JP2019026580A - Composition for hair, and hair treatment method - Google Patents
Composition for hair, and hair treatment method Download PDFInfo
- Publication number
- JP2019026580A JP2019026580A JP2017146077A JP2017146077A JP2019026580A JP 2019026580 A JP2019026580 A JP 2019026580A JP 2017146077 A JP2017146077 A JP 2017146077A JP 2017146077 A JP2017146077 A JP 2017146077A JP 2019026580 A JP2019026580 A JP 2019026580A
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- JP
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- Prior art keywords
- hair
- composition
- mass
- blended
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 158
- 239000000203 mixture Substances 0.000 title claims abstract description 100
- 238000000034 method Methods 0.000 title claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 47
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000007788 liquid Substances 0.000 claims abstract description 31
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229940032094 squalane Drugs 0.000 claims abstract description 14
- 150000002430 hydrocarbons Chemical group 0.000 claims abstract description 10
- 229930195734 saturated hydrocarbon Natural products 0.000 claims abstract description 7
- -1 2-ethylhexyl isopalmitate Chemical compound 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 150000004671 saturated fatty acids Chemical group 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 9
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 claims description 4
- 229940060384 isostearyl isostearate Drugs 0.000 claims description 4
- GLXBPZNFNSLJBS-UHFFFAOYSA-N 11-methyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C GLXBPZNFNSLJBS-UHFFFAOYSA-N 0.000 claims description 3
- WPIOBXGJZUSKGK-UHFFFAOYSA-N 16-methylheptadecyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C WPIOBXGJZUSKGK-UHFFFAOYSA-N 0.000 claims description 3
- SAMYFBLRCRWESN-UHFFFAOYSA-N 16-methylheptadecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C SAMYFBLRCRWESN-UHFFFAOYSA-N 0.000 claims description 3
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 claims description 3
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 claims description 3
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 claims description 3
- MWKPHOIHTLQZIY-UHFFFAOYSA-N 2-hexyldecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC MWKPHOIHTLQZIY-UHFFFAOYSA-N 0.000 claims description 3
- OGJDIJKJFYOENF-UHFFFAOYSA-N 2-hexyldecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC OGJDIJKJFYOENF-UHFFFAOYSA-N 0.000 claims description 3
- QNJOVLAFLJQFBF-UHFFFAOYSA-N 2-octyldodecyl 16-methylheptadecanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C QNJOVLAFLJQFBF-UHFFFAOYSA-N 0.000 claims description 3
- 239000003599 detergent Substances 0.000 claims description 3
- 229940113915 isostearyl palmitate Drugs 0.000 claims description 3
- VRBHTEGUHVNKEA-UHFFFAOYSA-N 16-methylheptadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC(C)C VRBHTEGUHVNKEA-UHFFFAOYSA-N 0.000 claims description 2
- JVXJFNLEXLGQIO-UHFFFAOYSA-N 2-hexyldecyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC JVXJFNLEXLGQIO-UHFFFAOYSA-N 0.000 claims description 2
- VNKGALKDWIGYGW-UHFFFAOYSA-N 2-octyldecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCC VNKGALKDWIGYGW-UHFFFAOYSA-N 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 abstract description 13
- 210000000170 cell membrane Anatomy 0.000 abstract description 12
- 125000005471 saturated fatty acid group Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 13
- 230000005068 transpiration Effects 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 11
- 150000002632 lipids Chemical class 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 150000005846 sugar alcohols Polymers 0.000 description 7
- 206010016807 Fluid retention Diseases 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229920001059 synthetic polymer Polymers 0.000 description 6
- 239000002280 amphoteric surfactant Substances 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 5
- 239000002552 dosage form Substances 0.000 description 5
- 239000003925 fat Substances 0.000 description 5
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 229940031439 squalene Drugs 0.000 description 4
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000014593 oils and fats Nutrition 0.000 description 2
- 239000008385 outer phase Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 206010019049 Hair texture abnormal Diseases 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 229920002385 Sodium hyaluronate Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000001341 hydroxy propyl starch Substances 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000013828 hydroxypropyl starch Nutrition 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000010667 rosehip oil Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000010686 shark liver oil Substances 0.000 description 1
- 229940069764 shark liver oil Drugs 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
本発明は、洗い流すトリートメント、洗い流さないトリートメント、毛髪洗浄剤などに使用される毛髪用組成物に関するものである。 The present invention relates to a hair composition used for a treatment to be washed away, a treatment not to be washed away, a hair cleanser and the like.
ブラッシング、ドライヤー、熱アイロン、ヘアカラー、パーマネントウェーブなどの物理的処理、熱処理、又は化学的処理により、毛髪が損傷する。その損傷の結果、毛髪の水分保持性の低下、感触の悪化などの様々な変化が、毛髪に生じる。 Physical treatment such as brushing, dryer, hot iron, hair color, permanent wave, heat treatment, or chemical treatment damages the hair. As a result of the damage, various changes occur in the hair, such as a decrease in the moisture retention of the hair and a deterioration in touch.
上記の損傷が生じさせる毛髪の変化に対して、その改善を目的とした数多くの提案が公開されている。例えば特許文献１〜３には、スクワランと特定の成分とを配合した組成物により、毛髪の感触を改善する提案が開示されている。 Numerous proposals for improving the hair changes caused by the above damage have been published. For example, Patent Documents 1 to 3 disclose proposals for improving the feel of hair with a composition in which squalane and a specific component are blended.
ところで、上記特許文献は、毛髪感触を変化させる組成物の評価を、官能で行ったことを開示するに留まり、実際の水分保持性を高める組成物を開示してはいない。また、毛髪における細胞膜複合体（ＣＭＣ）は、水分保持性能に関与するといわれているが、そのＣＭＣへの作用に関する記載は、上記特許文献には一切ない。 By the way, the above-mentioned patent document only discloses that the evaluation of the composition that changes the hair feel was performed by sensory means, and does not disclose a composition that improves the actual water retention. Moreover, although the cell membrane complex (CMC) in hair is said to be involved in moisture retention performance, there is no description about the action on CMC in the above patent document.
本発明は、上記事情に鑑み、毛髪の水分保持性の向上、及び細胞膜複合体への作用の少なくとも一方を実現できる毛髪用組成物、並びに、その組成物を使用する毛髪処理方法の提供を目的とする。 In view of the above circumstances, the present invention aims to provide a hair composition capable of realizing at least one of improvement of moisture retention of hair and action on a cell membrane complex, and a hair treatment method using the composition. And
本発明者等が鋭意検討を行った結果、スクワランと特定のエステルとの併用が、毛髪の水分保持性の向上、及び、細胞膜複合体における脂質層（β層）の厚みの増加に適することを見出し、本発明を完成するに至った。 As a result of intensive studies by the present inventors, the combination of squalane and a specific ester is suitable for improving the water retention of hair and increasing the thickness of the lipid layer (β layer) in the cell membrane complex. The headline and the present invention were completed.
すなわち、本発明に係る毛髪用組成物は、下記成分（Ａ）及び（Ｂ）が配合されたことを特徴とする。
（Ａ）スクワラン
（Ｂ）下記一般式（Ｉ）で表される液状エステル（Ｉ）
Ｒ１ＣＯＯ−Ｒ２ （Ｉ）
［上記一般式（Ｉ）において、Ｒ１ＣＯＯは炭素数が１２以上１８以下である飽和脂肪酸残基を表し、Ｒ２は炭素数が８以上２０以下である飽和炭化水素基を表す。］
That is, the hair composition according to the present invention is characterized in that the following components (A) and (B) are blended.
(A) Squalane (B) Liquid ester (I) represented by the following general formula (I)
R 1 COO-R 2 (I)
[In the general formula (I), R 1 COO represents a saturated fatty acid residue having 12 to 18 carbon atoms, and R 2 represents a saturated hydrocarbon group having 8 to 20 carbon atoms. ]
本発明に係る毛髪用組成物は、例えば、前記（Ｂ）成分として下記一般式（Ｉ−１）で表される液状エステル（Ｉ−１）が配合されたものである。
Ｒ３ＣＯＯ−Ｒ４ （Ｉ−１）
［上記一般式（Ｉ−１）において、Ｒ３ＣＯＯは炭素数が１２以上１８以下である分岐状の飽和脂肪酸残基を表し、Ｒ４は炭素数が８以上２０以下である分岐状の飽和炭化水素基を表す。］
The composition for hair which concerns on this invention mix | blends the liquid ester (I-1) represented by the following general formula (I-1) as said (B) component, for example.
R 3 COO-R 4 (I-1)
[In the above general formula (I-1), R 3 COO represents a branched saturated fatty acid residue having 12 to 18 carbon atoms, and R 4 represents a branched saturated fatty acid having 8 to 20 carbon atoms. Represents a hydrocarbon group. ]
本発明に係る毛髪用組成物に液状エステル（Ｉ−１）を配合する場合、その液状エステル（Ｉ−１）は、例えば、イソパルミチン酸２−エチルヘキシル、イソステアリン酸２−ヘキシルデシル、イソステアリン酸イソステアリル、及びイソステアリン酸２−オクチルドデシルから選ばれた一種又は二種以上である。 When liquid ester (I-1) is blended in the hair composition according to the present invention, the liquid ester (I-1) is, for example, 2-ethylhexyl isopalmitate, 2-hexyldecyl isostearate or isoisostearate. One or more selected from stearyl and 2-octyldodecyl isostearate.
また、本発明に係る毛髪用組成物は、例えば、前記（Ｂ）成分として下記一般式（Ｉ−２）で表される液状エステル（Ｉ−２）が配合されたものである。
Ｒ５ＣＯＯ−Ｒ６ （Ｉ−２）
［上記一般式（Ｉ−２）において、Ｒ５ＣＯＯは炭素数が１２以上１８以下である直鎖状の飽和脂肪酸残基を表し、Ｒ６は炭素数が８以上２０以下である分岐状の飽和炭化水素基を表す。］
Moreover, the composition for hair which concerns on this invention mix | blends liquid ester (I-2) represented by the following general formula (I-2) as the said (B) component, for example.
R 5 COO-R 6 (I-2)
[In the general formula (I-2), R 5 COO represents a linear saturated fatty acid residue having 12 to 18 carbon atoms, and R 6 is a branched chain having 8 to 20 carbon atoms. Represents a saturated hydrocarbon group. ]
本発明に係る毛髪用組成物に液状エステル（Ｉ−２）を配合する場合、その液状エステル（Ｉ−２）は、例えば、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸２−ヘキシルデシル、ミリスチン酸イソステアリル、ミリスチン酸２−オクチルドデシル、パルミチン酸２−エチルヘキシル、パルミチン酸２−ヘキシルデシル、パルミチン酸イソステアリル、ステアリン酸２−エチルヘキシル、及びステアリン酸２−ヘキシルデシルから選ばれた一種又は二種以上である。 When liquid ester (I-2) is blended in the hair composition according to the present invention, the liquid ester (I-2) is, for example, isostearyl laurate, isotridecyl myristate, 2-hexyldecyl myristate, myristine. One or two selected from isostearyl acid, 2-octyldodecyl myristate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, isostearyl palmitate, 2-ethylhexyl stearate, and 2-hexyldecyl stearate That's it.
本発明に係る毛髪用組成物は、例えば、洗い流すトリートメント、洗い流さないトリートメント、又は毛髪洗浄剤として用いられる。 The hair composition according to the present invention is used, for example, as a treatment for washing away, a treatment not washing away, or a hair cleansing agent.
本発明に係る毛髪処理方法は、本発明に係る毛髪用組成物を使用することを特徴とする。 The hair treatment method according to the present invention is characterized by using the hair composition according to the present invention.
本発明によれば、スクワラン及び特定の液状エステルが配合されているので、毛髪の水分保持性の向上、又は、細胞膜複合体における脂質層（β層）の厚みの増加を実現できる。 According to the present invention, since squalane and a specific liquid ester are blended, it is possible to improve the moisture retention of hair or increase the thickness of the lipid layer (β layer) in the cell membrane complex.
本発明の実施形態に基づき、本発明を以下に説明する。
本実施形態に係る毛髪用組成物は、下記成分（Ａ）及び（Ｂ）が配合されたものである。
（Ａ）スクワラン
（Ｂ）後記液状エステル（Ｉ）
また、実使用上許容されるのであれば、公知の毛髪用組成物に配合されている原料を、更に配合しても良い。
Based on an embodiment of the present invention, the present invention will be described below.
The hair composition according to the present embodiment is a blend of the following components (A) and (B).
(A) Squalane (B) Liquid ester (I) described later
Moreover, as long as it is accept | permitted on actual use, you may further mix | blend the raw material mix | blended with the well-known hair composition.
毛髪の水分保持性は、成分（Ａ）及び（Ｂ）の双方を配合すれば、いずれか一方を配合するよりも向上する。また、成分（Ａ）及び（Ｂ）の双方の配合により、毛髪の細胞膜複合体（ＣＭＣ）における脂質層（β層）の厚みの増加が確認されている。前者の水分保持性能の向上と、後者のβ層の厚みの増加は、相関すると考えられる。すなわち、ＣＭＣはβ層と当該β層内のタンパク質層（δ層）とで構成されているところ、水分保持の観点からは、δ層よりも疎水性が高いβ層の厚みが、水分保持性に関与する水分蒸散抑制に寄与すると考えられる。 If both the components (A) and (B) are blended, the moisture retention of hair is improved as compared with blending either one. Moreover, the increase in the thickness of the lipid layer (β layer) in the cell membrane complex (CMC) of hair has been confirmed by blending both components (A) and (B). The improvement in the former moisture retention performance and the increase in the thickness of the latter β layer are considered to be correlated. That is, the CMC is composed of a β layer and a protein layer (δ layer) in the β layer. From the viewpoint of moisture retention, the thickness of the β layer, which is more hydrophobic than the δ layer, has a moisture retention property. It is thought to contribute to the suppression of moisture transpiration related to
本実施形態における成分（Ａ）であるスクワランは、公知である。このスクワランとしては、例えば、イソプレンを重合して得られる合成スクワラン、オリーブ油、コメヌカ、ゴマ種子などの植物由来物から得られるスクワレンを水素添加して得られる植物性スクワラン、及び、サメの肝油から得られるスクワレンを水素添加して得られるスクワランが挙げられる。本実施形態の毛髪用組成物には、公知のスクワランから選ばれた一種又は二種以上が成分（Ａ）として配合される。 The squalane which is a component (A) in this embodiment is well-known. Examples of this squalane include synthetic squalane obtained by polymerizing isoprene, olive oil, rice bran, plant squalene obtained by hydrogenating squalene obtained from plant-derived materials such as sesame seeds, and shark liver oil. And squalane obtained by hydrogenating the obtained squalene. In the hair composition of this embodiment, one or more selected from known squalanes are blended as the component (A).
本実施形態の毛髪用組成物における成分（Ａ）の配合量は、例えば、０．００１質量％以上１０質量％以下であり、０．００２質量％以上５質量％以下が良く、０．００４質量％以上３質量％以下が好ましく、０．００８質量％以上１質量％以下がより好ましく、０．０１質量％以上０．５質量％以下が更に好ましい。０．００１質量％以上であると、毛髪の水分保持性の向上、又は、細胞膜複合体における脂質層（β層）の厚みの増加がより優れる。１０質量％以下であると、本実施形態の毛髪用組成物の低コスト化を図れる。 The blending amount of the component (A) in the hair composition of the present embodiment is, for example, 0.001% by mass to 10% by mass, preferably 0.002% by mass to 5% by mass, and 0.004% by mass. % To 3% by mass, more preferably 0.008% to 1% by mass, and still more preferably 0.01% to 0.5% by mass. When the content is 0.001% by mass or more, the water retention of hair is improved, or the thickness of the lipid layer (β layer) in the cell membrane complex is more excellent. When the content is 10% by mass or less, the cost of the hair composition of this embodiment can be reduced.
本実施形態における成分（Ｂ）である液状エステル（Ｉ）は、下記一般式（Ｉ）で表されるものである。当該エステル（Ｉ）の「液状」とは、２０℃以上３０℃以下の温度範囲における状態が液状であることを意味する。
Ｒ１ＣＯＯ−Ｒ２ （Ｉ）
［上記一般式（Ｉ）において、Ｒ１ＣＯＯは炭素数が１２以上１８以下である飽和脂肪酸残基を表し、Ｒ２は炭素数が８以上２０以下である飽和炭化水素基を表す。］
The liquid ester (I) which is the component (B) in this embodiment is represented by the following general formula (I). The “liquid” of the ester (I) means that the state in the temperature range of 20 ° C. or higher and 30 ° C. or lower is liquid.
R 1 COO-R 2 (I)
[In the general formula (I), R 1 COO represents a saturated fatty acid residue having 12 to 18 carbon atoms, and R 2 represents a saturated hydrocarbon group having 8 to 20 carbon atoms. ]
上記Ｒ１ＣＯＯとしては、例えば、イソパルミチン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸などの飽和脂肪酸残基が挙げられる。また、上記Ｒ２としては、例えば、２−エチルヘキシル基、イソトリデシル基、２−ヘキシルデシル基、イソステアリル基、２−オクチルドデシル基が挙げられる。 Examples of R 1 COO include saturated fatty acid residues such as isopalmitic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, and stearic acid. Examples of R 2 include a 2-ethylhexyl group, an isotridecyl group, a 2-hexyldecyl group, an isostearyl group, and a 2-octyldodecyl group.
本実施形態の毛髪用組成物には、公知の液状エステル（Ｉ）から選ばれた一種又は二種以上が成分（Ａ）として配合される。本実施形態の毛髪用組成物において、成分（Ｂ）である液状エステル（Ｉ）の配合量は、例えば、０．００１質量％以上１０質量％以下であり、０．００２質量％以上５質量％以下が良く、０．００４質量％以上３質量％以下が好ましく、０．００８質量％以上１質量％以下がより好ましく、０．０１質量％以上０．５質量％以下が更に好ましい。０．００１質量％以上であると、毛髪の水分保持性の向上、又は、細胞膜複合体における脂質層（β層）の厚みの増加がより優れる。１０質量％以下であると、本実施形態の毛髪用組成物の低コスト化を図れる。 In the hair composition of this embodiment, one or more selected from known liquid esters (I) are blended as component (A). In the hair composition of the present embodiment, the blending amount of the liquid ester (I) as the component (B) is, for example, from 0.001% by mass to 10% by mass, and from 0.002% by mass to 5% by mass. The following is good, 0.004 mass% or more and 3 mass% or less are preferable, 0.008 mass% or more and 1 mass% or less are more preferable, 0.01 mass% or more and 0.5 mass% or less are still more preferable. When the content is 0.001% by mass or more, the water retention of hair is improved, or the thickness of the lipid layer (β layer) in the cell membrane complex is more excellent. When the content is 10% by mass or less, the cost of the hair composition of this embodiment can be reduced.
本実施形態の毛髪用組成物に配合する成分（Ａ）と（Ｂ）の質量比は、例えば、１：０．３以上２．５以下である。 The mass ratio of the components (A) and (B) blended in the hair composition of the present embodiment is, for example, 1: 0.3 or more and 2.5 or less.
上記液状エステル（Ｉ）としては、例えば、下記一般式（Ｉ−１）で表される液状エステル（Ｉ−１）が挙げられる。
Ｒ３ＣＯＯ−Ｒ４ （Ｉ−１）
［上記一般式（Ｉ−１）において、Ｒ３ＣＯＯは炭素数が１２以上１８以下である分岐状の飽和脂肪酸残基を表し、Ｒ４は炭素数が８以上２０以下である分岐状の飽和炭化水素基を表す。］
As said liquid ester (I), the liquid ester (I-1) represented by the following general formula (I-1) is mentioned, for example.
R 3 COO-R 4 (I-1)
[In the above general formula (I-1), R 3 COO represents a branched saturated fatty acid residue having 12 to 18 carbon atoms, and R 4 represents a branched saturated fatty acid having 8 to 20 carbon atoms. Represents a hydrocarbon group. ]
上記液状エステル（Ｉ−１）としては、例えば、イソパルミチン酸２−エチルヘキシル、イソステアリン酸２−ヘキシルデシル、イソステアリン酸イソステアリル、イソステアリン酸２−オクチルドデシルが挙げられる。これらから選ばれた一種又は二種以上が、本実施形態の毛髪用組成物に配合される。 Examples of the liquid ester (I-1) include 2-ethylhexyl isopalmitate, 2-hexyldecyl isostearate, isostearyl isostearate, and 2-octyldodecyl isostearate. One or more selected from these are blended in the hair composition of the present embodiment.
本実施形態の毛髪用組成物において、液状エステル（Ｉ−１）の配合量は、例えば、０．００１質量％以上１０質量％以下であり、０．００２質量％以上５質量％以下が良く、０．００４質量％以上３質量％以下が好ましく、０．００８質量％以上１質量％以下がより好ましく、０．０１質量％以上０．５質量％以下が更に好ましい。０．００１質量％以上であると、毛髪の水分保持性の向上、又は、細胞膜複合体における脂質層（β層）の厚みの増加がより優れる。１０質量％以下であると、本実施形態の毛髪用組成物の低コスト化を図れる。 In the hair composition of the present embodiment, the blending amount of the liquid ester (I-1) is, for example, from 0.001% by mass to 10% by mass, preferably from 0.002% by mass to 5% by mass, 0.004 mass% or more and 3 mass% or less are preferable, 0.008 mass% or more and 1 mass% or less are more preferable, and 0.01 mass% or more and 0.5 mass% or less are still more preferable. When the content is 0.001% by mass or more, the water retention of hair is improved, or the thickness of the lipid layer (β layer) in the cell membrane complex is more excellent. When the content is 10% by mass or less, the cost of the hair composition of this embodiment can be reduced.
配合する成分（Ａ）と液状エステル（Ｉ−１）の質量比は、例えば、１：０．３以上２．５以下である。 The mass ratio of the component (A) to be blended and the liquid ester (I-1) is, for example, from 1: 0.3 to 2.5.
また、上記液状エステル（Ｉ）としては、下記一般式（Ｉ−２）で表される液状エステル（Ｉ−２）が挙げられる。
Ｒ５ＣＯＯ−Ｒ６ （Ｉ−２）
［上記一般式（Ｉ−２）において、Ｒ５ＣＯＯは炭素数が１２以上１８以下である直鎖状の飽和脂肪酸残基を表し、Ｒ６は炭素数が８以上２０以下である分岐状の飽和炭化水素基を表す。］
Moreover, as said liquid ester (I), the liquid ester (I-2) represented by the following general formula (I-2) is mentioned.
R 5 COO-R 6 (I-2)
[In the general formula (I-2), R 5 COO represents a linear saturated fatty acid residue having 12 to 18 carbon atoms, and R 6 is a branched chain having 8 to 20 carbon atoms. Represents a saturated hydrocarbon group. ]
上記液状エステル（Ｉ−２）としては、例えば、ラウリン酸イソステアリル、ミリスチン酸イソトリデシル、ミリスチン酸２−ヘキシルデシル、ミリスチン酸イソステアリル、ミリスチン酸２−オクチルドデシル、パルミチン酸２−エチルヘキシル、パルミチン酸２−ヘキシルデシル、パルミチン酸イソステアリル、ステアリン酸２−エチルヘキシル、ステアリン酸２−ヘキシルデシルが挙げられる。これらから選ばれた一種又は二種以上が、本実施形態の毛髪用組成物に配合される。 Examples of the liquid ester (I-2) include isostearyl laurate, isotridecyl myristate, 2-hexyldecyl myristate, isostearyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl palmitate, palmitic acid 2 -Hexyldecyl, isostearyl palmitate, 2-ethylhexyl stearate, 2-hexyldecyl stearate. One or more selected from these are blended in the hair composition of the present embodiment.
本実施形態の毛髪用組成物において、液状エステル（Ｉ−２）の配合量は、例えば、０．００１質量％以上１０質量％以下であり、０．００２質量％以上５質量％以下が良く、０．００４質量％以上３質量％以下が好ましく、０．００８質量％以上１質量％以下がより好ましく、０．０１質量％以上０．５質量％以下が更に好ましい。０．００１質量％以上であると、毛髪の水分保持性の向上、又は、細胞膜複合体における脂質層（β層）の厚みの増加がより優れる。１０質量％以下であると、本実施形態の毛髪用組成物の低コスト化を図れる。 In the hair composition of the present embodiment, the blending amount of the liquid ester (I-2) is, for example, 0.001% by mass to 10% by mass, and preferably 0.002% by mass to 5% by mass. 0.004 mass% or more and 3 mass% or less are preferable, 0.008 mass% or more and 1 mass% or less are more preferable, and 0.01 mass% or more and 0.5 mass% or less are still more preferable. When the content is 0.001% by mass or more, the water retention of hair is improved, or the thickness of the lipid layer (β layer) in the cell membrane complex is more excellent. When the content is 10% by mass or less, the cost of the hair composition of this embodiment can be reduced.
配合する成分（Ａ）と液状エステル（Ｉ−２）の質量比は、例えば、１：０．３以上２．５以下である。 The mass ratio of the component (A) to be blended and the liquid ester (I-2) is, for example, from 1: 0.3 to 2.5.
本実施形態の毛髪用組成物には、上記の通り、公知の毛髪用組成物に配合されている原料を更に配合しても良い。その原料としては、毛髪用組成物の用途に応じて適宜選定され、例えば、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、高級アルコール、多価アルコール、油脂、シリコーン、高分子化合物である。 You may further mix | blend the raw material mix | blended with the well-known hair composition as above-mentioned in the composition for hair of this embodiment. The raw material is appropriately selected according to the use of the hair composition. For example, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, higher alcohols, polyhydric alcohols, oils and fats, silicones Is a polymer compound.
アニオン界面活性剤としては、例えば、アルキルエーテルカルボン酸塩、アルカンスルホン酸塩、α−オレフィンスルホン酸塩、アルキル硫酸塩、アルキルエーテル硫酸塩が挙げられる。毛髪用組成物にアニオン界面活性剤を配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物におけるアニオン界面活性剤の配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上２０質量％以下である。 Examples of the anionic surfactant include alkyl ether carboxylates, alkane sulfonates, α-olefin sulfonates, alkyl sulfates, and alkyl ether sulfates. When an anionic surfactant is blended in the hair composition, one or more may be blended. The concentration of the anionic surfactant in the hair composition is appropriately set according to the use of the composition, and is, for example, from 0.1% by mass to 20% by mass.
カチオン界面活性剤としては、例えば、脂肪酸アミドアミン塩、エステル含有３級アミン塩、長鎖アルキルトリメチルアンモニウム塩、ジ長鎖アルキルジメチルアンモニウム塩が挙げられる。毛髪用組成物にカチオン界面活性剤を配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物におけるカチオン界面活性剤の配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上２０質量％以下である。 Examples of the cationic surfactant include fatty acid amidoamine salts, ester-containing tertiary amine salts, long chain alkyltrimethylammonium salts, and dilong chain alkyldimethylammonium salts. When a cationic surfactant is blended in the hair composition, one or more kinds may be blended. Further, the concentration of the cationic surfactant in the hair composition is appropriately set according to the use of the composition, and is, for example, from 0.1% by mass to 20% by mass.
両性界面活性剤としては、例えば、アルキルジメチルアミノ酢酸ベタイン、脂肪酸アミドプロピルジメチルアミノ酢酸ベタイン、アルキルジヒドロキシエチルアミノ酢酸ベタインが挙げられる。毛髪用組成物に両性界面活性剤を配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物における両性界面活性剤の配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上１０質量％以下である。 Examples of amphoteric surfactants include alkyldimethylaminoacetic acid betaines, fatty acid amidopropyldimethylaminoacetic acid betaines, and alkyldihydroxyethylaminoacetic acid betaines. When the amphoteric surfactant is blended in the hair composition, one or more may be blended. Moreover, the compounding concentration of the amphoteric surfactant in the hair composition is appropriately set according to the use of the composition, and is, for example, from 0.1% by mass to 10% by mass.
ノニオン界面活性剤としては、例えば、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステルが挙げられる。毛髪用組成物にノニオン界面活性剤を配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物におけるノニオン界面活性剤の配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上２０質量％以下である。 Examples of the nonionic surfactant include polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, Sucrose fatty acid ester is mentioned. When a nonionic surfactant is blended in the hair composition, one or two or more types may be blended. The concentration of the nonionic surfactant in the hair composition is appropriately set according to the use of the composition, and is, for example, from 0.1% by mass to 20% by mass.
高級アルコールとしては、例えば、セタノール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、ミリスチルアルコールが挙げられる。毛髪用組成物に高級アルコールを配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物における高級アルコールの配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば１質量％以上１０質量％以下である。 Examples of the higher alcohol include cetanol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, and myristyl alcohol. When a higher alcohol is blended in the hair composition, one or more may be blended. Moreover, although the mixing | blending density | concentration of the higher alcohol in the composition for hair is set suitably according to the use of the said composition, it is 1 to 10 mass%, for example.
多価アルコールとしては、例えば、エチレングリコール、ジエチレングリコール、トリエチレングリコール、プロピレングリコール、ジプロピレングリコール、グリセリン、ジグリセリン、ブチレングリコールが挙げられる。毛髪用組成物に多価アルコールを配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物における多価アルコールの配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上２０質量％以下である。 Examples of the polyhydric alcohol include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin, and butylene glycol. When blending polyhydric alcohol in the hair composition, it is preferable to blend one or more kinds. The blending concentration of the polyhydric alcohol in the hair composition is appropriately set according to the use of the composition, and is, for example, 0.1% by mass or more and 20% by mass or less.
油脂としては、例えばアボガド油、オリーブ油、シア脂油、月見草油、ツバキ油、ローズヒップ油が挙げられる。毛髪用組成物に油脂を配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物における油脂の配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上５質量％以下である。 Examples of the fats and oils include avocado oil, olive oil, shea fat oil, evening primrose oil, camellia oil, and rosehip oil. When oils and fats are blended in the hair composition, one or more may be blended. Moreover, although the compounding density | concentration of the fats and oils in the composition for hair is set suitably according to the use of the said composition, it is 0.1 to 5 mass%, for example.
シリコーンとしては、例えば、ジメチルシリコーン、環状ジメチルシリコーン、アミノ変性シリコーンが挙げられる。毛髪用組成物にシリコーンを配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物におけるシリコーンの配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上５０質量％以下である。 Examples of silicone include dimethyl silicone, cyclic dimethyl silicone, and amino-modified silicone. When silicone is blended in the hair composition, one or more may be blended. Moreover, although the compounding density | concentration of the silicone in the composition for hair is set suitably according to the use of the said composition, it is 0.1 to 50 mass%, for example.
合成高分子化合物としては、例えば、ポリアクリル酸系高分子（カルボキシビニルポリマー、ポリアクリル酸アミド、ポリアクリル酸ナトリウム、（アクリル酸／メタクリル酸アルキル）コポリマーが挙げられる。半合成高分子化合物としては、例えば、セルロース誘導体（ヒドロキシエチルセルロース、カチオン化セルロースなど）、デンプン誘導体（ヒドロキシプロピルデンプンリン酸など）、グアーガム誘導体（カチオン化グアーガム、ヒドロキシプロピル化グアーガムなど）が挙げられる。また、天然高分子としては、例えば、ヒアルロン酸ナトリウムが挙げられる。毛髪用組成物に高分子化合物（合成高分子化合物、半合成高分子化合物、天然高分子化合物）を配合する場合、一種又は二種以上を配合すると良い。また、毛髪用組成物における高分子化合物の配合濃度は、当該組成物の用途に応じて適宜設定されるものであるが、例えば０．１質量％以上５質量％以下である。 Examples of the synthetic polymer compound include polyacrylic acid polymers (carboxyvinyl polymer, polyacrylic acid amide, sodium polyacrylate, (acrylic acid / alkyl methacrylate) copolymer. Examples include cellulose derivatives (such as hydroxyethyl cellulose and cationized cellulose), starch derivatives (such as hydroxypropyl starch phosphate), and guar gum derivatives (such as cationized guar gum and hydroxypropylated guar gum). For example, sodium hyaluronate, etc. When blending a polymer compound (synthetic polymer compound, semi-synthetic polymer compound, natural polymer compound) into the hair composition, one or more may be blended. Hair set Blending the concentration of the polymer compound in things, but is set as appropriate depending on the application of the composition, for example, a 5 wt% or less than 0.1 wt%.
本実施形態の毛髪用組成物は、毛髪に塗布して毛髪処理する方法で使用される。例えば、（１）濡れた毛髪に塗布後、毛髪を水洗して使用する洗い流すトリートメント、（２）濡れた毛髪又は乾燥した毛髪に塗布後、毛髪を水洗しないで使用する洗い流さないトリートメント、（３）毛髪表面を洗浄するために、濡れた毛髪に塗布後、毛髪を水洗して使用する毛髪洗浄剤として、本実施形態の毛髪用組成物が用いられる。 The hair composition of the present embodiment is used in a method for applying hair treatment to hair. For example, (1) a wash-out treatment in which the hair is washed and used after being applied to wet hair, (2) a non-wash-out treatment in which the hair is not washed with water after being applied to wet or dry hair, and (3) In order to wash the hair surface, the hair composition of this embodiment is used as a hair washing agent that is applied to wet hair and then washed with water.
上記毛髪用組成物が、洗い流すトリートメント、洗い流さないトリートメント、又は毛髪洗浄剤として用いられる場合、成分（Ａ）及び（Ｂ）と共に配合される原料の組合せ例を挙げれば次の通りである。洗い流すトリートメントにおいて配合される原料の組合せとしては、カチオン界面活性剤、ノニオン界面活性剤、高級アルコール、多価アルコール、油脂、シリコーン、合成高分子化合物、及び水である。洗い流さないトリートメントにおいて配合される原料の組合せとしては、カチオン界面活性剤、ノニオン界面活性剤、多価アルコール、油脂、シリコーン、合成高分子化合物、天然高分子化合物、及び水である。毛髪洗浄剤において配合される原料の組合せとしては、アニオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、多価アルコール、半合成高分子化合物、及び水である。 When the hair composition is used as a treatment for washing away, a treatment for not washing away, or a hair washing agent, examples of combinations of raw materials to be blended with the components (A) and (B) are as follows. As a combination of raw materials to be blended in the washing treatment, there are a cationic surfactant, a nonionic surfactant, a higher alcohol, a polyhydric alcohol, an oil and fat, silicone, a synthetic polymer compound, and water. A combination of raw materials to be blended in a treatment that does not wash away is a cationic surfactant, a nonionic surfactant, a polyhydric alcohol, an oil or fat, silicone, a synthetic polymer compound, a natural polymer compound, and water. The combination of raw materials blended in the hair cleansing agent is an anionic surfactant, an amphoteric surfactant, a nonionic surfactant, a polyhydric alcohol, a semi-synthetic polymer compound, and water.
本実施形態の毛髪用組成物の使用時の剤型は、特に限定されず、例えば、液状、クリーム状、ゲル状、フォーム状（泡状）、霧状が挙げられる。また、本実施形態の毛髪用組成物が油相と水相を有する場合、外相が水である水中油型の剤型、外相が油相である油中水型の剤型のいずれであっても良い。水中油型の剤型である場合、水の配合量は、例えば６０質量％以上である。油中水型の剤型である場合、水の配合量は、例えば１０質量％以下である。 The dosage form at the time of use of the composition for hair of this embodiment is not specifically limited, For example, liquid form, cream form, gel form, foam form (foam form), and mist form are mentioned. In addition, when the hair composition of the present embodiment has an oil phase and an aqueous phase, it is either an oil-in-water dosage form in which the outer phase is water, or a water-in-oil dosage form in which the outer phase is an oil phase. Also good. In the case of an oil-in-water dosage form, the amount of water is, for example, 60% by mass or more. In the case of a water-in-oil dosage form, the amount of water is, for example, 10% by mass or less.
本実施形態の毛髪用組成物の２５℃におけるｐＨは、適宜設定されるべきものであるが、例えば４．０以上７．０以下である。 The pH at 25 ° C. of the hair composition of the present embodiment should be appropriately set, and is, for example, 4.0 or more and 7.0 or less.
以下、実施例に基づき本発明を詳述するが、この実施例の記載に基づいて本発明が限定的に解釈されるものではない。 EXAMPLES Hereinafter, although this invention is explained in full detail based on an Example, this invention is not interpreted limitedly based on description of this Example.
（毛髪用組成物）
スクワラン（オリーブ油由来のスクワレンを水素添加した植物性スクワラン）、イソステアリン酸イソステアリル、及び、デカメチルシクロペンタシロキサンを使用し、実施例１及び比較例１〜２の毛髪用組成物を調製した。これら組成物の配合量は、下記表１の通りとした。
(Hair composition)
The hair compositions of Example 1 and Comparative Examples 1 and 2 were prepared using squalane (a vegetable squalane obtained by hydrogenating squalene derived from olive oil), isostearyl isostearate, and decamethylcyclopentasiloxane. The blending amounts of these compositions were as shown in Table 1 below.
（水分保持性）
実施例１又は比較例１〜２の毛髪用組成物で処理した毛髪、及び未処理毛髪の水分蒸散率を算出して、毛髪の水分保持性の試験を行った。試験の詳細は、下記の通りとした。
(Moisture retention)
The moisture transpiration rate of hair treated with the hair composition of Example 1 or Comparative Examples 1 and 2 and untreated hair was calculated, and the moisture retention test of the hair was performed. The details of the test were as follows.
無作為に選定した日本人女性５名から採取した毛髪を「未処理毛髪」として、準備した。それぞれの未処理毛髪を実施例１の毛髪用組成物に１０分間浸漬した後、水洗し、温風乾燥させて、毛髪処理を行った。同様の毛髪処理を、比較例１又は比較例２の毛髪用組成物を使用して行った。 The hair collected from five randomly selected Japanese women was prepared as “untreated hair”. Each untreated hair was immersed in the hair composition of Example 1 for 10 minutes, then washed with water and dried with warm air to perform hair treatment. The same hair treatment was performed using the hair composition of Comparative Example 1 or Comparative Example 2.
上記未処理の毛髪及び処理した毛髪を１ｍｍ程度に細断し、２５℃、湿度５０％の室内に６時間以上放置してから、細断後の毛髪各１００ｍｇを収集した。この収集した毛髪を、２５℃、湿度８５質量％の恒温恒湿槽内に６時間以上放置した。次いで、２５℃、湿度５０％の室内に移動させてから、３５〜４５秒の時間内に毛髪質量を測定し、この測定値を毛髪質量の初期（Ｗｉｎｉ）とした。Ｗｉｎｉ測定後、室内に毛髪を継続して放置し、放置時間３０分後の毛髪質量（Ｗ３０）と、６０分後の毛髪質量（Ｗ６０）を測定した。 The untreated hair and the treated hair were chopped to about 1 mm and left in a room at 25 ° C. and a humidity of 50% for 6 hours or more, and then 100 mg of each chopped hair was collected. The collected hair was left in a constant temperature and humidity chamber at 25 ° C. and a humidity of 85% by mass for 6 hours or more. Next, after moving into a room at 25 ° C. and a humidity of 50%, the hair mass was measured within a period of 35 to 45 seconds, and this measured value was taken as the initial value (W ini ) of the hair mass. After the Wini measurement, the hair was left in the room, and the hair mass (W 30 ) after 30 minutes and the hair mass (W 60 ) after 60 minutes were measured.
そして、放置時間３０分後の水分蒸散率（Ｔ３０）と、６０分後の水分蒸散率（Ｔ６０）とを下記式により算出した（下記式におけるＷ３０、Ｗ６０、Ｗｉｎｉは、上記参照。）。
Ｔ３０＝１００−Ｗ３０／Ｗｉｎｉ×１００
Ｔ６０＝１００−Ｗ６０／Ｗｉｎｉ×１００
Then, the moisture transpiration rate after 30 minutes of standing (T 30 ) and the moisture transpiration rate after 60 minutes (T 60 ) were calculated by the following formulas (W 30 , W 60 , W ini in the following formulas are reference.).
T 30 = 100−W 30 / W ini × 100
T 60 = 100−W 60 / W ini × 100
下記表２に、放置時間３０分後の水分蒸散率に関する結果を示す。なお、下記表２における「毛髪質量」及び「水分蒸散率」は、上記採取した５名の毛髪に基づく平均値である。
上記表２に示す通り、成分（Ａ）であるスクワラン又は成分（Ｂ）であるイソステアリン酸イソステアリルを配合した比較例１〜２は、未処理毛髪よりも水分蒸散率が低い値であった。成分（Ａ）及び（Ｂ）の双方を配合した実施例１は、比較例１〜２よりも水分蒸散率が低く、水分保持性に優れるものであった。 As shown in Table 2 above, Comparative Examples 1 and 2 in which squalane as the component (A) or isostearyl isostearate as the component (B) was blended had a lower moisture transpiration rate than untreated hair. Example 1 in which both components (A) and (B) were blended had a lower moisture transpiration rate than Comparative Examples 1 and 2, and was excellent in moisture retention.
下記表３に、３０分後の水分蒸散率に関する結果を示す。なお、上記表２と同様、下記表３における「毛髪質量」及び「水分蒸散率」は平均値である。
上記表３に示す通り、上記表２と同様、成分（Ａ）及び（Ｂ）の双方を配合した実施例１は、水分蒸散率が最も低く、水分保持性に優れるものであった。 As shown in Table 3, Example 1 in which both components (A) and (B) were blended had the lowest moisture transpiration rate and was excellent in moisture retention, as in Table 2 above.
（細胞膜複合体における脂質層及びタンパク質層の厚み）
ブリーチ処理および実施例１の毛髪用組成物で処理した毛髪、ブリーチ処理後の毛髪、未処理毛髪について、毛髪キューティクルの細胞膜複合体（ＣＭＣ）における脂質層（β層）及びタンパク質層（δ層）の厚みを測定した。この測定までの詳細は、以下の通りとした。
(Thickness of lipid layer and protein layer in cell membrane complex)
Lipid layer (β layer) and protein layer (δ layer) in the cell membrane complex (CMC) of the hair cuticle for the bleach treatment and the hair treated with the hair composition of Example 1, the hair after the bleach treatment, and the untreated hair The thickness of was measured. The details up to this measurement were as follows.
酸化染毛処理などの化学的処理の履歴がない２０〜５０代の日本人女性１８名から採取した毛髪を「未処理毛髪」として準備した。それぞれの未処理毛髪を、ブリーチ剤（過酸化水素が３質量％であり、アンモニア水でｐＨを１０．０に調整した水溶液）に２０分間浸漬した後、水洗し、温風乾燥させて、ブリーチ処理を行った。また、ブリーチ処理後の毛髪を、実施例１の毛髪用組成物に１０分間浸漬した後、水洗し、温風乾燥させて、毛髪処理を行った。 Hair collected from 18 Japanese women in their 20s and 50s who had no history of chemical treatment such as oxidative hair dyeing was prepared as “untreated hair”. Each untreated hair was immersed in a bleaching agent (aqueous solution containing 3% by mass of hydrogen peroxide and adjusted to pH 10.0 with aqueous ammonia) for 20 minutes, washed with water, dried in warm air, and bleached. Processed. The hair after bleaching was dipped in the hair composition of Example 10 for 10 minutes, then washed with water and dried with warm air to perform hair treatment.
上記の未処理毛髪、ブリーチ処理後の毛髪、実施例１の毛髪用組成物を使用した毛髪処理後の毛髪のキューティクルにおけるＣＭＣのβ層、δ層について、大型放射光施設ＳＰｒｉｎｇ−８のビームラインＢＬ２４ＸＵを使用して測定した。この測定では、毛髪の軸に垂直にして、Ｘ線マイクロビームを毛髪のキューティクルに照射した。他の測定条件は、次の通りである。
ビームサイズ：５．６μｍ×４．８μｍ
カメラ長：１１２２ｍｍ
露光時間：３０秒
For the above-mentioned untreated hair, bleached hair, and CMC β layer and δ layer in the cuticle of hair using the hair composition of Example 1, the beam line of the large synchrotron radiation facility SPring-8 Measurements were made using BL24XU. In this measurement, the hair cuticle was irradiated with an X-ray microbeam perpendicular to the hair axis. Other measurement conditions are as follows.
Beam size: 5.6 μm × 4.8 μm
Camera length: 1122mm
Exposure time: 30 seconds
公知の報告（N.Ohta,et al.,J.Appl.Crystal.38,274-279(2005).）を参考に、ＳＰｒｉｎｇ−８による測定結果である散乱プロファイルからβ層とδ層の厚みを算出した。算出した結果は、下表４〜５の「毛髪処理後」、「ブリーチ処理後」、「未処理」の値の通りである。 With reference to a known report (N. Ohta, et al., J. Appl. Crystal. 38, 274-279 (2005)), the thicknesses of the β layer and δ layer are calculated from the scattering profile as a result of measurement by SPring-8. did. The calculated results are as shown in the values of “after hair treatment”, “after bleach treatment”, and “untreated” in Tables 4 to 5 below.
上記表４〜５において、β層及びδ層の値が「ブリーチ処理」は「未処理」よりも小さく、化学的処理（ブリーチ処理）により、β層及びδ層の厚みが減少していた。しかし、β層については、成分（Ａ）及び（Ｂ）を配合した実施例１の毛髪用組成物の処理により、大きく増加していた（表４〜５の『厚みの差（ｎｍ）：「毛髪処理後」−「ブリーチ処理後」』参照）。 In Tables 4 to 5, the values of the β layer and the δ layer were “bleached” smaller than “untreated”, and the thickness of the β layer and δ layer was reduced by chemical treatment (bleaching treatment). However, the β layer was greatly increased by the treatment of the hair composition of Example 1 in which the components (A) and (B) were blended ("Thickness difference (nm) in Tables 4 to 5:" After hair treatment "-" After bleaching treatment ").
Claims (7)
（Ａ）スクワラン
（Ｂ）下記一般式（Ｉ）で表される液状エステル（Ｉ）
Ｒ１ＣＯＯ−Ｒ２ （Ｉ）
［上記一般式（Ｉ）において、Ｒ１ＣＯＯは炭素数が１２以上１８以下である飽和脂肪酸残基を表し、Ｒ２は炭素数が８以上２０以下である飽和炭化水素基を表す。］ A hair composition comprising the following components (A) and (B):
(A) Squalane (B) Liquid ester (I) represented by the following general formula (I)
R 1 COO-R 2 (I)
[In the general formula (I), R 1 COO represents a saturated fatty acid residue having 12 to 18 carbon atoms, and R 2 represents a saturated hydrocarbon group having 8 to 20 carbon atoms. ]
Ｒ３ＣＯＯ−Ｒ４ （Ｉ−１）
［上記一般式（Ｉ−１）において、Ｒ３ＣＯＯは炭素数が１２以上１８以下である分岐状の飽和脂肪酸残基を表し、Ｒ４は炭素数が８以上２０以下である分岐状の飽和炭化水素基を表す。］ The hair composition according to claim 1, wherein a liquid ester (I-1) represented by the following general formula (I-1) is blended as the component (B).
R 3 COO-R 4 (I-1)
[In the above general formula (I-1), R 3 COO represents a branched saturated fatty acid residue having 12 to 18 carbon atoms, and R 4 represents a branched saturated fatty acid having 8 to 20 carbon atoms. Represents a hydrocarbon group. ]
Ｒ５ＣＯＯ−Ｒ６ （Ｉ−２）
［上記一般式（Ｉ−２）において、Ｒ５ＣＯＯは炭素数が１２以上１８以下である直鎖状の飽和脂肪酸残基を表し、Ｒ６は炭素数が８以上２０以下である分岐状の飽和炭化水素基を表す。］ The composition for hair of any one of Claims 1-3 with which liquid ester (I-2) represented by the following general formula (I-2) was mix | blended as said (B) component.
R 5 COO-R 6 (I-2)
[In the general formula (I-2), R 5 COO represents a linear saturated fatty acid residue having 12 to 18 carbon atoms, and R 6 is a branched chain having 8 to 20 carbon atoms. Represents a saturated hydrocarbon group. ]
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH101423A (en) * | 1996-06-14 | 1998-01-06 | Kanebo Ltd | Hair-treatment agent |
| JP2006316003A (en) * | 2005-05-13 | 2006-11-24 | Shin-Ei Chemical Co Ltd | Stable liquid composition containing alcohol ester of hydrogenated rosin and cosmetic product containing the same |
| JP2008127337A (en) * | 2006-11-21 | 2008-06-05 | Kracie Home Products Kk | Hair cosmetic |
| JP2013040107A (en) * | 2011-08-11 | 2013-02-28 | Kao Corp | Emulsion type hair dressing agent |
| JP2016222583A (en) * | 2015-05-29 | 2016-12-28 | 高級アルコール工業株式会社 | Hair cosmetic |
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2017
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH101423A (en) * | 1996-06-14 | 1998-01-06 | Kanebo Ltd | Hair-treatment agent |
| JP2006316003A (en) * | 2005-05-13 | 2006-11-24 | Shin-Ei Chemical Co Ltd | Stable liquid composition containing alcohol ester of hydrogenated rosin and cosmetic product containing the same |
| JP2008127337A (en) * | 2006-11-21 | 2008-06-05 | Kracie Home Products Kk | Hair cosmetic |
| JP2013040107A (en) * | 2011-08-11 | 2013-02-28 | Kao Corp | Emulsion type hair dressing agent |
| JP2016222583A (en) * | 2015-05-29 | 2016-12-28 | 高級アルコール工業株式会社 | Hair cosmetic |
Non-Patent Citations (2)
| Title |
|---|
| MOISTURE RICH HAIR CREAM, ID# 189490, MINTEL GNPD [ONLINE], 2003年2月, [検索日2021.10.08], URL HTTPS, JPN6021041357, ISSN: 0004622743 * |
| SATIN SOFTENING DRY OIL, ID# 2972997, MINTEL GNPD [ONLINE], 2015年4月, [検索日2022.3.1], URL HTTPS:/, JPN6022009187, ISSN: 0004719457 * |
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