JP2019149386A - Light-emitting element, illuminating device, light-emitting device, display device, and electronic apparatus - Google Patents

Abstract

To provide a light-emitting element using a plurality of light emitting dopant, which has high light-emitting efficiency, and provide each of a light-emitting device, a light-emitting module, a light-emitting display device, an electronic apparatus, and an illuminating device, in which a power consumption is reduced by using the light-emitting element as mentioned.SOLUTION: By focusing on a Foerster mechanism as one of an intermolecular energy transfer mechanism, an energy transfer in the Foerster mechanism can be efficiently performed by overlapping a light emission wavelength of an energy giving side molecule and a peak having a local maximum on the longest wavelength side in a graph obtained by multiplying an absorption spectrum on the side of receiving energy by a wavelength to the fourth power.SELECTED DRAWING: Figure 2

Description

The present invention relates to a light-emitting element, a display device, a light-emitting device, an electronic device, and a lighting device using an organic compound as a light-emitting substance.

In recent years, research and development of light-emitting elements using electroluminescence (EL) have been actively conducted. The basic structure of these light emitting elements is:
A layer containing a light-emitting substance (EL layer) is sandwiched between a pair of electrodes. By applying a voltage to this element, light emission from the light-emitting substance can be obtained.

Since such a light-emitting element is a self-luminous type, it has advantages such as higher pixel visibility than a liquid crystal display and the need for a backlight, and is considered suitable as a flat panel display element. In addition, a display using such a light emitting element has a great advantage that it can be manufactured to be thin and light. Another feature is that the response speed is very fast.

Since these light emitting elements can form a light emitting layer in a film shape, light emission can be obtained in a planar shape. Therefore, a large-area element can be easily formed. This is a feature that is difficult to obtain with a point light source typified by an incandescent bulb or LED, or a line light source typified by a fluorescent lamp, and therefore has a high utility value as a surface light source applicable to illumination or the like.

In the case of an organic EL element in which an organic compound is used as a light-emitting substance and the EL layer is provided between a pair of electrodes,
By applying a voltage between the pair of electrodes, electrons are injected from the cathode and holes from the anode are injected into the light-emitting EL layer, and a current flows. Then, when the injected electrons and holes are recombined, the light-emitting organic compound is in an excited state, and light emission can be obtained from the excited light-emitting organic compound.

The types of excited states formed by an organic compound include a singlet excited state and a triplet excited state. Light emission from the singlet excited state (S ^* ) is fluorescence, and light emission from the triplet excited state (T ^* ) is generated. It is called phosphorescence. The statistical generation ratio of the light emitting element is S ^* : T ^* =
It is considered 1: 3.

A compound emitting light from a singlet excited state (hereinafter referred to as a fluorescent compound) usually does not emit light (phosphorescence) from a triplet excited state at room temperature, and only emits light (fluorescence) from a singlet excited state. Is observed. Therefore, the theoretical limit of the internal quantum efficiency (ratio of photons generated with respect to injected carriers) in a light emitting device using a fluorescent compound is S ^* : T ^* =
25% based on 1: 3.

On the other hand, if a compound that emits light from a triplet excited state (hereinafter referred to as a phosphorescent compound) is used,
Light emission (phosphorescence) from the triplet excited state is observed. In addition, phosphorescent compounds are intersystem crossing (
The internal quantum efficiency is 1 because the transition from the singlet excited state to the triplet excited state is likely to occur.
It is theoretically possible to 00%. That is, higher light emission efficiency than the fluorescent compound can be realized. For these reasons, in order to realize a highly efficient light-emitting element, development of a light-emitting element using a phosphorescent compound has been actively performed in recent years.

Patent Document 1 discloses a white light-emitting element that has a light-emitting region containing a plurality of light-emitting dopants, and the light-emitting dopant emits phosphorescence.

JP-T-2004-522276

Although it is a phosphorescent compound that can theoretically have an internal quantum efficiency of 100%, it is difficult to achieve high efficiency without optimizing the device structure and combination with other materials. In particular, in a light-emitting element using a plurality of types of phosphorescent compounds having different bands (light-emitting colors) as light-emitting dopants, not only energy transfer is taken into consideration, but also the efficiency of the energy transfer itself is high without optimization. It is difficult to obtain efficient light emission. In fact, in Patent Document 1, the external quantum efficiency is about 3 to 4% even if the light emitting dopant is a phosphorescent device. Even if the light extraction efficiency is taken into consideration, the internal quantum efficiency is considered to be 20% or less, and it must be said that the phosphorescent light emitting device has a low value.

In addition to improving luminous efficiency, in a multicolor light emitting device using dopants of different emission colors, it is necessary that the dopants of the respective emission colors emit light with a good balance. It is not easy to achieve a high light emission efficiency and maintain the light emission balance of each dopant.

In view of the above, an object of one embodiment of the present invention is to provide a light-emitting element with high emission efficiency in a light-emitting element using a plurality of light-emitting dopants. Another object of one embodiment of the present invention is to provide a light-emitting device, a display device, an electronic device, and a lighting device each having reduced power consumption by using the above light-emitting element.

The present invention should solve any one of the above-mentioned problems.

In the present invention, attention is paid to the Forster mechanism, which is one of the energy transfer mechanisms between molecules. By applying a combination of molecules such that the peak having the maximum on the longest wavelength side in the multiplied characteristic curve overlaps, energy transfer in the Forster mechanism can be efficiently performed. Here, one of the characteristics is that the energy transfer is not energy transfer from a general host to a dopant but energy transfer between dopants. In this way, by applying a combination of dopants that increase the energy transfer efficiency between the dopants, and by designing an element structure that appropriately separates the dopant molecules, the light-emitting element of one embodiment of the present invention Can be obtained.

That is, according to one embodiment of the present invention, the first phosphorescent compound is dispersed between the pair of electrodes in the first host material and the first phosphorescent compound is longer than the first phosphorescent compound. A second phosphorescent compound exhibiting light emission of a wavelength includes a second light-emitting layer dispersed in a second host material, and represented by ε (λ) λ ⁴ of the second phosphorescent compound. In the light emitting element, the wavelength of the maximum value located on the longest wavelength side of the function overlaps with the phosphorescence emission spectrum F (λ) of the first phosphorescent compound. (Where ε (λ) represents the molar extinction coefficient of each phosphorescent compound and is a function of wavelength λ.)

Another embodiment of the present invention includes a first light-emitting layer in which a first phosphorescent compound is dispersed in a first host material between a pair of electrodes, and a first phosphorescent compound. The second phosphorescent compound exhibiting long wavelength emission includes a second light emitting layer dispersed in the second host material, and the maximum value of the phosphorescence emission spectrum of the first phosphorescent compound Is a light emitting element in which a peak including the maximum value located on the longest wavelength side of the function represented by ε (λ) λ ⁴ of the second phosphorescent compound overlaps. (Where ε (λ) represents the molar extinction coefficient of each phosphorescent compound and is a function of wavelength λ.)

In addition, according to another embodiment of the present invention, in the above structure, the first light-emitting layer further includes a first organic compound, the first host material and the first organic compound form an exciplex, This is a light-emitting element in which the emission of one phosphorescent compound has a longer wavelength than that of the exciplex.

Another embodiment of the present invention is the above configuration, wherein the emission spectrum of the exciplex and the maximum position of the function represented by ε (λ) λ ⁴ of the first phosphorescent compound are located on the longest wavelength side. It is a light emitting element in which the wavelength of the value overlaps. (Where ε (λ) represents the molar extinction coefficient of each phosphorescent compound,
Function of wavelength λ. )

Another embodiment of the present invention is the above structure, wherein the peak of the emission spectrum of the exciplex is included and the function represented by ε (λ) λ ⁴ of the first phosphorescent compound is the most. This is a light emitting element in which a peak including a maximum value located on the long wavelength side overlaps. (Where ε (λ) represents the molar extinction coefficient of each phosphorescent compound and is a function of wavelength λ.)

Another embodiment of the present invention is the above structure, wherein the first phosphorescent compound is 500 nm.
The second phosphorescent compound has a phosphorescent emission peak in the range of 600 nm to 600 nm.
The light-emitting element has a phosphorescence emission peak in a range of m to 700 nm.

Another embodiment of the present invention is a light-emitting element having the above structure in which a recombination region of electrons and holes is a first light-emitting layer.

According to another embodiment of the present invention, in the above structure, the first light-emitting layer is positioned on the anode side of the second light-emitting layer, and at least the second light-emitting layer has an electron transport property rather than a hole transport property. It is a light emitting element with high properties.

In addition, according to another embodiment of the present invention, in the above structure, the first light-emitting layer is positioned on the anode side with respect to the second light-emitting layer, and both the first host material and the second host material transport electrons. It is a light emitting element having the property. Note that a material having an electron transporting property is preferably a material having a higher electron transporting property than a hole transporting property.

In addition, according to another embodiment of the present invention, in the above structure, the first light-emitting layer is located on the cathode side with respect to the second light-emitting layer, and at least the second light-emitting layer has a hole transport property rather than an electron transport property. It is a light emitting element with high properties.

Another embodiment of the present invention is the above structure, in which the first light-emitting layer is located on the cathode side of the second light-emitting layer, and both the first host material and the second host material are holes. A light-emitting element having transportability. Note that a material having a hole transporting property is preferably a material having a hole transporting property higher than the electron transporting property.

Another embodiment of the present invention is a light-emitting element in which the first light-emitting layer and the second light-emitting layer are stacked in contact with each other in the above structure.

Another embodiment of the present invention is a light-emitting device, a light-emitting display device, an electronic device, and a lighting device each including the light-emitting element having the above structure.

Note that the light-emitting device in this specification includes an image display device using a light-emitting element. In addition, a connector such as an anisotropic conductive film or a TCP (Tape C) is used as a light emitting element.
Modules with an attached Arrier Package), a module with a printed wiring board provided at the end of a TCP, or a module in which an IC (Integrated Circuit) is directly mounted on a light emitting element by a COG (Chip On Glass) method are all included in the light emitting device. Shall be included. Furthermore, a light emitting device used for a lighting fixture or the like is also included.

One embodiment of the present invention can provide a light-emitting element with high emission efficiency. According to one embodiment of the present invention, a light-emitting device, a light-emitting display device, an electronic device, and a lighting device with reduced power consumption can be provided by using the light-emitting element.

The conceptual diagram of a light emitting element. Diagram showing energy transfer in the luminescent layer The figure explaining Forster movement. 1 is a conceptual diagram of an active matrix light-emitting device. 1 is a conceptual diagram of a passive matrix light emitting device. 1 is a conceptual diagram of an active matrix light-emitting device. 1 is a conceptual diagram of an active matrix light-emitting device. The conceptual diagram of an illuminating device. FIG. 10 illustrates an electronic device. FIG. 10 illustrates an electronic device. The figure showing an illuminating device. The figure showing an illuminating device and a display apparatus. The figure showing a vehicle-mounted display apparatus and an illuminating device. FIG. 10 illustrates an electronic device. Luminance-current efficiency characteristics of the light-emitting element 1. The voltage-luminance characteristics of the light-emitting element 1. Luminance of the light-emitting element 1-external quantum efficiency characteristics. Luminance-power efficiency characteristics of the light-emitting element 1. The emission spectrum of the light-emitting element 1. FIG. 6 illustrates Forster movement of the light-emitting element 1. FIG. 6 illustrates Forster movement of the light-emitting element 1. FIG. 6 illustrates Forster movement of the light-emitting element 1. PL spectrum of 2mDBTPDBq-II, PCBA1BP and their mixed films. Luminance-current efficiency characteristics of the light-emitting element 2. The voltage-luminance characteristic of the light emitting element 2. Luminance of the light-emitting element 2 vs. external quantum efficiency characteristics. Luminance-power efficiency characteristics of the light-emitting element 2. The emission spectrum of the light-emitting element 2. FIG. 10 shows a reliability test result of the light-emitting element 2. Luminance-current efficiency characteristics of the light-emitting element 3. The voltage-luminance characteristic of the light emitting element 3. Luminance of the light-emitting element 3 vs. external quantum efficiency characteristics. Luminance-power efficiency characteristics of the light-emitting element 3. The emission spectrum of the light-emitting element 3. Luminance-current efficiency characteristics of the light-emitting element 4. The voltage-luminance characteristics of the light-emitting element 4. Luminance of the light-emitting element 4-external quantum efficiency characteristics. Luminance-power efficiency characteristics of the light-emitting element 4. The emission spectrum of the light-emitting element 4. Luminance-current efficiency characteristics of the light-emitting element 5. The voltage-luminance characteristic of the light emitting element 5. Luminance of the light-emitting element 5-external quantum efficiency characteristics. Luminance-power efficiency characteristics of the light-emitting element 5. The emission spectrum of the light-emitting element 5. FIG. 6 illustrates Forster movement of the light-emitting element 4. FIG. 6 illustrates Forster movement of the light-emitting element 4. FIG. 6 illustrates Forster movement of the light-emitting element 5. FIG. 6 illustrates Forster movement of the light-emitting element 5. FIG. 6 illustrates Forster movement of the light-emitting element 5.

Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. However, the present invention is not limited to the following description, and it is easily understood by those skilled in the art that modes and details can be variously changed without departing from the spirit and scope of the present invention. Therefore, the present invention should not be construed as being limited to the description of the embodiments below.

(Embodiment 1)
First, the operation principle of the light-emitting element of one embodiment of the present invention is described. The gist of the present invention is that the first phosphorescent compound and the second phosphorescent compound that emits light having a longer wavelength than the first phosphorescent compound are used. A highly efficient multicolor light emitting device is obtained by efficiently emitting both of the phosphorescent compounds.

As a general technique for obtaining a multicolor light emitting device using a phosphorescent compound, a technique in which a plurality of phosphorescent compounds having different emission colors are dispersed in an appropriate ratio in any host material is conceivable. However, in the case of such a method, the phosphorescent compound that emits light with the longest wavelength is likely to emit light, so that an element structure for obtaining multicolor light emission (especially the concentration of each phosphorescent compound in the host material). ) Is very difficult to design and control.

Another method for obtaining a multicolor light emitting element is a so-called tandem structure in which light emitting elements of different emission colors are stacked in series. For example, if three light emitting elements, a blue light emitting element, a red light emitting element, and a red light emitting element are stacked in series and simultaneously emitted, multicolor light (in this case, white light) can be easily obtained. The element structure can also be optimized for each of the blue, green and red elements.
Control is relatively easy. However, since the three elements are stacked, the number of layers increases and the production becomes complicated. In addition, when a problem occurs in electrical contact at a connection portion (so-called intermediate layer) of each element, an increase in driving voltage, that is, power loss may be caused.

On the other hand, the light-emitting element of one embodiment of the present invention includes a first light-emitting layer in which a first phosphorescent compound is dispersed in a first host material between a pair of electrodes, and a first phosphorescent compound. Also, a light-emitting element in which a second phosphorescent compound that emits light having a long wavelength is laminated with a second light-emitting layer in which the second host material is dispersed. At this time, the first light-emitting layer and the second light-emitting layer may be provided in contact with each other, unlike the tandem structure.

FIG. 1 schematically shows an element structure of the above-described light-emitting element of one embodiment of the present invention. FIG. 1C illustrates a first electrode 101, a second electrode 102, and an EL layer 103. The EL layer 103 is provided with at least a light-emitting layer 113, and the other layers may be provided as appropriate.
In FIG. 1C, a structure in which a hole injection layer 111, a hole transport layer 112, an electron transport layer 114, and an electron injection layer 115 are provided is temporarily illustrated. Note that the first electrode 101 functions as an anode and the second electrode 102 functions as a cathode.

FIGS. 1A and 1B are enlarged views of the light-emitting layer 113 in the light-emitting element. 1A and 1B, the first light-emitting layer 113a, the second light-emitting layer 113b, 2
The combined light-emitting layer 113, first phosphorescent compound 113Da, second phosphorescent compound 1
13Db, a first host material 113Ha, and a second host material 113Hb are shown.
FIG. 1B is a schematic view in the case where the first light emitting layer 113a further includes the first organic compound 113A. In either case, each phosphorescent compound (first and second)
The phosphorescent compounds are dispersed in the host material, so that each phosphorescent compound is isolated from each other by each host material. Note that the first and second host materials may be the same or different. In addition, the first light-emitting layer 113a and the second light-emitting layer 113b may be on either the anode side or the cathode side.

In this case, electron exchange interaction (so-called Dexter mechanism) between each phosphorescent compound
Energy transfer due to is suppressed. That is, after the first phosphorescent compound 113Da is excited, the excitation energy is converted to the second phosphorescent compound 113Db by the Dexter mechanism.
The phenomenon of moving to can be prevented. Therefore, the phenomenon in which the second phosphorescent compound 113Db that emits light with the longest wavelength mainly emits light can be suppressed. The second
When the excitons are directly generated in the light emitting layer 113b, the second phosphorescent compound 113Db mainly emits light, so that the carrier recombination region is in the first light emitting layer 113a (that is, the first phosphor layer 113b). The phosphorescent compound 113Da is mainly excited).

However, if the energy transfer from the first phosphorescent compound 113Da is completely suppressed, the light emission of the second phosphorescent compound 113Db cannot be obtained. Thus, in one embodiment of the present invention, the excitation energy of the first phosphorescent compound 113Da is partially increased by the second energy.
The device is designed so as to move to phosphorescent compound 113Db. Such energy transfer between isolated molecules is possible by utilizing a dipole-dipole interaction (Förster mechanism).

Here, the Forster mechanism will be described. In the following, the molecule that gives excitation energy is referred to as an energy donor, and the molecule that receives excitation energy is referred to as an energy acceptor. That is, in one embodiment of the present invention, both the energy donor and the energy acceptor are phosphorescent compounds and are separated from each other by the host material.

The Forster mechanism does not require direct contact between molecules for energy transfer. Energy transfer occurs through the resonance phenomenon of dipole vibration between the energy donor and the energy acceptor. The energy donor delivers energy to the energy acceptor by the resonance phenomenon of dipole vibration, the excited state energy donor becomes the ground state, and the ground state energy acceptor becomes the excited state. The rate constant k _F of energy transfer by the Förster mechanism is shown in Equation (1).

In Equation (1), ν represents a frequency, and F (ν) represents a normalized emission spectrum of an energy donor (a fluorescence spectrum or triplet excited state when discussing energy transfer from a singlet excited state). Is the phosphorescence spectrum when discussing the energy transfer of
ν) represents the molar extinction coefficient of the energy acceptor, N represents the Avogadro number, n
Represents the refractive index of the medium, R represents the intermolecular distance between the energy donor and the energy acceptor, τ represents the lifetime of the measured excited state (fluorescence lifetime or phosphorescence lifetime), and c represents the speed of light Φ represents the emission quantum yield (fluorescence quantum yield when discussing energy transfer from singlet excited state, phosphorescence quantum yield when discussing energy transfer from triplet excited state), K ² Is a coefficient (0-4) representing the orientation of the transition dipole moment of the energy donor and energy acceptor. In the case of random orientation, K ² = 2/3.

As can be seen from equation (1), the conditions for energy transfer (Felster movement) by the Förster mechanism are: 1. Energy donor and energy acceptor are not too far apart (related to distance R). 2. Energy donor emits light (related to emission quantum yield φ); The emission spectrum of the energy donor and the absorption spectrum of the energy acceptor have an overlap (related to the integral term).

Here, as explained in FIG. 1, each phosphorescent compound (first and second phosphorescent compounds).
Are dispersed in each host material, and each phosphorescent compound is separated from each other by each host material, and therefore, the distance R has a distance of at least one molecule (1 nm or more).
Therefore, all of the excitation energy generated in the first phosphorescent compound is not transferred to the second phosphorescent compound by the Forster mechanism. On the other hand, R is 1
If it is from about 0 nm to about 20 nm, Forster movement is possible. In order to secure a distance R of at least one molecule between the first and second phosphorescent compounds, the volume of each phosphorescent compound dispersed in the host material is preferably set to a certain value or less. The concentration of each phosphorescent compound corresponding to this in the light emitting layer is 10 wt% or less. Since it is difficult to obtain good characteristics even if the concentration of the phosphorescent compound is too thin, the concentration of the phosphorescent compound in this embodiment is preferably 0.1 wt% or more and 10 wt% or less. In particular, the first phosphorescent compound is more preferably contained in the first light-emitting layer 113a at a concentration of 0.1 wt% or more and 5 wt% or less.

Each phosphorescence in the light-emitting element of one embodiment of the present invention using the first phosphorescent compound 113Da and the second phosphorescent compound 113Db that emits light having a longer wavelength than the first phosphorescent compound. FIG. 2 shows a schematic diagram of Forster movement between compounds. In FIG. 2, the structure in which the first light emitting layer 113a and the second light emitting layer 113b are stacked between the electrode 10 and the electrode 11 is shown. Note that one of the electrode 10 and the electrode 11 functions as an anode and the other functions as a cathode. As shown in FIG. 2A, first, the singlet excited state (S _a ) generated in the first phosphorescent compound 113Da is converted into _a triplet excited state (T _a ) by intersystem crossing.
In other words, excitons of the first light-emitting layer 113a are aggregated essentially _{T a.}

Next, the energy of excitons of the T _a state, although part of it is directly converted into light emission, by utilizing the Förster mechanism, some of the triplet excited state of the second phosphorescent compound 113Db It is possible to move to (T _b ). This is because the first phosphorescent compound 113Da is luminescent (the phosphorescence quantum yield φ is high) and the second phosphorescent compound 113Db is in an electronic transition from a singlet ground state to a triplet excited state. This is due to the fact that it has a direct absorption corresponding to (there is an absorption spectrum of a triplet excited state). If these conditions are met, T
triplet from _a to T _b - becomes possible triplet Förster transfer.

Note that the singlet excited state (S _b ) of the second phosphorescent compound 113Db often has higher energy than the triplet excited state (T _a ) of the first phosphorescent compound 113Da. Often does not contribute much to energy transfer. Therefore, it is omitted here.
Of course, when the energy of the singlet excited state (S _b ) of the second phosphorescent compound 113Db is lower than that of the triplet excited state (T _a ) of the first phosphorescent compound 113Da, energy transfer occurs similarly. sell. In this case, the singlet excited state of the second phosphorescent compound 113Db (
The energy transferred to S _b ) is transferred to the triplet excited state (T _b ) of the second phosphorescent compound 113Db through intersystem crossing, and is involved in light emission.

In order to design the above-described Forster transfer efficiently between phosphorescent compounds as dopants and not to transfer energy to the host material, the first and second host materials are: The phosphorescent compound 113Da preferably has no absorption spectrum in the light emitting region. In this way, by causing direct energy transfer between dopants without using a host material (specifically, the second host material), generation of an extra energy transfer path is suppressed, and high luminous efficiency is achieved. This is a preferable structure because it can be tied.

In addition, the first host material preferably has triplet excitation energy higher than that of the first phosphorescent compound so as not to quench the first phosphorescent compound.

As described above, the basic concept of one embodiment of the present invention is that the first and second phosphorescent compounds are first isolated using the host material and the stacked structure, and the first light emitting light having a short wavelength is obtained. It is to make the element structure which mainly excites the phosphorescent compound. In such an element structure, if the distance is within a certain distance (˜20 nm), the Förster energy transfer occurs in part, so that the excitation energy of the first phosphorescent compound is partially increased by the second energy. It moves to a phosphorescent compound, and light emission can be obtained from each of the first and second phosphorescent compounds.

However, the more important point in one embodiment of the present invention is the selection of a material and the element structure in consideration of the energy transfer.

First, in order to generate Förster movement, the emission quantum yield φ on the energy donor side needs to be high, but in one embodiment of the present invention, a phosphorescent compound (specifically, the phosphorescence quantum yield is Since a light emitting compound of 0.1 or more is used, no problem occurs. The important point is that the formula (1
) Is increased, that is, the emission spectrum F (ν) of the energy donor and the molar absorption coefficient ε (ν) of the energy acceptor are overlapped well.

In general, the emission spectrum F (ν) of the energy donor should be overlapped in a wavelength region where the molar absorption coefficient ε (ν) of the energy acceptor is large (that is, the product of F (ν) ε (ν) should be increased). It is considered good). However, this is not necessarily true in the Forster mechanism. This is because the integral term of equation (1) is inversely proportional to the fourth power of the frequency ν,
This is because wavelength dependence exists.

In order to make it easier to understand, equation (1) is first transformed. If the wavelength of light is λ, ν = c
Since / λ, the formula (1) can be rewritten as the following formula (2).

That is, it can be seen that the integral term increases as the wavelength λ increases. In short, it means that energy transfer is more likely to occur on the longer wavelength side. That is, molar extinction coefficient ε (λ)
It is not as simple as F (lambda) may be they overlap in a large wavelength region, ε (λ) at lambda ⁴ is large area F (lambda) must be such overlap.

Therefore, as the second phosphorescent compound 113Db in the light-emitting element of one embodiment of the present invention, light emission of the first phosphorescent compound 113Da is performed in order to increase energy transfer efficiency from the first phosphorescent compound 113Da. The peak of the spectrum where the maximum value of the spectrum exists, and the second
Phosphorus optical compound 113Db ε (λ) λ ⁴ in use longest phosphorescent compound such as mountains overlap the maximum value exists located wavelength side of the function expressed in.

Note that the maximum wavelength located on the longest wavelength side of the function represented by ε (λ) λ ⁴ of the second phosphorescent compound is the phosphorescence emission spectrum F (λ) of the first phosphorescent compound. It is preferable to overlap. In addition, in the mountain where the maximum value of the emission spectrum of the first phosphorescent compound 113Da exists, a wavelength range having an intensity half the maximum value and ε (λ) λ ^{4 of} the second phosphorescent compound. It is more preferable that there is an overlap in the wavelength range having half the intensity of the maximum value in the mountain where the maximum value of the function represented by

The light-emitting element having the above structure can have a high light emission efficiency and can be a light-emitting element capable of obtaining light emission from each phosphorescent compound in a balanced manner.

In order to deepen the understanding of the structure of such a phosphorescent compound, a specific example will be described below. Here, as the first phosphorescent compound 113Da, the following compound (1) (bis [
2- (6-tert-butyl-4-pyrimidinyl-κN3) phenyl-κC] (2,4-
Pentandionato-κ ² O, O ′) Iridium (III) (abbreviation: Ir (tBupppm)
₂ (acac))) is a second light emitting with a longer wavelength than the first phosphorescent compound 113Da.
As the phosphorescent compound 113Db, the following compound (2) (bis (2,3,5-triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation: Ir (tppr
) ₂ (dpm))) will be described as an example.

FIG. 3A shows the molar extinction coefficient ε (λ) of the second phosphorescent compound (2) and ε
(Lambda) illustrates a lambda ^4. The molar extinction coefficient ε (λ) decreases as the wavelength increases, but ε (λ) λ ⁴ has a maximum value near 550 nm (corresponding to the triplet MLCT absorption band of compound (2)). doing. As can be seen from this example, the influence of lambda ⁴ sections, epsilon (lambda) lambda ⁴ of the second phosphorescent compound is maximum value within the absorption band located at the longest wavelength side (triplet MLCT absorption band) Have

On the other hand, FIG. 3B shows the photoluminescence (PL) spectrum F (λ) of the compound (1).
And ε (λ) λ ^{4 of} the compound (2). Compound (1) is the first phosphorescent compound and emits green light having an emission peak near 545 nm. The PL spectrum F (λ) of the first phosphorescent compound has a large overlap with ε (λ) λ ⁴ in the vicinity of the maximum value of ε (λ) λ ⁴ of the second phosphorescent compound. Thus, energy transfer by the Forster mechanism occurs from the first phosphorescent compound to the second phosphorescent compound. In this case, since the maximum value corresponds to the triplet MLCT absorption band, it is a triplet-triplet Forster energy transfer (T _a -T _b energy transfer in FIG. 2). At this time, the emission peak wavelength of the PL spectrum F (λ) of the first phosphorescent compound and ε (
A difference in wavelength of the maximum value of [lambda]) [lambda] ⁴ is 0.2 eV or less, which is a preferable configuration because energy transfer is efficiently performed. The emission peak wavelength of the PL spectrum F (λ) of the compound (1) is 546 nm, the wavelength of the maximum value of ε (λ) λ ⁴ of the compound (2) is 543 nm, and the difference corresponds to 0.01 eV at 3 nm. Therefore, it turns out that the energy transfer between a compound (1) and a compound (2) is performed very efficiently.

From the above, the second phosphorescent compound has a direct absorption (for example, triplet ML) corresponding to an electronic transition from a singlet ground state to a triplet excited state on the longest wavelength side of the absorption spectrum.
It is preferable to have (CT absorption). With such a configuration, triplet-triplet energy transfer as shown in FIG. 2 occurs efficiently.

In order to obtain the above-described recombination region, when the first light-emitting layer 113a is located on the anode side, at least the second light-emitting layer 113b is preferably electron-transporting, and the first light-emitting layer 1
Both 13a and the second light emitting layer 113b may be electron transporting. In the case where the first light-emitting layer 113a is located on the cathode side, at least the second light-emitting layer 113b is preferably hole transporting, and both the first light-emitting layer 113a and the second light-emitting layer 113b are positive. It may be pore transportable.

Here, in the first light-emitting layer 113a, a peak where the maximum value of the photoluminescence (PL) spectrum F (λ) of the first host material 113Ha exists, and ε ( It is preferable that the overlap of the peaks where the maximum value located on the longest wavelength side of the function represented by λ) λ ⁴ exists is large.

However, usually the photoluminescence (PL) spectrum F (λ) of the host material
And a ε (λ) λ of the guest material (the first phosphorescent compound 113Da).
It is difficult to overlap a peak having a maximum value located on the longest wavelength side of the function represented by ⁴ . This is because the photoluminescence (PL) of the host material is usually fluorescence emission, and the fluorescence emission is emission from an energy level higher than that of phosphorescence emission. This is because the triplet excitation energy level of the host material at a wavelength close to the spectrum (the triplet excited state of the guest material) is highly likely to be lower than the triplet excitation energy level of the guest material. If the triplet excitation energy level of the host material is lower than the triplet excitation energy level of the guest material, the triplet excitation energy of the guest material moves to the host material, leading to a decrease in light emission efficiency.

Therefore, in this embodiment mode, the first light-emitting layer 113a further includes the first organic compound 113.
A, and the first host material 113Ha and the first organic compound 113A include the exciplex 11
A combination that forms 3Ec (also referred to as an exciplex) is preferable (FIGS. 1B and 2B). In FIG. 2B, reference numerals 10 and 11 denote electrodes, and one of the electrodes 10 and 11 functions as an anode and the other functions as a cathode. In the figure, exciplex 113E
The singlet excited state of c is represented by Se, the triplet excited state is represented by Te, and the first phosphorescent compound 11
The singlet excited state of 3Da is represented by Sa, the triplet excited state is represented by Ta, the singlet excited state of the second phosphorescent compound 113Db is represented by Sb, and the triplet excited state is represented by Tb.

In this case, when recombination of carriers (electrons and holes) in the first light-emitting layer 113a, the first organic compound 113A and the first host material 113Ha obtain energy by recombination of electrons and holes. The exciplex 113Ec is formed. The fluorescence emission from the exciplex 113Ec has a longer wavelength than the fluorescence spectrum of the first organic compound 113A alone and the first host material 113Ha alone, but the singlet excited state Se of the exciplex 113Ec. And triplet excited state Te has a feature that the energy is very close. Therefore, PL spectrum F (λ), which is emission from the singlet excited state of exciplex 113Ec
And a ε (λ) λ of the guest material (the first phosphorescent compound 113Da).
Energy transfer from Se to Ta by superimposing a peak (corresponding to the absorption spectrum of the triplet excited state Ta of the guest material) where the maximum value located on the longest wavelength side of the function represented by ⁴ exists. Both energy transfers from Te to Ta can be maximized. At this time, the emission peak wavelength of the exciplex 113Ec and the guest material (first phosphorescent compound 113)
The difference in the wavelength of the maximum value of ε (λ) λ ⁴ of Da) is is not more than 0.2 eV, is a preferred arrangement for energy transfer can be efficiently performed. The triplet excitation energy level of the first organic compound 113A and the first host material 113Ha is preferably kept higher than the triplet excitation energy level of the first phosphorescent compound 113Da.

As described above, part of the energy transferred to the first phosphorescent compound 113Da moves to the second phosphorescent compound 113Db as described above, and the first phosphorescent compound 113Da.
Both the second phosphorescent compound 113Db emits light efficiently.

Note that the first phosphorescent compound 113D from the triplet excited state (Te) of the exciplex 113Ec is used.
The energy transfer to a occurs efficiently by the Dexter mechanism. Singlet excited state (Se
) Is efficiently generated by the Förster mechanism having the above-described configuration, so that total and efficient energy transfer is realized.

The first organic compound 113A and the first host material 113Ha may be a combination that generates an exciplex, but a compound that easily receives electrons (electron trapping compound),
It is preferable to combine with a compound that easily accepts holes (hole trapping compound).

As a compound which easily receives electrons, bis (10-hydroxybenzo [h] quinolinato) beryllium (II) (abbreviation: BeBq ₂ ), bis (2-methyl-8-quinolinolato) (
4-Phenylphenolato) aluminum (III) (abbreviation: BAlq), bis (8-quinolinolato) zinc (II) (abbreviation: Znq), bis [2- (2-benzoxazolyl) phenolato] zinc (II) (Abbreviation: ZnPBO), metal complexes such as bis [2- (2-benzothiazolyl) phenolato] zinc (II) (abbreviation: ZnBTZ), 2- (4-biphenylyl) -5- (4-tert-butylphenyl) -1,3,4-oxadiazole (abbreviation: P
BD), 3- (4-biphenylyl) -4-phenyl-5- (4-tert-butylphenyl) -1,2,4-triazole (abbreviation: TAZ), 1,3-bis [5- (p- tert
-Butylphenyl) -1,3,4-oxadiazol-2-yl] benzene (abbreviation: OX
D-7), 9- [4- (5-Phenyl-1,3,4-oxadiazol-2-yl) phenyl] -9H-carbazole (abbreviation: CO11), 2,2 ′, 2 ″- (1,3,5-Benzenetriyl) tris (1-phenyl-1H-benzimidazole) (abbreviation: TPBI)
), 2- [3- (dibenzothiophen-4-yl) phenyl] -1-phenyl-1H-benzimidazole (abbreviation: mDBTBIm-II), or a heterocyclic compound having a polyazole skeleton, such as 2- [3- ( Dibenzothiophen-4-yl) phenyl] dibenzo [f, h
] Quinoxaline (abbreviation: 2mDBTPDBq-II), 2- [3 ′-(dibenzothiophen-4-yl) biphenyl-3-yl] dibenzo [f, h] quinoxaline (abbreviation: 2mD)
BTBPDBq-II), 2- [3 ′-(9H-carbazol-9-yl) biphenyl-
3-yl] dibenzo [f, h] quinoxaline (abbreviation: 2mCzBPDBq), 4,6-bis [3- (phenanthrene-9-yl) phenyl] pyrimidine (abbreviation: 4,6mPnP2)
Pm), 4,6-bis [3- (4-dibenzothienyl) phenyl] pyrimidine (abbreviation: 4)
, 6mDBTP2Pm-II) and other heterocyclic compounds having a diazine skeleton, and 3,5-bis [3- (9H-carbazol-9-yl) phenyl] pyridine (abbreviation: 35DCzPP).
y) 1,3,5-tri [3- (3-pyridyl) -phenyl] benzene (abbreviation: TmPy)
And heterocyclic compounds having a pyridine skeleton such as PB). Among the compounds described above, a heterocyclic compound having a diazine skeleton and a heterocyclic compound having a pyridine skeleton are preferable because of their good reliability. In particular, a heterocyclic compound having a diazine (pyrimidine or pyrazine) skeleton has a high electron transporting property and contributes to a reduction in driving voltage.

As a compound that easily receives holes, 4,4′-bis [N- (1-naphthyl) -N—
Phenylamino] biphenyl (abbreviation: NPB), N, N′-bis (3-methylphenyl)
-N, N'-diphenyl- [1,1'-biphenyl] -4,4'-diamine (abbreviation: TP
D), 4,4′-bis [N- (spiro-9,9′-bifluoren-2-yl) -N-phenylamino] biphenyl (abbreviation: BSPB), 4-phenyl-4 ′-(9-phenyl) Fluoren-9-yl) triphenylamine (abbreviation: BPAFLP), 4-phenyl-3'-
(9-phenylfluoren-9-yl) triphenylamine (abbreviation: mBPAFLP),
4-phenyl-4 ′-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBA1BP), 4,4′-diphenyl-4 ″-(9-phenyl-9H
-Carbazol-3-yl) triphenylamine (abbreviation: PCBBi1BP), 4- (1
-Naphthyl) -4 '-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBBANB), 4,4'-di (1-naphthyl) -4''-(9-phenyl- 9H-carbazol-3-yl) triphenylamine (abbreviation: PCBNBB), 9,9
-Dimethyl-N-phenyl-N- [4- (9-phenyl-9H-carbazol-3-yl) phenyl] fluoren-2-amine (abbreviation: PCBAF), N-phenyl-N- [4-
A compound having an aromatic amine skeleton such as (9-phenyl-9H-carbazol-3-yl) phenyl] spiro-9,9′-bifluoren-2-amine (abbreviation: PCBASF),
1,3-bis (N-carbazolyl) benzene (abbreviation: mCP), 4,4′-di (N-carbazolyl) biphenyl (abbreviation: CBP), 3,6-bis (3,5-diphenylphenyl)
-9-phenylcarbazole (abbreviation: CzTP), 3,3′-bis (9-phenyl-9H)
-Carbazole) (abbreviation: PCCP) and other compounds having a carbazole skeleton,
', 4''-(benzene-1,3,5-triyl) tri (dibenzothiophene) (abbreviation:
DBT3P-II), 2,8-diphenyl-4- [4- (9-phenyl-9H-fluoren-9-yl) phenyl] dibenzothiophene (abbreviation: DBTFLP-III), 4- [
Compounds having a thiophene skeleton such as 4- (9-phenyl-9H-fluoren-9-yl) phenyl] -6-phenyldibenzothiophene (abbreviation: DBTFLP-IV),
4 ′, 4 ″-(benzene-1,3,5-triyl) tri (dibenzofuran) (abbreviation: D
And compounds having a furan skeleton such as BF3P-II) and 4- {3- [3- (9-phenyl-9H-fluoren-9-yl) phenyl] phenyl} dibenzofuran (abbreviation: mmDBFFLBi-II). Among the compounds described above, a compound having an aromatic amine skeleton and a compound having a carbazole skeleton are preferable because they have good reliability, high hole transportability, and contribute to reduction in driving voltage.

The first organic compound 113A and the first host material 113Ha are not limited to these, and are a combination capable of forming an exciplex, and the photoluminescence (PL of the exciplex (PL)
) A peak where the maximum value of the spectrum F (λ) exists and a peak where the maximum value located on the longest wavelength side of the function represented by ε (λ) λ ⁴ of the first phosphorescent compound exists. It is sufficient that the peak of the emission spectrum of the exciplex is longer than the peak of the emission spectrum of the first phosphorescent compound 113Da.

Note that in the case where the first organic compound 113A and the first host material 113Ha are formed of a compound that easily receives electrons and a compound that easily receives holes, the carrier balance can be controlled by the mixing ratio thereof. Specifically, the first organic compound 113A and the first host material 113Ha = 1: 9 to 9: 1 are preferable.

Here, in this configuration, the peak of the photoluminescence (PL) spectrum F (λ) of the exciplex and the function represented by ε (λ) λ ⁴ of the first phosphorescent compound are the most. 1st host material 1 which comprises the exciplex which the mountain in which the maximum value located in the long wavelength side exists overlaps
13Ha and the first organic compound 113A are selected. The larger the pile overlap, the better.

Note that the wavelength of the maximum value located on the longest wavelength side of the function represented by ε (λ) λ ⁴ of the first phosphorescent compound overlaps with the photoluminescence (PL) spectrum F (λ) of the exciplex. It is preferable. Also, the photoluminescence (PL) spectrum F (λ of the exciplex
) In the mountain where the maximum value of the function and the maximum value of the function represented by ε (λ) λ ⁴ of the first phosphorescent compound exist. It is more preferable that there is an overlap in the wavelength range having half the intensity of the above-mentioned maximum value because the overlap between the spectra increases.

In this configuration, energy can be efficiently transferred from the exciplex composed of the first host material 113Ha and the first organic compound 113A to the first phosphorescent compound 113Da. Therefore, a light-emitting element with higher external quantum efficiency can be realized.

(Embodiment 2)
In this embodiment, an example of a detailed structure of the light-emitting element described in Embodiment 1 is described below with reference to FIGS.

The light-emitting element in this embodiment includes an EL layer including a plurality of layers between a pair of electrodes.
In this embodiment mode, the light-emitting element includes a first electrode 101, a second electrode 102, and an EL layer 103 provided between the first electrode 101 and the second electrode 102. Yes.
Note that in this embodiment mode, the first electrode 101 functions as an anode and the second electrode 102 functions as a cathode. That is, the first electrode 101 is the second electrode 10.
Light emission is obtained when a voltage is applied to the first electrode 101 and the second electrode 102 so that the potential is higher than 2.

Since the first electrode 101 functions as an anode, it has a high work function (specifically, 4.0 e
V or higher) It is preferable to use a metal, an alloy, a conductive compound, a mixture thereof, or the like. Specifically, for example, indium oxide-tin oxide (ITO: Indium T
in Oxide), indium oxide-tin oxide containing silicon or silicon oxide,
Indium oxide-indium oxide containing zinc oxide, tungsten oxide and zinc oxide (
IWZO) and the like. These conductive metal oxide films are usually formed by a sputtering method, but may be formed by applying a sol-gel method or the like. As an example of a manufacturing method, indium oxide-zinc oxide can be formed by a sputtering method using a target in which 1 to 20 wt% of zinc oxide is added to indium oxide. Indium oxide containing tungsten oxide and zinc oxide (IWZO) is formed by sputtering using a target containing 0.5 to 5 wt% tungsten oxide and 0.1 to 1 wt% zinc oxide with respect to indium oxide. You can also In addition, gold (Au), platinum (
Pt), nickel (Ni), tungsten (W), chromium (Cr), molybdenum (Mo)
, Iron (Fe), cobalt (Co), copper (Cu), palladium (Pd), or a nitride of a metal material (for example, titanium nitride). Graphene can also be used. Note that by using a composite material described later for a layer in contact with the first electrode 101 in the EL layer 103, an electrode material can be selected regardless of a work function.

There is no particular limitation on the stacked structure of the EL layer 103 as long as the light-emitting layer 113 has the structure described in Embodiment Mode 1. For example, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, a carrier block layer, an intermediate layer, and the like can be combined as appropriate. In this embodiment, the EL layer 103 includes a hole injection layer 111, a hole transport layer 112, a light-emitting layer 113, an electron transport layer 114, and an electron injection layer 115 which are sequentially stacked over the first electrode 101.
A configuration having the above will be described. The materials constituting each layer are specifically shown below.

The hole injection layer 111 is a layer containing a substance having a high hole injection property. Molybdenum oxide, vanadium oxide, ruthenium oxide, tungsten oxide, manganese oxide, or the like can be used. In addition, phthalocyanine (abbreviation: H ₂ Pc) and copper phthalocyanine (CuPC)
Phthalocyanine compounds such as 4,4′-bis [N- (4-diphenylaminophenyl) -N-phenylamino] biphenyl (abbreviation: DPAB), N, N′-bis {4- [bis (3- Aromatic amine compounds such as methylphenyl) amino] phenyl} -N, N′-diphenyl- (1,1′-biphenyl) -4,4′-diamine (abbreviation: DNTPD), or poly (ethylenedioxythiophene) / Poly (styrene sulfonic acid) (PEDOT / PSS)
The hole injection layer 111 can also be formed by a polymer such as).

For the hole-injecting layer 111, a composite material in which an acceptor substance is contained in a hole-transporting substance can be used. Note that by using a hole transporting substance containing an acceptor substance, a material for forming the electrode can be selected regardless of the work function of the electrode. That is, not only a material with a high work function but also a material with a low work function can be used for the first electrode 101. Acceptable substances include 7, 7, 8
, 8-tetracyano-2,3,5,6-tetrafluoroquinodimethane (abbreviation: F ₄ -TC)
NQ) and chloranil. Moreover, a transition metal oxide can be mentioned. In addition, oxides of metals belonging to Groups 4 to 8 in the periodic table can be given. Specifically, vanadium oxide, niobium oxide, tantalum oxide, chromium oxide, molybdenum oxide, tungsten oxide, manganese oxide, and rhenium oxide are preferable because of their high electron accepting properties. Among these, molybdenum oxide is especially preferable because it is stable in the air, has a low hygroscopic property, and is easy to handle.

As the hole-transporting substance used for the composite material, various organic compounds such as aromatic amine compounds, carbazole derivatives, aromatic hydrocarbons, and high molecular compounds (oligomers, dendrimers, polymers, and the like) can be used. Note that the organic compound used for the composite material is preferably an organic compound having a high hole-transport property. Specifically, a substance having a hole mobility of 10 ⁻⁶ cm ² / Vs or higher is preferable. Hereinafter, organic compounds that can be used as the hole transporting substance in the composite material are specifically listed.

For example, as an aromatic amine compound, N, N′-di (p-tolyl) -N, N′-diphenyl-p-phenylenediamine (abbreviation: DTDPPA), 4,4′-bis [N- (4-
Diphenylaminophenyl) -N-phenylamino] biphenyl (abbreviation: DPAB), N
, N′-bis {4- [bis (3-methylphenyl) amino] phenyl} -N, N′-diphenyl- (1,1′-biphenyl) -4,4′-diamine (abbreviation: DNTPD), 1 , 3
, 5-tris [N- (4-diphenylaminophenyl) -N-phenylamino] benzene (abbreviation: DPA3B), and the like.

Specific examples of the carbazole derivative that can be used for the composite material include 3- [N—
(9-phenylcarbazol-3-yl) -N-phenylamino] -9-phenylcarbazole (abbreviation: PCzPCA1), 3,6-bis [N- (9-phenylcarbazole-3)
-Yl) -N-phenylamino] -9-phenylcarbazole (abbreviation: PCzPCA2)
, 3- [N- (1-naphthyl) -N- (9-phenylcarbazol-3-yl) amino]
-9-phenylcarbazole (abbreviation: PCzPCN1) and the like can be given.

Other carbazole derivatives that can be used for the composite material include 4,4′-
Di (N-carbazolyl) biphenyl (abbreviation: CBP), 1,3,5-tris [4- (N-
Carbazolyl) phenyl] benzene (abbreviation: TCPB), 9- [4- (10-phenyl-)
9-anthryl) phenyl] -9H-carbazole (abbreviation: CzPA), 1,4-bis [
4- (N-carbazolyl) phenyl] -2,3,5,6-tetraphenylbenzene or the like can be used.

Moreover, as an aromatic hydrocarbon which can be used for a composite material, for example, 2-tert
-Butyl-9,10-di (2-naphthyl) anthracene (abbreviation: t-BuDNA), 2-
tert-Butyl-9,10-di (1-naphthyl) anthracene, 9,10-bis (3
5-diphenylphenyl) anthracene (abbreviation: DPPA), 2-tert-butyl-9
, 10-bis (4-phenylphenyl) anthracene (abbreviation: t-BuDBA), 9,1
0-di (2-naphthyl) anthracene (abbreviation: DNA), 9,10-diphenylanthracene (abbreviation: DPAnth), 2-tert-butylanthracene (abbreviation: t-BuAn)
th), 9,10-bis (4-methyl-1-naphthyl) anthracene (abbreviation: DMNA)
2-tert-butyl-9,10-bis [2- (1-naphthyl) phenyl] anthracene, 9,10-bis [2- (1-naphthyl) phenyl] anthracene, 2,3,6,7-
Tetramethyl-9,10-di (1-naphthyl) anthracene, 2,3,6,7-tetramethyl-9,10-di (2-naphthyl) anthracene, 9,9′-bianthryl, 10,1
0′-diphenyl-9,9′-bianthryl, 10,10′-bis (2-phenylphenyl) -9,9′-bianthryl, 10,10′-bis [(2,3,4,5,6- Pentaphenyl) phenyl] -9,9′-bianthryl, anthracene, tetracene, rubrene,
Examples include perylene, 2,5,8,11-tetra (tert-butyl) perylene, and the like. In addition, pentacene, coronene, and the like can also be used. Thus, 1 × 10 ⁻⁶
It is more preferable to use an aromatic hydrocarbon having a hole mobility of cm ² / Vs or more and having 14 to 42 carbon atoms.

Note that the aromatic hydrocarbon that can be used for the composite material may have a vinyl skeleton. Examples of the aromatic hydrocarbon having a vinyl group include 4,4′-bis (2,2-
Diphenylvinyl) biphenyl (abbreviation: DPVBi), 9,10-bis [4- (2,2-
Diphenylvinyl) phenyl] anthracene (abbreviation: DPVPA) and the like.

In addition, poly (N-vinylcarbazole) (abbreviation: PVK), poly (4-vinyltriphenylamine) (abbreviation: PVTPA), poly [N- (4- {N ′-[4- (4-diphenylamino)] Phenyl] phenyl-N′-phenylamino} phenyl) methacrylamide] (
An abbreviation: PTPDMA) or a polymer compound such as poly [N, N′-bis (4-butylphenyl) -N, N′-bis (phenyl) benzidine] (abbreviation: Poly-TPD) can also be used.

By forming the hole injecting layer, the hole injecting property is improved and a light emitting element with a low driving voltage can be obtained.

The hole transport layer 112 is a layer containing a hole transporting substance. As a hole transporting substance,
For example, 4,4′-bis [N- (1-naphthyl) -N-phenylamino] biphenyl (abbreviation: NPB) or N, N′-bis (3-methylphenyl) -N, N′-diphenyl- [ 1,
1′-biphenyl] -4,4′-diamine (abbreviation: TPD), 4,4 ′, 4 ″ -tris (N, N-diphenylamino) triphenylamine (abbreviation: TDATA), 4,4 ′, 4
'' -Tris [N- (3-methylphenyl) -N-phenylamino] triphenylamine (abbreviation: MTDATA), 4,4'-bis [N- (spiro-9,9'-bifluorene-2
-Yl) -N-phenylamino] biphenyl (abbreviation: BSPB), 4-phenyl-4'-
An aromatic amine compound such as (9-phenylfluoren-9-yl) triphenylamine (abbreviation: BPAFLP) or the like can be used. The substances described here are substances that have a high hole-transport property and mainly have a hole mobility of 10 ⁻⁶ cm ² / Vs or higher. The organic compounds mentioned as the hole transporting substance in the above composite material can also be used for the hole transporting layer 112. Alternatively, a high molecular compound such as poly (N-vinylcarbazole) (abbreviation: PVK) or poly (4-vinyltriphenylamine) (abbreviation: PVTPA) can be used. Note that the layer containing a hole-transporting substance is not limited to a single layer, and two or more layers containing the above substances may be stacked.

The light emitting layer 113 is a layer containing a first phosphorescent compound and a second phosphorescent compound. Since the light-emitting layer 113 has the structure described in Embodiment 1, the light-emitting element in this embodiment can be a light-emitting element with extremely high light emission efficiency. Light emitting layer 113
Refer to the description of the first embodiment for the main configuration.

In the light-emitting layer 113, materials that can be used as the first phosphorescent compound and the second phosphorescent compound are not particularly limited as long as the materials have a relationship as described in Embodiment Mode 1. No. Examples of the first phosphorescent compound and the second phosphorescent compound include the following.

Tris {2- [5- (2-methylphenyl) -4- (2,6-dimethylphenyl) -4H
-1,2,4-triazol-3-yl-κN ² ] phenyl-κC} iridium (III
) (Abbreviation: Ir (mpptz-dmp) ₃ ), tris (5-methyl-3,4-diphenyl-4H-1,2,4-triazolato) iridium (III) (abbreviation: Ir (Mptz) ₃
), Tris [4- (3-biphenyl) -5-isopropyl-3-phenyl-4H-1,2
, 4-triazolate] iridium (III) (abbreviation: Ir (iPrptz-3b) ₃ ), organometallic iridium complexes having a 4H-triazole skeleton, tris [3-methyl-1- (2-methylphenyl)- 5-phenyl-1H-1,2,4-triazolate] iridium (III) (abbreviation: Ir (Mptz1-mp) ₃ ), tris (1-methyl-5-phenyl-3-propyl-1H-1,2, Organometallic iridium complexes having a 1H-triazole skeleton such as 4-triazolato) iridium (III) (abbreviation: Ir (Prptz1-Me) ₃ ), and fac-tris [1- (2,6-diisopropylphenyl) -2 -Phenyl-1H-imidazole] iridium (III) (abbreviation: Ir (iPrpmi) ₃ ),
An imidazole skeleton such as tris [3- (2,6-dimethylphenyl) -7-methylimidazo [1,2-f] phenanthridinato] iridium (III) (abbreviation: Ir (dmpimpt-Me) ₃ ) Organometallic iridium complexes, bis [2- (4 ′, 6′-difluorophenyl) pyridinato-N, C ^{2 ′} ] iridium (III) tetrakis (1-pyrazolyl) borate (abbreviation: FIr6), bis [2- (4 ', 6'-difluorophenyl)
Pyridinato-N, C ^{2 ′} ] iridium (III) picolinate (abbreviation: FIrpic),
Bis {2- [3 ′, 5′-bis (trifluoromethyl) phenyl] pyridinato-N, C ^2
' } Iridium (III) picolinate (abbreviation: Ir (CF ₃ ppy) ₂ (pic)),
Bis [2- (4 ′, 6′-difluorophenyl) pyridinato-N, C ^{2 ′} ] iridium (
III) Organometallic iridium complexes having a phenylpyridine derivative having an electron-withdrawing group such as acetylacetonate (abbreviation: FIracac) as a ligand. These are compounds that exhibit blue phosphorescence emission, and are compounds having an emission peak from 440 nm to 520 nm. Among those described above, organometallic iridium complexes having a polyazole skeleton such as 4H-triazole, 1H-triazole, and imidazole have high hole trapping properties. Therefore, these compounds are used as the first phosphorescent compound in the light-emitting element of one embodiment of the present invention, the first light-emitting layer is provided on the cathode side with respect to the second light-emitting layer, and the second light-emitting element is used. When the layer has a hole transporting property (specifically, when the second host material is a hole transporting material), it becomes easy to control the carrier recombination region in the first light emitting layer. Therefore, it is preferable.
Note that an organometallic iridium complex having a 4H-triazole skeleton is particularly preferable because it is excellent in reliability and luminous efficiency.

In addition, tris (4-methyl-6-phenylpyrimidinato) iridium (III) (abbreviation:
Ir (mppm) ₃ ), tris (4-t-butyl-6-phenylpyrimidinato) iridium (III) (abbreviation: Ir (tBupppm) ₃ ), (acetylacetonato) bis (6-methyl-4-phenyl) Pyrimidinato) iridium (III) (abbreviation: Ir (mppm) ₂ (
acac)), (acetylacetonato) bis (6-tert-butyl-4-phenylpyrimidinato) iridium (III) (abbreviation: Ir (tBupppm) ₂ (acac)), (acetylacetonato) bis [6- (2-norbornyl) -4-phenylpyrimidinato] iridium (III) (abbreviation: Ir (nbppm) ₂ (acac)), (acetylacetonato) bis [5-methyl-6- (2-methylphenyl)- 4-phenylpyrimidinato] iridium (III) (abbreviation: Ir (mpmppm) ₂ (acac)), (acetylacetonato) bis (4,6-diphenylpyrimidinato) iridium (III) (abbreviation: Ir (dpp)
m) ₂ (acac)), an organometallic iridium complex having a pyrimidine skeleton, and (acetylacetonato) bis (3,5-dimethyl-2-phenylpyrazinato) iridium (I
II) (abbreviation: Ir (mppr-Me) ₂ (acac)), (acetylacetonato) bis (5-isopropyl-3-methyl-2-phenylpyrazinato) iridium (III) (abbreviation: Ir (mppr- organometallic iridium complexes having a pyrazine skeleton such as iPr) ₂ (acac)) and tris (2-phenylpyridinato-N, C ^{2 ′} ) iridium (III
) (Abbreviation: Ir (ppy) ₃ ), bis (2-phenylpyridinato-N, C ^{2 ′} ) iridium (III) acetylacetonate (abbreviation: Ir (ppy) ₂ (acac)), bis (benzo [ h] quinolinato) iridium (III) acetylacetonate (abbreviation: Ir (bz
q) ₂ (acac)), tris (benzo [h] quinolinato) iridium (III) (abbreviation: Ir (bzq) ₃ ), tris (2-phenylquinolinato-N, C ^{2 ′} ) iridium (I
II) (abbreviation: Ir (pq) ₃ ), pyridine skeletons such as bis (2-phenylquinolinato-N, C ^{2 ′} ) iridium (III) acetylacetonate (abbreviation: Ir (pq) ₂ (acac)) In addition to the organometallic iridium complex having bismuth, a rare earth metal complex such as tris (acetylacetonato) (monophenanthroline) terbium (III) (abbreviation: Tb (acac) ₃ (Phen)) can be given. These are compounds that emit green phosphorescence mainly, and have an emission peak at 500 nm to 600 nm. Among the above-mentioned, organometallic iridium complexes having a diazine skeleton such as pyrimidine and pyrazine have a weak hole trapping property,
High electron trapping property. Therefore, these compounds are used as the first phosphorescent compound in the light-emitting element of one embodiment of the present invention, the first light-emitting layer is provided on the anode side of the second light-emitting layer, and the second light-emitting element is used. When the layer has an electron transporting property (specifically, when the second host material is an electron transporting material), it is preferable because the carrier recombination region can be easily controlled in the first light-emitting layer. . Note that an organometallic iridium complex having a pyrimidine skeleton is particularly preferable because of its outstanding reliability and luminous efficiency.

In addition, bis [4,6-bis (3-methylphenyl) pyrimidinato] (diisobutyrylmethano) iridium (III) (abbreviation: Ir (5 mdppm) ₂ (divm)), bis [4,
6-bis (3-methylphenyl) pyrimidinato] (dipivaloylmethanato) iridium (
III) (abbreviation: Ir (5 mdppm) ₂ (dpm)), bis [4,6-di (naphthalen-1-yl) pyrimidinato] (dipivaloylmethanato) iridium (III) (abbreviation: I
an organometallic iridium complex having a pyrimidine skeleton such as r (d1npm) ₂ (dpm)), or (acetylacetonato) bis (2,3,5-triphenylpyrazinato) iridium (III) (abbreviation: Ir ( tppr) ₂ (acac)), bis (2,3,5-triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation: Ir (tppr
) ₂ (dpm)), (acetylacetonato) bis [2,3-bis (4-fluorophenyl) quinoxalinato] iridium (III) (abbreviation: Ir (Fdpq) ₂ (acac)) Organometallic iridium complexes, tris (1-phenylisoquinolinato-N, C ^{2 ′} ) iridium (III) (abbreviation: Ir (piq) ₃ ), bis (1-phenylisoquinolinato-N, C ^{2 ′} ) In addition to organometallic iridium complexes having a pyridine skeleton such as iridium (III) acetylacetonate (abbreviation: Ir (piq) ₂ (acac)), 2,3,7,8,12,13,17,18-octaethyl Platinum complexes such as -21H, 23H-porphyrin platinum (II) (abbreviation: PtOEP) and tris (1,3-diphenyl-1,3- Panjionato) (mono-phenanthroline) europium (III
) (Abbreviation: Eu (DBM) ₃ (Phen)), tris [1- (2-thenoyl) -3,3,
Rare earth metal complexes such as 3-trifluoroacetonato] (monophenanthroline) europium (III) (abbreviation: Eu (TTA) ₃ (Phen)). These are compounds that exhibit red phosphorescence, and have an emission peak from 600 nm to 700 nm. Among those described above, organometallic iridium complexes having a diazine skeleton such as pyrimidine and pyrazine have a weak hole trapping property and a high electron trapping property. Therefore, an organometallic iridium complex having a diazine skeleton is used as the second phosphorescent compound, the first light-emitting layer is provided on the cathode side of the second light-emitting layer, and the second light-emitting layer is a hole. When it is transportable (specifically, when the second host material is a hole transport material), the carrier recombination region is the first
Since it becomes easy to control in the light emitting layer, it is preferable. Note that an organometallic iridium complex having a pyrimidine skeleton is particularly preferable because of its outstanding reliability and luminous efficiency. In addition, since an organometallic iridium complex having a pyrazine skeleton can emit red light with good chromaticity, color rendering can be improved when applied to a white light-emitting element.

In addition to the phosphorescent compounds described above, the first phosphorescent material and the second phosphorescent material having the relationship shown in Embodiment Mode 1 are selected from known phosphorescent light emitting materials. It may be selected and used.

The phosphorescent compounds (the first phosphorescent compound 113a and the second phosphorescent compound 1)
13b), a material that exhibits thermally activated delayed fluorescence, ie thermally activated delayed fluorescence (TADF)
) Materials may be used. Here, delayed fluorescence refers to light emission having a remarkably long lifetime while having the same spectrum as normal fluorescence. The lifetime is 10 ⁻⁶ seconds or more, preferably 10 ^−3.
More than a second. Specific examples of the thermally activated delayed fluorescent material include fullerene and derivatives thereof, acridine derivatives such as proflavine, and eosin. Magnesium (Mg
), Zinc (Zn), cadmium (Cd), tin (Sn), platinum (Pt), indium (I
n) or metal-containing porphyrins including palladium (Pd) and the like. Examples of the metal-containing porphyrin include a protoporphyrin-tin fluoride complex (abbreviation: Sn
F ₂ (Proto IX)), mesoporphyrin-tin fluoride complex (abbreviation: SnF ₂ (M
eso IX)), hematoporphyrin-tin fluoride complex (abbreviation: SnF ₂ (Hemat
o IX)), coproporphyrin tetramethyl ester-tin fluoride complex (abbreviation: Sn
F ₂ (Copro III-4Me)), octaethylporphyrin-tin fluoride complex (
Abbreviation: SnF ₂ (OEP)), etioporphyrin-tin fluoride complex (abbreviation: SnF ₂ (
Etio I)), octaethylporphyrin-platinum chloride complex (abbreviation: PtCl ₂ (OE)
P)) and the like. Furthermore, 2- (biphenyl-4-yl) -4,6-bis (12-
Heterocycles having a π-rich heteroaromatic ring and a π-deficient heteroaromatic ring such as phenylindolo [2,3-a] carbazol-11-yl) -1,3,5-triazine (abbreviation: PIC-TRZ) Compounds can also be used. A substance in which a π-rich heteroaromatic ring and a π-deficient heteroaromatic ring are directly bonded has both a donor property of the π-rich heteroaromatic ring and an acceptor property of the π-deficient heteroaromatic ring, and S ₁ and since the energy difference of T ₁ is smaller, particularly preferred.

The material that can be used as the first and second host materials is not particularly limited, and various carrier transport materials may be selected and combined as appropriate so that the element structure shown in FIG. 1 can be obtained. .

For example, as a host material having an electron transporting property, bis (10-hydroxybenzo [h]
Quinolinato) beryllium (II) (abbreviation: BeBq ₂ ), bis (2-methyl-8-quinolinolato) (4-phenylphenolato) aluminum (III) (abbreviation: BAlq), bis (8-quinolinolato) zinc (II) (Abbreviation: Znq), bis [2- (2-benzoxazolyl) phenolato] zinc (II) (abbreviation: ZnPBO), bis [2- (2-benzothiazolyl) phenolato] zinc (II) (abbreviation: ZnBTZ) Metal complexes such as 2- (4-biphenylyl) -5- (4-tert-butylphenyl) -1,3,4-oxadiazole (abbreviation: PBD), 3- (4-biphenylyl) -4- Phenyl-5- (4-tert-butylphenyl) -1,2,4-triazole (abbreviation: TAZ), 1,3-bis [5- (p
-Tert-butylphenyl) -1,3,4-oxadiazol-2-yl] benzene (
Abbreviations: OXD-7), 9- [4- (5-phenyl-1,3,4-oxadiazole-2-)
Yl) phenyl] -9H-carbazole (abbreviation: CO11), 2,2 ′, 2 ″-(1,
3,5-benzenetriyl) tris (1-phenyl-1H-benzimidazole) (abbreviation: TPBI), 2- [3- (dibenzothiophen-4-yl) phenyl] -1-phenyl-1H-benzimidazole ( Abbreviations: mDBTBIm-II) and other heterocyclic compounds having a polyazole skeleton, 2- [3- (dibenzothiophen-4-yl) phenyl] dibenzo [f, h] quinoxaline (abbreviation: 2mDBTPDBq-II), 2- [ 3 ′-(dibenzothiophen-4-yl) biphenyl-3-yl] dibenzo [f, h] quinoxaline (abbreviation: 2mDBTBPDBq-II), 2- [3 ′-(9H-carbazol-9-yl) biphenyl-3 -Yl] dibenzo [f, h] quinoxaline (abbreviation: 2mCzBPDBq),
4,6-bis [3- (phenanthrene-9-yl) phenyl] pyrimidine (abbreviation: 4,6
mPnP2Pm), 4,6-bis [3- (4-dibenzothienyl) phenyl] pyrimidine (abbreviation: 4,6mDBTP2Pm-II) and other heterocyclic compounds having a diazine skeleton,
3,5-bis [3- (9H-carbazol-9-yl) phenyl] pyridine (abbreviation: 35
And heterocyclic compounds having a pyridine skeleton such as DCzPPy) and 1,3,5-tri [3- (3-pyridyl) -phenyl] benzene (abbreviation: TmPyPB). Among the compounds described above, a heterocyclic compound having a diazine skeleton and a heterocyclic compound having a pyridine skeleton are preferable because of their good reliability. In particular, a heterocyclic compound having a diazine (pyrimidine or pyrazine) skeleton has a high electron transporting property and contributes to a reduction in driving voltage.

In addition, as a host material having a hole transporting property, 4,4′-bis [N- (1-naphthyl)
-N-phenylamino] biphenyl (abbreviation: NPB), N, N'-bis (3-methylphenyl) -N, N'-diphenyl- [1,1'-biphenyl] -4,4'-diamine (abbreviation) : TPD), 4,4′-bis [N- (spiro-9,9′-bifluoren-2-yl) -N
-Phenylamino] biphenyl (abbreviation: BSPB), 4-phenyl-4 '-(9-phenylfluoren-9-yl) triphenylamine (abbreviation: BPAFLP), 4-phenyl-
3 ′-(9-phenylfluoren-9-yl) triphenylamine (abbreviation: mBPAFL)
P), 4-phenyl-4 ′-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBA1BP), 4,4′-diphenyl-4 ″-(9-phenyl-9H— Carbazol-3-yl) triphenylamine (abbreviation: PCBBi1BP), 4
-(1-Naphtyl) -4 '-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBANB), 4,4'-di (1-naphthyl) -4''-(9 -Phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBNBB),
9,9-Dimethyl-N-phenyl-N- [4- (9-phenyl-9H-carbazole-3
-Yl) phenyl] fluoren-2-amine (abbreviation: PCBAF), N-phenyl-N-
[4- (9-Phenyl-9H-carbazol-3-yl) phenyl] spiro-9,9′-
Compounds having an aromatic amine skeleton such as bifluoren-2-amine (abbreviation: PCBASF), 1,3-bis (N-carbazolyl) benzene (abbreviation: mCP), 4,4′-di (N
-Carbazolyl) biphenyl (abbreviation: CBP), 3,6-bis (3,5-diphenylphenyl) -9-phenylcarbazole (abbreviation: CzTP), 3,3'-bis (9-phenyl-9H-carbazole) ( (Abbreviation: PCCP) compounds having a carbazole skeleton,
4,4 ′, 4 ″-(benzene-1,3,5-triyl) tri (dibenzothiophene) (
Abbreviation: DBT3P-II), 2,8-diphenyl-4- [4- (9-phenyl-9H-fluoren-9-yl) phenyl] dibenzothiophene (abbreviation: DBTFLP-III),
Compounds having a thiophene skeleton such as 4- [4- (9-phenyl-9H-fluoren-9-yl) phenyl] -6-phenyldibenzothiophene (abbreviation: DBTFLP-IV), 4,4 ′, 4 ″ -(Benzene-1,3,5-triyl) tri (dibenzofuran) (abbreviation: DBF3P-II), 4- {3- [3- (9-phenyl-9H-fluoren-9-yl) phenyl] phenyl} dibenzofuran And a compound having a furan skeleton such as (abbreviation: mmDBFFLBi-II). Among the compounds described above, a compound having an aromatic amine skeleton and a compound having a carbazole skeleton are preferable because they have good reliability, high hole transportability, and contribute to reduction in driving voltage.

In addition to the host materials described above, a host material may be used from among known substances. Note that as the host material, a substance having a triplet level larger than the triplet level (energy difference between the ground state and the triplet excited state) of the phosphorescent compound is preferably selected. Also,
These host materials preferably do not have an absorption spectrum in the blue region. Specifically, the absorption edge of the absorption spectrum is preferably 440 nm or less.

The light emitting layer 113 having the above-described configuration can be manufactured by co-evaporation using a vacuum evaporation method, an inkjet method, a spin coating method, a dip coating method, or the like as a mixed solution.

The electron transport layer 114 is a layer containing an electron transporting substance. For example, tris (8-quinolinolato) aluminum (abbreviation: Alq), tris (4-methyl-8-quinolinolato) aluminum (abbreviation: Almq ₃ ), bis (10-hydroxybenzo [h] quinolinato) beryllium (abbreviation: BeBq ₂ ), Bis (2-methyl-8-quinolinolato) (4-phenylphenolato) aluminum (abbreviation: BAlq), and the like, a layer made of a metal complex having a quinoline skeleton or a benzoquinoline skeleton. In addition, bis [2- (2-hydroxyphenyl) benzoxazolate] zinc (abbreviation: Zn (BOX) ₂ ), bis [2- (2-hydroxyphenyl) benzothiazolate] zinc (abbreviation: Zn (BTZ)) A metal complex having an oxazole-based or thiazole-based ligand such as ₂ ) can also be used. In addition to metal complexes, 2- (4-biphenylyl) -5- (4-tert-butylphenyl) -1,3
, 4-oxadiazole (abbreviation: PBD) and 1,3-bis [5- (p-tert-butylphenyl) -1,3,4-oxadiazol-2-yl] benzene (abbreviation: OXD- 7
), 3- (4-biphenylyl) -4-phenyl-5- (4-tert-butylphenyl)
-1,2,4-triazole (abbreviation: TAZ), bathophenanthroline (abbreviation: BPhe)
n), bathocuproine (abbreviation: BCP), and the like can also be used. The substances described here are substances that have a high electron-transport property and mainly have an electron mobility of 10 ⁻⁶ cm ² / Vs or higher. Note that the above-described electron-transporting host material may be used for the electron-transport layer 114.

Further, the electron-transport layer 114 is not limited to a single layer, and two or more layers including the above substances may be stacked.

Further, a layer for controlling the movement of electron carriers may be provided between the electron transport layer and the light emitting layer.
This is a layer obtained by adding a small amount of a substance having a high electron trapping property to a material having a high electron transporting property as described above. By suppressing the movement of electron carriers, the carrier balance can be adjusted. Such a configuration is very effective in suppressing problems that occur when electrons penetrate through the light emitting layer (for example, a reduction in device lifetime).

Further, an electron injection layer 115 may be provided in contact with the second electrode 102 between the electron transport layer 114 and the second electrode 102. As the electron injection layer 115, lithium fluoride (LiF),
An alkali metal or an alkaline earth metal such as cesium fluoride (CsF), calcium fluoride (CaF ₂ ), or the like, or a compound thereof can be used. For example, a layer made of a substance having an electron transporting property containing an alkali metal, an alkaline earth metal, or a compound thereof can be used. Note that by using an electron injection layer 115 containing an alkali metal or an alkaline earth metal in a layer made of a substance having an electron transporting property, electron injection from the second electrode 102 is efficiently performed. Therefore, it is more preferable.

As a material for forming the second electrode 102, a work function is small (specifically, 3.8 eV).
The following may be used: metals, alloys, electrically conductive compounds, and mixtures thereof. Specific examples of such a cathode material include alkali metals such as lithium (Li) and cesium (Cs), magnesium (Mg), calcium (Ca), and strontium (Sr).
Elements belonging to Group 1 or Group 2 of the periodic table, and alloys containing these (MgAg
, AlLi), europium (Eu), ytterbium (Yb) and the like, and alloys containing these. However, by providing an electron injection layer between the second electrode 102 and the electron transport layer, indium oxide-tin oxide containing Al, Ag, ITO, silicon, or silicon oxide regardless of the work function. Various conductive materials such as second
The electrode 102 can be used. These conductive materials can be formed by a sputtering method, an inkjet method, a spin coating method, or the like.

In addition, as a formation method of the EL layer 103, various methods can be used regardless of a dry method or a wet method. For example, a vacuum deposition method, an ink jet method, a spin coating method, or the like may be used. Moreover, you may form using the different film-forming method for each electrode or each layer.

The electrode may also be formed by a wet method using a sol-gel method, or may be formed by a wet method using a paste of a metal material. Alternatively, a dry method such as a sputtering method or a vacuum evaporation method may be used.

In the light-emitting element having the above structure, current flows due to a potential difference generated between the first electrode 101 and the second electrode 102, so that holes are formed in the light-emitting layer 113 that is a layer containing a highly light-emitting substance. And electrons recombine and emit light. That is, a light emitting region is formed in the light emitting layer 113.

Light emission is extracted outside through one or both of the first electrode 101 and the second electrode 102. Therefore, either one or both of the first electrode 101 and the second electrode 102 is a light-transmitting electrode. When only the first electrode 101 is a light-transmitting electrode, light emission is extracted through the first electrode 101. In the case where only the second electrode 102 is a light-transmitting electrode, light emission is extracted through the second electrode 102. In the case where both the first electrode 101 and the second electrode 102 are light-transmitting electrodes, light emission is extracted from both through the first electrode 101 and the second electrode 102.

Note that the structure of the layers provided between the first electrode 101 and the second electrode 102 is not limited to the above. However, in order to suppress quenching caused by the proximity of the light emitting region and the metal used for the electrode and the carrier injection layer, holes and electrons are separated from the first electrode 101 and the second electrode 102. A structure in which a light-emitting region in which is recombined is provided is preferable.

In addition, the hole transport layer and the electron transport layer in contact with the light emitting layer 113, particularly the carrier transport layer in contact with the light emitting layer 113 closer to the light emitting region, suppress energy transfer from excitons generated in the light emitting layer. It is preferable that the band gap is made of a light emitting material constituting the light emitting layer or a material having a band gap larger than that of the light emission center material included in the light emitting layer.

The light-emitting element in this embodiment may be manufactured over a substrate made of glass, plastic, or the like. As an order of manufacturing on the substrate, the layers may be sequentially stacked from the first electrode 101 side or may be sequentially stacked from the second electrode 102 side. The light emitting device may be one in which one light emitting element is formed on one substrate, but a plurality of light emitting elements may be formed. By manufacturing a plurality of such light-emitting elements over one substrate, an element-divided lighting device or a passive matrix light-emitting device can be manufactured. Alternatively, for example, a thin film transistor (TFT) may be formed over a substrate made of glass, plastic, or the like, and a light-emitting element may be formed over an electrode electrically connected to the TFT. Thus, an active matrix light-emitting device in which driving of the light-emitting element is controlled by the TFT can be manufactured. Note that the structure of the TFT is not particularly limited. Stagger type TF
T or a reverse stagger type TFT may be used. Further, there is no particular limitation on the crystallinity of the semiconductor used for the TFT, and an amorphous semiconductor or a crystalline semiconductor may be used. Also, the driving circuit formed on the TFT substrate may be composed of N-type and P-type TFTs, or may be composed of only one of N-type TFTs and P-type TFTs. Good.

  Note that this embodiment can be combined with any of the other embodiments as appropriate.

(Embodiment 3)
In this embodiment, a light-emitting device using the light-emitting element described in Embodiments 1 and 2 will be described.

In this embodiment, a light-emitting device manufactured using the light-emitting element described in Embodiments 1 and 2 will be described with reference to FIGS. 4A is a top view illustrating the light-emitting device, and FIG. 4B is a cross-sectional view taken along lines AB and CD of FIG. 4A. This light-emitting device includes a drive circuit portion (source line drive circuit) 601, a pixel portion 602, and a drive circuit portion (gate line drive circuit) 603 indicated by dotted lines, which control light emission of the light-emitting elements. Reference numeral 604 denotes a sealing substrate, reference numeral 625 denotes a desiccant, reference numeral 605 denotes a sealing material, and the inside surrounded by the sealing material 605 is a space 607.

Note that the lead wiring 608 is a wiring for transmitting a signal input to the source line driver circuit 601 and the gate line driver circuit 603, and a video signal, a clock signal, an FPC (flexible printed circuit) 609 serving as an external input terminal, Receives start signal, reset signal, etc. Although only the FPC is shown here, a printed wiring board (PWB) may be attached to the FPC. The light-emitting device in this specification includes not only a light-emitting device body but also a state in which an FPC or a PWB is attached thereto.

Next, a cross-sectional structure is described with reference to FIG. A driver circuit portion and a pixel portion are formed over the element substrate 610. Here, a source line driver circuit 601 which is a driver circuit portion is formed.
One pixel in the pixel portion 602 is shown.

Note that the source line driver circuit 601 includes an n-channel TFT 623 and a p-channel TFT 62.
4 is formed. The drive circuit may be formed of various CMOS circuits, PMOS circuits, or NMOS circuits. In this embodiment mode, a driver integrated type in which a driver circuit is formed over a substrate is shown; however, this is not necessarily required, and the driver circuit can be formed outside the substrate.

The pixel portion 602 is formed by a plurality of pixels including a switching TFT 611, a current control TFT 612, and a first electrode 613 electrically connected to the drain thereof.
Note that an insulator 614 is formed so as to cover an end portion of the first electrode 613. Here, a positive photosensitive acrylic resin film is used.

In order to improve the coverage, a curved surface having a curvature is formed at the upper end or the lower end of the insulator 614. For example, when positive photosensitive acrylic is used as a material for the insulator 614, it is preferable that only the upper end portion of the insulator 614 has a curved surface with a curvature radius (0.2 μm to 3 μm). Further, as the insulator 614, a negative photosensitive resin,
Alternatively, any of positive type photosensitive resins can be used.

An EL layer 616 and a second electrode 617 are formed over the first electrode 613. Here, as a material used for the first electrode 613 functioning as an anode, a material having a high work function is preferably used. For example, an ITO film, an indium tin oxide film containing silicon, an indium oxide film containing 2 to 20 wt% zinc oxide, a titanium nitride film,
In addition to a single layer film such as a chromium film, a tungsten film, a Zn film, or a Pt film, a stack of titanium nitride and a film containing aluminum as a main component, a titanium nitride film, a film containing aluminum as a main component, and a titanium nitride film. A three-layer structure or the like can be used. Note that with a stacked structure, resistance as a wiring is low, good ohmic contact can be obtained, and a function as an anode can be obtained.

The EL layer 616 is formed by various methods such as an evaporation method using an evaporation mask, an inkjet method, and a spin coating method. The EL layer 616 includes the first embodiment and the second embodiment.
The configuration as described in the above is included. Further, as other materials constituting the EL layer 616,
It may be a low molecular compound or a high molecular compound (including oligomers and dendrimers).

Further, as a material used for the second electrode 617 formed over the EL layer 616 and functioning as a cathode, a material having a low work function (Al, Mg, Li, Ca, or an alloy or compound thereof, MgAg, MgIn, AlLi or the like is preferably used. Note that the EL layer 616
In the case where the light generated in step 2 transmits through the second electrode 617, the second electrode 617 includes a thin metal film and a transparent conductive film (ITO, indium oxide containing 2 to 20 wt% zinc oxide). In addition, a stack with indium tin oxide containing silicon, zinc oxide (ZnO), or the like is preferably used.

Note that a light-emitting element is formed using the first electrode 613, the EL layer 616, and the second electrode 617. The light-emitting element is the light-emitting element described in Embodiments 1 and 2. Note that a plurality of light-emitting elements are formed in the pixel portion. However, in the light-emitting device in this embodiment mode, light-emitting elements described in Embodiment Modes 1 and 2 and other configurations are used. Both of the elements may be included.

Further, the sealing substrate 604 is bonded to the element substrate 610 with the sealing material 605,
A light-emitting element 618 is provided in a space 607 surrounded by the element substrate 610, the sealing substrate 604, and the sealant 605. Note that the space 607 is filled with a filler, and may be filled with a sealant 605 in addition to an inert gas (such as nitrogen or argon). When a recess is formed in the sealing substrate and a drying material 625 is provided there, deterioration due to the influence of moisture can be suppressed, which is a preferable structure.

Note that an epoxy resin or glass frit is preferably used for the sealant 605. Moreover, it is desirable that these materials are materials that do not transmit moisture and oxygen as much as possible. Further, as a material used for the sealing substrate 604, in addition to a glass substrate and a quartz substrate, FRP (Fiberg
A plastic substrate made of glass-reinforced plastics), PVF (polyvinyl fluoride), polyester, acrylic, or the like can be used.

As described above, a light-emitting device manufactured using the light-emitting element described in Embodiments 1 and 2 can be obtained.

Since the light-emitting device described in Embodiment 1 and Embodiment 2 is used for the light-emitting device in this embodiment, a light-emitting device having favorable characteristics can be obtained. Specifically, the light-emitting element with favorable light emission efficiency described in Embodiments 1 and 2 and a light-emitting device with low power consumption can be obtained. Further, a light-emitting element with a low driving voltage and a low driving voltage can be obtained.

As described above, although the active matrix light-emitting device is described in this embodiment mode, a passive matrix light-emitting device may also be used. FIG. 5 shows a passive matrix light-emitting device manufactured by applying the present invention. 5A is a perspective view illustrating the light-emitting device, and FIG. 5B is a cross-sectional view taken along line XY in FIG. 5A. In FIG.
An EL layer 955 is provided between the electrode 952 and the electrode 956 over the substrate 951.
An end portion of the electrode 952 is covered with an insulating layer 953. A partition layer 9 is formed on the insulating layer 953.
54 is provided. The side wall of the partition wall layer 954 has an inclination such that the distance between one side wall and the other side wall becomes narrower as it approaches the substrate surface. That is, the cross section in the short side direction of the partition wall layer 954 has a trapezoidal shape, and the bottom side (the side facing the insulating layer 953 in the same direction as the surface direction of the insulating layer 953) is the top side (the surface of the insulating layer 953). Facing the same direction as the direction of the insulating layer 9
Shorter than the side that does not contact 53). In this manner, by providing the partition layer 954, defects in the light-emitting element due to static electricity or the like can be prevented. A passive matrix light-emitting device can also be driven with low power consumption by including the light-emitting elements described in Embodiments 1 and 2 that operate at a low driving voltage. In addition, a highly reliable light-emitting device can be provided by including the light-emitting elements described in Embodiments 1 and 2.

In order to achieve full color display, a colored layer or a color conversion layer may be provided on an optical path for light from the light emitting element to go out of the light emitting device. FIGS. 6A and 6B show examples of a light-emitting device that is made full color by providing a colored layer or the like. FIG. 6A shows a substrate 1001,
Base insulating film 1002, gate insulating film 1003, gate electrodes 1006, 1007, 1008
, First interlayer insulating film 1020, second interlayer insulating film 1021, peripheral portion 1042, and pixel portion 10
40, driving circuit unit 1041, first electrode 1024W, 1024R, 1024G of light emitting element
1024B, a partition wall 1025, an EL layer 1028, a second electrode 1029 of a light-emitting element, a sealing substrate 1031, a sealing material 1032, and the like are illustrated. Also, a colored layer (red colored layer 10
34R, a green colored layer 1034G, and a blue colored layer 1034B) are provided on a transparent substrate 1033. Further, a black layer (black matrix) 1035 may be further provided. The transparent base material 1033 provided with the coloring layer and the black layer is aligned and fixed to the substrate 1001.
Note that the colored layer and the black layer are covered with an overcoat layer 1036. Further, in this embodiment, there are a light emitting layer that emits light without passing through the colored layer and a light emitting layer that emits light through the colored layer of each color and does not pass through the colored layer. Since the light is white and the light transmitted through the colored layer is red, blue, and green, an image can be expressed by pixels of four colors.

In the light-emitting device described above, a light-emitting device having a structure in which light is extracted to the substrate 1001 side where the TFT is formed (bottom emission type) is used. However, a structure in which light is extracted from the sealing substrate 1031 side (top-emission type). ). A cross-sectional view of a top emission type light emitting device is shown in FIG. In this case, a substrate that does not transmit light can be used as the substrate 1001. Until the connection electrode for connecting the TFT and the anode of the light emitting element is manufactured, it is formed in the same manner as the bottom emission type light emitting device. Thereafter, a third interlayer insulating film 1037 is formed so as to cover the electrode 1022. The third interlayer insulating film 1037 may play a role of planarization. The third interlayer insulating film 1037 can be formed using other known materials in addition to the same material as the second interlayer insulating film.

The first electrodes 1024W, 1024R, 1024G, and 1024B of the light-emitting element are anodes here, but may be cathodes. In the case of a top emission type light emitting device as shown in FIG. 7, the first electrode is preferably a reflective electrode. The EL layer 1028 has a structure as described in Embodiments 1 and 2 and has an element structure in which white light emission can be obtained. As a configuration for obtaining white light emission, when two EL layers are used, blue light can be obtained from the light emitting layer in one EL layer, and orange light can be obtained from the light emitting layer in the other EL layer. Blue light is emitted from the light emitting layer in one EL layer and the other E layer.
A configuration in which red and green light can be obtained from the light emitting layer in the L layer is conceivable. In addition, when three EL layers are used, a light-emitting element that emits white light can be obtained by emitting red, green, and blue light from each light-emitting layer. Note that, as long as the configuration described in Embodiments 1 and 2 is applied, the configuration for obtaining white light emission is not limited to this.

The colored layer is provided on an optical path through which light from the light emitting element goes out. In the case of a bottom emission type light-emitting device as shown in FIG. 6A, the colored layers 1034R and 1034 are formed on the transparent base material 1033.
G and 1034B can be provided and fixed to the substrate 1001. Alternatively, a coloring layer may be provided between the gate insulating film 1003 and the first interlayer insulating film 1020 as illustrated in FIG. In the case of a top emission structure as shown in FIG. 7, sealing can be performed with a sealing substrate 1031 provided with colored layers (red colored layer 1034R, green colored layer 1034G, and blue colored layer 1034B). A black layer (black matrix) 1035 may be provided on the sealing substrate 1031 so as to be positioned between the pixels. The colored layer (red colored layer 1034R, green colored layer 1034G, blue colored layer 1034B) and black layer (black matrix) 1035 may be covered with an overcoat layer 1036.
Note that the sealing substrate 1031 is a light-transmitting substrate.

When a voltage is applied between the pair of electrodes of the organic light emitting device thus obtained, a white light emitting region 10 is obtained.
44W is obtained. Further, by combining with a colored layer, a red light emitting region 1044R,
A blue light emitting region 1044B and a green light emitting region 1044G are obtained. Since the light-emitting device of this embodiment uses the light-emitting element described in Embodiments 1 and 2, a light-emitting device with low power consumption can be realized.

Although an example in which full color display is performed with four colors of red, green, blue, and white is shown here, the present invention is not particularly limited, and full color display may be performed with three colors of red, green, and blue. Further, the color purity may be improved by providing a microcavity structure. At this time, the microcavity structure may be provided in all pixels, but may be provided only in blue pixels.

Further, this embodiment can be freely combined with any of the other embodiments.

(Embodiment 4)
In this embodiment, an example in which the light-emitting element described in Embodiments 1 and 2 is used for a lighting device will be described with reference to FIGS. 8B is a top view of the lighting device, and FIG. 8A is a cross-sectional view taken along line ef in FIG. 8B.

In the lighting device in this embodiment, the first light-transmitting substrate 400 serving as the support is provided over the first substrate.
Electrode 401 is formed. The first electrode 401 is the first electrode 1 in the third embodiment.
Corresponds to 01.

An auxiliary electrode 402 is provided over the first electrode 401. In this embodiment, an example in which light emission is extracted from the first electrode 401 side is described; therefore, the first electrode 401 is formed using a light-transmitting material. The auxiliary electrode 402 is provided to compensate for the low conductivity of the light-transmitting material, and suppresses uneven luminance in the light-emitting surface due to a voltage drop due to the high resistance of the first electrode 401. It has the function to do. The auxiliary electrode 402 is formed using at least a material having higher conductivity than the material of the first electrode 401, and preferably formed using a material having high conductivity such as aluminum. Note that the surface of the auxiliary electrode 402 other than the portion in contact with the first electrode 401 is preferably covered with an insulating layer. This is for suppressing light emission from the upper part of the auxiliary electrode 402 that cannot be taken out, for reducing reactive current and suppressing reduction in power efficiency. Note that the second electrode 404 is formed simultaneously with the formation of the auxiliary electrode 402.
A pad 412 for supplying a voltage may be formed.

An EL layer 403 is formed over the first electrode 401 and the auxiliary electrode 402. EL layer 40
3 has the configuration described in the first and second embodiments. For these configurations, refer to the description. Note that the EL layer 403 is preferably formed slightly larger than the first electrode 401 in plan view because the EL layer 403 can also serve as an insulating layer for suppressing a short circuit between the first electrode 401 and the second electrode 404. It is a configuration.

A second electrode 404 is formed so as to cover the EL layer 403. The second electrode 404 is the same as in Embodiment Mode 3.
This corresponds to the second electrode 102 in FIG. In this embodiment mode, light emission is extracted from the first electrode 401 side; therefore, the second electrode 404 is preferably formed using a highly reflective material. In the present embodiment, the second electrode 404 is the pad 4
By connecting to 12, a voltage is supplied.

As described above, the first electrode 401, the EL layer 403, and the second electrode 404 (and the auxiliary electrode 402)
The lighting device described in this embodiment includes a light-emitting element including Since the light-emitting element is a light-emitting element with high emission efficiency, the lighting device in this embodiment can be a lighting device with low power consumption. Further, since the light-emitting element is a highly reliable light-emitting element, the lighting device in this embodiment can be a highly reliable lighting device.

The lighting device is completed by fixing and sealing the sealing substrate 407 to the light-emitting element having the above structure using the sealing materials 405 and 406. Either one of the sealing materials 405 and 406 may be used. In addition, a desiccant can be mixed in the inner sealing material 406, so that moisture can be adsorbed, leading to improvement in reliability.

Further, a part of the pad 412, the first electrode 401, and the auxiliary electrode 402 is formed with a sealant 405,
By extending outside 406, an external input terminal can be obtained. Further, an IC chip 420 mounted with a converter or the like may be provided thereon.

As described above, since the lighting device described in this embodiment includes the light-emitting element described in Embodiments 1 and 2 in an EL element, the lighting device can have low power consumption. In addition, the lighting device can have a low driving voltage. Further, a highly reliable lighting device can be obtained.

(Embodiment 5)
In this embodiment, examples of electronic devices each including the light-emitting element described in Embodiments 1 and 2 will be described. The light-emitting elements described in Embodiments 1 and 2 have high luminous efficiency and low power consumption. As a result, the electronic device described in this embodiment can be an electronic device including a light-emitting portion with reduced power consumption. Further, since the light-emitting elements described in Embodiments 1 and 2 are light-emitting elements with low driving voltage, they can be electronic devices with low driving voltage.

As an electronic device to which the light-emitting element is applied, for example, a television device (also referred to as a television or a television receiver), a monitor for a computer, a digital camera, a digital video camera, a digital photo frame, a mobile phone (a mobile phone, Large-sized game machines such as portable telephones, portable game machines, portable information terminals, sound reproduction apparatuses, and pachinko machines. Specific examples of these electronic devices are shown below.

FIG. 9A illustrates an example of a television device. The television device includes a housing 710.
1, a display portion 7103 is incorporated. Here, a structure in which the housing 7101 is supported by a stand 7105 is shown. The display portion 7103 can display an image. The display portion 7103 is formed by arranging the light-emitting elements described in Embodiments 1 and 2 in a matrix. The light-emitting element can be a light-emitting element with favorable light emission efficiency. Further, a light-emitting element with low driving voltage can be obtained. In addition, a light-emitting element with a long lifetime can be obtained. Therefore, the display part 7 comprised with the said light emitting element.
The television device having 103 can be a television device with reduced power consumption. In addition, a television device with low driving voltage can be provided. Further, a highly reliable television device can be obtained.

The television device can be operated with an operation switch included in the housing 7101 or a separate remote controller 7110. Operation keys 7109 provided on the remote controller 7110
Thus, the channel and volume can be operated, and the video displayed on the display portion 7103 can be operated. Further, the remote controller 7110 is connected to the remote controller 7110.
Alternatively, a display portion 7107 for displaying information output from the computer may be provided.

Note that the television device is provided with a receiver, a modem, and the like. General TV broadcasts can be received by a receiver, and connected to a wired or wireless communication network via a modem, so that it can be unidirectional (sender to receiver) or bidirectional (sender and receiver). It is also possible to perform information communication between each other or between recipients).

FIG. 9B1 illustrates a computer, which includes a main body 7201, a housing 7202, a display portion 7203, a keyboard 7204, an external connection port 7205, a pointing device 7206, and the like. Note that this computer is manufactured by using light-emitting elements similar to those described in Embodiment Mode 2 or Embodiment Mode 3 in a matrix and used for the display portion 7203. FIG.
The computer of B1) may have a form as shown in FIG. 9B2. A computer in FIG. 9B2 is provided with a second display portion 7210 instead of the keyboard 7204 and the pointing device 7206. The second display portion 7210 is a touch panel type, and input can be performed by operating a display for input displayed on the second display portion 7210 with a finger or a dedicated pen. In addition, the second display portion 7210 can display not only an input display but also other images. The display portion 7203 may also be a touch panel. By connecting the two screens with hinges, it is possible to prevent troubles such as damage or damage to the screens during storage or transportation. The light-emitting element can have high emission efficiency. Therefore, a computer including the display portion 7203 which includes the light-emitting elements can be a computer with reduced power consumption.

FIG. 9C illustrates a portable game machine, which includes two housings, a housing 7301 and a housing 7302, which are connected with a joint portion 7303 so that the portable game machine can be opened or folded. A display portion 7304 manufactured by arranging the light-emitting elements described in Embodiments 1 and 2 in a matrix is incorporated in the housing 7301, and a display portion 7305 is incorporated in the housing 7302. . In addition, the portable game machine illustrated in FIG. 9C includes a speaker portion 7306, a recording medium insertion portion 7307, and the like.
LED lamp 7308, input means (operation key 7309, connection terminal 7310, sensor 73
11 (force, displacement, position, velocity, acceleration, angular velocity, rotation speed, distance, light, liquid, magnetism, temperature, chemical substance, sound, time, hardness, electric field, current, voltage, power, radiation, flow rate, humidity, Including a function of measuring inclination, vibration, odor, or infrared light), a microphone 7312), and the like. Of course, the configuration of the portable game machine is not limited to that described above, and at least the display unit 73.
04 and / or the display portion 7305 may be used as long as the display portion manufactured by arranging the light-emitting elements described in Embodiments 1 and 2 in a matrix is used for one or the other, and other accessory equipment is provided as appropriate. It can be set as the structure comprised. The portable game machine shown in FIG. 9C shares information by reading a program or data recorded in a recording medium and displaying the program or data on a display unit, or by performing wireless communication with another portable game machine. It has a function. Note that the function of the portable game machine illustrated in FIG. 9C is not limited to this, and the portable game machine can have a variety of functions. The portable game machine having the display portion 7304 as described above can be a portable game machine with low power consumption because the light-emitting element used for the display portion 7304 has favorable light emission efficiency. it can. Further, since the light-emitting element used for the display portion 7304 can be driven with a low driving voltage, a portable game machine with low driving voltage can be provided. Further, since the light-emitting element used for the display portion 7304 is a light-emitting element having a long lifetime, a highly reliable portable game machine can be obtained.

FIG. 9D illustrates an example of a mobile phone. The cellular phone includes a display portion 7402 incorporated in a housing 7401, an operation button 7403, an external connection port 7404, a speaker 74, and the like.
05, a microphone 7406, and the like. Note that the cellular phone 7400 includes a display portion 7402 which is manufactured by arranging the light-emitting elements described in Embodiments 1 and 2 in a matrix. The light-emitting element can have high emission efficiency. Also,
A light-emitting element with low driving voltage can be obtained. In addition, a light-emitting element with a long lifetime can be obtained. Therefore, a cellular phone including the display portion 7402 including the light-emitting element can be a cellular phone with reduced power consumption. Further, a mobile phone with a low driving voltage can be provided. In addition, a highly reliable mobile phone can be obtained.

The mobile phone illustrated in FIG. 9D can have a structure in which information can be input by touching the display portion 7402 with a finger or the like. In this case, operations such as making a call or creating a mail can be performed by touching the display portion 7402 with a finger or the like.

There are mainly three screen modes of the display portion 7402. The first mode is a display mode mainly for displaying an image. The first is a display mode mainly for displaying images, and the second is an input mode mainly for inputting information such as characters. The third is a display + input mode in which the display mode and the input mode are mixed.

For example, when making a call or creating a mail, the display portion 7402 may be set to a character input mode mainly for inputting characters, and an operation for inputting characters displayed on the screen may be performed. In this case, it is preferable to display a keyboard or number buttons on most of the screen of the display portion 7402.

In addition, by providing a detection device having a sensor for detecting inclination such as a gyroscope or an acceleration sensor inside the mobile phone, the orientation (portrait or horizontal) of the mobile phone is determined, and the screen display of the display portion 7402 is automatically displayed. Can be switched automatically.

Further, the screen mode is switched by touching the display portion 7402 or operating the operation button 7403 of the housing 7401. Further, switching can be performed depending on the type of image displayed on the display portion 7402. For example, if the image signal to be displayed on the display unit is moving image data, the mode is switched to the display mode, and if it is text data, the mode is switched to the input mode.

Further, in the input mode, when a signal detected by the optical sensor of the display unit 7402 is detected and there is no input by a touch operation of the display unit 7402 for a certain period, the screen mode is switched from the input mode to the display mode. You may control.

The display portion 7402 can function as an image sensor. For example, the display unit 74
The user can be authenticated by touching 02 with a palm or a finger and capturing an image of a palm print, a fingerprint, or the like. In addition, if a backlight that emits near-infrared light or a sensing light source that emits near-infrared light is used for the display portion, finger veins, palm veins, and the like can be imaged.

Note that the structure described in this embodiment can be combined with any of the structures described in Embodiments 1 to 4 as appropriate.

As described above, the applicable range of the light-emitting device including the light-emitting element described in Embodiments 1 and 2 is so wide that the light-emitting device can be applied to electronic devices in various fields.
By using the light-emitting elements described in Embodiments 1 and 2, an electronic device with reduced power consumption can be obtained.

FIG. 10 illustrates an example of a liquid crystal display device in which the light-emitting element described in Embodiments 1 and 2 is applied to a backlight. A liquid crystal display device illustrated in FIG. 10 includes a housing 901 and a liquid crystal layer 902.
, A backlight unit 903, and a housing 904, and the liquid crystal layer 902 includes a driver IC 90
5 is connected. The backlight unit 903 uses the light-emitting element described in Embodiments 1 and 2, and current is supplied from a terminal 906.

By applying the light-emitting element described in any of Embodiments 1 and 2 to a backlight of a liquid crystal display device, a backlight with reduced power consumption can be obtained. In addition, by using the light-emitting element described in Embodiment Mode 2, a surface-emitting lighting device can be manufactured and the area can be increased. Thereby, the area of the backlight can be increased, and the area of the liquid crystal display device can be increased. Further, since the light-emitting device to which the light-emitting element described in Embodiment 2 is applied can be thinner than the conventional one, the display device can be thinned.

FIG. 11 illustrates an example in which the light-emitting element described in Embodiments 1 and 2 is used for a table lamp which is a lighting device. A table lamp illustrated in FIG. 11 includes a housing 2001 and a light source 2002.
The light-emitting device described in Embodiment 4 is used as the light source 2002.

FIG. 12 illustrates an interior lighting device 300 using the light-emitting element described in Embodiments 1 and 2.
1 and the display device 3002. Since the light-emitting elements described in Embodiments 1 and 2 are light-emitting elements with reduced power consumption, a lighting device with reduced power consumption can be obtained. In addition, since the light-emitting elements described in Embodiments 1 and 2 can have a large area, they can be used as a large-area lighting device. In addition, since the light-emitting elements described in Embodiments 1 and 2 are thin, they can be used as thinned lighting devices.

The light-emitting elements described in Embodiments 1 and 2 can be mounted on a windshield or a dashboard of an automobile. FIG. 13 illustrates one mode in which the light-emitting element described in Embodiment 2 is used for a windshield or a dashboard of an automobile. Display 5000 to display 5005
These are displays provided using the light-emitting elements described in Embodiments 1 and 2.

A display 5000 and a display 5001 are display devices on which the light-emitting elements described in Embodiments 1 and 2 provided on a windshield of an automobile are mounted. The light-emitting element described in Embodiments 1 and 2 is a display device in a so-called see-through state in which the first electrode and the second electrode are formed using a light-transmitting electrode so that the opposite side can be seen through. It can be. If it is a see-through display, it can be installed without obstructing the field of view even if it is installed on the windshield of an automobile. Note that in the case where a transistor for driving or the like is provided, a light-transmitting transistor such as an organic transistor using an organic semiconductor material or a transistor using an oxide semiconductor is preferably used.

A display 5002 is a display device on which the light-emitting element described in Embodiments 1 and 2 provided in a pillar portion is mounted. The display 5002 can complement the field of view blocked by the pillars by displaying an image from the imaging means provided on the vehicle body. Similarly, the display 5003 provided on the dashboard portion compensates the blind spot and improves safety by projecting an image from the imaging means provided outside the automobile from the field of view blocked by the vehicle body. it can. By displaying the video so as to complement the invisible part, it is possible to check the safety more naturally and without a sense of incongruity.

The display 5004 and the display 5005 can provide various other information such as navigation information, a speedometer and a tachometer, a travel distance, an oil supply amount, a gear state, and an air conditioner setting. The display items and layout can be appropriately changed according to the user's preference. Note that these pieces of information can also be provided in the display 5000 to the display 5003.
In addition, the display 5000 to the display 5005 can be used as a lighting device.

The light-emitting elements described in Embodiments 1 and 2 can be light-emitting elements with high emission efficiency. Further, a light-emitting element with low power consumption can be obtained. From this, display 5
Even if a large number of large screens such as 000 to 5005 are provided, light is applied using the light-emitting elements described in Embodiments 1 and 2 because the battery is less burdened and can be used comfortably. The device or the lighting device can be suitably used as a vehicle-mounted light-emitting device or lighting device.

FIG. 14A and FIG. 14B illustrate an example of a tablet terminal that can be folded. FIG.
4A shows an open state, and the tablet terminal includes a housing 9630 and a display portion 9631a.
, A display portion 9631b, a display mode switching switch 9034, a power switch 9035, a power saving mode switching switch 9036, a fastener 9033, and an operation switch 9038. Note that the tablet terminal is manufactured using the light-emitting device including the light-emitting element described in Embodiments 1 and 2 for one or both of the display portion 9631a and the display portion 9631b.

Part of the display portion 9631 a can be a touch panel region 9632 a and data can be input when a displayed operation key 9637 is touched. The display portion 963
In 1a, as an example, a configuration in which half of the area has a display-only function and a configuration in which the other half has a touch panel function is shown, but the configuration is not limited thereto. Display unit 963
All the regions 1a may have a touch panel function. For example, the display unit 96
The entire surface of 31a can be displayed as a keyboard button and used as a touch panel, and the display portion 9631b can be used as a display screen.

Further, in the display portion 9631b as well, like the display portion 9631a, part of the display portion 9631b can be a touch panel region 9632b. In addition, a keyboard button can be displayed on the display portion 9631b by touching a position where the keyboard display switching button 9639 on the touch panel is displayed with a finger, a stylus, or the like.

Further, touch input can be performed on the touch panel region 9632a and the touch panel region 9632b at the same time.

A display mode switching switch 9034 can switch the display direction such as vertical display or horizontal display, and can select switching between monochrome display and color display. The power saving mode change-over switch 9036 can optimize the display luminance in accordance with the amount of external light during use detected by an optical sensor built in the tablet terminal. The tablet terminal may include not only an optical sensor but also other detection devices such as a gyroscope, an acceleration sensor, and other sensors that detect inclination.

FIG. 14A shows an example in which the display areas of the display portion 9631b and the display portion 9631a are the same, but there is no particular limitation. One size and the other size may be different, and the display quality is also high. May be different. For example, one display panel may be capable of displaying images with higher definition than the other.

FIG. 14B illustrates a closed state. In the tablet terminal in this embodiment, the housing 9630, the solar cell 9633, the charge / discharge control circuit 9634, the battery 9635, and the DCD
An example including a C converter 9636 is shown. 14B, the charge / discharge control circuit 963 is used.
4 illustrates a configuration including a battery 9635 and a DCDC converter 9636.

Note that since the tablet terminal can be folded in two, the housing 9630 can be closed when not in use. Therefore, since the display portion 9631a and the display portion 9631b can be protected,
It is possible to provide a tablet terminal with excellent durability and high reliability from the viewpoint of long-term use.

In addition, the tablet terminal shown in FIGS. 14A and 14B has a function for displaying various information (still images, moving images, text images, etc.), a calendar, a date, or a time. A function for displaying on the display unit, a touch input function for performing touch input operation or editing of information displayed on the display unit, a function for controlling processing by various software (programs), and the like can be provided.

Electric power can be supplied to the touch panel, the display unit, the video signal processing unit, or the like by the solar battery 9633 mounted on the surface of the tablet terminal. Note that the solar cell 9633 can be provided on one or both surfaces of the housing 9630 and the battery 9635 can be charged efficiently.

FIG. 14B illustrates the structure and operation of the charge and discharge control circuit 9634 illustrated in FIG.
C) will be described with reference to a block diagram. FIG. 14C illustrates a solar cell 9633, a battery 9
635, DCDC converter 9636, converter 9638, switches SW1 to SW3
, A display portion 9631, a battery 9635, a DCDC converter 963
6, the converter 9638 and the switches SW1 to SW3 are portions corresponding to the charge / discharge control circuit 9634 shown in FIG.

First, an example of operation in the case where power is generated by the solar battery 9633 using external light is described. The power generated by the solar battery is DC so that it becomes a voltage for charging the battery 9635.
The DC converter 9636 performs step-up or step-down. When the power charged in the solar battery 9633 is used for the operation of the display portion 9631, the switch SW1 is turned on, and the converter 9638 increases or decreases the voltage required for the display portion 9631. In the case where display on the display portion 9631 is not performed, the battery 9635 may be charged by turning off SW1 and turning on SW2.

Note that although the solar cell 9633 is shown as an example of the power generation unit, the power generation unit is not particularly limited, and the battery 9635 is charged by another power generation unit such as a piezoelectric element (piezo element) or a thermoelectric conversion element (Peltier element). The structure which performs this may be sufficient. A non-contact power transmission module that wirelessly (contactlessly) transmits and receives power for charging and a combination of other charging means may be used, and the power generation means may not be provided.

Further, as long as the display portion 9631 is included, the tablet terminal is not limited to the shape illustrated in FIG.

In this example, a manufacturing method and characteristics of a light-emitting element corresponding to one embodiment of the present invention described in Embodiments 1 and 2 will be described. The structural formula of the organic compound used in this example is shown below.

Next, a method for manufacturing the light-emitting element of this example is described.

First, indium tin oxide containing silicon oxide (ITSO) was formed over a glass substrate by a sputtering method, so that the first electrode 101 was formed. The film thickness was 110 nm and the electrode area was 2 mm × 2 mm. Here, the first electrode 101 is an electrode that functions as an anode of the light-emitting element.

Next, as a pretreatment for forming a light emitting element on the substrate, the substrate surface is washed with water, and 200
After baking at 0 ° C. for 1 hour, UV ozone treatment was performed for 370 seconds.

Thereafter, the substrate is introduced into a vacuum vapor deposition apparatus whose internal pressure is reduced to about 10 ⁻⁴ Pa, vacuum baking is performed at 170 ° C. for 30 minutes in a heating chamber in the vacuum vapor deposition apparatus, and then the substrate is released for about 30 minutes. Chilled.

Next, the substrate on which the first electrode 101 is formed is fixed to a substrate holder provided in the vacuum evaporation apparatus so that the surface on which the first electrode 101 is formed is downward, and is approximately 10 ⁻⁴ Pa. After the pressure is reduced to 4,4 ′, 4 ″-(benzene-1,3,5-triyl represented by the above structural formula (i) on the first electrode 101 by an evaporation method using resistance heating. ) Tri (dibenzothiophene) (abbreviation: DBT3P-II) and molybdenum oxide (VI) were co-evaporated to form the hole injection layer 111. The film thickness was 33 nm, and the weight ratio of DBT3P-II and molybdenum oxide was adjusted to 4: 2 (= DBT3P-II: molybdenum oxide). Note that the co-evaporation method is an evaporation method in which evaporation is performed simultaneously from a plurality of evaporation sources in one processing chamber.

Next, on the hole injection layer 111, 4-phenyl-4 ′-(
9-phenylfluoren-9-yl) triphenylamine (abbreviation: BPAFLP) 20
The hole transport layer 112 was formed by forming a film having a thickness of nm.

Further, 2- [3- (dibenzothiophen-4-yl) phenyl] dibenzo [f, h] quinoxaline (abbreviation: 2mDBT) represented by the above structural formula (iii) is formed over the hole transport layer 112.
PDBq-II) and 4-phenyl-4 ′-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBA1BP) represented by the above structural formula (iv) and the above structural formula (v) Bis [2- (6-tert-butyl-4-pyrimidinyl-κN3]
) Phenyl-κC] (2,4-pentanedionato-κ ² O, O ′) iridium (III)
(Abbreviation: Ir (tBupppm) ₂ (acac)) in a weight ratio of 0.8: 0.2: 0.05
(= 2mDBTPDBq-II: PCBA1BP: Ir (tBupppm) ₂ (acac)
) To form a first light-emitting layer 113a by 2 nm DBTPDBq-I
I and bis (2,3,5-triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation: Ir (tppr) ₂ (dpm)) represented by the above structural formula (vi) In a weight ratio of 1: 0.06 (= 2mDBTPDBq-II: Ir (tppr) ₂ (dpm))
Thus, the second light-emitting layer 113b was formed by co-evaporation with a thickness of 20 nm. Note that 2mDBTPDBq-II, which is a host material, and PCBA1BP form an exciplex.

After that, 2mDBTPDBq-II was formed to a thickness of 15 nm over the light-emitting layer 113, and further, bathophenanthroline (abbreviation: BPhen) represented by the above structural formula (vii).
Was deposited to a thickness of 15 nm to form an electron transport layer 114.

After the electron transport layer 114 was formed, lithium fluoride (LiF) was then deposited to a thickness of 1 nm to form the electron injection layer 115.

Lastly, as the second electrode 102 functioning as a cathode, aluminum was deposited to a thickness of 200 nm, whereby the light-emitting element 1 of this example was manufactured.

Note that, in the above-described vapor deposition process, the vapor deposition was all performed by a resistance heating method.

Table 1 shows an element structure of the light-emitting element 1 obtained as described above.

The light-emitting element 1 is sealed with a glass substrate so as not to be exposed to the atmosphere in a glove box in a nitrogen atmosphere (a sealing material is applied around the element and heat-treated at 80 ° C. for 1 hour at the time of sealing). It was.

In the light-emitting element 1, the first phosphorescent compound 113Da is Ir (tBupppm) ₂ (ac
ac) is Ir (tppr) ₂ (dpm) as the second phosphorescent compound 113Db. Here, the PL spectrum of Ir (tBupppm) ₂ (acac) and Ir (tp
The relationship of ε (λ) λ ⁴ of pr) ₂ (dpm) will be described. Note that λ is a wavelength and ε (λ) is a molar extinction coefficient.

First, FIG. 20A shows a molar extinction coefficient ε (λ) of Ir (tppr) ₂ (dpm) and ε (λ
) Showed a graph representing the lambda ^4. The molar extinction coefficient epsilon (lambda) whereas no peaks prominent in the area of long wavelength side in the graph of epsilon (lambda) lambda ^4, Peak exists with maximum at 543 nm. This peak is Ir (tppr) ₂ (dpm) triplet ML
It is CT absorption, and by superimposing the emission peak of the first phosphorescent compound 113Da on this peak, the efficiency of energy transfer can be greatly increased.

In FIG. 20B, Ir (tBupppm) ₂ (ac
ac) PL spectrum F (λ) and Ir (tpp) which is the second phosphorescent compound 113Db
A graph showing ε (λ) λ ⁴ of r) ₂ (dpm) is shown. From this graph, Ir (tBu
ppm) ₂ (acac) PL spectrum F (λ) peaks and Ir (tpp)
r) ₂ (dpm) ε (λ) λ ⁴ has a peak having the maximum value on the longest wavelength side, and it is understood that this is a combination in which energy transfer is performed very efficiently. Also,
The emission peak of Ir (tBupppm) ₂ (acac), which is the first phosphorescent compound 113Da, is present at 546 nm, and Ir (tppr) _2, which is the second phosphorescent compound 113Db.
Since the maximum on the long wavelength side in the spectrum representing ε (λ) λ ⁴ of (dpm) exists at 543 nm, the difference is 3 nm. 546nm is 2.27eV, 543nm is 2.28e
Since it corresponds to V, the difference is 0.01 eV, and since the difference is smaller than 0.2 eV, it is suggested that efficient energy transfer is also performed from the peak position.

Subsequently, FIG. 21A shows Ir (tBupppm) ₂ which is the first phosphorescent compound 113Da.
A graph showing the molar extinction coefficient ε (λ) and ε (λ) λ ^{4 of} (acac) is shown. In the graph showing the molar extinction coefficient ε (λ), the peak in the region on the long wavelength side is smaller in intensity than the peak on the short wavelength side, whereas in the graph of ε (λ) λ ⁴ it is 494 nm. There is a local maximum having a large strength. The peak (mountain) where the local maximum exists is Ir (tBu
ppm) ₂ (acac) triplet MLCT absorption, and by superimposing the emission peak of the energy donor on this peak, the efficiency of energy transfer can be greatly increased.

Here, in the light-emitting element 1 of this example, 2mDBTPDBq-II, which is the first host material, is used.
And PCBA1BP which is the first organic compound form an exciplex 113Ec, and energy is supplied from the exciplex 113Ec to the first phosphorescent compound 113Da. FIG. 23 is a diagram showing PL spectra of 2mDBTPDBq-II, PCBA1BP, and a mixed film thereof (mass ratio of 0.8: 0.2).
It can be seen that -II and PCBA1BP which is the first organic compound form exciplex 113Ec. FIG. 21B shows a graph representing the PL spectrum F (λ) of the exciplex and ε (λ) λ ⁴ of Ir (tBupppm) ₂ (acac) which is the first phosphorescent compound 113Da. It was. From this graph, the peak where the peak of the PL spectrum F (λ) of the exciplex is present overlaps with the peak having the maximum value on the longest wavelength side of ε (λ) λ ⁴ of Ir (tBupppm) ₂ (acac). It can be seen that this is a combination in which energy transfer is performed efficiently. In addition, the peak of the PL spectrum of the exciplex is present at 519 nm, and the maximum on the long wavelength side in the spectrum representing ε (λ) λ ⁴ of Ir (tBupppm) ₂ (acac) which is the first phosphorescent compound 113Da Is present at 494 nm, the difference is 25 nm. When converted to energy, 519 nm corresponds to 2.39 eV, and when converted to energy, 494 nm corresponds to 2.51 eV. Therefore, the difference is 0.12 eV, and the difference is smaller than 0.2 eV. It is suggested that energy transfer occurs.

As can be seen from FIG. 23, 2mDBTPDBq which is the first host material 113Ha.
-II has a PL spectrum peak of 426 nm, which is 2.91 in terms of energy.
It corresponds to eV. Moreover, the peak of the PL spectrum of PCBA1BP which is the first organic compound 113A is 405 nm, which corresponds to 3.06 eV in terms of energy. Ir
In the spectrum representing ε (λ) λ ⁴ of (tBupppm) ₂ (acac), the maximum value on the long wavelength side exists at 494 nm, which corresponds to 2.51 eV when converted to energy, and the difference between each is 0.4 eV (First host material 113Ha: 2mDBTPDBq-II),
0.55 eV (first organic compound 113A: PCBA1BP), both 0.2e
Since it has an energy difference of V or more, it can be seen that energy transfer is difficult from 2mDBTPDBq-II, PCBA1BP to Ir (tBupppm) ₂ (acac).

FIG. 22 shows the PL spectrum F (λ), Ir (tBupppm) ₂ (acac) of the exciplex.
) PL spectrum F (λ), Ir (tppr) ₂ (dpm) PL spectrum F (λ)
, Ir (tBupppm) ₂ (acac) ε (λ) λ ⁴ , Ir (tppr) ₂ (dpm)
Is a graph in which ε (λ) λ ⁴ of each is combined into one. PL spectrum of exciplex and Ir (tB
uppm) ₂ (acac) with ε (λ) λ ⁴ overlap (near the local maximum A) from the exciplex to Ir (tBupppm) ₂ (acac) and Ir (tBupppm) ₂ (aca
c) From Ir (tBupppm) ₂ (acac) to Ir (tppr) ₂ (dp) using the overlap (near the local maximum B) of the PL spectrum of c) and Ir (tppr) ₂ (dpm) ε (λ) λ ⁴
It can be seen that energy transfer is possible step by step to m). From the exciplex, the second
It is also possible to transfer energy directly to Ir (tppr) ₂ (dpm) which is a phosphorescent compound. As can be seen from FIG. 22, this is the triplet ML of Ir (tppr) ₂ (dpm).
On the short wavelength side of the CT absorption band (near the maximum value B), the PL spectrum F (λ) of the exciplex is also Ir.
This is because ε (λ) λ ^{4 of} (tppr) ₂ (dpm) overlaps.

The element characteristics of the light emitting element were measured. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 15 shows luminance-current efficiency characteristics of the light-emitting element 1. In FIG. 15, the horizontal axis represents luminance (cd /
m ² ), and the vertical axis represents current efficiency (cd / A). Further, voltage-luminance characteristics are shown in FIG. In FIG. 16, the horizontal axis represents voltage (V) and the vertical axis represents luminance (cd / m ² ). In addition, FIG. 17 shows luminance vs. external quantum efficiency characteristics. In FIG. 17, the horizontal axis represents luminance (cd / m ² ) and the vertical axis represents external quantum efficiency (%). Further, FIG. 18 shows luminance-power efficiency characteristics. In FIG.
The horizontal axis represents luminance (cd / m ² ), and the vertical axis represents power efficiency (%).

As described above, it was found that the light-emitting element 1 exhibited good element characteristics. In particular, FIG. 15 and FIG.
7. As can be seen from FIG. 18, the external quantum efficiency has a practical luminance (
In the vicinity of 1000 cd / m ² ), a high value of 20% or more was shown. Similarly, the current efficiency is about 60 cd / A and the power efficiency is about 60 lm / W.

In addition, FIG. 19 shows an emission spectrum obtained when a current of 0.1 mA was passed through the light-emitting element 1. In FIG. 19, the horizontal axis represents wavelength (nm) and the vertical axis represents emission intensity (arbitrary unit). From FIG.
The light-emitting element 1 includes bis [2- (6-tert-butyl-4-pyrimidinyl-κN3) phenyl-κC] (2,4-pentandionato-κ ² O, O ′) iridium (III) (abbreviation: I
light of green wavelength derived from r (tBupppm) ₂ (acac)) and bis (2,3,5-triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation: Ir (tp
Pr) ₂ (dpm)) was found to show an emission spectrum containing red light in a well-balanced manner.

As described above, it was found that the light-emitting element 1 corresponding to one embodiment of the present invention has favorable light emission efficiency and can obtain light from two types of light emission center materials in a well-balanced manner.

In this example, a manufacturing method and characteristics of a light-emitting element corresponding to one embodiment of the present invention described in Embodiments 1 and 2 will be described. The structural formula of the organic compound used in this example is shown below.

Next, a method for manufacturing the light-emitting element of this example is described.

First, indium tin oxide containing silicon oxide (ITSO) was formed over a glass substrate by a sputtering method, so that the first electrode 101 was formed. The film thickness was 110 nm and the electrode area was 2 mm × 2 mm. Here, the first electrode 101 is an electrode that functions as an anode of the light-emitting element.

Next, as a pretreatment for forming a light emitting element on the substrate, the substrate surface is washed with water, and 200
After baking at 0 ° C. for 1 hour, UV ozone treatment was performed for 370 seconds.

Thereafter, the substrate is introduced into a vacuum vapor deposition apparatus whose internal pressure is reduced to about 10 ⁻⁴ Pa, vacuum baking is performed at 170 ° C. for 30 minutes in a heating chamber in the vacuum vapor deposition apparatus, and then the substrate is released for about 30 minutes. Chilled.

Next, the substrate on which the first electrode 101 is formed is fixed to a substrate holder provided in the vacuum evaporation apparatus so that the surface on which the first electrode 101 is formed is downward, and is approximately 10 ⁻⁴ Pa. Then, the above structural formula (viii) is formed on the first electrode 101 by vapor deposition using resistance heating.
)-[3- (4- (9-phenanthryl) -phenyl] -9-phenyl-9H-carbazole (abbreviation: PCPPn) and molybdenum oxide (VI) are co-evaporated to form the hole injection layer 111. Formed. The film thickness was 33.3 nm, and the weight ratio of PCPPn and molybdenum oxide was adjusted to 1: 0.5 (= PCPPn: molybdenum oxide). Note that the co-evaporation method is an evaporation method in which evaporation is performed simultaneously from a plurality of evaporation sources in one processing chamber.

Next, on the hole injection layer 111, 4-phenyl-4 ′-(
9-phenylfluoren-9-yl) triphenylamine (abbreviation: BPAFLP) 20
The hole transport layer 112 was formed by forming a film having a thickness of nm.

Further, 2- [3 ′-(dibenzothiophen-4-yl) biphenyl-3-yl] dibenzo [f, h] quinoxaline (abbreviation :) represented by the above structural formula (ix) is provided over the hole transport layer 112. 2mDBTBPDBq-II) and 4,4′-di (1-naphthyl) -4 ″-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBNBB) and bis [2- (6-tert-butyl-4-pyrimidinyl-κN3) phenyl-κC] (2,4-pentanedionato-κ ² O represented by the structural formula (v).
, O ′) iridium (III) (abbreviation: Ir (tBupppm) ₂ (acac)) and a weight ratio of 0.8: 0.2: 0.06 (= 2mDBTBPDBq-II: PCNBBB: Ir (
tBupppm) ₂ (acac)) is co-evaporated to 20 nm to form the first light-emitting layer 113a.
And 2mDBTBPDBq-II and the bis (2,3,5-
Triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation: Ir
(Tppr) ₂ (dpm)) and a weight ratio of 1: 0.06 (= 2mDBTBPDBq-II
: Ir (tppr) ₂ (dpm)), the second light emitting layer 113 is co-evaporated to 20 nm.
b was formed. Note that 2mDBTBPDBq-II, which is a host material, and PCBNBB form an exciplex.

Then, 2mDBTBPDBq-II was formed to a thickness of 15 nm over the light-emitting layer 113, and further, bathophenanthroline (abbreviation: BPhen) represented by the above structural formula (vii).
) To a thickness of 15 nm to form an electron transport layer 114.

After the electron transport layer 114 was formed, lithium fluoride (LiF) was then deposited to a thickness of 1 nm to form the electron injection layer 115.

Lastly, as the second electrode 102 functioning as a cathode, aluminum was deposited to a thickness of 200 nm, whereby the light-emitting element 2 of this example was manufactured.

Note that, in the above-described vapor deposition process, the vapor deposition was all performed by a resistance heating method.

Table 2 shows an element structure of the light-emitting element 2 obtained as described above.

The light-emitting element 2 is sealed with a glass substrate so as not to be exposed to the atmosphere in a glove box in a nitrogen atmosphere (a sealing material is applied around the element and heat-treated at 80 ° C. for 1 hour at the time of sealing). It was.

In the light-emitting element 2, as in the light-emitting element 1, the first phosphorescent compound 113Da is Ir (tB
uppm) ₂ (acac) as Ir (tppr) as the second phosphorescent compound 113Db
₂ (dpm) is used. Therefore, for the relationship between the PL spectrum of Ir (tBupppm) ₂ (acac) and ε (λ) λ ⁴ of Ir (tppr) ₂ (dpm), the light-emitting element 1
Because it is the same as, I will omit the repeated explanation. See the description of FIGS. 20A and 20B of the first embodiment. As described above, the first phosphorescent compound 113 in the light-emitting element 2 is used.
It is suggested that energy transfer between Da and the second phosphorescent compound 113Db is performed efficiently.

The element characteristics of the light emitting element were measured. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 24 shows luminance-current efficiency characteristics of the light-emitting element 2. The voltage-luminance characteristics are shown in FIG. In addition, FIG. 26 shows luminance vs. external quantum efficiency characteristics. Further, the luminance-power efficiency characteristics are shown in FIG.
Shown in

As described above, it has been found that the light-emitting element 2 exhibits good element characteristics. In particular, FIG. 24 and FIG.
6. As can be seen from FIG. 27, it has a very good luminous efficiency, and the external quantum efficiency is a practical luminance (
In the vicinity of 1000 cd / m ² ), a high value of 20% or more was shown. Similarly, the current efficiency is very good around 60 cd / A, and the power efficiency is around 60 lm / W.

In addition, an emission spectrum when a current of 0.1 mA is passed through the light-emitting element 2 is shown in FIG. From FIG. 28, the light-emitting element 2 is bis [2- (6-tert-butyl-4-pyrimidinyl-κN 3).
) Phenyl-κC] (2,4-pentanedionato-κ ² O, O ′) iridium (III)
(Abbreviation: Ir (tBupppm) ₂ (acac)) derived from green wavelength light and bis (2, 3,
5-Triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation:
It was found that an emission spectrum including red light derived from Ir (tppr) ₂ (dpm)) is included in a well-balanced manner.

Further, the initial luminance is set to 5000 cd / m ² , and the initial luminance is set to 100 under the condition of constant current density.
FIG. 29 shows the result of the reliability test in the case of the above. From FIG. 29, the light-emitting element 2 has 96% of the initial luminance after 70 hours despite the reliability test of the initial luminance of 5000 cd / m ^2.
Thus, it was found that the light-emitting element had good reliability.

Thus, it was found that the light-emitting element 2 corresponding to one embodiment of the present invention has favorable light emission efficiency and can obtain light from two types of light emission center materials in a well-balanced manner. Further, it was found that the light-emitting element has a high reliability and a long lifetime.

In this example, a manufacturing method and characteristics of a light-emitting element corresponding to one embodiment of the present invention described in Embodiments 1 and 2 will be described. The structural formula of the organic compound used in this example is shown below.

Next, a method for manufacturing the light-emitting element of this example is described.

First, indium tin oxide containing silicon oxide (ITSO) was formed over a glass substrate by a sputtering method, so that the first electrode 101 was formed. The film thickness was 110 nm and the electrode area was 2 mm × 2 mm. Here, the first electrode 101 is an electrode that functions as an anode of the light-emitting element.

Next, as a pretreatment for forming a light emitting element on the substrate, the substrate surface is washed with water, and 200
After baking at 0 ° C. for 1 hour, UV ozone treatment was performed for 370 seconds.

Thereafter, the substrate is introduced into a vacuum vapor deposition apparatus whose internal pressure is reduced to about 10 ⁻⁴ Pa, vacuum baking is performed at 170 ° C. for 30 minutes in a heating chamber in the vacuum vapor deposition apparatus, and then the substrate is released for about 30 minutes. Chilled.

Next, the substrate on which the first electrode 101 is formed is fixed to a substrate holder provided in the vacuum evaporation apparatus so that the surface on which the first electrode 101 is formed is downward, and is approximately 10 ⁻⁴ Pa. After the pressure is reduced to 4,4 ′, 4 ″-(benzene-1,3,5-triyl represented by the above structural formula (i) on the first electrode 101 by an evaporation method using resistance heating. ) Tri (dibenzothiophene) ((abbreviation: DBT3P-II)) and molybdenum oxide (VI) were co-evaporated to form the hole injection layer 111. The film thickness was 40 nm, and DBT3P-II was oxidized. The ratio of molybdenum was adjusted to be 4: 2 (= DBT3P-II: molybdenum oxide) by weight (co-evaporation method) vapor deposition is performed simultaneously from a plurality of evaporation sources in one processing chamber. It is a vapor deposition method.

Next, a film thickness of 4, 4 ′, 4 ″ -tri (N-carbazolyl) triphenylamine (abbreviation: TCTA) represented by the above structural formula (xi) is formed on the hole injection layer 111 with a thickness of 10 nm. Then, a hole transport layer 112 was formed.

Further, on the hole transport layer 112, TCTA and bis (2,3 represented by the above structural formula (vi) are provided.
, 5-triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation: Ir (tppr) ₂ (dpm)) and a weight ratio of 1: 0.1 (= TCTA: Ir (tpp)
r) ₂ (dpm)) is co-evaporated to 10 nm to form the second light-emitting layer 113b, and 2- [3- (dibenzothiophen-4-yl) phenyl] dibenzo represented by the structural formula (iii) above. [F, h] quinoxaline (abbreviation: 2mDBTPDBq-II) and the above structural formula (iv)
4-phenyl-4 ′-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBA1BP) and bis [2- (6
-Tert-butyl-4-pyrimidinyl-κN3) phenyl-κC] (2,4-pentanedionato-κ ² O, O ′) iridium (III) (abbreviation: Ir (tBupppm) ₂ (ac
ac)) and a weight ratio of 0.8: 0.2: 0.05 (= 2mDBTPDBq-II: PCB).
The first light-emitting layer 113a was formed by co-evaporation with a thickness of 5 nm so that A1BP: Ir (tBupppm) ₂ (acac)). The host material 2mDBTPDBq-II and PCB
A1BP forms an exciplex.

After that, 2mDBTPDBq-II and Ir (tBupppm) ₂ (aca
c) and 1: 0.05 (= 2mDBTPDBq-II: Ir (tBupppm) ₂ (aca
c)), 20 nm is co-evaporated to form 2 mDBTPDBq-II to a thickness of 10 nm, and further, bathophenanthroline (abbreviation: BPhen) represented by the structural formula (vii) is 2
The electron transport layer 114 was formed by forming a film to have a thickness of 0 nm.

After the electron transport layer 114 was formed, lithium fluoride (LiF) was then deposited to a thickness of 1 nm to form the electron injection layer 115.

Lastly, as the second electrode 102 functioning as a cathode, aluminum was deposited so as to have a thickness of 200 nm, whereby the light-emitting element 3 of this example was manufactured.

Note that, in the above-described vapor deposition process, the vapor deposition was all performed by a resistance heating method.

Table 3 shows an element structure of the light-emitting element 3 obtained as described above. The light-emitting element 3 is a light-emitting element in which the material for the hole transport layer and the second host material are manufactured using materials that are significantly different from those of the light-emitting elements 1 and 2. Further, the positions of the first light-emitting layer and the second light-emitting layer with respect to the electrodes and the structure of the electron transport layer are also greatly different.

The light emitting device 3 is sealed with a glass substrate in a glove box in a nitrogen atmosphere so as not to be exposed to the atmosphere (a sealing material is applied around the device and heat-treated at 80 ° C. for 1 hour at the time of sealing). It was.

In the light-emitting element 3, as in the light-emitting element 1, Ir (tB
uppm) ₂ (acac) as Ir (tppr) as the second phosphorescent compound 113Db
₂ (dpm) is used. Therefore, for the relationship between the PL spectrum of Ir (tBupppm) ₂ (acac) and ε (λ) λ ⁴ of Ir (tppr) ₂ (dpm), the light-emitting element 1
Because it is the same as, I will omit the repeated explanation. See the description of FIGS. 20A and 20B of the first embodiment. As described above, the first phosphorescent compound 113 in the light-emitting element 3 is used.
It is suggested that energy transfer between Da and the second phosphorescent compound 113Db is performed efficiently.

The element characteristics of the light emitting element were measured. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 30 shows luminance-current efficiency characteristics of the light-emitting element 3. Further, FIG. 31 shows voltage-luminance characteristics. In addition, FIG. 32 shows luminance vs. external quantum efficiency characteristics. Further, the luminance-power efficiency characteristics are shown in FIG.
Shown in

As described above, it was found that the light-emitting element 3 showed good element characteristics. In particular, FIG. 30 and FIG.
2. As can be seen from FIG. 33, it has a very good luminous efficiency, and the external quantum efficiency is a practical luminance (
In the vicinity of 1000 cd / m ² ), a high value of 20% or more was shown. Similarly, the current efficiency is very good around 60 cd / A and the power efficiency is around 70 lm / W.

In addition, FIG. 34 shows an emission spectrum obtained when a current of 0.1 mA was passed through the light-emitting element 3. FIG. 34 shows that the light-emitting element 3 is bis [2- (6-tert-butyl-4-pyrimidinyl-κN3).
) Phenyl-κC] (2,4-pentanedionato-κ ² O, O ′) iridium (III)
(Abbreviation: Ir (tBupppm) ₂ (acac)) derived from green wavelength light and bis (2, 3,
5-Triphenylpyrazinato) (dipivaloylmethanato) iridium (III) (abbreviation:
It was found that an emission spectrum including red light derived from Ir (tppr) ₂ (dpm)) is included in a well-balanced manner.

As described above, the light-emitting element 3 which corresponds to one embodiment of the present invention uses a host material different from that of the light-emitting element 1 and the light-emitting element 2. It was found that this was a light-emitting element capable of obtaining a good balance of light.

In this example, a manufacturing method and characteristics of a light-emitting element corresponding to one embodiment of the present invention described in Embodiments 1 and 2 will be described. The structural formula of the organic compound used in this example is shown below.

Next, a method for manufacturing the light-emitting elements (light-emitting element 4 and light-emitting element 5) of this example is described.

First, indium tin oxide containing silicon oxide (ITSO) was formed over a glass substrate by a sputtering method, so that the first electrode 101 was formed. The film thickness was 110 nm and the electrode area was 2 mm × 2 mm. Here, the first electrode 101 is an electrode that functions as an anode of the light-emitting element.

Next, as a pretreatment for forming a light emitting element on the substrate, the substrate surface is washed with water, and 200
After baking at 0 ° C. for 1 hour, UV ozone treatment was performed for 370 seconds.

Thereafter, the substrate is introduced into a vacuum vapor deposition apparatus whose internal pressure is reduced to about 10 ⁻⁴ Pa, vacuum baking is performed at 170 ° C. for 30 minutes in a heating chamber in the vacuum vapor deposition apparatus, and then the substrate is released for about 30 minutes. Chilled.

Next, the substrate on which the first electrode 101 is formed is fixed to a substrate holder provided in the vacuum evaporation apparatus so that the surface on which the first electrode 101 is formed is downward, and is approximately 10 ⁻⁴ Pa. After reducing the pressure to 4-phenyl-4 ′-(9-phenylfluoren-9-yl) tril represented by the above structural formula (ii) on the first electrode 101 by a vapor deposition method using resistance heating. A hole injection layer 111 was formed by co-evaporation of phenylamine (abbreviation: BPAFLP) and molybdenum oxide (VI). The film thickness was 33.3 nm, and the weight ratio of BPAFLP to molybdenum oxide was adjusted to 1: 0.5 (= BPAFLP: molybdenum oxide). Note that the co-evaporation method is an evaporation method in which evaporation is performed simultaneously from a plurality of evaporation sources in one processing chamber.

Next, a BPAFLP film was formed to a thickness of 20 nm on the hole injection layer 111 to form a hole transport layer 112.

Further, 2- [3- (dibenzothiophen-4-yl) phenyl] dibenzo [f, h] quinoxaline (abbreviation: 2mDBT) represented by the above structural formula (iii) is formed over the hole transport layer 112.
PDBq-II) and 4-phenyl-4 ′-(9-phenyl-9H-carbazol-3-yl) triphenylamine (abbreviation: PCBA1BP) represented by the above structural formula (iv) and the above structural formula (v) Bis [2- (6-tert-butyl-4-pyrimidinyl-κN3]
) Phenyl-κC] (2,4-pentanedionato-κ ² O, O ′) iridium (III)
(Abbreviation: Ir (tBupppm) ₂ (acac)) with a weight ratio of 0.8: 0.2: 0.06.
(= 2mDBTPDBq-II: PCBA1BP: Ir (tBupppm) ₂ (acac)
) To form a first light-emitting layer 113a by 2 nm DBTPDBq-I
I and the bis {4,6-dimethyl-2- [3- (3,5-dimethylphenyl) -5-phenyl-2-pyrazinyl-κN] phenyl-κC} represented by the structural formula (xii) (2) , 6-
Dimethyl-3,5-heptanedionato-κ ² O, O ″) iridium (III) (abbreviation:
[Ir (dmdppr−P) ₂ (divm)]) in a weight ratio of 1: 0.06 (= 2 mDB
TPDBq-II: 20n so that [Ir (dmdppr-P) ₂ (divm)])
m was co-evaporated to form the second light-emitting layer 113b. 2mDBTPD as host material
Bq-II and PCBA1BP form an exciplex.

After that, 2mDBTPDBq-II was formed to a thickness of 15 nm over the light-emitting layer 113, and further, bathophenanthroline (abbreviation: BPhen) represented by the above structural formula (vii).
Was deposited to a thickness of 15 nm to form an electron transport layer 114.

After the electron transport layer 114 was formed, lithium fluoride (LiF) was then deposited to a thickness of 1 nm to form the electron injection layer 115.

Lastly, as the second electrode 102 functioning as a cathode, aluminum was deposited to a thickness of 200 nm, whereby the light-emitting element 4 of this example was manufactured.

The light-emitting element 5 includes tris [2- (6-tert-butyl-4-pyrimidinyl-κN3) in which [Ir (tBupppm) ₂ (acac)] in the first light-emitting layer 113a is represented by the above structural formula (xiii). ) Phenyl-κC] iridium (III) (abbreviation: [Ir (tBupppm)
₃ ) It was fabricated in the same manner as the light-emitting element 4 except that it was fabricated instead of]).

Note that, in the above-described vapor deposition process, the vapor deposition was all performed by a resistance heating method.

Table 4 shows an element structure of the light-emitting element 4 obtained as described above, and Table 5 shows an element structure of the light-emitting element 5.

The operation of sealing the light-emitting element 4 and the light-emitting element 5 with a glass substrate in a glove box in a nitrogen atmosphere so as not to be exposed to the atmosphere (a sealant is applied around the element and 8
(Heat treatment at 0 ° C. for 1 hour).

In the light-emitting element 4, the first phosphorescent compound 113Da is Ir (tBupppm) ₂ (ac
ac) as the second phosphorescent compound 113Db [Ir (dmdppr-P) ₂ (di
bm)]. Here, the relationship between the PL spectrum of Ir (tBupppm) ₂ (acac) and ε (λ) λ ⁴ of [Ir (dmdppr−P) ₂ (divm)] will be described. Note that λ is a wavelength and ε (λ) is a molar extinction coefficient.

First, FIG. 45A shows [Ir (dmd] which is the light emitting element 4 second phosphorescent compound 113Db.
The graph showing the molar extinction coefficient ε (λ) and ε (λ) λ ^{4 of} ppr-P) ₂ (divm)] is shown. The molar extinction coefficient ε (λ) does not have a conspicuous peak in the region on the long wavelength side, whereas in the graph of ε (λ) λ ⁴ , the maximum value of 509 nm and 550 nm, 605 n
There is a peak (mountain) with a shoulder near m. This peak is [Ir (dmdppr-P)
₂ (divm)] triplet MLCT absorption, the first phosphorescent compound 11
By superimposing the 3Da emission peak, the efficiency of energy transfer can be greatly increased.

FIG. 45B shows Ir (tBuppp) which is the first phosphorescent compound 113 Da of the light-emitting element 4.
m) A graph showing the PL spectrum F (λ) of ₂ (acac) and ε (λ) λ ⁴ of [Ir (dmdppr-P) ₂ (divm)] which is the second phosphorescent compound 113Db is shown. From this graph, the peak where the peak of the PL spectrum F (λ) of Ir (tBupppm) ₂ (acac) exists and the longest wavelength side of ε (λ) λ ⁴ of [Ir (dmdppr-P) ₂ (divm)] It is understood that this is a combination in which energy transfer is performed very efficiently. In addition, Ir which is the first phosphorescent compound 113Da
The emission peak of (tBupppm) ₂ (acac) is present at 546 nm, in the spectrum representing ε (λ) λ ⁴ of [Ir (dmdppr-P) ₂ (divm)], which is the second phosphorescent compound 113Db. Since the maximum on the long wavelength side exists at 509 nm, the difference is 37 nm.
It is. Since 546 nm corresponds to 2.27 eV and 509 nm corresponds to 2.44 eV, the difference is 0.17 eV, which is smaller than 0.2 eV, suggesting that efficient energy transfer is also performed from the peak position. Is done. In addition, [Ir (dmdppr-P) ₂
In the spectrum representing ε (λ) λ ⁴ of (divb)], the long-wavelength side maximum (maximum value C) and the emission spectrum F (λ) of Ir (tBupppm) ₂ (acac) hardly overlap, The peak having the maximum value C in the spectrum representing ε (λ) λ ⁴ of Ir (dmdppr−P) ₂ (divm)] has a broad shape on the long wavelength side, and this long wavelength side spectrum and Ir ( The emission spectrum F (λ) of tBupppm) ₂ (acac) has a large overlap. Therefore, very good energy transfer is realized

In the light-emitting element 4, 2mDBTPDBq-II which is the first host material and PCBA1BP which is the first organic compound form an exciplex, and Ir which is the first phosphorescent compound 113Da.
Energy transfer is efficiently performed to (tBupppm) ₂ (acac). Since these relationships are the same as those of the light-emitting element 1 and are described in detail in Example 1, repeated descriptions are omitted. See the corresponding description in Example 1.

FIG. 46 shows the PL spectrum F (λ), Ir (tBupppm) ₂ (acac) of the exciplex.
) PL spectrum F (λ), [Ir (dmdppr−P) ₂ (divm)] PL spectrum F (λ), Ir (tBupppm) ₂ (acac) ε (λ) λ ⁴ , [Ir (dmd
ppr−P) ₂ (divm)] is a graph that summarizes ε (λ) λ ⁴ into one. Using the overlap of the PL spectrum of the exciplex and Ir (tBupppm) ₂ (acac) ε (λ) λ ⁴ (near the local maximum A), from the exciplex to Ir (tBupppm) ₂ (acac) and I
The PL spectrum of r (tBupppm) ₂ (acac) and [Ir (dmdppr-P) ₂ (
dibm)] with ε (λ) λ ⁴ (from the maximum C to around 650 nm), Ir (
It can be seen that energy transfer is possible in a stepwise manner from tBupppm) ₂ (acac) to [Ir (dmdppr-P) ₂ (divm)]. Note that energy can also be directly transferred from the exciplex to [Ir (dmdppr-P) ₂ (divm)], which is the second phosphorescent compound. As can be seen from FIG. 46, [Ir (dmdppr−P) ₂ (dib
m)] in the triplet MLCT absorption band (near the maximum C), the PL spectrum F (λ) of the exciplex
This is because ε (λ) λ ^{4 of} [Ir (dmdppr−P) ₂ (divm)] overlaps.

In the light-emitting element 5, Ir (tBupppm) ₃ is used as the first phosphorescent compound 113Da, and [Ir (dmdppr-P) ₂ (divm)] is used as the second phosphorescent compound 113Db. Here, the PL spectrum of Ir (tBupppm) ₃ and [Ir (dmdppr
-P) ₂ (divm)] will be described in relation to ε (λ) λ ⁴ . Where λ is the wavelength and ε (λ
) Is the molar extinction coefficient.

First, FIG. 47A shows the light-emitting element 4 second phosphorescent compound 113Db [Ir (dmd
The graph showing the molar extinction coefficient ε (λ) and ε (λ) λ ^{4 of} ppr-P) ₂ (divm)] is shown. The molar extinction coefficient ε (λ) does not have a conspicuous peak in the region on the long wavelength side, whereas in the graph of ε (λ) λ ⁴ , the maximum value of 509 nm and 550 nm, 605 n
There is a peak (mountain) with a shoulder near m. This peak is [Ir (dmdppr-P)
₂ (divm)] triplet MLCT absorption, the first phosphorescent compound 11
By superimposing the 3Da emission peak, the efficiency of energy transfer can be greatly increased.

FIG. 47B shows Ir (tBuppp) which is the first phosphorescent compound 113 Da of the light-emitting element 5.
_m) a ₃ of the PL spectrum F and (lambda) second phosphorescent compound 113 dB [Ir (dm
The graph showing ε (λ) λ ⁴ of (dppr−P) ₂ (divm)] is shown. From this graph, the peak where the peak of the PL spectrum F (λ) of Ir (tBupppm) ₃ exists and [Ir (dm
dppr-P) ₂ (divm)] has a peak that has a maximum value on the longest wavelength side of ε (λ) λ ⁴ , and it can be seen that the energy transfer is a highly efficient combination. In addition, the emission peak of Ir (tBupppm) ₃ which is the first phosphorescent compound 113Da is present at 540 nm, and [Ir (dmdp] which is the second phosphorescent compound 113Db.
pr−P) ₂ (divm)] has a local maximum at 509 nm in the spectrum representing ε (λ) λ ⁴ , and the difference is 31 nm. 540 nm is 2.30 eV, 50
Since 9 nm corresponds to 2.44 eV, the difference is 0.14 eV, which is smaller than 0.2 eV, suggesting that efficient energy transfer is also performed from the peak position. Note that the long wavelength maximum (maximum value C) and the emission spectrum F (λ) of Ir (tBupppm) ₃ in the spectrum representing ε (λ) λ ⁴ of [Ir (dmdppr−P) ₂ (divm)] are Although there is almost no overlap, ε of [Ir (dmdppr−P) ₂ (divm)]
The peak having the maximum value C in the spectrum representing (λ) λ ⁴ has a broad shape on the long wavelength side, and this long wavelength side spectrum and Ir (tBupppm) ₃ emission spectrum F (
λ) has a large overlap. Therefore, very good energy transfer is realized

Subsequently, FIG. 48A shows Ir (tB) which is the first phosphorescent compound 113Da of the light-emitting element 5.
The graph shows the molar extinction coefficient ε (λ) and ε (λ) λ ^{4 of} uppm) ₃ . ε (λ
) In the graph of λ ⁴ , maximum values having large intensities at 409 and 465 nm and 49
There is a peak (mountain) with a shoulder at 4 nm. This peak (mountain) is the triplet MLCT absorption of Ir (tBupppm) _3. By superimposing the emission peak of the energy donor on this peak, the efficiency of energy transfer can be greatly increased.

Here, in the light-emitting element 5 of this example, 2mDBTPDBq-II, which is the first host material, is used.
And PCBA1BP which is the first organic compound form an exciplex 113Ec, and energy is supplied from the exciplex 113Ec to the first phosphorescent compound 113Da. FIG. 23 is a diagram showing PL spectra of 2mDBTPDBq-II, PCBA1BP, and a mixed film thereof (mass ratio of 0.8: 0.2).
It can be seen that -II and PCBA1BP which is the first organic compound form exciplex 113Ec. FIG. 48B shows a graph representing the PL spectrum F (λ) of the exciplex and ε (λ) λ ⁴ of Ir (tBupppm) ₃ which is the first phosphorescent compound 113Da. From this graph, a part of the wavelength range having half the intensity of the peak where the peak of the PL spectrum F (λ) of the exciplex exists and the maximum on the longest wavelength side of ε (λ) λ ⁴ of Ir (tBupppm) ₃ A part of the wavelength range having half the intensity in the mountain having the value overlaps, and it can be seen that the energy transfer is performed efficiently.

FIG. 49 shows the PL spectrum F (λ) of the exciplex, the PL spectrum F (λ) of Ir (tBupppm) ₃ , and the PL spectrum F (λ of [Ir (dmdppr−P) ₂ (divm)].
), Ir (tBupppm) ₃ ε (λ) λ ⁴ , [Ir (dmdppr-P) ₂ (divm
)] Is a graph in which ε (λ) λ ⁴ is combined into one. The PL spectrum of the exciplex and Ir (
tBuppm) ₃ with ε (λ) λ ⁴ (near the maximum A)
(TBupppm) ₃ and then the Ir spectrum of Ir (tBupppm) ₃ and [Ir (d
mdppr−P) ₂ (divm)] with ε (λ) λ ⁴ (from maximum C to 650 nm
) From Ir (tBupppm) ₃ to [Ir (dmdppr-P) ₂ (divm)
It can be seen that energy can be transferred step by step. Note that energy can also be directly transferred from the exciplex to [Ir (dmdppr-P) ₂ (divm)], which is the second phosphorescent compound. As can be seen from FIG. 49, [Ir (dmdppr-P) ₂
(Divm)] triplet MLCT absorption band (near maximum C), and the PL spectrum F (λ) of the exciplex overlaps with ε (λ) λ ^{4 of} [Ir (dmdppr-P) ₂ (divm)]. Because it is.

The element characteristics of these light emitting elements were measured. The measurement was performed at room temperature (atmosphere kept at 25 ° C.).

FIG. 35 shows luminance-current efficiency characteristics of the light-emitting element 4. In addition, FIG. 36 shows voltage-luminance characteristics. In addition, FIG. 37 shows luminance vs. external quantum efficiency characteristics. Further, the luminance-power efficiency characteristic is shown in FIG.
Shown in

As described above, it was found that the light-emitting element 4 exhibited favorable element characteristics. In particular, FIG. 35 and FIG.
7. As can be seen from FIG. 38, the external quantum efficiency has a practical luminance (
In the vicinity of 1000 cd / m ² ), a high value of 20% or more was shown. Similarly, the current efficiency is about 50 cd / A, and the power efficiency is about 50 lm / W.

In addition, FIG. 39 shows an emission spectrum obtained when a current of 0.1 mA was passed through the light-emitting element 4. In FIG. 39, the horizontal axis represents wavelength (nm) and the vertical axis represents emission intensity (arbitrary unit). From FIG.
The light-emitting element 4 includes green light derived from [Ir (tBupppm) ₂ (acac)] and [Ir (t
dmdppr-P) ₂ (divm)] was found to exhibit an emission spectrum containing light in red having a good balance.

FIG. 40 shows luminance-current efficiency characteristics of the light-emitting element 5. Further, voltage-luminance characteristics are shown in FIG. Further, FIG. 42 shows luminance vs. external quantum efficiency characteristics. Further, the luminance-power efficiency characteristics are shown in FIG.
Shown in

As described above, it was found that the light-emitting element 5 showed good element characteristics. In particular, FIG. 40 and FIG.
2. As can be seen from FIG. 43, it has a very good luminous efficiency, and the external quantum efficiency is a practical luminance (
In the vicinity of 1000 cd / m ² ), a high value of around 25% was shown. Similarly, the current efficiency shows a very good value of around 65 cd / A and the power efficiency of around 70 lm / W.

In addition, an emission spectrum when a current of 0.1 mA is passed through the light-emitting element 5 is shown in FIG. In FIG. 44, the horizontal axis represents wavelength (nm) and the vertical axis represents emission intensity (arbitrary unit). From FIG.
The light-emitting element 5 includes green light derived from [Ir (tBupppm) ₂ (acac)] and [Ir (t
dmdppr-P) ₂ (divm)] was found to exhibit an emission spectrum containing light in red having a good balance.

As described above, it is found that the light-emitting element 4 and the light-emitting element 5 which correspond to one embodiment of the present invention have favorable light emission efficiency, and are light-emitting elements from which light from two kinds of emission center substances can be obtained in a balanced manner. It was.

(Reference Example 1)
The organometallic complex used in the above embodiment, bis [2- (6-tert-butyl-4-pyrimidinyl-κN3) phenyl-κC] (2,4-pentandionato-κ ² O, O ′) iridium ( III) A synthesis example of (abbreviation: [Ir (tBupppm) ₂ (acac)]) is shown. The structure of [Ir (tBupppm) ₂ (acac)] is shown below.

<Step 1; 4-tert-butyl-6-phenylpyrimidine (abbreviation: HtBupppm)
Synthesis)
First, 22.5 g of 4,4-dimethyl-1-phenylpentane-1,3-dione and 50 g of formamide were placed in an eggplant flask equipped with a reflux tube, and the interior was purged with nitrogen. The reaction solution was refluxed for 5 hours by heating the reaction vessel. Thereafter, this solution was poured into an aqueous sodium hydroxide solution, and the organic layer was extracted with dichloromethane. The obtained organic layer was washed with water and saturated brine, and dried over magnesium sulfate. The solution after drying was filtered. After the solvent of this solution was distilled off, the obtained residue was purified by silica gel column chromatography using hexane: ethyl acetate = 10: 1 (volume ratio) as a developing solvent, and pyrimidine derivative HtBupp.
m was obtained (colorless oil, yield 14%). The synthesis scheme of Step 1 is shown below.

<Step 2; Synthesis of di-μ-chloro-bis [bis (6-tert-butyl-4-phenylpyrimidinato) iridium (III)] (abbreviation: [Ir (tBupppm) ₂ Cl] ₂ )>
Next, 15 mL of 2-ethoxyethanol and 5 mL of water, HtBupp obtained in Step 1 above
1.49 g of m and iridium chloride hydrate (IrCl ₃ .H ₂ O) 1.04 g were placed in a recovery flask equipped with a reflux tube, and the atmosphere in the flask was replaced with argon. Then microwave (2.4
(5 GHz 100 W) was irradiated for 1 hour to react. After the solvent was distilled off, the resulting residue was suction filtered and washed with ethanol to obtain a binuclear complex [Ir (tBupppm) ₂ Cl] ₂ (yellow green powder, yield 73%). The synthesis scheme of Step 2 is shown below.

<Step 3; Synthesis of (acetylacetonato) bis (6-tert-butyl-4-phenylpyrimidinato) iridium (III) (abbreviation: [Ir (tBupppm) ₂ (acac)]>
Further, 40 mL of 2-ethoxyethanol and the binuclear complex [Ir (tB
uppm) ₂ Cl] ₂ 1.61 g, acetylacetone 0.36 g, sodium carbonate 1.
27 g was placed in an eggplant flask equipped with a reflux tube, and the atmosphere in the flask was replaced with argon. Then, the microwave (2.45 GHz 120W) was irradiated for 60 minutes, and it was made to react. The solvent was distilled off, and the resulting residue was suction filtered with ethanol and washed with water and ethanol. This solid was dissolved in dichloromethane, and celite (Wako Pure Chemical Industries, Ltd., catalog number: 531-1).
6855), and filtered through a filter aid laminated in the order of alumina and celite. By recrystallizing the solid obtained by distilling off the solvent with a mixed solvent of dichloromethane and hexane,
The target product was obtained as a yellow powder (yield 68%). The synthesis scheme of Step 3 is shown below.

The analysis results of the yellow powder obtained in Step 3 above by nuclear magnetic resonance spectroscopy ( ¹ H NMR) are shown below. From this result, it was found that an organometallic complex Ir (tBupppm) ₂ (acac) was obtained.

¹ H NMR. δ (CDCl ₃ ): 1.50 (s, 18H), 1.79 (s, 6H),
5.26 (s, 1H), 6.33 (d, 2H), 6.77 (t, 2H), 6.85 (t,
2H), 7.70 (d, 2H), 7.76 (s, 2H), 9.02 (s, 2H).

(Reference Example 2)
In this reference example, the organometallic iridium complex used in the examples, bis {4,6-dimethyl-2,
-[3- (3,5-dimethylphenyl) -5-phenyl-2-pyrazinyl-κN] phenyl-κC} (2,6-dimethyl-3,5-heptanedionato-κ ² O, O ″) iridium ( III) A method for synthesizing (abbreviation: [Ir (dmdppr-P) ₂ (divm)]) will be described. Note that a structure of [Ir (dmdppr-P) ₂ (divm)] (abbreviation) is shown below.

<Step 1: 2,3-bis (3,5-dimethylphenyl) pyrazine (abbreviation: Hdmdp)
pr) Synthesis>
First, 5.00 g of 2,3-dichloropyrazine and 10,5-dimethylphenylboronic acid 10
. 23 g, sodium carbonate 7.19 g, bis (triphenylphosphine) palladium (I
I) 0.29 g of dichloride (abbreviation: Pd (PPh ₃ ) ₂ Cl ₂ ), 20 mL of water, and 20 mL of acetonitrile were placed in an eggplant flask equipped with a reflux tube, and the interior was purged with argon. The reaction vessel was heated by irradiation with microwaves (2.45 GHz, 100 W) for 60 minutes. Here further 2.55-g 3,5-dimethylphenylboronic acid, 1.80 g sodium carbonate
, Pd (PPh ₃ ) ₂ Cl ₂ 0.070 g, 5 mL of water, and 5 mL of acetonitrile were placed in a flask and heated again by irradiation with microwaves (2.45 GHz 100 W) for 60 minutes.

Thereafter, water was added to this solution, and the organic layer was extracted with dichloromethane. The obtained organic layer was washed with a saturated aqueous sodium hydrogen carbonate solution, water and saturated brine, and dried over magnesium sulfate. The solution after drying was filtered. After the solvent of this solution was distilled off, the obtained residue was purified by flash column chromatography using hexane: ethyl acetate = 5: 1 (volume ratio) as a developing solvent. The solvent was distilled off, and the resulting solid was dissolved in dichloromethane: ethyl acetate = 10:
Purification by flash column chromatography using 1 (volume ratio) as a developing solvent gave the target pyrazine derivative Hdmdppr (abbreviation) (white powder, 44% yield). For microwave irradiation, a microwave synthesizer (Discover manufactured by CEM) was used. The synthesis scheme of Step 1 is shown in (a-1) below.

<Step 2: Synthesis of 2,3-bis (3,5-dimethylphenyl) -5-phenylpyrazine (abbreviation: Hdmdppr-P)>
First, 4.28 g of Hdmpppr (abbreviation) obtained in Step 1 above and dryTHF 80 m
L was placed in a three-necked flask, and the inside was replaced with nitrogen. After cooling the flask with ice, phenyl lithium (
(1.9 M butyl ether solution) 9.5 mL was added dropwise and stirred at room temperature for 23 and a half hours. The reaction solution was poured into water and extracted with chloroform. The obtained organic layer was washed with water and saturated brine, and dried over magnesium sulfate. Manganese oxide was added to the resulting mixture and stirred for 30 minutes. Thereafter, the solution was filtered and the solvent was distilled off. The obtained residue was purified by silica gel column chromatography using dichloromethane as a developing solvent to obtain the target pyrazine derivative Hdmdppr.
-P (abbreviation) was obtained (orange oil, yield 26%). The synthesis scheme of Step 2 is as follows (a
-2).

<Step 3: Di-μ-chloro-tetrakis {4,6-dimethyl-2- [3- (3,5-
Synthesis of (Dimethylphenyl) -5-phenyl-2-pyrazinyl-κN] phenyl-κC} diiridium (III) (abbreviation: [Ir (dmdppr-P) ₂ Cl] ₂ )>
Next, 15 mL of 2-ethoxyethanol and 5 mL of water, Hdmpd obtained in Step 2 above
pr-P (abbreviation) 1.40 g, iridium chloride hydrate (IrCl ₃ .H ₂ O) (Sigma)
0.51 g (manufactured by a-Aldrich) was placed in an eggplant flask equipped with a reflux tube, and the inside of the flask was purged with argon. Then, the microwave (2.45 GHz 100W) was irradiated for 1 hour, and was made to react. After the solvent was distilled off, the resulting residue was suction filtered and washed with ethanol to obtain a binuclear complex [Ir (dmdppr-P) ₂ Cl] ₂ (abbreviation) (reddish brown powder, yield 58%
). The synthesis scheme of Step 3 is shown in (a-3) below.

<Step 4: Bis {4,6-dimethyl-2- [3- (3,5-dimethylphenyl) -5
-Phenyl-2-pyrazinyl-κN] phenyl-κC} (2,6-dimethyl-3,5-heptanedionato-κ ² O, O ″) iridium (III) (abbreviation: [Ir (dmdppr
-P) ₂ (divm)] Synthesis>
Furthermore, 30 mL of 2-ethoxyethanol, the binuclear complex [Ir (d
mdppr-P) ₂ Cl] ₂ 0.94 g, diisobutyrylmethane (abbreviation: Hdivm)
0.23 g and 0.52 g of sodium carbonate were placed in an eggplant flask equipped with a reflux tube, and the atmosphere in the flask was replaced with argon. Then, it heated by irradiating with a microwave (2.45 GHz 120W) for 60 minutes. The solvent was distilled off, and the resulting residue was suction filtered with ethanol. The obtained solid was washed with water and ethanol, and recrystallized with a mixed solvent of dichloromethane and ethanol, whereby the organometallic complex of the present invention [Ir (dmdppr-P) ₂ (divm)].
(Abbreviation) was obtained as a dark red powder (yield 75%). The synthesis scheme of Step 4 is as follows (a
-4).

In addition, the analysis result by the nuclear magnetic resonance spectroscopy (< ¹ > H-NMR) of the dark red powder obtained by the said synthesis method is shown below. From this result, the organometallic complex [Ir (dmdp
pr-P) ₂ (divm)] (abbreviation) was obtained.

¹ H-NMR. δ (CDCl ₃ ): 0.79 (d, 6H), 0.96 (d, 6H), 1
. 41 (s, 6H), 1.96 (s, 6H), 2.24-2.28 (m, 2H), 2.4
1 (s, 12H), 5.08 (s, 1H), 6.46 (s, 2H), 6.82 (s, 2H)
), 7.18 (s, 2H), 7.39-7.50 (m, 10H), 8.03 (d, 4H)
, 8.76 (s, 2H).

DESCRIPTION OF SYMBOLS 10 Electrode 11 Electrode 101 1st electrode 102 2nd electrode 103 EL layer 111 Hole injection layer 112 Hole transport layer 113 Light emitting layer 113a 1st light emitting layer 113Da 1st phosphorescent compound 113Ha 1st host material 113b second light emitting layer 113Db second phosphorescent compound 113Hb second host material 113A first organic compound 113Ec exciplex 114 electron transport layer 115 electron injection layer 400 substrate 401 first electrode 402 auxiliary electrode 403 EL layer 404 Second electrode 405 Sealing material 406 Sealing material 407 Sealing substrate 412 Pad 420 IC chip 601 Driving circuit portion (source line driving circuit)
602 Pixel portion 603 Drive circuit portion (gate line drive circuit)
604 Sealing substrate 605 Sealing material 607 Space 608 Wiring 609 FPC (flexible printed circuit)
610 Element substrate 611 TFT for switching
612 Current control TFT
613 First electrode 614 Insulator 616 EL layer 617 Second electrode 618 Light-emitting element 623 n-channel TFT
624 p-channel TFT
625 Drying material 901 Case 902 Liquid crystal layer 903 Backlight unit 904 Case 905 Driver IC
906 terminal 951 substrate 952 electrode 953 insulating layer 954 partition layer 955 EL layer 956 electrode 1001 substrate 1002 base insulating film 1003 gate insulating film 1006 gate electrode 1007 gate electrode 1008 gate electrode 1020 first interlayer insulating film 1021 second interlayer insulating film 1022 Electrode 1024W First electrode 1024R of light emitting element First electrode 1024G of light emitting element First electrode 1024B of light emitting element First electrode 1025 of light emitting element Partition 1028 EL layer 1029 Second electrode 1031 of light emitting element Sealing Substrate 1032 Sealing material 1033 Transparent base material 1034R Red colored layer 1034G Green colored layer 1034B Blue colored layer 1035 Black layer (black matrix)
1036 Overcoat layer 1037 Third interlayer insulating film 1040 Pixel portion 1041 Drive circuit portion 1042 Peripheral portion 1044W White light emitting region 1044R Red light emitting region 1044B Blue light emitting region 1044G Green light emitting region 2001 Housing 2002 Light source 3001 Lighting device 3002 Display device 5000 Display 5001 Display 5002 Display 5003 Display 5004 Display 5005 Display 7101 Housing 7103 Display unit 7105 Stand 7107 Display unit 7109 Operation key 7110 Remote controller 7201 Main body 7202 Housing 7203 Display unit 7204 Keyboard 7205 External connection port 7206 Pointing device 7210 Second display portion 7301 Case 7302 Case 7303 Connection portion 7304 Display portion 7305 Display portion 7306 Speaker portion 7307 Recording medium Input portion 7308 LED lamp 7309 Operation key 7310 Connection terminal 7311 Sensor 7400 Mobile phone 7401 Case 7402 Display portion 7403 Operation button 7404 External connection port 7405 Speaker 7406 Microphone 9033 Fastener 9034 Switch 9035 Power switch 9036 Switch 9038 Operation switch 9630 Case 9631 Display Part 9631a display part 9631b display part 9632a touch panel area 9632b touch panel area 9633 solar cell 9634 charge / discharge control circuit 9635 battery 9636 DCDC converter 9537 operation key 9638 converter 9539 button

Claims (7)

A first electrode, a second electrode, a first light emitting layer, and a second light emitting layer;
The first light emitting layer is provided between the first electrode and the second light emitting layer,
The second light emitting layer is provided between the first light emitting layer and the second electrode,
The first light-emitting layer includes a first phosphorescent compound, a first host material, and a first organic compound,
The second light emitting layer has a second phosphorescent compound and a second host material,
The first host material and the first organic compound are a combination that forms an exciplex,
The emission of the second phosphorescent compound has a longer wavelength than the emission of the first phosphorescent compound;
The peak having the maximum value on the longest wavelength side of the function represented by ε (λ) λ ⁴ of the second phosphorescent compound is the phosphorescence emission spectrum F (λ) of the first phosphorescent compound. The light emitting element which overlaps with the peak which has the maximum value of.
(Where ε (λ) represents the molar extinction coefficient and is a function of wavelength λ) In claim 1,
The first electrode can function as a cathode;
The light emitting element, wherein the second electrode can function as an anode. In claim 1 or 2,
A light emitting element in which the first light emitting layer and the second light emitting layer are in contact with each other.   The illuminating device which has a light emitting element as described in any one of Claims 1 thru | or 3.   A light emitting device comprising: the light emitting element according to claim 1; and means for controlling the light emitting element.   A display device comprising the light emitting element according to claim 1 in a display portion, and means for controlling the light emitting element.   The electronic device which has a light emitting element as described in any one of Claims 1 thru | or 3.