JP2019070111A5 - - Google Patents
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- Publication number
- JP2019070111A5 JP2019070111A5 JP2018170736A JP2018170736A JP2019070111A5 JP 2019070111 A5 JP2019070111 A5 JP 2019070111A5 JP 2018170736 A JP2018170736 A JP 2018170736A JP 2018170736 A JP2018170736 A JP 2018170736A JP 2019070111 A5 JP2019070111 A5 JP 2019070111A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- polymerization initiator
- radical polymerization
- gel
- reaction solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 claims 10
- 239000007870 radical polymerization initiator Substances 0.000 claims 5
- 239000000178 monomer Substances 0.000 claims 4
- 239000002243 precursor Substances 0.000 claims 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 239000012986 chain transfer agent Substances 0.000 claims 3
- 239000007810 chemical reaction solvent Substances 0.000 claims 3
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- ZUDLIFVTNPYZJH-UHFFFAOYSA-N 1,1,2,2-tetraphenylethylbenzene Chemical compound C1=CC=CC=C1C(C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C=1C=CC=CC=1)C1=CC=CC=C1 ZUDLIFVTNPYZJH-UHFFFAOYSA-N 0.000 claims 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 230000001588 bifunctional effect Effects 0.000 claims 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 150000001451 organic peroxides Chemical class 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims 1
- 150000003573 thiols Chemical class 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/728,385 | 2017-10-09 | ||
| US15/728,385 US10626224B2 (en) | 2017-10-09 | 2017-10-09 | Method to produce transparent polymer aerogels using chain transfer agents |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019070111A JP2019070111A (ja) | 2019-05-09 |
| JP2019070111A5 true JP2019070111A5 (https=) | 2021-10-14 |
| JP7101089B2 JP7101089B2 (ja) | 2022-07-14 |
Family
ID=64017253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018170736A Active JP7101089B2 (ja) | 2017-10-09 | 2018-09-12 | 連鎖移動剤を使用して透明ポリマーエアロゲルを生成する方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US10626224B2 (https=) |
| EP (1) | EP3466986B1 (https=) |
| JP (1) | JP7101089B2 (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10960224B2 (en) | 2017-01-12 | 2021-03-30 | Janssen Pharmaceutica Nv | Trans-orbital infrared light therapy |
| US10836855B2 (en) | 2018-07-26 | 2020-11-17 | Palo Alto Research Center Incorporated | Method to produce colorless, high porosity, transparent polymer aerogels |
| US11614409B2 (en) | 2018-12-20 | 2023-03-28 | Palo Alto Research Center Incorporated | Printed sensor with vibrant colorimetric particles |
| US10995191B2 (en) | 2018-12-20 | 2021-05-04 | Palo Alto Research Center Incoporated | High optical transparency polymer aerogels using low refractive index monomers |
| US10874874B2 (en) | 2019-04-15 | 2020-12-29 | Janssen Pharmaceutica Nv | Transorbital NIR light therapy device |
| US10926102B2 (en) | 2019-04-15 | 2021-02-23 | Janssen Pharmaceutica Nv | Transorbital NIR LIGHT THERAPY DEVICES |
| CN110437496B (zh) * | 2019-07-19 | 2020-10-27 | 淮阴工学院 | 一种用于高效水蒸发的聚硅氧烷气凝胶复合材料及其制备方法和应用 |
| WO2021132296A1 (ja) * | 2019-12-23 | 2021-07-01 | 国立研究開発法人理化学研究所 | エアロゲル及びその製造方法 |
| US11493451B2 (en) | 2019-12-23 | 2022-11-08 | Palo Alto Research Center Incorporated | Colorimetric drug test strip using porous support material |
| US11612852B2 (en) | 2020-05-28 | 2023-03-28 | Palo Alto Research Center Incorporated | Tunable, rapid uptake, aminopolymer aerogel sorbent for direct air capture of CO2 |
| US12491494B2 (en) | 2021-04-02 | 2025-12-09 | Genesee Valley Innovations, LLC | Moisture swing CO2 sorbents with enhanced capacity and kinetics |
| EP4582381A3 (en) | 2022-03-09 | 2025-10-01 | Cardinal CG Company | Silica wet gel and aerogel |
| US20240024852A1 (en) * | 2022-07-22 | 2024-01-25 | Palo Alto Research Center Incorporated | Adsorbent aerogel membrane sheets for direct air capture of co2 |
| EP4652349A1 (en) | 2023-01-20 | 2025-11-26 | Cardinal CG Company | Aerogel molding and handling technology, multiple-pane insulating glazing units incorporating aerogel, and ig unit manufacturing methods |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2736342B1 (fr) | 1995-07-07 | 1999-01-29 | Univ Claude Bernard Lyon | Procede pour la fabrication d'aerogels de silice monolithiques et aerogels de silice ainsi obtenus |
| JP3296153B2 (ja) | 1995-09-06 | 2002-06-24 | 住友化学工業株式会社 | スチレン系重合体の製造方法、スチレン系樹脂組成物及びその成形品 |
| NZ505056A (en) | 1998-03-12 | 2003-05-30 | Lucite Int Uk Ltd | A branched polymer composition containing a monofunctional monomer, a polyfunctional monomer and a chain transfer agent |
| WO2004003023A1 (ja) * | 2002-06-28 | 2004-01-08 | Mitsubishi Rayon Co., Ltd. | ビニル系架橋樹脂多孔質体およびその製造方法 |
| EP1714195A2 (en) * | 2004-01-06 | 2006-10-25 | Aspen Aerogels Inc. | Ormosil aerogels containing silicon bonded polymethacrylate |
| US7732496B1 (en) * | 2004-11-03 | 2010-06-08 | Ohio Aerospace Institute | Highly porous and mechanically strong ceramic oxide aerogels |
| US8110258B2 (en) | 2005-11-25 | 2012-02-07 | Advanced Glazing Technologies Limited (Agtl) | Glazing unit with transparent filler |
| US7981988B2 (en) * | 2006-05-25 | 2011-07-19 | 3M Innovative Properties Company | Ultraviolet radiation-polymerizable compositions |
| CA2727778A1 (en) * | 2008-06-30 | 2010-03-25 | Stc.Unm | Durable polymer-aerogel based superhydrophobic coatings: a composite material |
| BRPI0922279A2 (pt) | 2008-12-18 | 2018-06-05 | 3M Innovative Properties Co | "aerogéis híbridos telequélicos". |
| US8691883B2 (en) * | 2009-02-11 | 2014-04-08 | Samsung Electronics Co., Ltd. | Aerogel-foam composites |
| JP5671003B2 (ja) * | 2009-04-15 | 2015-02-18 | スリーエム イノベイティブ プロパティズ カンパニー | ナノ中空物品用プロセス及び装置 |
| WO2012154602A1 (en) * | 2011-05-06 | 2012-11-15 | Showers Robert James | Aerogel window film system |
| WO2016019308A1 (en) * | 2014-07-31 | 2016-02-04 | Virginia Commonwealth University | Method for one-step synthesis, cross-linking and drying of aerogels |
| US10421253B2 (en) | 2016-10-05 | 2019-09-24 | Palo Alto Research Center Incorporated | Polymer aerogel for window glazings |
-
2017
- 2017-10-09 US US15/728,385 patent/US10626224B2/en active Active
-
2018
- 2018-09-12 JP JP2018170736A patent/JP7101089B2/ja active Active
- 2018-10-05 EP EP18198980.7A patent/EP3466986B1/en active Active
- 2018-12-26 US US16/232,688 patent/US10717824B2/en active Active
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