JP2018028696A5 - - Google Patents

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Publication number
JP2018028696A5
JP2018028696A5 JP2017219036A JP2017219036A JP2018028696A5 JP 2018028696 A5 JP2018028696 A5 JP 2018028696A5 JP 2017219036 A JP2017219036 A JP 2017219036A JP 2017219036 A JP2017219036 A JP 2017219036A JP 2018028696 A5 JP2018028696 A5 JP 2018028696A5
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JP
Japan
Prior art keywords
plasticizer
polarizing plate
unevenly distributed
plate according
cellulose ester
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Pending
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JP2017219036A
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Japanese (ja)
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JP2018028696A (en
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Priority to JP2017219036A priority Critical patent/JP2018028696A/en
Priority claimed from JP2017219036A external-priority patent/JP2018028696A/en
Publication of JP2018028696A publication Critical patent/JP2018028696A/en
Publication of JP2018028696A5 publication Critical patent/JP2018028696A5/ja
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Claims (11)

偏光子の両面に、活性エネルギー線硬化型接着剤に活性エネルギー線を照射することにより形成された接着剤層を介して、第1および第2透明保護フィルムが貼り合わされている偏光板であって、
少なくとも第1透明保護フィルムは、可塑剤およびセルロースエステルを含有してなり、かつ、前記可塑剤が一方の面に偏在している、可塑剤偏在セルロースエステルフィルムであり、
前記可塑剤偏在セルロースエステルフィルムにおいて可塑剤が偏在している面側が、前記接着剤層を介して貼り合わされていることを特徴とする偏光板。
A polarizing plate in which first and second transparent protective films are bonded to both surfaces of a polarizer via an adhesive layer formed by irradiating an active energy ray-curable adhesive with active energy rays. ,
At least the first transparent protective film is a plasticizer unevenly distributed cellulose ester film comprising a plasticizer and a cellulose ester, and wherein the plasticizer is unevenly distributed on one surface,
The polarizing plate characterized in that the plasticizer is unevenly distributed in the plasticizer unevenly-distributed cellulose ester film, and the surface side where the plasticizer is unevenly distributed is bonded via the adhesive layer.
前記可塑剤偏在セルロースエステルフィルムは、厚さが1μm以上であり、かつ、
前記可塑剤偏在セルロースエステルフィルムにおいて可塑剤が偏在している面側から厚さ5nmまでの範囲における可塑剤の割合(a)が、可塑剤が偏在していない面側から5nmまでの範囲における可塑剤の割合(b)より大きいことを特徴とする請求項1記載の偏光板。
The plasticizer unevenly distributed cellulose ester film has a thickness of 1 μm or more, and
In the plasticizer unevenly distributed cellulose ester film, the proportion (a) of the plasticizer in the range from the surface side where the plasticizer is unevenly distributed to the thickness of 5 nm is plastic in the range from the surface side where the plasticizer is not unevenly distributed to 5 nm. The polarizing plate according to claim 1, wherein the polarizing plate is larger than the ratio (b) of the agent.
前記可塑剤偏在セルロースエステルフィルムが含有する可塑剤がリン系可塑剤を含有することを特徴とする請求項2記載の偏光板。 The polarizing plate according to claim 2, wherein the plasticizer contained in the plasticizer unevenly distributed cellulose ester film contains a phosphorus plasticizer. リン系可塑剤中のリン原子に基づく、リン系可塑剤の前記割合(a)が0.5〜3atomic%であることを特徴とする請求項3記載の偏光板。   The polarizing plate according to claim 3, wherein the proportion (a) of the phosphorus plasticizer based on phosphorus atoms in the phosphorus plasticizer is 0.5 to 3 atomic%. 前記可塑剤偏在セルロースエステルフィルムは、nx>ny>nz(但し、面内屈折率が最大となる方向をX軸、X軸に垂直な方向をY軸、厚さ方向をZ軸とし、それぞれの軸方向の屈折率をnx、ny、nzとする)の関係を満足する位相差板であることを特徴とする請求項1〜4のいずれかに記載の偏光板。   The plasticizer unevenly distributed cellulose ester film has nx> ny> nz (where the in-plane refractive index has the maximum X-axis direction, the direction perpendicular to the X-axis has the Y-axis, and the thickness direction has the Z-axis, The polarizing plate according to any one of claims 1 to 4, wherein the polarizing plate satisfies a relationship of nx, ny, and nz in the axial refractive index. 前記第2透明保護フィルムが、透湿度が120g/m/24h以下であることを特徴とする請求項1〜5のいずれかに記載の偏光板。 The second transparent protective film, a polarizing plate according to any one of claims 1 to 5, wherein the moisture permeability is not more than 120g / m 2 / 24h. 前記第2透明保護フィルムが、(メタ)アクリル系樹脂、環状ポリオレフィン系樹脂またはポリエステル系樹脂を含有すること特徴とする請求項1〜6のいずれかに記載の偏光板。   The polarizing plate according to claim 1, wherein the second transparent protective film contains a (meth) acrylic resin, a cyclic polyolefin resin, or a polyester resin. 前記活性エネルギー線硬化型接着剤が、ラジカル重合性化合物を含有するラジカル硬化型の活性エネルギー線硬化型接着剤であることを特徴とする請求項1〜7のいずれかに記載の偏光板。   The polarizing plate according to claim 1, wherein the active energy ray curable adhesive is a radical curable active energy ray curable adhesive containing a radical polymerizable compound. 前記可塑剤偏在セルロースエステルフィルムにおいて、可塑剤が偏在していない面側の表面は、可塑剤が存在しないことを特徴とする請求項1〜8のいずれかに記載の偏光板。The polarizing plate according to any one of claims 1 to 8, wherein the plasticizer unevenly distributed cellulose ester film has no plasticizer on the surface side where the plasticizer is not unevenly distributed. 請求項1〜9のいずれかに記載の偏光板が、少なくとも1枚積層されていることを特徴とする光学フィルム。 An optical film in which at least one polarizing plate according to claim 1 is laminated. 請求項1〜9のいずれかに記載の偏光板または請求項10記載の光学フィルムが用いられていることを特徴とする画像表示装置。 An image display device, wherein a used optical film of the polarizing plate or claim 10, wherein according to any one of claims 1 to 9.
JP2017219036A 2017-11-14 2017-11-14 Polarizing plate, optical film and image display device Pending JP2018028696A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2017219036A JP2018028696A (en) 2017-11-14 2017-11-14 Polarizing plate, optical film and image display device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2017219036A JP2018028696A (en) 2017-11-14 2017-11-14 Polarizing plate, optical film and image display device

Related Parent Applications (1)

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JP2012285424A Division JP6245803B2 (en) 2012-12-27 2012-12-27 Polarizing plate, optical film and image display device

Publications (2)

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JP2018028696A JP2018028696A (en) 2018-02-22
JP2018028696A5 true JP2018028696A5 (en) 2018-05-17

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5040651B2 (en) * 2005-06-08 2012-10-03 コニカミノルタアドバンストレイヤー株式会社 Cellulose ester film, polarizing plate and liquid crystal display device
JP5231181B2 (en) * 2007-11-30 2013-07-10 日東電工株式会社 Polarizing plate, manufacturing method thereof, optical film, and image display device
JP5948794B2 (en) * 2011-11-04 2016-07-06 コニカミノルタ株式会社 Circularly polarizing plate, manufacturing method of circularly polarizing plate, and organic electroluminescence display device using circularly polarizing plate
JP6245803B2 (en) * 2012-12-27 2017-12-13 日東電工株式会社 Polarizing plate, optical film and image display device

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