JP2020063350A5 - - Google Patents

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Publication number
JP2020063350A5
JP2020063350A5 JP2018195276A JP2018195276A JP2020063350A5 JP 2020063350 A5 JP2020063350 A5 JP 2020063350A5 JP 2018195276 A JP2018195276 A JP 2018195276A JP 2018195276 A JP2018195276 A JP 2018195276A JP 2020063350 A5 JP2020063350 A5 JP 2020063350A5
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Japan
Prior art keywords
cellulose
resin composition
producing
resin
composition according
Prior art date
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Pending
Application number
JP2018195276A
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Japanese (ja)
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JP2020063350A (en
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Priority to JP2018195276A priority Critical patent/JP2020063350A/en
Priority claimed from JP2018195276A external-priority patent/JP2020063350A/en
Publication of JP2020063350A publication Critical patent/JP2020063350A/en
Publication of JP2020063350A5 publication Critical patent/JP2020063350A5/ja
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Claims (7)

ポリオレフィン系樹脂と、セルロースと、界面活性剤とを含む樹脂組成物の製造方法であって
前記ポリオレフィン系樹脂は、酸変性されたポリオレフィン系樹脂を含み、
前記セルロースは、径が1μm未満のセルロースファイバー、径が1μm未満のセルロースウィスカー、又はこれらの混合物であり、
前記方法は、
水を主成分とする分散媒と、前記分散媒中に分散させたセルロースとを含むセルロース分散液を調製する第一の工程、
溶融状態にある熱可塑性樹脂中に前記セルロース分散液を添加し、溶融混練して混練物を得る第二の工程、及び
第二の工程で得られた混練物から分散媒を除去して樹脂組成物を得る第三の工程、
をこの順に含み、
第二の工程におけるセルロース分散液の添加を、前記溶融状態にある熱可塑性樹脂の温度における水の蒸気圧以上の圧力で実施する、樹脂組成物の製造方法。
A method for producing a resin composition containing a polyolefin resin, cellulose, and a surfactant .
The polyolefin-based resin contains an acid-modified polyolefin-based resin.
The cellulose is a cellulose fiber having a diameter of less than 1 μm, a cellulose whisker having a diameter of less than 1 μm, or a mixture thereof.
The method is
The first step of preparing a cellulose dispersion liquid containing a dispersion medium containing water as a main component and cellulose dispersed in the dispersion medium.
The second step of adding the cellulose dispersion liquid to the molten thermoplastic resin and melt-kneading to obtain a kneaded product, and removing the dispersion medium from the kneaded product obtained in the second step to form a resin composition. The third process of getting things,
In this order,
A method for producing a resin composition, wherein the addition of the cellulose dispersion liquid in the second step is carried out at a pressure equal to or higher than the vapor pressure of water at the temperature of the thermoplastic resin in the molten state.
樹脂組成物中のポリオレフィン系樹脂の比率が、樹脂組成物100質量%に対して50〜99質量%である、請求項1に記載の樹脂組成物の製造方法。 The method for producing a resin composition according to claim 1, wherein the ratio of the polyolefin-based resin in the resin composition is 50 to 99% by mass with respect to 100% by mass of the resin composition. 前記ポリオレフィン系樹脂が、ポリエチレン、ポリプロピレン、エチレンとα−オレフィンとの共重合体、エチレン−プロピレンターポリマー、及びこれらの混合物から選ばれる1種以上である、請求項1又は2に記載の樹脂組成物の製造方法。 The resin composition according to claim 1 or 2, wherein the polyolefin-based resin is at least one selected from polyethylene, polypropylene, a copolymer of ethylene and α-olefin, an ethylene-propylene terpolymer, and a mixture thereof. How to make things. 第一の工程で得られたセルロース分散液中のセルロースの比率が、セルロース分散液100質量%に対して1〜30質量%である、請求項1〜3のいずれか一項に記載の樹脂組成物の製造方法。 The resin composition according to any one of claims 1 to 3, wherein the ratio of cellulose in the cellulose dispersion obtained in the first step is 1 to 30% by mass with respect to 100% by mass of the cellulose dispersion. Manufacturing method of things. 第一の工程で得られた前記セルロース分散液中で前記セルロースが径1μm未満で分散している、請求項1〜4のいずれか一項に記載の樹脂組成物の製造方法。 The method for producing a resin composition according to any one of claims 1 to 4, wherein the cellulose is dispersed in the cellulose dispersion obtained in the first step with a diameter of less than 1 μm. 第三の工程における分散媒の除去の少なくとも一部が、減圧状態にて実施される、請求項1〜5のいずれか一項に記載の樹脂組成物の製造方法。 The method for producing a resin composition according to any one of claims 1 to 5, wherein at least a part of the removal of the dispersion medium in the third step is carried out under reduced pressure. 第二の工程及び第三の工程が、同一の押出機で引き続いて実施される請求項1〜6のいずれか一項に記載の樹脂組成物の製造方法。 The method for producing a resin composition according to any one of claims 1 to 6, wherein the second step and the third step are subsequently carried out in the same extruder.
JP2018195276A 2018-10-16 2018-10-16 Production method of cellulose-reinforced polyolefin resin composition Pending JP2020063350A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2018195276A JP2020063350A (en) 2018-10-16 2018-10-16 Production method of cellulose-reinforced polyolefin resin composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2018195276A JP2020063350A (en) 2018-10-16 2018-10-16 Production method of cellulose-reinforced polyolefin resin composition

Publications (2)

Publication Number Publication Date
JP2020063350A JP2020063350A (en) 2020-04-23
JP2020063350A5 true JP2020063350A5 (en) 2021-07-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP2018195276A Pending JP2020063350A (en) 2018-10-16 2018-10-16 Production method of cellulose-reinforced polyolefin resin composition

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7449323B2 (en) * 2022-03-24 2024-03-13 大王製紙株式会社 Fibrous cellulose composite resin
WO2023234157A1 (en) * 2022-06-01 2023-12-07 丸紅ケミックス株式会社 Methods for producing molded resin article and resin pellets containing environmentally degradable ingredient, device for forming resin pellets, and resin pellets

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018123150A1 (en) * 2016-12-28 2018-07-05 旭化成株式会社 Cellulose-containing resin composition and cellulosic ingredient
JP6422540B1 (en) * 2017-08-29 2018-11-14 旭化成株式会社 Method for producing cellulose reinforced resin composition

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