JP2019059525A - Packaging material - Google Patents

Abstract

To provide a packaging material which has both sealability that is suitable for an individual package of a cheese and has high storage property and easy openability, and has water repellency of the surface and is excellent in productivity at the time of packaging.SOLUTION: A packaging materiel 1 has an anchor coat agent layer 3, an interlaminar release layer 4 and a seal layer 5 in this order laminated on one surface side of a base material layer 2, where a water-repellent coat layer 6 and a heat seal layer 7 are provided on the same plane on the other surface side of the base material layer 2. The heat seal layer 7 is partially formed in a predetermined region. The seal layer 5 contains at least one selected from linear low-density polyethylene, low-density polyethylene, medium-density polyethylene and high-density polyethylene with a predetermined blending ratio. The water-repellent coat layer 6 contains a polyamide resin and a nitrocellulose resin with predetermined blending ratios.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a packaging material. More particularly, the present invention relates to a packaging material capable of easily opening a package in which food, medicine and the like are packaged.

  Plastic film packaging materials are used for filling and packaging foods such as cheese, ham, sausages, kamaboko, sheep rattan and jelly, and for packaging pharmaceuticals such as powders. For example, sliced cheese obtained by forming processed cheese into a sheet of several mm thick and 10 cm square is directly and individually packaged with a plastic film, and a plurality of individual packages are used. They are piled up and are sold in the form stored in packing bags, such as pillow shape.

  Such individual packages of food are described by way of example of sliced cheese packaging. One example of a conventional sliced cheese packaging material is a laminated plastic film with a sealing layer on one side of the substrate.

  An example of the process of packaging sliced cheese continuously with a filling machine using a sliced cheese packaging material is demonstrated. A long slice cheese packaging material is set in the feeding section of the filling machine, pulled out in the longitudinal direction, and while moving continuously at a predetermined line speed, both ends in the width direction of the slice cheese packaging material are drawn to overlap Align and center seal the overlapped part to make it cylindrical. After pouring melted processed cheese into the cylindrical internal space, the processed cheese is pressed by a roll so as to have a predetermined cheese thickness to form a flat shape. The processed cheese is sealed in the package by sandwiching the openings at both ends in the longitudinal direction of the film and bringing the seal layers located on the inner surface into close contact with each other and heat sealing (side seal). After sealing, it is passed through water to cool and solidify the contents processed cheese. After cooling and solidification, the moisture on the packaging surface is removed using air and a brush. Thereafter, it is cut into a predetermined size to form individual packages, and a plurality of individual packages are stacked and packaged in an outer packaging bag.

  In the process of removing moisture on the packaging surface, in order to avoid problems due to moisture in the process of stacking a plurality of individual packagings performed thereafter and to perform high-speed filling of the outer packaging bag, the efficiency of the packaging process is improved. It is desirable to reliably remove the moisture on the packaging surface in a shorter time.

  Therefore, regarding a cheese packaging material that focuses on the water repellency of the surface, a propylene resin water repellent agent is applied entirely on the outer surface side of the film substrate, and from the propylene-ethylene copolymer etc. on the inner surface side of the film substrate. Patent Document 1 discloses that a heat seal layer is provided.

JP 10-101174 A

  However, the cheese package described in Patent Document 1 has a low sealing property in order to ensure that the food can be easily opened when the food is taken out from the individual package (hereinafter, also referred to as "openability"). Since the packaging material is sealed at such a strength that the heat-sealed part is easily peeled off when the cheese is taken out from the cheese package, the sealing property of the cheese is low. Moreover, since the overlap part of the film which wound the cheese was not sealed but was merely superimposed, the sealing property of the cheese was low also from this point. Therefore, after the cheese package body of patent document 1 was taken out from the exterior bag which has gas-barrier property, and was opened, the time of drying and deterioration of cheese was quick, and the storage period was not long.

  The present invention advantageously solves the above-mentioned problems, and has both high sealability and easy openability, as well as a water-repellent surface and excellent packaging productivity at the time of packaging. The purpose is to provide materials.

  As a result of intensive studies on packaging materials suitable for individually packaging thin foods such as sliced cheese and pharmaceuticals such as powders, the present inventors have found that a water repellent coating layer is formed on one side of a substrate layer. And a heat seal layer in parallel on one side, and the anchor coat agent layer, the delamination layer and the seal layer are provided on the other side of the substrate layer, and between the delamination layer and the substrate layer In addition, it has been found that by forming an anchor coating agent layer, a packaging material having both high shelf life sealability and easy openability, and further having water repellency on the surface can be obtained, and further from this, a seal is obtained. The layer comprises linear low density polyethylene and at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene (HDPE), and said linear low density polyethylene and said low density polyethylene A seal layer having both high sealability and high openability is obtained by setting the compounding ratio with at least one selected from medium density polyethylene and high density polyethylene in a predetermined range, and the water repellent coating layer is made of polyamide It was found that a water repellent coating layer excellent in water repellency and heat resistance can be obtained by containing a resin and a nitrocellulose resin, and setting the blending ratio of the polyamide resin to the nitrocellulose resin within a predetermined range.

The packaging material of the present invention based on the above findings comprises an anchor coating agent layer, an interlayer peeling layer, and a seal layer laminated in this order on one surface side of the base material layer, and the base material A water repellent coating layer and a heat seal layer are provided on the other surface side of the layer, and the sealing layer contains at least one selected from linear low density polyethylene and low density polyethylene, medium density polyethylene and high density polyethylene. A blending ratio of the linear low density polyethylene to at least one selected from the low density polyethylene, the medium density polyethylene, and the high density polyethylene is 90:10 to 60:40 by mass%, and the water repellent coating layer Contains a polyamide resin and a nitrocellulose resin, and the blending ratio of the polyamide resin to the nitrocellulose resin is 60:20 to 80: in mass%. Characterized in that it is a zero.
The packaging material of the present invention preferably has a density of at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene of the above-mentioned seal layer from 0.925 to 0.970 g / cm ³ .

In the packaging material of the present invention, the heat seal layer preferably contains an ethylene-vinyl acetate copolymer, and the anchor coating agent layer is an application layer of an aqueous dispersion containing a polyolefin resin, and the polyolefin resin Is a copolymer of a polyolefin component and an unsaturated carboxylic acid component, and the polyolefin component is preferably polypropylene, and the interlayer release layer is preferably polypropylene.
Furthermore, the packaging material of the present invention is suitable as a packaging material for cheese.

  According to the packaging material of the present invention, it is possible to obtain a packaging material excellent in water repellency, having both high sealability and easy openability.

It is a typical sectional view of one embodiment of the packaging material of the present invention. It is a schematic cross section of the seal part of the package using the packaging material of FIG. It is a schematic cross section which shows the state which the seal | sticker part of the package using the packaging material of FIG. 1 isolate | separated. It is a top view of an example of the packing object using the packing material of the present invention.

Hereinafter, an embodiment of the packaging material of the present invention will be specifically described using an example of packaging cheese, using the drawings.
FIG. 1 shows a schematic cross-sectional view of an embodiment of the packaging material of the present invention. In FIG. 1, the packaging material 1 is formed of a multilayer film, and the base material layer 2, the anchor coat agent layer 3, the interlayer peeling layer 4 and the seal layer 5 are provided on one surface side of the base material layer 2. It is stacked and prepared in this order. In the illustrated example, the anchor coat agent layer 3 is formed in contact with the surface 2 a of the base material layer 2. By providing the delamination layer 4, the packaging material 1 of the present embodiment has excellent easy-openability. Further, the seal layer 5 is provided to contribute to high sealing performance when side sealing is performed.

  Further, on the other surface side of the substrate layer, in other words, on the surface side of the substrate layer 2 on the opposite side to the surface of the substrate layer 2 in contact with the anchor coating agent layer 3, the water repellent coating layer 6 and heat are provided. A sealing layer 7 is provided. In the illustrated example, the water repellent coating layer 6 and the heat seal layer 7 are respectively formed on the same surface in contact with the surface 2 b of the base material layer 2. More specifically, the heat seal layer 7 is partially formed in a predetermined region of the surface 2 b of the base material layer 2, and the region where the heat seal layer 7 is formed on the surface 2 b of the base material layer 2 The water repellent coating layer 6 is formed in the other area. By providing the water repellent coating layer 6, the packaging material 1 of the present embodiment has excellent water repellency. Moreover, the packaging material 1 of this embodiment contributes to the high sealing property of the overlap part of the film which wound the cheese by having the heat seal layer 7. As shown in FIG.

  In addition, in the surface 2 b of the base material layer 2, in consideration of the coating accuracy and the like when forming the water repellent coating layer 6 and the heat seal layer 7, there is a gap between the water repellent coating layer 6 and the heat seal layer 7. It does not exclude certain structures. In addition, the water repellent coating layer 6 may not be formed on the surface 2 b of the base material layer 2 as the outer surface of the package other than the region contributing to water repellency.

  FIG. 2 shows a schematic cross-sectional view of the seal portion of the package using the packaging material 1 shown in FIG. 1, specifically the side seal portion, and FIG. 3 shows the seal when the package of FIG. 2 is opened. The typical sectional view of the state where the part separated is shown. In the seal portion shown in FIG. 2, the same kind of seal layer 5 is obtained by folding one packaging material 1 and overlapping the part 1a and the other part 1b in a state where the seal layers 5 face each other. They are sealed by heat fusion. The seal strength by heat fusion between the same seal layers 5 is high, whereby the side seal portion has high sealability when used for an individual package of sliced cheese. Further, for example, polyethylene, which is suitable as the sealing layer 5, has relatively low adhesion to, for example, a polypropylene layer as the interlayer peeling layer 4, so that sufficient sealing property for practical use of the package can be obtained. As shown, it is possible to delaminate between the delamination layer 4 and the seal layer 5 and, consequently, the package using the packaging material 1 can be easily opened. Although FIG. 3 shows an example in which the delamination is performed between the delamination layer 4 and the seal layer 5 in the other portion 1b of the packaging material 1, the delamination layer 4 and the seal layer 5 of the portion 1a are shown. There may be delamination between them.

  Further, as shown in FIG. 2, the outer surface of the package obtained by overlapping and overlapping the seal layers 5 of the portion 1 a and the other portion 1 b of one sheet of wrapping material 1 is a partial heat seal layer 7. Since the water repellent coating layer 6 is formed except for the region, it has excellent water repellency. Therefore, for example, the moisture after being cooled in water in one step in the production of the individual package of sliced cheese can be removed quickly and reliably. In addition, when the heat seal layer 7 is wound and overlapped on the cheese, the heat seal layer 7 and the seal layer 5 are brought into contact with each other since the heat seal layer 7 is opposed to the seal layer 5 at the overlapping portion. Thus, the center seal portion has high sealing performance by heat-sealing and sealing the two.

Each layer will be specifically described below.
[Base layer]
As the base material layer 2, the resin film which comprises a normal packaging material can be used suitably. Specifically, low density polyethylene, medium density polyethylene, high density polyethylene, linear low density polyethylene, polypropylene, polyvinyl alcohol, polyacrylonitrile, polycarbonate, ethylene-vinyl acetate copolymer, ionomer, ethylene- (meth) acrylic acid Copolymer, ethylene-ethyl (meth) acrylate copolymer, ethylene-propylene copolymer, methylpentene, polybutene, acid-modified polyolefin resin, polyamide resin, polystyrene resin, low crystalline saturated polyester or non-crystalline Crystalline polyester resin, polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyvinylidene fluoride (PVDF), tetrafluoroethylene-ethylene copolymer (ETFE), polytetrafluoroethylene (PTFE) , It can be used a film made of like MXD6.
Among the above-described resin films, polyester resins such as polyethylene terephthalate (hereinafter also referred to as "PET"), polyethylene naphthalate (PEN), polybutylene terephthalate (PBT), polybutylene naphthalate (PBN); Polyamide resins such as amide (nylon 6), polyhexamethylene adipamide (nylon 66) and poly-p-xylylene adipamide (MXD6 nylon); polyolefin resins such as polyethylene and polypropylene are preferable. In particular, a PET film is more preferable for the base material layer 2 because of its high transparency, excellent dimensional stability, heat resistance and the like. The above polyester resin, polyamide resin and polyolefin resin may be a mixture thereof.
The base material layer 2 may be a multilayer film in which two or more resin films are laminated. When it is a multilayer film, each layer may have the same composition or different compositions.

  These resin films may be non-oriented films, but from the viewpoint of transparency and the like, uniaxially oriented films or biaxially oriented films are preferably used. The thickness of the film is not particularly limited, but is about 5 to 500 μm, preferably 5 to 300 μm, and more preferably 10 to 100 μm.

  The base material layer 2 may have a laminated structure in which a barrier layer is further laminated on the above-mentioned resin film layer. By laminating the barrier layer, weight reduction of the content and deterioration of the content can be effectively suppressed. When the barrier layer is laminated, the water repellent coating layer 6 and the heat seal layer are provided on the barrier layer side of the base layer 2, and the anchor coating agent layer 3, the interlayer peeling layer 4 and the seal layer are provided on the resin film layer side. A laminated structure in which 5 is provided is preferable. However, in the packaging material of the present invention, the anchor coating agent layer 3, the interlayer peeling layer 4 and the seal layer 5 are provided on the barrier layer side of the base layer 2, and the water repellent coating layer 6 and the heat seal layer are provided on the resin film layer side. It is good also as a laminated structure which provides.

The barrier layer may be, for example, a metal foil made of aluminum foil or the like, a deposited film of an inorganic substance or an inorganic oxide, a deposited film having the deposited film on a resin film, or an ethylene-vinyl alcohol copolymer, polyvinylidene chloride, polyvinyl The layer may be made of alcohol, a gas barrier resin such as MXD6, or a combination thereof.
In order to ensure the visibility of food, the barrier layer is preferably transparent, and a vapor-deposited film of an inorganic oxide or an inorganic oxide vapor-deposited film formed by providing the vapor-deposited film on a plastic film is particularly preferably used Be done. The inorganic oxide for forming the vapor deposition film may be any inorganic oxide having transparency and gas barrier properties such as oxygen and water vapor. For example, aluminum oxide, silicon oxide, magnesium oxide, calcium oxide, oxide The oxides are zirconium, titanium oxide, boron oxide, hafnium oxide, barium oxide, etc. In particular, aluminum oxide and silicon oxide are preferably used in view of gas barrier properties, production efficiency and the like.

  The surface of the base material layer 2 may be subjected to surface treatment for improving wettability such as corona treatment, ozone treatment, and flame treatment in order to improve adhesion. Such surface treatment can be applied to any of the surface of the base material layer 2 on which the anchor coating agent layer 3 is formed and the surface on which the water repellent coating layer 6 is formed, and is applied to both surfaces. Is preferred. Moreover, when the base material layer 2 has the barrier layer mentioned above, it can surface-treat on the surface of this barrier layer.

[Anchor coat agent layer]
The anchor coating agent layer 3 is a layer provided with an adhesive property to the base material layer 2 and a property capable of adhering to an extrusion laminated polypropylene as a specific example of the delamination layer 4. The anchor coat agent layer 3 is preferably a coated layer of an aqueous dispersion containing a polyolefin resin as an anchor coat agent. In the anchor coat agent of the anchor coat agent layer 3, the polyolefin resin is a copolymer of a polyolefin component and an unsaturated carboxylic acid component, and the polyolefin component is polypropylene.

The effects of the packaging material 1 of the present invention provided with the anchor coating agent layer 3 will be described.
In the case of a packaging material comprising a multilayer film, when the polypropylene layer and the polyethylene layer are laminated, the adhesive strength between the polypropylene layer and the polyethylene layer becomes lower than the adhesive strength between similar layers. It is considered that easy openability of the packaging material can be obtained by utilizing this low interlayer adhesion strength. However, the polypropylene layer has poor adhesion to the base material layer generally used for the packaging material, and even if the conventionally known urethane anchor coating agent is formed on the surface of the base material layer, the polypropylene layer is extruded and laminated With the base material layer, the interlayer adhesion strength required for the packaging material was not obtained.

  Bonding the polypropylene layer and the base layer with an adhesive, so-called dry lamination, is possible, but the cost is high, and a certain thickness of the polypropylene layer is necessary to bond with the adhesive. Specifically, a thickness of 20 μm or more is required. The polypropylene layer of such a thickness has a problem in packaging processing such as bending of a packaging material made of a multilayer film.

  Therefore, instead of the polypropylene layer, the polyethylene layer is extrusion laminated directly or through the anchor coating agent layer to the substrate layer, and the polypropylene layer is superimposed on the side opposite to the substrate layer as viewed from the polyethylene layer. A packaging material of a multilayer film provided with a layer structure which is laminated and formed as the outermost layer can be considered. Since the polyethylene layer has high adhesion to the base layer, the interlayer adhesion strength required for the packaging material can be obtained between the polyethylene layer and the base layer. However, in such a layer configuration, the heat seal layer of the outermost layer of the laminated film becomes a polypropylene layer, and the polyethylene layer is disposed on the inner layer side. A package having a polypropylene layer as a heat seal layer has a melting point of polypropylene higher than that of polyethylene, so depending on the heating conditions at the time of heat sealing, the polyethylene layer on the inner layer may be melted first to make delamination difficult. In some cases, it may be difficult to obtain sufficient bonding strength between layers. Therefore, at the time of manufacture of a package, the suitable condition range of the heating temperature at the time of heat sealing and heating time was narrow, and it was difficult to raise the line speed of a packaging machine.

  In contrast, the packaging material of the present invention comprises an anchor coating agent layer using a specific anchor coating agent containing a copolymer of polypropylene and an unsaturated carboxylic acid component, and the polypropylene component of this anchor coating agent layer The polypropylene of the extrusion-laminated delamination layer is compatible and can be firmly adhered. Therefore, the extrusion-laminated polypropylene layer and the base material layer provide the interlayer adhesion strength required for the packaging material. In addition, by adhering a polypropylene layer having a layer thickness of less than 20 μm, which was difficult in dry lamination, to the base material layer via the anchor coating agent layer, packaging processability such as bending of the packaging material can be improved. Since a polyethylene layer can be used for the outermost seal layer, the suitable condition range of heating temperature at the time of heat sealing and heating time is wide at the time of manufacture of the package. Furthermore, since it can be made to delaminate between a polypropylene layer and the outermost layer, for example, a polyethylene layer, stable opening strength can be obtained without depending on heating temperature and heating time, and it is excellent in easy opening property. ing.

  Polypropylene of the polyolefin component can be roughly classified into homopolypropylene consisting of homopolymer, random polypropylene consisting of random copolymer, and block polypropylene consisting of block copolymer, and adhesion between the base material layer 2 and the extrusion laminated polypropylene as the delamination layer 4 described later. From the viewpoint of properties, homopolypropylene and random polypropylene are preferred.

  Examples of unsaturated carboxylic acid components include acrylic acid, methacrylic acid, maleic acid and maleic anhydride.

  The anchor coating agent of the anchor coating agent layer 3 is an aqueous dispersion containing an acid-modified polypropylene resin described in JP-A-2015-163688 and an aqueous medium, and the polypropylene component of the acid-modified polypropylene resin is An anchor coat agent which is a homopolypropylene having a tactic structure can be used. Moreover, as an anchor coating agent of the anchor coating agent layer 3, DA-1200 made from Unitika, Inc. can be used as a commercial item.

  The aqueous medium of the aqueous dispersion as the anchor coating agent is water, and may be a liquid containing water as a main component other than water, and contains, for example, a basic compound such as ammonia or an organic solvent. It is also good.

  In order to further improve the performance according to the purpose, additives such as other resins and crosslinking agents can be added to the anchor coating agent.

  Other resins that may be added to the anchor coat agent include, for example, polyurethane resins. By adding the polyurethane resin, when the contents are stored using the packaging material, it is possible to suppress the delamination that may occur in the fold portion.

  As the polyurethane resin, a polymer containing a urethane bond in the main chain can be used, and for example, a polymer obtained by the reaction of a polyol compound and a polyisocyanate compound can be used.

  It does not specifically limit as a polyol component which comprises a polyurethane resin, For example, water, ethylene glycol, diethylene glycol, triethylene glycol, a 1, 3- butanediol, a 1, 4- butanediol, 1, 2- propanediol, 1 , 3-propanediol, 1,6-hexanediol, neopentyl glycol, 1,4-cyclohexanedimethanol, methyl-1,5-pentanediol, 1,8-octanediol, 2-ethyl-1,3-hexane Low molecular weight glycols such as diol, diethylene glycol, triethylene glycol and dipropylene glycol Low molecular weight polyols such as trimethylolpropane, glycerin and pentaerythritol, and polyols having ethylene oxide and propylene oxide units Compounds, polyether diols, high molecular weight diols such as polyester diols, bisphenols such as bisphenol A, bisphenol F, dimer diol or the like carboxyl group was converted to a hydroxyl group of the dimer acid.

  Moreover, as a polyisocyanate component which comprises a polyurethane resin, 1 type, or 2 or more types of mixtures of the well-known diisocyanates which belong to aromatic, an aliphatic, or an alicyclic can be used. Specific examples of diisocyanates include tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, 1,3-phenylene diisocyanate, hexamethylene diisocyanate, xylylene diisocyanate, 1,5-naphthalene diisocyanate, isophorone diisocyanate, dimethyl diisocyanate, lysine diisocyanate And hydrogenated 4,4'-diphenylmethane diisocyanate, hydrogenated tolylene diisocyanate, dimeric isocyanate obtained by converting the carboxyl group of dimer acid to isocyanate group, and adducts, biuret and isocyanurate thereof. Moreover, you may use polyisocyanate of trifunctional or more than triphenyl methane triisocyanate, polymethylene polyphenyl isocyanate, etc. as diisocyanates.

  The addition amount of the other resin such as the polyurethane resin described above is preferably 1 to 100 parts by mass with respect to 100 parts by mass of the copolymer of the polypropylene and the unsaturated carboxylic acid component in the aqueous dispersion, More preferably, it is 60 parts by mass.

  The crosslinking agent which can be added to the anchor coating agent includes a crosslinking agent having a self-crosslinking property, a compound having a plurality of functional groups capable of reacting with the unsaturated carboxylic acid component, and a metal having a polyvalent coordination site. Etc. can be used.

  Specific examples include oxazoline group-containing compounds, carbodiimide group-containing compounds, isocyanate group-containing compounds, epoxy group-containing compounds, melamine compounds, urea compounds, zirconium salt compounds, silane coupling agents, organic peroxides, etc. Depending on the case, a plurality of things may be mixed and used. Among them, from the viewpoint of easy handling, it is preferable to add an oxazoline group-containing compound, a carbodiimide group-containing compound, an isocyanate group-containing compound, and an epoxy group-containing compound.

  The oxazoline group-containing compound is not particularly limited as long as it has at least two or more oxazoline groups in the molecule. For example, 2,2'-bis (2-oxazoline), 2,2'-ethylene-bis (4,4'-dimethyl-2-oxazoline), 2,2'-p-phenylene-bis (2-oxazoline) And compounds having an oxazoline group such as bis (2-oxazolinylcyclohexane) sulfide, and oxazoline group-containing polymers. One or more of these can be used. Among these, oxazoline group-containing polymers are preferable in terms of ease of handling.

  The oxazoline group-containing polymer is generally obtained by polymerizing an addition polymerizable oxazoline such as 2-vinyl-2-oxazoline, 2-vinyl-4-methyl-2-oxazoline, 2-isopropenyl-2-oxazoline and the like. Other monomers may be copolymerized with the oxazoline group-containing polymer, if necessary. It does not specifically limit as a polymerization method of an oxazoline group containing polymer, A well-known polymerization method is employable.

  The carbodiimide group-containing compound is not particularly limited as long as it has at least two or more carbodiimide groups in the molecule. For example, a compound having a carbodiimide group such as p-phenylene-bis (2, 6-xylsilyl carbodiimide), tetramethylene-bis (t-butyl carbodiimide), cyclohexane-1, 4-bis (methylene-t-butyl carbodiimide), etc. And polycarbodiimide which is a polymer having a carbodiimide group. One or more of these can be used. Among these, polycarbodiimide is preferable in terms of ease of handling.

  The manufacturing method of polycarbodiimide is not specifically limited, For example, it can manufacture by the condensation reaction accompanied by the carbon dioxide removal of an isocyanate compound. The isocyanate compound is not limited either, and any of aliphatic isocyanate, alicyclic isocyanate and aromatic isocyanate may be used. The isocyanate compound may be copolymerized with a polyfunctional liquid rubber, a polyalkylene diol or the like, if necessary.

The amount of addition of crosslinking agents such as oxazoline crosslinking agents and carbodiimide crosslinking agents is 0.1 to 20 parts by mass with respect to 100 parts by mass of the copolymer of polypropylene and unsaturated carboxylic acid component in the aqueous dispersion. Is preferable, and 1 to 10 parts by mass is more preferable.
[Peeling layer]
The material of the delamination layer 4 is preferably polypropylene. By making the delamination layer 4 into polypropylene, it can be firmly adhered to the base material layer 2 under the specific anchor coating agent described above. In addition, the seal layer 5 can be made of polyethylene, and can be delaminated while maintaining excellent heat sealability.

Specifically, polypropylene may be any of homopolypropylene, random polypropylene, block polypropylene, and acid-modified polypropylene. Among them, random polypropylene is preferable from the viewpoint of extrusion lamination suitability. The above-mentioned acid-modified polypropylene is preferably one which is modified to an unsaturated carboxylic acid. Examples of unsaturated carboxylic acids include maleic acid, itaconic acid, fumaric acid and acrylic acid. Derivatives of unsaturated carboxylic acids include, for example, maleic anhydride, maleic acid monoester, maleic acid diester, itaconic acid monoester Itaconic acid diesters, itaconic anhydride, fumaric acid monoesters, fumaric acid diesters and the like. Among these, maleic anhydride is preferable because the adhesion to the base of the acid-modified polypropylene obtained is improved.
The melt flow rate MFR (230 ° C., 2.16 kg) of polypropylene used for the interlayer peeling layer 4 is preferably 1 to 100 g / 10 min, and more preferably 3 to 50 g / min.

  The layer thickness of the interlayer peeling layer 4 can be about 1 to 100 μm. When the interlayer peeling layer 4 is in the range of 1 to 100 μm, it is possible to reliably delaminate the sealing layer 5 described later. The interlayer peeling layer 4 has a sufficient thickness as long as it is 5 μm, but can be made up to about 100 μm according to the application of the packaging material of the present invention.

  The delamination layer 4 is preferably a layer laminated on the anchor coating agent layer 3 by extrusion lamination, that is, an extrusion lamination layer. Extrusion laminating is a method of melting resin to a film which becomes a base, making it a film form, and bonding. The extrusion laminating is preferable because an adhesive is not necessary and the thickness of the interlayer peeling layer to be laminated can be reduced as compared with the method of laminating using an adhesive. For example, an interlayer peeling layer having a thickness of less than 20 μm, which can not be bonded by so-called dry lamination, can be formed.

  In addition, as described later, the extrusion lamination of the interlayer peeling layer 4 is performed by melt coextrusion with the seal layer 5 so that the interlayer peeling layer 4 and the seal layer 5 are formed on the anchor coat agent layer 3 of the base material layer 2 once. It is preferable in order to improve the productivity of the packaging material 1.

[Seal layer]
The seal layer 5 includes linear low density polyethylene and at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene, and the linear low density polyethylene, the low density polyethylene, and medium density polyethylene And it is preferable that a compounding ratio with at least 1 type chosen from high density polyethylene is 90:10-60:40 by mass%.

Moreover, it is preferable that the density of at least 1 type chosen from low density polyethylene, medium density polyethylene, and high density polyethylene is 0.925-0.970 g / cm < ³ >.

  The seal layer 5 is a resin layer that can be melted by heat and fused together. In general, as a resin used for heat sealing, low density polyethylene, medium density polyethylene, high density polyethylene, linear (linear) low density polyethylene, ethylene-vinyl acetate copolymer, ionomer resin, ethylene- (meth) Ethyl acrylate copolymer, ethylene- (meth) acrylic acid copolymer, ethylene-propylene copolymer, methyl pentene polymer, polyolefin resin (except polypropylene) such as polyethylene acrylic acid, methacrylic acid, maleic anhydride , Polyolefin resins modified with unsaturated carboxylic acids such as fumaric acid, etc., terpolymer resin of ethylene- (meth) acrylic acid ester-unsaturated carboxylic acid, cyclic polyolefin resin, cyclic olefin copolymer, polyethylene terephthalate (PET ), Polyacry Nitrile (PAN), one or resin comprising more other like can be used. In the present invention, among the general resins exemplified above, polypropylene is used.

In the present invention, since the delamination between the seal layer 5 and the interlayer peeling layer 4 is used for easy opening property of the packaging material 1, the adhesion between the interlayer peeling layer 4 and the polypropylene is the present invention. The adhesion between the other layers in the laminated structure of the packaging material is required to be lower, and for heat sealing, a material having a melting point lower than that of the polypropylene of the delamination layer 4 is required. The seal layer 5 is also required to be non-sticky. Therefore, the sealing layer 5 of the packaging material 1 of the present invention is preferably polyethylene among the resins used for the above-described heat sealing. Specific examples of polyethylene include low density polyethylene, linear low density polyethylene, medium density polyethylene and polyethylene of one or more of high density polyethylene, and as the seal layer 5 of the packaging material 1 of the present invention, among others The linear low density polyethylene (LLDPE) and at least one selected from low density polyethylene (LDPE), medium density polyethylene (MDPE), and high density polyethylene (HDPE), by mass%, 90:10 to 60: Those blended at 40 are preferred. In addition, the density of at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene is preferably 0.925 to 0.970 g / cm ³ .

  Linear low density polyethylene has high sealability. Therefore, although linear low density polyethylene is suitable for the sealing layer 5, it may adhere to a certain extent to the polypropylene delamination layer 4 because of its high sealing property. For example, when the delamination layer 4 is random polypropylene or block polypropylene, the sealing layer 5 of linear low density polyethylene can generate adhesion. When the sealing layer 5 of linear low density polyethylene has an adhesive force to the polypropylene peel layer 4, the easy opening property of the packaging material 1 is reduced. Here, when linear low density polyethylene is blended with at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene, the tear resistance of the seal layer 5 is reduced, and the polypropylene peel layer 4 is obtained. It becomes easy to peel off, the easy openability of the packaging material 1 can be improved, and high sealability and high easy openability can be achieved at a high level. A seal layer 5 obtained by blending linear low density polyethylene with at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene is particularly preferable when the delamination layer 4 is random polypropylene or block polypropylene.

  In the sealing layer 5, a blending ratio in which the linear low density polyethylene is 90 to 60% by mass and at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene is 10 to 40% by mass is suitable . When the linear low density polyethylene is 60% by mass or more, high sealability is obtained, and in particular, the low temperature sealability is excellent. Although 10% by mass or more of at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene, high easy openability can be obtained, if it exceeds 40% by mass, the sealability is lowered.

According to a further study of the present inventors, at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene blended with linear low density polyethylene has its density (in the case of two or more types, average density Or, it was found that the tear resistance of the seal layer 5 fluctuates depending on the density of the blend. When the density is 0.925 to 0.970 g / cm ³ , the tear resistance of the seal layer 5 is favorably reduced and the polypropylene peels easily with respect to the delamination layer 4. When the density is less than 0.925 g / cm ³ , the tear resistance of the polyethylene becomes strong, which is not preferable. And when it exceeds 0.970 g / cm ³ , the sealability and the processability are unfavorably reduced.

  The thickness of the seal layer 5 is not particularly limited, but is preferably about 1 to 100 μm. Preferably it is 40 micrometers or less, More preferably, it is 30 micrometers or less.

  The seal layer 5 is preferably a layer laminated by extrusion lamination on the anchor coat agent layer 3, that is, an extrusion laminate layer. The extrusion laminating does not require an adhesive as compared with the method of laminating using an adhesive, and the thickness of the sealing layer to be laminated can be reduced. For example, a seal layer having a thickness of less than 20 μm, which can not be bonded by so-called dry lamination, can be formed.

  The seal layer 5 is preferably a layer laminated by melt coextrusion with the delamination layer 4 during extrusion lamination, that is, a melt coextrusion layer. By melt coextrusion, the interlayer peeling layer 4 and the seal layer 5 can be bonded at once on the anchor coating agent layer 3 of the base material layer 2, and the packaging material 1 can be manufactured with high productivity.

[Water-repellent coating layer]
The water repellent coating layer 6 preferably contains a polyamide resin and a nitrocellulose resin, and the blending ratio of the polyamide resin to the nitrocellulose resin is preferably 60:20 to 80:40 by mass.

  The temperature when filling the melted cheese into the package using the packaging material 1 of the present invention is about 80.degree. Therefore, it is preferable that the water repellent coating layer 6 have heat resistance at the time of filling of the melted cheese in addition to having water repellency. Here, the polyamide resin improves the water repellency of the water repellent coating layer 6. Further, the nitrocellulose resin improves the heat resistance of the water repellent coating layer 6 and improves the adhesion of the water repellent coating layer 6. Therefore, the water repellent coating layer 6 has both the excellent water repellency and the excellent heat resistance under good adhesion by containing the polyamide resin and the nitrocellulose resin.

  When the water repellent coating layer 6 is composed of a polyamide resin and a nitrocellulose resin, a blending ratio of 60 to 80% by mass of the polyamide resin and 20 to 40% by mass of the cellulose resin is preferable. When the content of the polyamide resin is 80% or less, the water repellency is improved. However, when the content exceeds 80%, the heat resistance is reduced and post-processing becomes difficult. The heat resistance is improved when the polyamide resin is 60% or more, but the water repellency is insufficient when it exceeds 60% by mass. That is, when the cellulose-based resin is added too much, the water repellency is reduced, but the heat resistance is improved. When the addition is small, the water repellency is improved but the heat resistance is inferior.

  The water repellent coating layer 6 is mainly composed of a polyamide resin and a nitrocellulose resin, and in addition to this main component, an acrylic copolymer resin, a vinyl chloride-vinyl acetate copolymer resin, a polyester resin, a polyurethane as an accessory component Resin, chlorinated polyolefin resin, ethylene-vinyl acetate copolymer resin, urea resin, epoxy resin, different from polyamide resin contained in main component, different from polyamide resin contained in main component, nitrocellulose resin contained in main component It can be set as the layer formed by blending 1 type, or 2 or more types of resin chosen from the cellulose resin of a kind. It is preferable that the compounding ratio (mass%) of the polyamide resin of the main component in this case and nitrocellulose resin is 60: 20-80: 40. In addition, the total of the main components preferably includes 50% by mass or more of the water repellent coating layer 6.

  Further, the water repellent coating layer 6 contains the above-described polyamide resin and nitrocellulose resin, and, if necessary, an acrylic copolymer resin, a vinyl chloride-vinyl acetate copolymer resin, a polyester resin, a polyurethane resin, a chlorinated polyolefin resin Ethylene-vinyl acetate copolymer resin, urea resin, epoxy resin, polyamide resin of a type different from the main component, cellulose resin of a type different from the main component alone or two types of resins Even though the above is blended, polyethylene tetrafluoroethylene particles can be further added.

  The polyethylene tetrafluoroethylene particles preferably have a volume average particle size of 2 to 5 μm. If the volume average particle diameter is less than 2 μm, the water repellency improvement effect can not be sufficiently obtained, and if it exceeds 5 μm, the coating properties of the water repellent coating layer 6 are reduced. The addition amount of the polyethylene tetrafluoroethylene particles is preferably 2 to 30 parts by mass with respect to 100 parts by mass of the resin. When the amount is less than 2 parts by mass, the effect of improving water repellency can not be sufficiently obtained, and when the amount is more than 30 parts by mass, the coating properties of the water repellent coating layer 6 are reduced.

[Heat seal layer]
The heat seal layer 7 is excellent in adhesion to the substrate layer 2 to be coated, and is preferably blocking when it is rolled up after printing. Specifically, an ethylene-vinyl acetate copolymer can be used as the heat seal agent of the heat seal layer 7. The vinyl acetate content in the ethylene-vinyl acetate copolymer is preferably 20 to 40% by mass. If the amount is less than 20% by mass, the low temperature stability is poor, and if the amount is more than 40% by mass, the heat seal strength is reduced.

The ethylene-vinyl acetate copolymer used for the heat seal layer 7 may be modified with an unsaturated carboxylic acid and / or a derivative thereof. Examples of unsaturated carboxylic acids include maleic acid, itaconic acid, fumaric acid and acrylic acid. Derivatives of unsaturated carboxylic acids include, for example, maleic anhydride, maleic acid monoester, maleic acid diester, itaconic acid monoester Itaconic acid diesters, itaconic anhydride, fumaric acid monoesters, fumaric acid diesters and the like. Among these, maleic anhydride is preferable because the heat resistance of the resulting ethylene-vinyl acetate copolymer resin composition is improved.
The amount of unsaturated carboxylic acid and / or derivative thereof in the ethylene-vinyl acetate copolymer is preferably 0.01 to 2.0% by mass because heat resistance is improved.

  Further, the heat seal agent of the heat seal layer 7 preferably contains a polyamide resin in order to prevent blocking. The polyamide resin is a thermoplastic polyamide which can be obtained by polycondensation of an amine and an acid. As the amine, for example, hexamethylenediamine can be used, and as the acid, for example, adipic acid, sebacic acid And trimellitic anhydride, dimer acid and the like can be used, and further, as those having both an amine and an acid, there are 11-aminoundecanoic acid, 12-aminododecanoic acid and the like, and a polyamide resin combining these It can be used.

[Method of manufacturing packaging material]
Next, the manufacturing method of the packaging material of this invention is demonstrated. One example of the method for producing the package of the present invention is an aqueous dispersion containing a polyolefin resin on one surface of a substrate, wherein the polyolefin resin is a copolymer of a polyolefin component and an unsaturated carboxylic acid component. And after the polyolefin component is coated with an anchor coating agent which is propylene and dried to form an anchor coating agent layer, the release coating layer is formed by melt coextrusion on the surface of the anchor coating agent layer. , And the seal layer are formed by laminating one on another in that order. In addition, a water repellent coating agent and a heat sealing agent are separately coated on another surface of the substrate to form a water repellent coating layer and a heat seal layer, respectively.

As the method for applying the anchor coating agent described above as the anchor coating agent layer, a known application method can be performed. After application, the aqueous medium is evaporated by a drying treatment to obtain an anchor coating agent layer. The drying conditions are not particularly limited, but may be appropriately selected as a heating temperature of 40 to 200 ° C. and a heating time of 1 to 600 seconds.
The application amount of the anchor coating agent is preferably 0.001 to 5 g / m ² in terms of the dry weight of the anchor coating agent with respect to the application surface. Sufficient adhesion can be economically obtained when the amount of the anchor coating agent is in the range of 0.001 to 5 g / m ² .

  The delamination layer can be formed on the anchor coating agent layer by extrusion lamination. The seal layer can also be formed on the delamination layer by extrusion lamination. In particular, it is preferable to simultaneously form the delamination layer and the seal layer on the anchor coating agent layer by melt co-extrusion. Thereby, the packaging material of the present invention can be manufactured with high productivity, and the layer thickness can be made thinner than the method of bringing the interlayer peeling layer and the sealing layer into close contact by dry lamination. The thin layer thickness of the delamination layer and the sealing layer can improve the bending processability when the content is sealed in the packaging material to manufacture the package.

  The water repellent coating layer is formed by applying a varnish containing the above-mentioned resin or one obtained by adding polyethylene tetrafluoroethylene particles to the varnish to the surface of the substrate layer by an appropriate coating method such as gravure printing or silk screen printing. be able to. Before coating, the surface of the base material layer is preferably subjected to surface treatment such as corona treatment, ozone treatment, or flame treatment.

  The heat seal layer can be formed by applying a varnish containing the above heat seal agent to the surface of the substrate layer by an appropriate coating method such as gravure printing or silk screen printing. Before coating, the surface of the base material layer is preferably subjected to surface treatment such as corona treatment, ozone treatment, or flame treatment.

  The heat seal layer is partially formed on the surface of the base material layer in the area to be heat sealed in the package. Such partial formation can be performed by an appropriate coating method such as gravure printing or silk screen printing described above. On the surface of the base layer, the above-described water repellent coating layer is formed in the region other than the heat seal layer. Such separate application of the heat seal layer and the water repellent coating layer on the surface of the base material layer can also be performed by an appropriate application method such as the above-described gravure printing or silk screen printing.

[Packaging]
The packaging material of the present invention is sealed by heat sealing, is required to be easily opened, and can be used for applications in which it is immersed in water in the packaging process, and the contents are not particularly limited. For example, it is suitable for use in packaging of thin food such as sliced cheese and nori. FIG. 4 shows a plan view of an example of a package 10 in which sliced cheese is packaged with the packaging material of the present invention as a content. In the package 10 shown in the figure, the packaging material 1 covers the back surface of the sliced cheese 11 in a square plane, and is folded at two opposing sides of the sliced cheese 11 and wound so as to overlap on the surface of the sliced cheese 11 The center seal is achieved by bringing the heat seal layer 7 and the seal layer 5 into contact and heat-sealing between the overlap L between the one end 10 a of the one and the other end 10 b opposite thereto. The center seal part 10c center-sealed is shown in FIG. The seal layers 5 of the two stacked packaging materials 1 are heat-sealed at the ends of the other two opposing sides of the sliced cheese 11. The side seal part 10d is shown in figure in FIG. In the packaging material 1 of the present invention, since the seal layer 5 is polyethylene, the side seal portion 11 b can be sealed at high speed and stably.

  Hereinafter, the present invention will be described in more detail using examples, but the present invention is not limited to these examples.

Example 1
A water repellent consisting of 60% by mass of polyamide resin and 40% by mass of nitrocellulose resin is coated on one side of a 12 μm-thick PET film (E-5200, Toyobo Co., Ltd.) with corona treatment on both sides as a base layer. Heat-sealing agent of ethylene-vinyl acetate copolymer system (Seikadyne SC) in a region where a water repellent coating layer (MFG cheese varnish 3 Toyo Ink Co., Ltd.) is partially formed and a water repellent coating layer on the same surface is not formed. (D) -NT Dainichi Seika Kogyo Co., Ltd. was coated to a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) with a thickness of 8 μm as a delamination layer, linear low density polyethylene (KC570S, Japan Polyethylene Co., Ltd.) as a sealing layer and low density A laminate of Example 1 was obtained by melt coextrusion at 4 ° C. with a resin 4% in thickness by dry-blending polyethylene (Z372 Ube Maruzen Polyethylene Corporation) at a mass ratio of 8: 2.

Example 2
Example 2 is an example where the compounding ratio of the seal layer is changed in comparison with Example 1.
A water repellent consisting of 60% by mass of polyamide resin and 40% by mass of nitrocellulose resin is coated on one side of a 12 μm-thick PET film (E-5200, Toyobo Co., Ltd.) with corona treatment on both sides as a base layer. Heat-sealing agent of ethylene-vinyl acetate copolymer system (Seikadyne SC) in a region where a water repellent coating layer (MFG cheese varnish 3 Toyo Ink Co., Ltd.) is partially formed and a water repellent coating layer on the same surface is not formed. (D) -NT Dainichi Seika Kogyo Co., Ltd. was coated to a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) with a thickness of 8 μm as a delamination layer, linear low density polyethylene (KC570S, Japan Polyethylene Co., Ltd.) as a sealing layer and low density A laminate of Example 1 was obtained by melt co-extrusion at 4 ° C. with a resin having a weight ratio of 6: 4 polyethylene (Z372 Ube Maruzen Polyethylene Co., Ltd.) and a thickness of 4 μm.

[Example 3]
Example 3 is different from Example 1 in that the compounding ratio of the water repellent coating layer is changed.
As a substrate layer, a water repellent agent consisting of 80% by mass of polyamide resin and 20% by mass of nitrocellulose resin is coated on one side of a 12 μm thick PET film (E-5200 made by Toyobo Co., Ltd.) corona-treated on both sides. Heat-sealing agent of ethylene-vinyl acetate copolymer system in the region where the water-repellent coating layer is partially formed and the water-repellent coating layer on the same surface is not formed (Seikadyne SC (D)-NT Co., Ltd.) at a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) with a thickness of 8 μm as a delamination layer, linear low density polyethylene (KC570S, Japan Polyethylene Co., Ltd.) as a sealing layer and low density A laminate of Example 1 was obtained by melt coextrusion at 4 ° C. with a resin 4 μm thick of a dry blend of polyethylene (Z372 Ube Maruzen Polyethylene Co., Ltd.) at a mass ratio of 8: 2.

Comparative Example 1
Comparative Example 1 is an example in which the compounding ratio of the water repellent coating layer is changed in comparison with Example 1.
A water repellent agent consisting of 50% by mass of polyamide resin and 50% by mass of nitrocellulose resin is coated on one side of a 12 μm-thick PET film (E-5200, Toyobo Co., Ltd.) with corona treatment on both sides as a substrate layer. Heat-sealing agent of ethylene-vinyl acetate copolymer system in the region where the water-repellent coating layer is partially formed and the water-repellent coating layer on the same surface is not formed (Seikadyne SC (D)-NT Co., Ltd.) at a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) with a thickness of 8 μm as a delamination layer, linear low density polyethylene (KC570S, Japan Polyethylene Co., Ltd.) as a sealing layer and low density A laminate of Example 1 was obtained by melt coextrusion at 4 ° C. with a 4 μm thick resin obtained by dry blending polyethylene (Z372 Ubemaruzen Polyethylene Co., Ltd.) at a mass ratio of 8: 2.

Comparative Example 2
Comparative Example 2 is an example where the compounding ratio of the water repellent coating layer is changed in comparison with Example 1.
As a substrate layer, a water repellent consisting of 90% by mass of polyamide resin and 10% by mass of nitrocellulose resin is coated on one side of a 12 μm thick PET film (E-5200, Toyobo Co., Ltd.) with corona treatment on both sides. Heat-sealing agent of ethylene-vinyl acetate copolymer system in the region where the water-repellent coating layer is partially formed and the water-repellent coating layer on the same surface is not formed (Seikadyne SC (D)-NT Co., Ltd.) at a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) with a thickness of 8 μm as a delamination layer, linear low density polyethylene (KC570S, Japan Polyethylene Co., Ltd.) as a sealing layer and low density A laminate of Example 1 was obtained by melt coextrusion at 4 ° C. with a 4 μm thick resin obtained by dry blending polyethylene (Z372 Ubemaruzen Polyethylene Co., Ltd.) at a mass ratio of 8: 2.

Comparative Example 3
Comparative Example 3 is an example in which only LLDPE is used as a seal layer in contrast to Example 1.
A water repellent consisting of 60% by mass of polyamide resin and 40% by mass of nitrocellulose resin is coated on one side of a 12 μm-thick PET film (E-5200, Toyobo Co., Ltd.) with corona treatment on both sides as a base layer. Heat-sealing agent of ethylene-vinyl acetate copolymer system (Seikadyne SC) in a region where a water repellent coating layer (MFG cheese varnish 3 Toyo Ink Co., Ltd.) is partially formed and a water repellent coating layer on the same surface is not formed. (D) -NT Dainichi Seika Kogyo Co., Ltd. was coated to a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) 8 μm thick as an interlayer peeling layer and linear low density polyethylene (KC 570S, Japan Polyethylene Co., Ltd.) as a sealing layer The laminate of Comparative Example 3 was obtained by melt coextrusion of 4 μm at 290 ° C.

Comparative Example 4
In Comparative Example 4, the compounding ratio of the seal layer was changed in comparison with Example 1.
A water repellent consisting of 60% by mass of polyamide resin and 40% by mass of nitrocellulose resin is coated on one side of a 12 μm-thick PET film (E-5200, Toyobo Co., Ltd.) with corona treatment on both sides as a base layer. Heat-sealing agent of ethylene-vinyl acetate copolymer system (Seikadyne SC) in a region where a water repellent coating layer (MFG cheese varnish 3 Toyo Ink Co., Ltd.) is partially formed and a water repellent coating layer on the same surface is not formed. (D) -NT Dainichi Seika Kogyo Co., Ltd. was coated to a thickness of 1 μm to form a heat seal layer. Next, a polyolefin-based anchor coating agent (DA-1010J2, manufactured by UNITICA CORPORATION) is coated on the surface of the substrate layer opposite to the surface on which the water repellent coating layer and the heat seal layer are formed, and dried at 100 ° C. Then, an anchor coat agent layer was formed. On the surface of this anchor coating agent layer, polypropylene (F329RA, made by Prime Polymer Co., Ltd.) with a thickness of 8 μm as a delamination layer, linear low density polyethylene (KC570S, Japan Polyethylene Co., Ltd.) as a sealing layer and low density A laminate of Example 1 was obtained by melt coextrusion at 4 ° C. with a resin having a weight ratio of 5: 5 of polyethylene (Z372 Ube Maruzen Polyethylene Co., Ltd.) dry blended with a thickness of 4 μm.

<Water repellant evaluation>
The water repellency of each package after packaging and filling was evaluated by two test methods. First, it measured by the contact angle method based on JISR3257. Next, a 0.1 ml water droplet was dropped on a friction angle measuring device according to JIS P8147, and the angle at which the water droplet slipped was measured when the water droplet was inclined. The results are shown in Table 1.

  In the paired comparison of Table 1 to Example 1 and Comparative Example 1, no difference was found in the contact angle, but in the inclination method, a difference in water repellency was observed, and Comparative Example 1 in which the composition was 5: 5 The aqueous was found to be inferior.

<Seal strength measurement>
In order to measure the seal strength of the area corresponding to the side seal portion of the packaging material of the laminates of Examples 1 and 2 and Comparative Examples 1 and 2, the heat seal layer of the sample of each laminate was placed inside. The heat seal layers were brought into contact with each other, pressed at 1 kgf / cm ² and sealed for 1 second at various temperatures from 110 ° C. to 180 ° C. in 10 ° C. steps. The strength of the sealed portion was measured at 25 ° C. in an atmosphere at a temperature of 50 mm / min according to JIS K 6854, and the peeled state was observed. The seal strength can be said to be good if it is in the range of 2.0 to 3.0 N / 15 mm. The results are shown in Table 2. The unit of seal strength in the table is N / 15 mm.

  From Table 2, sufficient strength was obtained at 130 ° C. or higher in Examples 1 to 3 and Comparative Examples 1 and 2, and because PP / PE interlayer was peeled off between the delamination layer and the seal layer. The temperature range of peeling was wide. On the other hand, the comparative example 3 performed condensation peeling at 110-140 degreeC, and the comparative example 4 at 110-140 degreeC. Moreover, Comparative Example 4 was insufficient in sealability.

<Filling test>
Using a packaging and filling machine (FP2000 manufactured by natec), a cheese-packed package was produced, which was melted at 80 ° C. in the packaging material of the laminate of Example 1 and Comparative Example 1. At the time of production of the package, the side seal was performed under the two conditions of the rotation speed of the seal bar of the device of 400 rpm and 1000 rpm. It means that the production speed of a package is high, so that rotation speed is high. The seal temperature of the side seal was 150 ° C.
About the water repellency of each package after packing and filling, drop 0.1 ml water drop on the friction angle measurement machine of JIS P8147, measure the angle that the water drop slides down when applying inclination, and the angle is good as 20 degrees or less did.
The side seal portion of each package after filling in the package was cut into a strip having a width of 15 mm, and in accordance with JIS K 6854, the interlayer adhesion strength was measured under an atmosphere of 25 ° C. with a tensile speed of 50 mm / min. Moreover, the peeling form of the peeled laminated body after a test was confirmed.
The results are shown in Table 3. The unit of seal strength in the table is N / 15 mm.

From Table 3, in Examples 1 to 3, good water repellency, high seal strength, and easy openability by delamination were obtained.
On the other hand, Comparative Example 1 was inferior in water repellency, so that it was not possible to stack due to water repellency failure at high speed rotation. In Comparative Example 2, the heat resistance of the water repellent varnish was inferior, and the water repellent was taken on the heat plate, resulting in water repellent failure. In Comparative Example 3, since the seal temperature was insufficient, delamination did not occur, and the seal surface became cohesive. Comparative Example 4 was poor in high-speed filling suitability, and the seal strength was not stable.

  As mentioned above, although the packaging material of this invention was concretely demonstrated using embodiment and an Example, the packaging material of this invention is not limited to the description of these embodiments and an example, The meaning of this invention Many modifications are possible without departing from the above. For example, the packaging material of the present invention is not limited to that for cheese, and can also be used for packages of food other than cheese, and powders of pharmaceuticals other than foods.

Reference Signs List 1 packaging material 2 base material layer 3 anchor coating agent layer 4 delamination layer 5 sealing layer 6 water-repellent coating layer 7 heat sealing layer

Claims (6)

An anchor coating agent layer, an interlayer peeling layer, and a seal layer are laminated in this order on one surface side of the base material layer, and a water repellent coating layer is provided on the other surface side of the base material layer. And a heat seal layer,
The seal layer contains linear low density polyethylene and at least one selected from low density polyethylene, medium density polyethylene and high density polyethylene, and the linear low density polyethylene, the low density polyethylene, and medium density polyethylene And the compounding ratio with at least one selected from high density polyethylene is 90:10 to 60:40 by mass%,
A packaging material, wherein the water repellent coating layer contains a polyamide resin and a nitrocellulose resin, and a blending ratio of the polyamide resin and the nitrocellulose resin is 60:20 to 80:40 by mass%. Low density polyethylene, the packaging material according to claim 1, wherein at least one of the density selected from medium density polyethylene and high density polyethylene is in the range of 0.925~0.970g / cm ³ of the sealing layer.   The packaging material according to claim 1, wherein the heat seal layer contains an ethylene-vinyl acetate copolymer.   The anchor coating agent layer is a coating layer of an aqueous dispersion containing a polyolefin resin, and the polyolefin resin is a copolymer of a polyolefin component and an unsaturated carboxylic acid component, and the polyolefin component is The packaging material according to any one of claims 1 to 3, which is polypropylene.   The packaging material according to any one of claims 1 to 4, wherein the interlayer peeling layer is polypropylene.   The packaging material according to any one of claims 1 to 5, which is a packaging material for cheese.

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