JP2017149653A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2017149653A5 JP2017149653A5 JP2016031272A JP2016031272A JP2017149653A5 JP 2017149653 A5 JP2017149653 A5 JP 2017149653A5 JP 2016031272 A JP2016031272 A JP 2016031272A JP 2016031272 A JP2016031272 A JP 2016031272A JP 2017149653 A5 JP2017149653 A5 JP 2017149653A5
- Authority
- JP
- Japan
- Prior art keywords
- mass
- pest repellent
- group
- component
- repellent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000607479 Yersinia pestis Species 0.000 claims description 23
- 239000005871 repellent Substances 0.000 claims description 23
- 230000002940 repellent Effects 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 15
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 12
- 125000006353 oxyethylene group Chemical group 0.000 claims description 12
- -1 oxypropylene group Chemical group 0.000 claims description 12
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- MMOXZBCLCQITDF-UHFFFAOYSA-N DEET Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000000077 insect repellent Substances 0.000 claims description 3
Description
すなわち、本発明は下記の［１］〜［６］である。
［１］ 害虫忌避成分（Ａ）を０．１〜５０質量％、下記の式（Ｉ）で表されるアルキレンオキシド誘導体（Ｂ）を０．１〜２０質量％、および溶剤（Ｃ）を９９．８〜３０質量％含有することを特徴とする、害虫忌避剤組成物。
Ｚ−｛Ｏ（ＰＯ）k（ＥＯ）m−（ＢＯ）nＨ｝a ・・・（Ｉ）
（式（１）において、
Ｚは、５〜９個の水酸基を有する化合物からすべての前記水酸基を除いた残基であり、
ａは５〜９であり、
ＰＯはオキシプロピレン基であり、ＥＯはオキシエチレン基であり、ＢＯは炭素数４のオキシアルキレン基であり、
ｋ、ｍおよびｎは、それぞれ、オキシプロピレン基、オキシエチレン基および炭素数４のオキシアルキレン基の平均付加モル数であって、１≦ｋ≦４０、０≦ｍ≦４０、ｎ＝０かつ（ｋ＋ｍ＋ｎ）×ａ≧８であり、
ＰＯとＥＯの合計量を１００質量部としたとき、ＰＯの質量割合は、２５〜１００質量部であり、
ｍが１以上の場合、ＰＯとＥＯはランダム状に結合している。）
［２］ 前記成分（Ｂ）の５質量％水溶液の曇点が１５℃以上であることを特徴とする、［１］の害虫忌避剤組成物。
［３］ 前記害虫忌避成分（Ａ）がＮ，Ｎ−ジエチル−ｍ−トルアミドであることを特徴とする、［１］たは［２］の害虫忌避剤組成物。
［４］ 害虫忌避成分（Ａ）を０．１〜５０質量％、下記の式（Ｉ）で表されるアルキレンオキシド誘導体（Ｂ）を０．１〜２０質量％、および溶剤（Ｃ）を９９．８〜３０質量％含有することを特徴とする、害虫忌避剤組成物。
Ｚ−｛Ｏ（ＰＯ）k（ＥＯ）m−（ＢＯ）nＨ｝a ・・・（Ｉ）
（式（１）において、
Ｚは、１〜９個の水酸基を有する化合物からすべての前記水酸基を除いた残基であり、
ａは１〜９であり、
ＰＯはオキシプロピレン基であり、ＥＯはオキシエチレン基であり、ＢＯは炭素数４のオキシアルキレン基であり、
ｋ、ｍおよびｎは、それぞれ、オキシプロピレン基、オキシエチレン基および炭素数４のオキシアルキレン基の平均付加モル数であって、１≦ｋ≦４０、０≦ｍ≦４０、０≦ｎ≦３（ｎ＝０を除く）かつ（ｋ＋ｍ＋ｎ）×ａ≧８であり、
ＰＯとＥＯの合計量を１００質量部としたとき、ＰＯの質量割合は、２５〜１００質量部であり、
ｍが１以上の場合、ＰＯとＥＯはランダム状に結合している。）
［５］ 前記成分（Ｂ）の５質量％水溶液の曇点が１５℃以上であることを特徴とする、［４］の害虫忌避剤組成物。
［６］ 前記害虫忌避成分（Ａ）がＮ，Ｎ−ジエチル−ｍ−トルアミドであることを特徴とする、［４］または［５］の害虫忌避剤組成物。
That is, this invention is following [1]-[ 6 ].
[1] Pest repellent component (A) 0.1 to 50% by mass, alkylene oxide derivative (B) represented by the following formula (I) 0.1 to 20% by mass, and solvent (C) 99 A pest repellent composition characterized by containing .8-30 mass%.
Z- {O (PO) k (EO) m- (BO) nH} a (I)
(In Formula (1),
Z is a residue obtained by removing all the hydroxyl groups from a compound having 5 to 9 hydroxyl groups,
a is 5-9,
PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxyalkylene group having 4 carbon atoms,
k, m and n are the average added moles of the oxypropylene group, oxyethylene group and oxyalkylene group having 4 carbon atoms, respectively, 1 ≦ k ≦ 40, 0 ≦ m ≦ 40, n = 0 and ( k + m + n) × a ≧ 8,
When the total amount of PO and EO is 100 parts by mass, the mass ratio of PO is 25 to 100 parts by mass,
When m is 1 or more, PO and EO are bonded in a random manner. )
[2] The insect repellent composition according to [1], wherein the cloud point of a 5% by mass aqueous solution of the component (B) is 15 ° C. or higher.
[3] The pest repellent composition according to [1] or [2], wherein the pest repellent component (A) is N, N-diethyl-m-toluamide.
[4] Pest repellent component (A) 0.1 to 50% by mass, alkylene oxide derivative (B) represented by the following formula (I) 0.1 to 20% by mass, and solvent (C) 99 A pest repellent composition characterized by containing .8-30 mass%.
Z- {O (PO) k (EO) m- (BO) nH} a (I)
(In Formula (1),
Z is a residue obtained by removing all the hydroxyl groups from a compound having 1 to 9 hydroxyl groups;
a is 1-9,
PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxyalkylene group having 4 carbon atoms,
k, m and n are the average added moles of the oxypropylene group, oxyethylene group and oxyalkylene group having 4 carbon atoms, respectively, 1 ≦ k ≦ 40, 0 ≦ m ≦ 40, 0 ≦ n ≦ 3 (Except n = 0) and (k + m + n) × a ≧ 8,
When the total amount of PO and EO is 100 parts by mass, the mass ratio of PO is 25 to 100 parts by mass,
When m is 1 or more, PO and EO are bonded in a random manner. )
[5] The insect repellent composition according to [4], wherein the cloud point of a 5% by mass aqueous solution of the component (B) is 15 ° C. or higher.
[6] The pest repellent composition according to [4] or [5], wherein the pest repellent component (A) is N, N-diethyl-m-toluamide.
以下、さらに詳細に本発明の説明をする。
本発明の害虫忌避剤組成物は、害虫忌避成分（Ａ）、下記の式（Ｉ）で表されるアルキレンオキシド誘導体（Ｂ）、および溶剤（Ｃ）を含有する。
Ｚ−｛Ｏ（ＰＯ）k（ＥＯ）m−（ＢＯ）nＨ｝a ・・・（Ｉ）
（式（１）において、
Ｚは、５〜９個の水酸基を有する化合物からすべての前記水酸基を除いた残基であり、
ａは５〜９であり、
ＰＯはオキシプロピレン基であり、ＥＯはオキシエチレン基であり、ＢＯは炭素数４のオキシアルキレン基であり、
ｋ、ｍおよびｎは、それぞれ、オキシプロピレン基、オキシエチレン基および炭素数４のオキシアルキレン基の平均付加モル数であって、１≦ｋ≦４０、０≦ｍ≦４０、ｎ＝０かつ（ｋ＋ｍ＋ｎ）×ａ≧８であり、
ＰＯとＥＯの合計量を１００質量部としたとき、ＰＯの質量割合は、２５〜１００質量部であり、
ｍが１以上の場合、ＰＯとＥＯはランダム状に結合している。）
本発明の害虫忌避剤組成物は、害虫忌避成分（Ａ）、下記の式（Ｉ）で表されるアルキレンオキシド誘導体（Ｂ）、および溶剤（Ｃ）を含有する。
あるいは、本発明の害虫忌避剤組成物は、害虫忌避成分（Ａ）、下記の式（Ｉ）で表されるアルキレンオキシド誘導体（Ｂ）、および溶剤（Ｃ）を含有する。
Ｚ−｛Ｏ（ＰＯ）k（ＥＯ）m−（ＢＯ）nＨ｝a ・・・（Ｉ）
（式（１）において、
Ｚは、１〜９個の水酸基を有する化合物からすべての前記水酸基を除いた残基であり、
ａは１〜９であり、
ＰＯはオキシプロピレン基であり、ＥＯはオキシエチレン基であり、ＢＯは炭素数４のオキシアルキレン基であり、
ｋ、ｍおよびｎは、それぞれ、オキシプロピレン基、オキシエチレン基および炭素数４のオキシアルキレン基の平均付加モル数であって、１≦ｋ≦４０、０≦ｍ≦４０、０≦ｎ≦３（ｎ＝０を除く）かつ（ｋ＋ｍ＋ｎ）×ａ≧８であり、
ＰＯとＥＯの合計量を１００質量部としたとき、ＰＯの質量割合は、２５〜１００質量部であり、
ｍが１以上の場合、ＰＯとＥＯはランダム状に結合している。）
Hereinafter, the present invention will be described in more detail.
The pest repellent composition of the present invention contains a pest repellent component (A), an alkylene oxide derivative (B) represented by the following formula (I), and a solvent (C).
Z- {O (PO) k (EO) m- (BO) nH} a (I)
(In Formula (1),
Z is a residue obtained by removing all the hydroxyl groups from a compound having 5 to 9 hydroxyl groups,
a is 5-9,
PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxyalkylene group having 4 carbon atoms,
k, m and n are the average added moles of the oxypropylene group, oxyethylene group and oxyalkylene group having 4 carbon atoms, respectively, 1 ≦ k ≦ 40, 0 ≦ m ≦ 40, n = 0 and ( k + m + n) × a ≧ 8,
When the total amount of PO and EO is 100 parts by mass, the mass ratio of PO is 25 to 100 parts by mass,
When m is 1 or more, PO and EO are bonded in a random manner. )
The pest repellent composition of the present invention contains a pest repellent component (A), an alkylene oxide derivative (B) represented by the following formula (I), and a solvent (C).
Alternatively, the pest repellent composition of the present invention contains a pest repellent component (A), an alkylene oxide derivative (B) represented by the following formula (I), and a solvent (C).
Z- {O (PO) k (EO) m- (BO) nH} a (I)
(In Formula (1),
Z is a residue obtained by removing all the hydroxyl groups from a compound having 1 to 9 hydroxyl groups;
a is 1-9,
PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxyalkylene group having 4 carbon atoms,
k, m and n are the average added moles of the oxypropylene group, oxyethylene group and oxyalkylene group having 4 carbon atoms, respectively, 1 ≦ k ≦ 40, 0 ≦ m ≦ 40, 0 ≦ n ≦ 3 (Except n = 0) and (k + m + n) × a ≧ 8,
When the total amount of PO and EO is 100 parts by mass, the mass ratio of PO is 25 to 100 parts by mass,
When m is 1 or more, PO and EO are bonded in a random manner. )
Claims (6)
Ｚ−｛Ｏ（ＰＯ）k（ＥＯ）m−（ＢＯ）nＨ｝a ・・・（Ｉ）
（式（１）において、
Ｚは、５〜９個の水酸基を有する化合物からすべての前記水酸基を除いた残基であり、
ａは５〜９であり、
ＰＯはオキシプロピレン基であり、ＥＯはオキシエチレン基であり、ＢＯは炭素数４のオキシアルキレン基であり、
ｋ、ｍおよびｎは、それぞれ、オキシプロピレン基、オキシエチレン基および炭素数４のオキシアルキレン基の平均付加モル数であって、１≦ｋ≦４０、０≦ｍ≦４０、ｎ＝０かつ（ｋ＋ｍ＋ｎ）×ａ≧８であり、
ＰＯとＥＯの合計量を１００質量部としたとき、ＰＯの質量割合は、２５〜１００質量部であり、
ｍが１以上の場合、ＰＯとＥＯはランダム状に結合している。）
Pest repellent component (A) is 0.1-50 mass%, alkylene oxide derivative (B) represented by the following formula (I) is 0.1-20 mass%, and solvent (C) is 99.8- A pest repellent composition comprising 30% by mass.
Z- {O (PO) k (EO) m- (BO) nH} a (I)
(In Formula (1),
Z is a residue obtained by removing all the hydroxyl groups from a compound having 5 to 9 hydroxyl groups,
a is 5-9,
PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxyalkylene group having 4 carbon atoms,
k, m and n are the average added moles of the oxypropylene group, oxyethylene group and oxyalkylene group having 4 carbon atoms, respectively, 1 ≦ k ≦ 40, 0 ≦ m ≦ 40, n = 0 and ( k + m + n) × a ≧ 8,
When the total amount of PO and EO is 100 parts by mass, the mass ratio of PO is 25 to 100 parts by mass,
When m is 1 or more, PO and EO are bonded in a random manner. )
The pest repellent composition according to claim 1, wherein the cloud point of a 5 mass% aqueous solution of the component (B) is 15 ° C or higher.
The pest repellent composition according to claim 1 or 2, wherein the pest repellent component (A) is N, N-diethyl-m-toluamide.
Ｚ−｛Ｏ（ＰＯ）k（ＥＯ）m−（ＢＯ）nＨ｝a ・・・（Ｉ）
（式（１）において、
Ｚは、１〜９個の水酸基を有する化合物からすべての前記水酸基を除いた残基であり、
ａは１〜９であり、
ＰＯはオキシプロピレン基であり、ＥＯはオキシエチレン基であり、ＢＯは炭素数４のオキシアルキレン基であり、
ｋ、ｍおよびｎは、それぞれ、オキシプロピレン基、オキシエチレン基および炭素数４のオキシアルキレン基の平均付加モル数であって、１≦ｋ≦４０、０≦ｍ≦４０、０≦ｎ≦３（ｎ＝０を除く）かつ（ｋ＋ｍ＋ｎ）×ａ≧８であり、
ＰＯとＥＯの合計量を１００質量部としたとき、ＰＯの質量割合は、２５〜１００質量部であり、
ｍが１以上の場合、ＰＯとＥＯはランダム状に結合している。）
Pest repellent component (A) is 0.1-50 mass%, alkylene oxide derivative (B) represented by the following formula (I) is 0.1-20 mass%, and solvent (C) is 99.8- A pest repellent composition comprising 30% by mass.
Z- {O (PO) k (EO) m- (BO) nH} a (I)
(In Formula (1),
Z is a residue obtained by removing all the hydroxyl groups from a compound having 1 to 9 hydroxyl groups;
a is 1-9,
PO is an oxypropylene group, EO is an oxyethylene group, BO is an oxyalkylene group having 4 carbon atoms,
k, m and n are the average added moles of the oxypropylene group, oxyethylene group and oxyalkylene group having 4 carbon atoms, respectively, 1 ≦ k ≦ 40, 0 ≦ m ≦ 40, 0 ≦ n ≦ 3 (Except n = 0) and (k + m + n) × a ≧ 8,
When the total amount of PO and EO is 100 parts by mass, the mass ratio of PO is 25 to 100 parts by mass,
When m is 1 or more, PO and EO are bonded in a random manner. )
The insect repellent composition according to claim 4 , wherein the cloud point of a 5% by mass aqueous solution of the component (B) is 15 ° C or higher.
The pest repellent composition according to claim 4 or 5 , wherein the pest repellent component (A) is N, N-diethyl-m-toluamide.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016031272A JP6814382B2 (en) | 2016-02-22 | 2016-02-22 | Pest repellent composition |
| JP2019020581A JP6899855B2 (en) | 2016-02-22 | 2019-02-07 | Pest repellent composition for human skin application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016031272A JP6814382B2 (en) | 2016-02-22 | 2016-02-22 | Pest repellent composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019020581A Division JP6899855B2 (en) | 2016-02-22 | 2019-02-07 | Pest repellent composition for human skin application |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017149653A JP2017149653A (en) | 2017-08-31 |
| JP2017149653A5 true JP2017149653A5 (en) | 2019-03-28 |
| JP6814382B2 JP6814382B2 (en) | 2021-01-20 |
Family
ID=59739473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016031272A Active JP6814382B2 (en) | 2016-02-22 | 2016-02-22 | Pest repellent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP6814382B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109843055B (en) * | 2016-08-10 | 2022-06-10 | 阿斯制药株式会社 | Method for inhibiting penetration of pest repellent into skin and penetration inhibitor for inhibiting penetration of pest repellent into skin |
| KR102564753B1 (en) * | 2018-04-09 | 2023-08-08 | 다이니혼 죠츄기쿠 가부시키가이샤 | Insect Repellents, and Insect Repellent Products |
| JP7344451B2 (en) * | 2020-03-17 | 2023-09-14 | 日油株式会社 | Transdermal absorption inhibitor and insect repellent composition |
-
2016
- 2016-02-22 JP JP2016031272A patent/JP6814382B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2017149653A5 (en) | ||
| JP2014500356A5 (en) | ||
| JP2007532720A5 (en) | ||
| JP2015523439A5 (en) | Quantum dot binding ligands and compositions | |
| JP2008266636A5 (en) | Active energy ray-curable liquid composition, aqueous ink, and liquid cartridge | |
| RU2013117004A (en) | SURFACE-ACTIVE SUBSTANCES BASED ON AMINE AND AMINE OXIDE FOR REGULATING THE DEMOCRACY OF A HERBICIDAL AEROSOL | |
| RU2009143175A (en) | ALCOHOLS OF ALCOHOLS CONTAINING THEIR COMPOSITIONS AND APPLICATION OF ALCOHOSILATES OF ALCOHOLS AS ADJUVANTS IN THE FIELD OF AGROCHEMISTRY | |
| FI3206486T3 (en) | Pesticide formulations having physical mode of action | |
| JP2009161764A5 (en) | ||
| JP2015511595A5 (en) | ||
| JP2012526890A5 (en) | ||
| JP2016514192A5 (en) | ||
| WO2013158824A3 (en) | Cosmetic compositions comprising an alkylene oxide derivative and a n-acyl amino acid compound | |
| BR112014001277A2 (en) | improved method for producing emulsifiable pesticide solutions | |
| PH12021551040A1 (en) | Mixtures and compositions comprising 5-fluoro-4-imino-3- methyl-1-tosyl-3,4-dihydropyrimidin-2-one, and methods of use thereof | |
| JP2018522112A5 (en) | ||
| JP2018521056A5 (en) | ||
| JP2017528568A5 (en) | ||
| JP2008266635A5 (en) | Active energy ray-curable liquid composition, aqueous ink, and liquid cartridge | |
| JP2011093883A5 (en) | ||
| JP2008515891A5 (en) | ||
| MX2018013783A (en) | Glyphosate formulations containing amidoalkylamine surfactants. | |
| JP2009149858A5 (en) | ||
| JP2015514885A5 (en) | ||
| JP2019172844A5 (en) |