JP2019155260A - Exhaust gas processing device and exhaust gas processing method - Google Patents

Abstract

To provide an exhaust gas processing device and an exhaust gas processing method which perform adsorption/removal processing under adequate supply amounts of active charcoal so that a mercury concentration in exhaust gas is below a set value, even if an oxygen concentration and a hydrogen chloride concentration in the exhaust gas containing mercury vary.SOLUTION: The exhaust gas processing device comprises: a dust collector 3 that performs processing for removing exhaust gas from a furnace 1; an active charcoal supply device 5 that blows active charcoal to an exhaust gas flow path A through which exhaust gas is introduced from the furnace to the dust collector; an oxygen concentration meter 7 that measures an oxygen concentration in the exhaust gas and a hydrogen chloride concentration meter 8 that measure a hydrogen chloride concentration in the exhaust gas, at a downstream side of the furnace 1 and at an upstream side of the dust collector 3; and a control device 6 that controls supply amounts of active charcoal of the active carbon supply device. The control device 6 controls the supply amounts of active carbon on the basis of a predetermined correspondence relation between the measured value of the oxygen concentration, the measured value of the hydrogen chloride concentration and the supply amounts of active carbon so that a mercury concentration in the exhaust gas at the downstream side of the dust collector 3 is below a set value on the basis of the measured value of the oxygen concentration by the oxygen concentration meter 7 and the measured value of the hydrogen chloride concentration by the hydrogen chloride concentration meter 8.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a treatment apparatus and a treatment method for exhaust gas containing mercury discharged from various factories such as a waste incineration facility, a cement manufacturing factory, a thermal power plant, and a non-ferrous metal smelting factory.

  Mercury may be contained in exhaust gas discharged from cement kiln furnaces and non-ferrous metal smelting furnaces, and wastes containing mercury incinerated in waste incinerators, and are released directly into the atmosphere. It causes air pollution and becomes a problem. Therefore, it is required to remove mercury in the exhaust gas.

  Furthermore, the Minamata Convention on Mercury was adopted in 2013, and global movements to strengthen mercury management are in progress. After the convention enters into force, measures to reduce mercury emissions are being considered for facilities subject to mercury emission control. Facilities subject to mercury emission regulations include coal-fired power plants, coal-fired boilers, non-ferrous metal smelting facilities, waste incineration facilities, and cement manufacturing facilities. Under such circumstances, there is an increasing demand for a treatment method for efficiently removing mercury in exhaust gas discharged from these facilities.

  For example, as a general method for removing mercury in exhaust gas discharged from waste incinerators and boiler furnaces, bag filters that remove dust in exhaust gas, ducts that lead exhaust gas to an electric dust collector, bag filters, etc. On the other hand, Patent Document 1 discloses a method in which granular activated carbon is blown at an upstream position, mercury is adsorbed on the activated carbon, and the activated carbon adsorbed with mercury is collected together with dust by a bag filter or the like and removed from the exhaust gas. ing.

  In addition, a mixed powder prepared by previously mixing activated carbon with slaked lime to neutralize and remove the acidic gas in the exhaust gas is prepared, and this mixed powder is blown into the exhaust gas in the duct upstream of the bag filter. There is a case where a reaction product of slaked lime and activated carbon adsorbed with mercury are collected together with dust by a bag filter or the like and processed. Thus, after mercury in the exhaust gas is adsorbed by the activated carbon, it is collected and removed by a bag filter or the like.

JP2010-221085

  Depending on the type of waste incinerated in the incinerator and the type of raw material smelted in the cement kiln furnace or non-ferrous metal smelting furnace, fluctuations may occur that temporarily increase the mercury concentration in the exhaust gas. There is. In this case as well, in order to keep the mercury concentration in the exhaust gas discharged from the chimney low, it is necessary to constantly blow in a large amount of activated carbon to be blown into the duct, or mixed powder in which slaked lime and activated carbon are mixed in advance. When supplying into the duct, it is necessary to constantly blow a large amount of the mixed powder.

  Thus, if activated carbon or mixed powder is constantly supplied in a large amount into the duct assuming a temporarily high mercury concentration, the activated carbon and the mixed powder are excessively used in many time zones excluding the temporary time zone. As a result, the amount of activated carbon or mixed powder used is increased, and the exhaust gas treatment cost is increased, and the amount of collected dust is increased, resulting in an increase in the dust removal cost.

  In addition, mercury contained in exhaust gas discharged from waste incinerators, cement kiln furnaces, and non-ferrous metal smelting furnaces mainly has two forms, mercury chloride and metal mercury. The adsorption performance of activated carbon for mercury varies depending on the form of mercury in these exhaust gases and the components in the exhaust gases. Oxygen and hydrogen chloride are examples of components in exhaust gas that affect the mercury adsorption performance of activated carbon.

  In view of such circumstances, the present invention reliably adsorbs and removes mercury in exhaust gas, and can supply activated carbon with an appropriate amount of activated carbon even if the mercury concentration in the exhaust gas fluctuates. It is an object of the present invention to provide an exhaust gas treatment apparatus and an exhaust gas treatment method that can appropriately perform adsorption removal treatment with activated carbon in response to fluctuations in the oxygen concentration and hydrogen chloride.

  According to the present invention, the above-described problems are solved by the following exhaust gas treatment apparatus and the method thereof.

[Exhaust gas treatment equipment]
The exhaust gas treatment apparatus of the present invention is configured as in the following first invention, second invention and third invention, and the above-mentioned problems can be solved by any of them. Here, the activated carbon supply amount (mg / Nm ³ ) is determined as the activated carbon blowing weight with respect to the treated exhaust gas flow rate.

<First invention>
In an exhaust gas treatment apparatus comprising: a dust collector that removes exhaust gas containing mercury discharged from a furnace; and an activated carbon supply device that blows activated carbon into an exhaust gas passage that guides the exhaust gas from the furnace to the dust collector.
The oxygen concentration meter that measures the oxygen concentration in the exhaust gas, the hydrogen chloride concentration meter that measures the hydrogen chloride concentration in the exhaust gas, and the activated carbon supply amount of the activated carbon supply device on the downstream side of the furnace and upstream of the dust collector A control device for controlling,
Based on the oxygen concentration measurement value by the oxygen concentration meter and the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, the control device makes the downstream mercury concentration in the exhaust gas downstream of the dust collector less than the set value. An exhaust gas treatment apparatus that controls an activated carbon supply amount based on a predetermined correspondence relationship between an oxygen concentration measurement value, a hydrogen chloride concentration measurement value, and an activated carbon supply amount.

<Second invention>
In an exhaust gas treatment apparatus comprising: a dust collector that removes exhaust gas containing mercury discharged from a furnace; and an activated carbon supply device that blows activated carbon into an exhaust gas passage that guides the exhaust gas from the furnace to the dust collector.
The oxygen concentration meter that measures the oxygen concentration in the exhaust gas, the hydrogen chloride concentration meter that measures the hydrogen chloride concentration in the exhaust gas, and the upstream mercury concentration in the exhaust gas at the downstream side of the furnace and the upstream side of the dust collector. Equipped with an upstream mercury concentration meter to measure and a control device to control the activated carbon supply amount of the activated carbon supply device,
Based on the oxygen concentration measurement value by the oxygen concentration meter, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, and the upstream mercury concentration measurement value by the upstream mercury concentration meter, the control device An exhaust gas treatment apparatus, wherein the activated carbon supply amount is controlled so that the downstream mercury concentration is lower than a set value.

<Third invention>
In an exhaust gas treatment apparatus comprising: a dust collector that removes exhaust gas containing mercury discharged from a furnace; and an activated carbon supply device that blows activated carbon into an exhaust gas passage that guides the exhaust gas from the furnace to the dust collector.
The oxygen concentration meter that measures the oxygen concentration in the exhaust gas, the hydrogen chloride concentration meter that measures the hydrogen chloride concentration in the exhaust gas, and the upstream mercury concentration in the exhaust gas at the downstream side of the furnace and the upstream side of the dust collector. Equipped with an upstream mercury concentration meter to measure, a downstream mercury concentration meter to measure the mercury concentration in the exhaust gas downstream of the dust collector, and a control device to control the activated carbon supply amount of the activated carbon supply device,
The control device consists of an oxygen concentration measurement value by an oxygen concentration meter, a hydrogen chloride concentration measurement value by a hydrogen chloride concentration meter, an upstream mercury concentration measurement value by an upstream mercury concentration meter, and a downstream mercury concentration measurement value by a downstream mercury concentration meter. And the activated carbon supply amount is controlled so that the downstream mercury concentration in the exhaust gas downstream of the dust collector is not more than a set value.

  In 1st thru | or 3rd invention, it is preferable that a control apparatus controls so that activated carbon supply amount may be maintained more than predetermined minimum value. By such control, an activated carbon adsorption layer is always formed on the bag filter of the dust collector, so that the adsorption removal action by the previously formed adsorption layer and the adsorption removal action by the activated carbon blown at that time Thus, mercury can be adsorbed and removed quickly and reliably, and the mercury concentration of the exhaust gas after dust collection can be made sufficiently low. In the second or third invention, when the mercury concentration in the exhaust gas is lower than a predetermined value, it is preferable to control the supply amount of the activated carbon so as to keep the predetermined minimum value. An adsorption layer of activated carbon is always formed on the bag filter of the dust collector, and even when exhaust gas containing mercury at a concentration higher than the predetermined value is discharged, adsorption by the adsorption layer formed in advance is performed. Mercury can be adsorbed and removed quickly and reliably by the removal action and the adsorption removal action by activated carbon blown at that time, and the mercury concentration of the exhaust gas after dust collection can be made sufficiently low.

  In the second or third aspect of the invention, when the upstream mercury concentration measurement value by the upstream mercury concentration meter or the downstream mercury concentration measurement value by the downstream mercury concentration meter is equal to or greater than the predetermined mercury concentration, It is preferable to control the supply amount so as to maintain a predetermined maximum value. Although the mercury concentration is not so high as a time average, when the mercury concentration suddenly increases temporarily, if a large amount of activated carbon is supplied in accordance with this high mercury concentration, the activated carbon will be excessively excessive over the subsequent time. The result will be to supply. Such excessive supply can be prevented by controlling the supply amount of the activated carbon so as to keep the predetermined maximum value.

  Further, in the second or third invention, regarding the increase from the minimum value to the maximum value of the activated carbon supply amount, the control device is configured such that the mercury concentration measurement value in the exhaust gas is zero or less than a measurable minimum value. In the range until the first predetermined mercury concentration is reached, activated carbon is supplied based on the predetermined minimum activated carbon supply amount, and after the mercury concentration measurement value reaches the first predetermined mercury concentration, the mercury As the concentration measurement value increases, the activated carbon supply amount is increased linearly from the predetermined minimum value, and when the mercury concentration measurement value reaches the second predetermined mercury concentration, the activated carbon supply amount is supplied to the predetermined maximum value. After the mercury concentration measurement value reaches the second predetermined mercury concentration, the activated carbon supply amount can be kept constant at the predetermined maximum value with respect to the increase in the mercury concentration measurement value.

  Further, in the second or third invention, with respect to the increase from the minimum value to the maximum value of the activated carbon supply amount, the control device determines that the measured value of mercury concentration in the exhaust gas is zero or less than a measurable minimum value. In the range until the first predetermined mercury concentration is reached, activated carbon is supplied based on the amount of activated carbon supplied as the first supply amount at a predetermined minimum value, and the measured mercury concentration is the above-mentioned first predetermined mercury concentration. When the concentration is reached, the activated carbon supply amount is increased stepwise to the predetermined second supply amount, and the activated carbon supply amount is increased within the range until the measured mercury concentration reaches the second predetermined mercury concentration. The mercury concentration measurement so that the activated carbon supply amount is increased to the predetermined third supply amount when the mercury concentration measurement value reaches the second predetermined mercury concentration. The activated carbon supply can be increased stepwise as the Repeating, after increasing the activated carbon supply amount to a predetermined maximum value may also be to keep the activated carbon supply amount constant at its predetermined maximum value with an increase in mercury density measurements.

  As described above, by increasing the activated carbon supply amount from the minimum value to the maximum value based on the measured value of mercury concentration in the exhaust gas, the activated carbon supply can be performed without causing any trouble in the supply amount adjustment mechanism of the activated carbon supply device. The amount can be controlled smoothly.

[Exhaust gas treatment method]
The exhaust gas treatment method of the present invention is configured as in the following fourth, fifth and sixth inventions, and the above-described problems can be solved by any of them.

<Fourth Invention>
In the exhaust gas treatment method in which the exhaust gas exhausted from the furnace is dust-removed by the dust collector, and activated carbon is blown from the activated carbon supply device to the exhaust gas passage that leads the exhaust gas from the furnace to the dust collector.
An oxygen concentration measurement process that measures the oxygen concentration in the exhaust gas with an oximeter downstream of the furnace and upstream of the dust collector, and the concentration of hydrogen chloride in the exhaust gas downstream of the furnace and upstream of the dust collector A hydrogen chloride measurement process for measuring the activated carbon supply with a hydrogen chloride concentration meter, and a control process for controlling the activated carbon supply amount of the activated carbon supply apparatus with a control device,
In the control step, the downstream mercury concentration in the exhaust gas on the downstream side of the dust collector is set to be lower than the set value based on the measured oxygen concentration value by the oxygen concentration meter and the measured hydrogen chloride concentration value by the hydrogen chloride concentration meter. An exhaust gas treatment method characterized by controlling an activated carbon supply amount.

<Fifth invention>
In the exhaust gas treatment method in which the exhaust gas exhausted from the furnace is dust-removed by the dust collector, and activated carbon is blown from the activated carbon supply device to the exhaust gas passage that leads the exhaust gas from the furnace to the dust collector.
An oxygen concentration measurement process that measures the oxygen concentration in the exhaust gas with an oximeter downstream of the furnace and upstream of the dust collector, and the concentration of hydrogen chloride in the exhaust gas downstream of the furnace and upstream of the dust collector Of measuring hydrogen chloride concentration with a hydrogen chloride concentration meter and upstream mercury concentration measurement step with an upstream mercury concentration meter for measuring the upstream mercury concentration in the exhaust gas downstream of the furnace and upstream of the dust collector And a control process for controlling the activated carbon supply amount of the activated carbon supply device by the control device,
In the control process, in the exhaust gas at the downstream side of the dust collector, based on the oxygen concentration measurement value by the oxygen concentration meter, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, and the upstream mercury concentration measurement value by the upstream mercury concentration meter. An exhaust gas treatment method, wherein the activated carbon supply amount is controlled so that the downstream mercury concentration of the gas is not more than a set value.

<Sixth Invention>
In the exhaust gas treatment method in which the exhaust gas exhausted from the furnace is dust-removed by the dust collector, and activated carbon is blown from the activated carbon supply device to the exhaust gas passage that leads the exhaust gas from the furnace to the dust collector.
An oxygen concentration measurement process that measures the oxygen concentration in the exhaust gas with an oximeter downstream of the furnace and upstream of the dust collector, and the concentration of hydrogen chloride in the exhaust gas downstream of the furnace and upstream of the dust collector A hydrogen chloride concentration measuring step for measuring the mercury concentration in the exhaust gas on the downstream side of the furnace and upstream of the dust collector, and an upstream mercury concentration measuring step for measuring the mercury concentration in the exhaust gas with an upstream mercury concentration meter; A downstream mercury concentration measurement step for measuring the downstream mercury concentration in the exhaust gas with the downstream mercury concentration meter downstream of the dust collector, and a control step for controlling the activated carbon supply amount of the activated carbon supply device with the control device,
In the control process, the oxygen concentration measurement value by the oxygen concentration meter, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, the upstream mercury concentration measurement value by the upstream mercury concentration meter, and the downstream mercury concentration measurement value by the downstream mercury concentration meter An exhaust gas treatment method characterized in that the activated carbon supply amount is controlled so that the downstream mercury concentration in the exhaust gas on the downstream side of the dust collector is not more than a set value.

  In the fourth to sixth inventions, it is preferable that in the control step, the activated carbon supply amount is controlled to be maintained at a predetermined minimum value or more. By such control, an activated carbon adsorption layer is always formed on the bag filter of the dust collector, so that the adsorption removal action by the previously formed adsorption layer and the adsorption removal action by the activated carbon blown at that time Thus, mercury can be adsorbed and removed quickly and reliably, and the mercury concentration of the exhaust gas after dust collection can be made sufficiently low. Further, in the fifth or sixth invention, when the mercury concentration in the exhaust gas is lower than a predetermined value, it is preferable to control the activated carbon supply amount to be kept at a predetermined minimum value. An adsorption layer of activated carbon is always formed on the bag filter of the dust collector, and even when exhaust gas containing mercury at a concentration higher than the predetermined value is discharged, adsorption by the adsorption layer formed in advance is performed. Mercury can be adsorbed and removed quickly and reliably by the removal action and the adsorption removal action by activated carbon blown at that time, and the mercury concentration of the exhaust gas after dust collection can be made sufficiently low.

  In the fifth or sixth invention, in the control step, when the mercury concentration measured by the upstream mercury concentration meter or the downstream mercury concentration meter is equal to or higher than the predetermined mercury concentration, the activated carbon supply amount is maintained at the predetermined maximum value. It is preferable to control as described above. Although the mercury concentration is not so high as a time average, when the mercury concentration suddenly increases temporarily, if a large amount of activated carbon is supplied in accordance with this high mercury concentration, the activated carbon will be excessively excessive over the subsequent time. The result will be to supply. Such excessive supply can be prevented by controlling the supply amount of the activated carbon so as to keep the predetermined maximum value.

  In addition, in the fifth or sixth invention, regarding the increase from the minimum value to the maximum value of the activated carbon supply amount, the control process starts from a value at which the measured mercury concentration in the exhaust gas is zero or less than a measurable minimum value. In the range until the first predetermined mercury concentration is reached, activated carbon is supplied based on the predetermined minimum activated carbon supply amount, and after the mercury concentration measurement value reaches the first predetermined mercury concentration, the mercury As the concentration measurement value increases, the activated carbon supply amount is increased linearly from the predetermined minimum value, and when the mercury concentration measurement value reaches the second predetermined mercury concentration, the activated carbon supply amount is supplied to the predetermined maximum value. After the mercury concentration measurement value reaches the second predetermined mercury concentration, the activated carbon supply amount can be kept constant at the predetermined maximum value with respect to the increase in the mercury concentration measurement value.

  Furthermore, in the fifth or sixth invention, regarding the increase from the minimum value to the maximum value of the activated carbon supply amount, the control process is performed from the value where the mercury concentration measurement value of the exhaust gas is zero or less than the measurable minimum value, In the range until the first predetermined mercury concentration is reached, activated carbon is supplied based on the activated carbon supply amount that is the first supply amount at a predetermined minimum value, and the measured mercury concentration value is the first predetermined mercury concentration. When the activated carbon supply amount is increased to the predetermined second supply amount in a stepwise manner, the activated carbon supply amount is increased within the range until the mercury concentration measurement value reaches the second predetermined mercury concentration. Of the mercury concentration measurement value so that the activated carbon supply amount is increased to the predetermined third supply amount when the mercury concentration measurement value reaches the second predetermined mercury concentration. Increasing the amount of activated carbon supplied in a stepped manner as the number increases Repeating, after increasing the activated carbon supply amount to a predetermined maximum value may also be to keep the activated carbon supply amount constant at its predetermined maximum value with an increase in mercury density measurements.

  As described above, by increasing the activated carbon supply amount from the minimum value to the maximum value based on the mercury concentration measurement value of the exhaust gas, the activated carbon supply amount does not cause a problem for the supply amount adjustment mechanism of the activated carbon supply device. Can be controlled smoothly.

  According to this invention, in the first invention and the fourth invention, the oxygen concentration in the exhaust gas is measured with an oximeter on the downstream side of the furnace and the upstream side of the dust collector, and the hydrogen chloride concentration is measured with hydrogen chloride. Measured with a densitometer and adjusted the supply amount of activated carbon based on the measured oxygen concentration and measured hydrogen chloride concentration. In response to the oxygen concentration and hydrogen chloride concentration in the exhaust gas, By grasping the mercury removal performance and adjusting the supply amount of activated carbon without excess or deficiency, the mercury concentration in the exhaust gas on the downstream side of the dust collector can be set to an allowable set value or less.

  In the second and fifth inventions, the oxygen concentration in the exhaust gas is measured with an oxygen concentration meter and the hydrogen chloride concentration is measured with a hydrogen chloride concentration meter downstream from the furnace and upstream from the dust collector. The upstream mercury concentration is measured with an upstream mercury concentration meter, and the activated carbon supply amount is adjusted based on the measured value so that the downstream mercury concentration in the exhaust gas on the downstream side of the dust collector is not more than the allowable set value. When the oxygen concentration and hydrogen chloride concentration in the exhaust gas from the furnace fluctuate, grasp the mercury removal performance in the exhaust gas by activated carbon based on the measured oxygen concentration value and the measured hydrogen chloride concentration, and the mercury concentration in the exhaust gas In the case of fluctuations, the upstream mercury concentration can be measured before the exhaust gas flows into the dust collector, and the activated carbon supply can be quickly adjusted to an appropriate amount based on the measured value. The mercury concentration in the exhaust gas discharged from the chimney can be surely set to an allowable set value or less without causing a delay.

  Further, in the third and sixth inventions, the oxygen concentration in the exhaust gas is measured with an oxygen concentration meter downstream of the furnace and upstream of the dust collector, and the hydrogen chloride concentration is measured with a hydrogen chloride concentration meter. Measure the side mercury concentration with the upstream mercury concentration meter, measure the downstream mercury concentration with the downstream mercury concentration meter at the downstream side of the dust collector, and adjust the amount of activated carbon based on these four measured values. The downstream mercury concentration on the downstream side of the dust collector is set to an allowable setting value or less. When the oxygen concentration and hydrogen chloride concentration in the exhaust gas from the furnace fluctuate, grasp the mercury removal performance of the exhaust gas by activated carbon based on the measured oxygen concentration value and the measured hydrogen chloride concentration, and further downstream from the furnace The amount of activated carbon supplied is controlled based on the upstream mercury concentration measurement value upstream of the dust collector and the downstream mercury concentration measurement value downstream of the dust collector. By doing in this way, the mercury concentration in the exhaust gas discharged from the chimney can be more reliably set to an allowable set value or less without causing a delay with respect to fluctuations in oxygen concentration, hydrogen chloride concentration and mercury concentration. .

  In the first invention and the fourth invention, the mercury removal performance by the activated carbon is grasped based on the oxygen concentration measurement value and the hydrogen chloride concentration measurement value, and the activated carbon supply amount is controlled, but the mercury concentration in the exhaust gas from the furnace is When it fluctuates, the adjustment of the activated carbon supply amount may be delayed with respect to the fluctuation. On the other hand, in the second invention and the fifth invention, since the upstream mercury concentration is measured on the upstream side of the dust collector, the above fluctuation can be dealt with promptly. Furthermore, in the third and sixth inventions, the upstream mercury concentration is measured on the upstream side of the dust collector, and further, the downstream mercury concentration is measured on the downstream side of the dust collector. By adjusting the activated carbon supply amount based on this, the mercury concentration in the exhaust gas discharged from the chimney can be more reliably reduced to a set value or less without delay with respect to the fluctuation of the mercury concentration in the exhaust gas.

  As described above, according to the present invention, the oxygen concentration and the hydrogen chloride concentration in the exhaust gas are measured at a position upstream of the dust collector, or the oxygen concentration and the hydrogen chloride concentration are measured upstream of the dust collector and upstream. Measure the side mercury concentration, or measure the oxygen concentration and hydrogen chloride concentration upstream of the dust collector, and measure the upstream mercury concentration upstream and the downstream mercury concentration downstream of the dust collector, Based on the temperature measurement value and hydrogen chloride concentration measurement value, the mercury removal performance in the exhaust gas by activated carbon is grasped, and the supply amount of activated carbon to be blown is adjusted, so the mercury concentration in the exhaust gas discharged from the chimney is reliably allowed The activated carbon will be supplied without excess and deficiency, and the amount of activated carbon used can be suppressed, and the exhaust gas treatment cost can be reduced.

  Further, according to the present invention, the activated carbon to be blown in based on the measurement of the hydrogen chloride concentration and the upstream mercury concentration on the upstream side of the dust collector as the oxygen concentration in the exhaust gas and the hydrogen chloride concentration or the oxygen concentration in the exhaust gas. Since the oxygen and hydrogen chloride concentrations in the exhaust gas are reduced and the mercury adsorption efficiency by activated carbon is reduced, the activated carbon blowing amount is controlled to control the amount of exhaust gas discharged from the chimney. The mercury concentration in the exhaust gas can be reduced to a predetermined value or less. In addition, when the mercury concentration measurement value is equal to or higher than the predetermined mercury concentration, the activated carbon is supplied without excess or deficiency by controlling the activated carbon supply amount so as to maintain the predetermined maximum value. At the same time, the cost of exhaust gas treatment can be reduced.

BRIEF DESCRIPTION OF THE DRAWINGS The 1st embodiment apparatus of this invention is shown, (A) is the schematic block diagram, (B) is a schematic block diagram of activated carbon supply apparatus. It is a schematic block diagram of the apparatus of 2nd embodiment of this invention. It is a schematic block diagram of the apparatus of 3rd embodiment of this invention. (A)-(H) have shown the various patterns which can be employ | adopted as a relationship between the mercury concentration in waste gas, and activated carbon supply amount. It is a figure which shows the relationship between oxygen concentration, hydrogen chloride concentration, and activated carbon supply amount.

  Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings.

  In the present embodiment, an incinerator that incinerates waste is described as a furnace that discharges exhaust gas containing mercury. However, the present invention is not limited to this, and various types such as a cement kiln furnace and a nonferrous metal smelting furnace are described. It can be used as a treatment apparatus and treatment method for exhaust gas containing mercury discharged from a furnace.

  For the exhaust gas from the incinerator that incinerates waste, the activated carbon is blown into the exhaust gas channel upstream of the bag filter installed for dust collection, so that the mercury floating in the exhaust gas channel is adsorbed by the activated carbon. At the same time, an activated carbon layer is created on the filter medium surface of the bag filter, and mercury is adsorbed by the activated carbon layer to absorb and remove the mercury in the exhaust gas, thereby suppressing the mercury concentration downstream of the bag filter to a low concentration level. In the past, due to changes in the type and amount of waste, the form of mercury and the mercury concentration in the exhaust gas from the incinerator fluctuate, and the mercury concentration temporarily increases downstream of the bag filter. In preparation for the case, it is necessary to always blow a large amount of activated carbon, which increases the cost of exhaust gas treatment.

  Therefore, in this embodiment, an oxygen concentration meter, a hydrogen chloride concentration meter or an oxygen concentration meter, a hydrogen chloride concentration meter, and a mercury concentration meter are installed upstream from the position where activated carbon is blown in the exhaust gas flow path upstream of the bag filter, Measure the oxygen concentration and hydrogen chloride concentration or oxygen concentration and hydrogen chloride concentration and mercury concentration, and control the amount of activated carbon to be injected based on the measured oxygen concentration and hydrogen chloride concentration or oxygen concentration and hydrogen chloride concentration and mercury concentration; Blowing into the exhaust gas flow path. The oxygen concentration meter, the hydrogen chloride concentration meter, and the mercury concentration meter are preferably continuously measured.

<First embodiment>
In FIG. 1A showing a schematic configuration of the apparatus of the present embodiment, a boiler 2 from the upstream side and a bag filter 3 as a dust collector are disposed in an exhaust gas flow path A that guides exhaust gas from the incinerator 1 to the chimney 4. An activated carbon supply device 5 for blowing activated carbon for adsorbing and removing mercury in the exhaust gas to the exhaust gas flow path A at a position upstream of the bag filter 3 and a control device 6 for controlling the activated carbon supply device 5 are provided. 3, an oxygen concentration meter 7 that measures the oxygen concentration in the exhaust gas at a position upstream of the activated carbon blowing position by the activated carbon supply device 5, and a hydrogen chloride that measures the hydrogen chloride concentration immediately downstream thereof A concentration meter 8 is provided, and the oxygen concentration meter 7 and the hydrogen chloride concentration meter 8 transmit the measured values of the oxygen concentration meter 7 and the hydrogen chloride concentration meter 8 as output signals to the control device 6. Connected to That.

  The measured value of the oxygen concentration meter 7 and the measured value of the hydrogen chloride concentration meter 8 are sent to the control device 6, and the activated carbon supply device 5 is controlled based on the measured value.

  The control device 6 stores a predetermined correspondence relationship between the oxygen concentration measurement value by the oxygen concentration meter 7 and the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter 8 and the activated carbon supply amount. Based on this correspondence relationship, the activated carbon The supply amount may be controlled.

  Specifically, as shown in FIG. 1 (B), the activated carbon supply device 5 includes a hopper 5A for storing activated carbon, a rotary-type cutting member 5B provided at a lower outlet of the hopper 5A, and It has a valve or damper 5C provided below it. In the activated carbon supply device 5, upon receiving a command signal from the control device 6, at least one of the rotational speed of the cutting member 5B, the opening of the valve, and the opening of the damper 5C is adjusted, and the activated carbon adjusts the supply amount. And supplied to the exhaust gas passage A.

<Explanation of Correspondence between Oxygen Concentration Measurement and Hydrogen Chloride Concentration Measurement and Activated Carbon Supply>
The procedure for determining the correspondence between the oxygen concentration measurement value and the hydrogen chloride concentration measurement value and the activated carbon supply amount is shown below.

An experiment was conducted to adsorb and remove mercury in the exhaust gas by activated carbon using the exhaust gas treatment apparatus shown in FIG. The upstream mercury concentration in the exhaust gas in the exhaust gas passage A upstream from the bag filter 3 is approximately constant at about 200 μg / Nm ³ , and the oxygen concentration is 4 vol% or less, 4 to 8 vol%, 3 types of 8 vol% or more. The oxygen chloride concentration in the exhaust gas is changed in the range of 50 to 400 ppm, and the above three kinds of oxygen concentrations in the exhaust gas in the chimney 4 on the downstream side of the bag filter 3 in the case of various hydrogen chloride concentrations. Fig. 5 shows a preferable correspondence relationship between the oxygen concentration in the exhaust gas, the hydrogen chloride concentration, and the activated carbon supply amount obtained by obtaining the activated carbon supply amount required to make the downstream-side mercury concentration of 50 µg / Nm ³ or less as an average value for one hour. It was determined as shown in

  As shown in FIG. 5, when the oxygen concentration is a high concentration of 8 vol% or more, the mercury removal performance of the activated carbon is high and mercury is sufficiently adsorbed and removed, so that the activated carbon supply amount is 4 to 8 vol% oxygen concentration. As compared with the case of 4 vol% or less, mercury can be sufficiently removed with a small supply amount, and the mercury concentration in the exhaust gas can be made sufficiently lower than a set value. On the other hand, when the oxygen concentration is low, the adsorption and removal performance of mercury in the exhaust gas by activated carbon is low, so a large amount of activated carbon supply is required, and the activated carbon supply is increased to allow the mercury concentration in the exhaust gas to be allowed. Try to keep it below the value. That is, the lower the oxygen concentration, the greater the required amount of activated carbon supply.

Further, as shown in FIG. 5, in any of the above three oxygen concentrations, when the hydrogen chloride concentration is high, the adsorption and removal performance of mercury in the exhaust gas by the activated carbon is high, and the activated carbon is sufficiently adsorbed and removed by the activated carbon. Is done. For example, when the oxygen concentration is 8 vol% or more and the hydrogen chloride concentration is 300 ppm or more, the adsorption and removal performance of mercury in the exhaust gas by the activated carbon is high, and the activated carbon is sufficiently adsorbed and removed by the activated carbon. Mercury can be sufficiently removed at about / Nm ³ , and the mercury concentration in the exhaust gas can be set to a sufficiently allowable set value or less. On the other hand, when the hydrogen chloride concentration is lower than 300 ppm, the adsorption and removal performance of mercury in exhaust gas by activated carbon is low, so a large amount of activated carbon supply is required, and the activated carbon supply is increased to allow the mercury concentration in the exhaust gas. To be less than or equal to the set value. That is, the lower the hydrogen chloride concentration, the greater the required amount of activated carbon supply.

  Similarly, when the mercury concentration in the exhaust gas is different, the preferred correspondence between the measured oxygen concentration value and the measured hydrogen chloride concentration in the exhaust gas and the amount of activated carbon supplied is determined, and the measured oxygen concentration measured value and the hydrogen chloride concentration are determined. Based on the measured value, the activated carbon supply amount of the activated carbon supply device is controlled.

<Second embodiment>
The second embodiment shown in FIG. 2 is a position upstream of the activated carbon blowing position by the activated carbon supply device 5 in addition to the oxygen concentration meter 7 and the hydrogen chloride concentration meter 8 as compared with the first embodiment described above. The only difference is that the upstream mercury concentration meter 9 is installed, and the others are the same as in FIG. Therefore, in FIG. 2, the same code | symbol is attached | subjected about the site | part common in the 1st embodiment of FIG. 1, and the description is abbreviate | omitted.

  In this embodiment, as shown in FIG. 2, the upstream mercury concentration meter 9 is downstream of the incinerator 1 and upstream of the bag filter 3 and upstream of the activated carbon blowing position by the activated carbon supply device 5. It is arranged to measure the upstream mercury concentration in the exhaust gas at the position on the side. In the present embodiment, the relationship between the oxygen concentration and hydrogen chloride concentration, the upstream mercury concentration and the activated carbon supply amount at the measurement position, and the downstream mercury concentration at the downstream position from the bag filter 3 is based on accumulated data. It is grasped. Therefore, measure the oxygen concentration, hydrogen chloride concentration and upstream mercury concentration upstream of the activated carbon blowing position, supply the oxygen measurement value, hydrogen chloride concentration measurement value and upstream mercury concentration measurement value and supply at that time. From the activated carbon supply amount, the downstream mercury concentration downstream of the bag filter 3 can be estimated. That is, the control device 6 estimates the downstream mercury concentration downstream of the bag filter 3 based on the measured oxygen concentration, hydrogen chloride concentration, and upstream mercury concentration upstream of the activated carbon blowing position, The activated carbon supply amount necessary for setting the estimated downstream mercury concentration below the set value can be obtained, and the activated carbon supply amount of the activated carbon supply device 5 is controlled. As a result, the downstream mercury concentration at the downstream side of the bag filter 3 is set to a set value or less. The control device 6 is supplied at the time of controlling the oxygen concentration measurement value by the oxygen concentration meter 7, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter 8, and the upstream mercury concentration measurement value by the upstream mercury concentration meter 9. The activated carbon supply amount may be controlled based on a predetermined correspondence relationship with the activated carbon supply amount.

  In this embodiment, when there is a change in the oxygen concentration, hydrogen chloride concentration, or mercury concentration in the exhaust gas from the incinerator 1, the oxygen concentration, hydrogen chloride concentration, or mercury concentration is changed downstream of the incinerator 1 and The oxygen concentration meter 7, the hydrogen chloride concentration meter 8, and the upstream mercury concentration meter 9 measure and detect at a position upstream of the activated carbon blowing position by the activated carbon supply device 5, and promptly adjust the activated carbon supply amount. Therefore, there is no time lag, and the mercury concentration in the exhaust gas downstream of the bag filter 3 can be reliably maintained below the set value. In the example shown in FIG. 2, the measurement position of the oxygen concentration and hydrogen chloride concentration by the oxygen concentration meter 7 and the hydrogen chloride concentration meter 8 and the measurement position of the upstream mercury concentration by the upstream mercury concentration meter 9 are the activated carbon blowing position. However, the present invention is not limited to this, and may be upstream of the bag filter 3 and downstream of the activated carbon blowing position.

  Various forms can be applied as a correspondence relationship in which the activated carbon supply amount corresponds to a change in the measured mercury concentration value.

When the measured mercury concentration in the exhaust gas is zero or less than the minimum measurable limit value or lower than a predetermined value, activated carbon is not supplied and the mercury concentration in the exhaust gas is zero or the minimum limit value that can be measured. Alternatively, when the value is higher than a predetermined value, the form of correspondence (form 1) may be adopted in which the activated carbon supply amount is gradually increased as the mercury concentration in the exhaust gas increases. Further, in addition to the above-described form 1, the activated carbon supply amount is increased in accordance with the increase in mercury concentration until the measured value of mercury concentration reaches a predetermined mercury concentration, and the measured value of mercury concentration becomes the predetermined mercury. When the concentration is equal to or higher than the concentration, the activated carbon supply amount may be a predetermined maximum value supply amount and may be in a constant form (form 2). Moreover, in the form 1 or the form 2, when the activated carbon supply amount is increased as the mercury concentration increases, the activated carbon supply amount may be increased linearly or stepwise.

  In addition, as a correspondence relationship for the activated carbon supply amount to correspond to the change in the mercury concentration measurement value, when the mercury concentration measurement value is equal to or lower than the predetermined mercury concentration, the activated carbon supply amount is set to the predetermined minimum value, and the mercury concentration measurement value is When the mercury concentration is higher than the predetermined mercury concentration, the activated carbon supply amount is gradually increased from the predetermined minimum value as the mercury concentration measurement value increases, and when the mercury concentration measurement value is higher than the predetermined mercury concentration, the activated carbon supply is increased. You may make it the form (form 3) of the correspondence which maintains quantity at a predetermined maximum value. As the minimum value of the activated carbon supply amount, during operation in which the exhaust gas is discharged from the incinerator 1, even when the mercury concentration in the exhaust gas is extremely low, the activated carbon is always blown in at the minimum supply amount. A value for the amount of activated carbon that will ensure that the mercury concentration in the exhaust gas in the chimney is maintained below the set value is determined. As the mercury concentration measurement value increases, the activated carbon supply amount is gradually increased from a predetermined minimum value, whereby an appropriate amount of activated carbon can be supplied with respect to the mercury concentration in the exhaust gas. When the activated carbon supply amount is gradually increased from a predetermined minimum value, the activated carbon supply amount may be increased linearly or may be increased in steps in a plurality of stages, and various forms of correspondence are adopted. it can.

  As a means of adjusting the supply amount of activated carbon, the rotary speed of the rotary type cutting member of the activated carbon supply device, the opening degree of the valve, the opening degree of the damper, etc. are adjusted alone or in combination. It is preferable to adopt a form of correspondence that is suitable for the adjustment range of the mechanism and the characteristics of adjustment (for example, the supply amount can be increased or decreased continuously or stepwise).

  FIG. 4 shows examples of various application forms for the form 3 among the forms of the correspondence relationship between the measured mercury concentration value and the supplied amount of activated carbon.

  In the application form shown in FIG. 4A, the activated carbon having a predetermined minimum value is in a range from a value where the measured mercury concentration in the exhaust gas is zero or less than a minimum measurable limit value to a predetermined predetermined mercury concentration. Activated carbon is supplied under the supply amount, and when the measured value of mercury concentration reaches the above specified mercury concentration, the activated carbon supply amount is increased in steps to the predetermined maximum value, and the mercury concentration in the exhaust gas is further increased. In this mode, the activated carbon supply amount is kept constant at the predetermined maximum value. When the measured value of mercury concentration is lower than the predetermined mercury concentration, the activated carbon supply amount is set to the predetermined minimum value, and when it is higher than the predetermined mercury concentration, the activated carbon supply amount is set to the predetermined maximum value. The activated carbon supply amount can be controlled by a simple control mechanism.

  In the application form shown in FIG. 4B, the range from the measured value of the mercury concentration in the exhaust gas to zero or less than the minimum measurable minimum value until the first predetermined mercury concentration is reached is a predetermined minimum. When the activated carbon is supplied based on the activated carbon supply amount (the first supply amount) and the measured value of the mercury concentration reaches the first predetermined mercury concentration, the activated carbon supply amount is set step by step. The activated carbon supply amount was kept constant at the second supply amount with respect to the increase in the mercury concentration in the exhaust gas, and the measured value of the mercury concentration reached the second predetermined mercury concentration. When the activated carbon supply amount is increased to a predetermined third supply amount, the activated carbon supply amount is repeatedly increased in small steps as the mercury concentration in the exhaust gas is increased. After increasing to the maximum value, the mercury concentration in the exhaust gas A form to maintain the activated carbon supply amount constant at its predetermined maximum value with an increase. As the mercury concentration in the exhaust gas increases, the supply of activated carbon is increased in a stepwise manner from the predetermined minimum value to the predetermined maximum value, thereby providing a more appropriate amount of activated carbon for the mercury concentration in the exhaust gas. It can be controlled to supply.

  The application form shown in FIG. 4C is a form in which the activated carbon supply amount is linearly increased from a predetermined minimum value as the mercury concentration in the exhaust gas increases. In addition, in the application mode shown in FIG. 4D, in the range until the measured value of the mercury concentration in the exhaust gas reaches the predetermined mercury concentration, linearly increases from the predetermined minimum value as the mercury concentration in the exhaust gas increases. When the measured value of mercury concentration reaches the mercury concentration in the predetermined exhaust gas, the activated carbon supply amount is set to the predetermined maximum supply amount, and the activated carbon supply amount is set to the predetermined maximum value. After the increase, the activated carbon supply amount is kept constant at the predetermined maximum value with respect to the increase in the mercury concentration in the exhaust gas. In the application mode shown in FIGS. 4C and 4D, the activated carbon supply amount is continuously increased from a predetermined minimum value as the mercury concentration in the exhaust gas increases, so that the mercury concentration in the exhaust gas is increased. It can be controlled to supply activated carbon in a fine and appropriate amount.

  The application form shown in FIG. 4 (E) has a predetermined minimum in a range from the measured value of the mercury concentration in the exhaust gas to zero or less than the measurable minimum value to the first predetermined mercury concentration. After the activated carbon is supplied under the activated carbon supply amount and the measured value of the mercury concentration reaches the first predetermined mercury concentration, linearly increases from the predetermined minimum value as the mercury concentration in the exhaust gas increases. When the activated carbon supply amount is increased and the measured value of the mercury concentration reaches the second predetermined mercury concentration, the activated carbon supply amount is set to the predetermined maximum supply amount, and the activated carbon supply amount is increased to the predetermined maximum value. After that, the activated carbon supply amount is kept constant at the predetermined maximum value with respect to the increase in the mercury concentration in the exhaust gas. The application mode shown in FIG. 4 (E) is a combination of the application modes shown in FIGS. 4 (A) and 4 (C), and has the characteristics and effects of each mode.

  In the application form shown in FIG. 4 (F), there is a predetermined minimum in the range from the measured value of the mercury concentration in the exhaust gas to zero or less than the measurable minimum value to the first predetermined mercury concentration. After the activated carbon is supplied under the activated carbon supply amount (first supply amount) and the measured mercury concentration reaches the first predetermined mercury concentration, The activated carbon supply amount is increased linearly from one supply amount to a second supply amount corresponding to the second predetermined mercury concentration, and then the activated carbon supply amount is increased with respect to the increase in the mercury concentration in the exhaust gas. When the third predetermined mercury concentration is reached, the activated carbon supply amount is increased linearly from the second supply amount, and the third predetermined mercury concentration corresponding to the fourth predetermined mercury concentration is maintained. Increased to the supply amount, and then active against increasing mercury concentration in exhaust gas Keep the supply amount constant at the third supply amount, and keep increasing and increasing the activated carbon supply amount against such an increase in the mercury concentration in the exhaust gas, so that the activated carbon supply amount becomes a predetermined maximum value. After the increase, the activated carbon supply amount is kept constant at the predetermined maximum value with respect to the increase in the mercury concentration in the exhaust gas. The application mode shown in FIG. 4 (F) is a combination of the application modes shown in FIGS. 4 (B) and 4 (D), and has the characteristics and effects of each mode.

  In the application mode shown in FIG. 4G, the amount of activated carbon supplied linearly from a predetermined minimum value as the mercury concentration in the exhaust gas increases until the measured value of the mercury concentration in the exhaust gas reaches the predetermined mercury concentration. After the measured value of mercury concentration reaches the above specified mercury concentration, the activated carbon supply amount is increased to the predetermined maximum value in steps, and the activated carbon supply amount is increased to the predetermined maximum value. Is a mode in which the activated carbon supply amount is kept constant at the predetermined maximum value with respect to the increase in the mercury concentration in the exhaust gas. When the measured value of mercury concentration in the exhaust gas is lower than a relatively medium predetermined value, the activated carbon supply is continuously increased from the predetermined minimum value according to the increase in the mercury concentration in the exhaust gas. The activated carbon can be controlled to be supplied in a fine and appropriate amount with respect to the mercury concentration in the exhaust gas, and if the measured value of the mercury concentration in the exhaust gas is higher than the predetermined moderate mercury concentration, This corresponds to a predetermined maximum value, and the activated carbon supply amount can be controlled with an appropriate amount by effectively using a plurality of means for adjusting the supply amount of activated carbon.

  In the application mode shown in FIG. 4 (H), the measured value of the mercury concentration in the exhaust gas reaches the first predetermined mercury concentration, and linearly increases from the predetermined minimum value as the mercury concentration in the exhaust gas increases. When the activated carbon supply amount is increased and the measured mercury concentration reaches the first predetermined mercury concentration, the activated carbon supply amount is set as the predetermined first supply amount, and the measured mercury concentration value is the second predetermined mercury. Until the concentration is reached, the activated carbon supply amount is kept constant at the predetermined first supply amount, and when the measured value of the mercury concentration reaches the second predetermined mercury concentration, the activated carbon supply amount is set in a stepped manner. After increasing the activated carbon supply amount to a predetermined maximum value, the activated carbon supply amount is kept constant at the predetermined maximum value with respect to the increase in the mercury concentration in the exhaust gas. . The application mode shown in FIG. 4 (H) is different from the application mode shown in FIG. 4 (G) in a predetermined range in which the measured value of the mercury concentration in the exhaust gas is relatively moderate (from the first predetermined mercury concentration to the second level). The range up to the predetermined silver concentration) is a combination of keeping the activated carbon supply amount constant at the first predetermined supply amount, and the supply of activated carbon can be controlled to be supplied in a more appropriate amount.

<Third embodiment>
Compared with the second embodiment described above, the third embodiment shown in FIG. 3 includes an oxygen concentration meter 7, a hydrogen chloride concentration meter 8, and an upstream side of the activated carbon blowing position by the activated carbon supply device 5. In addition to the first mercury concentration meter (upstream mercury concentration meter) 9A, the second mercury concentration meter (downstream mercury) that measures the mercury concentration in the exhaust gas at the outlet of the bag filter 3 or the chimney 4 downstream of the bag filter 3 It is characterized in that a densitometer) 9B is also provided. Except for this point, the second embodiment is the same as the second embodiment. The measurement value of the second mercury concentration meter 9B is sent to the control device 6 as an output signal together with the measurement values of the oxygen concentration meter 7, the hydrogen chloride concentration meter 8 and the first mercury concentration meter 9A. In FIG. 3, parts that are the same as the parts in the second embodiment of FIG.

  In this embodiment, as can be seen from FIG. 3, as described above, the mercury concentration meter is arranged on the upstream side of the activated carbon blowing position by the activated carbon supply device 5 of the second embodiment described above. In addition to the mercury concentration meter 9A (upstream mercury concentration meter), a second mercury concentration meter 9B (downstream mercury concentration meter) is provided at the outlet of the bag filter 3 or the chimney 4. As in the second embodiment, the oxygen concentration by the oxygen concentration meter 7, the hydrogen chloride concentration by the hydrogen chloride concentration meter 8, and the upstream mercury concentration by the first mercury concentration meter 9 </ b> A upstream from the activated carbon blowing position by the activated carbon supply device 5. The amount of activated carbon supplied is controlled based on the measured value, and further, the oxygen concentration by the oxygen concentration meter 7 and the chloride by the hydrogen chloride concentration meter 8 based on the downstream mercury concentration measurement value by the second mercury concentration meter 9B at the outlet of the bag filter 3. The control based on the hydrogen concentration and the upstream mercury concentration measurement value by the first mercury concentration meter 9A is complemented, and the activated carbon supply amount is controlled to increase or decrease.

  When the set value of the mercury concentration in the exhaust gas at the outlet of the bag filter 3 or the chimney 4 is determined in advance, and the downstream mercury concentration measured value by the second mercury concentration meter 9B exceeds the set value, the activated carbon supply amount is Further, the control may be performed so as to increase.

  By incorporating this control, the mercury concentration at the outlet of the bag filter 3 or the chimney 4 can be controlled more reliably than the set value as compared with the second embodiment.

1 furnace (incinerator)
2 Boiler 3 Dust collector (bug filter)
4 Chimney 5 Activated carbon supply device 6 Control device 7 Oxygen concentration meter 8 Hydrogen chloride concentration meter 9 Mercury concentration meter 9A First mercury concentration meter (upstream mercury concentration meter)
9B Second mercury concentration meter (downstream mercury concentration meter)

Claims (10)

In an exhaust gas treatment apparatus comprising: a dust collector that removes exhaust gas containing mercury discharged from a furnace; and an activated carbon supply device that blows activated carbon into an exhaust gas passage that guides the exhaust gas from the furnace to the dust collector.
An oxygen concentration meter that measures the oxygen concentration in the exhaust gas downstream of the furnace and upstream of the dust collector;
A hydrogen chloride concentration meter that measures the hydrogen chloride concentration in the exhaust gas at the downstream side of the furnace and the upstream side of the dust collector, and a control device that controls the activated carbon supply amount of the activated carbon supply device,
Based on the oxygen concentration measurement value by the oxygen concentration meter and the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, the control device makes the downstream mercury concentration in the exhaust gas downstream of the dust collector less than the set value. An exhaust gas treatment apparatus that controls an activated carbon supply amount by controlling an activated carbon supply amount based on a predetermined correspondence relationship between an oxygen concentration measurement value and a hydrogen chloride concentration measurement value and an activated carbon supply amount. In an exhaust gas treatment apparatus comprising: a dust collector that removes exhaust gas containing mercury discharged from a furnace; and an activated carbon supply device that blows activated carbon into an exhaust gas passage that guides the exhaust gas from the furnace to the dust collector.
An oxygen concentration meter that measures the oxygen concentration in the exhaust gas downstream of the furnace and upstream of the dust collector, and hydrogen chloride that measures the hydrogen chloride concentration in exhaust gas downstream of the furnace and upstream of the dust collector Equipped with a concentration meter, an upstream mercury concentration meter for measuring the upstream mercury concentration in the exhaust gas, and a control device for controlling the activated carbon supply amount of the activated carbon supply device,
Based on the oxygen concentration measurement value by the oxygen concentration meter, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, and the upstream mercury concentration measurement value by the upstream mercury concentration meter, the control device An exhaust gas treatment apparatus, wherein the activated carbon supply amount is controlled so that the downstream mercury concentration is lower than a set value. In an exhaust gas treatment apparatus comprising: a dust collector that removes exhaust gas containing mercury discharged from a furnace; and an activated carbon supply device that blows activated carbon into an exhaust gas passage that guides the exhaust gas from the furnace to the dust collector.
An oxygen concentration meter that measures the oxygen concentration in the exhaust gas downstream of the furnace and upstream of the dust collector, and hydrogen chloride that measures the hydrogen chloride concentration in exhaust gas downstream of the furnace and upstream of the dust collector A concentration meter, an upstream mercury concentration meter that measures the upstream mercury concentration in the exhaust gas, a downstream mercury concentration meter that measures the mercury concentration in the exhaust gas downstream of the dust collector, and an activated carbon supply amount of the activated carbon supply device A control device for controlling
The control device consists of an oxygen concentration measurement value by an oxygen concentration meter and a hydrogen chloride concentration measurement value by a hydrogen chloride concentration meter, an upstream mercury concentration measurement value by an upstream mercury concentration meter, and a downstream mercury concentration measurement by a downstream mercury concentration meter. Based on the value, the activated carbon supply amount is controlled so that the downstream mercury concentration in the exhaust gas downstream of the dust collector is equal to or less than a set value.   The exhaust gas treatment device according to any one of claims 1 to 3, wherein the control device controls the activated carbon supply amount so as to be maintained at a predetermined minimum value or more.   When the upstream mercury concentration measurement value by the upstream mercury concentration meter or the downstream mercury concentration measurement value by the downstream mercury concentration meter is equal to or higher than the predetermined mercury concentration, the control device keeps the activated carbon supply amount at a predetermined maximum value. The exhaust gas treatment apparatus according to claim 2 or 3 to be controlled. In the exhaust gas treatment method in which the exhaust gas exhausted from the furnace is dust-removed by the dust collector, and activated carbon is blown from the activated carbon supply device to the exhaust gas passage that leads the exhaust gas from the furnace to the dust collector.
An oxygen concentration measurement process that measures the oxygen concentration in the exhaust gas with an oximeter downstream of the furnace and upstream of the dust collector, and the concentration of hydrogen chloride in the exhaust gas downstream of the furnace and upstream of the dust collector A hydrogen chloride measurement process for measuring the activated carbon supply with a hydrogen chloride concentration meter, and a control process for controlling the activated carbon supply amount of the activated carbon supply apparatus with a control device,
In the control step, the downstream mercury concentration in the exhaust gas on the downstream side of the dust collector is set to be lower than the set value based on the measured oxygen concentration value by the oxygen concentration meter and the measured hydrogen chloride concentration value by the hydrogen chloride concentration meter. An exhaust gas treatment method characterized by controlling an activated carbon supply amount. In the exhaust gas treatment method in which the exhaust gas exhausted from the furnace is dust-removed by the dust collector, and activated carbon is blown from the activated carbon supply device to the exhaust gas passage that leads the exhaust gas from the furnace to the dust collector.
An oxygen concentration measurement process that measures the oxygen concentration in the exhaust gas with an oximeter downstream of the furnace and upstream of the dust collector, and the concentration of hydrogen chloride in the exhaust gas downstream of the furnace and upstream of the dust collector The hydrogen chloride concentration measurement process that measures the amount of activated carbon in the exhaust gas, the upstream mercury concentration measurement process that measures the upstream mercury concentration in the exhaust gas with the upstream mercury concentration meter, and the activated carbon supply amount of the activated carbon supply device by the controller A control process to control,
In the control process, based on the oxygen concentration measurement value by the oxygen concentration meter, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, and the upstream mercury concentration measurement value by the upstream mercury concentration meter, the exhaust gas downstream of the dust collector An exhaust gas treatment method characterized by controlling the supply amount of activated carbon so that the downstream mercury concentration in the inside is not more than a set value. In the exhaust gas treatment method in which activated carbon is blown from the activated carbon supply device from the activated carbon supply device to the exhaust gas flow path that guides the exhaust gas from the furnace to the dust collection device by exhausting the exhaust gas containing mercury discharged from the furnace,
An oxygen concentration measurement process that measures the oxygen concentration in the exhaust gas with an oximeter downstream of the furnace and upstream of the dust collector, and the concentration of hydrogen chloride in the exhaust gas downstream of the furnace and upstream of the dust collector A hydrogen chloride concentration measurement process that measures the concentration of mercury in the exhaust gas, an upstream mercury concentration measurement process that measures the mercury concentration in the exhaust gas with an upstream mercury concentration meter, and a downstream mercury in the exhaust gas that is downstream of the dust collector A downstream mercury concentration measurement step for measuring the concentration with a downstream mercury concentration meter, and a control step for controlling the activated carbon supply amount of the activated carbon supply device with a control device,
In the control process, the oxygen concentration measurement value by the oxygen concentration meter, the hydrogen chloride concentration measurement value by the hydrogen chloride concentration meter, the upstream mercury concentration measurement value by the upstream mercury concentration meter, and the downstream mercury concentration measurement value by the downstream mercury concentration meter And the activated carbon supply amount is controlled so that the downstream mercury concentration in the exhaust gas downstream of the dust collector is not more than a set value.   The exhaust gas treatment method according to any one of claims 6 to 8, wherein in the control step, the activated carbon supply amount is controlled to be maintained at a predetermined minimum value or more.   In the control process, when the upstream mercury concentration measurement value by the upstream mercury concentration meter or the downstream mercury concentration measurement value by the downstream mercury concentration meter is equal to or higher than the predetermined mercury concentration, the activated carbon supply amount is maintained at the predetermined maximum value. The exhaust gas treatment method according to claim 7 or claim 8 to be controlled.

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