JP2018048345A - Method for producing ester-exchanged oil and fat composition and ester-exchanged oil and fat composition - Google Patents
Method for producing ester-exchanged oil and fat composition and ester-exchanged oil and fat composition Download PDFInfo
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本発明はマーガリンやショートニング等に用いることができるエステル交換油脂組成物の製造方法およびエステル交換油脂組成物に関する。 The present invention relates to a method for producing a transesterified oil and fat composition that can be used for margarine, shortening, and the like, and a transesterified oil and fat composition.
マーガリンやショートニング等の可塑性を必要とされる油脂食品は、一般に、高融点油脂と液状の低融点油脂とを組み合わせたり、高融点油脂と中融点油脂と低融点油脂とを組み合わせた可塑性油脂組成物を用いることで、広い温度範囲における可塑性、良好な口溶け感、高温における油脂の滲み出し抑制効果を得ている。この種の可塑性油脂組成物に用いられる高融点油脂としては、従来より、動植物油脂に水素添加して高融点とした硬化油が用いられている。しかしながら高融点油脂が部分水素添加した油脂の場合、心臓疾患が懸念されるトランス酸を生成するという問題があった。一方、極度硬化油はトランス酸生成の虞はないが、高融点油脂として極度硬化油を用いると、可塑性を呈する温度範囲が狭く、口溶け感も悪いという問題があった。 Oil and fat foods that require plasticity, such as margarine and shortening, are generally a combination of a high melting point fat and a liquid low melting point fat or a plastic fat composition comprising a combination of a high melting point fat, a medium melting point fat and a low melting point fat. By using this, the plasticity in a wide temperature range, the good mouth-melting feeling, and the oil and fat exudation suppressing effect at a high temperature are obtained. As high melting point fats and oils used in this type of plastic fat and oil composition, conventionally, hardened oils having a high melting point by hydrogenation of animal and vegetable fats and oils have been used. However, in the case where the high melting point fat / oil is a partially hydrogenated fat / oil, there is a problem in that trans acid is produced which may cause heart disease. On the other hand, although extremely hardened oil has no fear of producing a trans acid, when extremely hardened oil is used as a high melting point fat, there is a problem that the temperature range exhibiting plasticity is narrow and the mouth meltability is poor.
このため近年は、エステル交換により調製したトランス酸生成の虞のない可塑性油脂組成物が用いられるようになっている。可塑性を有するエステル交換油脂組成物としては、ラウリン酸を含む油脂と炭素数１６以上の飽和脂肪酸を含む油脂混合物を特定のランダム化率にエステル交換したもの（特許文献１）、脂肪酸組成としてパルミチン酸とラウリン酸とが特定の割合となるように混合した油脂をエステル交換した後、更に水素添加したもの（特許文献２）、炭素数１２の飽和脂肪酸と、炭素数１６〜１８の飽和脂肪酸を非選択的にエステル交換した高融点油脂と、特定の油脂を含む中融点油脂とを混合したもの（特許文献３）、構成脂肪酸としてラウリン酸を２５〜４５重量％含有し、ヨウ素価が０〜２５であり、特定のトリグリセリド組成を満たす硬質脂肪（特許文献４）等が知られている。 For this reason, in recent years, a plastic fat composition prepared by transesterification and having no fear of producing a trans acid has been used. The transesterified oil / fat composition having plasticity is obtained by transesterifying an oil / fat mixture containing lauric acid and an oil / fat containing a saturated fatty acid having 16 or more carbon atoms to a specific randomization rate (Patent Document 1), and palmitic acid as a fatty acid composition. The oil and fat mixed so that lauric acid and lauric acid have a specific ratio are transesterified and then hydrogenated (Patent Document 2), a saturated fatty acid having 12 carbon atoms and a saturated fatty acid having 16 to 18 carbon atoms. A mixture of a high melting point oil / fatty oil selectively transesterified and a medium melting point oil / fat containing a specific fat / oil (Patent Document 3), containing 25 to 45% by weight of lauric acid as a constituent fatty acid, and an iodine value of 0 to 25 And a hard fat satisfying a specific triglyceride composition (Patent Document 4) and the like are known.
しかしながら、特許文献１記載の油脂組成物は、特定のランダム化率となるようにエステル交換する必要があるため、目的とする油脂組成物を得るためのコントロールが難しく、製造コストが高くなるとともに、他の油脂との相溶性が十分ではないため、他の油脂を配合すると保形性が低下するという問題がある。また特許文献２に記載されている油脂組成物は、経時的な硬さの変化が大きいため使用しづらいという問題があり、特許文献３、４に記載の油脂組成物は口溶けが悪く、口溶けを良好にするためには他の油脂との併用が必要であるが、他の油脂との相溶性が悪いという問題があった。
本発明は上記従来の課題を解決したエステル交換油脂組成物の製造方法およびエステル交換油脂組成物を提供することを目的とする。
However, since the oil and fat composition described in Patent Document 1 needs to be transesterified so as to have a specific randomization rate, it is difficult to control to obtain the target oil and fat composition, and the production cost is increased. Since the compatibility with other fats and oils is not sufficient, there is a problem that the shape retention is lowered when other fats and oils are blended. In addition, the oil and fat composition described in Patent Document 2 has a problem that it is difficult to use because the change in hardness over time is large, and the oil and fat composition described in Patent Documents 3 and 4 is poorly melted in the mouth. In order to make it good, it is necessary to use with other fats and oils, but there is a problem that the compatibility with other fats and oils is poor.
An object of this invention is to provide the manufacturing method of the transesterified oil-fat composition which solved the said conventional subject, and the transesterified oil-fat composition.
即ち本発明は、
（１）全構成脂肪酸中のラウリン酸含有量が３０重量％以上であるラウリン系油脂（Ａ）１０〜３０重量％（但し、前記ラウリン系油脂（Ａ）がパーム核油または前記パーム核油の分別油若しくは硬化油である）と、全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）７０〜９０重量％（但し、前記パーム系油脂（Ｂ）が、極度硬化油を５〜４５重量％含有する）とをエステル交換して、総炭素数４０〜４６のトリグリセリドの割合が１５〜３５重量％の油脂組成物を得ることを特徴とするエステル交換油脂組成物の製造方法、
（２）ラウリン系油脂（Ａ）のヨウ素価が２以下である上記（１）に記載のエステル交換油脂組成物の製造方法、
（３）パーム系油脂（Ｂ）のヨウ素価が３０〜４８である上記（１）又は（２）に記載のエステル交換油脂組成物の製造方法、
（４）油脂組成物における総炭素数４６のトリグリセリドの割合が７〜１５重量％である上記（１）から（３）のいずれか一項に記載のエステル交換油脂組成物の製造方法、
（５）油脂組成物において、構成脂肪酸として飽和脂肪酸（Ｓ）を２個、不飽和脂肪酸（Ｕ）を１個含む非対称型トリグリセリド（ＳＳＵ）と、対称型トリグリセリド（ＳＵＳ）との重量比率が、ＳＳＵ／ＳＵＳ＝１．８〜２．２である上記（１）から（４）のいずれか一項に記載のエステル交換油脂組成物の製造方法、
（６）油脂組成物において、全構成脂肪酸中におけるラウリン酸量の、ステアリン酸量に対する比率が０．２〜０．７であり、かつ炭素数１８の不飽和脂肪酸量の、炭素数１８の飽和脂肪酸量に対する比率が０．５〜４．０である上記（１）から（５）のいずれか一項に記載のエステル交換油脂組成物の製造方法、
（７）油脂組成物の５℃におけるＳＦＣが５５〜８０％である上記（１）から（６）のいずれか一項に記載のエステル交換油脂成物の製造方法、
（８）油脂組成物の３５℃におけるＳＦＣが１５〜３０％である上記（７）に記載のエステル交換油脂組成物の製造方法、
（９）全構成脂肪酸中のラウリン酸含有量が３０重量％以上であるラウリン系油脂（Ａ）と、全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）とのエステル交換油脂組成物であって、総炭素数４０〜４６のトリグリセリドの割合が１５〜３５重量％であり、前記ラウリン系油脂（Ａ）がパーム核油または前記パーム核油の分別油若しくは硬化油であり、かつ、前記パーム系油脂（Ｂ）が、極度硬化油を５〜４５重量％含有することを特徴とするエステル交換油脂組成物、
（１０）総炭素数４６のトリグリセリドの割合が７〜１５重量％である上記（９）に記載のエステル交換油脂組成物、
（１１）全構成脂肪酸中におけるラウリン酸量の、ステアリン酸量に対する比率が０．２〜０．７であり、かつ炭素数１８の不飽和脂肪酸量の、炭素数１８の飽和脂肪酸量に対する比率が０．５〜４．０である上記（９）又は（１０）に記載のエステル交換油脂組成物、
を要旨とするものである。
That is, the present invention
(1) Lauric acid content (A) in which the content of lauric acid in all the constituent fatty acids is 30% by weight or more (A) is 10 to 30% by weight (provided that the lauric oil (A) is palm kernel oil or palm kernel oil. It is a fractionated oil or a hardened oil) and a palm-based fat / oil (B) having a fatty acid content of 16 or more carbon atoms in all constituent fatty acids of 35% by weight or more (provided that the palm-based fat / oil (B) Ester) characterized in that the oil-and-fat composition having a total carbon number of 40-46 triglycerides of 15-35 wt. A method for producing an exchangeable fat composition,
(2) The method for producing a transesterified oil / fat composition according to the above (1), wherein the iodine value of the lauric fat / oil (A) is 2 or less,
(3) The method for producing a transesterified oil / fat composition according to (1) or (2) above, wherein the iodine value of the palm-based oil / fat (B) is 30 to 48,
(4) The method for producing a transesterified oil and fat composition according to any one of (1) to (3), wherein the ratio of the triglyceride having a total carbon number of 46 in the oil and fat composition is 7 to 15% by weight,
(5) In the oil and fat composition, the weight ratio of the asymmetric triglyceride (SSU) containing two saturated fatty acids (S) and one unsaturated fatty acid (U) as a constituent fatty acid to the symmetric triglyceride (SUS) is as follows: The method for producing a transesterified oil and fat composition according to any one of (1) to (4), wherein SSU / SUS = 1.8 to 2.2,
(6) In the oil and fat composition, the ratio of the amount of lauric acid in the total constituent fatty acids to the amount of stearic acid is 0.2 to 0.7, and the amount of unsaturated fatty acids having 18 carbons is saturated with 18 carbons. The method for producing a transesterified oil and fat composition according to any one of (1) to (5), wherein the ratio to the amount of fatty acid is 0.5 to 4.0,
(7) The method for producing a transesterified oil / fat composition according to any one of (1) to (6), wherein the SFC of the oil / fat composition at 55 ° C is 55 to 80%,
(8) The method for producing a transesterified oil / fat composition according to (7), wherein the SFC of the oil / fat composition at 15 ° C. is 15 to 30%,
(9) Lauric oil and fat (A) having a lauric acid content in all constituent fatty acids of 30% by weight or more and palm oil and fat having a fatty acid content of 16 or more carbon atoms in all constituent fatty acids of 35% by weight or more It is a transesterified oil / fat composition with (B), Comprising: The ratio of a C-40-46 triglyceride is 15-35 weight%, The said lauric oil (A) is a palm kernel oil or the said palm kernel oil. A transesterified oil / fat composition, which is a fractionated oil or a hardened oil, and the palm-based fat / oil (B) contains 5 to 45% by weight of an extremely hardened oil,
(10) The transesterified oil / fat composition according to (9), wherein the proportion of the triglyceride having a total carbon number of 46 is 7 to 15% by weight,
(11) The ratio of the amount of lauric acid in all constituent fatty acids to the amount of stearic acid is 0.2 to 0.7, and the ratio of the amount of unsaturated fatty acid having 18 carbon atoms to the amount of saturated fatty acid having 18 carbon atoms is The transesterified oil / fat composition according to (9) or (10), which is 0.5 to 4.0,
Is a summary.
本発明のエステル交換油脂組成物は、トランス酸を実質的に含有していなくても、従来のトランス酸を含む硬化油と同等の保形性を有し、口溶けに優れ、経時的な硬さの変化がなく安定性に優れる等の効果を有する。また他の油脂を配合する場合でも他の油脂との相溶性に優れるため、他の油脂と配合してマーガリンやショートニングなどの可塑性油脂として用いた場合、経時的な性状の変化がなく安定性に優れる等の効果を有する。また本発明の製造方法によれば、上記保形性、口溶け、経時安定性等の優れた物性を有するエステル交換油脂組成物を製造することができる。 The transesterified oil / fat composition of the present invention has a shape-retaining property equivalent to that of a conventional oil containing trans acid even if it does not substantially contain trans acid, is excellent in melting in the mouth, and has a hardness over time. There is an effect that the stability is excellent. In addition, even when blended with other fats and oils, it is excellent in compatibility with other fats and oils, so when blended with other fats and oils and used as plastic fats such as margarine and shortening, there is no change in properties over time and stability It has the effect of being excellent. Moreover, according to the manufacturing method of this invention, the transesterified oil-and-fat composition which has the outstanding physical properties, such as the said shape retention property, melt in a mouth, and temporal stability, can be manufactured.
本発明のエステル交換油脂組成物は、全構成脂肪酸中のラウリン酸含有量が３０重量％以上であるラウリン系油脂（Ａ）と、全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）とをエステル交換して得られる油脂組成物であって、総炭素数４０〜４６のトリグリセリドの組成物中の割合が１５〜３５重量％であるが、２５〜３５重量％が好ましい。総炭素数４０〜４６のトリグリセリドの割合が１５重量％未満であると極端に口溶けが悪くなり、３５重量％を超えると他の油脂との相溶性が悪くなる。総炭素数４０〜４６のトリグリセリドのなかでも、口溶けや保形性、相溶性が良好となるため総炭素数４６のトリグリセリドの組成物中の割合が７〜１５重量％であることが好ましく、特に１０〜１５重量％が好ましい。 In the transesterified oil / fat composition of the present invention, the content of lauric acid (A) in which the lauric acid content in the total constituent fatty acids is 30% by weight or more, and the content of fatty acids having 16 or more carbon atoms in the total constituent fatty acids is 35%. % Of an oil / fat composition obtained by transesterification with palm-based oil / fat (B) having a total carbon number of 40 to 46, which is 15 to 35% by weight. ~ 35 wt% is preferred. If the proportion of triglycerides having a total carbon number of 40 to 46 is less than 15% by weight, the solubility in the mouth becomes extremely bad, and if it exceeds 35% by weight, the compatibility with other fats and oils becomes worse. Among triglycerides having a total carbon number of 40 to 46, the ratio of the triglycerides having a total carbon number of 46 in the composition is preferably 7 to 15% by weight, because the mouth melting, shape retention and compatibility are good. 10-15 weight% is preferable.
本発明のエステル交換油脂組成物は、構成脂肪酸のうち、２個が飽和脂肪酸（Ｓ）で、１個が不飽和脂肪酸（Ｕ）であるトリグリセリドのうちの、非対称トリグリセリド（ＳＳＵ）と対称トリグリセリド（ＳＵＳ）との重量比率が、ＳＳＵ／ＳＵＳ＝１．８〜２．２であるものが好ましい。これにより結晶性が良くなり、製造機内での結晶化が速くなり、可塑性の良好な油脂を製造し易くなる。 The transesterified oil / fat composition of the present invention comprises an asymmetric triglyceride (SSU) and a symmetric triglyceride (of triglycerides, two of which are saturated fatty acids (S) and one of unsaturated fatty acids (U)). The weight ratio with respect to (SUS) is preferably SSU / SUS = 1.8 to 2.2. This improves the crystallinity, speeds up the crystallization in the production machine, and makes it easy to produce oils with good plasticity.
更にトリグリセリドの全構成脂肪酸中、ラウリン酸量の、ステアリン酸量に対する比率（ラウリン酸量／ステアリン酸量）が０．２〜０．７であり、炭素数１８の不飽和脂肪酸量の、炭素数１８の飽和脂肪酸量に対する比率（Ｃ１８の不飽和脂肪酸量／Ｃ１８の飽和脂肪酸量）が０．５〜４．０であるものが好ましい。これにより保形性の良好な油脂を得ることができる。ラウリン酸量の、ステアリン酸量に対する比率（ラウリン酸量／ステアリン酸量）が０．４〜０．６であり、炭素数１８の不飽和脂肪酸量の、炭素数１８の飽和脂肪酸量に対する比率（Ｃ１８の不飽和脂肪酸量／Ｃ１８の飽和脂肪酸量）が１．０〜２．０であると、口溶けと保形性に優れるので、さらに好ましい。 Furthermore, in the total constituent fatty acids of triglycerides, the ratio of the amount of lauric acid to the amount of stearic acid (the amount of lauric acid / the amount of stearic acid) is 0.2 to 0.7, and the number of unsaturated fatty acids having 18 carbon atoms. It is preferable that the ratio of 18 to the amount of saturated fatty acid (C18 unsaturated fatty acid amount / C18 saturated fatty acid amount) is 0.5 to 4.0. Thereby, fats and oils with good shape retention can be obtained. The ratio of the amount of lauric acid to the amount of stearic acid (the amount of lauric acid / the amount of stearic acid) is 0.4 to 0.6, and the ratio of the unsaturated fatty acid amount having 18 carbon atoms to the saturated fatty acid amount having 18 carbon atoms ( It is more preferable that the amount of unsaturated fatty acid of C18 / the amount of saturated fatty acid of C18) is 1.0 to 2.0, since it is excellent in mouth melting and shape retention.
本発明のエステル交換油脂組成物は、５℃におけるＳＦＣが５５〜８０％であるものが、他油脂との相溶性が良く、結晶核となり固化し易く、マーガリンやショートニングなどの可塑性油脂を製造し易く、また油脂の染みだしなどの経時的な性状の変化がなく、安定性に優れ好ましく、更に３５℃におけるＳＦＣが１５％以上であると保形性が良好となるが、なかでも１５〜３０％であるものが、他油脂との相溶性が良く、エステル交換油脂組成物が結晶核となって固化し易く、マーガリンやショートニングなどの可塑性油脂を製造し易く、口溶けが良好で保形性を有するマーガリンやショートニングなどの可塑性油脂を製造し易いため好ましい。３５℃におけるＳＦＣは２０〜３０％であることがより好ましい。 The transesterified oil / fat composition of the present invention has an SFC of 55 to 80% at 5 ° C., which has good compatibility with other fats and oils and is easy to solidify as crystal nuclei, producing plastic fats such as margarine and shortening. It is easy, and there is no change in properties over time, such as oil and oil oozing, and it is excellent in stability. Further, when the SFC at 35 ° C. is 15% or more, the shape retention is good. % Is good compatibility with other fats and oils, transesterified fats and oils composition is easy to solidify as crystal nuclei, easy to produce plastic fats and oils such as margarine and shortening, good meltability and shape retention It is preferable because it is easy to produce plastic fats such as margarine and shortening. The SFC at 35 ° C. is more preferably 20-30%.
本発明のエステル交換油脂組成物は、構成脂肪酸のうち２個が不飽和脂肪酸で１個が飽和脂肪酸であるトリグリセリドと、３個の構成脂肪酸全てが不飽和脂肪酸であるトリグリセリドの合計の割合が、全トリグリセリド中９〜３７重量％であるものが好ましい。これによりエステル交換油脂組成物の融点を調整することができる。また他の油脂と混合しマーガリンやショートニングを作る際に、結晶核となって、可塑性の良好な油脂を得ることができる。 The transesterified oil and fat composition of the present invention has a total ratio of triglycerides in which two of the constituent fatty acids are unsaturated fatty acids and one is a saturated fatty acid, and triglycerides in which all three constituent fatty acids are unsaturated fatty acids, What is 9 to 37 weight% in all the triglycerides is preferable. Thereby, melting | fusing point of transesterified oil-fat composition can be adjusted. Moreover, when mixing with other fats and oils and making a margarine and shortening, it becomes a crystal nucleus and can obtain fats and oils with favorable plasticity.
本発明の総炭素数４０〜４６のトリグリセリドを１５〜３５重量％含有するエステル交換油脂組成物は、全構成脂肪酸中のラウリン酸含有量が３０重量％以上であるラウリン系油脂（Ａ）１０〜３０重量％と、全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）７０〜９０重量％とをエステル交換して得ることができる。全構成脂肪酸中のラウリン酸含有量が３０重量％以上であるラウリン系油脂（Ａ）としては、ヤシ油、パーム核油、これらの分別油、硬化油等の１種又は２種以上が挙げられる。これらのうち、ヤシ油に比べて融点が高く、高融点のエステル交換油を容易に得ることができるパーム核油、その分別油や硬化油が好ましい。硬化油の場合、水素添加量によってトランス酸の含有量が増加する虞があるため、硬化油を用いる場合には微水素添加したものか、低温硬化したもの、完全水素添加した極度硬化油が好ましく、特に極度硬化油が好ましい。ラウリン系油脂（Ａ）はラウリン酸含有量が４０〜５５重量％のものが好ましく、特に４５〜５０重量％のものが好ましい。ラウリン系油脂（Ａ）としては、ヨウ素価が２以下のものを用いることが好ましく、特にヨウ素価１以下が好ましい。ヨウ素価が２以下のラウリン系油脂（Ａ）を用いると、トランス酸の生成の虞が少なく、エステル交換油を他油脂と混合する際に結晶核となり、固化し易くかつ口溶けの良い油脂組成物となる利点がある。 The transesterified oil-and-fat composition containing 15 to 35% by weight of triglycerides having a total carbon number of 40 to 46 according to the present invention has a lauric-based fat and oil (A) 10 to 10 having a lauric acid content in all the constituent fatty acids of 30% by weight or more. It can be obtained by transesterification of 30% by weight and 70 to 90% by weight of palm-based fats and oils (B) in which the content of fatty acids having 16 or more carbon atoms in all the constituent fatty acids is 35% by weight or more. Examples of lauric fats and oils (A) having a lauric acid content of 30% by weight or more in all constituent fatty acids include one or more of coconut oil, palm kernel oil, fractionated oils thereof, hardened oils and the like. . Among these, palm kernel oil, its fractionated oil and hydrogenated oil, which have a higher melting point than palm oil and can easily obtain a high melting point transesterified oil, are preferred. In the case of hydrogenated oil, the content of trans acid may increase depending on the amount of hydrogenation. Therefore, when hydrogenated oil is used, a slightly hydrogenated oil, a low-temperature-cured oil, or a fully hydrogenated ultra-hardened oil is preferred. Particularly preferred is an extremely hardened oil. The lauric oil (A) preferably has a lauric acid content of 40 to 55% by weight, particularly 45 to 50% by weight. As the lauric fats and oils (A), those having an iodine value of 2 or less are preferably used, and an iodine value of 1 or less is particularly preferred. When a lauric oil (A) having an iodine value of 2 or less is used, there is little risk of the formation of trans acid, and the oil composition is easy to solidify and melt well when it is mixed with other fats and oils. There is an advantage to become.
一方、全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）としては、パーム油、パーム分別油や、これらの硬化油やエステル交換油等の１種又は２種以上が用いられる。パーム分別油としては、硬質部、軟質部、中融点部等を用いることができる。硬化油の場合、微水添硬化油、低温硬化油、極度硬化油が好ましいが、特に極度硬化油が好ましい。 On the other hand, as the palm-based oil (B) having a fatty acid content of 16 or more carbon atoms in the total constituent fatty acids of 35% by weight or more, 1 such as palm oil, palm fractionated oil, hardened oil or transesterified oil thereof, etc. Species or two or more are used. As palm fractionation oil, a hard part, a soft part, a middle melting point part, etc. can be used. In the case of a hardened oil, a slightly hydrogenated hardened oil, a low-temperature hardened oil, and an extremely hardened oil are preferable, but an extremely hardened oil is particularly preferable.
パーム系油脂（Ｂ）としてヨウ素価が２以上のものを用いるとともに、ラウリン系油脂（Ａ）とパーム系油脂（Ｂ）の全構成脂肪酸中、ラウリン酸量を１４％未満とすることにより、総炭素数４０〜４６のトリグリセリドの割合が１５〜３５重量％であって、かつ総炭素数４６のトリグリセリドの割合が７〜１５重量％であるエステル交換油脂組成物を得ることができるが、パーム系油脂（Ｂ）はヨウ素価が３０〜４８であるものを用いると、口溶けを低下させることなく保形性を確保できるという利点がありより好ましい。パーム系油脂（Ｂ）は特にヨウ素価３０〜４０のものが長期に渡る保形性があるのでより好ましい。またパーム系油脂（Ｂ）中には、パーム系油脂の極度硬化油を５〜４５重量％含有することが好ましく、特に２０〜４０重量％含有することが好ましい。５％以上であると、経時的な硬さの変化がなく、また保形性が良好なものを得ることができるが、パーム系油脂（Ｂ）中に極度硬化油が５〜４５重量％含有されていると、エステル交換油脂組成物の融点を高めることができる利点があり、２０〜４０重量％であると口溶けと保形性の双方が良好なものを得ることができる。
更にラウリン系油脂（Ａ）とパーム系油脂（Ｂ）の全構成脂肪酸中、ラウリン系油脂（Ａ）由来のステアリン酸が０．２〜９重量％、パーム系油脂（Ｂ）由来のステアリン酸が６．５〜２８．０重量％となるように、ラウリン系油脂（Ａ）を１０〜３０重量％、パーム系油脂（Ｂ）を９０〜７０重量％の範囲で用いてエステル交換することにより、エステル交換油脂組成物の全構成脂肪酸中におけるラウリン酸の、ステアリン酸に対する比率が０．２〜０．７であり、かつ炭素数１８の不飽和脂肪酸量の、炭素数１８の飽和脂肪酸量に対する比率が０．５〜４．０であるエステル交換油脂組成物を得ることができる。
またパーム系油脂（Ｂ）としてヨウ素価３０〜５４のものを用いるとともに、ラウリン系油脂（Ａ）としてヨウ素価１８以下のものを用いることにより、５℃におけるＳＦＣが５５〜８０％であるエステル交換油脂組成物を得ることができる。更にパーム系油脂（Ｂ）としてヨウ素価３０〜４８のものを用いるとともに、ラウリン系油脂（Ａ）としてヨウ素価２以下のものを用いることにより、５℃におけるＳＦＣが５５〜８０％であるとともに、更に３５℃におけるＳＦＣが１５〜３０％のエステル交換油脂組成物を得ることができる。
By using a palm oil and fat (B) having an iodine value of 2 or more, and making the amount of lauric acid less than 14% in the total constituent fatty acids of the lauric oil and fat (A) and palm oil and fat (B), A transesterified oil and fat composition in which the proportion of triglycerides having 40 to 46 carbon atoms is 15 to 35% by weight and the proportion of triglycerides having 46 carbon atoms is 7 to 15% by weight can be obtained. It is more preferable to use oils and fats (B) having an iodine value of 30 to 48 because there is an advantage that shape retention can be ensured without lowering the melting of the mouth. Palm oils and fats (B) are particularly preferred since those having an iodine value of 30 to 40 have shape retention over a long period of time. Moreover, it is preferable to contain 5 to 45 weight% of extremely hardened oils of palm oil and fat in palm oil and fat (B), and it is preferable to contain especially 20 to 40 weight%. When it is 5% or more, there is no change in hardness over time and a good shape-retaining property can be obtained, but an extremely hardened oil is contained in the palm-based oil (B) in an amount of 5 to 45% by weight. If it is, there is an advantage that the melting point of the transesterified oil and fat composition can be increased, and if it is 20 to 40% by weight, a product that has both good meltability and shape retention can be obtained.
Furthermore, in all the constituent fatty acids of lauric fats and oils (A) and palm fats and oils (B), stearic acid derived from lauric fats and oils (A) is 0.2 to 9% by weight, and stearic acid derived from palm fats and oils (B) is By transesterification using 10-30 wt% of lauric fat (A) and 90-70 wt% of palm fat (B) so as to be 6.5-28.0 wt%, Ratio of lauric acid to stearic acid in all constituent fatty acids of transesterified oil and fat composition is 0.2 to 0.7, and ratio of unsaturated fatty acid having 18 carbon atoms to saturated fatty acid having 18 carbon atoms Can obtain a transesterified oil-and-fat composition having 0.5 to 4.0.
Moreover, while using the thing of 30-54 iodine value as palm oil fat (B) and using the thing of iodine number 18 or less as lauric oil fat (A), transesterification whose SFC in 5 degreeC is 55-80% An oil and fat composition can be obtained. Furthermore, while using the thing of iodine numbers 30-48 as palm type fats and oils (B), and using the thing of iodine numbers 2 or less as lauric type fats and oils (A), while SFC in 5 ° C is 55 to 80%, Furthermore, a transesterified oil and fat composition having an SFC of 15 to 30% at 35 ° C. can be obtained.
ラウリン系油脂（Ａ）と、パーム系油脂（Ｂ）のエステル交換反応には、エステル交換触媒として化学触媒や酵素触媒が用いられる。化学触媒としてはナトリウムメチラートや水酸化ナトリウム等が用いられ、酵素触媒としてはリバーゼ等が用いられる。リパーゼとしてはアスペルギルス属、アルカリゲネス属等のリパーゼが挙げられ、イオン交換樹脂、ケイ藻土、セラミック等の担体上に固定し固定化したものを用いても、粉末の形態として用いても良い。また位置選択性のあるリパーゼ、位置選択性のないリパーゼの何れも用いることができるが、位置選択性のないリパーゼを使用することが好ましい。エステル交換触媒として化学触媒や位置選択性のない酵素触媒を用いた場合、ラウリン系油脂（Ａ）とパーム系油脂（Ｂ）とのエステル交換反応が完了すると、構成脂肪酸として飽和脂肪酸（Ｓ）を２個、不飽和脂肪酸（Ｕ）を１個含む非対称型トリグリセリド（ＳＳＵ）と、対称型トリグリセリド（ＳＵＳ）とのエステル交換油脂組成物中における重量比率が、ＳＳＵ／ＳＵＳ＝１．８〜２．２となる。 A chemical catalyst or an enzyme catalyst is used as a transesterification catalyst in the transesterification of the lauric fat (A) and the palm fat (B). Sodium methylate, sodium hydroxide or the like is used as the chemical catalyst, and ribose or the like is used as the enzyme catalyst. Examples of the lipase include lipases of the genus Aspergillus, Alkagenes, etc., which may be fixed and immobilized on a carrier such as an ion exchange resin, diatomaceous earth, or ceramic, or may be used in the form of a powder. Either lipase with regioselectivity or lipase without regioselectivity can be used, but it is preferable to use a lipase without regioselectivity. When a chemical catalyst or an enzyme catalyst without regioselectivity is used as the transesterification catalyst, when the transesterification reaction between the lauric fat (A) and the palm fat (B) is completed, a saturated fatty acid (S) is used as a constituent fatty acid. The weight ratio of the asymmetric triglyceride (SSU) containing two unsaturated fatty acids (U) and the symmetric triglyceride (SUS) in the transesterified oil / fat composition is SSU / SUS = 1.8-2. 2.
エステル交換に化学触媒を用いる場合、触媒を油脂重量の０．０５〜０．１５重量％添加し、減圧下で８０〜１２０℃に加熱し、０．５〜１．０時間攪拌することでラウリン系油脂（Ａ）とパーム系油脂（Ｂ）とのエステル交換反応が平衡状態となって完了し、本発明のエステル交換油脂組成物を得ることができる。また酵素触媒を用いる場合、リパーゼ等の酵素触媒を油脂重量の０．０１〜１０重量％添加し、４０〜８０℃でエステル交換反応を行うことによりエステル交換反応が平衡状態となって完了し、本発明のエステル交換油脂組成物を得ることができる。エステル交換反応はカラムによる連続反応、バッチ反応のいずれの方法で行うこともできる。エステル交換反応後、必要に応じて脱色、脱臭等の精製を行うことができる。 When using a chemical catalyst for transesterification, 0.05 to 0.15% by weight of the fat / oil is added to the catalyst, heated to 80 to 120 ° C. under reduced pressure, and stirred for 0.5 to 1.0 hour. The transesterification reaction between the base oil and fat (A) and the palm oil and fat (B) is completed in an equilibrium state, and the transesterification oil and fat composition of the present invention can be obtained. When an enzyme catalyst is used, an enzyme catalyst such as lipase is added in an amount of 0.01 to 10% by weight of the fat and fat, and the ester exchange reaction is completed by performing the ester exchange reaction at 40 to 80 ° C. The transesterified oil / fat composition of the present invention can be obtained. The transesterification reaction can be carried out by either a continuous reaction using a column or a batch reaction. After the transesterification reaction, purification such as decolorization and deodorization can be performed as necessary.
本発明において、ラウリン系油脂（Ａ）における全構成脂肪酸中のラウリン酸の割合、パーム系油脂（Ｂ）における全構成脂肪酸中の炭素数１６以上の脂肪酸含有量、エステル交換反応の終了は、ガスクロマトグラフ法により確認することができる。 In the present invention, the proportion of lauric acid in the total constituent fatty acids in the lauric fats and oils (A), the content of fatty acids having 16 or more carbon atoms in the total constituent fatty acids in the palm-based fats and oils (B), and the end of the transesterification reaction are gas chromates. It can be confirmed by the graph method.
以下、実施例、比較例を挙げて本発明を更に詳細に説明する。
実施例１〜１２、比較例１〜５、参考例
表１、表２に示す割合でラウリン系油脂（Ａ）とパーム系油脂（Ｂ）とを混合し１１０℃に加熱し、十分に脱水させた後、化学触媒としてナトリウムメチラートを油脂重量の０．０６重量％添加し、減圧下、１００℃で０．５時間攪拌しながらエステル交換反応を行った。エステル交換反応後、水洗して触媒を除去し、活性白土を用いて脱色し、さらに脱臭を行ってエステル交換油脂組成物を得た。得られた油脂組成物の性状を、表３、表４に示す。エステル交換に用いたラウリン系油脂（Ａ）、パーム系油脂（Ｂ）を以下に示す。尚、参考例としては、下記パーム系油脂（Ｂ）のパーム硬化油をそのまま用いた。実施例、比較例のエステル交換油脂組成物における非対称型トリグリセリド（ＳＳＵ）と、対称型トリグリセリド（ＳＵＳ）の割合（ＳＳＵ／ＳＵＳ）は、ガスクロマトグラフ法(基準油脂分析試験法(社団法人日本油化学会)の「２．４．２．２−１９９６ 脂肪酸組成(ＦＩＤ昇温ガスクロマトグラフ法)」と「暫７-２００３ ２位脂肪酸組成」)により求めたＳＳＵ型トリグリセリドとＳＵＳ型トリグリセリドの重量より算出した。
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples.
Examples 1 to 12, Comparative Examples 1 to 5, Reference Example Laurin oil (A) and palm oil (B) are mixed in the ratios shown in Table 1 and Table 2, heated to 110 ° C., and sufficiently dehydrated. After that, sodium methylate as a chemical catalyst was added in an amount of 0.06% by weight of the fat and oil, and the ester exchange reaction was carried out with stirring at 100 ° C. for 0.5 hours under reduced pressure. After the transesterification reaction, the catalyst was removed by washing with water, decolorized using activated clay, and further deodorized to obtain a transesterified oil / fat composition. Tables 3 and 4 show the properties of the obtained oil and fat composition. The lauric oil (A) and palm oil (B) used for transesterification are shown below. In addition, as a reference example, palm hardened oil of the following palm oil fat (B) was used as it was. The ratio (SSU / SUS) of the asymmetric triglyceride (SSU) and the symmetric triglyceride (SUS) in the transesterified oil / fat compositions of Examples and Comparative Examples was determined by gas chromatography (reference oil analysis test method (Japan Oil Chemical Co., Ltd.). Calculated from the weights of SSU-type triglycerides and SUS-type triglycerides obtained by “2.4.2.2-1996 fatty acid composition (FID temperature rising gas chromatographic method)” and “temporary 7-2003 2-position fatty acid composition”). did.
ラウリン系油脂（Ａ）
パーム核極度硬化油 ：ラウリン酸含量 ４５．７重量％（ヨウ素価２）
パーム核油 ：ラウリン酸含量 ４５．７重量％（ヨウ素価１８）
パーム系油脂（Ｂ）
パーム油 ：Ｃ１６以上の脂肪酸含有量 ９７．９重量％（ヨウ素価５３）
パーム分別油硬質部 ：Ｃ１６以上の脂肪酸含有量 ９８．８重量％（ヨウ素価４３）
パーム分別油軟質部 ：Ｃ１６以上の脂肪酸含有量 ９７．７重量％（ヨウ素価６１）
パーム極度硬化油 ：Ｃ１６以上の脂肪酸含有量 ９７．９重量％（ヨウ素価２）
パーム硬化油（融点４５℃）：Ｃ１６以上の脂肪酸含有量 ９７．８重量％（ヨウ素価４５）
Laurin oil (A)
Palm kernel extremely hardened oil: Lauric acid content 45.7% by weight (iodine value 2)
Palm kernel oil: lauric acid content 45.7% by weight (iodine value 18)
Palm oil (B)
Palm oil: C16 or higher fatty acid content 97.9 wt% (iodine value 53)
Palm fractionated oil hard part: C16 or higher fatty acid content 98.8 wt% (iodine value 43)
Palm fractionated oil soft part: C16 or higher fatty acid content 97.7% by weight (iodine value 61)
Palm extremely hardened oil: C16 or higher fatty acid content 97.9 wt% (iodine value 2)
Hardened palm oil (melting point 45 ° C.): C16 or higher fatty acid content 97.8 wt% (iodine value 45)
※１ ヨウ素価は「２．３．４．１−１９９６ ヨウ素価（ウィイス−シクロヘキサン法）」で測定した。 * 1 The iodine value was measured by “2.3.4.1-1996 Iodine value (Wiis-cyclohexane method)”.
※２ 総炭素数４０〜４６のトリグリセリド含有量は、ガスクロマトグラフ法(基準油脂分析試験法(社団法人日本油化学会)の「２．４．６．１−１９９６ トリアシルグリセリン組成（ガスクロマトグラフ法)」）により測定した。 * 2 The triglyceride content with a total carbon number of 40 to 46 is determined according to the gas chromatographic method (standard oil analysis test method (Japan Oil Chemists' Society) "2.4.6.1-1996 triacylglycerol composition (gas chromatographic method). ) ").
※３ 総炭素数４６のトリグリセリド含有量は、ガスクロマトグラフ法(基準油脂分析試験法(社団法人日本油化学会)の「２．４．６．１−１９９６ トリアシルグリセリン組成（ガスクロマトグラフ法)」）により測定した。 * 3 The content of triglycerides having a total carbon number of 46 is determined according to the gas chromatographic method (standard oil analysis test method (Japan Oil Chemists' Society) “2.4.6.1-1996 triacylglycerol composition (gas chromatographic method)”). ).
※４ 全構成脂肪酸中のラウリン酸量のステアリン酸量に対する比率（ラウリン酸量／ステアリン酸量）はガスクロマトグラフ法により(基準油脂分析試験法(社団法人日本油化学会)の「２．４．２．２−１９９６ 脂肪酸組成(ＦＩＤ昇温ガスクロマトグラフ法)」で測定し、それぞれ脂肪酸量を用いて計算にて求めた。 * 4 The ratio of the amount of lauric acid to the amount of stearic acid in all the constituent fatty acids (lauric acid amount / stearic acid amount) is determined by the gas chromatographic method (reference oil analysis method (Japan Oil Chemists' Society), “2.4. 2.2-1996 Fatty acid composition (FID temperature rising gas chromatograph method) ", and each was calculated by using the amount of fatty acid.
※５ 不飽和脂肪酸を２個含むトリグリセリド（２不飽和トリグセリド）と、不飽和脂肪酸を３個含むトリグリセリド（３不飽和トリグリセリド）の合計割合は、ガスクロマトグラフ法により(基準油脂分析試験法(社団法人日本油化学会)の「２．４．２．２−１９９６ 脂肪酸組成(ＦＩＤ昇温ガスクロマトグラフ法)」と「暫７-２００３ ２位脂肪酸組成」で測定し、それぞれ脂肪酸量を用いて計算にて求めた。 * 5 The total ratio of triglycerides containing 2 unsaturated fatty acids (2 unsaturated triglycerides) and triglycerides containing 3 unsaturated fatty acids (3 unsaturated triglycerides) was determined by gas chromatography (standard oil analysis test method (corporate association) Measured by “2.4.2.2-1996 fatty acid composition (FID temperature rising gas chromatograph method)” and “temporary 7-2003 2-position fatty acid composition” of the Japan Oil Chemists' Society, and calculated using the amount of fatty acid respectively. Asked.
※６
全構成脂肪酸中の炭素数１８の不飽和脂肪酸量の、炭素数１８の飽和脂肪酸量に対する比率（Ｃ１８の不飽和脂肪酸量／Ｃ１８の飽和脂肪酸量）はガスクロマトグラフ法により(基準油脂分析試験法(社団法人日本油化学会)の「２．４．２．２−１９９６ 脂肪酸組成(ＦＩＤ昇温ガスクロマトグラフ法)」で測定し、それぞれ脂肪酸量を用いて計算にて求めた。
* 6
The ratio of the amount of unsaturated fatty acids having 18 carbon atoms to the amount of saturated fatty acids having 18 carbon atoms in all the constituent fatty acids (the amount of unsaturated fatty acids of C18 / the amount of saturated fatty acids of C18) was determined by gas chromatography (standard oil analysis test method It was measured by “2.4.2.2-1996 fatty acid composition (FID temperature rising gas chromatograph method)” of Japan Oil Chemists' Society, and each was calculated by using the amount of fatty acid.
※７ トランス酸含有量はガスクロマトグラフ法により(基準油脂分析試験法(社団法人日本油化学会)の「２．４．２．２−１９９６ 脂肪酸組成(ＦＩＤ昇温ガスクロマトグラフ法)」で測定した。 * 7 Trans acid content was measured by “2.4.2.2-1996 Fatty acid composition (FID temperature rising gas chromatograph method)” of “Standard oil analysis test method (Japan Oil Chemists' Society)” by gas chromatographic method. .
※８ ５℃のＳＦＣ、３５℃のＳＦＣは基準油脂分析試験法(社団法人日本油化学会)の「２．２．９−２００３ 固体脂含量(ＮＭＲ法)」により測定した。 * 8 SFC at 5 ° C. and SFC at 35 ° C. were measured by “2.2.9-2003 solid fat content (NMR method)” of the standard fat analysis method (Japan Oil Chemistry Society).
※９ 硬さは、２００ｍｌのビーカーにエステル交換油脂組成物を１５０ｇ入れ、３０℃にて２時間保持した後、８時間保持した後にレオメータ（測定条件：プランジャー 直径８ｍｍ円柱状、速度 ６０ｍｍ/分 深度 接触面から５ｍｍ）により測定し、以下の基準により２時間後の硬さ、８時間後の硬さを評価した。
（２時間後の硬さ）
○・・２０００gｆ/ｍ2未満
△・・２０００gｆ/ｍ2以上、３５００gｆ/ｍ2未満
×・・３５００gｆ/ｍ2以上
（８時間後の硬さ）
○・・３０００gｆ/ｍ2未満
△・・３０００gｆ/ｍ2以上、６０００gｆ/ｍ2未満
×・・６０００gｆ/ｍ2以上
* 9 The hardness is 150 g of the transesterified oil / fat composition in a 200 ml beaker, held at 30 ° C. for 2 hours, then held for 8 hours and then rheometer (measurement condition: plunger diameter 8 mm cylindrical, speed 60 mm / min. Depth was measured by 5 mm from the contact surface, and the hardness after 2 hours and the hardness after 8 hours were evaluated according to the following criteria.
(Hardness after 2 hours)
○ · · 2000 gf / m less than 2 △ ·· 2000gf / m 2 or more, 3500gf / m 2 less × ·· 3500gf / m 2 or more (hardness after 8 hours)
○ ·· 3000gf / m less than 2 △ ·· 3000gf / m 2 or more, 6000gf / m 2 less than × ·· 6000gf / m 2 or more
※１０ 上記硬さの試験において、２時間保持した後と８時間保持した後の硬さの増加率を下記式より求め、以下の基準により評価した。
（数１）
増加率＝（８時間保持後の硬さ−２時間保持後の硬さ）／２時間保持後の硬さ×１００ ○・・８０％未満
△・・８０％以上１２０％未満
×・・１２０％以上
* 10 In the hardness test, the rate of increase in hardness after holding for 2 hours and after holding for 8 hours was obtained from the following formula and evaluated according to the following criteria.
(Equation 1)
Rate of increase = (Hardness after holding for 8 hours-Hardness after holding for 2 hours) / Hardness after holding for 2 hours x 100 Less than 80% △ 80% or more but less than 120% x 120% that's all
※１１ 相溶性は、エステル交換油脂組成物とパーム油を１：１で混合し８０℃に溶解し、示差走査熱測定分析(ＤＳＣ)で６０℃から−４０℃に冷却するクーリング試験（冷却速度１０℃／分）を行い、発熱のピーク温度を測定し、第１ピークと第２ピークの温度差よ
り、以下の基準で評価した。結果を表３．４に示す。
○：温度差が１５℃以上〜２０℃未満
△：温度差が２０℃以上〜２５℃未満
×：温度差が２５℃以上〜３０℃未満
* 11 Compatibility is a cooling test (cooling rate) in which the transesterified oil and fat composition and palm oil are mixed at a ratio of 1: 1 and dissolved at 80 ° C, and cooled to 60 ° C to -40 ° C by differential scanning calorimetry (DSC). 10 ° C./min), the peak temperature of the exotherm was measured, and the temperature was evaluated according to the following criteria from the temperature difference between the first peak and the second peak. The results are shown in Table 3.4.
○: Temperature difference is 15 ° C. or more and less than 20 ° C. Δ: Temperature difference is 20 ° C. or more and less than 25 ° C. ×: Temperature difference is 25 ° C. or more and less than 30 ° C.
※１２ 口溶けは、各エステル交換油脂組成物をマーガリン・ショートニング製造機にて急冷・捏和によりショートニングを作成し、それらをパネラーにより参考例のパーム硬化油(融点４５℃)から作成したショートニングを指標に試食し、その結果から、以下の基準で評価した。結果を表３．４に示す。
◎：良い
○：同等
△：やや劣る
×：劣る
* 12 Mouth melting is a shortening made by quenching and kneading each transesterified oil / fat composition on a margarine / shortening manufacturing machine, and using the panel to make a shortening from the palm hardened oil (melting point 45 ° C) in the reference example. And the results were evaluated according to the following criteria. The results are shown in Table 3.4.
◎: Good ○: Equivalent △: Slightly inferior ×: Inferior
※１３ 保形性は、各エステル交換油脂組成物をマーガリン・ショートニング製造機にて急冷・捏和によりショートニングを作成し、それらを絞り袋にて絞り３５℃で２４時間置いたものの保形性を観測した、以下の基準で評価した。結果を表３．４に示す。
◎：非常に良く、染みだしない。
○：良く、染みだしない。
△：やや弱く、若干染みだしある。
×：弱く、油の染み出しがある
* 13 Shape retention is the shape retention of each transesterified oil / fat composition prepared by quenching and kneading with a margarine / shortening manufacturing machine, and then squeezing them at 35 ° C for 24 hours. Observed and evaluated according to the following criteria. The results are shown in Table 3.4.
A: Very good and does not ooze out.
○: Well, it does not ooze out.
Δ: Slightly weak and slightly exuding.
×: Weak and oil oozes out
※１４ 保形性は、各エステル交換油脂組成物をマーガリン・ショートニング製造機にて急冷・捏和によりショートニングを作成し、それらを絞り袋にて絞り３５℃で７２時間置いたものの保形性を観測した、以下の基準で評価した。結果を表３．４に示す。
◎：非常に良く、染みだしない。
○：良く、染みだしない。
△：やや弱く、若干染みだしある。
×：弱く、油の染み出しがある。
* 14 Shape retention is the shape retention of each transesterified oil / fat composition prepared by quenching and kneading with a margarine / shortening production machine and then squeezing them at 35 ° C for 72 hours. Observed and evaluated according to the following criteria. The results are shown in Table 3.4.
A: Very good and does not ooze out.
○: Well, it does not ooze out.
Δ: Slightly weak and slightly exuding.
X: Weak and oil oozes out.
Claims (11)
全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）７０〜９０重量％（但し、前記パーム系油脂（Ｂ）が、極度硬化油を５〜４５重量％含有する）とをエステル交換して、
総炭素数４０〜４６のトリグリセリドの割合が１５〜３５重量％の油脂組成物を得ることを特徴とするエステル交換油脂組成物の製造方法。 10% to 30% by weight of lauric oil / fat (A) having a lauric acid content in all constituent fatty acids of 30% by weight or more (provided that the lauric oil / fat (A) is a palm kernel oil or a fractionated oil of the palm kernel oil or Hardened oil)
Palm-based fats and oils (B) having a fatty acid content of 16 or more carbon atoms in all constituent fatty acids of 35% by weight or more (provided that the palm-based fats and oils (B) are extremely hardened oils in an amount of 5 to 45%. Transesterified with
The manufacturing method of the transesterified oil-fat composition characterized by obtaining the oil-fat composition whose ratio of a C40-46 triglyceride is 15-35 weight%.
全構成脂肪酸中の炭素数１６以上の脂肪酸含有量が３５重量％以上であるパーム系油脂（Ｂ）とのエステル交換油脂組成物であって、総炭素数４０〜４６のトリグリセリドの割合が１５〜３５重量％であり、
前記ラウリン系油脂（Ａ）がパーム核油または前記パーム核油の分別油若しくは硬化油であり、かつ、
前記パーム系油脂（Ｂ）が、極度硬化油を５〜４５重量％含有することを特徴とするエステル交換油脂組成物。 A lauric oil (A) having a lauric acid content of 30% by weight or more in all constituent fatty acids;
It is a transesterified oil / fat composition with a palm oil / fat (B) having a fatty acid content of 16 or more carbon atoms in all constituent fatty acids of 35% by weight or more, and the ratio of triglycerides having a total carbon number of 40 to 46 is 15 to 35% by weight,
The lauric fat (A) is palm kernel oil or a fractionated oil or hardened oil of the palm kernel oil, and
The said palm oil fat (B) contains 5-45 weight% of extremely hardened oil, The transesterified oil-fat composition characterized by the above-mentioned.
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