the container is filled with the hair styling product composition and the propellant. The properties of the hair styling product composition, which is in the state of the emulsified composition, can be changed into a foam shape at the time of discharge from the container to the container or after discharge.

The container is preferably the aerosol container. The hair styling agent is preferably an aerosol hair styling product.

The aerosol hair styling agent includes an aerosol container, the above-mentioned hair styling composition, and a propellant. The aerosol container has a nozzle. In the aerosol hair styling agent, the aerosol hair styling agent composition and the propellant are filled in the aerosol container. The aerosol hair styling composition is a composition of the aerosol hair styling agent, excluding the propellant, among the fillers filled in the aerosol container.

From the viewpoint of enhancing the stability of the hair styling product composition, it is preferable that the hair styling product composition and the propellant are not in contact with each other in the container. From the viewpoint of enhancing the stability of the hair styling product composition, it is preferable that the hair styling product composition and the propellant are separated in the container. From the viewpoint of enhancing the stability of the hair styling product composition, the hair styling agent of the present invention includes a bag container placed in the container (container body), which is different from the container (container body), and the hair styling product is provided. It is preferable that the agent composition is contained in the bag container. It is preferable that the hair styling product composition cannot be mixed with the propellant in the container (container body).

Examples of the propellant include dimethyl ether (DME), isobutane, liquefied petroleum gas (LPG), nitrogen gas and the like. Only one type of the propellant may be used, or two or more types may be used in combination.

The aerosol hair styling product can be produced by a known method. As a method for producing the above-mentioned aerosol hair styling agent, each compounding component contained in the aerosol hair styling agent composition or the aerosol hair styling agent composition is filled in the aerosol container, the aerosol container is clinched by the aerosol valve, and then the propellant. Is filled from the stem, and an injection button suitable for the stem is attached.

In the aerosol hair styling agent, the content of the aerosol hair styling agent composition is preferably 40.0% by mass or more, more preferably 45.0, based on 100% by mass of the total of the aerosol hair styling agent composition and the propellant. It is mass% or more, preferably 60.0 mass% or less, and more preferably 55.0 mass% or less. When the content of the aerosol hair styling agent composition is not less than the above lower limit and not more than the above upper limit, the ejection property is further improved.

In the aerosol hair styling agent, the content of the propellant is preferably 40.0% by mass or more, more preferably 45.0% by mass or more, in a total of 100% by mass of the aerosol hair styling composition and the propellant. , Preferably 60.0% by mass or less, more preferably 55.0% by mass or less. When the content of the propellant is not less than the above lower limit and not more than the above upper limit, the ejection property is further improved.

Conventionally, there is a gel-like hair styling agent as a hair styling agent having excellent hair styling ability and arranging ability to raise hair. Further, there is an aerosol foam hair styling agent as a hair styling agent having excellent usability because it is hard to drip and has good applicability to hair because it is discharged in the form of foam.

However, since the aerosol foam hair styling agent is shaken immediately before use to mix the undiluted solution which is the hair styling agent composition and the propellant in the aerosol container, it is necessary to reduce the viscosity of the hair styling agent composition, and the hair styling product is required. Generally, the styling power of the time was low. When a gel-like hair styling composition is used as the stock solution of the aerosol foam hair styling agent, it is gel-like and has a high viscosity, and the propellant cannot be mixed by shaking immediately before use. It was necessary to use it in a stable emulsified state with the agent composition, which was highly difficult. Although shaving foam and the like are known as aerosol foams using the gel-like composition, the shaving foam is achieved by using a fatty acid soap-based surfactant, and is highly sticky and has a shaving foam composition. The compounding composition of the product could not be used as the compounding composition of the hair styling agent composition. Therefore, with the conventional hair styling agent composition, it is difficult to enhance all of the hair styling power, the arranging power, and the usability to raise the hair.

On the other hand, in the hair styling composition of the present invention, a liquefied gas is emulsified in the gel-like composition containing the film-forming polymer [component (C)] and the thickener [component (D)]. Polyoxyethylene oleyl ether [component (A)] having excellent foaming properties and polyoxyethylene alkyl ether [component (B)] having an HLB value of 10.0 or more, which is excellent in foamability and foam retention (foam persistence). )] Is blended. As a result, it is an emulsified composition in which the liquefied gas [component (X)] is stably emulsified, and a hair styling agent composition that exhibits good foaming property when used can be obtained, and the hair styling power and arranging power for raising hair can be obtained. It is possible to achieve both the characteristics of an excellent gel-like hair styling composition and the characteristics of a foam-like hair styling composition that is excellent in usability. Further, since the hair styling product composition of the present invention is in the state of a gel-like emulsified composition when it is filled in the container, the container is shaken immediately before use like the conventional aerosol foam hair styling product composition. The hair styling product composition can be satisfactorily discharged from the container without any trouble.

Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited to the following examples.

In Examples and Comparative Examples, the following components were used to prepare the hair styling product composition.

(Component (A))
Polyoxyethylene oleyl ether 1 (average number of moles of polyoxyalkylene group added 10) (manufactured by Nippon Surfant Industry Co., Ltd., trade name "NIKKOL BO-10V")
Polyoxyethylene oleyl ether 2 (average number of moles of polyoxyalkylene group added 20) (manufactured by Nippon Surfant Industry Co., Ltd., trade name "NIKKOL BO-20V")
Polyoxyethylene oleyl ether 3 (average number of moles of polyoxyalkylene group added 50) (manufactured by Nippon Surfant Industry Co., Ltd., trade name "NIKKOL BO-50V")

(Component (B))
Polyoxyethylene lauryl ether (HLB value 14.5, average number of moles of polyoxyethylene group added 9, manufactured by Nippon Surfartant Industry Co., Ltd., trade name "NIKKOL BL-9")
Polyoxyethylene cetyl ether (HLB value 17.0, average number of moles of polyoxyethylene group added 20, manufactured by Nippon Surfartant Industries, Ltd., trade name "NIKKOL BC-20")

(Component (C))
Acrylic resin alkanolamine ("Plus size L-6330" manufactured by Reciprocal Chemical Industry Co., Ltd.): Anionic film-forming polymer Polyvinylpyrrolidone (Manufactured by AISP, trade name "PVP K-90"): Nonionic film-forming polymer N-methacrylic Oxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer (manufactured by Mitsubishi Chemical Corporation, trade name "Yukaformer 301"): Amphoteric film-forming polymer

(Component (D))
Fluorosilicate (sodium / magnesium) (manufactured by Rockwood Adaptives Limited, trade name "Laponite XL21"): Ingredient (D1)
Hydroxyethyl cellulose (manufactured by Daicel Chemical Industries, Ltd., trade name "HEC Daicel SE900"): Ingredient (D2)
Xanthan gum (manufactured by DSP Gokyo Food & Chemical Co., Ltd., trade name "Echo Gum T"): Ingredient (D2)
Acrylic acid / alkyl methacrylate copolymer (manufactured by Rohm and Haas, trade name "Accurin TM 22"): Ingredient (D3)
Carboxyvinyl polymer (manufactured by LUBRIZOL, trade name "CARBOPOL 980 POLYMER"): Ingredient (D3)
Alkylate Acrylate / Alkyl Methacrylate / Polyoxyethylene Stearyl Ether Copolymer Methacrylate (Average number of moles of polyoxyalkylene group added 20): Component (D3)

(Component (E))
purified water

(Component (F))
Coconut oil fatty acid sorbitan (HLB value 8.5, manufactured by Nippon Surfant Industry Co., Ltd., trade name "NIKKOL SL-10")
Sorbitan monolaurate (HLB value 8.6, manufactured by Kao Corporation, trade name "Leodor Super SP-L10")
Sorbitan monopalmitate (HLB value 6.7, manufactured by Kao Corporation, trade name "Leodor SP-P10")

(Component (G))
Polyoxyethylene sorbitan monostearate (HLB value 14.9, average number of moles of polyoxyethylene group added 20, manufactured by Kao Corporation, trade name "Leodor TW-S120V")
Polyoxyethylene sorbitan monooleate (HLB value 15.0, average number of moles of polyoxyethylene group added 20, manufactured by Kao Corporation, trade name "Leodor TW-O120V")
Polyoxyethylene sorbitan monolaurate (HLB value 16.7, average number of moles of polyoxyethylene group added 20, manufactured by Kao Corporation, trade name "Leodor TW-L120")

(Other)
TEA (manufactured by Japan Chemtech, trade name "TEA-99", triethanolamine)
2-Ethylhexyl palmitate (manufactured by Koyo Fine Chemicals, trade name "Koyo POC")

(Component (X))
Liquefied gas containing 90% by mass of isopentane and 10% by mass of isobutane

(Examples 1 to 39 and Comparative examples 1 to 5)
The compounding ingredients shown in Tables 1 to 6 below were blended to prepare a gel-like composition. The obtained gel-like composition was filled in an aerosol test bottle (pressure resistant glass container, manufactured by Tokyo Polymer Co., Ltd.). Next, after crimping the aerosol valve into the aerosol test bottle, the component (X) is filled from the stem with the blending amounts shown in Tables 1 to 6 below, and shaken to obtain the gel-like composition and the component (X). And were emulsified to prepare a hair styling composition.

Next, a compressed gas (nitrogen gas) is filled from the stem, a button suitable for the stem is attached, and an aerosol hair styling agent (an aerosol hair styling agent in which a hair styling composition and a compressed gas as a propellant are filled in an aerosol container). ) Was prepared. After the obtained hair styling product was left to stand for 24 hours, the following evaluation was performed.

The blending amount in the table (blending amount in 100% by mass of the gel-like composition and blending amount in 100% by mass of the hair styling agent composition) is shown by the blending amount of pure content (unit: mass%).

(Evaluation)
Three expert panels made the following evaluations.

(Test Example 1: Usability (foaming))
In the obtained hair styling product, 1.5 g of the hair styling product composition was discharged from the container. The properties of the hair styling product composition 1 minute after discharge were visually confirmed. The hair styling product compositions obtained in Examples 1 to 39 could be satisfactorily discharged from the container.

<Evaluation criteria for usability (foaming)>
○ (Good): Foams during or after discharge, and the properties change to foam × (Defective): Does not foam

(Test Example 2: Usability (property at the time of application))
In the obtained hair styling product, 1.5 g of the hair styling product composition was discharged in a palm shape from the container. After that, the hair styling composition discharged onto the palm is evenly applied to the hair on one half of the wig (lesson mannequin: manufactured by Eucalyptus Japan), and the hair is patted from front to back so as to follow the shape of the wig. Hair styling was applied. The properties at the time of application at this time were evaluated. The hair styling product compositions obtained in Examples 1 to 39 can be applied evenly on the hair of the wig without causing stickiness, and the application feeling is good. The hair styling product compositions obtained in ~ 34 had a better coating feeling than the hair styling product compositions obtained in Examples 35 to 39.

<Evaluation criteria for usability (property at the time of application)>
○ (Good): The viscosity is relatively high and the hair styling product composition does not spill from the palm during application, and it is easy to apply to the hair. × (Poor): The viscosity is low and the hair styling product composition spills from the palm during application. Difficult to apply to hair

(Test Example 3: Hair styling ability to raise hair)
In the obtained hair styling product, 1.5 g of the hair styling product composition was discharged onto the palm from the container. After that, the hair styling composition discharged onto the palm was applied to one half of the hair of a short hair wig (lesson mannequin: manufactured by Eucalyptus Japan), and the hair was raised upward from the root of the hair to perform hair styling. .. Immediately after hair styling, the angle at which the hair rises near the crown was observed, and the hair styling ability to raise the hair was evaluated according to the following criteria. The above angles are 0 ° in the horizontal direction and 90 ° in the vertical direction.

<Evaluation criteria for hair styling ability to raise hair>
○ (Good): Hair rises (at an angle of 45 ° or more)
× (bad): Hair does not rise (angle is less than 45 °)

(Test Example 4: Arrangement power)
Immediately after hair styling according to Test Example 2, the hairstyle (temporal) of the wig that had been styling was observed, and the hair styling power (arranging power) was determined according to the following criteria.

<Evaluation criteria for arranging ability>
○ (Good): Hair flow is firmly formed △ (Available): Hair is slightly falling downward and hair flow formation is slightly weak, but it is a practically acceptable arranging force. × (bad): Hair has fallen downward and the flow of hair cannot be maintained.

The composition and results are shown in Tables 1-6 below.

(Example 40)
A valve with an inner bag (the inner bag is made of resin-coated aluminum) was clinched in an aerosol container (aluminum can), and nitrogen gas as a propellant was filled in the container (outside the inner bag). Further, the gel-like composition and the component (X) were mixed and emulsified to prepare a hair styling product composition having the same compounding composition as in Example 2. From the stem of the aerosol container, the prepared hair styling composition was filled in the inner bag. Finally, a button suitable for the stem is attached, and a hair styling agent (an aerosol hair styling agent in which the inner bag is filled with a hair styling composition (emulsifying composition) and the inner bag is filled with a propellant) Was produced. After the obtained hair styling product was left to stand for 24 hours, the above-mentioned Test Examples 1 to 4 were evaluated.

As a result of the evaluation, the hair styling agent obtained in Example 40 can satisfactorily discharge the hair styling composition from the container, and also has usability (foaming property), usability (property at the time of application), and hair. Both the hair styling ability and the arranging ability were good (○).

An example of prescribing the hair styling product composition of the present invention is shown below.

(Prescription example 1)
<Gel-like composition>
Polyoxyethylene oleyl ether (20EO) 5.0% by mass
Polyoxyethylene lauryl ether (10EO) 4.0% by mass
Coconut oil fatty acid sorbitan 1.0% by mass
Polyoxyethylene sorbitan monostearate (20EO) 1.0% by mass
Acrylic resin Alkanolamine 1.5% by mass
Fluorosilicate (sodium / magnesium) 2.8% by mass
Hydroxyethyl cellulose 0.05% by mass
2-Ethylhexyl palmitate 3.0% by mass
Fragrance 0.1% by mass
Blue No. 1 0.0001 mass%
Remaining water
Total 100.0% by mass

<Liquefied gas>
Isopentane 90.0% by mass
Isobutane 10.0% by mass
Total 100.0% by mass

<Hair styling composition (emulsification composition)>
95% by mass of gel-like composition and 5% by mass of liquefied gas are mixed and emulsified.

(Prescription example 2)
<Gel-like composition>
Polyoxyethylene oleyl ether (10EO) 6.0% by mass
Polyoxyethylene cetyl ether (20EO) 3.0% by mass
Sorbitan monolaurate 1.0% by mass
Polyoxyethylene sorbitan monooleate (20EO) 1.0% by mass
Polyvinylpyrrolidone 1.0% by mass
N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer 0.5% by mass
Fluorosilicate (sodium / magnesium) 3.0% by mass
Xanthan gum 0.05% by mass
Isononyl isononanoate 2.0% by mass
Fragrance 0.1% by mass
Red 227 0.0002% by mass
Remaining water
Total 100.0% by mass

<Liquefied gas>
Isopentane 90.0% by mass
Isobutane 10.0% by mass
Total 100.0% by mass

<Hair styling composition (emulsification composition)>
95% by mass of gel-like composition and 5% by mass of liquefied gas are mixed and emulsified.

Claims (6)

A hair styling composition that is discharged from a container and used.
A gel-like composition containing the following component A, the following component B, the following component C, the following component D, and the following component E,
Including the following component X
It is a state of an emulsified composition in which the component X is present as a dispersoid in the gel-like composition as a dispersion medium.
A hair styling composition that can be transformed into a foam during or after discharge from the container.
Component A: Polyoxyethylene oleyl ether Component B: Polyoxyethylene alkyl ether having an HLB value of 10.0 or more Component C: Film-forming polymer Component D: Thickener Component E: Water Component X: Liquefied gas The hair styling composition according to claim 1, wherein the gel-like composition further contains the following component F and the following component G.
Component F: Sorbitan fatty acid ester having an HLB value of less than 10.0 Component G: Polyoxyethylene sorbitan fatty acid ester having an HLB value of 10.0 or more The hair styling composition according to claim 1 or 2, wherein the component C contains the following component C1.
Component C1: Acrylic resin A film-forming polymer selected from the group consisting of alkanolamine, polyvinylpyrrolidone, and N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer. The hair styling composition according to any one of claims 1 to 3, wherein the component D contains the following component D1 and the following component D2.
Ingredient D1: Clay mineral Ingredient D2: Polysaccharide thickener With the container
The hair styling product composition according to any one of claims 1 to 4.
Equipped with a propellant,
A hair styling product in which the hair styling product composition and the propellant are filled in the container. The hair styling product according to claim 5, wherein the hair styling product composition and the propellant are not in contact with each other in the container.