JP2018023338A - Citrus fruit-like beverage and manufacturing method therefor - Google Patents
Citrus fruit-like beverage and manufacturing method therefor Download PDFInfo
- Publication number
- JP2018023338A JP2018023338A JP2016158817A JP2016158817A JP2018023338A JP 2018023338 A JP2018023338 A JP 2018023338A JP 2016158817 A JP2016158817 A JP 2016158817A JP 2016158817 A JP2016158817 A JP 2016158817A JP 2018023338 A JP2018023338 A JP 2018023338A
- Authority
- JP
- Japan
- Prior art keywords
- beverage
- citrus fruit
- citral
- lemon
- nonanal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000020971 citrus fruits Nutrition 0.000 title claims abstract description 79
- 235000013361 beverage Nutrition 0.000 title claims abstract description 69
- 241000207199 Citrus Species 0.000 title claims abstract description 68
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 claims abstract description 63
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims abstract description 49
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229940043350 citral Drugs 0.000 claims abstract description 45
- 235000013334 alcoholic beverage Nutrition 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002781 deodorant agent Substances 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 7
- 235000019520 non-alcoholic beverage Nutrition 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000796 flavoring agent Substances 0.000 abstract description 30
- 235000019634 flavors Nutrition 0.000 abstract description 30
- 230000001737 promoting effect Effects 0.000 abstract description 3
- 235000005979 Citrus limon Nutrition 0.000 description 34
- 244000131522 Citrus pyriformis Species 0.000 description 34
- 239000000284 extract Substances 0.000 description 31
- 238000011156 evaluation Methods 0.000 description 19
- 235000019645 odor Nutrition 0.000 description 19
- 235000015203 fruit juice Nutrition 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 235000019441 ethanol Nutrition 0.000 description 11
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 9
- 230000001476 alcoholic effect Effects 0.000 description 7
- 230000006866 deterioration Effects 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 238000002470 solid-phase micro-extraction Methods 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 235000013399 edible fruits Nutrition 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 235000000346 sugar Nutrition 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 3
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 240000000560 Citrus x paradisi Species 0.000 description 3
- 229930091371 Fructose Natural products 0.000 description 3
- 239000005715 Fructose Substances 0.000 description 3
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 3
- 239000004376 Sucralose Substances 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 240000006909 Tilia x europaea Species 0.000 description 3
- 239000000619 acesulfame-K Substances 0.000 description 3
- 239000000538 analytical sample Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 235000013405 beer Nutrition 0.000 description 3
- 235000019658 bitter taste Nutrition 0.000 description 3
- 235000014171 carbonated beverage Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 235000003599 food sweetener Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000019408 sucralose Nutrition 0.000 description 3
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 3
- 150000005846 sugar alcohols Chemical class 0.000 description 3
- 239000003765 sweetening agent Substances 0.000 description 3
- 235000019640 taste Nutrition 0.000 description 3
- 230000002123 temporal effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- PFTAWBLQPZVEMU-ZFWWWQNUSA-N (+)-epicatechin Natural products C1([C@@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-ZFWWWQNUSA-N 0.000 description 2
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 description 2
- DOUMFZQKYFQNTF-WUTVXBCWSA-N (R)-rosmarinic acid Chemical compound C([C@H](C(=O)O)OC(=O)\C=C\C=1C=C(O)C(O)=CC=1)C1=CC=C(O)C(O)=C1 DOUMFZQKYFQNTF-WUTVXBCWSA-N 0.000 description 2
- CDOSHBSSFJOMGT-GYCZTXFPSA-N 1,1,2-trideuterio-3-(dideuteriomethyl)-7-methylocta-1,6-dien-3-ol Chemical compound [2H]C([2H])C(O)(CCC=C(C)C)C([2H])=C([2H])[2H] CDOSHBSSFJOMGT-GYCZTXFPSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- XPCTZQVDEJYUGT-UHFFFAOYSA-N 3-hydroxy-2-methyl-4-pyrone Chemical compound CC=1OC=CC(=O)C=1O XPCTZQVDEJYUGT-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 description 2
- 108010011485 Aspartame Proteins 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- 244000133098 Echinacea angustifolia Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- HDOMLWFFJSLFBI-UHFFFAOYSA-N Eriocitrin Natural products CC1OC(OCC2OC(Oc3cc(O)c4C(=O)CC(Oc4c3)c5ccc(OC6OC(COC7OC(C)C(O)C(O)C7O)C(O)C(O)C6O)c(O)c5)C(O)C(O)C2O)C(O)C(O)C1O HDOMLWFFJSLFBI-UHFFFAOYSA-N 0.000 description 2
- OMQADRGFMLGFJF-MNPJBKLOSA-N Eriodictioside Chemical compound O[C@@H]1[C@H](O)[C@@H](O)[C@H](C)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](OC=2C=C3O[C@@H](CC(=O)C3=C(O)C=2)C=2C=C(O)C(O)=CC=2)O1 OMQADRGFMLGFJF-MNPJBKLOSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 240000004670 Glycyrrhiza echinata Species 0.000 description 2
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 2
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 2
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 2
- 244000062730 Melissa officinalis Species 0.000 description 2
- 239000004384 Neotame Substances 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- REFJWTPEDVJJIY-UHFFFAOYSA-N Quercetin Chemical compound C=1C(O)=CC(O)=C(C(C=2O)=O)C=1OC=2C1=CC=C(O)C(O)=C1 REFJWTPEDVJJIY-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 244000228451 Stevia rebaudiana Species 0.000 description 2
- 235000006468 Thea sinensis Nutrition 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- 235000010358 acesulfame potassium Nutrition 0.000 description 2
- 229960004998 acesulfame potassium Drugs 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000605 aspartame Substances 0.000 description 2
- 235000010357 aspartame Nutrition 0.000 description 2
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 2
- 229960003438 aspartame Drugs 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 235000014134 echinacea Nutrition 0.000 description 2
- XMOCLSLCDHWDHP-IUODEOHRSA-N epi-Gallocatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-IUODEOHRSA-N 0.000 description 2
- LPTRNLNOHUVQMS-UHFFFAOYSA-N epicatechin Natural products Cc1cc(O)cc2OC(C(O)Cc12)c1ccc(O)c(O)c1 LPTRNLNOHUVQMS-UHFFFAOYSA-N 0.000 description 2
- 235000012734 epicatechin Nutrition 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000008123 high-intensity sweetener Substances 0.000 description 2
- 235000012907 honey Nutrition 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229940010454 licorice Drugs 0.000 description 2
- 229940069445 licorice extract Drugs 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- BNWJOHGLIBDBOB-UHFFFAOYSA-N myristicin Chemical compound COC1=CC(CC=C)=CC2=C1OCO2 BNWJOHGLIBDBOB-UHFFFAOYSA-N 0.000 description 2
- 235000019412 neotame Nutrition 0.000 description 2
- HLIAVLHNDJUHFG-HOTGVXAUSA-N neotame Chemical compound CC(C)(C)CCN[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 HLIAVLHNDJUHFG-HOTGVXAUSA-N 0.000 description 2
- 108010070257 neotame Proteins 0.000 description 2
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 2
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 235000019204 saccharin Nutrition 0.000 description 2
- 229940081974 saccharin Drugs 0.000 description 2
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
- ZMQAAUBTXCXRIC-UHFFFAOYSA-N safrole Chemical compound C=CCC1=CC=C2OCOC2=C1 ZMQAAUBTXCXRIC-UHFFFAOYSA-N 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 235000020083 shōchū Nutrition 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000001433 sodium tartrate Substances 0.000 description 2
- 229960002167 sodium tartrate Drugs 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- JMSVCTWVEWCHDZ-UHFFFAOYSA-N syringic acid Chemical compound COC1=CC(C(O)=O)=CC(OC)=C1O JMSVCTWVEWCHDZ-UHFFFAOYSA-N 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 description 2
- KYWIYKKSMDLRDC-UHFFFAOYSA-N undecan-2-one Chemical compound CCCCCCCCCC(C)=O KYWIYKKSMDLRDC-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 description 1
- GEWDNTWNSAZUDX-WQMVXFAESA-N (-)-methyl jasmonate Chemical compound CC\C=C/C[C@@H]1[C@@H](CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-WQMVXFAESA-N 0.000 description 1
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 description 1
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 description 1
- PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 description 1
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 description 1
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- RUYNUXHHUVUINQ-UHFFFAOYSA-N 2-Methyl-3-furanthiol Chemical compound CC=1OC=CC=1S RUYNUXHHUVUINQ-UHFFFAOYSA-N 0.000 description 1
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- 235000013668 Aloysia triphylla Nutrition 0.000 description 1
- 240000008554 Aloysia triphylla Species 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241001589086 Bellapiscis medius Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- 241000132536 Cirsium Species 0.000 description 1
- 241000951471 Citrus junos Species 0.000 description 1
- 240000004784 Cymbopogon citratus Species 0.000 description 1
- 235000017897 Cymbopogon citratus Nutrition 0.000 description 1
- 244000019459 Cynara cardunculus Species 0.000 description 1
- 235000019106 Cynara scolymus Nutrition 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 description 1
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 244000119298 Emblica officinalis Species 0.000 description 1
- 235000015489 Emblica officinalis Nutrition 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- YIKYNHJUKRTCJL-UHFFFAOYSA-N Ethyl maltol Chemical compound CCC=1OC=CC(=O)C=1O YIKYNHJUKRTCJL-UHFFFAOYSA-N 0.000 description 1
- XXRCUYVCPSWGCC-UHFFFAOYSA-N Ethyl pyruvate Chemical compound CCOC(=O)C(C)=O XXRCUYVCPSWGCC-UHFFFAOYSA-N 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- WMBWREPUVVBILR-UHFFFAOYSA-N GCG Natural products C=1C(O)=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-UHFFFAOYSA-N 0.000 description 1
- 235000017048 Garcinia mangostana Nutrition 0.000 description 1
- 240000006053 Garcinia mangostana Species 0.000 description 1
- 240000001972 Gardenia jasminoides Species 0.000 description 1
- 241000134874 Geraniales Species 0.000 description 1
- 241000578422 Graphosoma lineatum Species 0.000 description 1
- 235000005206 Hibiscus Nutrition 0.000 description 1
- 235000007185 Hibiscus lunariifolius Nutrition 0.000 description 1
- 244000284380 Hibiscus rosa sinensis Species 0.000 description 1
- 101000652226 Homo sapiens Suppressor of cytokine signaling 6 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XMOCLSLCDHWDHP-UHFFFAOYSA-N L-Epigallocatechin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C1=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-UHFFFAOYSA-N 0.000 description 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- HYMLWHLQFGRFIY-UHFFFAOYSA-N Maltol Natural products CC1OC=CC(=O)C1=O HYMLWHLQFGRFIY-UHFFFAOYSA-N 0.000 description 1
- VSBHYRPUJHEOBE-UHFFFAOYSA-N Maltyl isobutyrate Chemical compound CC(C)C(=O)OC1=C(C)OC=CC1=O VSBHYRPUJHEOBE-UHFFFAOYSA-N 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 1
- 244000183278 Nephelium litchi Species 0.000 description 1
- 235000016698 Nigella sativa Nutrition 0.000 description 1
- 244000090896 Nigella sativa Species 0.000 description 1
- 241000219925 Oenothera Species 0.000 description 1
- 235000004496 Oenothera biennis Nutrition 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 235000003421 Plantago ovata Nutrition 0.000 description 1
- 244000134552 Plantago ovata Species 0.000 description 1
- HLCFGWHYROZGBI-JJKGCWMISA-M Potassium gluconate Chemical compound [K+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O HLCFGWHYROZGBI-JJKGCWMISA-M 0.000 description 1
- 241000508269 Psidium Species 0.000 description 1
- 239000009223 Psyllium Substances 0.000 description 1
- ZVOLCUVKHLEPEV-UHFFFAOYSA-N Quercetagetin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=C(O)C(O)=C(O)C=C2O1 ZVOLCUVKHLEPEV-UHFFFAOYSA-N 0.000 description 1
- HWTZYBCRDDUBJY-UHFFFAOYSA-N Rhynchosin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=CC(O)=C(O)C=C2O1 HWTZYBCRDDUBJY-UHFFFAOYSA-N 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- ZZAFFYPNLYCDEP-HNNXBMFYSA-N Rosmarinsaeure Natural products OC(=O)[C@H](Cc1cccc(O)c1O)OC(=O)C=Cc2ccc(O)c(O)c2 ZZAFFYPNLYCDEP-HNNXBMFYSA-N 0.000 description 1
- 241001092459 Rubus Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 102100030530 Suppressor of cytokine signaling 6 Human genes 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000011517 Terminalia chebula Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- KPQJOKRSYYJJEL-VLQRKCJKSA-K [Na+].[Na+].CC1(C)[C@H](CC[C@@]2(C)[C@H]1CC[C@]1(C)[C@@H]2C(=O)C=C2[C@@H]3C[C@](C)(CC[C@]3(C)CC[C@@]12C)C([O-])=O)O[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)C([O-])=O)C([O-])=O Chemical compound [Na+].[Na+].CC1(C)[C@H](CC[C@@]2(C)[C@H]1CC[C@]1(C)[C@@H]2C(=O)C=C2[C@@H]3C[C@](C)(CC[C@]3(C)CC[C@@]12C)C([O-])=O)O[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)C([O-])=O)C([O-])=O KPQJOKRSYYJJEL-VLQRKCJKSA-K 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- -1 acidulant Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000010208 anthocyanin Nutrition 0.000 description 1
- 229930002877 anthocyanin Natural products 0.000 description 1
- 239000004410 anthocyanin Substances 0.000 description 1
- 150000004636 anthocyanins Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002921 anti-spasmodic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- 235000016520 artichoke thistle Nutrition 0.000 description 1
- 239000008122 artificial sweetener Substances 0.000 description 1
- 235000021311 artificial sweeteners Nutrition 0.000 description 1
- 235000020739 avocado extract Nutrition 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 235000020279 black tea Nutrition 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 235000004883 caffeic acid Nutrition 0.000 description 1
- 229940074360 caffeic acid Drugs 0.000 description 1
- LNMAXKMUGYXKPJ-UHFFFAOYSA-L calcium;1,1-dioxo-1,2-benzothiazol-2-id-3-one Chemical compound [Ca+2].C1=CC=C2C([O-])=NS(=O)(=O)C2=C1.C1=CC=C2C([O-])=NS(=O)(=O)C2=C1 LNMAXKMUGYXKPJ-UHFFFAOYSA-L 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000013736 caramel Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229960004424 carbon dioxide Drugs 0.000 description 1
- 235000021466 carotenoid Nutrition 0.000 description 1
- 150000001747 carotenoids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- WJSDHUCWMSHDCR-VMPITWQZSA-N cinnamyl acetate Natural products CC(=O)OC\C=C\C1=CC=CC=C1 WJSDHUCWMSHDCR-VMPITWQZSA-N 0.000 description 1
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 description 1
- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000013325 dietary fiber Nutrition 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- 239000012470 diluted sample Substances 0.000 description 1
- 229940048879 dl tartaric acid Drugs 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 229940045811 echinacea purpurea extract Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- DZYNKLUGCOSVKS-UHFFFAOYSA-N epigallocatechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3cc(O)c(O)c(O)c3 DZYNKLUGCOSVKS-UHFFFAOYSA-N 0.000 description 1
- 229940030275 epigallocatechin gallate Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940093503 ethyl maltol Drugs 0.000 description 1
- YYZUSRORWSJGET-UHFFFAOYSA-N ethyl octanoate Chemical compound CCCCCCCC(=O)OCC YYZUSRORWSJGET-UHFFFAOYSA-N 0.000 description 1
- 229940117360 ethyl pyruvate Drugs 0.000 description 1
- 235000001785 ferulic acid Nutrition 0.000 description 1
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 description 1
- 229940114124 ferulic acid Drugs 0.000 description 1
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000008369 fruit flavor Substances 0.000 description 1
- 229960002598 fumaric acid Drugs 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 235000013531 gin Nutrition 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229950006191 gluconic acid Drugs 0.000 description 1
- 235000012209 glucono delta-lactone Nutrition 0.000 description 1
- 239000000182 glucono-delta-lactone Substances 0.000 description 1
- 229960003681 gluconolactone Drugs 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 235000015092 herbal tea Nutrition 0.000 description 1
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 235000014058 juice drink Nutrition 0.000 description 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 229940043353 maltol Drugs 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- GEWDNTWNSAZUDX-UHFFFAOYSA-N methyl 7-epi-jasmonate Natural products CCC=CCC1C(CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229940116837 methyleugenol Drugs 0.000 description 1
- PRHTXAOWJQTLBO-UHFFFAOYSA-N methyleugenol Natural products COC1=CC=C(C(C)=C)C=C1OC PRHTXAOWJQTLBO-UHFFFAOYSA-N 0.000 description 1
- 235000020124 milk-based beverage Nutrition 0.000 description 1
- 229940029985 mineral supplement Drugs 0.000 description 1
- 235000020786 mineral supplement Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- UOISMTPJFYEVBW-UHFFFAOYSA-N o-[(2,3,4,5,6-pentafluorophenyl)methyl]hydroxylamine Chemical compound NOCC1=C(F)C(F)=C(F)C(F)=C1F UOISMTPJFYEVBW-UHFFFAOYSA-N 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 235000020333 oolong tea Nutrition 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229940109529 pomegranate extract Drugs 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229940070687 psyllium Drugs 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 229960001285 quercetin Drugs 0.000 description 1
- 235000005875 quercetin Nutrition 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- DOUMFZQKYFQNTF-MRXNPFEDSA-N rosemarinic acid Natural products C([C@H](C(=O)O)OC(=O)C=CC=1C=C(O)C(O)=CC=1)C1=CC=C(O)C(O)=C1 DOUMFZQKYFQNTF-MRXNPFEDSA-N 0.000 description 1
- TVHVQJFBWRLYOD-UHFFFAOYSA-N rosmarinic acid Natural products OC(=O)C(Cc1ccc(O)c(O)c1)OC(=Cc2ccc(O)c(O)c2)C=O TVHVQJFBWRLYOD-UHFFFAOYSA-N 0.000 description 1
- 235000013533 rum Nutrition 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940085605 saccharin sodium Drugs 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- KZQSXALQTHVPDQ-UHFFFAOYSA-M sodium;butanedioate;hydron Chemical compound [Na+].OC(=O)CCC([O-])=O KZQSXALQTHVPDQ-UHFFFAOYSA-M 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000013322 soy milk Nutrition 0.000 description 1
- 235000011496 sports drink Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- YIBXWXOYFGZLRU-UHFFFAOYSA-N syringic aldehyde Natural products CC12CCC(C3(CCC(=O)C(C)(C)C3CC=3)C)C=3C1(C)CCC2C1COC(C)(C)C(O)C(O)C1 YIBXWXOYFGZLRU-UHFFFAOYSA-N 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 239000000892 thaumatin Substances 0.000 description 1
- 235000010436 thaumatin Nutrition 0.000 description 1
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 description 1
- 235000019583 umami taste Nutrition 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- 235000012141 vanillin Nutrition 0.000 description 1
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 1
- 229940117960 vanillin Drugs 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 235000019195 vitamin supplement Nutrition 0.000 description 1
- 235000013522 vodka Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Alcoholic Beverages (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、柑橘類果実様飲料及びその製造方法に関する。 The present invention relates to a citrus fruit-like beverage and a method for producing the same.
シトラールは、柑橘類果実様香味、特に、レモン様香味を有する成分としてよく知られている。
また、シトラールは、熱、光、酸素、酸性等の外因的要因又は経時的要因によって、その化学構造が変化することが知られている。その結果、シトラールを含有した飲料は、柑橘類果実様香味(特に、レモン様香味)が経時的に減少することから、シトラールによる柑橘類果実様香味感、とりわけ、柑橘類果実(特に、レモン果実)をもぎたて搾り立てした際の果汁感又は新鮮感(フレッシュ感)が失われることがある。このため、シトラールによる柑橘類果実様香味感を低減させることなく、寧ろ、促進させることができる柑橘類果実様飲料が存在すれば、益々、消費者の嗜好に沿うものとなる。
Citral is well known as a component having a citrus fruit-like flavor, particularly a lemon-like flavor.
Moreover, it is known that the chemical structure of citral changes depending on external factors such as heat, light, oxygen, acidity, or temporal factors. As a result, the beverage containing citral has a citrus fruit-like flavor (especially lemon-like flavor) that decreases with time, so that it has a citrus fruit-like flavor, especially citrus fruits (particularly lemon fruits). The squeezed fruit juice or freshness (freshness) may be lost. For this reason, if there is a citrus fruit-like beverage that can be promoted without reducing the citrus fruit-like flavor caused by citral, it will become more and more in line with consumer preferences.
従来、果汁感を付与できるものとして、特許文献1(特開2016−106537号公報)では、柑橘系香料と、2-メチル-3-フランチオールとを含有した、容器詰めアルコール飲料が提案されている。また、特許文献2(特開2016−116493号公報)では、レモンらしさを向上させるために、(a)ノナナールと、(b)サフロール、メチルオイゲノール、又はミリスチシンを1ppb以上含有した、低レモン果汁含有飲料が提案されている。 Conventionally, as what can give a fruit juice feeling, patent document 1 (Unexamined-Japanese-Patent No. 2006-106537) has proposed the container-packed alcoholic drink containing a citrus-type fragrance | flavor and 2-methyl-3-furanthiol. Yes. Moreover, in patent document 2 (Unexamined-Japanese-Patent No. 2006-116493), in order to improve the character of lemon, it contains the low lemon juice containing (a) nonanal and (b) 1 ppb or more of safrole, methyl eugenol, or myristicin. Beverages have been proposed.
しかしながら、本願発明者等によれば、未だ、シトラールと併用され、シトラールによる柑橘類果実様香味感、とりわけ、柑橘類果実をもぎたて搾り立てした際の果汁感及び新鮮感を十分に付与し、促進させることができる、柑橘類果実様飲料は見出されていない。 However, according to the inventors of the present application, it is still used in combination with citral, and sufficiently imparts and promotes a citrus fruit-like flavor feeling by citral, in particular, a fruit juice feeling and freshness when squeezing and squeezing citrus fruit. No citrus fruit-like beverage has been found.
よって、今尚、柑橘類果実香味感を促進増進させ、シトラールと併用され、シトラールによる柑橘類果実様香味感を促進増強することが可能な物質とを組み合わせた、柑橘類果実様飲料の開発が要望されている。 Therefore, there is still a demand for the development of a citrus fruit-like beverage that is combined with a substance that promotes and enhances the citrus fruit flavor, is combined with citral, and can promote and enhance the citrus fruit-like flavor by citral. Yes.
本願発明者等は、今般、シトラールと併用され、シトラールによる柑橘類果実様香味感、とりわけ、柑橘類果実をもぎたて搾り立てした際の果汁感及び新鮮感を付与し、促進することができる物質として、ノナナールが優れた化合物であることを見出した。本願発明は、係る知見に基づいてなされたものである。 Inventors of the present application, as a substance that can be used in combination with citral, can impart and promote a citrus fruit-like flavor feeling by citral, particularly a fruit juice feeling and freshness when citrus fruit is squeezed and squeezed, Was found to be an excellent compound. This invention is made | formed based on the knowledge which concerns.
従って、本態様によれば、柑橘類果実様飲料であって、
シトラールと、ノナナールとを含んでなり、
前記シトラールの含有量(mg/L)を「X」とし、
前記ノナナールの含有量(mg/L)を「Y」とした場合、以下の数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
で表される関係を満たすものを提案することができる。
Therefore, according to this aspect, a citrus fruit-like beverage,
Comprising citral and nonanal,
The content of citral (mg / L) is “X”,
When the content (mg / L) of the nonanal is “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
It is possible to propose one satisfying the relationship expressed by
〔好ましい態様〕
好ましい態様は以下の通りである。
〔1〕 柑橘類果実様飲料であって、
シトラールと、ノナナールとを含んでなり、
前記シトラールの含有量(mg/L)を「X」とし、
前記ノナナールの含有量(mg/L)を「Y」とした場合、以下の数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
である関係を満たすものである、柑橘類果実様飲料。
〔2〕 前記数式1が、4.5≦X≦10であり、及び、
前記数式2が、0.23≦Y≦0.43である、〔1〕に記載の柑橘類果実様飲料。
〔3〕 劣化臭生成抑制剤又は劣化臭消臭剤をさらに含んでなる、〔1〕又は〔2〕に記載の柑橘類果実様飲料。
〔4〕 前記柑橘類果実様飲料のpHが、2以上7未満である、〔1〕〜〔3〕の何れか一項に記載の柑橘類果実様飲料。
〔5〕 前記柑橘類果実様飲料が、アルコール飲料又はノンアルコール飲料である、〔1〕〜〔4〕の何れか一項に柑橘類果実様飲料。
〔6〕 柑橘類果実様飲料を製造する方法であって、
シトラールと、ノナナールとを混合してなり、
前記混合が、前記シトラールの含有量(mg/L)を「X」とし、
前記ノナナールの含有量(mg/L)を「Y」とした場合、以下の数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
である関係を満たすように行われる、柑橘類果実様飲料の製造方法。
[Preferred embodiment]
Preferred embodiments are as follows.
[1] A citrus fruit-like beverage,
Comprising citral and nonanal,
The content of citral (mg / L) is “X”,
When the content (mg / L) of the nonanal is “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
A citrus fruit-like beverage that satisfies this relationship.
[2] Formula 1 is 4.5 ≦ X ≦ 10, and
The citrus fruit-like beverage according to [1], wherein Formula 2 is 0.23 ≦ Y ≦ 0.43.
[3] The citrus fruit-like beverage according to [1] or [2], further comprising a deteriorated odor production inhibitor or a deteriorated odor deodorant.
[4] The citrus fruit-like beverage according to any one of [1] to [3], wherein the pH of the citrus fruit-like beverage is 2 or more and less than 7.
[5] The citrus fruit-like beverage according to any one of [1] to [4], wherein the citrus fruit-like beverage is an alcoholic beverage or a non-alcoholic beverage.
[6] A method for producing a citrus fruit-like beverage,
A mixture of citral and nonanal,
In the mixing, the content (mg / L) of the citral is “X”,
When the content (mg / L) of the nonanal is “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
A method for producing a citrus fruit-like beverage, which is carried out so as to satisfy the relationship.
本発明によれば、シトラールと、ノナナールを採用することにより、柑橘類果実様飲料に、シトラールによる柑橘類果実様香味感(特に、レモン果実様香味)、とりわけ、柑橘類果実(特に、レモン果実)をもぎたて搾り立てした際の果汁感、新鮮感及び爽快感を継続付与し、促進させることが可能となる。この結果、本発明による柑橘類果実様飲料は、外因的要因又は経時的要因によっても、柑橘類果実をもぎたて搾り立てした際の果汁感、新鮮感及び爽快感を継続的に備えてなることとなる。 According to the present invention, by adopting citral and nonanal, a citrus fruit-like beverage with a citrus fruit-like flavor (particularly lemon fruit-like flavor), especially a citrus fruit (particularly lemon fruit) is picked up. It is possible to continuously give and promote the fruit juice feeling, freshness and refreshing feeling when squeezed. As a result, the citrus fruit-like beverage according to the present invention is continuously provided with a fruit juice feeling, a fresh feeling, and a refreshing feeling when the citrus fruit is squeezed and squeezed due to an external factor or a temporal factor.
〔定義〕
(シトラール)
シトラール(C10H16O)は、ゲラニアールとネラール(立体異性体)という化合物として存在し、一般には、精油に含まれる芳香成分の一つとして知られている。シトラールは、レモングラス、メリッサ(レモンバーム)、レモンバーベナ等の植物に多く含まれており、また、オレンジ、グレープフルーツ、ユズ、レモン、ライム等の柑橘系果実、並びに、山椒、生姜等の野菜に含まれている。
また、シトラール香料(柑橘系香料)は、強いレモン香を呈し、抗菌作用、鎮痙及び発汗作用に優れるという効果を有することから、従来、様々な飲食料品及び生活用品に使用されている。
しかし、シトラールは、柑橘類果実様香味(特に、強いレモン様香味)を有するものであるが、柑橘類果実様飲料に、例えば低濃度(例えば、一桁mg/Lオーダー)で含有させた場合、十分な柑橘類果実様香味を呈することは困難である。
また、シトラールは、加熱、光、酸性物質、酸素等の外因的要因により、また、柑橘類果実様飲料の保存、搬送、陳列等による経時的要因により、シトラールの化学構造が、環化、水和、異性化等の反応により変化し、その結果、劣化化学物質、例えば、p−クレゾール、p−サイメン、p−メチルアセトフェノンの化合物に変化する。しかもこれら劣化化合物は臭気を放ち、柑橘類果実様飲料に好ましくない臭い(悪臭)及び味を付与することがある。
[Definition]
(Citral)
Citral (C 10 H 16 O) exists as a compound called geranial and neral (stereoisomer), and is generally known as one of aromatic components contained in essential oils. Citral is abundant in plants such as lemongrass, Melissa (lemon balm), and lemon verbena, and also in citrus fruits such as orange, grapefruit, yuzu, lemon, and lime, and vegetables such as yam and ginger. It is.
Citral fragrance (citrus fragrance) has a strong lemon fragrance and has an effect of being excellent in antibacterial action, antispasmodic action and sweating action, and thus has been conventionally used in various foods and drinks and daily necessities.
However, citral has a citrus fruit-like flavor (particularly a strong lemon-like flavor), but is sufficient when it is contained in a citrus fruit-like beverage, for example, at a low concentration (eg, single digit mg / L order). It is difficult to exhibit a citrus fruit-like flavor.
Citral is also cyclized and hydrated due to extrinsic factors such as heating, light, acidic substances, oxygen, etc., and due to temporal factors such as storage, transportation and display of citrus fruit-like beverages. , Isomerization and the like, and as a result, it is changed to a deteriorated chemical substance such as p-cresol, p-cymene, p-methylacetophenone. In addition, these deteriorated compounds give off odors and may impart an unpleasant odor (bad odor) and taste to the citrus fruit-like beverage.
(ノナナール)
ノナナール:(C9H18O)は、多くの植物及び果実の精油中に見出され、一般には、精油に含まれる芳香成分の一つとして知られている。
本発明にあっては、ノナナールは、シトラールに併用されて、シトラールによる柑橘類果実様香味感を促進するものとして使用される。
具体的には、ノナナールは、シトラール含有柑橘類果実様飲料に混合されると、柑橘類果実様飲料に、柑橘類果実〔例えば、レモン、ライム、グレープフルーツ、オレンジ〕をもぎたて搾り立てした際の果汁感又は新鮮感を継続付与し、促進させる。
(Nonanar)
Nonanal: (C 9 H 18 O) is found in the essential oils of many plants and fruits and is generally known as one of the aromatic components contained in the essential oils.
In the present invention, nonanal is used in combination with citral to promote the citrus fruit-like flavor of citral.
Specifically, when nonanal is mixed with a citral-containing citrus fruit-like beverage, the citrus fruit-like beverage is squeezed and squeezed with citrus fruits (for example, lemon, lime, grapefruit, orange) or fresh. A feeling of continuation is given and promoted.
(含有量)
本発明にあっては、含有量は、本明細書において特にことわりがない限り、基本的に、mg/L、即ち、ppm(質量/体積)にて表す。
(Content)
In the present invention, the content is basically expressed in mg / L, that is, ppm (mass / volume) unless otherwise specified in the present specification.
〔柑橘類果実様飲料〕
柑橘類果実様飲料は、柑橘系果実様香味を有する飲料、好ましくは、レモン、グレープフルーツ、オレンジ、ライム等の果実様香味を持った飲料である。
[Citrus fruit-like beverage]
The citrus fruit-like beverage is a beverage having a citrus fruit-like flavor, preferably a beverage having a fruit-like flavor such as lemon, grapefruit, orange or lime.
(シトラールとノナナール)
本発明による柑橘類果実様飲料は、主成分として、シトラールと、ノナナールとを含んでなり、前記シトラールの含有量(mg/L)を「X」とし、前記ノナナールの含有量(mg/L)を「Y」とした場合、以下の数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
で表される関係を満たすものを提案することができる。
(Citral and Nonanal)
The citrus fruit-like beverage according to the present invention comprises citral and nonanal as main components, the content of citral (mg / L) is “X”, and the content of nonanal (mg / L) is In the case of “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
It is possible to propose one satisfying the relationship expressed by
好ましい態様によれば、
前記数式1が、4.5≦X≦10であり、及び、
前記数式2が、0.23≦Y≦0.43である、柑橘類果実様飲料を提案することができる。
According to a preferred embodiment,
Formula 1 is 4.5 ≦ X ≦ 10, and
It is possible to propose a citrus fruit-like beverage in which Equation 2 is 0.23 ≦ Y ≦ 0.43.
(pH値)
別の好ましい態様によれば、柑橘類果実様飲料のpHは、2以上7未満であり、好ましくは、3以上5以下である。
(PH value)
According to another preferred embodiment, the pH of the citrus fruit-like beverage is 2 or more and less than 7, and preferably 3 or more and 5 or less.
(任意成分)
本発明にあっては、柑橘類果実様飲料は、必要に応じて、任意成分を含んでなるものであってよい。任意成分としては、劣化臭生成抑制剤、劣化臭消臭剤(マスキング剤)、色素、果汁、エキス、香料、甘味料、酸味料、pH調整剤、酸化防止剤、保存料、ビタミン類、旨み成分、食物繊維、安定化剤、乳化剤等が挙げられる。これら任意成分は、厚生労働省、消費者庁等において定められたガイドライン及び関連法規(食品衛生法等)に規定されたものを用いる。
(Optional component)
In this invention, a citrus fruit-like drink may contain an arbitrary component as needed. As optional ingredients, deterioration odor production inhibitor, deterioration odor deodorant (masking agent), pigment, fruit juice, extract, fragrance, sweetener, acidulant, pH adjuster, antioxidant, preservative, vitamins, umami Ingredients, dietary fiber, stabilizers, emulsifiers and the like. As these optional components, those specified in the guidelines established by the Ministry of Health, Labor and Welfare and the Consumer Affairs Agency and related laws and regulations (Food Sanitation Law, etc.) are used.
〈劣化臭生成抑制剤又は劣化臭消臭剤〉
好ましい態様にあっては、シトラール劣化化合物による劣化臭対策として、劣化臭生成抑制剤又は劣化臭消臭剤(マスキング剤)を添加することができる。
<Deteriorated odor production inhibitor or deteriorated odor deodorant>
In a preferred embodiment, a deterioration odor production inhibitor or a deterioration odor deodorant (masking agent) can be added as a countermeasure against the deterioration odor caused by the citral deterioration compound.
劣化臭生成抑制剤としては、カリン抽出物、マンゴー抽出物、マンゴスチン抽出物、ミロバラン抽出物、ザクロ抽出物、カカオ抽出物、アシタバ抽出物、アボカド抽出物、オオバコ抽出物、ルブス抽出物、オリーブ果実及び葉抽出物、バンレイシ属植物の果皮抽出物、杜仲葉抽出物、エンメイソウ抽出物、ハイビスカス抽出物、ビート抽出物、ライチ種子抽出物、月見草種子抽出物、タヒボ抽出物、グァバ葉抽出物、マリーゴールド抽出物、ブラッククミン抽出物、マリアアザミ抽出物、アーティチョーク抽出物、アイブライト抽出物、エキナセアプルプレア抽出物、エキナセアアングスティフォリア抽出物、エキナセアパリダの抽出物;エピガロカテキン、エピカテキン、エピカテキンガレート、エピガロカテキンガレート;酵素処理ルチン、クエルセチン、フェルラ酸、カフェー酸、ロズマリン酸、シリンガ酸、没食子酸、エリオシトリン、エリオシトリン含有物、分子内に共役二重結合を有するジカルボン酸又はその金属塩(例えば、フマール酸、イタコン酸及びこれらの金属塩)等から選択される一種又は二種以上の混合物を用いることができる。 Deteriorated odor production inhibitors include Karin extract, Mango extract, Mangosteen extract, Myrobalan extract, Pomegranate extract, Cacao extract, Ashitaba extract, Avocado extract, Psyllium extract, Rubus extract, Olive fruit And leaf extract, pericarp extract of genus Vanleci, licorice leaf extract, enamel extract, hibiscus extract, beet extract, litchi seed extract, evening primrose seed extract, tahitibo extract, guava leaf extract, mary Gold extract, Black cumin extract, Maria thistle extract, Artichoke extract, Ibright extract, Echinacea purpurea extract, Echinacea anastifolia extract, Echinacea parida extract; Epigallocatechin, Epicatechin, Epicatechin Galate, epigallocatechin gallate; enzyme-treated ruch , Quercetin, ferulic acid, caffeic acid, rosmarinic acid, syringic acid, gallic acid, eriocitrin, eriocitrin-containing compound, dicarboxylic acid having a conjugated double bond in the molecule or a metal salt thereof (for example, fumaric acid, itaconic acid and One or a mixture of two or more selected from these metal salts) can be used.
劣化臭生成抑制剤の含有量は、柑橘類果実様飲料全質量に対して、0.001mg/L以上1000mg/L以下であり、より好ましくは、0.01mg/L以上100mg/L以下である。 Content of a deterioration odor production | generation inhibitor is 0.001 mg / L or more and 1000 mg / L or less with respect to the citrus fruit-like drink total mass, More preferably, it is 0.01 mg / L or more and 100 mg / L or less.
劣化臭消臭剤としては、難消化性デキストリン、バニリン、マルトール、エチルマルトール、オクタン酸エチル、2−ウンデカノン、エチルピルベート、メチルジャスモネート、メチルジヒドロジャスモネート、ジエチルマロネート、メチルベータナフチルケトン、マルトールイソブチレート、メントール、ラウリン酸、アセトイン、シンナミルアセテート、ベンジルアセテート、α−ターピネオール、クベボール、δカジネン等から選択される一種又は二種以上の混合物を用いることができる。 Deteriorating odor deodorants include indigestible dextrin, vanillin, maltol, ethyl maltol, ethyl octoate, 2-undecanone, ethyl pyruvate, methyl jasmonate, methyl dihydrojasmonate, diethyl malonate, methyl beta naphthyl One or a mixture of two or more selected from ketones, maltol isobutyrate, menthol, lauric acid, acetoin, cinnamyl acetate, benzyl acetate, α-terpineol, cubebole, δ-casinene and the like can be used.
劣化臭消臭剤の含有量は、柑橘類果実様飲料全質量に対して、0.0001mg/L以上100mg/L以下であり、より好ましくは、0.001mg/L以上10mg/L以下である。 The content of the deteriorated deodorant is 0.0001 mg / L or more and 100 mg / L or less, and more preferably 0.001 mg / L or more and 10 mg / L or less with respect to the total mass of the citrus fruit-like beverage.
〈酸味料〉
酸味料の具体例としては、アジピン酸、クエン酸、クエン酸(三)ナトリウム、グルコノデルタラクトン、グルコン酸、グルコン酸カリウム、グルコン酸ナトリウム、コハク酸、コハク酸一ナトリウム、コハク酸二ナトリウム、酢酸ナトリウム、DL−酒石酸、L−酒石酸、DL−酒石酸ナトリウム、L−酒石酸ナトリウム、二酸化炭素、乳酸、乳酸ナトリウム、氷酢酸、フマル酸、フマル酸一ナトリウム、DL−リンゴ酸、DL−リンゴ酸ナトリウム、リン酸及びこれらの塩(カリウム塩、ナトリウム塩)が挙げられる。酸味料は、pH調整剤としても使用可能である。
<Acidulant>
Specific examples of acidulants include adipic acid, citric acid, sodium citrate (tri) sodium, glucono delta lactone, gluconic acid, potassium gluconate, sodium gluconate, succinic acid, monosodium succinate, disodium succinate, Sodium acetate, DL-tartaric acid, L-tartaric acid, DL-sodium tartrate, L-sodium tartrate, carbon dioxide, lactic acid, sodium lactate, glacial acetic acid, fumaric acid, monosodium fumarate, DL-malic acid, DL-sodium malate , Phosphoric acid and salts thereof (potassium salt, sodium salt). The sour agent can also be used as a pH adjuster.
〈甘味料〉
甘味料としては、例えば、果糖、砂糖、果糖ぶどう糖液糖、ぶどう糖、麦芽糖、ショ糖、高果糖液糖、糖アルコール、オリゴ糖、はちみつ、サトウキビ搾汁液(黒糖蜜)、水飴、ステビア末、ステビア抽出物、羅漢果末、羅漢果抽出物、甘草末、甘草抽出物、ソーマトコッカスダニエリ種子末、ソーマトコッカスダニエリ種子抽出物などの天然甘味料や、アセスルファムカリウム、スクラロース、ネオテーム、アスパルテーム、サッカリンなどの人工甘味料などが挙げられる。
<sweetener>
Sweeteners include, for example, fructose, sugar, fructose glucose liquid sugar, glucose, maltose, sucrose, high fructose liquid sugar, sugar alcohol, oligosaccharide, honey, sugar cane juice (brown molasses), starch syrup, stevia powder, stevia Natural sweeteners such as extracts, Rahan fruit powder, Rahan fruit extract, licorice powder, licorice extract, Somatococcus danieri seed powder, Somatococcus danieri seed extract, and acesulfame potassium, sucralose, neotame, aspartame, saccharin, etc. Examples include artificial sweeteners.
また、高甘味度甘味料、糖類及び糖アルコールが挙げられる。高甘味度甘味料の具体例としては、アスパルテーム、アセスルファムカリウム(K)、キシリトール、グリチルリチン酸二ナトリウム、サッカリン、サッカリンカルシウム、サッカリンナトリウム、スクラロース、ネオテーム、アラビノース、カンゾウ抽出物、キシロース、ステビア、タウマチン、ラカンカ抽出物、ラムノース及びリボースが挙げられる。糖類の具体例としては、異性化糖、ブドウ糖、果糖、砂糖、麦芽糖及び乳糖が挙げられる。糖アルコールの具体例としては、還元麦芽糖水飴、エリスリトール、キシリトール及びマルチトールが挙げられる。 Also included are high intensity sweeteners, sugars and sugar alcohols. Specific examples of high-intensity sweeteners include aspartame, acesulfame potassium (K), xylitol, disodium glycyrrhizinate, saccharin, calcium saccharin, saccharin sodium, sucralose, neotame, arabinose, licorice extract, xylose, stevia, thaumatin, lacanca Extracts, rhamnose and ribose are mentioned. Specific examples of the saccharide include isomerized sugar, glucose, fructose, sugar, maltose and lactose. Specific examples of sugar alcohols include reduced maltose starch syrup, erythritol, xylitol, and maltitol.
〈色素〉
色素の具体例としては、カラメル、アントシアニン色素、フラボノイド色素、カロテノイド色素、キノン色素、ポリフィリン、ジケトン色素、ベタシアニン色素、アザフィロン色素、クチナシ色素等が挙げられる。
<Dye>
Specific examples of the dye include caramel, anthocyanin dye, flavonoid dye, carotenoid dye, quinone dye, porphyrin, diketone dye, betacyanine dye, azaphyrone dye, gardenia dye and the like.
(飲料)
柑橘類果実様飲料は、果汁飲料、野菜飲料、スポーツドリンク、ハチミツ飲料、豆乳、ビタミン補給飲料、ミネラル補給飲料、栄養ドリンク、滋養ドリンク、乳酸菌飲料、乳飲料などのソフト飲料;果汁入り炭酸飲料、乳類入り炭酸飲料、エキス入り飲料等の炭酸飲料;緑茶、紅茶、ウーロン茶、ハーブティー、ミルクティー、コーヒー飲料等の嗜好飲料、アルコール飲料;又はノンアルコール飲料のいずれであってよもよい。
(Beverage)
Citrus fruit-like beverages are juice drinks, vegetable drinks, sports drinks, honey drinks, soy milk, vitamin supplement drinks, mineral supplement drinks, nutrition drinks, nourishing drinks, lactic acid bacteria drinks, milk drinks, and other soft drinks; carbonated drinks with fruit juice, milk Carbonated beverages such as carbonated beverages containing beverages and beverages containing extracts; taste beverages such as green tea, black tea, oolong tea, herbal tea, milk tea, coffee beverages, alcoholic beverages; or non-alcoholic beverages.
ノンアルコール飲料は、実質的にアルコールを含まないアルコールテイストの飲料である。ノンアルコール飲料には、ノンアルコールビール(ビールテイスト飲料)、ノンアルコールワイン、ノンアルコールカクテル、ノンアルコール酎ハイ(酎ハイテイスト飲料)、ノンアルコール日本酒及びノンアルコール焼酎(焼酎テイスト飲料)等が含まれる。ノンアルコール飲料のアルコール濃度は、酒税法上は温度15度の時において原容量百分中に含有するエチルアルコールの容量が1%未満であると定義される。 A non-alcoholic beverage is a beverage with an alcoholic taste substantially free of alcohol. Non-alcoholic beverages include non-alcoholic beer (beer-taste beverages), non-alcoholic wines, non-alcoholic cocktails, non-alcoholic 酎 high (酎 high-taste beverages), non-alcoholic sake and non-alcoholic shochu (shochu-taste beverages), etc. . The alcohol concentration of a non-alcoholic beverage is defined as that the volume of ethyl alcohol contained in the original volume is less than 1% at a temperature of 15 degrees according to the liquor tax law.
アルコール飲料は、ビール、酎ハイ、カクテル、発泡酒等が挙げられる。ベースとなるアルコールは、飲料として許可されたアルコールであってよく、べースアルコールとしては、醸造酒又は蒸留酒(好ましい)であってよい。蒸留酒としては、好ましくは、焼酎、ウォッカ、ジン、ラム等であってよい。アルコール飲料は、そのアルコール含有量は特に限定されるものではないが、柑橘類果実様飲料の特性、酒税法等を考慮して適宜調整できる。アルコール含有量は30体積%以下、より好ましくは9体積%以下が好ましく、より好ましくは、3体積%以上9体積%以下、さらに好ましくは7体積%以上9体積%以下である。 Examples of alcoholic beverages include beer, strawberry high, cocktail, and sparkling liquor. The base alcohol may be an alcohol permitted as a beverage, and the base alcohol may be brewed liquor or distilled liquor (preferably). The distilled liquor may preferably be shochu, vodka, gin, rum and the like. The alcohol content of the alcoholic beverage is not particularly limited, but can be appropriately adjusted in consideration of the characteristics of the citrus fruit-like beverage, the liquor tax law, and the like. The alcohol content is 30% by volume or less, more preferably 9% by volume or less, more preferably 3% by volume or more and 9% by volume or less, and further preferably 7% by volume or more and 9% by volume or less.
〔柑橘類果実様飲料の製造方法〕
柑橘類果実様飲料の製造方法は、シトラールと、ノナナールとを混合してなり、
前記混合が、前記シトラールの含有量(mg/L)を「X」とし、
前記ノナナールの含有量(mg/L)を「Y」とした場合、下記数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
で表される関係を満たすように行われるものである。
[Method for producing citrus fruit-like beverage]
The method for producing a citrus fruit-like beverage is a mixture of citral and nonanal,
In the mixing, the content (mg / L) of the citral is “X”,
When the content (mg / L) of the nonanal is “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
It is performed so as to satisfy the relationship expressed by
より具体的な、柑橘類果実様飲料の製造態様は概説すると以下の通りである。シトラール及びノナナールと、任意成分と、飲用水(炭酸水)、必要に応じてベースアルコールとを所定の量で準備し、これらを混合する。次に、混合液を冷却し、必要に応じてカーボネーションを行う。その後、容器に充填・密封することにより、所望の柑橘類果実様香味の飲料を得ることができる。容器に充填する前に膜ろ過フィルターを用いてろ過してもよい。また、濃厚な状態で中間液を作成した後に、炭酸水を添加して飲料を調製してもよい。 A more specific production mode of the citrus fruit-like beverage is outlined as follows. Citral and nonanal, optional ingredients, drinking water (carbonated water), and base alcohol as required are prepared in predetermined amounts, and these are mixed. Next, the mixed solution is cooled, and carbonation is performed as necessary. Then, a desired citrus fruit-like beverage can be obtained by filling and sealing the container. You may filter using a membrane filtration filter before filling a container. Moreover, after creating an intermediate solution in a rich state, carbonated water may be added to prepare a beverage.
〔容器詰め飲料〕
別の好ましい態様によれば、柑橘類果実様飲料を容器に詰めた容器詰飲料を提案することができる。容器詰飲料とすることにより、柑橘類果実様香味感、とりわけ、柑橘類果実をもぎたて搾り立てした際の果汁感及び新鮮感を付与し、促進させると伴に、柑橘類果実様飲料の提供利便性、流通利便性、保存性、品質劣化防止を図ることが可能となる。
容器は、内容物が漏洩しない材料であれば、ビニール、プラスチック、ガラス、金属、紙、木又は皮等で、様々な形状で形成された容器に詰めることができる。より好ましい態様によれば、容器の内外に、光、熱、酸素、紫外線等を遮断するための素材(たとえば、金属箔)を備えたものであってよい。
[Contained beverage]
According to another preferred embodiment, a container-packed beverage in which a citrus fruit-like beverage is packed in a container can be proposed. Offering and promoting citrus fruit-like beverages by adding and promoting the citrus fruit-like flavor, especially the fruit juice and freshness when squeezed and squeezed citrus fruits Convenience, storage, and quality degradation can be prevented.
The container can be packed in various shapes made of vinyl, plastic, glass, metal, paper, wood, leather, or the like as long as the contents do not leak. According to a more preferred aspect, the container may be provided with a material (for example, a metal foil) for blocking light, heat, oxygen, ultraviolet rays and the like inside and outside the container.
以下の実施例により、本発明の内容を更に具体的に説明するが、本発明の範囲は下記実施例に限定して解釈されるものではない。また、以下の実施例は、本発明の実施態様の一例を示すものであるが、これら実施例により当業者は本発明の全ての範囲について容易に実施することができること当然に理解するものである。 The contents of the present invention will be described more specifically with reference to the following examples, but the scope of the present invention should not be construed as being limited to the following examples. In addition, the following examples show examples of embodiments of the present invention. However, it should be understood that those skilled in the art can easily implement the entire scope of the present invention by using these examples. .
〔分析〕
実施例、比較例の飲料中に含まれる各成分は、ガスクロマトグラフ質量分析(GC/MS)を用いて定量を行った。GC/MS分析の手順は以下の通りであった。
〔analysis〕
Each component contained in the beverages of Examples and Comparative Examples was quantified using gas chromatograph mass spectrometry (GC / MS). The procedure of GC / MS analysis was as follows.
(シトラール分析方法)
〈分析用試料調製〉
試料を5.0g秤量し、内部標準としてリナロール−d5を200μl添加した上で、45mLの水で希釈した。次にアセトニトリル浸漬および加熱にてコンディショニングを行ったTwister(PDMS,0.5mm×20mm)を希釈した試料に投入し、40℃2時間の撹拌吸着反応を行ったものを分析用試料として調製した。なお、試料調製は2点並行して行った。
(Citral analysis method)
<Sample preparation for analysis>
5.0 g of the sample was weighed, 200 μl of linalool-d5 was added as an internal standard, and diluted with 45 mL of water. Next, Twister (PDMS, 0.5 mm × 20 mm) that had been conditioned by acetonitrile immersion and heating was added to a diluted sample, and a mixture subjected to a stirring adsorption reaction at 40 ° C. for 2 hours was prepared as an analytical sample. Sample preparation was performed in parallel at two points.
〈定量方法〉
分析用試料中のシトラールの量は、内部標準(リナロール−d5)とのピーク面積比から計算した。また、同一試料について2点並行で行った分析値の平均値を試料中の成分量であるものとして定量を行った。
<Quantitative method>
The amount of citral in the analytical sample was calculated from the peak area ratio with the internal standard (linalool-d5). Moreover, it quantified by making the average value of the analysis value performed in parallel about 2 points | pieces about the same sample into what is the amount of components in a sample.
〈GC条件〉
装置:測定には昇温気化型注入口(CIS4,Gerstel社製)、加熱脱着ユニット(TDU, Gerstel社製)およびLTMカラム(1st:DB−WAX,20m×0.18mm;0.3μm、2nd:DB−5,10m×0.18mm;0.4μm,Agilent Technologies社製)を搭載した7890B GC System(Agilent Technologies社製)、5977A MSD(Agilent Technologies社製)を使用した。
TDU:20℃(1min)−(720℃/min)−250℃(3min)
CIS:−50℃(1.5min)−(12℃/min)−240℃(60min)
スプリット比:30:1
注入口圧:508.28kPa
ベント圧:314.11kPa
1stカラム温度:40℃(3min)−(5℃/min)−180℃(0min)
2ndカラム温度:40℃(31min)−(5℃/min)−200℃(0min)
MSD:Scan mode,m/z 29−230, 20Hz, EI
<GC condition>
Apparatus: For measurement, temperature rising vaporization type inlet (CIS4, manufactured by Gerstel), heat desorption unit (TDU, manufactured by Gerstel) and LTM column (1st: DB-WAX, 20 m × 0.18 mm; 0.3 μm, 2nd) : DB-5, 10 m × 0.18 mm; 0.4 μm, 7890B GC System (manufactured by Agilent Technologies) equipped with Agilent Technologies), 5977A MSD (manufactured by Agilent Technologies) was used.
TDU: 20 ° C. (1 min) − (720 ° C./min)−250° C. (3 min)
CIS: -50 ° C (1.5 min)-(12 ° C / min)-240 ° C (60 min)
Split ratio: 30: 1
Inlet pressure: 508.28 kPa
Vent pressure: 314.11 kPa
1st column temperature: 40 ° C. (3 min) − (5 ° C./min)−180° C. (0 min)
2nd column temperature: 40 ° C. (31 min) − (5 ° C./min)−200° C. (0 min)
MSD: Scan mode, m / z 29-230, 20 Hz, EI
(ノナナール分析方法)
「ノナナール」は、非特許文献(Vesely, P. et al.; Analysis of aldehydes in beer using solid−phase microextraction with on−fiber derivatization and gass chromatography/mass spectrometry. J. Agric. Food Chem. 2003, 51, 6941−6944)に記載された方法に基づいて分析した。
(Nonanar analysis method)
“Nonal” is described in non-patent literature (Vesery, P. et al .; Analysis of aldehydes in beer using solid-phase m ssr. Et. 6941-6944) was analyzed.
即ち、内部標準物質としてペンタナールを使用し、試料を固相マイクロ抽出(SPMEファイバー)GC/MS法により、測定した。具体的には、ニードルに結合された固相を有する市販のSPMEファイバー(SPELCO社製、PDMS/DVB,65μm×10mm)を用意し、これを誘導体化試薬であるPFBOA(o−(2,3,4,5,6−ペンタフルオロベンジル)−ヒドロキシルアミン)の溶液10mlを採取した20ml容バイアルのセプタムに貫通させることにより、ヘッドスペースにファイバーを露出させ、例えば50℃、10分間で60ppmのPFBOAをSPMEファイバーに固定化した。 That is, pentanal was used as an internal standard substance, and a sample was measured by solid phase microextraction (SPME fiber) GC / MS method. Specifically, a commercially available SPME fiber (manufactured by SPELCO, PDMS / DVB, 65 μm × 10 mm) having a solid phase bonded to a needle is prepared, and this is used as a derivatization reagent PFBOA (o- (2,3 , 4,5,6-pentafluorobenzyl) -hydroxylamine) was passed through a septum of a 20 ml vial collected to expose the fibers in the headspace, eg 60 ppm PFBOA at 50 ° C. for 10 minutes. Was immobilized on SPME fiber.
次に、PFBOAを固定化したSPMEファイバーを、試料溶液0.2g及び水(純度が高いヘキサン洗浄水等が好ましい)9.8gを採取した20ml容バイアルのセプタムに貫通させることにより、ヘッドスペースにSPMEファイバーを露出させて、例えば50℃、60分程度反応させ、固定化されているPFBOAと、ノナナールとの間でオキシム化反応を進行させ、誘導体を形成させた。このようにして、目的成分であるノナナールの誘導化物の抽出を行った。 Next, the SPME fiber in which PFBOA is immobilized is passed through a septum of a 20 ml vial in which 0.2 g of a sample solution and 9.8 g of water (preferably high-purity hexane washing water or the like) is collected, so that the headspace can be obtained. The SPME fiber was exposed and reacted, for example, at 50 ° C. for about 60 minutes, and an oxime reaction was allowed to proceed between immobilized PFBOA and nonanal to form a derivative. In this way, the derivative of nonanal, which is the target component, was extracted.
得られた誘導体化物が固定されたSPMEファイバーをGC/MSに注入し、ノナナールを測定した。GC条件は、DB−5ms(30m,0.25mmID,0.50μmF.T) (J&W社製)を用いて、スプリットレス法で注入し、40℃で2分保持した後、10℃/分で140℃まで昇温し、7℃/minで250℃まで昇温、3分保持した後、12℃/minで300℃まで昇温し、300℃にて5分間保持した。分析用試料中のノナナールの量は、内部標準ペンタナールとの面積比から計算した。ここでは、ノナナールのターゲットイオンm/z239を用いて、ペンタナールのターゲットイオン m/z239を用いたピークとの面積比から計算した。 The SPME fiber to which the obtained derivatized product was fixed was injected into GC / MS, and nonanal was measured. The GC conditions were DB-5ms (30 m, 0.25 mm ID, 0.50 μm FT) (manufactured by J & W), injected by the splitless method, held at 40 ° C. for 2 minutes, and then at 10 ° C./minute. The temperature was raised to 140 ° C., raised to 250 ° C. at 7 ° C./min, held for 3 minutes, then raised to 300 ° C. at 12 ° C./min, and held at 300 ° C. for 5 minutes. The amount of nonanal in the analytical sample was calculated from the area ratio with the internal standard pentanal. Here, the calculation was performed using the nonanal target ion m / z 239 and the area ratio to the peak using the pentanal target ion m / z 239.
〔飲料調製〕
下記処方に従って、実施例と比較例による柑橘類果実様アルコール飲料を調製した。
[Beverage preparation]
According to the following prescription, the citrus fruit-like alcoholic beverage by an Example and a comparative example was prepared.
(参考例0:対照)
下記組成表にある通り、レモン風味の炭酸アルコール飲料を調製し、参考例0(対照例)とした。飲料のpHは、3.4であった。ガス圧は2.4〜2.7volに調製した。pHは東亜ディーケーケー社製のpHメーター HM−30Rを用いて測定した。
(Reference Example 0: Control)
As shown in the following composition table, a lemon-flavored carbonated alcoholic beverage was prepared as Reference Example 0 (control example). The pH of the beverage was 3.4. The gas pressure was adjusted to 2.4 to 2.7 vol. The pH was measured using a pH meter HM-30R manufactured by Toa DKK Corporation.
〈組成表〉
95.3%アルコール 96.5ml/L(全体で9.20%)
レモン香料 0.05g/L
(シトラール0.3mg/L;ノナナール0.13mg/L)
クエン酸 4g/L
クエン酸ナトリウム 1.7g/L
アセスルファムK 0.1g/L
スクラロース 0.012g/L
<Composition table>
95.3% alcohol 96.5 ml / L (9.20% overall)
Lemon flavor 0.05g / L
(Citral 0.3 mg / L; Nonanal 0.13 mg / L)
Citric acid 4g / L
Sodium citrate 1.7 g / L
Acesulfame K 0.1g / L
Sucralose 0.012 g / L
(実施例及び比較例)
実施例及び比較例は、シトラールと、ノナナールとの添加量を、下記〔表1〕及び〔表2〕の組成表に従って処方した以外は、参考例0と同様にして、レモン風味のアルコール飲料を調製した。
(Examples and Comparative Examples)
In Examples and Comparative Examples, lemon-flavored alcoholic beverages were prepared in the same manner as in Reference Example 0, except that the addition amounts of citral and nonanal were prescribed according to the composition tables of [Table 1] and [Table 2] below. Prepared.
〔評価試験1:含有量対比〕
実施例と比較例における、シトラール含有量と、ノナナール含有量を下記表1に記載した。
[Evaluation Test 1: Contrast with Content]
Citral content and nonanal content in Examples and Comparative Examples are shown in Table 1 below.
〔評価試験2:官能評価試験〕
食品官能評価能力のある男女合わせて13名のパネルにより、実施例及び比較例のアルコール飲料を以下の基準で評価し、その平均値を得て、その結果を、下記表2に記載した。
[Evaluation Test 2: Sensory Evaluation Test]
The alcohol beverages of Examples and Comparative Examples were evaluated according to the following criteria by a panel of 13 men and women with food sensory evaluation ability, and the average values thereof were obtained. The results are shown in Table 2 below.
(評価基準1:レモン果汁感)
レモン果汁感は、レモンを搾った際のレモン香味として、以下の評価基準で評価して平均値を下記〔表2〕に記載した。
評価点1:レモン果汁感が極めて弱かった。
評価点2:レモン果汁感が弱かった。
評価点3:参考例0のレモン果汁感と同様であった。
評価点4:本来のレモン果汁感が強かった。
評価点5:本来のレモン果汁感が極めて強かった。
(Evaluation criteria 1: Lemon juice feeling)
The feeling of lemon juice was evaluated according to the following evaluation criteria as the lemon flavor when squeezing lemon, and the average value was described in the following [Table 2].
Evaluation point 1: The feeling of lemon juice was extremely weak.
Evaluation point 2: Lemon juice feeling was weak.
Evaluation point 3: It was the same as the lemon juice feeling of Reference Example 0.
Evaluation point 4: The original lemon juice feeling was strong.
Evaluation point 5: The original lemon juice feeling was extremely strong.
(評価基準2:レモン新鮮感(フレッシュ感))
レモン新鮮感は、レモンをもぎたて搾り立ての爽やかなレモン香味として以下の評価基準で評価して平均値を下記〔表2〕に記載した。
評価点1:爽やかなレモン香味感が極めて弱かった。
評価点2:爽やかなレモン香味感が弱かった。
評価点3:参考例0の爽やかなレモン香味感と同様であった。
評価点4:本来の爽やかなレモン香味感が強かった。
評価点5:本来の爽やかなレモン香味感が極めて強かった。
(Evaluation criteria 2: Lemon freshness (freshness))
The freshness of lemon was evaluated according to the following evaluation criteria as a fresh lemon flavor with freshly squeezed lemon, and the average value is shown in Table 2 below.
Evaluation point 1: Refreshing lemon flavor was extremely weak.
Evaluation point 2: Refreshing lemon flavor was weak.
Evaluation point 3: It was the same as the refreshing lemon flavor of Reference Example 0.
Evaluation point 4: The original refreshing lemon flavor was strong.
Evaluation point 5: The original refreshing lemon flavor was extremely strong.
〔総合評価〕
実施例1は、参考例0と比較して、果汁感が感じられた。
実施例2は、参考例0と比較して、果汁感、レモンキャンディな感じ、ボディ感が感じられた。
実施例3は、参考例0と比較して、レモンの皮の感じ、ボディ感、果汁感が感じられた。
実施例4は、参考例0と比較して、果汁感、新鮮感、レモンスカッシュ的な感じが感じられた。
実施例5は、参考例0と比較して、果汁感、新鮮感が感じられた。
実施例6は、参考例0と比較して、トップのレモン感、レモンの皮の感じ、新鮮感、グリーン感が感じられた。
〔Comprehensive evaluation〕
In Example 1, a fruit juice feeling was felt as compared with Reference Example 0.
In Example 2, as compared with Reference Example 0, a fruit juice feeling, a lemon candy feeling, and a body feeling were felt.
In Example 3, compared to Reference Example 0, a feeling of lemon peel, a feeling of body, and a feeling of fruit juice were felt.
In Example 4, as compared with Reference Example 0, a fruit juice feeling, a fresh feeling, and a lemon squash-like feeling were felt.
In Example 5, compared with Reference Example 0, a fruit juice feeling and a fresh feeling were felt.
In Example 6, compared to Reference Example 0, the top lemon feeling, lemon peel feeling, freshness, and green feeling were felt.
比較例1は、参考例0と比較して、溶媒臭がし、苦みがあり、カメムシ的なにおいが感じられた。
比較例2は、参考例0と比較して、苦みが認められた。
比較例3は、参考例0と比較して、ファッティ、オイリーな香りが強く認められた。
比較例4は、参考例0と比較して、グリーンでオイリーな感じが強く感じられた。
比較例5は、参考例0と比較して、エタノール臭や苦味が感じられた。
比較例6は、参考例0と比較して、レモン香気が弱く感じられた。
比較例7は、参考例0と比較して、人工的な香味がし、加熱臭やビタミン臭が感じられた。
Compared with Reference Example 0, Comparative Example 1 had a solvent odor, bitterness, and a stink bug smell.
In Comparative Example 2, bitterness was observed compared to Reference Example 0.
In Comparative Example 3, a fatty and oily fragrance was strongly recognized as compared with Reference Example 0.
In Comparative Example 4, compared to Reference Example 0, a green and oily feeling was strongly felt.
In Comparative Example 5, ethanol odor and bitterness were felt as compared with Reference Example 0.
In Comparative Example 6, the lemon flavor was felt weaker than that of Reference Example 0.
Compared with Reference Example 0, Comparative Example 7 had an artificial flavor and felt a heated odor and a vitamin odor.
〔結果〕
シトラールと、ノナナールと、上記数式1及び数式2で表される関係を満たす含有量で含有した柑橘類果実様飲料によれば、柑橘類果実様香味感、とりわけ、柑橘類果実をもぎたて搾り立てした際の果汁感及び爽やかな新鮮感を、付与し、促進させることが理解された。
〔result〕
According to the citrus fruit-like beverage containing citral, nonanal, and a content satisfying the relationship represented by the above formulas 1 and 2, the fruit juice when squeezing and squeezing the citrus fruit, in particular, the citrus fruit It was understood that it gives and promotes a feeling and a refreshing freshness.
Claims (6)
シトラールと、ノナナールとを含んでなり、
前記シトラールの含有量(mg/L)を「X」とし、
前記ノナナールの含有量(mg/L)を「Y」とした場合、以下の数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
である関係を満たすものである、柑橘類果実様飲料。 A citrus fruit-like beverage,
Comprising citral and nonanal,
The content of citral (mg / L) is “X”,
When the content (mg / L) of the nonanal is “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
A citrus fruit-like beverage that satisfies this relationship.
前記数式2が、0.23≦Y≦0.43である、請求項1に記載の柑橘類果実様飲料。 Formula 1 is 4.5 ≦ X ≦ 10, and
The citrus fruit-like beverage according to claim 1, wherein Formula 2 is 0.23 ≦ Y ≦ 0.43.
シトラールと、ノナナールとを混合してなり、
前記混合が、前記シトラールの含有量(mg/L)を「X」とし、
前記ノナナールの含有量(mg/L)を「Y」とした場合、以下の数式1及び数式2:
3≦X≦10 (数式1)
0.23≦Y≦0.43 (数式2)
である関係を満たすように行われる、柑橘類果実様飲料の製造方法。 A method for producing a citrus fruit-like beverage,
A mixture of citral and nonanal,
In the mixing, the content (mg / L) of the citral is “X”,
When the content (mg / L) of the nonanal is “Y”, the following formulas 1 and 2:
3 ≦ X ≦ 10 (Formula 1)
0.23 ≦ Y ≦ 0.43 (Formula 2)
A method for producing a citrus fruit-like beverage, which is carried out so as to satisfy the relationship.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016158817A JP6152458B1 (en) | 2016-08-12 | 2016-08-12 | Citrus fruit-like beverage and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2016158817A JP6152458B1 (en) | 2016-08-12 | 2016-08-12 | Citrus fruit-like beverage and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP6152458B1 JP6152458B1 (en) | 2017-06-21 |
JP2018023338A true JP2018023338A (en) | 2018-02-15 |
Family
ID=59081961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016158817A Active JP6152458B1 (en) | 2016-08-12 | 2016-08-12 | Citrus fruit-like beverage and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP6152458B1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018108097A (en) * | 2018-02-26 | 2018-07-12 | サントリーホールディングス株式会社 | Container packed lemon-flavored concentrated alcoholic beverage |
JP2020137443A (en) * | 2019-02-27 | 2020-09-03 | サッポロホールディングス株式会社 | Lemon flavor beverage and flavor improving method |
WO2021235360A1 (en) * | 2020-05-18 | 2021-11-25 | 高砂香料工業株式会社 | Fragrance composition, and food and beverage |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0838096A (en) * | 1994-07-27 | 1996-02-13 | Ogawa Koryo Kk | Perfume composition |
JPH11209294A (en) * | 1998-01-20 | 1999-08-03 | Karita Takahisa | Parasympathomimetic agent containing essential oil as active ingredient |
JP2002180081A (en) * | 2000-12-14 | 2002-06-26 | Ogawa & Co Ltd | Inhibitor and method for inhibiting against generation of deterioration odor of citral |
JP2004018613A (en) * | 2002-06-14 | 2004-01-22 | Ogawa & Co Ltd | Inhibitor for formation of off-odor from citral or citral-containing preparation |
JP2004168936A (en) * | 2002-11-21 | 2004-06-17 | Kiyomitsu Kawasaki | Citrus-note perfume composition |
JP2007282593A (en) * | 2006-04-19 | 2007-11-01 | T Hasegawa Co Ltd | Heat-and light-stable acid drink containing citral |
JP2008031230A (en) * | 2006-07-27 | 2008-02-14 | Soda Aromatic Co Ltd | Agent for suppressing degradation smell of citral |
JP2008194015A (en) * | 2007-02-16 | 2008-08-28 | Sanei Gen Ffi Inc | Citrus-containing food and drink additive comprising kahweofuran or its related variety |
JP2009203438A (en) * | 2008-02-29 | 2009-09-10 | T Hasegawa Co Ltd | Citrus flavor reinforcing agent |
JP2015123008A (en) * | 2013-12-26 | 2015-07-06 | キリン株式会社 | Lemon flavor beverage |
JP2015180715A (en) * | 2013-12-17 | 2015-10-15 | 三栄源エフ・エフ・アイ株式会社 | Degradation odor masking agent for citral or citral-containing article and degradation odor masking method |
JP2016116493A (en) * | 2014-12-22 | 2016-06-30 | サントリー食品インターナショナル株式会社 | Lemon juice-containing beverage |
-
2016
- 2016-08-12 JP JP2016158817A patent/JP6152458B1/en active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0838096A (en) * | 1994-07-27 | 1996-02-13 | Ogawa Koryo Kk | Perfume composition |
JPH11209294A (en) * | 1998-01-20 | 1999-08-03 | Karita Takahisa | Parasympathomimetic agent containing essential oil as active ingredient |
JP2002180081A (en) * | 2000-12-14 | 2002-06-26 | Ogawa & Co Ltd | Inhibitor and method for inhibiting against generation of deterioration odor of citral |
JP2004018613A (en) * | 2002-06-14 | 2004-01-22 | Ogawa & Co Ltd | Inhibitor for formation of off-odor from citral or citral-containing preparation |
JP2004168936A (en) * | 2002-11-21 | 2004-06-17 | Kiyomitsu Kawasaki | Citrus-note perfume composition |
JP2007282593A (en) * | 2006-04-19 | 2007-11-01 | T Hasegawa Co Ltd | Heat-and light-stable acid drink containing citral |
JP2008031230A (en) * | 2006-07-27 | 2008-02-14 | Soda Aromatic Co Ltd | Agent for suppressing degradation smell of citral |
JP2008194015A (en) * | 2007-02-16 | 2008-08-28 | Sanei Gen Ffi Inc | Citrus-containing food and drink additive comprising kahweofuran or its related variety |
JP2009203438A (en) * | 2008-02-29 | 2009-09-10 | T Hasegawa Co Ltd | Citrus flavor reinforcing agent |
JP2015180715A (en) * | 2013-12-17 | 2015-10-15 | 三栄源エフ・エフ・アイ株式会社 | Degradation odor masking agent for citral or citral-containing article and degradation odor masking method |
JP2015123008A (en) * | 2013-12-26 | 2015-07-06 | キリン株式会社 | Lemon flavor beverage |
JP2016116493A (en) * | 2014-12-22 | 2016-06-30 | サントリー食品インターナショナル株式会社 | Lemon juice-containing beverage |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018108097A (en) * | 2018-02-26 | 2018-07-12 | サントリーホールディングス株式会社 | Container packed lemon-flavored concentrated alcoholic beverage |
JP7054352B2 (en) | 2018-02-26 | 2022-04-13 | サントリーホールディングス株式会社 | Lemon-flavored packaged concentrated alcoholic beverage |
JP2020137443A (en) * | 2019-02-27 | 2020-09-03 | サッポロホールディングス株式会社 | Lemon flavor beverage and flavor improving method |
JP7324590B2 (en) | 2019-02-27 | 2023-08-10 | サッポロビール株式会社 | Lemon-flavored beverage and method for improving flavor |
WO2021235360A1 (en) * | 2020-05-18 | 2021-11-25 | 高砂香料工業株式会社 | Fragrance composition, and food and beverage |
CN115666267A (en) * | 2020-05-18 | 2023-01-31 | 高砂香料工业株式会社 | Spice composition and drink food |
EP4154732A4 (en) * | 2020-05-18 | 2023-11-08 | Takasago International Corporation | Fragrance composition, and food and beverage |
Also Published As
Publication number | Publication date |
---|---|
JP6152458B1 (en) | 2017-06-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7138144B2 (en) | Clear beverage containing fruit flavor | |
JP6353130B2 (en) | Citrus fruit-like flavor composition with improved residual amount of citral and product containing the same | |
JP7063626B2 (en) | Citrus fruit-like beverages, concentrates for citrus fruit-like beverages, and methods for producing them. | |
JP7133972B2 (en) | Alcoholic Beverage, Irritant Taste Mitigating Agent for Alcoholic Beverage, Method for Mitigating Irritant Taste of Alcoholic Beverage | |
JP5249455B1 (en) | Containerized carbonated drink and method for producing the same, and fruit feeling improvement method for containerized carbonated drink | |
JP6152458B1 (en) | Citrus fruit-like beverage and method for producing the same | |
JP2022186896A (en) | Packaged carbonated alcoholic beverage and method for producing the same | |
JP6280264B1 (en) | Citrus fruit-like beverage and method for producing the same | |
JP7274847B2 (en) | Method for improving flavor of beverage | |
JP6198906B1 (en) | Grapefruit fruit-like beverage and method for producing the same | |
JP2018027022A (en) | Monoterpene degradation inhibition composition, monoterpene-containing flavor composition and product containing the same | |
JP7299752B2 (en) | Beverage and method for improving palatability of beverage | |
JP6608087B1 (en) | Carbonated beverage and method for improving tea flavor of carbonated beverage | |
JP6207692B1 (en) | Pinene conversion composition, pinene-containing flavor composition, and products containing these | |
JP2022171024A (en) | Carbonated alcoholic beverage and method for producing the same | |
JP6798819B2 (en) | A composition for producing trans-2-hexenal, a flavor composition for producing trans-2-hexenal, and a product containing these. | |
JP7002365B2 (en) | Plum alcoholic beverage, ume alcoholic beverage base, ume alcoholic beverage manufacturing method, and ume alcoholic beverage flavor improvement method | |
JP7313531B1 (en) | Citrus-flavored beverage and method for improving flavor of citrus-flavored beverage | |
JP7189712B2 (en) | citrus flavored beverage | |
WO2022249778A1 (en) | Container-packaged alcoholic beverage and method for producing same | |
JP2023035494A (en) | Packed concentrated beverage and packed beverage | |
JP2022135386A (en) | Acetic acid-containing food or drink | |
JP2019054760A (en) | An ume alcoholic beverage, an ume alcoholic beverage base, a method for producing an ume alcoholic beverage, a method for producing an ume alcoholic beverage base, and a method for improving the flavor of an ume alcoholic beverage | |
JP2018143194A (en) | Carbonated alcoholic beverage and method for producing the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170509 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170529 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6152458 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |