JP2018080278A5

JP2018080278A5 -

Info

Publication number: JP2018080278A5
Application number: JP2016224097A
Authority: JP
Filing date: 2016-11-17
Publication date: 2019-12-26
Anticipated expiration: 2036-11-17

Claims

Method of manufacturing a row cormorants polymer polymerization reaction in the presence of a compound represented by the following formula (1).

(In the formula (1), R ¹ is an aliphatic hydrocarbon group having 1 to 18 carbon atoms or a structure represented by the following formula (2);

In the above formula (2), R ² and R ³ are each independently a hydroxyl group or an alkylcarbonyloxy group having 1 to 16 carbon atoms, provided that R ² and R ³ are not hydroxyl groups at the same time, The position of N to which R ¹ in formula (1) is bonded is shown. )

The R ^２2 And the R ^３3 Are each independently an alkylcarbonyloxy group having 1 to 16 carbon atoms, The method for producing a polymer according to claim 1, wherein

The polymerization reaction is represented by the following formula (3), equation (4) and is characterized by polymerizing at least one monomer represented by the formula (5), of the polymer according to claim 1 or 2 Production method.

(In the formulas (3), (4), and (5), A ¹ is each independently a hydrogen atom or a methyl group, and R ⁴ and R ⁵ are each independently a hydrogen atom, or a saturated or unsaturated group. Is an aliphatic hydrocarbon group having 1 to 12 carbon atoms.)

The polymerization reaction is represented by the following formula (6), equation (7), and characterized by polymerizing at least one of the monomers represented by the formula (8), according to claim 1 or 2 A method for producing a polymer.

(In the above formulas (6), (7) and (8), A ¹ is each independently a hydrogen atom or a methyl group, and A ² is each independently a formula (9), a formula (10), a formula (11) or a structure represented by the formula (12), wherein A ³ is an aliphatic hydrocarbon group having 1 to 18 carbon atoms,

In the formulas (9), (10), (11), and (12), R ⁶ and R ¹⁶ are each independently a hydrogen atom, or a saturated or unsaturated group which may be substituted with a nitro group or a halogen atom. Wherein R ⁷ to R ¹⁵ are each independently a hydrogen atom, a nitro group, a halogen atom, or a saturated or unsaturated aliphatic hydrocarbon optionally substituted with a nitro group or a halogen atom. R ⁷ and R ⁸ , or R ⁹ , R ¹⁰ and R ¹¹ may be bonded to each other to form a cyclic structure which may have an unsaturated bond in the ring; The position of N in (6), (7), and (8) is shown. )

A ² in the monomers represented by the formulas (6), (7) and (8) has a structure represented by the following formula (13), (14) or (15). The method for producing a polymer according to claim 4 , wherein:

(In the formulas (13), (14), and (15), R ¹⁷ and R ²⁷ are each independently a hydrogen atom or a saturated or unsaturated aliphatic hydrocarbon group, and R ¹⁸ to R ²⁶ are Each is independently a hydrogen atom, a nitro group, a halogen atom, or a saturated or unsaturated aliphatic hydrocarbon group, and * indicates the position of N in the above formulas (6) to (8).)

3. The polymer according to claim 1, wherein the polymerization reaction polymerizes at least one of the monomers represented by the following formulas (16), (17), and (18). 4. Manufacturing method of coalescence.

(In the formulas (16), (17) and (18), A ¹ is each independently a hydrogen atom or a methyl group, and R ¹⁷ and R ²⁷ are each independently a hydrogen atom or a saturated or unsaturated group. An aliphatic hydrocarbon group, and R ¹⁸ to R ²⁶ are each independently a hydrogen atom, a nitro group, a halogen atom, or a saturated or unsaturated aliphatic hydrocarbon group.)

The polymerization reaction, which comprises polymerizing a monomer represented by at least the formula (6) and (7), the polymer production method of claim 4 or 5.

The method for producing a polymer according to claim 7 , wherein the polymerization reaction polymerizes at least the monomers represented by the formulas (6), (7), and (8).

The method for producing a polymer according to any one of claims 1 to 8 , wherein the polymerization reaction polymerizes at least a polyfunctional monomer.

The method according to claim 9 , wherein the polyfunctional monomer is a monomer represented by the following formula (19).

(In the above formula (19), A ¹ is each independently a hydrogen atom or a methyl group, and R ²⁸ has a linear or cyclic aliphatic hydrocarbon group having 1 to 20 carbon atoms and a substituent. An aromatic hydrocarbon group which may be substituted, or a heteroaromatic hydrocarbon group which may have a substituent.)

The method for producing a polymer according to claim 10 , wherein the monomer represented by the formula (19) is selected from the group consisting of the following formulas (19-1) and (19-2). .

(In the above formulas (19-1) and (19-2), A ¹ is each independently a hydrogen atom or a methyl group, and A ⁴ is each independently a carbon atom having one nitrogen atom or one hydrogen atom bonded thereto. R ²⁹ and R ³⁰ are each independently an alkoxy group having 1 to 20 carbon atoms, an alkoxycarbonyl group, an alkylcarbonyloxy group, an alkylaminocarbonyl group, an alkylcarbonylamino group, an alkylthio group, or an alkylsulfonyl group. is there.)

The method for producing a polymer according to any one of claims 1 to 11, wherein the polymerization reaction is performed using a photopolymerization initiator.