JP2018202124A - Pulp-mixed nonwoven fabric wipe, and method of manufacturing the same - Google Patents

Pulp-mixed nonwoven fabric wipe, and method of manufacturing the same Download PDF

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JP2018202124A
JP2018202124A JP2017187491A JP2017187491A JP2018202124A JP 2018202124 A JP2018202124 A JP 2018202124A JP 2017187491 A JP2017187491 A JP 2017187491A JP 2017187491 A JP2017187491 A JP 2017187491A JP 2018202124 A JP2018202124 A JP 2018202124A
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pulp
nonwoven fabric
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JP7195046B2 (en
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力 大西
Tsutomu Onishi
力 大西
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Daio Paper Corp
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Abstract

To provide a pulp-mixed nonwoven fabric wipe excellent in liquid absorbing property and abrasion resistance.SOLUTION: In a pulp-mixed nonwoven fabric wipe in which pulp 3 and chemical fibers 2 are intertwined together, basis weight is in the range of 45 to 80 g/m; the basis weight of the chemical fibers 2 is in the range of 10 to 17 g/m; the blending ratio of the pulp 3 is 75 mass% or more; the aspect ratio of dry tensile strength is 3.0 or less: and a front-and-back-sides difference in measurement value in a Martindale method specified in JIS L 1096 E is 100 or less.SELECTED DRAWING: Figure 1

Description

本発明は、パルプ混合不織布ワイプ及びパルプ混合不織布ワイプの製造方法に関する。   The present invention relates to a pulp-mixed nonwoven fabric wipe and a method for producing a pulp-mixed nonwoven fabric wipe.

パルプと化学繊維とを水流絡合したパルプ混合不織布は、様々な用途に用いられているが、水や油等の吸液性に優れることから不織布ワイプとしても使用されている。
このパルプ混合不織布ワイプは、種々の拭き取りに使用されることから吸液性に加え耐磨耗性も重要となる。
Pulp-mixed nonwoven fabrics in which pulp and chemical fibers are hydroentangled are used in various applications, but are also used as nonwoven fabric wipes because of their excellent liquid absorbency such as water and oil.
Since this pulp-mixed nonwoven fabric wipe is used for various types of wiping, in addition to liquid absorption, wear resistance is also important.

そして、この種のパルプ混合不織布ワイプにおける吸液性、特に吸水性は、主に配合されるパルプ繊維が影響する。しかし、吸水性を高めるためにパルプ繊維の配合割合を単に増加させるとパルプ繊維が表面から離脱しやすくなり、特に強く擦りつけるような拭き取り操作を行った際に、パルプが剥がれ脱落するおそれが高まる。   And the liquid absorbency in this kind of pulp mixed nonwoven fabric wipe, especially water absorption, mainly affects the pulp fiber mix | blended. However, if the blending ratio of the pulp fiber is simply increased in order to increase the water absorption, the pulp fiber tends to be detached from the surface, and the pulp is likely to peel off and fall off when performing a wiping operation that particularly rubs strongly. .

このパルプの表面からの離脱を防止するために、表面にバインダーを塗布したり、バインダー繊維を配合する技術が知られているが、このようなバインダーの塗布等は吸液性が低下しまたコスト高となる欠点がある。   In order to prevent the pulp from detaching from the surface, a technique of applying a binder to the surface or blending a binder fiber is known. However, such a binder application reduces the liquid absorbency and costs. There is a drawback of becoming high.

特開2014−68855号公報JP 2014-68855 A

そこで、本発明の主たる課題は、吸液性と耐摩耗性に優れる、パルプと化学繊維とを水流絡合したパルプ混合不織布ワイプを提供することにある。   Then, the main subject of this invention is providing the pulp mixing nonwoven fabric wipe which water-entangled the pulp and the chemical fiber which is excellent in liquid absorption property and abrasion resistance.

本発明の課題を解決するための手段は次のとおりである。
すなわち、その第一の手段は、
パルプと化学繊維とが絡合されたパルプ混合不織布であり、
坪量が45〜80g/m2であり、
化学繊維の目付量が10〜17g/m2であり、
パルプの配合割合が75質量%以上あり、
乾燥引張強度の縦横比が3.0以下であり、
JIS L 1096 E法に規定されるマーチンデール法における測定値の表裏差が100以下である、
ことを特徴とするパルプ混合不織布ワイプである。
Means for solving the problems of the present invention are as follows.
That is, the first means is
A pulp mixed nonwoven fabric in which pulp and chemical fiber are entangled,
The basis weight is 45-80 g / m 2 ,
The basis weight of the chemical fiber is 10 to 17 g / m 2 ;
The blending ratio of the pulp is 75% by mass or more,
The aspect ratio of dry tensile strength is 3.0 or less,
The difference between the measured values in the Martindale method specified in JIS L 1096 E method is 100 or less,
This is a pulp-mixed nonwoven fabric wipe.

第二の手段は、パルプがNBKPを95質量%以上含み、化学繊維の太さが18〜22μmである上記第一の手段に係るパルプ混合不織布ワイプである。   A 2nd means is a pulp mixed nonwoven fabric wipe which concerns on said 1st means whose pulp contains 95 mass% or more of NBKP, and the thickness of a chemical fiber is 18-22 micrometers.

そして、第三の手段は、
目付量10〜17g/m2の化繊不織布シート上に、溶解パルプをスパンポンド不織布に積層する工程と、
ノズル径0.5〜0.15mmφのノズルから乾燥パルプシート面に水流を噴射する水流絡合工程と、
を有することを特徴とするパルプ混合不織布ワイプの製造方法である。
And the third means is
A step of laminating dissolving pulp on a spun pond non-woven fabric on a synthetic non-woven fabric sheet having a basis weight of 10 to 17 g / m 2 ;
A water entangling step of injecting a water flow from a nozzle having a nozzle diameter of 0.5 to 0.15 mmφ onto the surface of the dried pulp sheet;
It is a manufacturing method of the pulp mixing nonwoven fabric wipe characterized by having.

第四の手段は、パルプシートがNBKPを95質量%以上含み、化繊不織布シートを構成する化学繊維の太さが18〜22μmである上記第三の手段に係るパルプ混合不織布ワイプの製造方法である。   A 4th means is a manufacturing method of the pulp mixing nonwoven fabric wipe which concerns on the said 3rd means whose pulp sheet contains NBKP 95 mass% or more, and the thickness of the chemical fiber which comprises a chemical fiber nonwoven fabric sheet is 18-22 micrometers. .

本発明によれば、吸液性と耐摩耗性に優れる、パルプと化学繊維とを水流絡合したパルプ混合不織布ワイプが提供される。   ADVANTAGE OF THE INVENTION According to this invention, the pulp mixed nonwoven fabric wipe which water-entangled the pulp and the chemical fiber which is excellent in a liquid absorption property and abrasion resistance is provided.

実施例及び比較例の断面を示す写真である。It is a photograph which shows the cross section of an Example and a comparative example.

本実施形態のパルプ混合不織布ワイプ及びその製造方法を説明する。   The pulp mixed nonwoven fabric wipe of this embodiment and the manufacturing method thereof will be described.

本実施形態のパルプ混合不織布ワイプは、パルプと化学繊維とが絡合されたパルプ混合不織布である。
本実施形態のパルプ混合不織布ワイプは、パルプと化学繊維との絡合が水などの液体による液流絡合のパルプ混合不織布であり、スパンレース不織布、スパンレース式不織布などとも称される。
The pulp-mixed nonwoven fabric wipe of this embodiment is a pulp-mixed nonwoven fabric in which pulp and chemical fibers are entangled.
The pulp-mixed nonwoven fabric wipe of this embodiment is a pulp-mixed nonwoven fabric in which the entanglement between the pulp and the chemical fiber is liquid-entangled with a liquid such as water, and is also referred to as a spunlace nonwoven fabric or a spunlace nonwoven fabric.

パルプは、広葉樹由来のパルプ、針葉樹由来のパルプ、古紙由来のパルプから選択することができる。その平均繊維長(以下、繊維の長さともいう)は、3.0〜5.0mmであるのが望ましい。後述の化学繊維と絡合されやすい。パルプの中でも特に好ましくは、針葉樹由来のパルプである。針葉樹由来のパルプは、平均繊維長が3.5〜4.0mmであり、化学繊維と効果的に絡合され、繊維落ちが少なく紙粉が発生し難い。具体的には、針葉樹晒しクラフトパルプ(NBKP)、針葉樹未晒しパルプ(NUKP)である。パルプは、このNBKPを95質量%以上含むのが望ましい。   The pulp can be selected from hardwood-derived pulp, conifer-derived pulp, and wastepaper-derived pulp. The average fiber length (hereinafter also referred to as fiber length) is preferably 3.0 to 5.0 mm. It is easy to be entangled with the chemical fiber described later. Among the pulps, the coniferous pulp is particularly preferable. The pulp derived from conifers has an average fiber length of 3.5 to 4.0 mm, is effectively entangled with the chemical fiber, has little fiber drop, and does not easily generate paper dust. Specifically, they are coniferous bleached kraft pulp (NBKP) and coniferous unbleached pulp (NUKP). The pulp preferably contains 95% by mass or more of this NBKP.

化学繊維は、水流絡合不織布に用いられるものを使用できる。例えば、ポリエチレン繊維、ポリプロピレン繊維、ポリエチレンテレフタレート繊維等が挙げられる。複数の樹脂からなる繊維、例えば、芯鞘構造を有する化学繊維であってもよい。好ましくは、安価で軽量かつ十分な強度を発現でき、水流によって絡合しやすいポリエチレン繊維である。   The chemical fiber can use what is used for a hydroentangled nonwoven fabric. For example, a polyethylene fiber, a polypropylene fiber, a polyethylene terephthalate fiber, etc. are mentioned. A fiber made of a plurality of resins, for example, a chemical fiber having a core-sheath structure may be used. Preferably, it is a polyethylene fiber that is inexpensive, lightweight, can exhibit sufficient strength, and is easily entangled with water flow.

本実施形態に係るパルプ混合不織布ワイプの坪量は、45〜80g/m2である。より好ましくは、50〜60g/m2である。拭き取りに必要な強度及び十分な吸液性となる。 The basis weight of the pulp-mixed nonwoven fabric wipe according to this embodiment is 45 to 80 g / m 2 . More preferably, it is 50-60 g / m < 2 >. The strength required for wiping and sufficient liquid absorption are obtained.

他方、化学繊維の目付量は10〜17g/m2であり、好ましくは12〜14g/m2である。また、パルプの配合割合は、75質量%以上、好ましくは、80質量%以上である。このパルプ配合割合は、非常に高い数値であり、吸液性の点で優れる。すなわち、上記化学繊維の目付量の範囲で、パルプの配合割合が不織布全体の75質量%以上あると、十分な強度でありながら柔らかく、特に吸液性に優れるようになる。 On the other hand, the basis weight of the chemical fiber is 10 to 17 g / m 2 , preferably 12 to 14 g / m 2 . The blending ratio of the pulp is 75% by mass or more, preferably 80% by mass or more. This pulp blending ratio is a very high numerical value, and is excellent in terms of liquid absorbency. That is, when the blending ratio of the pulp is 75% by mass or more of the whole nonwoven fabric within the range of the basis weight of the chemical fiber, it is soft while having sufficient strength, and particularly excellent in liquid absorption.

化学繊維の太さは、18〜22μmであるのが望ましい。パルプ繊維、特に針葉樹由来のパルプとの絡合が強固でパルプ繊維が脱落し難いものとなる。   The thickness of the chemical fiber is desirably 18 to 22 μm. The entanglement with the pulp fibers, particularly the coniferous pulp, is strong and the pulp fibers are difficult to fall off.

他方で、本実施形態のパルプ混合不織布ワイプは、乾燥引張強度の縦横比が3.0以下、好ましくは2.5以下である。縦方向及び横方向の具体的な乾燥引張強度は、必ずしも限定されないが、縦方向で2,000〜3,400cN/25mm、横方向で700〜1,600cN/25mmであるのが望ましい。この範囲であれば拭き取りに十分な強度である。なお、乾燥引張強度の測定方法は、JIS P8113(1998)に準ずる方法で実施する。測定装置としては、ミネベア株式会社製「万能引張圧縮試験機 TG−200N」が挙げられる。   On the other hand, the pulp-mixed nonwoven fabric wipe of this embodiment has an aspect ratio of dry tensile strength of 3.0 or less, preferably 2.5 or less. Specific dry tensile strengths in the machine direction and the transverse direction are not necessarily limited, but are desirably 2,000 to 3,400 cN / 25 mm in the machine direction and 700 to 1,600 cN / 25 mm in the transverse direction. Within this range, the strength is sufficient for wiping. In addition, the measuring method of dry tensile strength is implemented by the method according to JIS P8113 (1998). Examples of the measuring device include “Universal Tensile Compression Tester TG-200N” manufactured by Minebea Co., Ltd.

ここで、本実施形態に係るパルプ混合不織布ワイプにおける縦横比の小さいのは特徴的である。すなわち、液流絡合のパルプ混合不織布ワイプは、通常、化学繊維の不織布シート(以下、化繊不織布シートともいう)にクレープ紙等の抄紙した紙を積層した後、紙積層面から液体を噴射することで、紙を構成するパルプ繊維と不織布シートの化学繊維を交絡させる。そして、化学繊維の不織布シートは、縦方向、横方向における乾燥引張強度の差はさほどない。したがって、パルプ混合不織布ワイプにおける縦横比は、抄紙という製造方法に由来する紙の縦横比の影響が少なからずある。すなわち、本実施形態のパルプ混合不織布ワイプは、このような紙由来の縦横比の影響等がない特徴的なものである。なお、係るパルプ混合不織布ワイプの製造方法例は、後述する。   Here, the aspect ratio of the pulp-mixed nonwoven fabric wipe according to this embodiment is small. That is, a liquid-entangled pulp-mixed non-woven wipe is usually made by laminating a paper made of crepe paper or the like on a non-woven fabric sheet of chemical fiber (hereinafter also referred to as a synthetic non-woven fabric sheet), and then ejecting liquid from the paper lamination surface. Thus, the pulp fiber constituting the paper and the chemical fiber of the nonwoven fabric sheet are entangled. And the nonwoven fabric sheet of a chemical fiber does not have much difference in dry tensile strength in the vertical direction and the horizontal direction. Therefore, the aspect ratio of the pulp-mixed nonwoven fabric wipe is not significantly affected by the aspect ratio of the paper derived from the papermaking method. That is, the pulp-mixed nonwoven fabric wipe according to the present embodiment is characteristic without the influence of the aspect ratio derived from such paper. In addition, the example of a manufacturing method of the pulp mixed nonwoven fabric wipe which concerns is mentioned later.

他方で、本実施形態に係るパルプ混合不織布ワイプは、JIS L 1096 E法(2010)に規定されるマーチンデール法における測定値の表裏差が100以下である。さらに、表裏の測定値が、ともに20以上であるのが望ましい。マーチンデール法は、耐摩耗性を図る試験であり、試験片の裏面にポリウレタンフォーム(見掛密度0.03g/cm、厚さ約3mm)を摩耗試験機の試料ホルダに取り付け、あらかじめ織フェルト(材質:毛、単位質量:750g/m2、厚さ:3mm)の上に標準摩擦布(材質:縦/毛、横/毛、繊度:縦/R63 tex/2、横/R74 tex/2、質量:215g/m2)を重ねて取り付けた摩擦台の上に載せて多方向に、パルプ面は10〜40回、不織布面は80〜120回摩擦し、エンドポイントまでの回数を測り、毛羽立ちが目視で確認された回数を測定する。その4回の平均を算出し、これを測定値とする。なお、本実施形態における測定値は1回単位で示す。摩耗試験機の具体例としては、グロッツ・ベッケルト製のマーチンデール摩耗試験機が挙げられる。なお、測定は、摩擦を加える素材は標準摩擦布、荷重は9Kpa、WET条件、動きはリサージュとして行う。WET条件は、試料面を霧吹きで吹くことによる。 On the other hand, the pulp-mixed nonwoven fabric wipe according to this embodiment has a difference of 100 or less in the measured value according to the Martindale method defined in JIS L 1096 E method (2010). Furthermore, it is desirable that the measured values on both sides are 20 or more. The Martindale method is a test for wear resistance. A polyurethane foam (apparent density: 0.03 g / cm, thickness: about 3 mm) is attached to a sample holder of a wear tester on the back surface of a test piece, and a woven felt ( Material: hair, unit mass: 750 g / m 2 , thickness: 3 mm) on top of standard friction cloth (material: vertical / hair, horizontal / hair, fineness: vertical / R63 tex / 2, horizontal / R74 tex / 2, Mass: 215 g / m 2 ) is placed on a friction table mounted in layers, and the pulp surface is rubbed 10 to 40 times and the nonwoven fabric surface is rubbed 80 to 120 times in multiple directions. Measure the number of times that is visually confirmed. The average of the four times is calculated and used as a measured value. In addition, the measured value in this embodiment is shown per unit. A specific example of the abrasion tester is a Martindale abrasion tester manufactured by Grotz-Beckert. The measurement is performed by using a standard friction cloth as a material to apply friction, a load of 9 Kpa, a WET condition, and a motion as a Lissajous. The WET condition is based on spraying the sample surface with a spray.

ここで、本実施形態に係るパルプ混合不織布ワイプにおけるマーチンデール法における測定値の表裏差が100以下というのは特徴的である。上記のとおり、液流絡合のパルプ混合不織布ワイプは、化学繊維の不織布シートにクレープ紙等の抄紙した紙を積層した後、紙積層面から液体を噴射するため、紙面側と不織布シート側とにおける測定値に差が生じやすい。特に、紙面における耐摩耗性が顕著に弱く測定値が低くなりやすい。本実施形態のパルプ混合不織布ワイプの表裏差が小さいということは、液流交絡によって化学繊維面側にまでパルプ繊維が十分に位置するまで絡合しており、繊維同士の絡みが良好となっており、パルプ繊維の脱落がし難いものとなっている。なお、係るパルプ混合不織布ワイプの製造方法例は、後述する。   Here, it is characteristic that the difference between the measured values in the Martindale method in the pulp-mixed nonwoven fabric wipe according to this embodiment is 100 or less. As described above, the liquid-entangled pulp-mixed nonwoven fabric wipe is made by laminating paper made of crepe paper or the like on a nonwoven fabric sheet of chemical fibers, and then jets liquid from the paper lamination surface. Differences are likely to occur in the measured values. In particular, the abrasion resistance on the paper surface is remarkably weak and the measured value tends to be low. The fact that the difference in front and back of the pulp-mixed nonwoven fabric wipe of this embodiment is small means that the pulp fibers are intertwined to the chemical fiber surface side by liquid entanglement and the entanglement between the fibers is good. Therefore, it is difficult for the pulp fibers to fall off. In addition, the example of a manufacturing method of the pulp mixed nonwoven fabric wipe which concerns is mentioned later.

他方、本実施形態に係るパルプ混合不織布ワイプは、表裏のMMD(摩擦係数の変動)がともに0.200以下であり、表裏差が0.020以下であるのが望ましい。MMDは滑らかさの指標の一つである。MMDが上記範囲であると滑らかさにおいて優れるとともに、官能評価による皮膚表面の感じ方の表裏差も少ないものとなる。なお、MMDは、カトーテック株式会社製の摩擦感テスター KES−SE、KES−SESRU及びこれらの相当機を用いて測定される値である。MMDは、MIU(平均摩擦係数)からどれだけ変動があるかという変動の度合いであり、数値が小さいほど滑らかとされる。本発明に係る測定条件は、摩擦子の接触面を所定方向に20g/cmの張力が付与された測定試料の表面に対して25gの接触圧で接触させながら、張力が付与された方向と略同じ方向に速度0.1cm/sで2cm移動させる。測定は、10回測定し、その平均値をMMDとする。なお、摩擦子は、標準付属のピアノワイヤーセンサーを用いる。このピアノワイヤーセンサーは、直径0.5mmのピアノ線を20本隣接させてなり、長さ及び幅がともに10mmとなるように形成された接触面を有するものである。接触面には、先端が20本のピアノ線(曲率半径0.25mm)で形成された単位膨出部が形成されている。   On the other hand, in the pulp mixed nonwoven fabric wipe according to the present embodiment, both the front and back MMD (fluctuation in friction coefficient) are preferably 0.200 or less, and the front / back difference is preferably 0.020 or less. MMD is one index of smoothness. When the MMD is in the above range, the smoothness is excellent, and the front / back difference in how the skin surface is sensed by sensory evaluation is small. In addition, MMD is a value measured using Kato Tech Co., Ltd. friction feeling tester KES-SE, KES-SESRU, and these equivalent machines. The MMD is a degree of variation indicating how much variation occurs from the MIU (average friction coefficient), and the smaller the numerical value, the smoother. The measurement conditions according to the present invention are substantially the same as the direction in which the tension is applied while bringing the contact surface of the friction element into contact with the surface of the measurement sample to which a tension of 20 g / cm is applied in a predetermined direction at a contact pressure of 25 g. Move 2 cm in the same direction at a speed of 0.1 cm / s. The measurement is performed 10 times, and the average value is taken as MMD. In addition, a standard attached piano wire sensor is used for the friction element. The piano wire sensor has 20 piano wires with a diameter of 0.5 mm adjacent to each other, and has a contact surface formed so that the length and width are both 10 mm. The contact surface is formed with a unit bulging portion whose tip is formed of 20 piano wires (with a radius of curvature of 0.25 mm).

他方、本実施形態に係るパルプ混合不織布ワイプは、表裏のSMD(表面粗さ)の差が0.7以下であるのが望ましい。SMDは、表面の粗さであり、SMDの表裏差が上記範囲であれば、繊維の絡みが良好となっている一つの指標となる。なお、SMDも、カトーテック株式会社製の摩擦感テスター KES−FB−4−AUTO、KES-KES−SE、KES−SESRU及びこれらの相当機を用いて測定される値である。   On the other hand, the pulp mixed nonwoven fabric wipe according to the present embodiment desirably has a difference in SMD (surface roughness) between the front and back surfaces of 0.7 or less. SMD is the roughness of the surface, and if the difference between the front and back of the SMD is in the above range, it is an indicator that the entanglement of the fibers is good. In addition, SMD is also a value measured using Kato Tech Co., Ltd. friction feeling tester KES-FB-4-AUTO, KES-KES-SE, KES-SESRU, and these equivalent machines.

以上のとおり、本実施形態に係るパルプ混合不織布ワイプは、パルプ繊維の配合率が高く吸液性に優れ、さらに表裏におけるパルプ繊維の離脱差が少なく化学繊維とパルプ繊維との絡合が良好なものとなっている。なお、本実施形態に係るパルプ混合不織布ワイプにおいては、吸液性を低下させやすいバインダー成分は塗布しないのが望ましい。   As described above, the pulp-mixed nonwoven fabric wipe according to this embodiment has a high pulp fiber blending ratio and excellent liquid absorbency, and there is little separation between the pulp fibers on the front and back, and the entanglement between the chemical fibers and the pulp fibers is good. It has become a thing. In the pulp-mixed nonwoven fabric wipe according to this embodiment, it is desirable not to apply a binder component that tends to lower the liquid absorbency.

次いで、本実施形態に係るパルプ混合不織布ワイプの製造方法について説明する。本実施形態に係るパルプ混合不織布ワイプは、目付量10〜17g/m2の化繊不織布シート上に、溶解パルプをシート状にして乾燥させた乾燥パルプシートを積層する工程を有する。化繊不織布シートは、スパンボンド法、メルトブロー法によって形成されたものであるのが望ましい。化繊不織布シートを構成する化学繊維及び溶解パルプを構成するパルプ繊維における繊維種、繊維長、繊維の太さは上記の本実施形態のパルプ混合不織布ワイプにおいて説明したとおりである。 Subsequently, the manufacturing method of the pulp mixed nonwoven fabric wipe which concerns on this embodiment is demonstrated. The pulp-mixed nonwoven fabric wipe according to this embodiment includes a step of laminating a dried pulp sheet obtained by dissolving dissolved pulp into a sheet on a synthetic fiber nonwoven sheet having a basis weight of 10 to 17 g / m 2 . The synthetic nonwoven fabric sheet is desirably formed by a spunbond method or a melt blow method. The fiber types, fiber lengths, and fiber thicknesses of the chemical fibers constituting the synthetic nonwoven fabric sheet and the pulp fibers constituting the dissolving pulp are as described in the pulp-mixed nonwoven fabric wipe of the present embodiment.

溶解パルプをシート状にした乾燥パルプシートは、水にパルプ繊維を分散懸濁させたパルプ溶解液を搬送平面上に吐出し、加熱ドラムで圧縮乾燥させてシート状にしたものを用いるのが望ましい。乾燥温度は、85〜115℃、好ましくは90〜110℃である。なお、パルプ溶解液中には本発明の効果を妨げない範囲で適宜の助剤を加えることができる。この乾燥パルプシートは、繊維配向性が小さく乾燥引張強度の縦横比差が非常に小さい。また、乾燥パルプシートの目付量(坪量)は、水流交絡時の歩留まり等を考慮して、パルプ混合不織布ワイプ時にパルプの繊維配合割合が75質量%以上、好ましくは80質量%以上となるように適宜に調整する。   Desirably, the dried pulp sheet in which the dissolving pulp is formed into a sheet is used by discharging a pulp solution in which pulp fibers are dispersed and suspended in water onto a transport plane and compressing and drying with a heating drum into a sheet. . The drying temperature is 85 to 115 ° C, preferably 90 to 110 ° C. In the pulp solution, an appropriate auxiliary agent can be added as long as the effects of the present invention are not hindered. This dry pulp sheet has a small fiber orientation and a very small aspect ratio of dry tensile strength. In addition, the basis weight (basis weight) of the dried pulp sheet is such that the fiber blending ratio of the pulp is 75% by mass or more, preferably 80% by mass or more at the time of pulp mixed nonwoven fabric wipe in consideration of the yield at the time of hydroentanglement. Adjust as appropriate.

次いで、ウォータージェット技術、ウォーターニードル技術等とも称されるスパンレース技術に準じて、化繊不織布シートと乾燥パルプシートとが積層された積層シートの乾燥パルプシート面に水を噴射して打ち付け、乾燥パルプシートにおけるパルプの結合を破壊するとともに化繊不織布シートの化学繊維と乾燥パルプシートのパルプ繊維とを水流絡合させる工程を行う。ここで、本実施形態のパルプ混合不織布ワイプの製造方法では、特に水流を噴射するノズルのノズル径0.5〜1.5mmφのノズルとする。より好ましくは、0.75〜1.25mmφである。水圧については必ずしも限定されないが、100〜110bar程度が望ましい。これは一般的な圧(80〜90bar)より高い値である。なお、適宜の調整は化学繊維の種類等によって行う。このノズル径は、従来パルプ混合不織布ワイプの製造方法よりも小さい。本実施形態では、目付量10〜17g/m2の化繊不織布シート上に積層した繊維配向性の少ない乾燥パルプシートに対して小径のノズルから水流を噴射して打ち付けることで、化学繊維とパルプ繊維との絡合が良好となり、とりわけ化繊不織布シート面側へのパルプ繊維の入り込みが良好となって表裏においてパルプ繊維が離脱し難いものとなる。特に、好ましい化学繊維の構成及びパルプ繊維の構成をとる場合に、水流による繊維の動きが良好で、効果的に本実施形態に係るワイプが製造できる。すなわち、乾燥パルプシートがNBKPを95質量%以上含み、化繊不織布シートを構成する化学繊維の太さが18〜22μmであるのが望ましい。 Next, in accordance with the spunlace technology, which is also called water jet technology, water needle technology, etc., water is sprayed on the dry pulp sheet surface of the laminated sheet in which the synthetic nonwoven fabric sheet and the dry pulp sheet are laminated, and the dry pulp A process of breaking the bond of the pulp in the sheet and hydroentangling the chemical fiber of the synthetic fiber nonwoven sheet and the pulp fiber of the dry pulp sheet is performed. Here, in the manufacturing method of the pulp mixing nonwoven fabric wipe of this embodiment, it is set as the nozzle with the nozzle diameter of 0.5-1.5 mmphi especially the nozzle which injects a water flow. More preferably, it is 0.75 to 1.25 mmφ. The water pressure is not necessarily limited, but is preferably about 100 to 110 bar. This is a higher value than the typical pressure (80-90 bar). Appropriate adjustments are made according to the type of chemical fiber. This nozzle diameter is smaller than the manufacturing method of the conventional pulp mixed nonwoven fabric wipe. In this embodiment, chemical fibers and pulp fibers are produced by spraying a water stream from a small-diameter nozzle onto a dry pulp sheet having a small fiber orientation and laminated on a synthetic nonwoven fabric sheet having a basis weight of 10 to 17 g / m 2. Entanglement with the fiber becomes particularly good, and the pulp fiber enters the synthetic nonwoven fabric sheet side in particular, making it difficult for the pulp fiber to be detached from the front and back. In particular, when the preferred chemical fiber configuration and pulp fiber configuration are adopted, the movement of the fiber by the water flow is good, and the wipe according to the present embodiment can be produced effectively. That is, it is desirable that the dry pulp sheet contains 95% by mass or more of NBKP, and the thickness of the chemical fiber constituting the synthetic nonwoven fabric sheet is 18 to 22 μm.

かくして水流交絡された積層シートは、適宜に乾燥工程を経てパルプ混合不織布シートとされた後、裁断等されパルプ混合不織布ワイプとされる。これらの乾燥工程及び裁断工程は公知の技術により行うことができる。   The laminated sheet thus hydroentangled is appropriately formed into a pulp-mixed nonwoven fabric sheet through a drying process, and then cut into a pulp-mixed nonwoven fabric wipe. These drying steps and cutting steps can be performed by known techniques.

次いで、本実施形態に係る製造方法によって製造されたパルプ混合不織布ワイプ(実施例1及び2)と、従来のパルプ混合不織布ワイプ(比較例1〜3)とについて試験を行った。   Subsequently, the pulp mixed nonwoven fabric wipes (Examples 1 and 2) manufactured by the manufacturing method according to the present embodiment and the conventional pulp mixed nonwoven fabric wipes (Comparative Examples 1 to 3) were tested.

試験の結果は、実施例及び比較例に係る物性値及び測定値とともに下記表1に示す。なお、行った試験は次のとおりである。繊維長は、カヤニ/ファイバーラボにて測定し、繊維太さは、電子顕微鏡にて観察し測定した。また、図1に、実施例1及び比較例1及び比較例2の断面写真を示す。   The test results are shown in Table 1 below together with the physical property values and measured values according to the examples and comparative examples. The tests performed are as follows. The fiber length was measured at Kayani / Fiber Lab, and the fiber thickness was observed and measured with an electron microscope. Moreover, the cross-sectional photograph of Example 1, the comparative example 1, and the comparative example 2 is shown in FIG.

(乾燥引張強度)
JIS P 8113(1998)の引張試験に従って測定した。試験片は縦・横方向ともに巾25mm(±0.5mm)×長さ150mm程度に裁断したものを用いた。試験機は、ミネベア株式会社製ロードセル引張り試験機TG−200Nを用いた。つかみ間隔が100mmに設定した。測定は、試験片の両端を試験機のつかみに締め付け、紙片を上下方向に引張り荷重をかけ、紙が破断する時の指示値(デジタル値)を読み取る手順で行った。引張速度は100mm/minとした。縦方向、横方向ともに各々5組の試料を用意して各5回ずつ測定し、その測定値の平均を各方向の乾燥引張強度とした。(試料の調整は、JIS P 8111(1998))なお、縦横比は、測定値から算出する。
(Dry tensile strength)
It was measured according to the tensile test of JIS P 8113 (1998). The test piece used was cut into a width of 25 mm (± 0.5 mm) and a length of about 150 mm in both the vertical and horizontal directions. As a tester, a load cell tensile tester TG-200N manufactured by Minebea Co., Ltd. was used. The holding interval was set to 100 mm. The measurement was performed by tightening both ends of the test piece to the grip of the testing machine, applying a tensile load in the vertical direction, and reading the indicated value (digital value) when the paper breaks. The tensile speed was 100 mm / min. Five sets of samples were prepared in each of the longitudinal direction and the transverse direction and measured 5 times each, and the average of the measured values was taken as the dry tensile strength in each direction. (Adjustment of the sample is JIS P 8111 (1998)) The aspect ratio is calculated from the measured value.

(耐摩耗試験1)
JIS L 1096 E法(2010)に規定されるマーチンデール法により測定した。摩耗試験機は、グロッツ・ベッケルト製マーチンデール試験機を用いた。摩擦を加える素材は標準摩擦布、荷重は9Kpa、WET条件、動きはリサージュとして行った。WET条件は、試料面を霧吹きで吹くことによる。
(Abrasion resistance test 1)
It was measured by the Martindale method defined in JIS L 1096 E method (2010). As the abrasion tester, a Martindale tester manufactured by Grotz-Beckert was used. The material to which friction was applied was a standard friction cloth, the load was 9 Kpa, WET conditions, and the motion was Lissajous. The WET condition is based on spraying the sample surface with a spray.

(耐摩耗試験2)
上記耐摩擦試験1と同様の手順で、摩擦を加える素材を標準摩擦布から、ニトリルゴム素材に変更して測定した、ニトリルゴム素材は、ニトリル手袋(エステー株式会社製 ニトリルモデル モデルグローブNo.600)の手のひらの部分を測定器附属の打ち抜き冶具によって38mφに打ち抜いたものとした。なお、ニトリル手袋の選択は、パルプ混合不織布ワイプが、当該手袋使用者の手拭きに使用されることがある実態による。
(Abrasion resistance test 2)
The nitrile rubber material measured by changing the material to which friction is applied from the standard friction cloth to the nitrile rubber material in the same procedure as in the friction test 1, is a nitrile glove (nitrile model model glove No. 600 manufactured by Este Corporation). ) Was punched out to 38 mφ with a punching jig attached to the measuring instrument. In addition, the selection of a nitrile glove is based on the actual condition that a pulp mixing nonwoven fabric wipe may be used for the glove user's hand-wiping.

〔吸水量〕
吸水量の測定は下記(1)〜(5)のとおりに行った。
(1)試験片の質量を電子天秤(A&D HR300等)により測定する。
(2)試験片よりも大きいトレイ(例えば、内寸:215mm×160mm)に、20mm程度の深さとなるように、25℃の水を入れる。
(3)試験片を、試験片以上の大きさの剛性のある平網(例えば、120mm×120mm、網目15mm)の上に拡げて載せ、前記水を入れたトレイ内におろして、水面に接触するように試験片を浸水させる。
(4)試験片の表面にまで十分に水が浸みこんだら、平網を水面より真上に上げ、ピンセットにより試験片の角を摘み、そのまま30秒静止する。
(5)30秒後に吸水した試験片の質量を電子天秤により測定し、下記式により1m2当たりの吸水量を算出する。
吸水量(g/m2)=((上記(4)で測定した吸水した試験片の質量)−(上記(1)で測定した試験片の質量))×100(注:m2に換算するため、100倍する)
[Water absorption]
The water absorption was measured as described in (1) to (5) below.
(1) The mass of the test piece is measured with an electronic balance (A & D HR300 or the like).
(2) Water at 25 ° C. is placed in a tray (for example, inner dimension: 215 mm × 160 mm) larger than the test piece so as to have a depth of about 20 mm.
(3) Spread the test piece on a rigid net (for example, 120 mm x 120 mm, mesh 15 mm) larger than the test piece, put it in the tray containing the water, and contact the water surface Immerse the test piece in the same manner.
(4) When water has sufficiently soaked into the surface of the test piece, raise the flat net directly above the surface of the water, pick the corner of the test piece with tweezers, and stand still for 30 seconds.
(5) The mass of the test piece absorbed after 30 seconds is measured with an electronic balance, and the amount of water absorption per 1 m 2 is calculated by the following formula.
Water absorption (g / m 2 ) = ((mass of the water-absorbed test piece measured in the above (4)) − (mass of the test piece measured in the above (1))) × 100 (note: converted to m 2 Therefore, multiply by 100)

〔吸油量〕
吸油量の測定は下記(1)〜(5)のとおりとした。
(1)試験片の質量を電子天秤(A&D HR300等)により測定する。
(2)試験片よりも大きいトレイ(例えば、内寸:215mm×160mm)に、20mm程度の深さとなるように、25℃のサラダ油(日清サラダ油:日清オイリオグループ株式会社製)を入れる。
(3)試験片を、試験片以上の大きさの剛性のある平網(例えば、120mm×120mm、網目30mm)の上に拡げて載せ、前記サラダ油を入れたトレイ内におろして、油面に接触するように試験片を浸油させる。
(4)試験片の表面にまで十分にサラダ油が浸みこんだら、平網を油面より真上に上げ、そのまま30秒静止した後、ピンセットにより試験片の角を摘み、予め秤量された測定容器に試験片を移す。このとき、平網を油面より上げて静止を開始してから測定容器に移すまで30秒を超えないようにする。
(5)試験片が入った測定容器の質量を電子天秤により測定し、その測定値より測定容器の質量を差し引いて、吸油後の試験片の質量を算出する。そして、下記式により1m2当たりの吸油量を算出する。
吸油量(g/m2)=((上記(4)で測定した吸油した試験片の質量)−(上記(1)で測定した試験片の質量))×100(注:m2に換算するため、100倍する)
[Oil absorption]
The oil absorption was measured as shown in (1) to (5) below.
(1) The mass of the test piece is measured with an electronic balance (A & D HR300 or the like).
(2) 25 ° C. salad oil (Nisshin Salad Oil: manufactured by Nisshin Oillio Group Co., Ltd.) is put in a tray (for example, inner dimension: 215 mm × 160 mm) larger than the test piece so as to have a depth of about 20 mm.
(3) Spread the test piece on a rigid flat net (for example, 120 mm x 120 mm, mesh 30 mm) larger than the test piece, put it in a tray containing the salad oil, and place it on the oil surface. The specimen is soaked in contact.
(4) When the salad oil is sufficiently infiltrated to the surface of the test piece, raise the flat net directly above the oil level, leave it as it is for 30 seconds, pick the corner of the test piece with tweezers, and measure it in advance. Transfer the specimen to. At this time, it does not exceed 30 seconds from when the flat net is raised above the oil level to start resting until it is transferred to the measuring container.
(5) The mass of the measurement container containing the test piece is measured with an electronic balance, and the mass of the measurement container is subtracted from the measured value to calculate the mass of the test piece after oil absorption. Then, the amount of oil absorption per 1 m 2 is calculated by the following formula.
Oil absorption (g / m 2 ) = ((mass of test piece absorbed in (4) above) − (mass of test specimen measured in (1) above)) × 100 (Note: converted to m 2 Therefore, multiply by 100)

〔吸水速度〕
吸水速度の測定は下記(1)〜(4)のとおりとした。
(1)100mm×100mmの試験片を準備する。
(2)試験片を中心部に直径40mm以上の穴を有する台(例えば、アルコールランプ用三脚)の上に、その試験片の中央部が前記穴の上に位置するようにして載置する。
(3)試験片の中心付近の任意の箇所に、試験片面より10mmの高さから、25℃の水300μlをマイクロピペットにより滴下する。この滴下は、例えば、アズワン ピペットガイPG−1000を用い目盛り300として行うことができる。
(4)マイクロピペットからの水が試験片に接触した瞬間から、試験片の水が浸透しきるまでの時間をストップウォッチにより測定し、その時間を吸水速度(sec)とする。なお、浸透終了は、試験片表面から水の光沢反射が消えることを目視にて確認することによる。
[Water absorption speed]
The water absorption rate was measured as follows (1) to (4).
(1) A test piece of 100 mm × 100 mm is prepared.
(2) The test piece is placed on a base (for example, a tripod for an alcohol lamp) having a hole having a diameter of 40 mm or more in the center so that the central portion of the test piece is positioned on the hole.
(3) To a desired location near the center of the test piece, 300 μl of water at 25 ° C. is dropped with a micropipette from a height of 10 mm from the surface of the test piece. This dripping can be performed as the scale 300 using, for example, the ASONE pipette guy PG-1000.
(4) The time from the moment when the water from the micropipette comes into contact with the test piece to the time when the water of the test piece completely permeates is measured with a stopwatch, and the time is taken as the water absorption rate (sec). In addition, the completion | finish of infiltration is by confirming visually that the glossy reflection of water disappears from the test piece surface.

(ソフトネス)
JIS L 1096 E法に準じたハンドルオメータ法に従って測定した。但し、試験片は100mm×100mmの大きさとし、クリアランスは5mmとして実施した。1プライで縦方向、横方向の各々5回ずつ測定し、縦方向、横方向それぞれ5回の平均値を、cN/100mmを単位として表した。ソフトネスは、柔らかさの指標の一つである。
(Softness)
It measured according to the handle ohm method according to JISL1096E method. However, the test piece was 100 mm × 100 mm in size, and the clearance was 5 mm. The measurement was performed 5 times each in the longitudinal direction and the lateral direction with 1 ply, and the average value of 5 times in each of the longitudinal direction and the lateral direction was expressed in units of cN / 100 mm. Softness is one of the indices of softness.

(表面粗さSMD)
カトーテック株式会社製の自動化表面試験機KES−FB−4−AUTOを用いて測定した。摩擦子の接触面を、所定方向に20g/cmの張力が付与された測定試料の表面に対して25gの接触圧で接触させながら、張力が付与された方向と略同じ方向に速度0.1cm/sで2cm移動させて行った。摩擦子は、標準付属の10mm角のピアノワイヤセンサー(1本)とした。摩擦子の初期荷重は、0.49Nで実施。SMDの測定は、各面について5回測定し、その平均値とする。
(Surface roughness SMD)
The measurement was performed using an automated surface tester KES-FB-4-AUTO manufactured by Kato Tech Co., Ltd. While the contact surface of the friction element is brought into contact with the surface of the measurement sample to which a tension of 20 g / cm is applied in a predetermined direction at a contact pressure of 25 g, the velocity is 0.1 cm in the same direction as the tension is applied. It was moved 2 cm at / s. The friction piece was a standard 10 mm square piano wire sensor (1 piece). The initial load of the friction element is 0.49N. SMD is measured five times for each surface, and the average value is taken.

(MMD)(摩擦抵抗MIU)
カトーテック株式会社製のカトーテック株式会社製の自動化表面試験機KES−FB−4−AUTOを用いて測定した。摩擦子の接触面を、所定方向に20g/cmの張力が付与された測定試料の表面に対して25gの接触圧で接触させながら、張力が付与された方向と略同じ方向に速度0.1cm/sで2cm移動させて行った。摩擦子は、標準付属の10mm角のピアノワイヤセンサー(20本)とした。MMDとMIUの測定は、各面について5回測定し、その平均値とする。
(MMD) (Friction resistance MIU)
The measurement was performed using an automated surface tester KES-FB-4-AUTO manufactured by Kato Tech Co., Ltd. While the contact surface of the friction element is brought into contact with the surface of the measurement sample to which a tension of 20 g / cm is applied in a predetermined direction at a contact pressure of 25 g, the velocity is 0.1 cm in the same direction as the tension is applied. It was moved 2 cm at / s. The friction piece was a standard 10 mm square piano wire sensor (20 pieces). MMD and MIU are measured five times for each surface, and the average value is taken.

各試験の結果を見てみると、まず(耐摩耗性試験1)及び(耐摩耗性試験2)の結果からして本発明の実施例は、耐摩耗性に優れるといえる。さらに、表裏差も非常に小さく耐摩耗性が表裏について達成されえいる。これは、水流交絡時にパルプ繊維が化繊不織布シートにおけるパルプシート接触面と反対面に至るまで十分に移動して、繊維同士の交絡が進みしっかりと絡合しているからである。これは、図1に示す断面写真にも現れている。図1の(A)で示す実施例1では、パルプ繊維が厚み方向に均一に存在しているのに対して、図1の(B)で示す比較例1や図1の(C)で示す比較例2では、パルプ繊維が偏在している。   Looking at the results of each test, it can be said from the results of (Abrasion Resistance Test 1) and (Abrasion Resistance Test 2) that the examples of the present invention are excellent in abrasion resistance. Furthermore, the difference between the front and back sides is very small, and wear resistance can be achieved on the front and back sides. This is because the pulp fibers are sufficiently moved to reach the surface opposite to the pulp sheet contact surface in the synthetic nonwoven fabric sheet at the time of hydroentanglement, and the entanglement between the fibers proceeds and is firmly intertwined. This also appears in the cross-sectional photograph shown in FIG. In Example 1 shown in FIG. 1 (A), pulp fibers are uniformly present in the thickness direction, whereas in Comparative Example 1 shown in FIG. 1 (B) and FIG. 1 (C). In Comparative Example 2, pulp fibers are unevenly distributed.

また、吸水量についても実施例1及び実施例2は、比較例1及び比較例2よりは良好である。比較例3よりは良好であるがその差は少ない。但し、比較例3は、耐摩耗性の表裏差が非常に大きい。すなわち、パルプ繊維が一方面に多く偏在していると考えられる。ゆえに、パルプ繊維偏在部分における水分保持性が高くなり吸水量が高い結果となったと考えられる。   Moreover, also about the amount of water absorption, Example 1 and Example 2 are better than Comparative Example 1 and Comparative Example 2. Although better than Comparative Example 3, the difference is small. However, Comparative Example 3 has a very large difference in wear resistance. That is, it is thought that many pulp fibers are unevenly distributed on one side. Therefore, it is considered that the moisture retention at the portion where the pulp fibers are unevenly distributed becomes high, resulting in a high water absorption.

さらに、吸水速度についてみてみると実施例1及び実施例2は、比較例1〜比較例3と比べて有意に早い。また、表裏の差も小さい。これは、縦横比が小さいため縦方向横方向における水分の分散性に差がないうえ、さらに、パルプ繊維が厚み方向に分散して化学繊維との絡合がしっかりとした状態になっているからと考えらえる。   Furthermore, in terms of the water absorption rate, Example 1 and Example 2 are significantly faster than Comparative Examples 1 to 3. Also, the difference between the front and back is small. This is because the aspect ratio is small, so there is no difference in the water dispersibility in the vertical and horizontal directions, and further, the pulp fibers are dispersed in the thickness direction and the entanglement with the chemical fibers is in a solid state. Can be considered.

次に、吸油量を見てみると実施例1及び実施例2は、比較例1〜3と比べて優位に多い。これは、化学繊維の網目中にパルプ繊維が分散して存在していることにより油の保持性が高まったものである。   Next, looking at the amount of oil absorption, Example 1 and Example 2 are more dominant than Comparative Examples 1-3. This is because the retention of oil is enhanced by the presence of dispersed pulp fibers in the network of chemical fibers.

他方、表1中の摩擦係数(MIU)、MMDを見てみると実施例及び比較例ともに良好で表裏差も大きくない。これはMIUやMMDが人の感じ方の指標であり、その視点からは大きな差異がない。しかし、実際の表面粗さ(SMD)を見てみると実施例1及び実施例2は、比較例1及び比較例3より非常に差がなく、比較例2よりも優れる。つまり、本実施例は、人の感じ方においては滑らかで表裏差がなく、しかも実際の表面性においても差がない。つまり、パルプ繊維の厚み方向への移動分散性に良好となっており化学繊維との絡合しっかりと進んでいる。   On the other hand, looking at the friction coefficient (MIU) and MMD in Table 1, both the examples and the comparative examples are good and the difference between the front and back is not large. MIU and MMD are indicators of how people feel, and there is no significant difference from that perspective. However, looking at the actual surface roughness (SMD), Example 1 and Example 2 are not significantly different from Comparative Example 1 and Comparative Example 3, and are superior to Comparative Example 2. In other words, the present embodiment is smooth and has no difference between the front and the back in terms of how the person feels, and also has no difference in the actual surface properties. In other words, the pulp fiber has good dispersibility in the thickness direction, and the entanglement with the chemical fiber is proceeding firmly.

以上のとおり、本実施形態に係るパルプ混合不織布ワイプは、パルプ繊維と化学繊維との絡合がしっかりとしており、耐摩耗性に優れ、さらに吸液性にも優れ、それらの表裏の差も小さいものといえる。   As described above, the pulp-mixed nonwoven fabric wipe according to the present embodiment has a solid entanglement between pulp fibers and chemical fibers, is excellent in abrasion resistance, is excellent in liquid absorption, and has a small difference in front and back. It can be said that.

1,101…パルプ混合不織布シート、2,102…化学繊維、3,103…パルプ繊維。   DESCRIPTION OF SYMBOLS 1,101 ... Pulp mixing nonwoven fabric sheet, 2,102 ... Chemical fiber, 3,103 ... Pulp fiber.

Claims (4)

パルプと化学繊維とが絡合されたパルプ混合不織布であり、
坪量が45〜80g/m2であり、
化学繊維の目付量が10〜17g/m2であり、
パルプの配合割合が75質量%以上あり、
乾燥引張強度の縦横比が3.0以下であり、
JIS L 1096 E法に規定されるマーチンデール法における測定値の表裏差が100以下である、
ことを特徴とするパルプ混合不織布ワイプ。
A pulp mixed nonwoven fabric in which pulp and chemical fiber are entangled,
The basis weight is 45-80 g / m 2 ,
The basis weight of the chemical fiber is 10 to 17 g / m 2 ;
The blending ratio of the pulp is 75% by mass or more,
The aspect ratio of dry tensile strength is 3.0 or less,
The difference between the measured values in the Martindale method specified in JIS L 1096 E method is 100 or less,
A pulp-mixed non-woven wipe characterized by that.
パルプはNBKPを95質量%以上含み、化学繊維の太さは18〜22μmである請求項1記載のパルプ混合不織布ワイプ。   The pulp-mixed nonwoven fabric wipe according to claim 1, wherein the pulp contains 95% by mass or more of NBKP, and the thickness of the chemical fiber is 18 to 22 µm. 目付量10〜17g/m2の化繊不織布シート上に、溶解パルプをシート状にした乾燥パルプシートを積層する工程と、
ノズル径0.5〜0.15mmφのノズルから乾燥パルプシート面に水流を噴射する水流絡合工程と、
を有することを特徴とするパルプ混合不織布ワイプの製造方法。
A step of laminating a dry pulp sheet made of dissolved pulp into a sheet on a synthetic nonwoven fabric sheet having a basis weight of 10 to 17 g / m 2 ;
A water entangling step of injecting a water flow from a nozzle having a nozzle diameter of 0.5 to 0.15 mmφ onto the surface of the dried pulp sheet;
A method for producing a pulp-mixed nonwoven fabric wipe, comprising:
パルプシートはNBKPを95質量%以上含み、化繊不織布シートを構成する化学繊維の太さが18〜22μmである請求項3記載のパルプ混合不織布ワイプの製造方法。   The method for producing a pulp-mixed nonwoven fabric wipe according to claim 3, wherein the pulp sheet contains 95% by mass or more of NBKP, and the thickness of the chemical fiber constituting the synthetic fiber nonwoven fabric sheet is 18 to 22 µm.
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