JP2018004505A - Hydrogen gas detection tape - Google Patents

Hydrogen gas detection tape Download PDF

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JP2018004505A
JP2018004505A JP2016133174A JP2016133174A JP2018004505A JP 2018004505 A JP2018004505 A JP 2018004505A JP 2016133174 A JP2016133174 A JP 2016133174A JP 2016133174 A JP2016133174 A JP 2016133174A JP 2018004505 A JP2018004505 A JP 2018004505A
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hydrogen gas
hydrogen
detection
layer
agent
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JP6669601B2 (en
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文彦 福地
Fumihiko Fukuchi
文彦 福地
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Tokyo Gas Co Ltd
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Tokyo Gas Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a hydrogen gas detection tape that has improved visibility.SOLUTION: A hydrogen gas detection tape 100 has a hydrogen detection agent 112 that discolors on contact with a hydrogen gas, and a light accumulation agent 114 that accumulates light energy to emit light. The structure including the light accumulation agent 114 makes it possible to improve the visibility of the hydrogen gas detection tape 100 itself, and the hydrogen detection agent 112.SELECTED DRAWING: Figure 1

Description

本発明は、水素ガスを検知する水素ガス検知テープに関する。   The present invention relates to a hydrogen gas detection tape that detects hydrogen gas.

水素ステーション、水素ガス製造プラント、水素ガス利用プラント等の水素ガスを取り扱う設備では、安全性を確保するために、水素ガスの漏洩を検知する水素ガス検知センサが設置されている。   In facilities that handle hydrogen gas, such as hydrogen stations, hydrogen gas production plants, and hydrogen gas utilization plants, a hydrogen gas detection sensor that detects leakage of hydrogen gas is installed to ensure safety.

一般に、水素ステーションなどにおいては、定位置に設置された水素ガス検知センサによって、極めて低濃度の水素ガスが漏洩した場合であっても、その漏洩を検知することができ、さらに、その監視もできる。また、水素ガス検知センサによって所定濃度以上の水素ガスの漏洩が検知されると、自動的にシステムがシャットダウンし、さらなる漏洩の防止が図られている。   In general, in a hydrogen station or the like, even when a very low concentration of hydrogen gas is leaked by a hydrogen gas detection sensor installed at a fixed position, the leak can be detected and further monitored. . Further, when the hydrogen gas detection sensor detects leakage of hydrogen gas having a predetermined concentration or more, the system is automatically shut down to prevent further leakage.

しかし、極めて低濃度の水素ガスが検知された場合に、その漏洩箇所を詳細に特定するためには、さらに、操作員が配管や機器の設置場所に赴き、携帯型の水素検知器などを用いて漏洩箇所を特定し、その対応措置を行う必要があり、簡便に漏洩箇所を特定する手段がなかった。   However, if an extremely low concentration of hydrogen gas is detected, an operator can go to the installation location of the piping and equipment and use a portable hydrogen detector, etc., in order to pinpoint the location of the leak. Therefore, it was necessary to identify the leak location and take countermeasures, and there was no simple way to identify the leak location.

これに関連する技術として、水素ガスと反応することで変色する水素ガス検知テープを、配管や容器等の水素ガスの漏洩が生じ得る箇所に貼付する技術(例えば、特許文献1)が開発されている。   As a technology related to this, a technology (for example, Patent Document 1) has been developed in which a hydrogen gas detection tape that changes color by reacting with hydrogen gas is attached to a location where leakage of hydrogen gas such as a pipe or container may occur. Yes.

特開平8−253742号公報JP-A-8-253742

ところで、上記水素ガスを取り扱う設備において、配管や容器は暗所に設置されることが多い。このため、上記特許文献1の水素ガス検知テープでは、テープ自体の存在を確認したり、テープの変色を確認したりするために、配管や容器が収容される空間全体を照明で照らしたり、テープ自体をライトで照らしたりする必要がある。   By the way, in the facility for handling the hydrogen gas, pipes and containers are often installed in a dark place. For this reason, in the hydrogen gas detection tape of the above-mentioned patent document 1, in order to confirm the existence of the tape itself or to confirm the discoloration of the tape, the entire space in which the pipes and containers are accommodated is illuminated with illumination, or the tape It is necessary to light itself.

本発明は、このような課題に鑑み、視認性を向上させることが可能な水素ガス検知テープを提供することを目的としている。   In view of such a problem, an object of the present invention is to provide a hydrogen gas detection tape capable of improving visibility.

上記課題を解決するために、本発明の水素ガス検知テープは、水素ガスの接触により変色する水素検知剤および蓄光剤を含む。   In order to solve the above problems, the hydrogen gas detection tape of the present invention includes a hydrogen detection agent and a phosphorescent agent that change color when contacted with hydrogen gas.

また、前記水素検知剤が含まれる水素検知層と、前記蓄光剤が含まれる蓄光層と、を備えるとしてもよい。   Moreover, you may provide the hydrogen detection layer in which the said hydrogen detection agent is contained, and the luminous layer in which the said luminous agent is contained.

また、粘着層を備えるとしてもよい。   Further, an adhesive layer may be provided.

本発明によれば、視認性を向上させることが可能となる。   According to the present invention, it is possible to improve visibility.

第1の実施形態にかかる水素ガス検知テープを説明する図である。It is a figure explaining the hydrogen gas detection tape concerning a 1st embodiment. 変形例にかかる水素ガス検知テープを説明する図である。It is a figure explaining the hydrogen gas detection tape concerning a modification. 第2の実施形態にかかる水素ガス検知テープを説明する図である。It is a figure explaining the hydrogen gas detection tape concerning 2nd Embodiment.

以下に添付図面を参照しながら、本発明の好適な実施形態について詳細に説明する。かかる実施形態に示す寸法、材料、その他具体的な数値等は、発明の理解を容易とするための例示にすぎず、特に断る場合を除き、本発明を限定するものではない。なお、本明細書および図面において、実質的に同一の機能、構成を有する要素については、同一の符号を付することにより重複説明を省略し、また本発明に直接関係のない要素は図示を省略する。   Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. The dimensions, materials, and other specific numerical values shown in the embodiments are merely examples for facilitating the understanding of the invention, and do not limit the present invention unless otherwise specified. In the present specification and drawings, elements having substantially the same function and configuration are denoted by the same reference numerals, and redundant description is omitted, and elements not directly related to the present invention are not illustrated. To do.

(第1の実施形態:水素ガス検知テープ100)
図1は、第1の実施形態にかかる水素ガス検知テープ100を説明する図であり、図1(a)は水素ガス検知テープ100の平面図を示し、図1(b)は図1(a)のIb−Ib線断面の拡大図を示す。なお、図1(b)中、水素検知剤112を黒い丸で示し、蓄光剤114を白い丸で示すが、理解を容易にするために、実際より大きく記載している。
(First embodiment: hydrogen gas detection tape 100)
1A and 1B are diagrams for explaining a hydrogen gas detection tape 100 according to the first embodiment. FIG. 1A is a plan view of the hydrogen gas detection tape 100, and FIG. ) Is an enlarged view of a cross section taken along line Ib-Ib. In FIG. 1B, the hydrogen detection agent 112 is indicated by a black circle and the phosphorescent agent 114 is indicated by a white circle. However, in order to facilitate understanding, the hydrogen detection agent 114 is shown larger than the actual size.

図1に示すように、水素ガス検知テープ100は、検知層110と、粘着層120とを含んで構成される。   As shown in FIG. 1, the hydrogen gas detection tape 100 includes a detection layer 110 and an adhesive layer 120.

検知層110は、水素検知剤112と、蓄光剤114とが、樹脂116に分散された層である。水素検知剤112は、水素ガスが接触すると変色する物質であり、例えば、酸化パラジウム、酸化パラジウム水化物、酸化タングステン等、既存の物質を利用することができる。   The detection layer 110 is a layer in which a hydrogen detection agent 112 and a phosphorescent agent 114 are dispersed in a resin 116. The hydrogen detection agent 112 is a substance that changes color when contacted with hydrogen gas. For example, an existing substance such as palladium oxide, palladium oxide hydrate, or tungsten oxide can be used.

蓄光剤114は、光エネルギー(可視光、紫外線等を含む電磁波のエネルギー)を蓄えて発光する物質であり、例えば、硫化物系の蓄光性蛍光体(例えば硫化亜鉛)、アルミン酸塩系蓄光性蛍光体(例えばアルミン酸ストロンチウム)等、既存の物質を利用することができる。   The phosphorescent agent 114 is a substance that stores light energy (electromagnetic energy including visible light, ultraviolet rays, etc.) and emits light. For example, a sulfide-based phosphorescent phosphor (for example, zinc sulfide), an aluminate-based phosphorescent material. Existing materials such as phosphors (eg, strontium aluminate) can be used.

樹脂116は、例えば、ポリイソシアネート化合物とポリオール樹脂とを主成分とする2液型ウレタン、アクリル樹脂、アルキド樹脂、ポリウレタン樹脂等で構成される。   The resin 116 is composed of, for example, a two-component urethane, an acrylic resin, an alkyd resin, a polyurethane resin, or the like mainly composed of a polyisocyanate compound and a polyol resin.

粘着層120は、水素ガスが漏洩し得る箇所(もしくは、その近傍)に検知層110を固定するための層であり、検知層110の一方の面(図1中、Z軸方向の一方の面)に当接して設けられる。粘着層120は、例えば、非架橋型粘着性樹脂組成物や架橋硬化型粘着性樹脂組成物で構成される。なお、非架橋型粘着性樹脂組成物は、例えば、塩化ビニル樹脂、ポリウレタン樹脂、ポリエステル樹脂、ゴム、ポリアミド樹脂、酢酸ビニル樹脂、アクリル樹脂、エチレン酢酸ビニル共重合体、塩化ビニル酢酸ビニル共重合体であり、架橋硬化型粘着性樹脂組成物は、尿素樹脂、メラミン樹脂、ポリイソシアネート化合物等の硬化剤をエポキシ樹脂、フェノール樹脂、アクリル樹脂、ポリエステル樹脂等の基体樹脂に混合してなる組成物である。   The adhesive layer 120 is a layer for fixing the detection layer 110 at a location (or the vicinity thereof) where hydrogen gas can leak, and one surface of the detection layer 110 (one surface in the Z-axis direction in FIG. 1). ). The adhesive layer 120 is composed of, for example, a non-crosslinked adhesive resin composition or a crosslinked curable adhesive resin composition. The non-crosslinking type adhesive resin composition includes, for example, vinyl chloride resin, polyurethane resin, polyester resin, rubber, polyamide resin, vinyl acetate resin, acrylic resin, ethylene vinyl acetate copolymer, vinyl chloride vinyl acetate copolymer. The crosslink curable adhesive resin composition is a composition obtained by mixing a curing agent such as urea resin, melamine resin, or polyisocyanate compound with a base resin such as epoxy resin, phenol resin, acrylic resin, or polyester resin. is there.

以上説明したように、本実施形態にかかる水素ガス検知テープ100によれば、蓄光剤114を有する構成により、水素ガス検知テープ100自体、および、水素検知剤112の視認性を向上させることができる。したがって、水素ガス検知テープ100自体の存在の確認作業が容易になるとともに、水素検知剤112の変色の有無を容易に確認することが可能となる。   As described above, according to the hydrogen gas detection tape 100 according to the present embodiment, the configuration having the phosphorescent agent 114 can improve the visibility of the hydrogen gas detection tape 100 itself and the hydrogen detection agent 112. . Therefore, it becomes easy to confirm the presence of the hydrogen gas detection tape 100 itself, and it is possible to easily confirm the presence or absence of discoloration of the hydrogen detection agent 112.

なお、水素ガス検知テープ100は、水素ガスが漏洩し得る箇所(配管の継手部分等)の上方に貼付されるとよい。水素ガスは空気より軽いため、漏洩した水素は、漏洩箇所より上方に移動する。したがって、水素ガスが漏洩し得る箇所の上方に水素ガス検知テープ100を貼付することにより、迅速かつ確実に水素ガスの漏洩を検知することができる。   In addition, the hydrogen gas detection tape 100 is good to affix above the location (the joint part etc. of piping) where hydrogen gas may leak. Since hydrogen gas is lighter than air, the leaked hydrogen moves upward from the leak location. Therefore, by sticking the hydrogen gas detection tape 100 above the portion where hydrogen gas can leak, the leakage of hydrogen gas can be detected quickly and reliably.

(変形例)
上記実施形態において、水素検知剤112と蓄光剤114とが同一の検知層110に含まれる水素ガス検知テープ100について説明した。しかし、水素検知剤112を含む層と、蓄光剤114を含む層とが別々に設けられていてもよい。
(Modification)
In the above embodiment, the hydrogen gas detection tape 100 in which the hydrogen detection agent 112 and the phosphorescent agent 114 are included in the same detection layer 110 has been described. However, the layer containing the hydrogen detection agent 112 and the layer containing the phosphorescent agent 114 may be provided separately.

図2は、変形例にかかる水素ガス検知テープ200を説明する図であり、図2(a)は第1の変形例にかかる水素ガス検知テープ200の平面図を示し、図2(b)は図2(a)のIIb−IIb線断面の拡大図を示し、図2(c)は第2の変形例にかかる水素ガス検知テープ250の平面図を示し、図2(d)は図2(c)のIId−IId線断面の拡大図を示す。なお、図2(b)、(d)中、水素検知剤112を黒い丸で示し、蓄光剤114を白い丸で示すが、理解を容易にするために、実際より大きく記載している。   FIG. 2 is a diagram for explaining a hydrogen gas detection tape 200 according to a modification. FIG. 2 (a) is a plan view of the hydrogen gas detection tape 200 according to the first modification, and FIG. 2A is an enlarged view of a section taken along line IIb-IIb of FIG. 2A, FIG. 2C is a plan view of a hydrogen gas detection tape 250 according to a second modification, and FIG. The enlarged view of the IId-IId sectional view of c) is shown. In FIGS. 2B and 2D, the hydrogen detection agent 112 is indicated by a black circle and the phosphorescent agent 114 is indicated by a white circle. However, in order to facilitate understanding, the hydrogen detection agent 112 is illustrated larger than the actual one.

図2(a)、(b)に示すように、第1の変形例にかかる水素ガス検知テープ200は、水素検知層210と、蓄光層220と、粘着層120とを含んで構成される。水素検知層210は、水素検知剤112が樹脂116に分散された層である。蓄光層220は、蓄光剤114が樹脂116に分散された層である。水素ガス検知テープ200において、水素検知層210と蓄光層220とは隣接して(図2(a)、(b)中、Y軸方向に隣接して)設けられている。   As shown in FIGS. 2A and 2B, the hydrogen gas detection tape 200 according to the first modification includes a hydrogen detection layer 210, a light storage layer 220, and an adhesive layer 120. The hydrogen detection layer 210 is a layer in which the hydrogen detection agent 112 is dispersed in the resin 116. The phosphorescent layer 220 is a layer in which the phosphorescent agent 114 is dispersed in the resin 116. In the hydrogen gas detection tape 200, the hydrogen detection layer 210 and the phosphorescent layer 220 are provided adjacent to each other (adjacent in the Y-axis direction in FIGS. 2A and 2B).

第1の変形例にかかる水素ガス検知テープ200では、水素検知剤112を含む水素検知層210に隣接して、蓄光層220が設けられる構成により、水素検知剤112の視認性を向上させることが可能となる。   In the hydrogen gas detection tape 200 according to the first modification, the visibility of the hydrogen detection agent 112 can be improved by the configuration in which the phosphorescent layer 220 is provided adjacent to the hydrogen detection layer 210 including the hydrogen detection agent 112. It becomes possible.

図2(c)、(d)に示すように、第2の変形例にかかる水素ガス検知テープ250は、水素検知層210と、蓄光層220と、粘着層120とを含んで構成される。水素ガス検知テープ250において、蓄光層220は、水素検知層210を囲繞して設けられる。かかる構成により、水素検知剤112の視認性をさらに向上させることが可能となる。   As shown in FIGS. 2C and 2D, the hydrogen gas detection tape 250 according to the second modified example includes a hydrogen detection layer 210, a phosphorescent layer 220, and an adhesive layer 120. In the hydrogen gas detection tape 250, the phosphorescent layer 220 is provided surrounding the hydrogen detection layer 210. With this configuration, the visibility of the hydrogen detection agent 112 can be further improved.

(第2の実施形態:水素ガス検知テープ300)
図3は、第2の実施形態にかかる水素ガス検知テープ300を説明する図であり、図3(a)は水素ガス検知テープ300の平面図を示し、図3(b)は図3(a)のIIIb−IIIb線断面の拡大図を示す。なお、図3(b)中、水素検知剤112を黒い丸で示し、蓄光剤114を白い丸で示すが、理解を容易にするために、実際より大きく記載している。
(Second Embodiment: Hydrogen Gas Detection Tape 300)
FIG. 3 is a diagram for explaining a hydrogen gas detection tape 300 according to the second embodiment. FIG. 3A is a plan view of the hydrogen gas detection tape 300, and FIG. ) Is an enlarged view of a section taken along line IIIb-IIIb. In FIG. 3B, the hydrogen detection agent 112 is indicated by a black circle and the phosphorescent agent 114 is indicated by a white circle. However, in order to facilitate understanding, the hydrogen detection agent 112 is shown larger than the actual size.

図3に示すように、水素ガス検知テープ300は、水素検知層210と、2つの蓄光層220と、2つの粘着層120とを含んで構成される。水素検知層210は、2つの蓄光層220の間に設けられる。また、蓄光層220における一方の面(図3中、Z軸方向の一方の面)には、粘着層120が設けられるが、水素検知層210における一方の面には粘着層120が配されない。   As shown in FIG. 3, the hydrogen gas detection tape 300 includes a hydrogen detection layer 210, two light storage layers 220, and two adhesive layers 120. The hydrogen detection layer 210 is provided between the two light storage layers 220. Further, the adhesive layer 120 is provided on one surface of the phosphorescent layer 220 (one surface in the Z-axis direction in FIG. 3), but the adhesive layer 120 is not disposed on one surface of the hydrogen detection layer 210.

かかる構成により、水素ガスが漏洩し得る箇所に水素ガス検知テープ300を貼付した場合に、漏洩した水素ガスは、粘着層120を通過することなく、水素検知層210に直接導かれることとなる。したがって、水素ガス検知テープ300は、水素ガス検知テープ300自体および水素検知剤112の視認性の向上に加えて、水素検知層210による水素ガスの検知感度を向上させることが可能となる。   With this configuration, when the hydrogen gas detection tape 300 is attached to a location where hydrogen gas can leak, the leaked hydrogen gas is directly guided to the hydrogen detection layer 210 without passing through the adhesive layer 120. Therefore, the hydrogen gas detection tape 300 can improve the detection sensitivity of the hydrogen gas by the hydrogen detection layer 210 in addition to improving the visibility of the hydrogen gas detection tape 300 itself and the hydrogen detection agent 112.

以上、添付図面を参照しながら本発明の好適な実施形態について説明したが、本発明はかかる実施形態に限定されないことは言うまでもない。当業者であれば、特許請求の範囲に記載された範疇内において、各種の変更例または修正例に想到し得ることは明らかであり、それらについても当然に本発明の技術的範囲に属するものと了解される。   As mentioned above, although preferred embodiment of this invention was described referring an accompanying drawing, it cannot be overemphasized that this invention is not limited to this embodiment. It will be apparent to those skilled in the art that various changes and modifications can be made within the scope of the claims, and these are naturally within the technical scope of the present invention. Understood.

例えば、第1の実施形態における水素ガス検知テープ100は、検知層110のうち、粘着層120が設けられる面の逆側の面に、検知層110を保護する保護層を備えてもよい。同様に、第1の変形例における水素ガス検知テープ200、第2の変形例における水素ガス検知テープ250は、水素検知層210および蓄光層220のうち、粘着層120が設けられる面の逆側の面に、水素検知層210および蓄光層220を保護する保護層を備えてもよい。また、第2の実施形態における水素ガス検知テープ300は、蓄光層220のうち粘着層120が設けられる面の逆側の面および、当該逆側の面と略面一となる水素検知層210の面に保護層を備えてもよい。これにより、検知層110、水素検知層210、蓄光層220を保護することができる。なお、保護層は、透明度が高く、水素の透過率が大きい材料で構成されるとよい。これにより、水素ガス検知テープ100、200、250、300の視認性を確保することができ、また、水素ガスの検知感度の低下を抑制することが可能となる。   For example, the hydrogen gas detection tape 100 according to the first embodiment may include a protective layer that protects the detection layer 110 on the surface of the detection layer 110 opposite to the surface on which the adhesive layer 120 is provided. Similarly, the hydrogen gas detection tape 200 in the first modification and the hydrogen gas detection tape 250 in the second modification are on the opposite side of the surface of the hydrogen detection layer 210 and the phosphorescent layer 220 where the adhesive layer 120 is provided. A protective layer that protects the hydrogen detection layer 210 and the phosphorescent layer 220 may be provided on the surface. Moreover, the hydrogen gas detection tape 300 in 2nd Embodiment is the surface of the reverse side of the surface in which the adhesion layer 120 is provided among the luminous layers 220, and the hydrogen detection layer 210 which becomes substantially flush with the surface on the opposite side. A protective layer may be provided on the surface. Thereby, the detection layer 110, the hydrogen detection layer 210, and the luminous layer 220 can be protected. Note that the protective layer is preferably made of a material having high transparency and high hydrogen permeability. Thereby, the visibility of the hydrogen gas detection tapes 100, 200, 250, and 300 can be ensured, and a decrease in the detection sensitivity of hydrogen gas can be suppressed.

また、水素ガス検知テープ100、200、250、300が、粘着層120を備える構成を例に挙げて説明した。しかし、粘着層120は必須の構成ではない。   In addition, the hydrogen gas detection tapes 100, 200, 250, and 300 have been described using the configuration including the adhesive layer 120 as an example. However, the adhesive layer 120 is not an essential configuration.

また、上記第1の実施形態において、検知層110と、粘着層120とが異なる層で構成される水素ガス検知テープ100について説明した。しかし、粘着層120が水素検知剤112および蓄光剤114を含んでもよい。また、水素検知剤112を含む粘着層120と、蓄光剤114を含む粘着層120とが隣接して設けられてもよい。   Moreover, in the said 1st Embodiment, the hydrogen gas detection tape 100 comprised by the layer from which the detection layer 110 and the adhesion layer 120 differ was demonstrated. However, the adhesive layer 120 may include the hydrogen detection agent 112 and the phosphorescent agent 114. Moreover, the adhesion layer 120 containing the hydrogen detection agent 112 and the adhesion layer 120 containing the luminous agent 114 may be provided adjacent to each other.

また、水素検知層210を最上面に、蓄光層220を水素検知層210の下面に、粘着層120を蓄光層220の下面とした、各層が分離された構成の水素ガス検知テープとしてもよい。   Alternatively, the hydrogen detection layer 210 may be a top surface, the phosphorescent layer 220 may be a lower surface of the hydrogen detection layer 210, and the adhesive layer 120 may be a lower surface of the phosphorescence layer 220.

また、プラスチック(例えば、アクリル)や、水を通さないシール等(材料は問わない)を水素検知テープの表面に付し、水分から水素検知テープを保護してもよい。   Further, a plastic (for example, acrylic), a water-impervious seal, or the like (regardless of material) may be attached to the surface of the hydrogen detection tape to protect the hydrogen detection tape from moisture.

本発明は、水素ガスを検知する水素ガス検知テープに利用することができる。   The present invention can be used for a hydrogen gas detection tape for detecting hydrogen gas.

100、200、250、300 水素ガス検知テープ
110 検知層
112 水素検知剤
114 蓄光剤
120 粘着層
210 水素検知層
220 蓄光層
100, 200, 250, 300 Hydrogen gas detection tape 110 Detection layer 112 Hydrogen detection agent 114 Phosphorescent agent 120 Adhesive layer 210 Hydrogen detection layer 220 Phosphorescence layer

Claims (3)

水素ガスの接触により変色する水素検知剤および蓄光剤を含む水素ガス検知テープ。   A hydrogen gas detection tape comprising a hydrogen detection agent and a phosphorescent agent that change color upon contact with hydrogen gas. 前記水素検知剤が含まれる水素検知層と、
前記蓄光剤が含まれる蓄光層と、
を備えたことを特徴とする請求項1に記載の水素ガス検知テープ。
A hydrogen detection layer containing the hydrogen detection agent;
A phosphorescent layer containing the phosphorescent agent;
The hydrogen gas detection tape according to claim 1, comprising:
粘着層を備えたことを特徴とする請求項2に記載の水素ガス検知テープ。   The hydrogen gas detection tape according to claim 2, further comprising an adhesive layer.
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CN111662650A (en) * 2020-05-07 2020-09-15 北京航天试验技术研究所 Hydrogen-sensitive color-changing detection adhesive tape and preparation method and application thereof
CN114460024A (en) * 2020-11-10 2022-05-10 蓝星智云(山东)智能科技有限公司 Method and system for online real-time monitoring of hydrogen and chlorine in hydrogen chloride synthesis furnace
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