JP2020152839A - Manufacturing method of adhesive tape - Google Patents

Manufacturing method of adhesive tape Download PDF

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JP2020152839A
JP2020152839A JP2019053350A JP2019053350A JP2020152839A JP 2020152839 A JP2020152839 A JP 2020152839A JP 2019053350 A JP2019053350 A JP 2019053350A JP 2019053350 A JP2019053350 A JP 2019053350A JP 2020152839 A JP2020152839 A JP 2020152839A
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layer
base material
pet film
film
protective layer
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JP7365777B2 (en
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内藤 真人
Masato Naito
真人 内藤
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Lintec Corp
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Abstract

To provide a manufacturing method of an adhesive film that is suppressed in the gross degradation and is difficult to be damaged in high-class feeling.SOLUTION: The present invention relates to a manufacturing method of an adhesive film 10 that has a surface protective layer 11, a base material layer 12, and an adhesive layer 13 in the lamination direction in this order, in which the base material layer is prepared in a state where a PET film 100 is directly placed at least one surface, after peeling of the PET film, on a surface 12A on which the PET film is placed, a surface protective layer is provided, and a PET film 120 is directly placed on the surface protective layer.SELECTED DRAWING: Figure 1

Description

本発明は、粘着フィルムの作製方法に関する。 The present invention relates to a method for producing an adhesive film.

従来、家電製品等に貼付され光沢によって高級感を演出する粘着フィルムが考えられており、そのような粘着フィルムの構成として、例えば特許文献1では、基材層の表面に、ハイグロスの表面保護層が積層された構成が開示されている。 Conventionally, an adhesive film that is attached to home appliances and the like to produce a high-class feeling by gloss has been considered. As a configuration of such an adhesive film, for example, in Patent Document 1, a high-gloss surface protective layer is formed on the surface of a base material layer. The configuration in which is laminated is disclosed.

特開2017−177622号公報JP-A-2017-177622

しかしながら、基材層に積層される表面保護層は、基材層の表面が荒れて凸凹であると、それに倣って凸凹となり、グロス低下を招いて高級感を損なう虞がある。 However, if the surface of the base material layer is rough and uneven, the surface protective layer laminated on the base material layer may become uneven accordingly, resulting in a decrease in gloss and impairing the sense of quality.

そこで、本発明は、グロス低下が抑制され、高級感を損ない難い粘着フィルムの作製方法を提供する。 Therefore, the present invention provides a method for producing an adhesive film in which a decrease in gloss is suppressed and a high-class feeling is not impaired.

上記目的を達成するための本発明の方法は、表面保護層、基材層、および粘着剤層を積層方向にこの順序で有する粘着フィルムの作製方法であって、前記基材層を、少なくとも一方の面にPETフィルムを直接配置した状態で準備し、前記PETフィルムの剥離後、当該PETフィルムの配置されていた面に、前記表面保護層を設け、当該表面保護層にPETフィルムを直接配置する。 The method of the present invention for achieving the above object is a method for producing an adhesive film having a surface protective layer, a base material layer, and an adhesive layer in this order in the stacking direction, and the base material layer is at least one of them. The PET film is prepared in a state of being directly arranged on the surface of the surface, and after the PET film is peeled off, the surface protective layer is provided on the surface on which the PET film is arranged, and the PET film is directly arranged on the surface protective layer. ..

上記構成を有する発明では、平滑度が他の樹脂フィルムに比べて比較的高いPETフィルムが基材層の面に直接配置され、これによって基材層の面が平滑化されるため、そこに設けられる表面保護層も平滑となり易い。さらに、表面保護層に対してもPETフィルムが直接配置されるため、表面保護層がより平滑になり易い。 In the invention having the above structure, a PET film having a relatively high smoothness as compared with other resin films is directly arranged on the surface of the base material layer, whereby the surface of the base material layer is smoothed, so that the PET film is provided there. The surface protective layer to be formed also tends to be smooth. Further, since the PET film is directly arranged on the surface protective layer, the surface protective layer tends to be smoother.

このように、上記構成を有する発明によれば、表面保護層が平滑になり易いため、粘着フィルムのグロス低下が抑制され、高級感が損なわれ難い。 As described above, according to the invention having the above structure, since the surface protective layer tends to be smooth, the gloss reduction of the adhesive film is suppressed, and the high-class feeling is not easily impaired.

実施形態の粘着フィルムを示す側面図である。It is a side view which shows the adhesive film of an embodiment. 両面にPETフィルムが配置された基材層を示す側面図である。It is a side view which shows the base material layer in which the PET film is arranged on both sides. 表面保護層が設けられた基材層を示す側面図である。It is a side view which shows the base material layer provided with the surface protection layer. 基材層に設けられた表面保護層へのPETフィルムの配置を示す側面図である。It is a side view which shows the arrangement of the PET film on the surface protection layer provided in the base material layer. 表面保護層に配置されたPETフィルムを剥がす前の粘着フィルムを示す側面図である。It is a side view which shows the adhesive film before peeling off the PET film arranged in the surface protection layer.

以下、添付した図面を参照しながら、本発明の実施形態を説明する。なお、図面の寸法比率は、説明の都合上誇張されており、実際の比率とは異なる。 Hereinafter, embodiments of the present invention will be described with reference to the attached drawings. The dimensional ratios in the drawings are exaggerated for convenience of explanation and differ from the actual ratios.

図1に示すように、実施形態の粘着フィルム10は、表面保護層11、基材層12、粘着剤層13、および剥離ライナー14を積層方向にこの順序で有する。 As shown in FIG. 1, the pressure-sensitive adhesive film 10 of the embodiment has a surface protective layer 11, a base material layer 12, a pressure-sensitive adhesive layer 13, and a release liner 14 in this order in the stacking direction.

粘着フィルム10は、剥離ライナー14を剥がし、粘着剤層13を介して被着体に貼付され、その表面を傷や汚れ等から保護する。粘着フィルム10が貼付される被着体は、例えば、スマートフォンやタブレットPC等であり、粘着フィルム10は、それらに貼付されて画面を保護するとともに、光沢によって高級感を演出する。 The adhesive film 10 peels off the release liner 14 and is attached to the adherend via the adhesive layer 13 to protect the surface thereof from scratches, stains, and the like. The adherend to which the adhesive film 10 is attached is, for example, a smartphone, a tablet PC, or the like, and the adhesive film 10 is attached to them to protect the screen and produce a high-class feeling by gloss.

被着体への粘着フィルム10の貼付は、例えば、粘着剤層13から剥離ライナー14を剥がした後、界面活性剤水溶液等の施工液を、粘着剤層13の面および被着体の少なくとも一方に噴霧して貼付する、いわゆる水貼りであるが、これに限定されず、剥離ライナー14を剥がしてそのまま粘着剤層13を被着体に付着させる、いわゆるドライ貼りであってもよい。 To attach the pressure-sensitive adhesive film 10 to the adherend, for example, after peeling off the release liner 14 from the pressure-sensitive adhesive layer 13, a working solution such as an aqueous surfactant solution is applied to at least one of the surface of the pressure-sensitive adhesive layer 13 and the adherend. The so-called water-paste is applied by spraying on the film, but the present invention is not limited to this, and a so-called dry-paste may be used in which the release liner 14 is peeled off and the adhesive layer 13 is directly attached to the adherend.

粘着フィルム10は、剥離ライナー14を剥がした状態で、透明性を有する。ここで、どの程度の透明性を有するかは特に限定されず、粘着フィルム10を貼付した状態でスマートフォンやタブレットPC等の画面を視認可能であればよい。 The adhesive film 10 has transparency in a state where the release liner 14 is peeled off. Here, the degree of transparency is not particularly limited as long as the screen of a smartphone, tablet PC or the like can be visually recognized with the adhesive film 10 attached.

表面保護層11は、スマートフォンやタブレットPC等の画面操作の際、使用者の指の滑りを円滑にする役割を果たす。また、それに限定されず、表面保護層11は、例えば耐傷性や防汚性等の機能を有してもよい。これらの観点から、表面保護層11の形成材料は、好ましくはフッ素樹脂であるが、これに限定されず、例えば、アクリル系樹脂、ウレタン系樹脂であってもよい。 The surface protective layer 11 plays a role of smoothing the sliding of the user's finger when operating the screen of a smartphone, tablet PC, or the like. Further, the surface protective layer 11 is not limited to this, and may have functions such as scratch resistance and antifouling property. From these viewpoints, the material for forming the surface protective layer 11 is preferably a fluororesin, but is not limited to this, and may be, for example, an acrylic resin or a urethane resin.

基材層12は、粘着剤層13を支持し、また、粘着フィルム10の用途に応じた機能、例えば、被着体への追従性や耐傷性等を付与する。基材層12の厚みは、特に限定されないが、例えば、50μm以上200μm以下である。 The base material layer 12 supports the pressure-sensitive adhesive layer 13 and also imparts functions according to the use of the pressure-sensitive adhesive film 10, such as followability to an adherend and scratch resistance. The thickness of the base material layer 12 is not particularly limited, but is, for example, 50 μm or more and 200 μm or less.

基材層12の形成材料は、被着体への形状追従性の観点から、柔軟性に優れるポリウレタンであるが、これに限定されず他の樹脂であってもよい。基材層12は、1つの材料からなる単層構造を有してもよいし、異なる複数の層が積層された構造を有してもよい。 The material for forming the base material layer 12 is polyurethane having excellent flexibility from the viewpoint of shape-following property to the adherend, but the material is not limited to this and may be another resin. The base material layer 12 may have a single-layer structure made of one material, or may have a structure in which a plurality of different layers are laminated.

粘着剤層13は、粘着フィルム10を被着体に貼付させることができれば、特に限定されないが、被着体への貼付後においても剥離可能な再剥離性を有することが好ましい。粘着剤層13を形成する粘着剤は、特に限定されないが、例えば、アクリル系粘着剤、ゴム系粘着剤、シリコーン系粘着剤、ポリウレタン系粘着剤、ポリエステル系粘着剤等が挙げられる。それらの粘着剤は、1種を単独で用いても2種以上を併用してもよい。 The pressure-sensitive adhesive layer 13 is not particularly limited as long as the pressure-sensitive adhesive film 10 can be attached to the adherend, but it is preferable that the pressure-sensitive adhesive layer 13 has a re-peelable property that can be peeled off even after the adhesive film 10 is attached to the adherend. The pressure-sensitive adhesive forming the pressure-sensitive adhesive layer 13 is not particularly limited, and examples thereof include an acrylic pressure-sensitive adhesive, a rubber-based pressure-sensitive adhesive, a silicone-based pressure-sensitive adhesive, a polyurethane-based pressure-sensitive adhesive, and a polyester-based pressure-sensitive adhesive. These adhesives may be used alone or in combination of two or more.

剥離ライナー14は、粘着剤層13に剥離可能に配置されている。剥離ライナー14の形成材料は、特に限定されないが、例えば、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート等のポリエステルフィルム、ポリプロピレンやポリエチレン等のポリオレフィンフィルムなどのプラスチックフィルム;上質紙、グラシン紙、クラフト紙、クレーコート紙などの紙、これらの紙をポリエチレンラミネートしたポリエチレンラミネート紙、これらの紙をポリプロピレンラミネートしたポリプロピレンラミネート紙等が挙げられる。 The release liner 14 is removably arranged on the pressure-sensitive adhesive layer 13. The material for forming the release liner 14 is not particularly limited, and is, for example, a polyester film such as polyethylene terephthalate, polybutylene terephthalate, or polyethylene naphthalate, or a plastic film such as a polyolefin film such as polypropylene or polyethylene; high-quality paper, glassin paper, or kraft paper. , Paper such as clay-coated paper, polyethylene-laminated paper obtained by polyethylene-laminating these papers, polypropylene-laminated paper obtained by polypropylene-laminating these papers, and the like.

次に、粘着フィルム10の作製方法を述べる。 Next, a method for producing the adhesive film 10 will be described.

図2に示すように、本実施形態の作製方法では、まず、基材層12が、両面12A、12Bに、PET(ポリエチレンテレフタレート)フィルム100、110を直接配置された状態で準備される。 As shown in FIG. 2, in the production method of the present embodiment, first, the base material layer 12 is prepared in a state where the PET (polyethylene terephthalate) films 100 and 110 are directly arranged on both sides 12A and 12B.

PETフィルム100、110のそれぞれにおいて、基材層12に接する面は、平滑であり、例えば、基材層12に接する面で算術平均粗さRaが5nm以上30nm以下であり、その最大山高さRpは100nm以上500nm以下である。算術平均粗さRaおよび最大山高さRpは、JIS B0601:2013に規定された方法で測定される値である。 In each of the PET films 100 and 110, the surface in contact with the base material layer 12 is smooth. For example, the surface in contact with the base material layer 12 has an arithmetic average roughness Ra of 5 nm or more and 30 nm or less, and its maximum mountain height Rp. Is 100 nm or more and 500 nm or less. The arithmetic mean roughness Ra and the maximum mountain height Rp are values measured by the method specified in JIS B0601: 2013.

PETフィルム100、110は、次の工程が行われる前に剥がされ、表面の平滑化された基材層12だけが、次の工程に用いられる。 The PET films 100 and 110 are peeled off before the next step is performed, and only the surface smoothed base material layer 12 is used in the next step.

図3に示すように、表面の平滑化された基材層12では、次の工程で、面12Aに表面保護層11が設けられる。表面保護層11をどのようにして形成するかは、特に限定されないが、例えば、表面保護層11の主要な構成要素である例えばフッ素樹脂等の樹脂を含む塗工液を、面12Aに塗工して塗膜を形成し、これを硬化させることによって、表面保護層11は形成される。 As shown in FIG. 3, in the base material layer 12 having a smoothed surface, the surface protective layer 11 is provided on the surface 12A in the next step. How the surface protective layer 11 is formed is not particularly limited, but for example, a coating liquid containing a resin such as a fluororesin, which is a main component of the surface protective layer 11, is applied to the surface 12A. The surface protective layer 11 is formed by forming a coating film and curing the coating film.

また、図4に示すように、表面保護層11には、PETフィルム120が直接配置される。PETフィルム120は、表面保護層11に直接配置されれば、いつ配置されるかは特に限定されず、例えば、表面保護層11を形成する塗膜の硬化後であってもよいが、好ましくは、塗膜が完全に硬化する前の柔らかい状態のとき、表面保護層11にPETフィルム120が直接配置される。こうすることによって、PETフィルム120の平滑性が、表面保護層11へ、より転写され易くなる。PETフィルム120において、表面保護層11に接する面の算術平均粗さRaおよび最大山高さRpは、上述のPETフィルム100、110における値と同様である。 Further, as shown in FIG. 4, the PET film 120 is directly arranged on the surface protective layer 11. If the PET film 120 is directly arranged on the surface protective layer 11, the time when the PET film 120 is arranged is not particularly limited, and may be, for example, after the coating film forming the surface protective layer 11 is cured, but it is preferable. When the coating film is in a soft state before it is completely cured, the PET film 120 is directly arranged on the surface protective layer 11. By doing so, the smoothness of the PET film 120 is more easily transferred to the surface protective layer 11. In the PET film 120, the arithmetic mean roughness Ra and the maximum mountain height Rp of the surface in contact with the surface protective layer 11 are the same as the values in the PET films 100 and 110 described above.

図5に示すように、PETフィルム120の配置後、粘着剤層13および剥離ライナー14が設けられ、粘着フィルム10ができる。 As shown in FIG. 5, after the PET film 120 is arranged, the pressure-sensitive adhesive layer 13 and the release liner 14 are provided to form the pressure-sensitive adhesive film 10.

粘着剤層13および剥離ライナー14を基材層12に対しどのように積層するかは、特に限定されず、例えば、基材層12の面12Bに粘着剤を塗布して粘着剤層13を形成した後、粘着剤層13に剥離ライナー14を積層してもよいし、粘着剤層13と剥離ライナー14との積層体を予め準備しておき、それを基材層12の面12Bに貼り合せてもよい。 How the pressure-sensitive adhesive layer 13 and the release liner 14 are laminated on the base material layer 12 is not particularly limited, and for example, the pressure-sensitive adhesive is applied to the surface 12B of the base material layer 12 to form the pressure-sensitive adhesive layer 13. After that, the release liner 14 may be laminated on the pressure-sensitive adhesive layer 13, or a laminate of the pressure-sensitive adhesive layer 13 and the release liner 14 may be prepared in advance and bonded to the surface 12B of the base material layer 12. You may.

粘着フィルム10の作製後、PETフィルム120は剥がされる。PETフィルム120をいつ剥がすかは、特に限定されず、例えば、粘着剤層13および剥離ライナー14を設ける前に剥がしてもよいが、本実施形態のように、粘着フィルム10の作製後に剥がすことによって、作製工程の間、表面保護層11を保護できる。 After producing the adhesive film 10, the PET film 120 is peeled off. When the PET film 120 is peeled off is not particularly limited. For example, the PET film 120 may be peeled off before the pressure-sensitive adhesive layer 13 and the release liner 14 are provided, but by peeling off the PET film 120 after the preparation of the pressure-sensitive adhesive film 10 as in the present embodiment. , The surface protective layer 11 can be protected during the manufacturing process.

次に、本実施形態の作用効果を述べる。 Next, the action and effect of this embodiment will be described.

本実施形態では、平滑度が他の樹脂フィルムに比べて比較的高いPETフィルム100が基材層12の面12Aに直接配置され、これによって面12Aが平滑化されるため、そこに設けられる表面保護層11も平滑となり易い。さらに、表面保護層11に対してもPETフィルム120が直接配置されるため、表面保護層11がより平滑になり易い。 In the present embodiment, the PET film 100 having a relatively high smoothness as compared with other resin films is directly arranged on the surface 12A of the base material layer 12, which smoothes the surface 12A, so that the surface provided there. The protective layer 11 also tends to be smooth. Further, since the PET film 120 is directly arranged on the surface protective layer 11, the surface protective layer 11 tends to be smoother.

このように、本実施形態によれば、表面保護層11が平滑になり易いため、粘着フィルム10のグロス低下が抑制され、高級感が損なわれ難い。 As described above, according to the present embodiment, since the surface protective layer 11 tends to be smooth, the gloss reduction of the adhesive film 10 is suppressed, and the high-class feeling is not easily impaired.

本実施形態では、基材層12は、表面保護層11の設けられる面12Aだけでなく、それと反対側の面12BでもPETフィルム110が直接配置された状態で準備され、面12Bも平滑化される。本実施形態と異なり面12Bが凸凹であると、粘着フィルム10を透過する光が面12Bで散乱し易いが、本実施形態では、面12Bは、PETフィルム110が直接配置されることによって平滑化されるため、面12Bでの光の散乱が抑制される。従って、粘着フィルム10の透明性を高めることができ、スマートフォンやタブレットPC等の画面の視認性を上げられる。 In the present embodiment, the base material layer 12 is prepared in a state where the PET film 110 is directly arranged not only on the surface 12A on which the surface protective layer 11 is provided but also on the surface 12B on the opposite side thereof, and the surface 12B is also smoothed. To. Unlike the present embodiment, if the surface 12B is uneven, the light transmitted through the adhesive film 10 is likely to be scattered on the surface 12B, but in the present embodiment, the surface 12B is smoothed by directly arranging the PET film 110. Therefore, the scattering of light on the surface 12B is suppressed. Therefore, the transparency of the adhesive film 10 can be improved, and the visibility of the screen of a smartphone, tablet PC, or the like can be improved.

本実施形態と異なり、表面保護層11に配置したPETフィルム120を剥がさず、そのままにしておく形態も本発明の範囲に含まれるが、本実施形態のように、PETフィルム120を剥がしておけば、粘着フィルム10の使用時にPETフィルム120を剥がす手間を省け、作業者の負担を軽減できる。 Unlike the present embodiment, a mode in which the PET film 120 arranged on the surface protective layer 11 is not peeled off and is left as it is is also included in the scope of the present invention, but if the PET film 120 is peeled off as in the present embodiment, It is possible to save the trouble of peeling off the PET film 120 when using the adhesive film 10 and reduce the burden on the operator.

基材層12をポリウレタンによって形成すれば、基材層12が高い柔軟性を有するため、粘着フィルム10を被着体に良好に追従させて貼付できる。 If the base material layer 12 is made of polyurethane, the base material layer 12 has high flexibility, so that the adhesive film 10 can be attached so as to follow the adherend well.

本発明は、上述した実施形態に限定されるものではなく、特許請求の範囲内で種々改変できる。 The present invention is not limited to the above-described embodiment, and various modifications can be made within the scope of the claims.

例えば、上記実施形態では、基材層12を、両面にPETフィルム100、110を配置した状態で準備したが、本発明は、この形態に限定されず、基材層を、一方の面だけにPETフィルムを配置した状態で準備する形態も、本発明の範囲に含まれる。 For example, in the above embodiment, the base material layer 12 is prepared with the PET films 100 and 110 arranged on both sides, but the present invention is not limited to this embodiment, and the base material layer is applied to only one side. The form of preparing the PET film in an arranged state is also included in the scope of the present invention.

また、上記実施形態では、基材層12に対して表面保護層11およびPETフィルム120が積層された後に、粘着剤層13および剥離ライナー14が設けられているが、本発明は、この形態に限定されず、基材層に対し、粘着剤層および剥離ライナーが設けられた後に、表面保護層およびPETフィルムが積層される形態も含む。 Further, in the above embodiment, the pressure-sensitive adhesive layer 13 and the release liner 14 are provided after the surface protective layer 11 and the PET film 120 are laminated on the base material layer 12, but the present invention relates to this embodiment. The present invention includes, but is not limited to, a form in which the surface protective layer and the PET film are laminated after the pressure-sensitive adhesive layer and the release liner are provided on the base material layer.

また、本発明によって作製される粘着フィルムは、上記実施形態のように、スマートフォンやタブレットPC等の画面に貼付される粘着フィルムに限定されず、例えば、自動車、バイク、鉄道車両、航空機、船舶等の移動体の内装材や外装材等に貼付される粘着フィルムであってもよい。 Further, the adhesive film produced by the present invention is not limited to the adhesive film attached to the screen of a smartphone, tablet PC, or the like as in the above embodiment, and is, for example, an automobile, a motorcycle, a railroad vehicle, an aircraft, a ship, or the like. It may be an adhesive film attached to the interior material, exterior material, or the like of the moving body.

10 粘着フィルム、
11 表面保護層、
12 基材層、
12A 基材層の一方の面、
12B 基材層の他方の面、
13 粘着剤層、
14 剥離ライナー、
100 基材層の一方の面に配置されるPETフィルム、
110 基材層の他方の面に配置されるPETフィルム、
120 表面保護層に配置されるPETフィルム。
10 Adhesive film,
11 Surface protective layer,
12 base material layer,
One surface of the 12A substrate layer,
The other surface of the 12B substrate layer,
13 Adhesive layer,
14 Peeling liner,
100 PET film placed on one side of the substrate layer,
110 PET film placed on the other side of the substrate layer,
120 PET film placed on the surface protective layer.

Claims (4)

表面保護層、基材層、および粘着剤層を積層方向にこの順序で有する粘着フィルムの作製方法であって、
前記基材層を、少なくとも一方の面にPETフィルムを直接配置した状態で準備し、
前記PETフィルムの剥離後、当該PETフィルムの配置されていた面に、前記表面保護層を設け、
当該表面保護層にPETフィルムを直接配置する、粘着フィルムの作製方法。
A method for producing an adhesive film having a surface protective layer, a base material layer, and an adhesive layer in this order in the stacking direction.
The base material layer is prepared with the PET film directly placed on at least one surface.
After the PET film was peeled off, the surface protective layer was provided on the surface on which the PET film was arranged.
A method for producing an adhesive film, in which a PET film is directly arranged on the surface protective layer.
前記基材層を、両面に前記PETフィルムを直接配置した状態で準備する、請求項1に記載の粘着フィルムの作製方法。 The method for producing an adhesive film according to claim 1, wherein the base material layer is prepared with the PET film directly arranged on both sides. 前記表面保護層に配置した前記PETフィルムを剥がす、請求項1または請求項2に記載の粘着フィルムの作製方法。 The method for producing an adhesive film according to claim 1 or 2, wherein the PET film arranged on the surface protective layer is peeled off. ポリウレタンによって形成された前記基材層を準備する、請求項1〜請求項3のうちのいずれか1つに記載の粘着フィルムの作製方法。 The method for producing an adhesive film according to any one of claims 1 to 3, wherein the base material layer formed of polyurethane is prepared.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010095560A (en) * 2008-10-14 2010-04-30 Nitto Denko Corp Protective adhesive sheet
JP2014224220A (en) * 2012-10-01 2014-12-04 日東電工株式会社 Coat layer composition
WO2018216113A1 (en) * 2017-05-23 2018-11-29 リンテック株式会社 Roll and method for manufacturing roll

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010095560A (en) * 2008-10-14 2010-04-30 Nitto Denko Corp Protective adhesive sheet
JP2014224220A (en) * 2012-10-01 2014-12-04 日東電工株式会社 Coat layer composition
WO2018216113A1 (en) * 2017-05-23 2018-11-29 リンテック株式会社 Roll and method for manufacturing roll

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