JP2017189817A - Lime-titania type coated arc welding electrode - Google Patents
Lime-titania type coated arc welding electrode Download PDFInfo
- Publication number
- JP2017189817A JP2017189817A JP2017014408A JP2017014408A JP2017189817A JP 2017189817 A JP2017189817 A JP 2017189817A JP 2017014408 A JP2017014408 A JP 2017014408A JP 2017014408 A JP2017014408 A JP 2017014408A JP 2017189817 A JP2017189817 A JP 2017189817A
- Authority
- JP
- Japan
- Prior art keywords
- total
- arc
- mass
- arc welding
- lime
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000003466 welding Methods 0.000 title claims abstract description 77
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 48
- 229910052751 metal Inorganic materials 0.000 claims abstract description 36
- 239000002184 metal Substances 0.000 claims abstract description 36
- 238000000576 coating method Methods 0.000 claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 8
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 7
- 239000010959 steel Substances 0.000 claims abstract description 7
- 229910000640 Fe alloy Inorganic materials 0.000 claims abstract description 4
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 18
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 18
- 239000004571 lime Substances 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 14
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000002893 slag Substances 0.000 abstract description 57
- 229910052748 manganese Inorganic materials 0.000 abstract description 4
- 239000005416 organic matter Substances 0.000 abstract description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 24
- 239000010936 titanium Substances 0.000 description 23
- 239000011324 bead Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 17
- 239000011734 sodium Substances 0.000 description 16
- 239000011572 manganese Substances 0.000 description 13
- 239000000395 magnesium oxide Substances 0.000 description 12
- 239000000292 calcium oxide Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 8
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000010433 feldspar Substances 0.000 description 3
- 238000009863 impact test Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910002551 Fe-Mn Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910006639 Si—Mn Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 229910002593 Fe-Ti Inorganic materials 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Landscapes
- Nonmetallic Welding Materials (AREA)
Abstract
Description
本発明は、溶接作業性等の諸性能を確保すると共に特にスラグ剥離性を向上させる上で好適なライムチタニヤ系被覆アーク溶接棒に関するものである。 The present invention relates to a lime titania-based coated arc welding rod suitable for ensuring various performances such as welding workability and improving slag removability.
非低水素系被覆アーク溶接棒は、各種被覆アーク溶接棒に比べて溶接作業性に優れることから、軟鋼及び４９０ＭＰａ級高張力鋼の溶接に多く使用される。中でもライムチタニヤ系被覆アーク溶接棒は、ビード外観が良好で、スパッタ発生量が少なく、再アーク性が良好であるため、車両、建築等の一般構造物に広く使用されている。 Non-low hydrogen-based coated arc welding rods are excellent in welding workability compared to various coated arc welding rods, and are therefore often used for welding mild steel and 490 MPa class high strength steel. Among them, lime titania-based coated arc welding rods are widely used in general structures such as vehicles and buildings because of their good bead appearance, low spatter generation, and good re-arcing properties.
しかし、ライムチタニヤ系被覆アーク溶接棒で狭開先の突合せ溶接を行った場合、スラグ剥離性が不良となり、溶接作業効率が悪化してしまうという問題点がある。 However, when butt welding with a narrow groove is performed with a lime titania-based coated arc welding rod, there is a problem that the slag peelability becomes poor and the welding work efficiency deteriorates.
このため、非低水素系被覆アーク溶接棒のスラグ剥離性の改善を図るため、従来より種々の提案がされている。例えば、特許文献１には、ライムチタニヤ系被覆アーク溶接の被覆剤中のＭｇＯ及び結晶水の含有量を規定し、ＭｇＯによってスラグの粘性を維持しつつ、結晶水から発生する水素をスラグ中に拡散させて多孔質化することで、スラグ剥離性を改善する技術が開示されている。この技術によれば、ライムチタニヤ系被覆アーク溶接棒のスラグ剥離性を改善することはできるが、狭開先の突合せ溶接等の厳しい溶接環境下では、十分なスラグ剥離性が得られないという問題点があった。 For this reason, various proposals have heretofore been made in order to improve the slag peelability of the non-low hydrogen-based coated arc welding rod. For example, Patent Document 1 defines the contents of MgO and crystallization water in a lime titania-based coated arc welding coating, and diffuses hydrogen generated from crystallization water into the slag while maintaining the viscosity of the slag by MgO. A technique for improving the slag peelability by making it porous is disclosed. According to this technology, the slag peelability of the lime titania-based coated arc welding rod can be improved, but sufficient slag peelability cannot be obtained in severe welding environments such as butt welding of narrow grooves. was there.
また特許文献２には、非低水素系被覆アーク溶接棒の被覆剤中の酸化鉄の合計量を極力抑えてスラグの熱膨張と収縮の差を大きくすることで、スラグ剥離性を改善する技術が開示されている。さらに、特許文献３には、イルミナイト系被覆アーク溶接の被覆剤中のＮｂ2Ｏ5及びＶ2Ｏ5等を低減することでスラグ剥離性を改善する技術が開示されている。しかし、この特許文献２、３の開示技術は、いずれも狭開先の突合せ溶接等の厳しい溶接環境下の場合では、十分なスラグ剥離性は確保できないという問題点があった。 Patent Document 2 discloses a technique for improving the slag peelability by suppressing the total amount of iron oxide in the coating material of the non-low hydrogen-based coated arc welding rod as much as possible and increasing the difference between thermal expansion and contraction of the slag. Is disclosed. Furthermore, Patent Document 3 discloses a technique for improving slag peelability by reducing Nb 2 O 5, V 2 O 5, and the like in a coating material for illuminite-based coated arc welding. However, the disclosed techniques of Patent Documents 2 and 3 have a problem that sufficient slag peelability cannot be ensured in a severe welding environment such as butt welding with a narrow groove.
そこで本発明は、上述した問題点に鑑みて案出されたものであり、溶接作業性等の諸性能を確保すると共に、狭開先の突合せ溶接等の厳しい溶接環境下においても十分なスラグ剥離性を確保することが可能なライムチタニヤ系被覆アーク溶接棒を提供することを目的とする。 Accordingly, the present invention has been devised in view of the above-described problems, and ensures various performances such as welding workability and sufficient slag peeling even in severe welding environments such as narrow gap butt welding. An object of the present invention is to provide a lime titania-based coated arc welding rod capable of ensuring the properties.
本発明の要旨は、
（１）鋼心線に被覆剤が被覆されているライムチタニヤ系被覆アーク溶接棒において、前記被覆剤は、被覆剤全質量に対する質量％で、金属炭酸塩の１種または２種以上の合計：１０〜２０％、Ｔｉ酸化物のＴｉＯ2換算値の合計：１０〜２５％、Ｓｉ酸化物のＳｉＯ2換算値の合計：１０〜２５％、Ａｌ酸化物のＡｌ2Ｏ3換算値の合計：１〜３％、有機物の１種または２種以上の合計：２〜６％、ＣａＯ：０．０１〜１．５０％、ＭｇＯ：１〜４％、Ｍｎ：２〜８％、鉄粉：２０〜４０％、Ｎａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計：０．５〜３．５％を含有し、残部が塗装剤、鉄合金からのＦｅ分及び不可避不純物からなることを特徴とするライムチタニヤ系被覆アーク溶接棒である。
The gist of the present invention is as follows:
(1) In a lime titania-based coated arc welding rod in which a coating material is coated on a steel core wire, the coating material is a mass% based on the total mass of the coating material, and a total of one or more metal carbonates: 10 -20%, total of TiO 2 converted value of Ti oxide: 10-25%, total of SiO 2 converted value of Si oxide: 10-25%, total of Al 2 O 3 converted value of Al oxide: 1 -3%, total of one or more organic substances: 2-6%, CaO: 0.01-1.50%, MgO: 1-4%, Mn: 2-8%, iron powder: 20- 40%, total of Na 2 O converted value and K 2 O converted value of Na compound and K compound: 0.5 to 3.5%, the balance is from coating agent, Fe content from iron alloy and inevitable impurities This is a lime-titania-based coated arc welding rod.
（２）被覆剤全質量に対する質量％で、Ｔｉ：０．０３〜０．５０％をさらに含有することを特徴とする（１）記載のライムチタニヤ系被覆アーク溶接棒である。 (2) The lime titania-based coated arc welding rod according to (1), further comprising Ti: 0.03 to 0.50% in terms of mass% with respect to the total mass of the coating agent.
（３）被覆剤全質量に対する質量％で、硫化鉄：０．０１〜０．０５％をさらに含有することを特徴とする（１）または（２）に記載のライムチタニヤ系被覆アーク溶接棒である。 (3) The lime titania-based coated arc welding rod according to (1) or (2), further comprising iron sulfide: 0.01 to 0.05% by mass% relative to the total mass of the coating agent. .
本発明のライムチタニヤ系被覆アーク溶接棒によれば、良好な溶接作業性等の諸性能を確保でき、特にスラグ剥離性に優れているので、溶接作業能率の向上に大いに貢献できる。 According to the lime titania-based coated arc welding rod of the present invention, various performances such as good welding workability can be ensured, and in particular, since the slag peelability is excellent, it can greatly contribute to the improvement of the welding work efficiency.
本発明者らは、上記課題を解決するために、ライムチタニヤ系被覆アーク溶接棒を作製し、スラグ剥離性等の溶接作業性について詳細に調査した。その結果、狭開先の突合せ溶接等の特に初層溶接では、溶融池を被包する溶融スラグの被包状態が不均一で、溶融スラグがビード表面に焼き付きやすく、スラグ剥離性が不良になることを突き止めた。そこで、ライムチタニヤ系被覆アーク溶接棒の特徴である優れたビード形状や外観、再アーク性、アーク安定性等の溶接作業性及び溶接金属の機械性能を維持しながらスラグ剥離性を改善する方法を種々検討した結果、被覆剤中にＭｎを適量添加することで必要な溶接金属の機械性能を確保し、Ｔｉ酸化物、Ｓｉ酸化物、Ａｌ酸化物、ＣａＯ、Ｎａ化合物及びＫ化合物を適量添加することでアーク安定性を向上させてスパッタ量を低減し、Ｔｉ酸化物を適量添加することでビード形状や外観を良好にし、有機物及び鉄粉を適量添加することで再アーク性、耐棒焼け性及び耐被覆欠け性を改善し、金属炭酸塩及びＭｎを適量添加することでブローホール等の溶接欠陥を防止できることを見出した。一方、スラグ剥離性に関しては、Ｓｉ酸化物、ＣａＯを適量添加することで溶融スラグの表面張力を下げることができ、溶融スラグが溶融池全面を均一に被包できるようになるので、スラグ焼き付きを防止でき、十分なスラグ剥離性が得られることを見出した。 In order to solve the above-mentioned problems, the present inventors produced a lime titania-based coated arc welding rod and investigated in detail the welding workability such as slag peelability. As a result, especially in the first layer welding such as butt welding of narrow grooves, the enveloping state of the molten slag encapsulating the molten pool is uneven, and the molten slag tends to seize on the bead surface, resulting in poor slag removability. I found out. Therefore, there are various methods for improving the slag peelability while maintaining the weldability such as the excellent bead shape and appearance, rearcability, arc stability, and the mechanical performance of the weld metal, which are the characteristics of lime-titania coated arc welding rods. As a result of investigation, the mechanical performance of the required weld metal is ensured by adding an appropriate amount of Mn to the coating material, and an appropriate amount of Ti oxide, Si oxide, Al oxide, CaO, Na compound and K compound is added. In order to improve arc stability and reduce the amount of spatter, adding a proper amount of Ti oxide improves the bead shape and appearance, and by adding a proper amount of organic matter and iron powder, It has been found that welding defects such as blow holes can be prevented by improving the resistance to chipping of the coating and adding appropriate amounts of metal carbonate and Mn. On the other hand, with regard to slag peelability, the surface tension of molten slag can be lowered by adding appropriate amounts of Si oxide and CaO, and the molten slag can uniformly encapsulate the entire surface of the molten pool. It was found that sufficient slag peelability can be obtained.
また、Ｔｉの添加量を調整することにより、さらにアークが安定し、溶接金属の靱性も良好になることを見出した。また、硫化鉄の添加量を調整することにより、さらにスラグ剥離性が良好になることも見出した。 Further, it has been found that adjusting the amount of Ti added further stabilizes the arc and improves the toughness of the weld metal. It was also found that the slag peelability is further improved by adjusting the amount of iron sulfide added.
以下、本発明におけるライムチタニヤ系被覆アーク溶接棒の被覆剤の成分組成と、その成分組成の限定理由について詳細に説明する。なお、各成分組成の含有量は、被覆剤全質量に対する質量％で表すこととし、その質量％を表すときには単に％と記載することとする。 Hereinafter, the component composition of the coating material of the lime titania-based coated arc welding rod in the present invention and the reason for limiting the component composition will be described in detail. The content of each component composition is expressed as mass% with respect to the total mass of the coating agent, and when expressing the mass%, it is simply described as%.
［金属炭酸塩の１種または２種以上の合計：１０〜２０％］
金属炭酸塩は、炭酸カルシウム、炭酸マグネシウム、炭酸バリウム、炭酸マンガン、炭酸リチウム等から添加され、アーク中で分解してＣＯ2ガスを発生させて溶着金属を大気から遮蔽して保護する効果を有する。金属炭酸塩の１種または２種以上の合計が１０％未満であると、シールド効果が不足してブローホールが発生しやすくなる。一方、金属炭酸塩の１種または２種以上の合計が２０％を超えると、アークが不安定で凸ビードとなり、スラグ剥離性も悪くなる。したがって、被覆剤中の金属炭酸塩の１種または２種以上の合計は１０〜２０％とする。
[Total of one or more metal carbonates: 10 to 20%]
Metal carbonate is added from calcium carbonate, magnesium carbonate, barium carbonate, manganese carbonate, lithium carbonate, etc. and decomposes in the arc to generate CO 2 gas and has an effect of shielding and protecting the deposited metal from the atmosphere. . When the total of one or more of the metal carbonates is less than 10%, the shielding effect is insufficient and blow holes are likely to occur. On the other hand, if the total of one or more of the metal carbonates exceeds 20%, the arc becomes unstable and becomes a convex bead, and the slag peelability is also deteriorated. Therefore, the total of one or more metal carbonates in the coating agent is 10 to 20%.
［Ｔｉ酸化物のＴｉＯ2換算値の合計：１０〜２５％］
Ｔｉ酸化物は、ルチール、酸化チタン、チタン酸ソーダ、チタンスラグ等から添加され、スラグ生成剤及びアーク安定剤として作用し、アーク安定性及びビード形状や外観を改善する効果を有する。Ｔｉ酸化物のＴｉＯ2換算値の合計が１０％未満であると、アークが不安定になるとともに、スラグ流動性が悪くなってビード形状や外観が不良となる。一方、Ｔｉ酸化物のＴｉＯ2換算値の合計が２５％を超えると、スラグが緻密になってスラグ剥離性が不良となる。したがって、被覆剤中のＴｉ酸化物のＴｉＯ2換算値の合計は、１０〜２５％とする。
[Total of TiO 2 converted values of Ti oxide: 10 to 25%]
Ti oxide is added from rutile, titanium oxide, sodium titanate, titanium slag, etc., and acts as a slag generator and arc stabilizer, and has an effect of improving arc stability, bead shape and appearance. When the total of TiO 2 converted values of the Ti oxide is less than 10%, the arc becomes unstable and the slag fluidity is deteriorated, resulting in poor bead shape and appearance. On the other hand, if the total of TiO 2 converted values of the Ti oxide exceeds 25%, the slag becomes dense and the slag peelability becomes poor. Therefore, the total of the TiO 2 converted values of the Ti oxide in the coating agent is 10 to 25%.
［Ｓｉ酸化物のＳｉＯ2換算値の合計：１０〜２５％］
Ｓｉ酸化物は、珪砂、長石、水ガラス等から添加され、スラグ生成剤及びアーク安定剤として作用し、アーク安定性及びスラグ剥離性を改善する効果を有する。Ｓｉ酸化物のＳｉＯ2換算値の合計が１０％未満であると、アークが弱く不安定になるとともに、生成したスラグのガラス質が少なくなり、スラグ剥離性が不良になる。一方、Ｓｉ酸化物のＳｉＯ2換算値の合計が２５％を超えると、スラグの粘性が高くなってビード形状が不良となる。したがって、被覆剤中のＳｉ酸化物のＳｉＯ2換算値の合計は、１０〜２５％とする。
[Total of SiO 2 conversion value of Si oxide: 10 to 25%]
Si oxide is added from silica sand, feldspar, water glass, etc., and acts as a slag generator and an arc stabilizer, and has an effect of improving arc stability and slag peelability. When the total of SiO 2 conversion values of the Si oxide is less than 10%, the arc becomes weak and unstable, and the generated slag becomes less vitreous, resulting in poor slag peelability. On the other hand, if the total of SiO 2 conversion values of Si oxide exceeds 25%, the viscosity of the slag becomes high and the bead shape becomes poor. Therefore, the total of SiO 2 conversion values of the Si oxide in the coating agent is 10 to 25%.
［Ａｌ酸化物のＡｌ2Ｏ3換算値の合計：１〜３％］
Ａｌ酸化物は、アルミナ、長石、珪砂、マイカ等から添加され、アークを安定にする効果を有する。Ａｌ酸化物のＡｌ2Ｏ3換算値の合計が１％未満では、アークが弱く不安定となる。一方、Ａｌ酸化物のＡｌ2Ｏ3換算値の合計が３％を超えると、スラグ剥離性が不良となる。したがって、被覆剤中のＡｌ酸化物のＡｌ2Ｏ3換算値の合計は１〜３％とする。
Total of terms of Al 2 O 3 value of Al oxides: 1-3%]
Al oxide is added from alumina, feldspar, silica sand, mica, etc., and has an effect of stabilizing the arc. When the total of Al 2 O 3 converted values of Al oxide is less than 1%, the arc is weak and unstable. On the other hand, when the total Al 2 O 3 conversion value of the Al oxide exceeds 3%, the slag peelability becomes poor. Therefore, the total of Al 2 O 3 conversion values of the Al oxide in the coating agent is 1 to 3%.
［有機物の１種または２種以上の合計：２〜６％］
有機物は、セルロース、デキストリン、小麦粉、澱粉、コーンスターチ等から添加され、再アーク性を改善するともに、耐被覆欠け性の改善にも有効である。有機物の１種または２種以上の合計が２％未満であると、良好な再アーク性が得られず、被覆欠けが発生しやすくなる。一方、有機物の１種または２種以上の合計が６％を超えると、アークが強くなりすぎ、ビード形状が不良となる。また、被覆剤が赤熱して棒焼けが発生しやすくなる。したがって、被覆剤中の有機物の１種または２種以上の合計は２〜６％とする。
[Total of one or more organic substances: 2 to 6%]
Organic substances are added from cellulose, dextrin, wheat flour, starch, corn starch, etc., and are effective in improving the resistance to chipping loss as well as improving the re-arcing property. When the total of one kind or two or more kinds of organic substances is less than 2%, good re-arcing property cannot be obtained, and coating failure tends to occur. On the other hand, when the total of one or more organic substances exceeds 6%, the arc becomes too strong and the bead shape becomes poor. In addition, the coating agent becomes red hot and bar burning tends to occur. Therefore, the total of one or more organic substances in the coating is 2 to 6%.
［ＣａＯ：０．０１〜１．５０％］
ＣａＯは、珪灰石、チタン酸カルシウム等から添加され、アークを安定化させ、スパッタ低減に有効である。ＣａＯが０．０１％未満では、その効果が得られず、アークが不安定となり、スパッタ量が多くなる。一方、ＣａＯが１．５０％を超えると、アークが弱くなって不安定になり、融合不良等の溶接欠陥が発生しやすくなる。したがって、被覆剤中のＣａＯは０．０１〜１．５０％とする。
[CaO: 0.01 to 1.50%]
CaO is added from wollastonite, calcium titanate, etc., stabilizes the arc, and is effective in reducing spatter. If CaO is less than 0.01%, the effect cannot be obtained, the arc becomes unstable, and the amount of sputtering increases. On the other hand, if CaO exceeds 1.50%, the arc becomes weak and unstable, and welding defects such as poor fusion tend to occur. Therefore, CaO in the coating agent is set to 0.01 to 1.50%.
［ＭｇＯ：１〜４％］
ＭｇＯは、マグネシアクリンカー等から添加され、スラグ剥離性を改善する効果を有する。ＭｇＯが１％未満では、その効果が得られず、スラグ剥離性が不良になる。一方、ＭｇＯが４％を超えると、スラグ自体が硬くなってビード形状が凸状になる。したがって、被覆剤中のＭｇＯは１〜４％とする。
[MgO: 1-4%]
MgO is added from magnesia clinker or the like, and has an effect of improving slag peelability. If MgO is less than 1%, the effect cannot be obtained and the slag peelability becomes poor. On the other hand, if MgO exceeds 4%, the slag itself becomes hard and the bead shape becomes convex. Therefore, MgO in the coating agent is 1 to 4%.
［Ｍｎ：２〜８％］
Ｍｎは、金属Ｍｎ、Ｆｅ−Ｍｎ、Ｆｅ−Ｓｉ−Ｍｎ等から添加され、脱酸剤として添加する他、溶接金属の強度及び靭性向上に有効である。Ｍｎが２％未満では、脱酸不足となり、ブローホールが発生しやすくなる。また、溶接金属の強度及び靭性が低下する。一方、Ｍｎが８％を超えると、溶接金属の強度が過剰に高くなり、靭性が低下する。したがって、被覆剤中のＭｎは２〜８％とする。
[Mn: 2 to 8%]
Mn is added from metal Mn, Fe-Mn, Fe-Si-Mn, etc., and is added as a deoxidizer, and is effective in improving the strength and toughness of the weld metal. If Mn is less than 2%, deoxidation is insufficient and blowholes are likely to occur. Moreover, the strength and toughness of the weld metal are reduced. On the other hand, if Mn exceeds 8%, the strength of the weld metal becomes excessively high and the toughness is lowered. Therefore, Mn in the coating agent is 2 to 8%.
［鉄粉：２０〜４０％］
鉄粉は、再アーク性を改善する効果を有する。鉄粉が２０％未満であると、良好な再アーク性を得ることはできない。一方、鉄粉が４０％を超えると、被覆筒が短くなってアークが不安定となるとともに、被覆の電気伝導性が過剰に高くなってサイドアークが発生しやすくなる。したがって、被覆剤中の鉄粉は２０〜４０％とする。
[Iron powder: 20-40%]
Iron powder has the effect of improving the re-arcing property. When the iron powder is less than 20%, good rearcability cannot be obtained. On the other hand, if the iron powder exceeds 40%, the coated cylinder becomes short and the arc becomes unstable, and the electrical conductivity of the coating becomes excessively high, so that a side arc is likely to occur. Therefore, the iron powder in the coating is 20 to 40%.
［Ｎａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計：０．５〜３．５％］
Ｎａ化合物及びＫ化合物は、水ガラス中の珪酸ソーダ、珪酸カリウム、カリ長石、カリガラス及びソーダ長石等から添加され、アーク安定性を改善する効果を有する。Ｎａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計が０．５％未満では、アークが不安定になる。一方、Ｎａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計が３．５％を超えると、再アーク性が不良になる。したがって、被覆剤中のＮａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計は０．５〜３．５％とする。
[Total of Na 2 O converted value and K 2 O converted value of Na compound and K compound: 0.5 to 3.5%]
Na compound and K compound are added from sodium silicate, potassium silicate, potassium feldspar, potash glass, soda feldspar and the like in water glass, and have an effect of improving arc stability. When the total of Na 2 O converted value and K 2 O converted value of Na compound and K compound is less than 0.5%, the arc becomes unstable. On the other hand, when the total of Na 2 O converted value and K 2 O converted value of Na compound and K compound exceeds 3.5%, the re-arcing property becomes poor. Therefore, the total of Na 2 O equivalent value and K 2 O equivalent value of Na compound and K compound in the coating agent is 0.5 to 3.5%.
［Ｔｉ：０．０３〜０．５０％］
Ｔｉは、金属Ｔｉ、Ｆｅ−Ｔｉ等から添加され、アークの電位頻度を低下させてアークを安定化させる効果を有する。またＴｉは、脱酸剤として有効で、溶接金属中に歩留まって溶接金属のミクロ組織を微細化して靱性を向上させる働きがある。Ｔｉが０．０３％未満では、アークが不安定となるとともに、脱酸不足となって溶接金属の靭性が低下する。一方、Ｔｉが０．５０％を超えると、溶接金属中のＴｉ酸化物の析出が増加して溶接金属の靱性が低下する。したがって、被覆剤中のＴｉは０．０３〜０．５０％とする。
[Ti: 0.03-0.50%]
Ti is added from metal Ti, Fe-Ti, or the like, and has an effect of stabilizing the arc by reducing the frequency of the arc potential. Ti is also effective as a deoxidizer and has a function of improving the toughness by yielding in the weld metal and refining the microstructure of the weld metal. If Ti is less than 0.03%, the arc becomes unstable and deoxidation becomes insufficient, and the toughness of the weld metal decreases. On the other hand, when Ti exceeds 0.50%, precipitation of Ti oxide in the weld metal increases and the toughness of the weld metal decreases. Therefore, Ti in the coating agent is 0.03 to 0.50%.
［硫化鉄：０．０１〜０．０５％］
硫化鉄は、溶融スラグの表面張力を下げて溶融池とのなじみを良好にし、溶融スラグを溶融池全面に均一に被包させることで、溶接ビード表面へのスラグ焼き付きを防止してスラグ剥離性を改善する効果を有する。硫化鉄が０．０１％未満では、その効果が得られず、ビード表面にスラグ焼き付きが発生してスラグ剥離性が不良となる。一方、硫化鉄が０．０５％を超えると、溶接金属の靭性が低下するとともに、高温割れが発生しやすくなる。したがって、被覆剤中の硫化鉄は０．０１〜０．０５％とする。
[Iron sulfide: 0.01-0.05%]
Iron sulfide lowers the surface tension of the molten slag to improve its compatibility with the molten pool, and evenly encapsulates the molten slag over the entire molten pool, preventing slag seizure on the weld bead surface and slag release. Has the effect of improving. If the iron sulfide is less than 0.01%, the effect cannot be obtained, and slag seizure occurs on the bead surface, resulting in poor slag removability. On the other hand, when iron sulfide exceeds 0.05%, the toughness of the weld metal is lowered and hot cracking is likely to occur. Therefore, the iron sulfide in the coating agent is set to 0.01 to 0.05%.
なお、本発明のライムチタニヤ系被覆アーク溶接棒の被覆剤の残部には、塗装剤としてアルギン酸ソーダ、マイカ等の１種以上を合計で６％以下含有することができ、その他はＦｅ−Ｍｎ、Ｆｅ−Ｓｉ−Ｍｎ等の鉄合金からのＦｅ分及び不可避不純物である。 In addition, the remainder of the coating material of the lime titania-based coated arc welding rod of the present invention may contain a total of 6% or less of one or more types such as sodium alginate and mica as a coating agent, and the others are Fe-Mn, Fe -Fe content and inevitable impurities from iron alloys such as Si-Mn.
また、使用する軟鋼心線は、ＪＩＳ Ｇ３５２３ ＳＷＹ１１を用いることが好ましい。さらに、軟鋼心線中のＣは、軟鋼心線全質量に対する質量％で０．０５〜０．０８％、被覆アーク溶接棒全質量に対する質量％で、軟鋼心線と被覆剤の合計でＣは０．０６〜０．２０％、Ｐは靭性が低化するので０．０１０％以下であることが好ましい。また、被覆剤の軟鋼心線への被覆率（アーク溶接棒全質量に対する被覆剤の質量％）は、２５〜４０％であることが好ましい。 Moreover, it is preferable to use JIS G3523 SWY11 for the soft steel core wire to be used. Further, C in the mild steel core wire is 0.05 to 0.08% by mass% with respect to the total mass of the mild steel core wire, and mass% with respect to the total mass of the coated arc welding rod, and C is the sum of the mild steel core wire and the coating agent. 0.06 to 0.20% and P is preferably 0.010% or less because the toughness decreases. Moreover, it is preferable that the coating rate (mass% of the coating agent with respect to the total mass of an arc welding rod) to the mild steel core wire of a coating agent is 25 to 40%.
本発明の効果を実施例により具体的に説明する。 The effects of the present invention will be specifically described with reference to examples.
表１に示す各種成分組成の被覆剤を直径３．２ｍｍ、長さ３５０ｍｍのＪＩＳ Ｇ３５２３ ＳＷＹ１１の軟鋼心線（軟鋼心線全質量に対して、Ｃ:０．０６質量％、Ｓｉ:０．０１質量％、Ｍｎ:０．４８質量％、Ｐ:０．００９質量％、Ｓ:０．００５質量％）に被覆率３６％で塗装することで被覆した後に乾燥して各種ライムチタニヤ系被覆アーク溶接棒を試作した。 JIS G3523 SWY11 soft steel core wire with a diameter of 3.2 mm and a length of 350 mm (C: 0.06% by mass, Si: 0.01% with respect to the total mass of the soft steel core wire) (Mass%, Mn: 0.48% by mass, P: 0.009% by mass, S: 0.005% by mass) by coating at a coating rate of 36% and then dried and various lime titania-based coated arc welding rods Prototyped.
溶接作業性の評価は、板厚９ｍｍのＪＩＳ Ｇ ３１０１ ＳＳ４００の軟鋼板を、開先角度３０°、Ｇａｐ：２ｍｍの開先形状に組んだ試験体を用い、二次側無負荷電圧が６０Ｖの小型溶接機を使用し、溶接電流１００〜１４０Ａで下向溶接を行い、アーク安定性、スパッタ発生状態、スラグ剥離性、ビード形状及び外観、溶接不良の有無を評価した。この溶接不良の有無は、被覆欠け、棒焼け高温割れ、サイドアーク発生の有無を調査した。 Welding workability was evaluated by using a specimen in which a 9 mm thick JIS G 3101 SS400 mild steel sheet was assembled into a groove shape with a groove angle of 30 ° and a gap of 2 mm, and the secondary no-load voltage was 60V. Using a small welding machine, downward welding was performed at a welding current of 100 to 140 A, and arc stability, spatter generation state, slag peelability, bead shape and appearance, and the presence or absence of poor welding were evaluated. The presence / absence of this welding defect was investigated for the presence of chipping, bar burned hot cracks, and side arcs.
また、再アーク性は、１０秒間溶接した後、直ちにアークが発生したものを合格とし、試験本数を２０本とし、２０本中１６本合格したものを良好とした。 Further, the re-arcing property was determined to be acceptable when arcing occurred immediately after welding for 10 seconds, and the number of test pieces was 20, and 16 of 20 samples were satisfactory.
機械性能の評価は、板厚１６ｍｍのＪＩＳ Ｇ ３１０６ ＳＭ４９０Ａを用い、ＪＩＺ Ｚ３１１１に準じて交流溶接機で溶着金属試験を行い、引張試験片（Ａ２号）と衝撃試験片（Ｖノッチ試験片）を採取して引張試験及び衝撃試験を行った。 The mechanical performance was evaluated using a JIS G 3106 SM490A with a plate thickness of 16 mm and conducting a weld metal test with an AC welding machine in accordance with JIS Z3111. Tensile test pieces (A2) and impact test pieces (V-notch test pieces) were used. The sample was collected and subjected to a tensile test and an impact test.
引張試験の評価は、引張強さが４００〜５６０ＭＰａを良好とした。また、靭性の評価は、試験温度０℃でシャルピー衝撃試験を行い、各々繰り返し３回の吸収エネルギーの平均値が６０Ｊ以上を良好とした。 In the evaluation of the tensile test, a tensile strength of 400 to 560 MPa was considered good. In addition, the evaluation of toughness was carried out by performing a Charpy impact test at a test temperature of 0 ° C., and the average value of the absorbed energy of 3 times was determined to be 60 J or more.
溶接欠陥の評価は、溶着金属試験後の試験体を、ＪＩＳ Ｚ ３１０６に準じてＸ線透過試験を実施し、ブローホール及び融合不良等の有無を調査した。これらの調査結果を表２にまとめて示す。 For the evaluation of welding defects, the specimen after the weld metal test was subjected to an X-ray transmission test according to JIS Z 3106, and the presence or absence of blowholes and poor fusion was investigated. These survey results are summarized in Table 2.
表１及び表２中、溶接棒Ｎｏ．１〜Ｎｏ．１０が本発明例、溶接棒Ｎｏ．１１〜Ｎｏ．２０は比較例である。 In Tables 1 and 2, the welding rod No. 1-No. 10 is an example of the present invention, welding rod No. 11-No. 20 is a comparative example.
本発明例である溶接棒Ｎｏ．１〜Ｎｏ．１０は、表１中の溶接棒Ｎｏ．１〜Ｎｏ．１０は、被覆剤中の金属炭酸塩の合計、Ｔｉ酸化物のＴｉＯ2換算値の合計、Ｓｉ酸化物のＳｉＯ2換算値の合計、Ａｌ酸化物のＡｌ2Ｏ3換算値の合計、有機物の合計、ＣａＯ、ＭｇＯ、Ｍｎ、鉄粉、Ｎａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計が適正であるので、アークが安定で、スパッタ量が少なく、再アーク性、スラグ剥離性及びビード外観・形状が良好であった。また、被覆欠け、棒焼け、サイドアーク等の溶接不良も発生せず、ブローホール、融合不良、高温割れもなく、溶着金属の引張強さ及び吸収エネルギーも良好で、極めて満足な結果であった。 The welding rod no. 1-No. 10 is a welding rod No. 1 in Table 1. 1-No. 10 is a total of metal carbonates in the coating, a total of TiO 2 converted values of Ti oxide, a total of SiO 2 converted values of Si oxide, a total of Al 2 O 3 converted values of Al oxide, The total of CaO, MgO, Mn, iron powder, Na compound and K compound Na 2 O conversion value and K 2 O conversion value is appropriate, so the arc is stable, the amount of spatter is small, re-arcing property, Slag peelability and bead appearance / shape were good. In addition, there were no weld defects such as chipping, bar burn, side arc, etc., no blowholes, poor fusion, high temperature cracking, and the tensile strength and absorbed energy of the weld metal were good, giving very satisfactory results. .
なお、溶接棒Ｎｏ．１、Ｎｏ．３、Ｎｏ．４及びＮｏ８は、被覆剤中にＴｉが添加されているのでアークが非常に安定で、溶着金属の吸収エネルギーが１００Ｊ以上と非常に良好であった。また、溶接棒Ｎｏ．３、Ｎｏ．４、Ｎｏ．７及びＮｏ．９は、被覆剤中に硫化鉄を適量含むためスラグ剥離性が非常に良好であった。 In addition, welding rod No. 1, no. 3, no. In No. 4 and No. 8, since Ti was added to the coating agent, the arc was very stable, and the absorbed energy of the deposited metal was very good at 100 J or more. Also, welding rod No. 3, no. 4, no. 7 and no. No. 9 had very good slag peelability because it contained an appropriate amount of iron sulfide in the coating agent.
比較例中溶接棒Ｎｏ．１１は、金属炭酸塩の合計が少ないので、溶接部にブローホールが発生した。また、鉄粉が少ないので、再アーク性が不良であった。さらに、Ｔｉが多いので、アークが非常に安定していたが、溶着金属の吸収エネルギーが低かった。 In the comparative example, the welding rod No. No. 11 had a small amount of metal carbonate, so blowholes occurred in the weld. Moreover, since there was little iron powder, re-arc property was unsatisfactory. Furthermore, since there was much Ti, the arc was very stable, but the absorbed energy of the deposited metal was low.
溶接棒Ｎｏ．１２は、金属炭酸塩が多いので、アークが不安定で、スラグ剥離性が不良となり、ビード形状も凸状であった。また、Ｍｎが多いので溶着金属の引張強さが高く、吸収エネルギーも低かった。 Welding rod no. No. 12 had a large amount of metal carbonate, so the arc was unstable, the slag peelability was poor, and the bead shape was also convex. Moreover, since there was much Mn, the tensile strength of the weld metal was high and the absorbed energy was also low.
溶接棒Ｎｏ．１３は、ＴｉＯ2換算値が少ないので、アークが不安定で、ビード外観が不良であった。また、有機物が少ないので、再アーク性が不良で、被覆欠けが発生した。 Welding rod no. No. 13 had a small TiO 2 conversion value, so the arc was unstable and the bead appearance was poor. Moreover, since there were few organic substances, the re-arcing property was poor and the coating chip occurred.
溶接棒Ｎｏ．１４は、ＴｉＯ2換算値が多いので、スラグ剥離性が不良であった。また、Ｎａ2Ｏ換算値とＫ2Ｏ換算値の合計が少ないのでアークが不安定であった。 Welding rod no. 14, since the TiO 2 converted value is large, the slag removability was poor. Further, the arc was unstable because the total of Na 2 O converted value and K 2 O converted value was small.
溶接棒Ｎｏ．１５は、ＳｉＯ2換算値が少ないので、アークが弱く、スラグ剥離性が不良であった。また、硫化鉄が少ないのでスラグ剥離性を向上させる効果も得られなかった。さらに、Ｎａ2Ｏ換算値とＫ2Ｏ換算値の合計が多いので、再アーク性も不良であった。 Welding rod no. No. 15 had a small SiO 2 conversion value, so the arc was weak and the slag peelability was poor. Moreover, since there was little iron sulfide, the effect which improves slag peelability was not acquired. Further, since the terms of Na 2 O values and K sum is often the 2 O converted value, re-arc resistance was also poor.
溶接棒Ｎｏ．１６は、ＣａＯが少ないので、アークが不安定で、スパッタ発生量も多かった。また、Ｍｎが少ないので、溶接部にブローホールが発生し、溶着金属の引張強さが低く、吸収エネルギーも低かった。さらに、Ｔｉが少ないのでアークを安定させる効果及び溶着金属の吸収エネルギーを向上させる効果が得られなかった。 Welding rod no. No. 16 had less CaO, so the arc was unstable and the amount of spatter was large. Further, since Mn was small, blow holes were generated in the welded portion, the tensile strength of the deposited metal was low, and the absorbed energy was also low. Furthermore, since Ti is small, the effect of stabilizing the arc and the effect of improving the absorbed energy of the deposited metal were not obtained.
溶接棒Ｎｏ．１７は、ＳｉＯ2換算値が多いので、ビード外観が不良であった。また、Ａｌ2Ｏ3換算値が少ないので、アークが弱かった。さらに、ＭｇＯが少ないので、スラグ剥離性が不良であった。 Welding rod no. No. 17 had a poor bead appearance because of its large SiO 2 conversion value. Further, since the Al 2 O 3 is small in terms of value, the arc was weak. Furthermore, since there was little MgO, slag peelability was unsatisfactory.
溶接棒Ｎｏ．１８は、Ａｌ2Ｏ3換算値が多いので、スラグ剥離性が不良であった。また、ＣａＯが多いので、アークが弱くなり、融合不良が発生した。 Welding rod no. 18, since in terms of Al 2 O 3 value is large, the slag removability was poor. Moreover, since there was much CaO, the arc became weak and poor fusion occurred.
溶接棒Ｎｏ．１９は、有機物が多いので、アークが強く、ビード外観が不良で、棒焼けも発生した。また、硫化鉄が多いのでスラグ剥離性が非常に良好であったが、クレータ割れが発生し、溶着金属の吸収エネルギーも低かった。 Welding rod no. No. 19 had a lot of organic matter, so the arc was strong, the bead appearance was poor, and bar burning occurred. Moreover, since there was much iron sulfide, the slag peelability was very good, but crater cracking occurred and the absorbed energy of the weld metal was low.
溶接棒Ｎｏ．２０は、ＭｇＯが多いので、ビードが凸状となった。また、鉄粉が多いので、アークが不安定で、サイドアークが発生した。 Welding rod no. No. 20 had a large amount of MgO, so the bead became convex. Moreover, since there was much iron powder, the arc was unstable and a side arc was generated.
Claims (3)
前記被覆剤は、被覆剤全質量に対する質量％で、
金属炭酸塩の１種または２種以上の合計：１０〜２０％、
Ｔｉ酸化物のＴｉＯ2換算値の合計：１０〜２５％、
Ｓｉ酸化物のＳｉＯ2換算値の合計：１０〜２５％、
Ａｌ酸化物のＡｌ2Ｏ3換算値の合計：１〜３％、
有機物の１種または２種以上の合計：２〜６％、
ＣａＯ：０．０１〜１．５０％、
ＭｇＯ：１〜４％、
Ｍｎ：２〜８％、
鉄粉：２０〜４０％、
Ｎａ化合物及びＫ化合物のＮａ2Ｏ換算値及びＫ2Ｏ換算値の合計：０．５〜３．５％を含有し、
残部が塗装剤、鉄合金からのＦｅ分及び不可避不純物からなることを特徴とするライムチタニヤ系被覆アーク溶接棒。 In a lime titania-based coated arc welding rod in which a coating is coated on the steel core wire,
The coating agent is in mass% based on the total mass of the coating agent,
Total of one or more metal carbonates: 10 to 20%,
Total of TiO 2 conversion value of Ti oxide: 10 to 25%,
Total of SiO 2 conversion value of Si oxide: 10 to 25%,
Total Al 2 O 3 conversion value of Al oxide: 1-3%
Total of one or more organic substances: 2 to 6%,
CaO: 0.01 to 1.50%,
MgO: 1-4%
Mn: 2-8%
Iron powder: 20-40%
Total of Na 2 O converted value and K 2 O converted value of Na compound and K compound: 0.5 to 3.5%,
A lime titania-based coated arc welding rod characterized in that the balance consists of a coating agent, an Fe component from an iron alloy, and inevitable impurities.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016079785 | 2016-04-12 | ||
| JP2016079785 | 2016-04-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2017189817A true JP2017189817A (en) | 2017-10-19 |
| JP6669680B2 JP6669680B2 (en) | 2020-03-18 |
Family
ID=60086438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017014408A Active JP6669680B2 (en) | 2016-04-12 | 2017-01-30 | Lime titania coated arc welding rod |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6669680B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019115913A (en) * | 2017-12-27 | 2019-07-18 | 日鉄溶接工業株式会社 | Lime-titania type covered electrode |
-
2017
- 2017-01-30 JP JP2017014408A patent/JP6669680B2/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019115913A (en) * | 2017-12-27 | 2019-07-18 | 日鉄溶接工業株式会社 | Lime-titania type covered electrode |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6669680B2 (en) | 2020-03-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5179073B2 (en) | Flux-cored wire for gas shielded arc welding | |
| JP5890280B2 (en) | Low hydrogen coated arc welding rod | |
| JP6437471B2 (en) | Low hydrogen coated arc welding rod | |
| JP5367312B2 (en) | High cellulosic coated arc welding rod | |
| JP2017087265A (en) | Flux-cored wire for carbon dioxide gas shielded arc welding | |
| JP6051086B2 (en) | Low hydrogen coated arc welding rod | |
| JP2012051021A (en) | FLUX-CORED WIRE FOR Ar-CO2 MIXED GAS SHIELDED ARC WELDING | |
| JP6688162B2 (en) | Illuminite coated arc welding rod | |
| JP6669680B2 (en) | Lime titania coated arc welding rod | |
| JP2017217672A (en) | Low-hydrogen type covered arc welding rod | |
| JP2020168651A (en) | COATED ARC WELDING ELECTRODE FOR 9% Ni STEEL WELDING | |
| JP2019181524A (en) | Covered electrode for low hydrogen type fillet welding | |
| JP6845094B2 (en) | High titanium oxide shielded metal arc welding rod | |
| JP6938361B2 (en) | Lime titania-based shielded metal arc welding rod | |
| JP7387450B2 (en) | Iron powder low hydrogen coated arc welding rod | |
| JP6987800B2 (en) | Illuminite-based shielded metal arc welding rod | |
| JP2018114515A (en) | Coated electrode for low hydrogen type fillet welding | |
| JP6999461B2 (en) | High titanium oxide-based shielded metal arc welding rod | |
| JP5455422B2 (en) | Low hydrogen coated arc welding rod | |
| JP2010194571A (en) | Flux-cored wire for two-electrode horizontal fillet gas shield arc welding | |
| JP5348937B2 (en) | Low hydrogen coated arc welding rod | |
| JP7039353B2 (en) | Low hydrogen coated arc welding rod | |
| JP7210410B2 (en) | Iron Powder Low Hydrogen Type Coated Arc Welding Rod | |
| JP7346328B2 (en) | Low hydrogen coated arc welding rod for horizontal fillet welding | |
| WO2021014452A1 (en) | Reduced hexavalent chromium emission sts electrodes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20181029 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190710 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190723 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190920 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20200225 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20200227 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6669680 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |