JP2017195846A - Method of producing frozen soybean curd - Google Patents

Method of producing frozen soybean curd Download PDF

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JP2017195846A
JP2017195846A JP2016091097A JP2016091097A JP2017195846A JP 2017195846 A JP2017195846 A JP 2017195846A JP 2016091097 A JP2016091097 A JP 2016091097A JP 2016091097 A JP2016091097 A JP 2016091097A JP 2017195846 A JP2017195846 A JP 2017195846A
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tofu
organic acid
dispersion
acid monoglyceride
weight
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晃弘 小川
Akihiro Ogawa
晃弘 小川
亮太 片平
Ryota Katahira
亮太 片平
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Mitsubishi Chemical Foods Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a method of producing frozen soybean curd capable of obtaining the same texture and taste after defrosting as that before freezing without improving a constituent and a production method of soybean curd itself, and a cryopreservation method of soybean curd.SOLUTION: A method of producing frozen soybean curd comprises: contacting soybean curd with a dispersed liquid containing an organic acid monoglyceride; and freezing the soybean curd attached with the dispersed liquid. The dispersed liquid is preferably contained in a seasoning liquid of soybean curd. The soybean curd is preferably contacted with a saccharide together with the dispersed liquid. The dispersed liquid preferably contains a sucrose fatty acid ester and/or a polyglyceryl fatty acid ester.SELECTED DRAWING: None

Description

本発明は冷凍豆腐の製造方法及び豆腐の冷凍保存方法に関し、市販されている豆腐を冷凍後に解凍しても、冷凍していないものと同等の食感や味が得られる冷凍豆腐の製造方法および豆腐の冷凍保存方法に関する。   The present invention relates to a method for producing frozen tofu and a method for freezing and preserving tofu, and a method for producing frozen tofu that provides a texture and taste equivalent to those that are not frozen, even if the commercially available tofu is thawed after freezing The present invention relates to a method for freezing tofu.

一般的に製造されている豆腐を冷凍して解凍すると、いわゆる鬆ができてスポンジ状に変質し元のような豆腐の食感や味が得られないことは良く知られている。豆腐は日持ちがしないため、従来より冷凍豆腐の製造方法について、様々な検討がなされてきた。   It is well known that when generally produced tofu is frozen and thawed, a so-called void is formed, which is transformed into a sponge and the original texture and taste of tofu cannot be obtained. Since tofu does not last for a long time, various studies have been made on methods for producing frozen tofu.

例えば、特許文献1では、豆腐の製造に際し平均粒径が10μm以下のデンプンを豆乳に添加することにより、豆腐に冷凍耐性を持たせる方法が提案されている。また、特許文献2では、豆乳、タンパク質を決着させる作用を有する酵素、澱粉を所定の割合で混合し固めて豆腐を作った後に冷凍する方法が提案されている。特許文献3では、水に対し、特定量の大豆粉末、コラーゲン粉末を添加して撹拌した乳化物を加熱、ろ過した後に冷凍する方法が提案されている。さらに特許文献4では、特定の固形分濃度の豆乳を一定温度に保ち、澱粉、トレハロース、にがり、トランスグルタミナーゼを添加した後に、加熱して冷凍する方法が提案されている。   For example, Patent Document 1 proposes a method of imparting freezing tolerance to tofu by adding starch having an average particle size of 10 μm or less to soy milk during the production of tofu. Further, Patent Document 2 proposes a method of freezing soybean milk, an enzyme having an action to settle proteins, and starch by mixing them at a predetermined ratio and solidifying them to make tofu. Patent Document 3 proposes a method in which an emulsion obtained by adding a specific amount of soybean powder or collagen powder to water and stirring the mixture is heated and filtered and then frozen. Further, Patent Document 4 proposes a method in which soymilk having a specific solid content concentration is kept at a constant temperature, starch, trehalose, bittern, and transglutaminase are added, followed by heating and freezing.

しかし、これらは、いずれの方法も豆腐自体の成分や製法を改良することにより、冷凍耐性を付与するものであり、一般的に市販されている豆腐をそのまま冷凍するための方法は開示されていない。   However, all of these methods impart freeze resistance by improving the components and production method of tofu itself, and a method for freezing generally commercially available tofu is not disclosed. .

特開平11−169128号公報JP-A-11-169128 特開2003−52326号公報JP 2003-52326 A 特開2003−325123号公報JP 2003-325123 A 特開2005−21070号公報JP-A-2005-21070

本発明は、豆腐自体の成分や製法を改良することなく、解凍後も冷凍前の豆腐と同等の食感や味が得られる冷凍豆腐の製造方法と豆腐の冷凍保存方法を提供することを課題とする。   It is an object of the present invention to provide a method for producing frozen tofu and a method for cryopreserving tofu that can provide the same texture and taste as those of tofu before freezing even after thawing without improving the components and production method of the tofu itself. And

本発明者らが検討した結果、有機酸モノグリセリドを含有する分散液と豆腐を接触させ、該分散液が付着した豆腐を冷凍することにより上記課題を解決できることが分かり本発明に到達した。
即ち、本発明は以下を要旨とするものである。
As a result of investigations by the present inventors, it was found that the above problem can be solved by bringing the dispersion containing organic acid monoglyceride into contact with tofu and freezing the tofu to which the dispersion has adhered.
That is, the gist of the present invention is as follows.

[1] 冷凍豆腐の製造方法であって、有機酸モノグリセリドを含有する分散液と豆腐を接触させ、該分散液が付着した豆腐を冷凍することを特徴とする、冷凍豆腐の製造方法。
[2] 該分散液は豆腐の調味液中に含有されている、[1]に記載の冷凍豆腐の製造方法。
[3] 該分散液とともに糖類を豆腐と接触させる、[1]または[2]に記載の冷凍豆腐の製造方法。
[4] 該分散液がショ糖脂肪酸エステルおよび/またはポリグリセリン脂肪酸エステルを含有する、[1]〜[3]のいずれかに記載の冷凍豆腐の製造方法。
[5] 有機酸モノグリセリドを含有する分散液と豆腐を接触させ、加熱した後に冷凍する、[1]〜[4]のいずれかに記載の冷凍豆腐の製造方法。
[6] 有機酸モノグリセリドを含有する分散液と豆腐を接触させ、該分散液が付着した豆腐を冷凍することを特徴とする、豆腐の冷凍保存方法。
[1] A method for producing frozen tofu, which comprises bringing a dispersion containing an organic acid monoglyceride into contact with tofu and freezing the tofu to which the dispersion has adhered.
[2] The method for producing frozen tofu according to [1], wherein the dispersion is contained in a tofu seasoning liquid.
[3] The method for producing frozen tofu according to [1] or [2], wherein a saccharide is brought into contact with tofu together with the dispersion.
[4] The method for producing frozen tofu according to any one of [1] to [3], wherein the dispersion contains a sucrose fatty acid ester and / or a polyglycerol fatty acid ester.
[5] The method for producing frozen tofu according to any one of [1] to [4], wherein the dispersion containing organic acid monoglyceride and tofu are brought into contact with each other and heated and then frozen.
[6] A method for cryopreserving tofu, comprising bringing a dispersion containing an organic acid monoglyceride into contact with tofu and freezing the tofu to which the dispersion has adhered.

本発明によれば、豆腐自体の成分や製法を改良することなく、解凍後も冷凍前の豆腐と同等の食感や味が得られる冷凍豆腐を製造することができる。このため、市販の豆腐に対して冷凍処理を施すことが可能となり、豆腐の保存、流通範囲を大幅に拡大することができる。   According to the present invention, it is possible to produce frozen tofu that has the same texture and taste as that of tofu before freezing after thawing without improving the components and production method of tofu itself. For this reason, it becomes possible to perform a freezing process with respect to commercially available tofu, and the preservation | save and distribution | circulation range of tofu can be expanded significantly.

以下に、本発明の実施の形態を詳細に説明する。
以下に記載する構成要件の説明は、本発明の実施態様の一例(代表例)であり、本発明はその要旨を超えない限り、これらの内容に特定はされない。
Hereinafter, embodiments of the present invention will be described in detail.
The description of the constituent elements described below is an example (representative example) of an embodiment of the present invention, and the present invention is not specified in these contents unless it exceeds the gist.

本発明の冷凍豆腐の製造方法は、有機酸モノグリセリドを含有する分散液と豆腐を接触させ、該分散液が付着した豆腐を冷凍することを特徴とする。
本発明の豆腐の冷凍保存方法は、有機酸モノグリセリドを含有する分散液と豆腐を接触させ、該分散液が付着した豆腐を冷凍することを特徴とする。
The method for producing frozen tofu according to the present invention is characterized in that a dispersion containing an organic acid monoglyceride is brought into contact with tofu and the tofu to which the dispersion is adhered is frozen.
The method for freezing and preserving tofu according to the present invention is characterized in that a dispersion containing an organic acid monoglyceride is brought into contact with tofu and the tofu to which the dispersion is adhered is frozen.

1.豆腐
本発明において冷凍する豆腐は、通常の豆腐の製造方法に従って豆乳ににがりやその他の豆腐用凝固剤で凝固させて製造されるものであり、特に制限はなく、市販品をそのまま用いることができる。
1. Tofu frozen in the present invention is produced by coagulating with soy milk bittern or other coagulant for tofu according to a conventional method for producing tofu, and there is no particular limitation, and a commercially available product can be used as it is. .

本発明は、豆腐のみを冷凍させる場合のみならず、豆腐を野菜や肉、魚、キノコ類、その他の食材と共に冷凍させる場合にも適用することができる。
豆腐は、調理の種類に応じて適当な大きさにカットして、好ましくは加熱調味された後、冷凍に供される。
The present invention can be applied not only to freezing tofu alone, but also to freezing tofu together with vegetables, meat, fish, mushrooms and other ingredients.
The tofu is cut into a suitable size according to the type of cooking, and is preferably seasoned by heating and then subjected to freezing.

2.有機酸モノグリセリドを含有する分散液
本発明で使用する有機酸モノグリセリドを含有する分散液(以下、有機酸モノグリセリド含有分散液という場合がある)について説明する。
2. Dispersion containing organic acid monoglyceride The dispersion containing the organic acid monoglyceride used in the present invention (hereinafter sometimes referred to as organic acid monoglyceride-containing dispersion) will be described.

本発明に係る有機酸モノグリセリドは、グリセリン1分子に脂肪酸1分子と有機酸1分子が結合した構造を有し、一般的には、有機酸の酸無水物と脂肪酸モノグリセリドを反応させることにより得られる。反応は、通常、無溶媒条件下で行われ、例えば無水コハク酸と炭素数18のモノグリセリドの反応では、温度120℃前後において90分程度で反応が完了する。かくして得られた有機酸モノグリセリドは、通常、有機酸、未反応モノグリセリド、ジグリセリド、その他オリゴマーを含む混合物となっている。本発明においては、このような混合物をそのまま使用してもよく、有機酸モノグリセリドの純度を高めたい場合は、蒸留モノグリセリドとして市販されているものを使用してもよい。また、有機酸部分が一部中和されたものを使用してもよい。   The organic acid monoglyceride according to the present invention has a structure in which one molecule of fatty acid and one molecule of organic acid are bonded to one molecule of glycerin, and is generally obtained by reacting an acid anhydride of an organic acid with a fatty acid monoglyceride. . The reaction is usually carried out under solvent-free conditions. For example, in the reaction of succinic anhydride and a monoglyceride having 18 carbon atoms, the reaction is completed in about 90 minutes at a temperature of about 120 ° C. The organic acid monoglyceride thus obtained is usually a mixture containing an organic acid, unreacted monoglyceride, diglyceride and other oligomers. In the present invention, such a mixture may be used as it is, and when it is desired to increase the purity of the organic acid monoglyceride, a commercially available product as a distilled monoglyceride may be used. Moreover, you may use what the organic acid part was partially neutralized.

有機酸モノグリセリドを構成する有機酸としては、例えば、コハク酸、クエン酸、酒石酸、ジアセチル酒石酸、リンゴ酸、アジピン酸、グルタル酸、マレイン酸、フマル酸、酢酸、乳酸などが挙げられる。これらの中では、食品用途に使用されるコハク酸、クエン酸、ジアセチル酒石酸が好ましく、特に風味の点からコハク酸が好ましい。   Examples of the organic acid constituting the organic acid monoglyceride include succinic acid, citric acid, tartaric acid, diacetyltartaric acid, malic acid, adipic acid, glutaric acid, maleic acid, fumaric acid, acetic acid, and lactic acid. Among these, succinic acid, citric acid and diacetyltartaric acid used for food applications are preferable, and succinic acid is particularly preferable from the viewpoint of flavor.

上記脂肪酸モノグリセリド由来の、有機酸モノグリセリドを構成する脂肪酸としては、例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸などの炭素数8〜22の飽和または不飽和の脂肪酸が挙げられる。これらの中では風味の観点からステアリン酸を主成分とする脂肪酸が好ましく、特に構成脂肪酸の70重量%以上がステアリン酸であるものが好ましい。   Examples of the fatty acid that constitutes the organic acid monoglyceride derived from the fatty acid monoglyceride include, for example, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, and the like, having 8 to 22 carbon atoms. Or an unsaturated fatty acid is mentioned. Among these, fatty acids mainly composed of stearic acid are preferable from the viewpoint of flavor, and those in which 70% by weight or more of the constituent fatty acids are stearic acid are particularly preferable.

有機酸モノグリセリドとしては1種のみを用いてもよく、これを構成する有機酸や脂肪酸が異なるものを2種以上混合して用いてもよい。   As an organic acid monoglyceride, only 1 type may be used and 2 or more types from which the organic acid and fatty acid which comprise this differ may be used.

上記の有機酸モノグリセリドと水との混合物は、これらの量比、温度変化により様々な相状態をとることが可能である。これらの相状態のうち、本発明ではラメラ構造体(ラメラ液晶構造体)を利用することが好ましい。   The mixture of the above-mentioned organic acid monoglyceride and water can take various phase states depending on the quantitative ratio and temperature change. Among these phase states, in the present invention, it is preferable to use a lamellar structure (lamellar liquid crystal structure).

ラメラ構造体とは、有機酸モノグリセリドを水に分散させた際に有機酸モノグリセリド2分子が親水基部分を水側に向け、疎水基部分(脂肪酸)が互いに向き合い、これが2次元的に広がった構造のことである。   A lamellar structure is a structure in which when organic acid monoglyceride is dispersed in water, two molecules of organic acid monoglyceride have hydrophilic groups facing the water side, and hydrophobic groups (fatty acids) face each other, which expands two-dimensionally. That is.

有機酸モノグリセリドは低濃度から高濃度領域の広い範囲でラメラ構造を形成し易いことが知られている。例えば、コハク酸ステアリン酸モノグリセリドは、ナトリウム塩の状態において、濃度が約35〜85重量%のような高濃度領域で且つ温度が50℃以上の条件でラメラ構造体を形成する。この場合、ラメラ構造体が何層にも重なった状態が認められ、水溶液の粘度も高くなる。濃度が85重量%よりも高い場合は固体状態となり、濃度が35重量%よりも低い場合は水溶液にラメラ構造体が分散して粘性が比較的小さい状態となる。作業性などを考慮すると、低濃度かつ高温領域でラメラ構造体を形成させることが好ましい。   It is known that organic acid monoglycerides easily form a lamellar structure in a wide range from a low concentration to a high concentration region. For example, succinic acid stearic acid monoglyceride forms a lamellar structure in a high concentration region such as a concentration of about 35 to 85% by weight and a temperature of 50 ° C. or higher in the sodium salt state. In this case, a state where the lamellar structure is overlapped in multiple layers is recognized, and the viscosity of the aqueous solution is increased. When the concentration is higher than 85% by weight, the solid state is obtained. When the concentration is lower than 35% by weight, the lamellar structure is dispersed in the aqueous solution and the viscosity is relatively small. In consideration of workability and the like, it is preferable to form a lamellar structure in a low concentration and high temperature region.

ラメラ構造体は、有機酸モノグリセリドを水などの分散媒中に分散させ、物理的に撹拌し加熱することにより、分散液として調製することができる。この際の加熱温度は、分散液の温度で、通常45℃以上、好ましくは50℃以上、通常100℃以下、好ましくは80℃以下、更に好ましくは70℃以下である。上記の物理的分散には、例えば、気泡の混入を避けるため、アンカーミキサー等を使用してゆっくりと撹拌することが好ましい。   The lamellar structure can be prepared as a dispersion by dispersing an organic acid monoglyceride in a dispersion medium such as water, physically stirring and heating. The heating temperature at this time is the temperature of the dispersion, and is usually 45 ° C. or higher, preferably 50 ° C. or higher, usually 100 ° C. or lower, preferably 80 ° C. or lower, more preferably 70 ° C. or lower. For the above physical dispersion, for example, it is preferable to slowly stir using an anchor mixer or the like in order to avoid mixing of bubbles.

このようにして得られるラメラ構造体を製造するための分散液(以下、ラメラ構造体分散液という場合がある)中の有機酸モノグリセリドの含有量は、通常0.1重量%以上、好ましくは1重量%以上、より好ましくは5重量%以上、通常99.9重量%以下、好ましくは60重量%以下、より好ましくは40重量%以下、さらに好ましくは30重量%以下、特に好ましくは20重量%以下である。   The content of the organic acid monoglyceride in the dispersion for producing the lamella structure thus obtained (hereinafter sometimes referred to as the lamella structure dispersion) is usually 0.1% by weight or more, preferably 1 % By weight or more, more preferably 5% by weight or more, usually 99.9% by weight or less, preferably 60% by weight or less, more preferably 40% by weight or less, still more preferably 30% by weight or less, particularly preferably 20% by weight or less. It is.

さらに、ラメラ構造体の安定性を高めるために、又は水中での分散性を向上させるために、ショ糖脂肪酸エステルやポリグリセリン脂肪酸エステル等の乳化剤の1種又は2種以上を用いることができる。安定化されたラメラ構造体は、親水基部分の強い水和力により層間に多量の水を保持する。   Furthermore, in order to improve the stability of the lamellar structure or to improve the dispersibility in water, one or more emulsifiers such as sucrose fatty acid ester and polyglycerin fatty acid ester can be used. The stabilized lamella structure retains a large amount of water between layers due to the strong hydration power of the hydrophilic group portion.

乳化剤を用いる場合、具体的には、該乳化剤をエタノール、水、糖類の水溶液などの分散媒に分散させた分散液と、上記ラメラ構造体水分散液とを混合させてもよいし、直接、ラメラ構造体水分散液に該乳化剤を添加してもよい。   When using an emulsifier, specifically, a dispersion in which the emulsifier is dispersed in a dispersion medium such as an aqueous solution of ethanol, water, and sugar may be mixed with the lamellar structure aqueous dispersion, or directly The emulsifier may be added to the lamella structure aqueous dispersion.

有機酸モノグリセリド含有分散液中の有機酸モノグリセリドの含有量は、通常0.1重量%以上、好ましくは1重量%以上、より好ましくは3重量%以上、通常50重量%以下、好ましくは20重量%以下、より好ましくは10重量%以下、特に好ましくは5重量%以下である。有機酸モノグリセリドの含有量が過度に少ない場合は、冷凍変性防止効果が不十分となり、過度に多い場合は、有機酸モノグリセリドが水(分散媒)中に均一に分散しなくなる場合がある。   The content of the organic acid monoglyceride in the organic acid monoglyceride-containing dispersion is usually 0.1% by weight or more, preferably 1% by weight or more, more preferably 3% by weight or more, usually 50% by weight or less, preferably 20% by weight. Hereinafter, it is more preferably 10% by weight or less, particularly preferably 5% by weight or less. When the content of the organic acid monoglyceride is excessively small, the effect of preventing freezing denaturation is insufficient, and when it is excessively large, the organic acid monoglyceride may not be uniformly dispersed in water (dispersion medium).

有機酸モノグリセリド含有分散液には、ショ糖脂肪酸エステルやポリグリセリン脂肪酸エステル等の乳化剤の1種又は2種以上が含まれていてもよい。特に、有機酸モノグリセリドをラメラ構造体として使用する場合は、乳化剤を使用することで上記のとおりラメラ構造体の安定性を高めることができる。   The organic acid monoglyceride-containing dispersion may contain one or more emulsifiers such as sucrose fatty acid ester and polyglycerin fatty acid ester. In particular, when an organic acid monoglyceride is used as a lamellar structure, the stability of the lamellar structure can be enhanced as described above by using an emulsifier.

有機酸モノグリセリド含有分散液に用いるショ糖脂肪酸エステルとしては、親水性が高く、水分散性に優れ、高温で高粘性の水分散液の状態となるものが好ましい。このようなショ糖脂肪酸エステルとして具体的には、構成脂肪酸として、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、オレイン酸などの炭素数14〜22の飽和または不飽和の脂肪酸を有するショ糖脂肪酸エステルが挙げられる。これらの中では、炭素数14〜18の飽和脂肪酸を有するものが、風味や酸化安定性の観点から好ましい。また、構成脂肪酸の70重量%以上がステアリン酸である脂肪酸を有するものが、風味の点から更に好ましい。また、親水性の点では、HLB値が通常5以上、好ましくは8以上、通常18以下、好ましくは15以下のショ糖脂肪酸エステルが好ましい。   As the sucrose fatty acid ester used in the organic acid monoglyceride-containing dispersion, those having high hydrophilicity, excellent water dispersibility, and a high viscosity aqueous dispersion at high temperature are preferable. Specifically, such sucrose fatty acid esters include sucrose fatty acids having, as constituent fatty acids, saturated or unsaturated fatty acids having 14 to 22 carbon atoms such as myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid and the like. Examples include esters. In these, what has a C14-C18 saturated fatty acid is preferable from a viewpoint of flavor or oxidation stability. Moreover, what has the fatty acid whose 70 weight% or more of constituent fatty acid is a stearic acid is still more preferable from the point of flavor. In terms of hydrophilicity, sucrose fatty acid esters having an HLB value of usually 5 or more, preferably 8 or more, and usually 18 or less, preferably 15 or less are preferred.

有機酸モノグリセリド含有分散液に用いるポリグリセリン脂肪酸エステルも、ショ糖脂肪酸エステルと同様に、親水性が高く、水分散性に優れ、高温で高粘性の水分散液の状態となるものが好ましい。斯かるポリグリセリン脂肪酸エステルとしては、ポリグリリンの平均重合度が通常2〜20、特に3〜10のものが好ましい。また、ポリグリセリン脂肪酸エステルの構成脂肪酸が前記ショ糖脂肪酸エステルと同様に炭素数14〜22の飽和または不飽和の脂肪酸を有するポリグリセリン脂肪酸エステルが好ましい。また、構成脂肪酸の70重量%以上がステアリン酸であるポリグリセリン脂肪酸エステルが風味の点から更に好ましい。また、親水性の点では、HLB値が通常5以上、好ましくは9以上、通常18以下、好ましくは16以下のポリグリセリン脂肪酸エステルが好ましい。   The polyglycerin fatty acid ester used in the organic acid monoglyceride-containing dispersion is also preferably one having a high hydrophilicity, excellent water dispersibility, and a high viscosity aqueous dispersion at the same temperature as the sucrose fatty acid ester. As such polyglycerin fatty acid ester, those having an average degree of polymerization of polyglycerin of usually 2 to 20, particularly 3 to 10 are preferred. Moreover, the polyglycerin fatty acid ester in which the constituent fatty acid of the polyglycerin fatty acid ester has a saturated or unsaturated fatty acid having 14 to 22 carbon atoms, like the sucrose fatty acid ester, is preferable. A polyglycerin fatty acid ester in which 70% by weight or more of the constituent fatty acid is stearic acid is more preferable from the viewpoint of flavor. From the viewpoint of hydrophilicity, polyglycerol fatty acid esters having an HLB value of usually 5 or more, preferably 9 or more, and usually 18 or less, preferably 16 or less are preferred.

ショ糖脂肪酸エステルやポリグリセリン脂肪酸エステル等の乳化剤を用いる場合、有機酸モノグリセリド含有分散液中の乳化剤の含有量は、通常0.1重量%以上、好ましくは1重量%以上、より好ましくは2重量%以上、更に好ましくは3重量%以上、通常50重量%以下、好ましくは20重量%以下、より好ましくは10重量%以下、更に好ましくは5重量%以下である。乳化剤の含有量がこの範囲にあることにより、有機酸モノグリセリドのラメラ構造体の水分散性がより向上する。   When an emulsifier such as sucrose fatty acid ester or polyglycerin fatty acid ester is used, the content of the emulsifier in the organic acid monoglyceride-containing dispersion is usually 0.1% by weight or more, preferably 1% by weight or more, more preferably 2% by weight. % Or more, more preferably 3% by weight or more, usually 50% by weight or less, preferably 20% by weight or less, more preferably 10% by weight or less, still more preferably 5% by weight or less. When the content of the emulsifier is within this range, the water dispersibility of the lamellar structure of the organic acid monoglyceride is further improved.

また、有機酸モノグリセリド含有分散液中において、有機酸モノグリセリドに対する乳化剤の含有量(重量比)は、通常500:1〜1:500、好ましくは100:1〜1:100、さらに好ましくは3:1〜1:3の範囲である。有機酸モノグリセリドに対する乳化剤の含有量(重量比)は、1:1であることがより好ましいが、さらには乳化剤よりも有機酸モノグリセリドが多い方が好ましく、乳化剤に対して有機酸モノグリセリドを1.5倍以上含有することが好ましく、2倍以上含有することがより好ましい。   In the organic acid monoglyceride-containing dispersion, the content (weight ratio) of the emulsifier with respect to the organic acid monoglyceride is usually 500: 1 to 1: 500, preferably 100: 1 to 1: 100, more preferably 3: 1. The range is ˜1: 3. The content (weight ratio) of the emulsifier with respect to the organic acid monoglyceride is more preferably 1: 1, but more preferably the organic acid monoglyceride is more than the emulsifier. It is preferable to contain 2 times or more, and it is more preferable to contain 2 times or more.

本発明で用いる有機酸モノグリセリド含有分散液は、糖類の1種又は2種以上を含んでいてもよく、糖類を含むことにより、ラメラ構造体の分散安定性が良好となる。   The organic acid monoglyceride-containing dispersion used in the present invention may contain one or more saccharides, and by including the saccharide, the dispersion stability of the lamellar structure becomes good.

糖類としては、特に制限されず、砂糖、ブドウ糖、異性化糖、マルトース、トレハロース、ソルビトール、マルチトール、ラクチトール、エリスリトール等の糖および糖アルコール;各種オリゴ糖;それらの混合物を使用することができる。これらの中ではオリゴ糖が好ましい。   The sugar is not particularly limited, and sugars and sugar alcohols such as sugar, glucose, isomerized sugar, maltose, trehalose, sorbitol, maltitol, lactitol, erythritol; various oligosaccharides; and mixtures thereof can be used. Of these, oligosaccharides are preferred.

上記のオリゴ糖としては、マルトオリゴ糖(好ましくは重合度3〜7)、ニゲロオリゴ糖、イソマルトオリゴ糖、パノースオリゴ糖、ゲンチオオリゴ糖、フラクトオリゴ糖、ガラクトオリゴ糖、キシロオリゴ糖、乳果オリゴ糖、それらのシラップ等が挙げられる。上記の糖類は、目的に応じ、適宜選択して使用され、冷凍耐性を向上させる場合にはオリゴ糖や糖アルコールが好ましく、該オリゴ糖の中ではマルトオリゴ糖が好ましい。   Examples of the oligosaccharide include maltooligosaccharide (preferably having a polymerization degree of 3 to 7), nigerooligosaccharide, isomaltooligosaccharide, panose oligosaccharide, gentiooligosaccharide, fructooligosaccharide, galactooligosaccharide, xylooligosaccharide, dairy oligosaccharide, and syrup thereof. Is mentioned. The above saccharides are appropriately selected and used according to the purpose, and oligosaccharides and sugar alcohols are preferable when improving the freezing tolerance, and among these oligosaccharides, maltooligosaccharides are preferable.

糖類は、糖類の水溶液として使用することが好ましく、例えばシラップの場合はそのまま使用することもできる。   The saccharide is preferably used as an aqueous solution of saccharide. For example, in the case of syrup, it can be used as it is.

また、上記乳化剤と糖類を用いる場合は、前述の乳化剤の分散液と糖類の水溶液を混合した後、ラメラ構造体水分散液などの有機酸モノグリセリドが分散した水分散液と混合してもよいし、乳化剤の分散液に糖類を添加または糖類の水溶液に乳化剤を添加した後に、これらの分散液または水溶液とラメラ構造体水分散液などの有機酸モノグリセリドが分散した水分散液とを混合してもよい。   When the above emulsifier and saccharide are used, the above-mentioned emulsifier dispersion and saccharide aqueous solution may be mixed and then mixed with an aqueous dispersion in which an organic acid monoglyceride is dispersed, such as a lamellar structure aqueous dispersion. After adding saccharide to the dispersion of the emulsifier or adding the emulsifier to the aqueous solution of saccharide, these dispersion or aqueous solution and an aqueous dispersion in which an organic acid monoglyceride such as a lamellar structure aqueous dispersion is dispersed may be mixed. Good.

ラメラ構造体水分散液などの有機酸モノグリセリドが分散した水分散液と、乳化剤の分散液、糖類の水溶液またはこれらの混合物とを混合する場合は、乳化剤の分散液、糖類の水溶液またはこれらの混合物を通常45℃以上、好ましくは50℃以上、通常100℃以下、好ましくは80℃以下、更に好ましくは70℃以下に加熱して用いてもよい。   When mixing an aqueous dispersion in which an organic acid monoglyceride such as a lamellar structure aqueous dispersion is dispersed with an emulsifier dispersion, an aqueous solution of saccharides, or a mixture thereof, an emulsifier dispersion, an aqueous solution of saccharides, or a mixture thereof. May be heated to 45 ° C. or higher, preferably 50 ° C. or higher, usually 100 ° C. or lower, preferably 80 ° C. or lower, more preferably 70 ° C. or lower.

糖類を用いる場合、有機酸モノグリセリド含有分散液中の糖類の含有量は、通常35重量%以上、好ましくは40重量%以上、通常85重量%以下、好ましくは60重量%以下である。糖類の含有量が上記下限以上であることにより、よりラメラ構造体の分散安定性が向上し、上記上限以下であることにより、糖の種類によって結晶が析出したり、粘度が高くなるなどの問題点が生じ難くなる。   When saccharides are used, the saccharide content in the organic acid monoglyceride-containing dispersion is usually 35% by weight or more, preferably 40% by weight or more, and usually 85% by weight or less, preferably 60% by weight or less. When the saccharide content is at least the above lower limit, the dispersion stability of the lamellar structure is further improved, and when it is at most the above upper limit, crystals are precipitated depending on the type of sugar or the viscosity is increased. Doing so is less likely to occur.

また、有機酸モノグリセリド含有分散液中において、有機酸モノグリセリドに対する糖類の含有量は、有機酸モノグリセリド:糖類(重量比)=10:7〜1:850の範囲であることが好ましく、より好ましくは1:4〜1:20の範囲である。   In the organic acid monoglyceride-containing dispersion, the saccharide content relative to the organic acid monoglyceride is preferably in the range of organic acid monoglyceride: saccharide (weight ratio) = 10: 7 to 1: 850, more preferably 1. : The range is 4 to 1:20.

本発明の効果を損なわない範囲において、有機酸モノグリセリド含有分散液には、前記以外の他の乳化剤、甘味料、香料、ビタミン、抗酸化剤、アルコールなどの公知の配合剤の1種又は2種以上が含まれていてもよい。その他の乳化剤としては、レシチン、リゾレシチン、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル等が挙げられる。   As long as the effects of the present invention are not impaired, the organic acid monoglyceride-containing dispersion contains one or two known compounding agents such as emulsifiers, sweeteners, fragrances, vitamins, antioxidants, and alcohols other than those described above. The above may be included. Examples of other emulsifiers include lecithin, lysolecithin, glycerin fatty acid ester, sorbitan fatty acid ester and the like.

有機酸モノグリセリド含有分散液中の水(分散媒)の含有量は、通常30重量%以上、好ましくは35重量%以上、より好ましくは40重量%以上、通常80重量%以下、好ましくは60重量%以下である。水の含有量が少な過ぎると、水分散液の粘度増大により作業性が悪くなり、多過ぎると、相対的にラメラ構造体の量が少なくなるため、冷凍変性防止効果が低下する場合がある。   The content of water (dispersion medium) in the organic acid monoglyceride-containing dispersion is usually 30% by weight or more, preferably 35% by weight or more, more preferably 40% by weight or more, usually 80% by weight or less, preferably 60% by weight. It is as follows. If the water content is too small, the workability deteriorates due to an increase in the viscosity of the aqueous dispersion, and if it is too much, the amount of lamellar structure is relatively reduced, and the effect of preventing freezing and denaturation may be reduced.

ラメラ構造体が形成されているか否かの確認は例えば偏光顕微鏡による観察によって容易に行うことができる。ラメラ構造体が存在する場合は偏光十字が見られる。更に、ラメラ構造体の微細構造は、電子顕微鏡観察により観察することができる。例えば試料を液体窒素で凍結させ、高真空条件下で割断し、割断表面に金属を蒸着させることにより試料のレプリカを作製し、透過型電子顕微鏡(TEM)により観察する。これにより層状のラメラ構造体を観察することができる。   Whether or not the lamella structure is formed can be easily confirmed by observation with a polarizing microscope, for example. If there is a lamella structure, a polarization cross can be seen. Furthermore, the fine structure of the lamella structure can be observed by observation with an electron microscope. For example, a sample is frozen with liquid nitrogen, cleaved under high vacuum conditions, and a replica of the sample is produced by depositing metal on the cleaved surface, and observed with a transmission electron microscope (TEM). Thereby, a layered lamellar structure can be observed.

下記詳述するとおり、本発明では、有機酸モノグリセリド含有分散液を豆腐に接触させ、有機酸モノグリセリド含有分散液が付着した豆腐を冷凍することで、豆腐の冷凍変性を防止でき、解凍後も、冷凍前の豆腐と同等の食感や風味を得ることができる。そのため、有機酸モノグリセリド含有分散液は豆腐の冷凍変性防止剤として使用することができる。   As described in detail below, in the present invention, the organic acid monoglyceride-containing dispersion is brought into contact with tofu, and the tofu on which the organic acid monoglyceride-containing dispersion is adhered can be frozen to prevent freezing and denaturation of tofu. A texture and flavor equivalent to tofu before freezing can be obtained. Therefore, the organic acid monoglyceride-containing dispersion liquid can be used as a freezing denaturation inhibitor for tofu.

3.豆腐への適用
本発明では、有機酸モノグリセリド含有分散液を豆腐に接触させ、有機酸モノグリセリド含有分散液が付着した豆腐を冷凍する。
有機酸モノグリセリド含有分散液は、豆腐の調味液中に含有させて豆腐に接触させることが好ましく、更に有機酸モノグリセリド含有分散液と共に糖類を接触させることが好ましい。
また、このように有機酸モノグリセリド含有分散液を豆腐に接触させて付着させた後、加熱してから冷凍することが好ましい。
3. Application to Tofu In the present invention, the organic acid monoglyceride-containing dispersion is brought into contact with tofu, and the tofu to which the organic acid monoglyceride-containing dispersion is attached is frozen.
The organic acid monoglyceride-containing dispersion is preferably contained in the tofu seasoning and brought into contact with the tofu, and the organic acid monoglyceride-containing dispersion is preferably brought into contact with the saccharide.
In addition, after the organic acid monoglyceride-containing dispersion is brought into contact with tofu and attached in this manner, it is preferably heated and then frozen.

有機酸モノグリセリド含有分散液を豆腐の調味液中に含有させて豆腐に接触させてこれを付着させてから、加熱するには、具体的には、豆腐の調理方法に従って調理する際に、調味液に有機酸モノグリセリド含有分散液、好ましくは有機酸モノグリセリド含有分散液と糖類を添加混合し、この調味液を用いて加熱調理を行えばよい。   The organic acid monoglyceride-containing dispersion liquid is contained in the tofu seasoning liquid, brought into contact with the tofu and attached thereto, and then heated, specifically, when cooking according to the tofu cooking method, the seasoning liquid The organic acid monoglyceride-containing dispersion liquid, preferably the organic acid monoglyceride-containing dispersion liquid and the saccharide are added and mixed, and the seasoning liquid is used for cooking.

有機酸モノグリセリド含有分散液の添加量は、豆腐の調理方法によっても異なるが、豆腐重量に対する有機酸モノグリセリド含有分散液の重量として0.1〜10重量%程度、豆腐重量に対する有機酸モノグリセリド含有分散液中の有機酸モノグリセリドの重量として0.0001〜2重量%となるように、調味液に添加することが好ましい。   The amount of the organic acid monoglyceride-containing dispersion added varies depending on the tofu cooking method, but the weight of the organic acid monoglyceride-containing dispersion with respect to the tofu weight is about 0.1 to 10% by weight, and the organic acid monoglyceride-containing dispersion with respect to the tofu weight It is preferable to add to a seasoning liquid so that it may become 0.0001 to 2 weight% as a weight of the organic acid monoglyceride in it.

有機酸モノグリセリド含有分散液と共に糖類を用いる場合、糖類と有機酸モノグリセリド含有分散液とを予め混合してから調味液に添加混合することが好ましい。
この場合、糖類としては、有機酸モノグリセリド含有分散液が含んでいてもよい糖類として例示したものの1種又は2種以上用いることができ、好ましくはマルトオリゴ糖(好ましくは重合度3〜7)である。
When saccharides are used together with the organic acid monoglyceride-containing dispersion, it is preferable that the saccharide and the organic acid monoglyceride-containing dispersion are mixed in advance and then added to the seasoning liquid.
In this case, as the saccharide, one or two or more of those exemplified as the saccharide that may be contained in the organic acid monoglyceride-containing dispersion can be used, and preferably a maltooligosaccharide (preferably having a polymerization degree of 3 to 7). .

糖類を併用する場合は、30〜90重量%程度の糖類水溶液に、有機酸モノグリセリド含有分散液を添加して溶解させたものを用いることが好ましい。糖類の添加量は、豆腐の調理方法によっても異なるが、有機酸モノグリセリド含有分散液に対して1〜10重量倍程度用いることが好ましく、特に有機酸モノグリセリド含有分散液中の有機酸モノグリセリドに対して0.001〜2重量倍程度用いることが好ましい。有機酸モノグリセリド含有分散液と共に糖類を用いることにより、解凍後の風味をより一層良好なものとすることができる。   When saccharides are used in combination, it is preferable to use a solution in which an organic acid monoglyceride-containing dispersion is added and dissolved in an aqueous saccharide solution of about 30 to 90% by weight. The amount of saccharide added varies depending on the cooking method of tofu, but it is preferably about 1 to 10 times by weight with respect to the organic acid monoglyceride-containing dispersion, and particularly with respect to the organic acid monoglyceride in the organic acid monoglyceride-containing dispersion. It is preferable to use about 0.001 to 2 times by weight. By using saccharides together with the organic acid monoglyceride-containing dispersion, the flavor after thawing can be made even better.

豆腐料理への有機酸モノグリセリド含有分散液の適用方法としては、具体的には次のようなものが挙げられる。   Specific methods for applying the organic acid monoglyceride-containing dispersion to tofu dishes include the following.

(1)麻婆豆腐
有機酸モノグリセリド含有分散液、或いは有機酸モノグリセリド含有分散液と糖類を添加した麻婆豆腐用調味液と、適当な大きさにカットした豆腐を鍋に入れ、必要に応じて、予め炒めたひき肉や刻み長ネギ、グリーンピースやその他の食材、調味料を添加して加熱し、麻婆豆腐とする。
(1) Mapo tofu Organic acid monoglyceride-containing dispersion, or organic acid monoglyceride-containing dispersion and sugar tofu seasoning liquid, and tofu cut into an appropriate size are put in a pan, as necessary. Add the pre-fried minced meat, chopped green onions, green peas and other ingredients, and seasonings and heat to make mapo tofu.

(2)豆腐入り味噌汁、スープ類
有機酸モノグリセリド含有分散液、或いは有機酸モノグリセリド含有分散液と糖類を添加した味噌汁やスープの調味液に、適当な大きさにカットした豆腐と、必要に応じてネギ、その他の野菜や油揚げ等(これらは予め別途加熱調理したものであってもよい)を入れて加熱し、豆腐入り味噌汁、又は豆腐入りスープとする。
(2) Miso soup with tofu, soups Organic acid monoglyceride-containing dispersions, organic acid monoglyceride-containing dispersions and miso soups with added sugar and soup seasonings, and tofu cut into appropriate sizes as needed Add green onions, other vegetables, fried oil, etc. (these may be cooked separately in advance) and heat to make miso soup with tofu or soup with tofu.

(3)豆腐入り炒め物
適当な大きさにカットした豆腐や、必要に応じて、ネギ、肉、その他の食材を油で炒め、ここへ、有機酸モノグリセリド含有分散液、或いは有機酸モノグリセリド含有分散液と糖類を添加した炒め物用の調味液を添加して更に炒めて豆腐入り炒め物とする。
(3) Stir-fried products with tofu and, if necessary, fried green onions, meat, and other ingredients, if necessary, stir-fry them with oil. Dispersion containing organic acid monoglyceride or dispersion containing organic acid monoglyceride Add the seasoning liquid for the stir-fry to which the liquid and saccharides are added and stir-fry to make a stir-fry with tofu.

(4)豆腐のあんかけ
適当な大きさにカットした豆腐を、有機酸モノグリセリド含有分散液、或いは有機酸モノグリセリド含有分散液と糖類を添加しただし汁で煮る。ここへ、別途調理した野菜、肉、キノコ類、魚介類等が入ったあんをかける。この場合、有機酸モノグリセリド含有分散液、或いは有機酸モノグリセリド含有分散液と糖類は、豆腐の煮汁ではなく、あんに添加して豆腐に付着させてもよく、豆腐の煮汁とあんの両方に添加してもよい。
(4) Tofu sauce Tofu cut into an appropriate size is added with an organic acid monoglyceride-containing dispersion, or an organic acid monoglyceride-containing dispersion and saccharides, but boiled in juice. Pour the sauce with vegetables, meat, mushrooms, seafood, etc. separately cooked here. In this case, the organic acid monoglyceride-containing dispersion, or the organic acid monoglyceride-containing dispersion and the saccharide may be added to the tofu instead of the tofu, and added to both the tofu and the tofu. May be.

その他の豆腐の煮物や蒸し物、揚げ物についても、調味液に有機酸モノグリセリド含有分散液、或いは有機酸モノグリセリド含有分散液と糖類を添加したものを用い、これを豆腐に付着させてからその調理に従って更に加熱すればよい。   For other tofu boiled foods, steamed foods, and deep-fried foods, use an organic acid monoglyceride-containing dispersion or a mixture of organic acid monoglyceride-containing dispersion and saccharides in the seasoning liquid. What is necessary is just to heat.

4.冷凍
上記の加熱処理後の豆腐を常法に従って、例えば−15℃〜−30℃に冷却して冷凍し、保存する。この際、緩慢冷凍、急速冷凍のいずれをも採用することができるが、急速冷凍の方が氷晶の粗大化を抑制できることから好ましい。
4). Freezing The tofu after the heat treatment is frozen and stored, for example, by cooling to −15 ° C. to −30 ° C. according to a conventional method. At this time, both slow freezing and quick freezing can be employed, but quick freezing is preferable because it can suppress the coarsening of ice crystals.

5.解凍
本発明により製造された冷凍豆腐の解凍方法としては、豆腐料理の種類や加熱処理の種類などに応じて、室温での放置による自然解凍、冷蔵庫の中で一晩から一昼夜置く庫内解凍、電子レンジによる解凍、流水や湯煎(沸騰水)による解凍などを採用することができる。
5. Thawing As a method of thawing frozen tofu produced according to the present invention, depending on the type of tofu dish and the type of heat treatment, natural thawing by leaving at room temperature, thawing in a refrigerator overnight to leave in a refrigerator, Thawing with a microwave oven, thawing with running water or hot water (boiling water) can be employed.

本発明を実施例によって更に具体的に説明するが、本発明はその要旨を超えない限り、以下の実施例の記載に限定されるものではない。   Examples The present invention will be described more specifically with reference to examples. However, the present invention is not limited to the description of the following examples unless it exceeds the gist.

(製造例1)
HLB11のショ糖ステアリン酸エステル(三菱化学フーズ社製「リョートー(登録商標)シュガーエステルS−1170」)3.5部を室温で、糖類の水溶液としてマルトオリゴ糖水溶液(三和澱粉工業社製「オリゴトース」、マルトオリゴ糖固形分72重量%)60部と水8部の混合液68部に分散し、撹拌しながら加温して75℃まで昇温した(以下「オリゴ糖液」と呼ぶ)。
(Production Example 1)
HLB11 sucrose stearate ("Ryoto (registered trademark) sugar ester S-1170" manufactured by Mitsubishi Chemical Foods Co., Ltd.) 3.5 parts at room temperature as an aqueous solution of maltooligosaccharide (Santo Starch Kogyo Co., Ltd. ”, Dispersed in 68 parts of a mixture of 60 parts of malto-oligosaccharide solid content of 72% by weight and 8 parts of water, heated with stirring and heated to 75 ° C. (hereinafter referred to as“ oligosaccharide liquid ”).

一方、コハク酸モノグリセリド(理研ビタミン社製「ポエムB−30」、脂肪酸としてステアリン酸を用いた)3.5部を脱塩水25部に分散し、60℃まで昇温しながら撹拌し、ラメラ構造体の水分散液を得た。   On the other hand, 3.5 parts of succinic acid monoglyceride ("Poem B-30" manufactured by Riken Vitamin Co., Ltd., using stearic acid as a fatty acid) was dispersed in 25 parts of demineralized water and stirred while raising the temperature to 60 ° C to obtain a lamellar structure An aqueous dispersion of the body was obtained.

前記のオリゴ糖液を55℃まで冷却し、上記のコハク酸モノグリセリドのラメラ構造体の水分散液を加えて20分間撹拌した。次いで、45℃まで冷却することにより、ラメラ構造体の水分散液を調製した(以下「組成物A」と呼ぶ)。なお、組成物Aのコハク酸モノグリセリドのラメラ構造体の確認は偏光顕微鏡による観察によって行った。偏光顕微鏡の写真中に偏光十字が観察され、組成物Aがラメラ構造体を有していることがわかった。   The oligosaccharide solution was cooled to 55 ° C., and the aqueous dispersion of the lamellar structure of the succinic monoglyceride was added and stirred for 20 minutes. Next, an aqueous dispersion of a lamellar structure was prepared by cooling to 45 ° C. (hereinafter referred to as “Composition A”). In addition, confirmation of the lamella structure of the succinic acid monoglyceride of the composition A was performed by observation with a polarizing microscope. A polarization cross was observed in the photograph of the polarizing microscope, and it was found that the composition A had a lamellar structure.

この組成物Aは、ショ糖ステアリン酸エステルを3.5重量%、マルトオリゴ糖を43重量%、コハク酸モノグリセリドのラメラ構造体を3.5重量%含むものである。   This composition A contains 3.5% by weight of sucrose stearate, 43% by weight of maltooligosaccharide, and 3.5% by weight of a lamellar structure of succinic monoglyceride.

(実施例1)
市販の麻婆豆腐用調味液(麻婆豆腐の素、丸美屋社製)120gに上記製造例1で製造された組成物Aを6.8g添加して混合した。
Example 1
6.8 g of the composition A produced in Production Example 1 was added to and mixed with 120 g of a commercially available seasoning solution for mapo tofu (majo tofu base, manufactured by Marumiya Co., Ltd.).

鍋に、予めサイコロ状にカットした豆腐220gと上記組成物Aが添加された麻婆豆腐用調味液を加え、麻婆豆腐用調味液が煮立ったところで、全体を混ぜながら1分間煮た。その後、刻み長ネギ10gと花椒0.5gを入れて軽く混ぜ、麻婆豆腐とした。
この麻婆豆腐を耐熱性の袋に入れ、冷凍した。冷凍された麻婆豆腐を湯煎にて加熱解凍して食感、味を調べたところ、解凍後の豆腐は、鬆がなく表面が滑らかであり、冷凍前と同様に美味しいものであった。
To the pan, 220 g of tofu previously cut in a dice shape and the seasoning solution for mapo tofu to which the above composition A was added were added. When the seasoning solution for mapo tofu was boiled, it was boiled for 1 minute while mixing the whole. Thereafter, 10 g of chopped long onion and 0.5 g of flower buds were added and lightly mixed to obtain mapo tofu.
This mapo tofu was put in a heat-resistant bag and frozen. The frozen mapo tofu was thawed in a hot water bath and examined for texture and taste. As a result, the tofu after thawing was free from voids and had a smooth surface and was as delicious as before freezing.

(実施例2)
マルトオリゴ糖水溶液(三和澱粉工業社製「オリゴトース」、マルトオリゴ糖固形分72重量%)30.4gに組成物A6.8gを溶解させたものを、市販の麻婆豆腐用調味液(麻婆豆腐の素、丸美屋社製)120gに添加して混合した以外は実施例1と同様にして、冷凍麻婆豆腐を製造した後、解凍した。
解凍後の豆腐は鬆がなく表面が滑らかであり、冷凍前と同様に美味しいものであった。また、実施例1よりも花椒の香り立ちがよかった。
(Example 2)
A solution prepared by dissolving 6.8 g of the composition A in 30.4 g of an aqueous solution of maltooligosaccharide (“Oligose” manufactured by Sanwa Starch Kogyo Co., Ltd., malto-oligosaccharide solid content: 72% by weight) Frozen mapo tofu was produced and then thawed in the same manner as in Example 1 except that it was added to and mixed with 120 g of Nomoto, Marumiya Co., Ltd.
The tofu after thawing had no voids and smooth surface, and was as delicious as before freezing. Further, the scent of the florets was better than that of Example 1.

(比較例1)
組成物Aを麻婆豆腐用調味液に添加混合しなかった以外は、実施例1と同様にして冷凍麻婆豆腐を製造した後、解凍した。
解凍後の豆腐には鬆が生じており、美味しいものではなかった。
(Comparative Example 1)
A frozen mapo tofu was produced in the same manner as in Example 1 except that the composition A was not added to and mixed with the mapo tofu seasoning liquid, and then thawed.
The tofu after thawing had a void and was not delicious.

Claims (6)

冷凍豆腐の製造方法であって、
有機酸モノグリセリドを含有する分散液と豆腐を接触させ、
該分散液が付着した豆腐を冷凍することを特徴とする、冷凍豆腐の製造方法。
A method for producing frozen tofu,
Contact the dispersion containing organic acid monoglyceride with tofu,
A method for producing frozen tofu characterized by freezing the tofu to which the dispersion has adhered.
該分散液は豆腐の調味液中に含有されている、請求項1に記載の冷凍豆腐の製造方法。   The method for producing frozen tofu according to claim 1, wherein the dispersion is contained in a tofu seasoning liquid. 該分散液とともに糖類を豆腐と接触させる、請求項1または2に記載の冷凍豆腐の製造方法。   The manufacturing method of the frozen tofu of Claim 1 or 2 which makes saccharides contact with tofu with this dispersion liquid. 該分散液がショ糖脂肪酸エステルおよび/またはポリグリセリン脂肪酸エステルを含有する、
請求項1〜3のいずれか一項に記載の冷凍豆腐の製造方法。
The dispersion contains a sucrose fatty acid ester and / or a polyglycerol fatty acid ester,
The manufacturing method of the frozen tofu as described in any one of Claims 1-3.
有機酸モノグリセリドを含有する分散液と豆腐を接触させ、
加熱した後に冷凍する、請求項1〜4のいずれか一項に記載の冷凍豆腐の製造方法。
Contact the dispersion containing organic acid monoglyceride with tofu,
The manufacturing method of the frozen tofu as described in any one of Claims 1-4 which freezes after heating.
有機酸モノグリセリドを含有する分散液と豆腐を接触させ、
該分散液が付着した豆腐を冷凍することを特徴とする、豆腐の冷凍保存方法。
Contact the dispersion containing organic acid monoglyceride with tofu,
A method for freezing and preserving tofu comprising freezing the tofu to which the dispersion has adhered.
JP2016091097A 2016-04-28 2016-04-28 Method of producing frozen soybean curd Pending JP2017195846A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020089359A (en) * 2018-11-22 2020-06-11 三菱ケミカルフーズ株式会社 Frozen gelatinous food product

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JPS5863359A (en) * 1981-10-09 1983-04-15 Meiji Seika Kaisha Ltd Preparation of dried food
JPH01179659A (en) * 1988-01-11 1989-07-17 Ajinomoto Co Inc Production of freezed soybean curd
JPH03147759A (en) * 1989-11-01 1991-06-24 Kiyohiro Nagai Cooked food of frozen bean curds
JPH05236919A (en) * 1992-03-02 1993-09-17 Kao Corp Quality-improver for frozen food and frozen food containing the agent
JPH11290000A (en) * 1998-04-14 1999-10-26 Dai Ichi Kogyo Seiyaku Co Ltd Emulsifying agent preparation for seasoning and seasoning composition containing the same
JP2009297024A (en) * 2008-05-16 2009-12-24 Mitsubishi Chemicals Corp Food product-conditioning agent and food product
JP2011172563A (en) * 2010-01-28 2011-09-08 Mitsubishi-Kagaku Foods Corp Quality improver for food and food
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Publication number Priority date Publication date Assignee Title
JPS5863359A (en) * 1981-10-09 1983-04-15 Meiji Seika Kaisha Ltd Preparation of dried food
JPH01179659A (en) * 1988-01-11 1989-07-17 Ajinomoto Co Inc Production of freezed soybean curd
JPH03147759A (en) * 1989-11-01 1991-06-24 Kiyohiro Nagai Cooked food of frozen bean curds
JPH05236919A (en) * 1992-03-02 1993-09-17 Kao Corp Quality-improver for frozen food and frozen food containing the agent
JPH11290000A (en) * 1998-04-14 1999-10-26 Dai Ichi Kogyo Seiyaku Co Ltd Emulsifying agent preparation for seasoning and seasoning composition containing the same
JP2009297024A (en) * 2008-05-16 2009-12-24 Mitsubishi Chemicals Corp Food product-conditioning agent and food product
JP2011172563A (en) * 2010-01-28 2011-09-08 Mitsubishi-Kagaku Foods Corp Quality improver for food and food
JP2015173622A (en) * 2014-03-14 2015-10-05 太陽化学株式会社 freeze denaturation inhibitor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020089359A (en) * 2018-11-22 2020-06-11 三菱ケミカルフーズ株式会社 Frozen gelatinous food product
JP7497569B2 (en) 2018-11-22 2024-06-11 三菱ケミカル株式会社 Frozen gel food

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