JP2018098074A - Battery pack - Google Patents

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JP2018098074A
JP2018098074A JP2016242614A JP2016242614A JP2018098074A JP 2018098074 A JP2018098074 A JP 2018098074A JP 2016242614 A JP2016242614 A JP 2016242614A JP 2016242614 A JP2016242614 A JP 2016242614A JP 2018098074 A JP2018098074 A JP 2018098074A
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heat insulating
cooling air
insulating material
air passage
case
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内田 仁
Hitoshi Uchida
仁 内田
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Mitsubishi Motors Corp
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Mitsubishi Motors Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

PROBLEM TO BE SOLVED: To prevent the expansion of thermal runaway among a plurality of single cells with a simple structure while securing cooling performance during the normal time.SOLUTION: Disclosed is a battery pack 1 which is constituted by arranging a plurality of single cells 3 in a case 2 and has a cooling air passage 4 extending in the vertical direction between single cells 3 adjacent to each other. Adiathermancy is provided upward of at least the cooling air passage 4 in the case 2 and a foam heat insulating material 10 is also provided, which is made of thermally expandable graphite thermally expanded at a predetermined temperature or higher to be flowed into the cooling air passage 4. Some of single batteries 3 has thermal runway, the foam heat insulating material 10 is thermally expanded by the heat and flowed into the cooling air passage 4, and the expansion of thermal runaway among a plurality of single cells 3 is prevented.SELECTED DRAWING: Figure 1

Description

本発明は、複数の単電池を組み合わせた組電池において、単電池間での熱暴走の拡大を防止する技術に関する。   The present invention relates to a technique for preventing expansion of thermal runaway between single cells in an assembled battery in which a plurality of single cells are combined.

車両に搭載した走行駆動用電池のように高出力高容量の電池は、単電池を複数個組み合わせて構成された組電池を採用しているものが多い。
例えば、特許文献1には、ハイブリッド車等の車両に搭載する組電池が記載されている。当該組電池は、リチウムイオン電池等からなる単電池を複数個組み合わせて構成されており、複数の単電池はケース内に収納されている。
Many batteries with high output and high capacity, such as a battery for driving driving mounted on a vehicle, employ an assembled battery formed by combining a plurality of single cells.
For example, Patent Document 1 describes an assembled battery mounted on a vehicle such as a hybrid vehicle. The assembled battery is configured by combining a plurality of unit cells made of lithium ion batteries or the like, and the plurality of unit cells are housed in a case.

また、特許文献1に記載された組電池は、充放電時における温度上昇を抑制するために、送風ファンによって外部からケース内に冷却風を導入する構造となっている。更に、短絡等によりケース内の単電池に熱暴走が発生した場合、外部への影響を抑えるためにケースの吸排気口を自動的に塞ぎ、ケース内部への空気の流入を遮断する構成となっている。   Moreover, the assembled battery described in Patent Document 1 has a structure in which cooling air is introduced into the case from the outside by a blower fan in order to suppress a temperature rise during charging and discharging. In addition, when a thermal runaway occurs in a single cell in the case due to a short circuit, etc., the case's intake / exhaust port is automatically closed in order to suppress external influences, and the inflow of air into the case is blocked. ing.

特開2013−246920号公報JP2013-246920A

しかし、ケース内の単電池の一部が熱暴走した場合、上記特許文献1に記載された組電池では、ケース内の他の単電池へ伝熱して他の単電池も熱暴走する虞がある。
なお、熱暴走の拡大を防止するために単電池の間に難燃性のシート等を挿入しておく方法が考えられるが、上記特許文献1のように単電池間に冷却風通路を備えた組電池においては、冷却風通路における冷却風の通過を妨げる要因となり、通常使用時での冷却性能が低下するといった問題点がある。
However, when some of the single cells in the case are thermally runaway, the assembled battery described in Patent Document 1 may transfer heat to the other single cells in the case, and the other single cells may also be thermally runaway. .
In order to prevent the thermal runaway from expanding, a method of inserting a flame retardant sheet or the like between the cells can be considered. However, as in Patent Document 1, a cooling air passage is provided between the cells. In the assembled battery, there is a problem that it becomes a factor that obstructs the passage of the cooling air in the cooling air passage, and the cooling performance is lowered during normal use.

本発明はこのような問題点を解決するためになされたもので、その目的とするところは、通常使用時での冷却性能を確保しつつ、単電池間での熱暴走の拡大を簡単な構造で防止することを可能とする組電池を提供することにある。   The present invention has been made to solve such problems, and the object of the present invention is to simplify the structure of thermal runaway between single cells while ensuring cooling performance during normal use. It is an object of the present invention to provide an assembled battery that can be prevented.

上記の目的を達成するため、本発明の組電池は、ケース内に複数の単電池を配置して構成され、隣り合う前記単電池の間には上下方向に延びる冷却風通路を有する組電池であって、前記ケース内の少なくとも前記冷却風通路の上方に、断熱性を有しかつ所定温度以上で熱膨張して前記冷却風通路に流入する熱膨張断熱材を備えたことを特徴とする。
また、好ましくは、前記熱膨張断熱材は、前記所定温度以上で全ての前記冷却風通路において前記単電池の下方まで熱膨張するとよい。
In order to achieve the above object, an assembled battery of the present invention is an assembled battery having a plurality of unit cells arranged in a case and having a cooling air passage extending in the vertical direction between the adjacent unit cells. A thermal expansion heat insulating material that has a heat insulating property and thermally expands at a predetermined temperature or more and flows into the cooling air passage is provided at least above the cooling air passage in the case.
Preferably, the thermal expansion heat insulating material is thermally expanded to the lower side of the unit cell in all the cooling air passages at the predetermined temperature or higher.

また、前記熱膨張断熱材は、熱膨張性黒鉛により形成されるとよい。
また、好ましくは、前記単電池は、リチウムイオン電池であるとよい。
また、好ましくは、前記熱膨張断熱材の設置位置の下方かつ前記単電池の上方に、熱膨張した前記熱膨張断熱材を前記冷却風通路に導く熱膨張断熱材導入部材を備えるとよい。
The thermal expansion heat insulating material may be formed of thermally expandable graphite.
Preferably, the unit cell is a lithium ion battery.
Preferably, a thermal expansion heat insulating material introduction member that guides the thermally expanded heat insulating material to the cooling air passage is provided below the installation position of the thermal expansion heat insulating material and above the unit cell.

本発明の組電池は、ケース内の少なくとも冷却風通路の上方に、所定温度以上で熱膨張して冷却風通路に流入する熱膨張断熱材を備えたので、例えば単電池の一部が熱暴走してケース内の温度が上昇した際に、隣り合う単電池の間に断熱性を有する熱膨張断熱材の壁が形成される。これにより、ケース内の熱暴走している単電池から他の単電池への熱伝導が抑えられ、他の単電池の熱暴走を防止することができる。   The assembled battery of the present invention includes a thermal expansion heat insulating material that thermally expands at a predetermined temperature or higher and flows into the cooling air passage at least above the cooling air passage in the case. And when the temperature in a case rises, the wall of the thermal expansion heat insulating material which has heat insulation is formed between adjacent unit cells. Thereby, the heat conduction from the unit cell which is in the case of thermal runaway to the other unit cell is suppressed, and the thermal runaway of the other unit cell can be prevented.

また、単電池が熱暴走しておらずケース内の温度が所定温度未満であって熱膨張断熱材が膨張していない状態では、冷却風通路に熱膨張断熱材が到達していないので、冷却風通路における冷却風の通過を妨げることなく、冷却風通路を通過する冷却風による単電池の冷却性能を確保することができる。
これにより、熱暴走していない通常使用時での冷却性能を確保しつつ、ケース内の単電池の少なくとも一部が熱暴走した際にケース内の他の単電池への熱暴走の拡大を防止することが簡単な構造で可能となる。
In addition, in the state where the unit cell is not thermally runaway and the temperature in the case is lower than the predetermined temperature and the thermal expansion insulation is not expanded, the thermal expansion insulation does not reach the cooling air passage. The cooling performance of the unit cell by the cooling air passing through the cooling air passage can be secured without hindering the passage of the cooling air in the air passage.
This ensures the cooling performance during normal use without thermal runaway, and prevents the thermal runaway from spreading to other cells in the case when at least some of the cells in the case run out of heat. This is possible with a simple structure.

本発明の第1の実施形態の組電池の概略構成を示す縦断面図である。It is a longitudinal cross-sectional view which shows schematic structure of the assembled battery of the 1st Embodiment of this invention. 熱暴走が発生した際における組電池の内部の状態を示す縦断面図である。It is a longitudinal cross-sectional view which shows the state inside an assembled battery when thermal runaway occurs. 本発明の第2の実施形態の組電池の概略構成を示す縦断面図である。It is a longitudinal cross-sectional view which shows schematic structure of the assembled battery of the 2nd Embodiment of this invention.

以下、本発明を具体化した組電池の一実施形態を説明する。
図1は本発明の第1の実施形態の組電池1の概略構成を示す縦断面図である。図2は、熱暴走が発生した際における組電池1の内部の状態を示す縦断面図である。
本実施形態の組電池1は、電気自動車やハイブリッド車の走行駆動用モータに電力を供給する電池のように高電圧高容量の電池であり、リチウムイオン電池からなる単電池を複数組み合わせて構成されている。
Hereinafter, an embodiment of a battery pack embodying the present invention will be described.
FIG. 1 is a longitudinal sectional view showing a schematic configuration of an assembled battery 1 according to a first embodiment of the present invention. FIG. 2 is a longitudinal sectional view showing an internal state of the assembled battery 1 when a thermal runaway occurs.
The assembled battery 1 of the present embodiment is a high-voltage, high-capacity battery such as a battery that supplies electric power to a driving motor for an electric vehicle or a hybrid vehicle, and is configured by combining a plurality of single cells made of lithium ion batteries. ing.

図1に示すように、組電池1は、矩形箱状のケース2内に複数の単電池3が収納されて構成されている。図1では、簡素化してケース2内に3個の単電池3が記載されているが、単電池3が前後左右に多数並べられていてもよい。
隣り合う単電池3の間や、ケース2の側壁2aと単電池3との間には、上下方向に延びる冷却風通路4が夫々形成されている。また、単電池3の下部及び上部には、夫々冷却風が通過可能な空間(上部空間5、下部空間6)が、ケース2内を前後左右方向に亘って広がっている。上部空間5と下部空間6とは各冷却風通路4によって連通している。
As shown in FIG. 1, the assembled battery 1 is configured by housing a plurality of single cells 3 in a rectangular box-shaped case 2. In FIG. 1, three unit cells 3 are illustrated in a simplified manner in the case 2, but a large number of unit cells 3 may be arranged in the front, rear, left, and right.
Cooling air passages 4 extending in the vertical direction are formed between the adjacent unit cells 3 and between the side wall 2a of the case 2 and the unit cell 3, respectively. In addition, in the lower part and the upper part of the unit cell 3, spaces (upper space 5 and lower space 6) through which the cooling air can pass are spread in the case 2 in the front-rear and left-right directions. The upper space 5 and the lower space 6 communicate with each other through the cooling air passages 4.

ケース2の側壁2aには、ケース2の外部から内部へ冷却風を導入する吸気口7と、ケース2の内部から外部へ冷却風を排出する排気口8が設けられている。吸気口7は下部空間6に面して配置され、排気口8は吸気口7とは左右あるいは前後反対側の側壁2aに上部空間5に面して配置されている。
なお、吸気口7には、車両の走行風や、図示しないブロアファンによって、冷却風が導入される。
The side wall 2a of the case 2 is provided with an intake port 7 for introducing cooling air from the outside to the inside of the case 2 and an exhaust port 8 for discharging cooling air from the inside of the case 2 to the outside. The intake port 7 is arranged facing the lower space 6, and the exhaust port 8 is arranged facing the upper space 5 on the side wall 2 a on the left and right or opposite to the front and rear sides of the intake port 7.
In addition, cooling air is introduced into the intake port 7 by vehicle driving air or a blower fan (not shown).

図1中の矢印に示すように、吸気口7から導入された冷却風は、下部空間6から分流して各冷却風通路4を通過し、上部空間5で合流して排気口8から排出される。
更に、本実施形態の組電池1では、ケース2の上壁2bの内側に熱膨張性黒鉛により形成された発泡断熱材10(熱膨張断熱材)が設けられている。発泡断熱材10は、例えば上壁2bの内側に塗布したり、あらかじめ薄板状に熱膨張性黒鉛を固めて形成した発泡断熱材を上壁2bの内側に設置したりすればよい。
As shown by the arrows in FIG. 1, the cooling air introduced from the intake port 7 is diverted from the lower space 6, passes through each cooling air passage 4, joins in the upper space 5, and is discharged from the exhaust port 8. The
Furthermore, in the assembled battery 1 of the present embodiment, a foam heat insulating material 10 (thermal expansion heat insulating material) formed of thermally expandable graphite is provided inside the upper wall 2b of the case 2. The foam heat insulating material 10 may be applied, for example, on the inner side of the upper wall 2b, or a foam heat insulating material formed by preliminarily solidifying thermally expandable graphite in a thin plate shape may be installed on the inner side of the upper wall 2b.

熱膨張性黒鉛は、黒鉛に熱膨張性を与えた公知の物質であり、例えば摂氏200〜300度(所定温度)以上で膨張するとともに、高い難燃性、断熱性を有する。また、この熱膨張性黒鉛からなる発泡断熱材10は、熱膨張時には高い流動性を有する。
発泡断熱材10は、ケース2の上壁2bの内側を全面に亘って配置されており、特に全ての冷却風通路4の上方には位置するように配置されている。
Thermally expansive graphite is a known substance that imparts thermal expansibility to graphite. For example, it expands at 200 to 300 degrees Celsius (predetermined temperature) or higher, and has high flame retardancy and heat insulation. In addition, the foam heat insulating material 10 made of this thermally expandable graphite has high fluidity at the time of thermal expansion.
The foam heat insulating material 10 is disposed over the entire inner surface of the upper wall 2 b of the case 2, and in particular, is disposed so as to be positioned above all the cooling air passages 4.

以上のような構成の組電池1において、少なくとも1つの単電池3が短絡事故等により熱暴走した場合、図2に示すように、その熱によって発泡断熱材10が膨張する。発泡断熱材10は、全ての冷却風通路4の上方に配置されるとともに、熱膨張時には高い流動性を有しているので、加熱された発泡断熱材10は下方に向けて、全ての冷却風通路4に流れ込むように膨張する。なお、発泡断熱材10は、熱膨張時に全ての冷却風通路4でケース2の下壁2cに到達するような量に設定されている。   In the assembled battery 1 having the above-described configuration, when at least one unit cell 3 is thermally runaway due to a short circuit accident or the like, as shown in FIG. 2, the foam heat insulating material 10 expands due to the heat. Since the foam heat insulating material 10 is disposed above all the cooling air passages 4 and has high fluidity at the time of thermal expansion, the heated foam heat insulating material 10 faces all the cooling air toward the lower side. It expands to flow into the passage 4. The foam heat insulating material 10 is set to an amount that reaches the lower wall 2c of the case 2 in all the cooling air passages 4 during thermal expansion.

したがって、熱膨張時には、全ての冷却風通路4において上部空間5から下部空間6に延びる熱膨張性黒鉛によって形成された発泡断熱材10の壁11が形成される。
これにより、ケース2内の少なくとも一部の単電池3で熱暴走した際に、その熱によって発泡断熱材10が膨張して、単電池3とその隣の単電池3とは、難燃性及び断熱性の優れた発泡断熱材10の壁11によって遮られるので、熱暴走している単電池3から熱暴走していない他の単電池3への熱伝導が抑制され、熱暴走の拡大が抑えられる。このように、ケース2内の冷却風通路4の上方に熱膨張性黒鉛からなる発泡断熱材10を設置するといった簡単な構成で、単電池3間の熱暴走の拡大を抑制することが可能となる。
Therefore, at the time of thermal expansion, the wall 11 of the foam heat insulating material 10 formed of thermally expandable graphite extending from the upper space 5 to the lower space 6 is formed in all the cooling air passages 4.
Thereby, when the thermal runaway occurs in at least a part of the single cells 3 in the case 2, the foam heat insulating material 10 expands due to the heat, and the single cell 3 and the adjacent single cells 3 have flame retardancy and Since it is blocked by the wall 11 of the foam insulation 10 having excellent heat insulating properties, heat conduction from the unit cell 3 that is thermally runaway to the other unit cell 3 that is not thermally runaway is suppressed, and expansion of the thermal runaway is suppressed. It is done. In this way, it is possible to suppress the expansion of the thermal runaway between the single cells 3 with a simple configuration in which the foam heat insulating material 10 made of thermally expandable graphite is installed above the cooling air passage 4 in the case 2. Become.

また、ケースの側壁2aと単電池3との間の冷却風通路4にも、単電池3の熱暴走時に発泡断熱材10が流入するので、吸気口7及び排気口8を閉鎖することができる。これにより、ケース2外部への影響も防止することが可能となる。
一方、単電池3の熱暴走が発生していない通常時には、発泡断熱材10が膨張しないので、冷却風通路4には発泡断熱材10が存在しておらず、冷却風通路4を通過する冷却風による単電池3の冷却性能が確保される。このように、通常時には冷却風通路4に発泡断熱材10が存在しないので、冷却風通路4の幅を冷却効率が確保される程度の最小限に設定することができ、組電池1をコンパクトに構成することができる。
Further, since the foam heat insulating material 10 flows into the cooling air passage 4 between the side wall 2a of the case and the unit cell 3 when the unit cell 3 is thermally runaway, the intake port 7 and the exhaust port 8 can be closed. . Thereby, it becomes possible to prevent the case 2 from being affected.
On the other hand, at the normal time when no thermal runaway of the unit cell 3 occurs, the foam heat insulating material 10 does not expand. Therefore, the foam heat insulating material 10 does not exist in the cooling air passage 4, and cooling that passes through the cooling air passage 4 is performed. The cooling performance of the cell 3 by wind is ensured. As described above, since the foamed heat insulating material 10 does not exist in the cooling air passage 4 in the normal state, the width of the cooling air passage 4 can be set to the minimum that ensures the cooling efficiency, and the assembled battery 1 can be made compact. Can be configured.

図3は、第2の実施形態の組電池20の概略構成を示す縦断面図である。
図3に示すように、本実施形態の組電池20は、上記第1の実施形態の組電池1に対して、ケース2内に発泡断熱材導入ブラケット21(熱膨張断熱材導入部材)が設けられていることが異なる。発泡断熱材導入ブラケット21は、単電池3の上方の上部空間5内に設けられている。発泡断熱材導入ブラケット21は、例えば板材を屈曲して形成され、その幅が略1つの単電池3の幅となっている。そして、発泡断熱材導入ブラケット21の左右位置を単電池3の左右位置と一致するようにして、中間部21aが上方に突出するように配置される。発泡断熱材導入ブラケット21は、発泡断熱材10が膨張した際に、単電池3の上方から単電池3に向かって下方に膨張してくる発泡断熱材10を冷却風通路4に導入する機能を有する。
FIG. 3 is a longitudinal sectional view showing a schematic configuration of the assembled battery 20 of the second embodiment.
As shown in FIG. 3, the assembled battery 20 of the present embodiment is provided with a foam heat insulating material introduction bracket 21 (thermal expansion heat insulating material introducing member) in the case 2 with respect to the assembled battery 1 of the first embodiment. It is different. The foam heat insulating material introduction bracket 21 is provided in the upper space 5 above the unit cell 3. The foam heat insulating material introduction bracket 21 is formed, for example, by bending a plate material, and the width thereof is substantially the width of one unit cell 3. And it arrange | positions so that the intermediate part 21a may protrude upwards so that the left-right position of the foam heat insulating material introduction bracket 21 may correspond with the left-right position of the cell 3. The foam heat insulating material introduction bracket 21 has a function of introducing the foam heat insulating material 10 that expands downward from the upper side of the single cell 3 toward the single cell 3 into the cooling air passage 4 when the foamed heat insulating material 10 expands. Have.

これにより、熱膨張した発泡断熱材10が発泡断熱材導入ブラケット21の上面に沿って冷却風通路4内に導入され易くなる。したがって、単電池3の熱暴走発生時に、冷却風通路4に発泡断熱材10の壁11を迅速に形成することができ、熱暴走の拡大を速やかに抑制して被害を少なくすることができる。
以上で実施形態の説明を終えるが、本発明の態様は以上の実施形態に限定されるものではない。例えば発泡断熱材10については、熱膨張性黒鉛以外であっても、断熱性を有しかつ熱膨張するような材料で形成すればよい。本発明は、複数の単電池の間に冷却風通路を備えた組電池に対し、広く適用することができる。
Thereby, the thermally expanded foam heat insulating material 10 is easily introduced into the cooling air passage 4 along the upper surface of the foam heat insulating material introduction bracket 21. Therefore, when thermal runaway of the unit cell 3 occurs, the wall 11 of the foam heat insulating material 10 can be quickly formed in the cooling air passage 4, and the expansion of the thermal runaway can be quickly suppressed to reduce damage.
The description of the embodiment is finished as above, but the aspect of the present invention is not limited to the above embodiment. For example, the foam heat insulating material 10 may be formed of a material that has heat insulating properties and thermally expands even if it is other than thermally expandable graphite. The present invention can be widely applied to an assembled battery including a cooling air passage between a plurality of single cells.

1、20 組電池
2 ケース
3 単電池
4 冷却風通路
10 発泡断熱材(熱膨張断熱材)
21 発泡断熱材導入ブラケット(熱膨張断熱材導入部材)
1, 20 Battery pack 2 Case 3 Cell 4 Cooling air passage 10 Foam insulation (thermal expansion insulation)
21 Foam insulation introduction bracket (thermal expansion insulation introduction member)

Claims (5)

ケース内に複数の単電池を配置して構成され、隣り合う前記単電池の間には上下方向に延びる冷却風通路を有する組電池であって、
前記ケース内の少なくとも前記冷却風通路の上方に、断熱性を有しかつ所定温度以上で熱膨張して前記冷却風通路に流入する熱膨張断熱材を備えたことを特徴とする組電池。
A battery assembly comprising a plurality of single cells arranged in a case, and having a cooling air passage extending in the vertical direction between the adjacent single cells,
A battery assembly comprising: a thermal expansion heat insulating material that has a heat insulating property and thermally expands at a predetermined temperature or higher and flows into the cooling air passage at least above the cooling air passage in the case.
前記熱膨張断熱材は、前記所定温度以上で全ての前記冷却風通路において前記単電池の下方まで熱膨張することを特徴とする請求項1に記載の組電池。   2. The assembled battery according to claim 1, wherein the thermal expansion heat insulating material thermally expands below the unit cell in all the cooling air passages at the predetermined temperature or higher. 前記熱膨張断熱材は、熱膨張性黒鉛により形成されることを特徴とする請求項1または2に記載の組電池。   The assembled battery according to claim 1, wherein the thermally expandable heat insulating material is formed of thermally expandable graphite. 前記単電池は、リチウムイオン電池であることを特徴とする請求項1から3のいずれか1項に記載の組電池。   The assembled battery according to any one of claims 1 to 3, wherein the single battery is a lithium ion battery. 前記熱膨張断熱材の設置位置の下方かつ前記単電池の上方に、熱膨張した前記熱膨張断熱材を前記冷却風通路に導く熱膨張断熱材導入部材を備えたことを特徴とする請求項1から4のいずれか1項に記載の組電池。   The thermal expansion heat insulating material introduction member which guides the thermally expanded heat insulating material thermally expanded to the cooling air passage is provided below the installation position of the thermal expansion heat insulating material and above the unit cell. 5. The assembled battery according to any one of items 1 to 4.
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