JP2020156669A - Nonwoven fabric for absorbent article - Google Patents

Nonwoven fabric for absorbent article Download PDF

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JP2020156669A
JP2020156669A JP2019058058A JP2019058058A JP2020156669A JP 2020156669 A JP2020156669 A JP 2020156669A JP 2019058058 A JP2019058058 A JP 2019058058A JP 2019058058 A JP2019058058 A JP 2019058058A JP 2020156669 A JP2020156669 A JP 2020156669A
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absorbent article
absorber
woven fabric
liquid
absorbent
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正和 佐瀬
Masakazu Sase
正和 佐瀬
拓也 幸田
Takuya Koda
拓也 幸田
裕貴 高田
Yuki Takada
裕貴 高田
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Kao Corp
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Kao Corp
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Abstract

To provide a nonwoven fabric for an absorbent article capable of achieving both of thinning of an absorber and liquid return reduction in the absorbent article, since, thinning is desired for improving wearing comfort, and as a technique for thinning the absorbent article, an amount of pulp fibers included in the absorber is reduced, or a high absorbent polymer material is held by a nonwoven fabric and making the material a sheet without a pulp fiber, however, due to thinning of the absorbent article, gel blocking by the high absorbent polymer material (called as SAP) in liquid absorption time easily occurs, and by excessive gel blocking, absorption performance is reduced and liquid return (wet back) easily occurs sometimes.SOLUTION: There is provided a nonwoven fabric for an absorbent article which has hydrophilic property and which includes a layer of long fibers whose average fiber diameter is 1 μm or smaller.SELECTED DRAWING: None

Description

本発明は、生理用ナプキンやパンティライナー等の吸収性物品用の不織布に関する。 The present invention relates to non-woven fabrics for absorbent articles such as sanitary napkins and panty liners.

生理用ナプキン等の吸収性物品において、液吸収性や着用感の向上のための種々の提案がされてきた。
例えば、特許文献1には、吸収体におけるゲルブロッキングを防止して液吸収速度を向上させる観点から、長繊維のウエブ中に高吸収性ポリマーを含ませる技術が記載されている。特許文献2記載の吸収性物品では、湿潤強度を高める観点から、マイクロファイバー間の溶融結合によって粒子状の高吸収性材料を固定する技術が記載されている。また、特許文献3には、層間の固着状態を保持するために、弾性ウエブを含んだ吸収性コアと、細孔を備えた収容層とを備えた吸収性物品が記載されている。同文献には、前記吸収性コアがメルトブローン繊維ウエブと超吸収性材料粒子を有することが記載されている。
Various proposals have been made for improving liquid absorbency and wearing feeling in absorbent articles such as sanitary napkins.
For example, Patent Document 1 describes a technique for including a highly absorbent polymer in a long fiber web from the viewpoint of preventing gel blocking in an absorber and improving the liquid absorption rate. The absorbent article described in Patent Document 2 describes a technique for fixing a highly absorbent material in the form of particles by melt bonding between microfibers from the viewpoint of increasing wet strength. Further, Patent Document 3 describes an absorbent article provided with an absorbent core including an elastic web and an accommodating layer having pores in order to maintain a fixed state between layers. The document describes that the absorbent core has a melt blown fiber web and superabsorbable material particles.

特開2007−144101号公報JP-A-2007-144101 特表2007−512868号公報Special Table 2007-512868A 特表平7−502433号公報Japanese Patent Publication No. 7-502433

吸収性物品においては、装着快適性の向上のため薄型化が望まれている。薄型化の技術として、吸収体に含まれるパルプ繊維を低減したり、パルプ繊維を用いずに高吸収性ポリマー材を不織布で挟持してシート化したりすることが行われてきた。しかし、薄型化によって、液吸収時に高吸収性ポリマー材(SAPともいう)によるゲルブロッキングが起こりやすくなる。ゲルブロッキングが過度に進むと、吸収性能が低下して液戻り(ウエットバック)が生じやすくなることがある。 Absorbent articles are desired to be thinner in order to improve wearing comfort. As a technique for reducing the thickness, the number of pulp fibers contained in the absorber has been reduced, and a highly absorbent polymer material has been sandwiched between non-woven fabrics to form a sheet without using pulp fibers. However, due to the thinning, gel blocking by a highly absorbent polymer material (also referred to as SAP) is likely to occur during liquid absorption. If gel blocking progresses excessively, the absorption performance may deteriorate and liquid return (wetback) may easily occur.

本発明は、上記の点に鑑み、吸収性物品における吸収体の薄型化と液戻り低減とを両立させ得る吸収性物品用不織布に関する。 In view of the above points, the present invention relates to a non-woven fabric for an absorbent article, which can achieve both thinning of the absorber and reduction of liquid return in the absorbent article.

本発明は、親水性で、かつ、平均繊維径1μm以下の長繊維の層を含む吸収性物品用不織布を提供する。 The present invention provides a non-woven fabric for an absorbent article that is hydrophilic and contains a layer of long fibers having an average fiber diameter of 1 μm or less.

本発明の吸収性物品用不織布は、吸収性物品における吸収体の薄型化と液戻り低減とを両立させることができる。 The non-woven fabric for absorbent articles of the present invention can achieve both thinning of the absorber and reduction of liquid return in the absorbent article.

以下、本発明の吸収性物品用不織布の好ましい実施形態について説明する。
本発明の吸収性物品用不織布は、親水性で、かつ、平均繊維径1μm以下の長繊維の層を含む。ここで「長繊維」とは、一般的な意味であるが、例えば繊維アスペクト比(繊維の長さ/直径)が1000以上であり、1mm以上の繊維長を有する繊維を含む。一般的には、溶融紡糸や乾式紡糸、湿式紡糸など、連続繊維を紡糸する方法で製造された不織布は、「長繊維の層」に該当する。また、「親水性で、かつ、平均繊維径1μm以下の長繊維の層」とは、該層に含まれる親水性長繊維の平均繊維径が1μm以下であることを意味し、該層に含まれる全ての繊維の平均繊維径が1μm以下であることを意味するものではない。
親水性で、かつ、平均繊維径1μm以下の長繊維の層は、繊維間の緻密な液流路(例えばナノメートルオーダーの液流路)を具備しており、液吸収性が高い。また、長繊維の層は、繊維長が1mm未満の短繊維の層に比べて、湿潤時に型崩れを起こし難い。すなわち湿潤時の強度が高く、層形状が保持されやすい。加えて、前記長繊維の層では、前記長繊維がうねりを伴いながらも繊維長の方向に向きを揃えて層をなしており、不織布が局所的に見た場合に一方向の繊維配向性を備える。これにより前述の緻密な液流路は筋状にされる。筋状の液流路同士は、薄い不織布内で近接しながらも極細の長繊維を介して連携し合い、緻密で複雑な立体空隙構造(液流路ネットワーク構造)を形成する。
これにより、本発明の吸収性物品用不織布は、高い液吸収性と高い形状維持性とを備え、一度吸収された液が外に排出され難くなる。具体的には、本発明の吸収性物品用不織布は、液を長繊維の繊維長方向に拡散させながら、繊維間の緻密な液流路へと引き込む。同時に、前述の立体空隙構造を形成する液流路が貯蔵隙(例えばナノメートルオーダーの貯蔵隙)となって液を保持し得る。吸収保持された液は、繊維長の方向に延びる緻密で筋状の貯蔵隙において安定的な液膜となりやすく、外に排出され難くなる。
このような本発明の吸収性物品用不織布は、吸収性物品における吸収体に液保持性部材として含むことができる。これにより、本発明に係る吸収体は、パルプ繊維や高吸収性ポリマー材に代わる高い液吸収性を備えるものとなり、薄型化と液戻り低減との両立が実現され得る。
Hereinafter, preferred embodiments of the non-woven fabric for absorbent articles of the present invention will be described.
The non-woven fabric for absorbent articles of the present invention is hydrophilic and contains a layer of long fibers having an average fiber diameter of 1 μm or less. Here, the term "long fiber" has a general meaning, and includes, for example, a fiber having a fiber aspect ratio (fiber length / diameter) of 1000 or more and a fiber length of 1 mm or more. In general, a non-woven fabric produced by a method of spinning continuous fibers such as melt spinning, dry spinning, and wet spinning falls under the category of "long fiber layer". Further, "a layer of long fibers that is hydrophilic and has an average fiber diameter of 1 μm or less" means that the average fiber diameter of the hydrophilic long fibers contained in the layer is 1 μm or less, and is included in the layer. It does not mean that the average fiber diameter of all the fibers is 1 μm or less.
The layer of long fibers having an average fiber diameter of 1 μm or less, which is hydrophilic, has a dense liquid flow path between the fibers (for example, a liquid flow path on the order of nanometers) and has high liquid absorption. Further, the layer of long fibers is less likely to lose its shape when wet than the layer of short fibers having a fiber length of less than 1 mm. That is, the strength when wet is high, and the layer shape is easily maintained. In addition, in the layer of the long fibers, the long fibers are undulated but oriented in the direction of the fiber length to form a layer, and the non-woven fabric has a unidirectional fiber orientation when viewed locally. Be prepared. As a result, the above-mentioned dense liquid flow path is streaked. The streaky liquid flow paths cooperate with each other through ultrafine long fibers while being close to each other in a thin non-woven fabric to form a dense and complicated three-dimensional void structure (liquid flow path network structure).
As a result, the non-woven fabric for absorbent articles of the present invention has high liquid absorbency and high shape retention, and the liquid once absorbed is difficult to be discharged to the outside. Specifically, the non-woven fabric for absorbent articles of the present invention draws the liquid into a dense liquid flow path between the fibers while diffusing the liquid in the fiber length direction of the long fibers. At the same time, the liquid flow path forming the above-mentioned three-dimensional void structure can serve as a storage gap (for example, a storage gap on the order of nanometers) to hold the liquid. The absorbed and retained liquid tends to form a stable liquid film in the dense and streaky storage gap extending in the fiber length direction, and is difficult to be discharged to the outside.
Such a non-woven fabric for an absorbent article of the present invention can be included as a liquid-retaining member in an absorber in the absorbent article. As a result, the absorber according to the present invention has high liquid absorbency instead of pulp fiber or a highly absorbent polymer material, and both thinning and reduction of liquid return can be realized.

液吸収性を高める観点から、前記長繊維の平均繊維径は、1μm以下が好ましく、0.9μm以下がより好ましく、0.8μm以下が更に好ましい。前記長繊維の平均繊維径は小さいほど好ましいが、液吸収速度の観点から、0.05μm以上が好ましく、0.1μm以上がより好ましく、0.2μm以上が更に好ましい。
また、前記長繊維の繊維長は、液吸収性、湿潤時の不織布の保形性及び吸収した液の放出抑制機能を高める観点から、1mm以上が好ましく、5mm以上がより好ましく、10mm以上が更に好ましい。
From the viewpoint of enhancing liquid absorption, the average fiber diameter of the long fibers is preferably 1 μm or less, more preferably 0.9 μm or less, still more preferably 0.8 μm or less. The smaller the average fiber diameter of the long fibers is, the more preferable, but from the viewpoint of the liquid absorption rate, 0.05 μm or more is preferable, 0.1 μm or more is more preferable, and 0.2 μm or more is further preferable.
The fiber length of the long fibers is preferably 1 mm or more, more preferably 5 mm or more, and further preferably 10 mm or more, from the viewpoint of enhancing liquid absorption, shape retention of the non-woven fabric when wet, and function of suppressing the release of absorbed liquid. preferable.

(平均繊維径の測定方法)
測定対象の不織布からランダムに小片サンプル5個を採取し、走査型電子顕微鏡(SEM)(例えば、日本電子株式会社製、JCM−6000PLUS(商品名))を用いて、視野に20〜60本の繊維が映るように観察倍率を例えば1000〜10000倍に拡大した写真を撮像する。前記写真について視野内すべての繊維についてそれぞれ1回ずつカウントするように繊維径を測定し、平均値の小数点以下第一位を四捨五入し算出することで、平均繊維径を求められる。
(繊維長の測定方法)
測定対象の不織布を、例えばSEMなどを用いて、繊維の長さ方向に追跡して、各繊維の繊維長を求めることができる。
(Measuring method of average fiber diameter)
Five small sample samples were randomly collected from the non-woven fabric to be measured, and 20 to 60 pieces were placed in the field of view using a scanning electron microscope (SEM) (for example, JCM-6000PLUS (trade name) manufactured by JEOL Ltd.). An image is taken in which the observation magnification is enlarged to, for example, 1000 to 10000 times so that the fibers are reflected. The average fiber diameter can be obtained by measuring the fiber diameter so as to count each fiber in the field of view once for each of the above photographs and rounding off the first decimal place of the average value.
(Method of measuring fiber length)
The non-woven fabric to be measured can be traced in the fiber length direction using, for example, SEM, and the fiber length of each fiber can be obtained.

本発明の吸収性物品用不織布は、上記の長繊維の層を少なくとも1層有して前述の作用を奏し得る限り、繊維長1mm未満の短繊維を含んでいてもよい。この場合、吸収性物品用不織布における短繊維の質量割合は、10%以下が好ましく、5%以下がより好ましい。また、長繊維の層による液吸収性、液戻り低減性及び薄型化を阻害しない範囲で、高吸収性ポリマー材が配されてもよい。この場合、吸収性物品用不織布における高吸収性ポリマー材の質量割合は、10%以下が好ましく、5%以下がより好ましい。ただし、本発明の吸収性物品用不織布は、短繊維や高吸収性ポリマー材を含まず、上記の長繊維の層のみからなることが特に好ましい。 The non-woven fabric for absorbent articles of the present invention may contain short fibers having a fiber length of less than 1 mm as long as it has at least one layer of the above-mentioned long fibers and can exert the above-mentioned action. In this case, the mass ratio of the short fibers in the non-woven fabric for absorbent articles is preferably 10% or less, more preferably 5% or less. Further, a highly absorbent polymer material may be arranged as long as it does not hinder the liquid absorbability, the liquid return reduction property and the thinning by the long fiber layer. In this case, the mass ratio of the highly absorbent polymer material in the non-woven fabric for absorbent articles is preferably 10% or less, more preferably 5% or less. However, it is particularly preferable that the non-woven fabric for absorbent articles of the present invention does not contain short fibers or a highly absorbent polymer material and consists only of the above-mentioned long fiber layer.

本発明の吸収性物品用不織布の坪量は、吸収体の高い液吸収性を保持しながら薄型化を実現する観点から、300g/m以下が好ましく、200g/m以下がより好ましく、100g/m以下が更に好ましい。また、本発明の吸収性物品用不織布の坪量は、吸収体の液吸収性及び液戻り低減性を高める観点から、4g/m以上が好ましく、7g/m以上がより好ましく、10g/m以上が更に好ましい。 The basis weight of the absorbent article for nonwoven fabric of the present invention, from the viewpoint of realizing a thinner while maintaining a high absorbent liquid absorbent is preferably 300 g / m 2 or less, more preferably 200 g / m 2, 100 g / M 2 or less is more preferable. Further, the basis weight of the non-woven fabric for absorbent articles of the present invention is preferably 4 g / m 2 or more, more preferably 7 g / m 2 or more, and 10 g / m 2 or more from the viewpoint of enhancing the liquid absorbency and the liquid return reducing property of the absorber. More than m 2 is more preferable.

(本発明の吸収性物品用不織布の坪量の測定方法)
測定対象の不織布について、重量と面積を求め、重量を面積で除することで吸収性物品用不織布の坪量を測定することができる。
(Method of measuring the basis weight of the non-woven fabric for absorbent articles of the present invention)
The weight and area of the non-woven fabric to be measured can be obtained, and the basis weight of the non-woven fabric for absorbent articles can be measured by dividing the weight by the area.

本発明に係る吸収体は、前述のとおり、本発明の吸収性物品用不織布を含み、高い吸収性を維持し、薄型化と液戻り低減との両立を実現する。本発明に係る吸収体において、本発明の吸収性物品用不織布は少なくとも1つ含まれており、2つ以上含まれていてもよい。また、本発明の作用効果を阻害しない限りにおいて、本発明に係る吸収体は、本発明の吸収性物品用不織布に他の部材を組み合わせて構成されていてもよい。ただし、高い吸収性を維持し、薄型化と液戻り低減との両立を実現する観点から、本発明に係る吸収体は、本発明の吸収性物品用不織布のみからなることが好ましい。 As described above, the absorber according to the present invention contains the non-woven fabric for absorbent articles of the present invention, maintains high absorbency, and realizes both thinning and reduction of liquid return. In the absorber according to the present invention, at least one non-woven fabric for absorbent articles of the present invention is contained, and two or more may be contained. Further, the absorber according to the present invention may be formed by combining the non-woven fabric for an absorbent article of the present invention with other members as long as the action and effect of the present invention are not impaired. However, from the viewpoint of maintaining high absorbency and achieving both thinning and reduction of liquid return, the absorber according to the present invention is preferably composed of only the non-woven fabric for absorbent articles of the present invention.

本発明の吸収性物品用不織布を含んだ吸収体は、繊維材料のみからなることが好ましい。すなわち、高吸収性ポリマー材を含まないことが好ましい。これにより、本発明に係る吸収体は、高吸収性ポリマー材によるゲルブロッキングの発生を回避して、薄型化にも拘らず、液戻り低減性とともに吸収速度を向上させることができる。
本発明に係る吸収体が含む繊維材料は、合成繊維のみからなることが好ましい。すなわち、本発明の吸収性物品用不織布が合成繊維のみからなることが好ましい。これにより、湿潤時の吸収体の保形性が更に高められ、液戻り低減性が更に高められる。
The absorber containing the non-woven fabric for absorbent articles of the present invention preferably comprises only a fiber material. That is, it is preferable that the highly absorbent polymer material is not contained. As a result, the absorber according to the present invention can avoid the occurrence of gel blocking due to the highly absorbent polymer material, and can improve the absorption rate as well as the liquid return reducing property in spite of the thinning.
The fiber material contained in the absorber according to the present invention is preferably composed only of synthetic fibers. That is, it is preferable that the non-woven fabric for absorbent articles of the present invention is composed only of synthetic fibers. As a result, the shape-retaining property of the absorber when wet is further enhanced, and the liquid return reducing property is further enhanced.

さらに、本発明の吸収性物品用不織布に含まれる前記長繊維は、親水化されたポリオレフィン系繊維であることが好ましい。これにより、湿潤時の吸収体の保形性と、吸収性物品の経済性とを両立することができる。また、前記長繊維は、繊維内部に親水化剤を有するものであることが好ましい。繊維内に親水化剤を含んでいることによって、吸収体において繰り返しの液吸収があっても、繊維の親水性が維持されやすくなる。これにより、吸収体の吸収性能(吸収速度及び吸収容量)、液戻り低減性が維持されやすくなる。このような親水化剤の繊維内部への添加(内添)は、不織布において用いられる種々の方法によって実施することができる。例えば、溶融樹脂を用いた紡糸直結型の製造方法(例えば、メルトブローン法)が挙げられる。具体的には、溶融樹脂に親水化剤を加えて混合し、極細の紡糸口金のノズルから溶融樹脂を吐出する。吐出した溶融樹脂に対し高温気体のジェット流等を吹きつけて極細の綿状の繊維を形成して堆積させ、冷却して不織布化する。 Further, the long fibers contained in the non-woven fabric for absorbent articles of the present invention are preferably hydrophilic polyolefin fibers. As a result, both the shape-retaining property of the absorber when wet and the economic efficiency of the absorbent article can be achieved. Further, it is preferable that the long fibers have a hydrophilizing agent inside the fibers. By containing the hydrophilic agent in the fiber, the hydrophilicity of the fiber can be easily maintained even if the absorber repeatedly absorbs the liquid. As a result, the absorption performance (absorption rate and absorption capacity) of the absorber and the liquid return reducing property can be easily maintained. The addition (internal addition) of such a hydrophilizing agent to the inside of the fiber can be carried out by various methods used in the non-woven fabric. For example, a spinning direct-coupled manufacturing method using a molten resin (for example, a melt blown method) can be mentioned. Specifically, a hydrophilic agent is added to the molten resin and mixed, and the molten resin is discharged from a nozzle of an ultrafine spinneret. A jet stream of high-temperature gas or the like is blown onto the discharged molten resin to form ultrafine cotton-like fibers, which are deposited and cooled to form a non-woven fabric.

上記の合成繊維や親水化剤としては、吸収性物品において通常用いられる種々のものを特に制限なく用いることができる。 As the synthetic fiber and the hydrophilic agent, various ones usually used in an absorbent article can be used without particular limitation.

(長繊維内に含有される親水化剤の確認方法)
経時での親水性能の変化や、長繊維の断面(繊維径方向の断面)を表面分析の手法で解析することで、長繊維内に含有される親水化剤を確認できる。例えば、表面の親水化剤を溶媒等で洗浄して洗い流し、一旦親水性能を消失させた長繊維の層について、経時で親水性能が向上することを確認したり、或いは長繊維の断面(繊維径方向の断面)を、飛行時間型二次イオン質量分析法などの方法により解析し、繊維内部の親水化剤を検出したりすることで確認できる。
(Method of confirming the hydrophilizing agent contained in the long fibers)
By analyzing the change in hydrophilicity performance with time and the cross section of the long fiber (cross section in the fiber radial direction) by the surface analysis method, the hydrophilic agent contained in the long fiber can be confirmed. For example, it can be confirmed that the hydrophilic performance of the layer of long fibers whose surface hydrophilicity is once lost by washing with a solvent or the like and washed away, or that the hydrophilic performance is improved with time, or the cross section of the long fibers (fiber diameter). The cross section in the direction) can be confirmed by analyzing the time-of-flight type secondary ion mass spectrometry or the like and detecting the hydrophilic agent inside the fiber.

本発明に係る吸収体は、本発明の吸収性物品用不織布を単層又は複数層のいずれの形態で含んでいてもよい。複数層の積層構造にすることによって、層間に極薄の面状空隙ができ、該面状空隙が、前述の層内の緻密な立体空隙構造と連動して液の吸収性能を高めることができ、好ましい。具体的には、各層内の緻密な立体空隙構造同士が層間の極薄の面状空隙によって連結されて、平面方向と厚み方向とに連動する、緻密で入り組んだ立体的な液流路ないし貯蔵隙が形成される。これにより、層内の立体空隙構造において、互いに連携する複数の筋状の液流路(貯蔵隙)にて長繊維の繊維長の方向に液を拡散させながら貯蔵し、貯まった液を層間の面状空隙が面で受け、更に次の層内の立体空隙構造へと引き渡す。すなわち、層間における液吸収力と、各層の緻密(例えばナノメートルオーダー)な筋状の液流路(貯蔵隙)の吸収力とが、吸収体の厚み方向に連動して強い液引き込み力を発現し、吸収体の吸収性能(吸収速度及び吸収容量)並びに液戻り低減性を更に高めることができる。
本発明に係る吸収体が、本発明の吸収性物品用不織布を単層又は複数層いずれの形態で含む場合であっても、長繊維の繊維長に沿った配向方向が、吸収体の長手方向であることが好ましい。これにより吸収体全体での効率的な液吸収ができ、また吸収体を組み込んだ吸収性物品における排泄液の横漏れの防止性を高めることができる。複数層の積層構造の形態では、本発明の吸収性物品用不織布を複数枚積層してもよく、本発明の吸収性物品用不織布を折り畳んで積層してもよい。
また、吸収性物品において液の排泄を直接受け取る受液領域(排泄ポイント)に対応する吸収体の部分に、折り畳み構造の最も厚みのある部分が配置されることが好ましい。これにより、長繊維の繊維長に沿った液の拡散と同時に、受液領域にて何層にも亘る厚み方向の液吸収を実現し得る。その結果、本発明に係る吸収体は、高い吸収容量で素早く液吸収して液の漏出を抑制し、加圧等による液戻り低減性を更に高めることができる。
The absorber according to the present invention may contain the non-woven fabric for absorbent articles of the present invention in either a single layer or a plurality of layers. By forming a laminated structure of a plurality of layers, ultrathin planar voids are formed between the layers, and the planar voids can enhance the liquid absorption performance in conjunction with the above-mentioned dense three-dimensional void structure in the layer. ,preferable. Specifically, the dense three-dimensional void structures in each layer are connected by ultrathin planar voids between layers, and are linked in the plane direction and the thickness direction, and a dense and intricate three-dimensional liquid flow path or storage. A gap is formed. As a result, in the three-dimensional void structure in the layer, the liquid is stored while being diffused in the direction of the fiber length of the long fibers in a plurality of streaky liquid flow paths (storage gaps) that cooperate with each other, and the stored liquid is stored between the layers. The planar voids are received by the surface and further delivered to the three-dimensional void structure in the next layer. That is, the liquid absorption power between the layers and the absorption power of the dense (for example, nanometer order) streaky liquid flow path (storage gap) of each layer are linked in the thickness direction of the absorber to develop a strong liquid drawing power. However, the absorption performance (absorption rate and absorption capacity) of the absorber and the liquid return reducing property can be further improved.
Even when the absorber according to the present invention contains the non-woven fabric for absorbent articles of the present invention in either a single layer or a plurality of layers, the orientation direction along the fiber length of the long fibers is the longitudinal direction of the absorber. Is preferable. As a result, the liquid can be efficiently absorbed by the entire absorber, and the preventive property of lateral leakage of the excrement liquid in the absorbent article incorporating the absorber can be enhanced. In the form of a multi-layer laminated structure, a plurality of non-woven fabrics for absorbent articles of the present invention may be laminated, or the non-woven fabric for absorbent articles of the present invention may be folded and laminated.
In addition, it is preferable that the thickest portion of the folding structure is arranged in the portion of the absorber corresponding to the receiving region (excretion point) that directly receives the excretion of the liquid in the absorbent article. As a result, it is possible to realize the diffusion of the liquid along the fiber length of the long fibers and the liquid absorption in the thickness direction over many layers in the liquid receiving region. As a result, the absorber according to the present invention can quickly absorb the liquid with a high absorption capacity, suppress the leakage of the liquid, and further enhance the liquid return reducing property due to pressurization or the like.

前記受液領域(排泄ポイント)は、前述のとおり、吸収性物品において排泄液を直接受ける領域であり、吸収性物品の種類等に応じて適宜設定される。例えば、吸収性物品が昼用の生理用ナプキンやパンティライナーである場合、前記受液領域は、長手方向に3等分した中間部分であって、該中間部分の幅方向の長さを2等分する線から左右幅方向2.5cm以内の領域とされる。吸収性物品が夜用など臀部を覆う幅広の後方フラップを備える生理用ナプキンである場合、長手方向に4等分して2番目の部分であって、該部分の幅方向の長さを2等分する線から左右幅方向2.5cm以内の領域が、受液領域となる。また、吸収性物品がおむつである場合、幅方向の長さを2等分する線から、左右の幅方向3.5cm以内の領域であって、長手方向の長さを2等分する線から前側方向8cm以内の領域である。吸収性物品が尿とりパッドや失禁パッドである場合は、おむつと同様に設定される。 As described above, the liquid receiving region (excretion point) is a region that directly receives the excretory liquid in the absorbent article, and is appropriately set according to the type of the absorbent article and the like. For example, when the absorbent article is a sanitary napkin or panty liner for daytime, the liquid receiving region is an intermediate portion divided into three equal parts in the longitudinal direction, and the length of the intermediate portion in the width direction is 2 mag. The area is within 2.5 cm in the left-right width direction from the dividing line. If the absorbent article is a sanitary napkin with a wide rear flap that covers the buttocks, such as for night use, it is the second part divided into four equal parts in the longitudinal direction, and the length in the width direction of the part is second magnitude. The area within 2.5 cm in the left-right width direction from the dividing line is the liquid receiving area. When the absorbent article is a diaper, from the line that divides the length in the width direction into two equal parts, from the line that divides the length in the longitudinal direction into two equal parts within 3.5 cm in the left and right width directions. It is an area within 8 cm in the anterior direction. If the absorbent article is a urine absorbing pad or an incontinence pad, it is set in the same way as a diaper.

本発明の吸収性物品用不織布を含んだ吸収体の坪量は、液吸収性と液戻り低減性を高める観点から、10g/m以上が好ましく、50g/m以上がより好ましく、100g/m以上が更に好ましい。前記吸収体の坪量は、薄型化の観点から、500g/m以下が好ましく、400g/m以下がより好ましく、300g/m以下が更に好ましい。
また、本発明の吸収性物品用不織布を含んだ吸収体の厚みは、薄型化の観点からはより薄いほうが好ましいが、装着安心感の観点からは一定以上の厚みを有することが好ましい。具体的には吸収性物品の種類によって、好ましい吸収体の厚みは変わり得る。
例えば、吸収性物品がパンティライナーの場合には、吸収体の厚みは、薄型化の観点から、0.6mm以下が好ましく、0.5mm以下がより好ましく、0.4mm以下が更に好ましい。吸収性物品がパンティライナーの場合には、前記吸収体の厚みは、装着安心感の観点から、0.05mm以上が好ましく、0.1mm以上がより好ましく、0.15mm以上が更に好ましい。
例えば、吸収性物品が生理用ナプキンの場合には、吸収体の厚みは、薄型化の観点から、10mm以下が好ましく、7mm以下がより好ましく、4mm以下が更に好ましい。吸収性物品が生理用ナプキンの場合には、前記吸収体の厚みは、装着安心感の観点から、0.5mm以上が好ましく、1mm以上がより好ましく、1.5mm以上が更に好ましい。
例えば、吸収性物品が子供用おむつの場合には、吸収体の厚みは、薄型化の観点から、10mm以下が好ましく、5mm以下がより好ましく、3mm以下が更に好ましい。吸収性物品が子供用おむつの場合には、前記吸収体の厚みは、装着安心感の観点から、0.5mm以上が好ましく、1mm以上がより好ましく、1.5mm以上が更に好ましい。
例えば、吸収性物品が大人用おむつの場合には、吸収体の厚みは、薄型化の観点から、12mm以下が好ましく、6mm以下がより好ましく、3mm以下が更に好ましい。吸収性物品が大人用おむつの場合には、前記吸収体の厚みは、装着安心感の観点から、0.5mm以上が好ましく、1mm以上がより好ましく、1.5mm以上が更に好ましい。
The basis weight of the absorber containing the non-woven fabric for absorbent articles of the present invention is preferably 10 g / m 2 or more, more preferably 50 g / m 2 or more, and 100 g / m 2 or more from the viewpoint of enhancing liquid absorption and liquid return reduction. More than m 2 is more preferable. From the viewpoint of thinning, the basis weight of the absorber is preferably 500 g / m 2 or less, more preferably 400 g / m 2 or less, and even more preferably 300 g / m 2 or less.
Further, the thickness of the absorbent body including the non-woven fabric for absorbent articles of the present invention is preferably thinner from the viewpoint of thinning, but preferably has a certain thickness or more from the viewpoint of wearing comfort. Specifically, the preferable thickness of the absorber may change depending on the type of the absorbent article.
For example, when the absorbent article is a panty liner, the thickness of the absorber is preferably 0.6 mm or less, more preferably 0.5 mm or less, still more preferably 0.4 mm or less from the viewpoint of thinning. When the absorbent article is a panty liner, the thickness of the absorber is preferably 0.05 mm or more, more preferably 0.1 mm or more, still more preferably 0.15 mm or more, from the viewpoint of a sense of security in wearing.
For example, when the absorbent article is a sanitary napkin, the thickness of the absorber is preferably 10 mm or less, more preferably 7 mm or less, still more preferably 4 mm or less, from the viewpoint of thinning. When the absorbent article is a sanitary napkin, the thickness of the absorber is preferably 0.5 mm or more, more preferably 1 mm or more, still more preferably 1.5 mm or more, from the viewpoint of comfort in wearing.
For example, when the absorbent article is a diaper for children, the thickness of the absorber is preferably 10 mm or less, more preferably 5 mm or less, still more preferably 3 mm or less, from the viewpoint of thinning. When the absorbent article is a diaper for children, the thickness of the absorber is preferably 0.5 mm or more, more preferably 1 mm or more, still more preferably 1.5 mm or more, from the viewpoint of comfort in wearing.
For example, when the absorbent article is an adult diaper, the thickness of the absorber is preferably 12 mm or less, more preferably 6 mm or less, still more preferably 3 mm or less, from the viewpoint of thinning. When the absorbent article is an adult diaper, the thickness of the absorber is preferably 0.5 mm or more, more preferably 1 mm or more, still more preferably 1.5 mm or more, from the viewpoint of comfort in wearing.

本発明の吸収性物品用不織布を含む吸収体は、排泄液を吸収保持する種々の吸収性物品に適用することができる。吸収性物品の具体例としては、生理用ナプキン、パンティライナー、おむつ、失禁パッド、尿とりパッドなどが挙げられる。排泄液としても尿に限らず経血など種々のものを対象とすることができる。特に、生理用ナプキンにおいては、吸収体の薄型化と液戻り低減性の両立とともに、吸収速度向上の効果が顕著となる。また、パンティライナーにおいては、高い吸収速度を維持しながら、吸収体の薄型化を実現して、液戻り低減性の効果が顕著となる。 The absorber containing the non-woven fabric for absorbent articles of the present invention can be applied to various absorbent articles that absorb and retain excrement. Specific examples of the absorbent article include sanitary napkins, panty liners, diapers, incontinence pads, urine absorbing pads and the like. The excretory fluid is not limited to urine, but various substances such as menstrual blood can be targeted. In particular, in sanitary napkins, the effect of improving the absorption rate is remarkable as well as the thinning of the absorber and the reduction of liquid return. Further, in the panty liner, the absorption body is made thinner while maintaining a high absorption rate, and the effect of reducing liquid return becomes remarkable.

前記吸収性物品は、典型的には、表面シート、裏面シート及び両シート間に介在配置された液保持性の吸収体を具備する。また、表面シートと吸収体との間に液拡散性のセカンドシートが配置されてもよい。
本発明の吸収性物品用不織布を吸収体に適用した場合の表面シート、裏面シート及びセカンドシートとしては、当該技術分野において通常用いられている材料を特に制限無く用いることができる。例えば表面シートとしては、親水性のエアスルー不織布などが挙げられる。裏面シートとしては、熱可塑性樹脂のフィルムや、該フィルムと不織布とのラミネート等の液不透過性ないし撥水性のシートを用いることができる。裏面シートは水蒸気透過性を有していてもよい。セカンドシートとしては、親水性の不織布やクレープ紙などが挙げられる。吸収性物品は更に、該吸収性物品の具体的な用途に応じた各種部材を具備していてもよい。
The absorbent article typically comprises a front sheet, a back sheet and a liquid-retaining absorber interspersed between the sheets. Further, a liquid diffusible second sheet may be arranged between the surface sheet and the absorber.
When the non-woven fabric for an absorbent article of the present invention is applied to an absorbent body, as the front sheet, the back sheet and the second sheet, materials usually used in the art can be used without particular limitation. For example, examples of the surface sheet include a hydrophilic air-through non-woven fabric. As the back sheet, a film made of a thermoplastic resin or a liquid-impermeable or water-repellent sheet such as a laminate of the film and a non-woven fabric can be used. The back sheet may have water vapor permeability. Examples of the second sheet include hydrophilic non-woven fabrics and crepe papers. The absorbent article may further include various members according to the specific use of the absorbent article.

以下、本発明を実施例に基づきさらに詳しく説明するが、本発明はこれにより限定して解釈されるものではない。 Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not construed as being limited thereto.

(実施例1)
親水化剤を混合したポリプロピレン樹脂を用いてメルトブローン法によって、表1に示す、長繊維の層からなる吸収性物品用不織布試料1を作製した。該吸収性物品用不織布試料1を長手方向100mm×幅方向65mmの大きさに切り出し、幅方向の片方の端から15mmのところで手前側に折り畳み、続いて、幅方向の反対側の端から20mmのところで同様に手前側に折り畳むことで、見かけの大きさが長手方向100mm×幅方向30mmの、2重(長手方向100mm×幅方向5mmの一部については3重)に折り重なった吸収性物品用不織布試料1を作製し、これを2つ準備して積層(それぞれの吸収性物品用不織布試料1の3重に折り重なった部分が重ならないように互い違いに積層)し、表1に示す吸収体試料1を作製した。こうして作製した吸収体試料1は、大きさが長手方向100mm×幅方向30mm、坪量が40g/m(長手方向100mm×幅方向10mmの一部については60g/m)であった。
上記の吸収体試料1に、花王株式会社製のパンティライナー(商品名:ロリエ きれいスタイル 無香料 2017年製)において用いられる表面シート及びセカンドシートを積層して、実施例1の吸収性物品試料1を作製した。
(Example 1)
A non-woven fabric sample 1 for an absorbent article composed of a layer of long fibers shown in Table 1 was prepared by a melt blown method using a polypropylene resin mixed with a hydrophilizing agent. The non-woven fabric sample 1 for absorbent articles is cut into a size of 100 mm in the longitudinal direction × 65 mm in the width direction, folded toward the front side at 15 mm from one end in the width direction, and subsequently 20 mm from the opposite end in the width direction. By the way, by folding it toward the front side in the same way, the non-woven fabric for absorbent articles has an apparent size of 100 mm in the longitudinal direction x 30 mm in the width direction, which is double-folded (triple for a part of 100 mm in the longitudinal direction x 5 mm in the width direction). Sample 1 is prepared, two of them are prepared and laminated (separately laminated so that the triple-folded portions of the respective non-woven fabric samples 1 for absorbent articles do not overlap), and the absorber sample 1 shown in Table 1 is laminated. Was produced. The absorber sample 1 thus produced had a size of 100 mm in the longitudinal direction × 30 mm in the width direction and a basis weight of 40 g / m 2 (60 g / m 2 for a part of 100 mm in the longitudinal direction × 10 mm in the width direction).
The surface sheet and the second sheet used in the panty liner manufactured by Kao Corporation (trade name: Laurier Clean Style Unscented 2017) are laminated on the above-mentioned absorber sample 1, and the absorbent article sample 1 of Example 1 is laminated. Was produced.

(実施例2)
吸収性物品用不織布試料を長手方向100mm×60mmの大きさに切り出し、これを2つ準備して折り畳まずに2つを積層した以外は、実施例1と同様にして、表1に示す実施例2の吸収体試料2及び吸収性物品試料2を作製した。
(Example 2)
Examples shown in Table 1 are the same as in Example 1 except that a non-woven fabric sample for an absorbent article is cut into a size of 100 mm × 60 mm in the longitudinal direction, two of them are prepared and the two are laminated without folding. The absorber sample 2 and the absorbent article sample 2 of 2 were prepared.

(実施例3)
実施例1と同様に2重(長手方向100mm×幅方向5mmの一部については3重)に折り重なった吸収性物品用不織布試料1を作製し、これを1つだけ用いて吸収体試料とした以外は、実施例1と同様にして、表1に示す実施例3の吸収体試料3及び吸収性物品試料3を作製した。
(Example 3)
Similar to Example 1, a double-folded (triple for a part of 100 mm in the longitudinal direction × 5 mm in the width direction) non-woven fabric sample 1 for an absorbent article was prepared, and only one of these was used as an absorber sample. Except for the above, the absorber sample 3 and the absorbent article sample 3 of Example 3 shown in Table 1 were prepared in the same manner as in Example 1.

(実施例4)
セカンドシートを配さなかった以外は、実施例3と同様にして、表1に示す実施例4の吸収体試料4及び吸収性物品試料4を作製した。
(Example 4)
The absorber sample 4 and the absorbent article sample 4 of Example 4 shown in Table 1 were prepared in the same manner as in Example 3 except that the second sheet was not arranged.

(比較例1)
花王株式会社製のパンティライナー(商品名:ロリエ きれいスタイル 無香料 2017年製)において用いられる表面シート、セカンドシート及び吸収体を積層して、比較例1の吸収性物品試料C1を作製した。ここで用いる吸収体は、表1に示すとおりであった。
(Comparative Example 1)
An absorbent article sample C1 of Comparative Example 1 was prepared by laminating a surface sheet, a second sheet and an absorber used in a panty liner manufactured by Kao Corporation (trade name: Laurier Clean Style Unscented 2017). The absorbers used here are as shown in Table 1.

(比較例2)
親水化剤を混合したポリプロピレン樹脂を用いてスパンボンド法によって、表1に示す、長繊維の層からなる吸収性物品用不織布試料C2を作製した。該吸収性物品用不織布試料C2を長手方向100mm×幅方向65mmの大きさに切り出し、幅方向の片方の端から15mmのところで手前側に折り畳み、続いて、幅方向の反対側の端から20mmのところで同様に手前側に折り畳むことで、見かけの大きさが長手方向100mm×幅方向30mmの、2重(長手方向100mm×幅方向5mmの一部については3重)に折り重なった試料を作製し、これを表1に示す吸収体試料C2とした。
この吸収体試料C2に対し、実施例3と同様にして、比較例2の吸収性物品試料C2を作製した。
(Comparative Example 2)
A non-woven fabric sample C2 for an absorbent article composed of a layer of long fibers shown in Table 1 was prepared by a spunbond method using a polypropylene resin mixed with a hydrophilizing agent. The non-woven fabric sample C2 for absorbent articles is cut into a size of 100 mm in the longitudinal direction × 65 mm in the width direction, folded toward the front side at 15 mm from one end in the width direction, and subsequently 20 mm from the opposite end in the width direction. By the way, by folding it toward the front side in the same manner, a sample having an apparent size of 100 mm in the longitudinal direction × 30 mm in the width direction and double (triple for a part of 100 mm in the longitudinal direction × 5 mm in the width direction) is prepared. This was designated as the absorber sample C2 shown in Table 1.
For this absorber sample C2, the absorbent article sample C2 of Comparative Example 2 was prepared in the same manner as in Example 3.

(試験1)
各吸収性物品試料の表面シート上に、中央に内径1cmの透過孔を有するアクリル板(160mm×60mm、75g)を載せ、その上に140gの錘を2個、均等に(透過孔を挟むように)載置した。斯かる荷重下において、該アクリル板の透過孔から経血に相当する疑似血液(株式会社日本バイオテスト研究所製の馬脱繊維血液を8.0cPに調整したもの)0.5gを、スポイトを用いて流し込んだ。なお、用いた馬脱繊維血液は、東機産業株式会社のTVB10形粘度計にて、30rpmの条件下で調整した。馬脱繊維血液は、放置すると、粘度の高い部分(赤血球など)は沈殿し、粘度の低い部分(血漿)は、上澄みとして残る。その部分の混合比率を、8.0cPになるように調整した。
疑似血液を流し込んでから1分間静置させた後、アクリル板を取り除いた。次いで、各吸収性物品試料の前記擬似血液を投入した部分に、80mm×60mmに裁断したろ紙No.2を重ねて、3g/cmの荷重を10秒間かけた後、ろ紙の質量(W2)を測定した。測定したろ紙の質量(W2)と、予め測定しておいた、各吸収性物品試料に重ねる前のろ紙の質量(W1)との差(W2−W1)を算出し、液戻り量とした。
また、上述した液戻り量試験の評価時に、0.5gの全量が各吸収性物品試料に吸収されるまでの時間を計測した。
(Test 1)
An acrylic plate (160 mm x 60 mm, 75 g) having a transmission hole with an inner diameter of 1 cm is placed on the surface sheet of each absorbent article sample, and two 140 g weights are evenly placed on the acrylic plate (160 mm × 60 mm, 75 g) so as to sandwich the transmission hole. ) Placed. Under such a load, 0.5 g of pseudo blood (horse defibered blood manufactured by Japan Biotest Research Institute Co., Ltd. adjusted to 8.0 cP) corresponding to menstrual blood was added to the dropper from the permeation hole of the acrylic plate. Pour in using. The horse defibered blood used was adjusted with a TVB10 viscometer manufactured by Toki Sangyo Co., Ltd. under the condition of 30 rpm. When left untreated, horse defibrous blood precipitates high-viscosity parts (erythrocytes, etc.) and low-viscosity parts (plasma) remain as supernatant. The mixing ratio of that part was adjusted to 8.0 cP.
After pouring in the pseudo blood and letting it stand for 1 minute, the acrylic plate was removed. Next, the filter paper No. cut into 80 mm × 60 mm was applied to the portion of each absorbent article sample into which the pseudo blood was charged. After stacking 2 and applying a load of 3 g / cm 2 for 10 seconds, the mass (W2) of the filter paper was measured. The difference (W2-W1) between the measured mass of the filter paper (W2) and the previously measured mass of the filter paper (W1) before being stacked on each absorbent article sample was calculated and used as the liquid return amount.
Further, at the time of evaluation of the liquid return amount test described above, the time until the entire amount of 0.5 g was absorbed by each absorbent article sample was measured.

Figure 2020156669
Figure 2020156669

表1に示すとおり、実施例1〜4では、比較例1及び2と比較して、液戻り量が抑えられており、液戻りを十分に低減できていた。特に、不織布を積層させた実施例1及び2において、高い液戻り防止性を示した。また、実施例1〜3では、疑似血液の吸収時間が短く、液吸収速度が優れていた。
このように、本発明の吸収性物品用不織布を含む吸収体は、坪量が低くても液戻り低減が可能であり、吸収性物品における吸収体の薄型化と液戻り低減とを両立させ得ることがわかる。
As shown in Table 1, in Examples 1 to 4, the amount of liquid return was suppressed as compared with Comparative Examples 1 and 2, and the liquid return could be sufficiently reduced. In particular, in Examples 1 and 2 in which the non-woven fabric was laminated, high liquid return prevention property was exhibited. Further, in Examples 1 to 3, the absorption time of the pseudo blood was short and the liquid absorption rate was excellent.
As described above, the absorber containing the non-woven fabric for the absorbent article of the present invention can reduce the liquid return even if the basis weight is low, and can achieve both the thinning of the absorber and the reduction of the liquid return in the absorbent article. You can see that.

(実施例5)
親水化剤を混合したポリプロピレン樹脂を用いてメルトブローン法によって、表2に示す、長繊維の層からなる吸収性物品用不織布試料5を作製した。該吸収性物品用不織布試料5を3枚積層して、表2に示す吸収体試料5を作製した。
上記の吸収体試料5に、花王株式会社製の生理用ナプキン(商品名:ロリエエフ しあわせ素肌 22.5cm 2017年製)において用いられる表面シートを積層して、実施例5の吸収性物品試料5を作製した。
(Example 5)
A non-woven fabric sample 5 for an absorbent article composed of a layer of long fibers shown in Table 2 was prepared by a melt blown method using a polypropylene resin mixed with a hydrophilizing agent. The absorbent sample 5 shown in Table 2 was prepared by laminating three non-woven fabric samples 5 for absorbent articles.
The surface sheet used in the sanitary napkin manufactured by Kao Corporation (trade name: Loriev Happy Bare Skin 22.5 cm, manufactured in 2017) is laminated on the above-mentioned absorber sample 5, and the absorbent article sample 5 of Example 5 is obtained. Made.

(実施例6)
吸収性物品用不織布試料の積層枚数を4枚とした以外は、実施例5と同様にして、表2に示す実施例6の吸収性物品用不織布試料6、吸収体試料6及び吸収性物品試料6を作製した。
(Example 6)
Similar to Example 5, the non-woven fabric sample 6 for absorbent articles, the absorber sample 6 and the absorbent article sample shown in Table 2 are shown in Table 2 except that the number of laminated non-woven fabric samples for absorbent articles is four. 6 was prepared.

(実施例7)
実施例5にて用いた吸収性物品用不織布試料を第1吸収性物品用不織布試料71として3枚積層し、これとは平均繊維径が異なる、表2に示す第2吸収性物品用不織布試料72を作製して前記3枚の肌面側に積層した以外は、実施例5と同様にして、表2に示す実施例7の吸収体試料7及び吸収性物品試料7を作製した。
(Example 7)
Three non-woven fabric samples for absorbent articles used in Example 5 were laminated as the first non-woven fabric sample for absorbent articles 71, and the average fiber diameter was different from this, and the non-woven fabric sample for second absorbent articles shown in Table 2 was laminated. Absorbent sample 7 and absorbent article sample 7 of Example 7 shown in Table 2 were prepared in the same manner as in Example 5 except that 72 was prepared and laminated on the skin surface side of the three sheets.

(比較例3)
花王株式会社製の生理用ナプキン(商品名:ロリエエフ しあわせ素肌 22.5cm 2017年製)において用いられる表面シート及び吸収体を積層して、比較例3の吸収性物品試料C3を作製した。ここで用いる吸収体は、表2に示すとおりであった。
(Comparative Example 3)
A surface sheet and an absorber used in a sanitary napkin manufactured by Kao Corporation (trade name: Loriev Happy Bare Skin 22.5 cm, manufactured in 2017) were laminated to prepare an absorbent article sample C3 of Comparative Example 3. The absorbers used here are as shown in Table 2.

(比較例4)
実施例7で用いた第2吸収性物品用不織布試料72と同様のものを吸収性物品用不織布試料C4として4枚重ねて吸収体試料C4とした以外は、実施例5と同様にして、表2に示す比較例4の吸収性物品用不織布試料C4、吸収体試料C4及び吸収性物品試料C4を作製した。
(Comparative Example 4)
Table 5 in the same manner as in Example 5 except that four non-woven fabric samples C4 for absorbent articles similar to the non-woven fabric sample 72 for second absorbent articles used in Example 7 were stacked to form an absorber sample C4. Nonwoven fabric sample C4 for absorbent article, absorber sample C4 and absorbent article sample C4 of Comparative Example 4 shown in 2 were prepared.

(比較例5)
親水化剤を混合したポリプロピレン樹脂を用いてスパンボンド法によって、表2に示す吸収性物品用不織布試料C5を作製した。該吸収性物品用不織布試料C5を用いて、表2に示す吸収体試料C5を作製した。
上記の吸収体試料C5に、花王株式会社製の生理用ナプキン(商品名:ロリエエフ しあわせ素肌 22.5cm 2017年製)において用いられる表面シートを積層して、比較例5の吸収性物品試料C5を作製した。
(Comparative Example 5)
A non-woven fabric sample C5 for absorbent articles shown in Table 2 was prepared by a spunbonding method using a polypropylene resin mixed with a hydrophilizing agent. The absorbent sample C5 shown in Table 2 was prepared using the non-woven fabric sample C5 for absorbent articles.
The surface sheet used in the sanitary napkin manufactured by Kao Corporation (trade name: Loriev Happy Bare Skin 22.5 cm, manufactured in 2017) is laminated on the above-mentioned absorber sample C5, and the absorbent article sample C5 of Comparative Example 5 is laminated. Made.

(試験2)
(1)各吸収性物品用試料の表面シート上に、中央に内径1cmの透過孔を有するアクリル板(200mm×100mm、210g)を載せた。斯かる荷重下において、該アクリル板の透過孔から前記(試験1)にて用いた擬似血液3gを一気に注入し、吸収時間を測定した。
(2)疑似血液を流し込んでから45秒間静置させた後、アクリル板を取り除いた。次いで、注入から1分後、各吸収性物品試料の前記擬似血液を投入した部分に、95mm×56mmに折り畳んだティッシュと錘(104mm×30mm、125g)を重ねて5秒置き、ティッシュの質量(W4)を測定した。予め測定しておいた、各吸収性物品試料に重ねる前のティッシュの質量(W3)との差(W4−W3)を算出し、液戻り量とした。
(3)評価開始時(疑似血液注入時)から3分後、6分後にナプキン+プレート上に擬似血液3gを注入する前記(1)〜(2)の手順を繰り返して、疑似血液を合計9g注入した。3g、6g、9g注入時それぞれにおける液戻り量及び吸収時間を測定した。
(Test 2)
(1) An acrylic plate (200 mm × 100 mm, 210 g) having a transmission hole with an inner diameter of 1 cm was placed on the surface sheet of each absorbent article sample. Under such a load, 3 g of the pseudo blood used in the above (Test 1) was injected at once from the through hole of the acrylic plate, and the absorption time was measured.
(2) After pouring the pseudo blood and letting it stand for 45 seconds, the acrylic plate was removed. Next, 1 minute after the injection, a tissue folded to 95 mm × 56 mm and a weight (104 mm × 30 mm, 125 g) were placed on the portion of each absorbent article sample into which the simulated blood was injected, and placed for 5 seconds to obtain the mass of the tissue (104 mm × 30 mm, 125 g). W4) was measured. The difference (W4-W3) from the mass (W3) of the tissue before being stacked on each absorbent article sample, which was measured in advance, was calculated and used as the amount of liquid return.
(3) Inject 3 g of pseudo blood onto a napkin + plate 3 minutes and 6 minutes after the start of evaluation (injection of pseudo blood). Repeat the steps (1) and (2) above to add a total of 9 g of pseudo blood. Infused. The amount of liquid return and the absorption time at the time of injecting 3 g, 6 g, and 9 g were measured.

Figure 2020156669
Figure 2020156669

表2に示すように、実施例5〜7では、比較例4及び5と比較して、疑似血液の3g、6g、9gのいずれの注入時においても液戻り量が大幅に少なく、液戻りを十分に低減できていた。また、実施例5〜7では、比較例3〜5と比較して、疑似血液の吸収時間が同等以下であった。
このように、本発明の吸収性物品用不織布を含む吸収体は、坪量が低くても液戻り低減が可能であり、吸収性物品における吸収体の薄型化と液戻り低減とを両立させ得ることがわかる。また、高吸収性ポリマー材(SAP)を含む吸収体に対して、繰り返し吸収時の吸収時間、液戻り性が顕著に改善され得ることがわかる。
As shown in Table 2, in Examples 5 to 7, the amount of liquid return was significantly smaller at the time of injection of 3 g, 6 g, or 9 g of pseudo blood as compared with Comparative Examples 4 and 5, and liquid return was performed. It was able to be reduced sufficiently. Further, in Examples 5 to 7, the absorption time of pseudo blood was equal to or less than that of Comparative Examples 3 to 5.
As described above, the absorber containing the non-woven fabric for the absorbent article of the present invention can reduce the liquid return even if the basis weight is low, and can achieve both the thinning of the absorber and the reduction of the liquid return in the absorbent article. You can see that. Further, it can be seen that the absorption time and the liquid return property at the time of repeated absorption can be remarkably improved with respect to the absorber containing the highly absorbent polymer material (SAP).

Claims (9)

親水性で、かつ、平均繊維径1μm以下の長繊維の層を含む吸収性物品用不織布。 A non-woven fabric for absorbent articles that is hydrophilic and contains a layer of long fibers having an average fiber diameter of 1 μm or less. 請求項1記載の吸収性物品用不織布を含む吸収体。 An absorber containing the non-woven fabric for absorbent articles according to claim 1. 前記吸収体が、前記長繊維を含む繊維材料のみからなる請求項2記載の吸収体。 The absorber according to claim 2, wherein the absorber is made of only a fiber material containing the long fibers. 前記繊維材料が合成繊維である請求項3記載の吸収体。 The absorber according to claim 3, wherein the fiber material is a synthetic fiber. 前記長繊維が親水化されたポリオレフィン系繊維である請求項1〜4のいずれか1項に記載の吸収体。 The absorber according to any one of claims 1 to 4, wherein the long fiber is a polyolefin-based fiber obtained by hydrophilization. 前記長繊維が、繊維内部に親水化剤を有する請求項1〜5のいずれか1項に記載の吸収体。 The absorber according to any one of claims 1 to 5, wherein the long fiber has a hydrophilizing agent inside the fiber. 表面シートと請求項2〜6のいずれか1項に記載の吸収体とを含む吸収性物品。 An absorbent article comprising a surface sheet and the absorber according to any one of claims 2 to 6. 表面シート、裏面シート、及び前記表面シートと前記裏面シートとの間に介在配置された請求項2〜6のいずれか1項に記載の吸収体を有する吸収性物品。 An absorbent article having an absorber according to any one of claims 2 to 6, which is interposed between the front surface sheet, the back surface sheet, and the back surface sheet. 前記表面シートと前記吸収体との間にセカンドシートを有する請求項7又は8記載の吸収性物品。 The absorbent article according to claim 7 or 8, which has a second sheet between the surface sheet and the absorber.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008161584A (en) * 2006-12-28 2008-07-17 Kao Corp Absorbent article
JP2010005431A (en) * 2003-06-30 2010-01-14 Procter & Gamble Co Article containing nanofiber produced from low energy process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010005431A (en) * 2003-06-30 2010-01-14 Procter & Gamble Co Article containing nanofiber produced from low energy process
JP2008161584A (en) * 2006-12-28 2008-07-17 Kao Corp Absorbent article

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