JP2020143336A - Method of coating surface of food utensil with hydrophobic polymer metal composite - Google Patents
Method of coating surface of food utensil with hydrophobic polymer metal composite Download PDFInfo
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- 235000013305 food Nutrition 0.000 title claims abstract description 88
- 239000002905 metal composite material Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000000576 coating method Methods 0.000 title claims abstract description 13
- 239000011248 coating agent Substances 0.000 title claims abstract description 12
- 229920001600 hydrophobic polymer Polymers 0.000 title abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 42
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910000765 intermetallic Inorganic materials 0.000 claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 25
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 21
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 21
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 21
- 238000005507 spraying Methods 0.000 claims abstract description 20
- 239000000725 suspension Substances 0.000 claims abstract description 12
- 239000007921 spray Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- 238000007711 solidification Methods 0.000 claims description 14
- 230000008023 solidification Effects 0.000 claims description 14
- 239000002131 composite material Substances 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 13
- 238000009501 film coating Methods 0.000 claims description 11
- 239000007888 film coating Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 239000000112 cooling gas Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 235000021168 barbecue Nutrition 0.000 claims description 3
- 235000014510 cooky Nutrition 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims 2
- 238000005245 sintering Methods 0.000 claims 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 238000010309 melting process Methods 0.000 claims 1
- 238000013021 overheating Methods 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 abstract description 7
- 239000004576 sand Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 238000007664 blowing Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000000181 anti-adherent effect Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000015220 hamburgers Nutrition 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000467686 Eschscholzia lobbii Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 229910001325 element alloy Inorganic materials 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
Landscapes
- Frying-Pans Or Fryers (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Cookers (AREA)
Abstract
【課題】食品器具の表面に疏水高分子金属複合皮膜を覆設する方法の提供【解決手段】本発明は、食品器具の表面に疏水高分子金属複合皮膜を覆設する方法に関する。その方法は、ポリテトラフルオロエチレン溶液とアルミベース金属間化合物粉末を撹拌して混ぜ合わせることで吹き付け懸濁液とし、且つ吹き付け懸濁液を食品器具の表面上に吹き付けることで、食品器具の表面に少なくとも一つのコーティングを形成させ、更に食品器具の表面のコーティングを加熱することで成型及び固化させて疏水高分子／金属複合皮膜とすることで、疏水高分子／金属複合皮膜の疏水性の接触角の増加により、高疏水性、高抗粘着性及び優れた表面の耐摩耗能力等の利点を獲得させる、というものである。【選択図】図４Kind Code: A1 The present invention relates to a method of covering a surface of a food utensil with a hydrophobic polymer-metal composite coating. The method comprises stirring and mixing a polytetrafluoroethylene solution and an aluminum-based intermetallic compound powder to form a spray suspension, and spraying the spray suspension onto the surface of the food appliance to obtain the surface of the food appliance. to form at least one coating on the surface of the food utensil, and heat the coating on the surface of the food utensil to mold and solidify to form a hydrophobic polymer/metal composite film, so that the hydrophobic contact of the hydrophobic polymer/metal composite film It is said that by increasing the angle, advantages such as high hydrophobicity, high anti-adhesion and excellent surface wear resistance ability are obtained. [Selection drawing] Fig. 4
Description
本発明は、食品器具の表面に疏水高分子金属複合皮膜を覆設する方法に関し、特に、有効的に食品器具の疏水性、抗粘着性を高め、且つ優れた表面の耐摩耗能力を有する食品器具表面処理の技術に関する。 The present invention relates to a method of lining a hydrophobic polymer metal composite film on the surface of a food utensil, and in particular, a food having an excellent surface abrasion resistance ability while effectively enhancing the water resistance and anti-adhesiveness of the food utensil. Regarding the technology of surface treatment of appliances.
デュポン社の生産するポリテトラフルオロエチレン塗料は、すでに、例えば炊飯釜や炒め鍋、ハンバーグ・ステーキプレート、フライパン、バーベキュープレート、オーブンプレート、トーストボックス、各種ケーキ型、各種クッキー型、ホットプレート、パイプレート及び食品用刀具等の、あらゆる食品器具上に応用されている。具体的な応用範囲としては、ポリテトラフルオロエチレン塗料を直接食品器具の搭載表面（食品を搭載する内面や底面、または食品用刀具の刀面等）に吹き付けることで、食品器具の表面に不粘着層を形成させるものである。この方法によって、ポリテトラフルオロエチレンを塗布された食品器具の表面は不粘着特性を得る。またこの方法においては、ポリテトラフルオロエチレンにより食品器具の清浄がし易い、粘着物が付きにくいという効果がもたらされるが、ポリテトラフルオロエチレンを塗布された食品器具の不粘着層を有する表面は、耐摩耗能力に優れず、長期にわたる使用や不適切な使用、または過度の清浄と言った原因から不粘着層を損傷させてしまい、ないしは不粘着層の雑屑や化学成分等がかき傷や裂け目から滲み出て食品内に混ざり、食品の安全に対する懸念を生む状況となっている。 Dupont's polytetrafluoroethylene paints are already available, for example, in rice cookers, stir-fry pans, hamburger steak plates, frying pans, barbecue plates, oven plates, toast boxes, various cake molds, various cookie molds, hot plates, and pipe rates. And it is applied to all food utensils such as food swords. As a specific application range, the polytetrafluoroethylene paint is directly sprayed on the mounting surface of the food appliance (the inner surface or bottom surface on which the food is mounted, or the sword surface of the food sword tool, etc.) to prevent adhesion to the surface of the food appliance. It forms a layer. By this method, the surface of the food utensil coated with polytetrafluoroethylene obtains non-adhesive properties. Further, in this method, the polytetrafluoroethylene has the effect of making it easy to clean the food utensil and making it difficult for sticky substances to adhere to it. However, the surface of the food utensil coated with polytetrafluoroethylene having a non-adhesive layer is It has poor wear resistance and damages the non-adhesive layer due to long-term use, improper use, or excessive cleaning, or the non-adhesive layer's dust and chemical components are scratched or crevices. It oozes out of the food and mixes with the food, creating concerns about food safety.
また、アルミベース金属間化合物の構造は独特の性質を有しており、異なる多元系合金のアルミベース金属間化合物材料は、例えば水素吸蔵材、遮熱コーティング，選択性光線吸収器、化学反応器、抗粘着コーティング、触媒剤粒子、及び強度の低い合金を強化する分散型強度粒子といった部分に広く応用されている。アルミニウム−銅−鉄の三元系合金は成分や熱力学の条件の違いにより、それぞれ結晶相、アルミベース金属間化合物、非結晶相を得る。アルミニウム系のアルミベース金属間化合物、例えばアルミニウム−銅−鉄が含む三つの元素はいずれも金属であるため、導電性に優れているが、ただこの三つの元素により組成されるアルミベース金属間化合物構造は、導電率がおよそ金属の一万分の一であり、ひいては成分が類似する非晶質よりも低く、また完美で整ったアルミベース金属間化合物構造であればあるほど、導電率は低くなり、丁度金属とは相反するものとなる。言い換えると、アルミベース金属間化合物構造は、金属元素により構成されるものの陶磁に類する特性を呈しており、一般的な金属及び非晶金属とは大きく異なっている。 In addition, the structure of the aluminum-based intermetallic compound has unique properties, and the aluminum-based intermetallic compound material of different multi-element alloys is, for example, a hydrogen storage material, a heat shield coating, a selective light absorber, and a chemical reactor. , Anti-adhesive coatings, catalyst particles, and dispersed strength particles that reinforce low strength alloys. The aluminum-copper-iron ternary alloy obtains a crystalline phase, an aluminum-based intermetallic compound, and a non-crystalline phase, respectively, depending on the difference in composition and thermodynamic conditions. Aluminum-based aluminum-based intermetallic compounds, for example, the three elements contained in aluminum-copper-iron are all metals, so they are excellent in conductivity, but only aluminum-based intermetallic compounds composed of these three elements. The structure has a conductivity of about 1 / 10,000 of that of a metal, which is lower than that of an amorphous material having similar components, and the more beautiful and well-organized aluminum-based intermetallic compound structure, the lower the conductivity. Therefore, it is exactly the opposite of metal. In other words, the aluminum-based intermetallic compound structure is composed of metal elements but exhibits properties similar to those of ceramics, and is significantly different from general metals and amorphous metals.
更に、アルミニウム（Ａｌｘ）、銅（Ｃｕｙ）、鉄（Ｆｅｚ）系といったアルミベース金属間化合物構造の材料により製成された疏水合金膜は、高疏水性、高抗粘着性の特性を有しているので、疏水合金膜の接触角は１００度以上に達する。よって、食品器具の表面に覆設できる疏水合金膜の開発を通じて、ポリテトラフルオロエチレン（Ｐ．Ｔ．Ｆ．Ｅ）の使用上の疑問を払拭すること、或いはポリテトラフルオロエチレンと合わせることで食品器具表面の処理技術へと応用することは、関連業界による達成が待たれている。 Furthermore, aluminum (Al x), copper (Cu y), iron (Fe z) hydrophobic alloy film was made manufactured by a material of an aluminum-based intermetallic compound structures such systems, high hydrophobic, high anti-tack properties Since it has, the contact angle of the hydrophobic alloy film reaches 100 degrees or more. Therefore, through the development of a water alloy film that can be overlaid on the surface of food utensils, the doubts about the use of polytetrafluoroethylene (PTFE) can be dispelled, or by combining with polytetrafluoroethylene, food products can be used. The application to the surface treatment technology of equipment is expected to be achieved by related industries.
本発明の主な目的は、食品器具の表面に疏水高分子金属複合皮膜を覆設する方法を提供し、主には食品器具の搭載表面に疏水高分子金属複合皮膜を覆設することで、食品器具の搭載表面に高疏水性、高抗粘着性及び優れた表面の耐摩耗能力等の利点を獲得させることにある。本発明の主な目的を達成するための技術的手段は、ポリテトラフルオロエチレン溶液とアルミベース金属間化合物粉末を撹拌して混ぜ合わせることで吹き付け懸濁液とし、且つ吹き付け懸濁液を食品器具の表面上に吹き付けることで、食品器具の表面に少なくとも一つのコーティングを形成させ、更に食品器具の搭載表面のコーティングを加熱することで成型及び固化させて一層の疏水高分子／金属複合皮膜とすることである。 A main object of the present invention is to provide a method of covering a surface of a food utensil with a hydrophobic polymer metal composite film, and mainly by covering a surface on which the food utensil is mounted with a hydrophobic polymer metal composite film. The purpose is to obtain advantages such as high water resistance, high anti-adhesiveness, and excellent surface abrasion resistance on the mounting surface of food utensils. The technical means for achieving the main object of the present invention is to make a spray suspension by stirring and mixing a polytetrafluoroethylene solution and an aluminum-based intermetallic compound powder, and the spray suspension is used as a food appliance. By spraying on the surface of the food utensil, at least one coating is formed on the surface of the food utensil, and by heating the coating on the mounting surface of the food utensil, it is molded and solidified to form a further water-stained polymer / metal composite film. That is.
図１から図５に示すように、本発明の実施例は以下のステップを含む。
（ａ）材料の準備：加工を行おうとする食品器具１０、重量比４５〜９５％のポリテトラフルオロエチレン溶液及び重量比５〜５５％且つ平均粒径が０．５〜５０μｍのアルミベース金属間化合物（Ａｌ−ＴＭ）粉末２０を準備する。食品器具１０はアルミニウムメッキ鋼板やステンレス鋼等の金属板で製成される。また、ポリテトラフルオロエチレン溶液中のポリテトラフルオロエチレン溶液の濃度は６０％〜９５％とする。
（ｂ）撹拌混合：ポリテトラフルオロエチレン溶液とアルミベース金属間化合物粉末２０を撹拌して混ぜ合わせることで吹き付け懸濁液とする。温度摂氏２０〜４０°、回転毎分１０〜５０の条件下で撹拌する。
（ｃ）吹き付け：吹き付け懸濁液を食品器具１０の表面１１上に吹き付けることで少なくとも一つのコーティングを形成させる。
（ｄ）成型及び固化：食品器具１０の表面１１のコーティングを加熱することで成型及び固化させて疏水高分子／金属複合皮膜３０とする。
As shown in FIGS. 1 to 5, the embodiments of the present invention include the following steps.
(A) Material preparation: Food equipment 10 to be processed, a polytetrafluoroethylene solution having a weight ratio of 45 to 95%, and an aluminum-based metal having a weight ratio of 5 to 55% and an average particle size of 0.5 to 50 μm. Compound (Al-TM) powder 20 is prepared. The food appliance 10 is made of a metal plate such as an aluminum-plated steel plate or stainless steel. The concentration of the polytetrafluoroethylene solution in the polytetrafluoroethylene solution is 60% to 95%.
(B) Stirring and mixing: The polytetrafluoroethylene solution and the aluminum-based intermetallic compound powder 20 are stirred and mixed to form a spray suspension. Stir at a temperature of 20-40 degrees Celsius and a rotation of 10-50 / min.
(C) Spraying: The spraying suspension is sprayed onto the surface 11 of the food utensil 10 to form at least one coating.
(D) Molding and solidification: The coating on the surface 11 of the food utensil 10 is heated to mold and solidify to form a water-stained polymer / metal composite film 30.
図７は、本発明における疏水高分子／金属複合皮膜３０のサンプルの接近写真である。また、図８はこれを偏光顕微鏡で１００倍拡大した場合の写真である。 FIG. 7 is a close-up photograph of a sample of the water-stained polymer / metal composite film 30 in the present invention. Further, FIG. 8 is a photograph when this is magnified 100 times with a polarizing microscope.
本発明は材料の準備のステップの前に、更に前処理のステップと砂吹き（サンドブラスト）のステップを順に含むことができる。前処理のステップでは、事前に成型を行った食品器具１０を、摂氏３００〜４５０℃の高温のオーブンに入れ１０〜３０分間熱することで、食品器具１０の表面１１の油汚を除去する。砂吹きのステップでは、食品器具１０を砂吹き機に置き、砂吹き機に砂吹き原料を投入し、砂吹き圧力２〜５ｋｇ／ｃｍ２のもと、食品器具１０の表面１１に砂吹き処理を行い、食品器具１０の表面１１の平均粗さを２〜５μｍとする。食品器具１０の表面１１への砂吹きにより粗面化を行うことで、疏水高分子／金属複合皮膜３０が更に食品器具１０の表面１１に成型及び固化しやすくなる。 The present invention can further include a pretreatment step and a sandblasting step in order before the material preparation step. In the pretreatment step, the pre-molded food utensil 10 is placed in a high-temperature oven at 300 to 450 ° C. and heated for 10 to 30 minutes to remove oil stains on the surface 11 of the food utensil 10. In the sand blowing step, the food appliance 10 is placed in a sand blower, the sand blowing raw material is put into the sand blowing machine, and the surface 11 of the food appliance 10 is sand blown under a sand blowing pressure of 2 to 5 kg / cm 2. The average roughness of the surface 11 of the food utensil 10 is set to 2 to 5 μm. By roughening the surface 11 of the food utensil 10 by sand blowing, the water-stained polymer / metal composite film 30 can be more easily molded and solidified on the surface 11 of the food utensil 10.
前述の吹き付けのステップは更にプライマー吹き付けのステップ及び上塗吹き付けのステップを含み、成型及び固化のステップは更に第一成型及び固化のステップ及び第二成型及び固化のステップを含む。順序は、プライマー吹き付けのステップ、第一成型及び固化のステップ、上塗吹き付けのステップ、そして第二成型及び固化のステップとなる。 The spraying steps described above further include a primer spraying step and a topcoat spraying step, and the molding and solidification steps further include a first molding and solidification step and a second molding and solidification step. The sequence consists of a primer spraying step, a first molding and solidification step, a topcoat spraying step, and a second molding and solidification step.
プライマー吹き付けのステップでは、吹き付け懸濁液を吹き付け装置によって食品器具１０の表面１１に吹き付けることで、プライマー複合皮膜コーティングを形成させる（プライマー複合皮膜コーティングの厚さは１０〜１５μｍとする）。第一成型及び固化のステップでは、摂氏１００〜２５０℃の温度で１０〜３０分間の成型及び固化を行い、プライマー複合皮膜コーティングをプライマー３０ａへと成型及び固化させる。上塗吹き付けのステップでは、吹き付け懸濁液を吹き付け装置によってプライマー３０ａ上に吹き付けることで、上塗複合皮膜コーティングを形成させる（上塗複合皮膜コーティングの厚さは１５〜２０μｍとする）。第二成型及び固化のステップでは、摂氏３５０〜４００℃の温度で２０〜４０分間の成型及び固化を行い、上塗複合皮膜コーティングを疏水高分子／金属複合皮膜３０へと成型及び固化させる。 In the primer spraying step, the spray suspension is sprayed onto the surface 11 of the food utensil 10 by a spraying device to form a primer composite film coating (the thickness of the primer composite film coating is 10 to 15 μm). In the first molding and solidification step, molding and solidification are performed at a temperature of 100 to 250 ° C. for 10 to 30 minutes, and the primer composite film coating is molded and solidified into the primer 30a. In the topcoat spraying step, the spray suspension is sprayed onto the primer 30a by a spraying device to form a topcoat composite film coating (the thickness of the topcoat composite film coating is 15 to 20 μm). In the second molding and solidification step, molding and solidification are performed at a temperature of 350 to 400 degrees Celsius for 20 to 40 minutes, and the topcoat composite film coating is molded and solidified into a water-stained polymer / metal composite film 30.
具体的には、アルミベース金属間化合物粉末２０は、重量比５０〜７０％のアルミニウム、重量比２０〜３５％の銅、そして重量比１０〜２０％の鉄を含み、且つ溶融処理、及び粉砕と篩分け処理等のステップによりアルミベース金属間化合物粉末２０へと製成される。 Specifically, the aluminum-based intermetallic compound powder 20 contains aluminum having a weight ratio of 50 to 70%, copper having a weight ratio of 20 to 35%, and iron having a weight ratio of 10 to 20%, and is melt-treated and pulverized. The aluminum-based intermetallic compound powder 20 is produced by steps such as sieving.
上述の溶融処理は、市販の高周波による溶融器具、または真空且つ高速で稼働するアルミベース金属間化合物の粉体製造器具により行うことができ、以下のステップを含む。
（ｅ）まず含量が重量比５０〜７０％のアルミニウムを坩堝内に加え、高周波で完全に溶融するまで加熱する。
（ｆ）坩堝に重量比２０〜３０％の銅及び重量比１０〜２０％の鉄を順に加え、また坩堝中のアルミニウム溶液の温度を摂氏８００〜１３００℃にまで上げて保ち、銅及び鉄が融化して均等に混じり合うことで金属混合溶液へと溶融した後、この金属混合溶液を迅速に粉付して凝固させた後粉砕と篩分け処理を行うことで、上述のアルミベース金属間化合物粉末２０を製成する。
The above-mentioned melting treatment can be performed by a commercially available high-frequency melting device or a powder manufacturing device for an aluminum-based intermetallic compound operating in vacuum and at high speed, and includes the following steps.
(E) First, aluminum having a content of 50 to 70% by weight is added to the crucible and heated at a high frequency until it is completely melted.
(F) Copper having a weight ratio of 20 to 30% and iron having a weight ratio of 10 to 20% are added to the crucible in order, and the temperature of the aluminum solution in the crucible is kept raised to 800 to 1300 ° C. to remove copper and iron. After melting into a metal mixed solution by melting and mixing evenly, the above-mentioned aluminum-based intermetallic compound is subjected to pulverization and sieving after rapidly powdering and solidifying this metal mixed solution. The powder 20 is produced.
具体的には、上述の粉砕と篩分け処理は、同様に市販の高周波による溶融器具、または真空且つ高速で稼働するアルミベース金属間化合物の粉体製造器具により行うことができ、具体的な方法は以下のステップを含む。
（ｇ）金属混合溶液を、静置され且つ真空環境にある容器内に注ぎ入れる。
（ｈ）高速ノズルにより、容器から流出する金属混合溶液に冷却気体（窒素ガスやアルゴンガス）を吹き付け、金属混合溶液を、冷却気体により急速に冷却及び凝固されてそれぞれが異なる大きさへと分散したアルミベース金属間化合物粉末２０へとドリップする。
（ｉ）粒径の大きさごとに、アルミベース金属間化合物粉末２０を篩分ける。
Specifically, the above-mentioned pulverization and sieving treatment can be performed by a commercially available melting instrument using a high frequency or a powder manufacturing instrument for an aluminum-based intermetallic compound that operates in a vacuum and at high speed. Includes the following steps:
(G) The metal mixed solution is poured into a container that is allowed to stand and is in a vacuum environment.
(H) A cooling gas (nitrogen gas or argon gas) is sprayed onto the metal mixed solution flowing out of the container by a high-speed nozzle, and the metal mixed solution is rapidly cooled and solidified by the cooling gas and dispersed into different sizes. Drip into the aluminum-based intermetallic compound powder 20.
(I) The aluminum-based intermetallic compound powder 20 is sieved according to the size of the particle size.
分かりやすく言うと、上述の食品器具１０の表面１１は搭載表面を言う。図２に示す食品器具１０はトーストボックスであり、トーストボックスの搭載表面は内面及び底面である。また、図３に示す食品器具１０は波刃包丁であり、この波刃包丁の搭載表面は二つの刀面、及び刀背である。加えて、図４に示す食品器具１０はオーブンプレートであり、このオーブンプレートの搭載表面は底面となる。 To put it simply, the surface 11 of the food utensil 10 described above refers to the mounting surface. The food appliance 10 shown in FIG. 2 is a toast box, and the mounting surface of the toast box is an inner surface and a bottom surface. The food appliance 10 shown in FIG. 3 is a wave blade knife, and the mounting surface of the wave blade knife is two sword surfaces and a sword spine. In addition, the food utensil 10 shown in FIG. 4 is an oven plate, and the mounting surface of the oven plate is the bottom surface.
本発明による疏水高分子／金属複合皮膜３０が覆設される食品器具１０は、表面エネルギーが比較的低いため、比較的高い疏水性を有する。加熱、成型及び固化後に測定実験を行っているが、測定においては、本発明による疏水高分子／金属複合皮膜３０が覆設される食品器具１０の疏水性の接触角は１４０から１５０度に達し、図６に示すように、卓越した疏水性と抗粘着効果を有する。 The food appliance 10 on which the hydrophobic polymer / metal composite film 30 according to the present invention is covered has a relatively high hydrophobicity because the surface energy is relatively low. Measurement experiments are conducted after heating, molding, and solidification. In the measurement, the hydrophobic contact angle of the food appliance 10 on which the hydrophobic polymer / metal composite film 30 according to the present invention is covered reaches 140 to 150 degrees. , As shown in FIG. 6, has excellent water resistance and anti-adhesive effect.
本発明による疏水高分子／金属複合皮膜３０が覆設される食品器具１０は、耐摩耗の測定実験（ＧＢ／Ｔ ３２３８９−２０１５耐摩耗試験を参考）を行っているが、測定においては、元々の基準であるポリテトラフルオロエチレンのコーティングのみの１０００回から７０００回以上へと大幅に上昇しており、本発明は卓越した耐摩耗性を有することが分かった。本発明ではそれぞれ異なる重量比のアルミベース金属間化合物粉末２０が添加されるものに対し耐摩耗回数の比較実験を行ったが、アルミベース金属間化合物粉末２０の重量比が０％の時、耐摩耗回数は１０００回であり、アルミベース金属間化合物粉末２０の重量比がそれぞれ５％、１０％、１５％そして２０％の時、耐摩耗回数はそれぞれ３５００回、３８００回、６０００回そして７５００回であった。よって、アルミベース金属間化合物粉末２０の重量比が大きくなるにつれ、耐摩耗回数も多くなることが分かる。 The food utensil 10 on which the water-stained polymer / metal composite film 30 according to the present invention is covered has been subjected to an abrasion resistance measurement experiment (refer to the GB / T 32389-2015 abrasion resistance test), but the measurement was originally performed. It was found that the present invention has excellent wear resistance, as it has increased significantly from 1000 times to 7000 times or more only for the coating of polytetrafluoroethylene, which is the standard of the above. In the present invention, a comparative experiment of the number of times of wear resistance was carried out for the aluminum-based intermetallic compound powder 20 to which different weight ratios were added. When the weight ratio of the aluminum-based intermetallic compound powder 20 was 0%, the resistance was reduced. The number of times of wear is 1000 times, and when the weight ratio of the aluminum-based intermetallic compound powder 20 is 5%, 10%, 15% and 20%, respectively, the number of times of wear resistance is 3500 times, 3800 times, 6000 times and 7500 times, respectively. Met. Therefore, it can be seen that as the weight ratio of the aluminum-based intermetallic compound powder 20 increases, the number of times of wear resistance also increases.
本発明による疏水高分子／金属複合皮膜３０が覆設される食品器具１０は、５％の塩化 ナトリウム溶液（ＮＡＣＬ）ミストによる防腐蝕測定実験（ＧＢ／Ｔ ３２３８９−２０１５耐塩性試験を参考）を行っており、５％のＮＡＣＬミストによる試験の時間が４８時間から１７５時間に伸びていることから、本発明が卓越した対塩霧防腐蝕能力を有することが分かっている。 The food appliance 10 on which the water polymer / metal composite film 30 according to the present invention is covered is subjected to an anticorrosion measurement experiment using a 5% sodium chloride solution (NACL) mist (see GB / T 32389-2015 salt tolerance test). It is known that the present invention has excellent anti-salt fog anticorrosion ability, as the test time with 5% NaCl mist has been extended from 48 hours to 175 hours.
本発明による疏水高分子／金属複合皮膜３０が覆設される食品器具１０は、関連する食品安全検査の実施を台湾標準（ＳＧＳ）に委託しており、検査により、本発明は中国大陸の食品安全法である、１）ＧＢ ４８０６．１−２０１６（食品安全国家標準食品接触材料及製品通用安全要求）、２）ＧＢ ４８０６．１０−２０１６（食品安全国家標準 食品接触塗料及塗層）、そして３）ＧＢ ９６８５−２０１６（食品安全国家標準 食品接触材料及製品用添加剤使用標準）を満たしていることが分かった。 The food appliance 10 on which the water polymer / metal composite film 30 according to the present invention is covered has outsourced the implementation of the related food safety inspection to the Taiwan Standard (SGS), and by the inspection, the present invention is the food of mainland China. Safety Laws: 1) GB 4806.1-2016 (Food Safety National Standard Food Contact Materials and Product Safety Requirements), 2) GB 4806.1-2016 (Food Safety National Standard Food Contact Paints and Coating Layers), and 3) It was found that GB 9685-2016 (Food Safety National Standard Food Contact Materials and Product Additive Use Standard) was satisfied.
以上をまとめると、本発明は、従来のポリテトラフルオロエチレン（Ｐ．Ｔ．Ｆ．Ｅ）の使用上の懸念を払拭し、飲食店で広く使用されうるものであり、例えば疏水高分子／金属複合皮膜３０を食品器具１０（例えば炊飯釜、炒め鍋、ハンバーグ・ステーキプレート、フライパン、バーベキュープレート、オーブンプレート、トーストボックス、各種ケーキ型、各種クッキー型、ホットプレート、パイプレート及び食品用刀具等）の搭載表面１１に覆設することで、疏水高分子／金属複合皮膜３０の疏水性の接触角が１４０から１５０度に達することにより卓越した効果を達する。その効果は、主に以下の二点である。
１．卓越した疏水及び抗粘着等の特性に加え、有効的に抗粘着効果を持続させるので、食品器具に粘着物が付着して清浄しにくい状況が起こりにくくなる。
２．卓越した耐摩耗性及び対塩霧防腐蝕能力を有するため、食品器具表面が出力に優れないためにスクラッチが残るという状況を予防し、且つ食品器具の使用寿命を持続させることができる。
Summarizing the above, the present invention dispels concerns about the use of conventional polytetrafluoroethylene (PTFE) and can be widely used in restaurants, for example, a hydrophobic polymer / metal. The composite film 30 is applied to food utensils 10 (for example, rice cooker, frying pan, hamburger steak plate, frying pan, barbecue plate, oven plate, toast box, various cake molds, various cookie molds, hot plates, piperates, food swords, etc.) By lining it on the mounting surface 11 of the above, the water-repellent contact angle of the hydrophobic polymer / metal composite film 30 reaches 140 to 150 degrees, thereby achieving an excellent effect. The effects are mainly the following two points.
1. 1. In addition to excellent water-sucking and anti-adhesive properties, the anti-adhesive effect is effectively maintained, so that it is difficult for sticky substances to adhere to food utensils and make it difficult to clean.
2. 2. Since it has excellent wear resistance and anti-corrosion ability against salt fog, it is possible to prevent the situation where scratches remain due to the poor output of the surface of the food utensil, and to extend the service life of the food utensil.
１０ 食品器具
１１ 表面
２０ アルミベース金属間化合物粉末
３０ 疏水高分子／金属複合皮膜
３０ａ プライマー
10 Food equipment 11 Surface 20 Aluminum-based intermetallic compound powder 30 Sui water polymer / metal composite film 30a Primer
Claims (10)
前記材料の準備のステップでは、加工を行おうとする食品器具、特定量のポリテトラフルオロエチレン溶液及び特定量のアルミベース金属間化合物粉末を提供し、
前記撹拌混合のステップでは、特定量の前記ポリテトラフルオロエチレン溶液と特定量の前記アルミベース金属間化合物粉末を撹拌して混ぜ合わせることで吹き付け懸濁液とし、
前記吹き付けのステップでは、前記吹き付け懸濁液を前記食品器具の表面上に吹き付けることで、前記食品器具の前記表面に少なくとも一つのコーティングを形成させ、
前記成型及び固化のステップでは、前記食品器具の前記表面の前記コーティングを加熱することで固化させて疏水高分子／金属複合皮膜とすることを特徴とする食品器具の表面に疏水高分子金属複合皮膜を覆設する方法。 A method of laying a polymer metal composite film on the surface of a food utensil, which includes a step of preparing a material, a step of stirring and mixing, a step of spraying, and a step of molding and solidification.
In the material preparation step, the food utensil to be processed, a specific amount of polytetrafluoroethylene solution and a specific amount of aluminum-based intermetallic compound powder are provided.
In the stirring and mixing step, a specific amount of the polytetrafluoroethylene solution and a specific amount of the aluminum-based intermetallic compound powder are stirred and mixed to form a spray suspension.
In the spraying step, the spray suspension is sprayed onto the surface of the food utensil to form at least one coating on the surface of the food utensil.
In the molding and solidification step, the coating on the surface of the food appliance is solidified by heating to form a polymer / metal composite film on the surface of the food appliance. How to lay down.
前記プライマー吹き付けのステップでは、前記吹き付け懸濁液を前記食品器具の表面上に吹き付けることで、プライマー複合皮膜コーティングを形成させ、且つ摂氏１００〜２５０℃の温度で１０〜３０分間の焼結固化を行い、前記プライマー複合皮膜コーティングをプライマーへと焼結固化させ、
前記上塗吹き付けのステップでは、前記吹き付け懸濁液を前記プライマー上に吹き付けることで、上塗複合皮膜コーティングを形成させ、且つ摂氏３５０〜４００℃の温度で２０〜４０分間の焼結固化を行い、前記上塗複合皮膜コーティングを前記疏水高分子／金属複合皮膜へと焼結固化させることを特徴とする請求項１に記載の食品器具の表面に疏水高分子金属複合皮膜を覆設する方法。 The spraying step includes a primer spraying step and a topcoat spraying step.
In the primer spraying step, the sprayed suspension is sprayed onto the surface of the food appliance to form a primer composite film coating, and sintering and solidifying at a temperature of 100 to 250 ° C. for 10 to 30 minutes. The primer composite film coating is sintered and solidified into a primer.
In the topcoat spraying step, the sprayed suspension is sprayed onto the primer to form a topcoat composite film coating, and sintering and solidification is performed at a temperature of 350 to 400 ° C. for 20 to 40 minutes. The method according to claim 1, wherein the topcoat composite film is sintered and solidified into the water polymer / metal composite film, and the water polymer metal composite film is covered on the surface of the food appliance.
まず含量が重量比５０〜７０％の前記アルミニウムを坩堝に加え、高周波で前記アルミニウムが完全に溶融するまで加熱するステップと、
前記坩堝に重量比２０〜３０％の前記銅及び重量比１０〜２０％の前記鉄を順に加え、また前記坩堝中の過熱温度を摂氏１０００℃にまで上げて保ち、前記アルミニウム、前記銅及び前記鉄が均等に混じり合うことで金属混合溶液へと溶融した後、前記金属混合溶液を迅速に粉付して凝固させた後に前記粉砕と篩分け処理を行うことで、前記アルミベース金属間化合物粉末を製成するステップとを含むことを特徴とする請求項６に記載の食品器具の表面に疏水高分子金属複合皮膜を覆設する方法。 The melting process
First, the aluminum having a content of 50 to 70% by weight is added to the crucible and heated at a high frequency until the aluminum is completely melted.
The copper having a weight ratio of 20 to 30% and the iron having a weight ratio of 10 to 20% are added to the crucible in order, and the overheating temperature in the crucible is kept raised to 1000 ° C., and the aluminum, the copper and the said copper. After the iron is evenly mixed to melt into a metal mixed solution, the metal mixed solution is rapidly powdered and solidified, and then the pulverization and sieving treatment are performed to carry out the aluminum-based intermetallic compound powder. The method for lining a copper polymer metal composite film on the surface of a food appliance according to claim 6, further comprising a step of producing the same.
前記金属混合溶液を、静置され且つ真空環境にある容器内に注ぎ入れるステップと、
高速ノズルにより、前記容器から流出する前記金属混合溶液に冷却気体を吹き付け、前記金属混合溶液を、前記冷却気体により急速に冷却及び凝固されてそれぞれが異なる大きさへと分散した前記アルミベース金属間化合物粉末へとドリップするステップと、
粒径の大きさごとに、前記アルミベース金属間化合物粉末を篩分けるステップとを含むことを特徴とする請求項７に記載の食品器具の表面に疏水高分子金属複合皮膜を覆設する方法。 The crushing and sieving process
The step of pouring the metal mixed solution into a container in a stationary and vacuum environment,
A cooling gas is blown onto the metal mixed solution flowing out of the container by a high-speed nozzle, and the metal mixed solution is rapidly cooled and solidified by the cooling gas to be dispersed between the aluminum-based metals having different sizes. Steps to drip into compound powder,
The method according to claim 7, further comprising a step of sieving the aluminum-based intermetallic compound powder for each size of particle size, wherein a sluice polymer metal composite film is placed on the surface of the food appliance.
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| JP2005253600A (en) * | 2004-03-10 | 2005-09-22 | Kansai Electric Power Co Inc:The | Pot for electromagnetic cooker |
| JP2014521428A (en) * | 2011-07-25 | 2014-08-28 | セブ ソシエテ アノニム | Heating device with microstructured heat-stable coating and method of manufacturing such a device |
| JP2014531326A (en) * | 2011-08-03 | 2014-11-27 | マサチューセッツ インスティテュート オブ テクノロジー | Article for manipulating impinging liquid and method of manufacturing the same |
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