JP2017143005A - Power storage element and manufacturing method therefor - Google Patents

Power storage element and manufacturing method therefor Download PDF

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JP2017143005A
JP2017143005A JP2016024177A JP2016024177A JP2017143005A JP 2017143005 A JP2017143005 A JP 2017143005A JP 2016024177 A JP2016024177 A JP 2016024177A JP 2016024177 A JP2016024177 A JP 2016024177A JP 2017143005 A JP2017143005 A JP 2017143005A
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electrode plate
positive electrode
cross
negative electrode
section changing
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洋喜 森永
Hiroki Morinaga
洋喜 森永
寛人 渡辺
Hiroto Watanabe
寛人 渡辺
訓良 胸永
Kuniyoshi Munenaga
胸永  訓良
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GS Yuasa Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Electric Double-Layer Capacitors Or The Like (AREA)
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Abstract

PROBLEM TO BE SOLVED: To provide a power storage element which simplifies a configuration for suppressing generation of wrinkles in an electrode plate, and to provide a manufacturing method therefor.SOLUTION: In a power storage element 100 including an electrode body 20 formed of wound positive electrode plate 21 and negative electrode plate 22, the positive electrode plate 21 and negative electrode plate 22 have profile change parts 24, formed by salients extending in the winding direction, at the ends 21d and 22d of the positive electrode plate 21 and negative electrode plate 22 in the winding axis A direction in the bends of the positive electrode plate 21 and negative electrode plate 22.SELECTED DRAWING: Figure 6

Description

本発明は、電極体を備える蓄電素子及びその製造方法に関する。   The present invention relates to a power storage device including an electrode body and a method for manufacturing the same.

リチウムイオン二次電池などの蓄電素子には、正極板と負極板と正極板及び負極板の間に挿入されたシート状のセパレータとが重ねられて渦巻き状に巻回されて形成される電極体を備えるものがある。例えば、特許文献1には、巻回された極板としての電極板を備えたリチウム電池が記載されている。上記電極板では、その基材を構成する集電体に、活物質を構成する電極物質が塗布されている。集電体上に塗布される電極物質の膜厚は、一定ではなく変化している。これにより、電極板が巻回されるときに電極板に皺等が発生することが抑えられる。なお、電極板における皺の発生は、電池の性能に悪影響を与える可能性がある。   A power storage device such as a lithium ion secondary battery includes an electrode body formed by stacking a positive electrode plate, a negative electrode plate, a sheet-like separator inserted between the positive electrode plate and the negative electrode plate, and winding them in a spiral shape. There is something. For example, Patent Document 1 describes a lithium battery including an electrode plate as a wound electrode plate. In the electrode plate, an electrode material constituting an active material is applied to a current collector constituting the base material. The film thickness of the electrode material applied on the current collector is not constant but varies. This suppresses wrinkles and the like from being generated on the electrode plate when the electrode plate is wound. In addition, generation | occurrence | production of the wrinkle in an electrode plate may have a bad influence on the performance of a battery.

特表2012−501052号公報Special table 2012-501052 gazette

特許文献1では、電極板における皺の発生を抑えるために、電極物質の膜厚を電極板上での場所に応じて変化させている。このため、電極板の製造は、その工数が増え、複雑になる。つまり、電極板における皺の発生を抑制するための構成が複雑である。   In Patent Document 1, in order to suppress the generation of wrinkles in the electrode plate, the film thickness of the electrode material is changed according to the location on the electrode plate. For this reason, the manufacturing of the electrode plate is complicated and complicated. That is, the configuration for suppressing the generation of wrinkles on the electrode plate is complicated.

本発明は、上述のような問題を解決するためになされたものであり、極板における皺等の発生を抑えるための構成を簡易にする蓄電素子を提供することを目的とする。   The present invention has been made to solve the above-described problems, and an object of the present invention is to provide a power storage device that simplifies a configuration for suppressing generation of wrinkles and the like in an electrode plate.

上記目的を達成するために、本発明に係る蓄電素子は、巻回された極板によって形成される電極体を備える蓄電素子であって、極板は、極板の湾曲部分における極板の巻回軸方向の端部に、極板の巻回方向に沿って延在する凸部又は凹部によって形成される断面変化部を有する。   In order to achieve the above object, an electricity storage device according to the present invention is an electricity storage device including an electrode body formed by a wound electrode plate, and the electrode plate is a winding of the electrode plate in a curved portion of the electrode plate. It has a cross-sectional change part formed by the convex part or recessed part extended along the winding direction of an electrode plate in the edge part of a rotating shaft direction.

上述の構成において、巻回方向に沿って延在する凸部又は凹部を形成する断面変化部は、極板に巻回軸方向に沿った折り目が入ることを抑制する。よって、断面変化部は、巻回軸方向で断面変化部よりも極板の端部の縁側に形成された極板の折り目、皺等が、断面変化部を越えて伸長することを抑制する。従って、凸部又は凹部を形成する断面変化部による簡易な構成によって、極板における皺、折り目等の発生が抑制される。   In the above-described configuration, the cross-section changing portion that forms the convex portion or the concave portion extending along the winding direction suppresses the fold along the winding axis direction from entering the electrode plate. Therefore, the cross-section changing portion suppresses the folds, wrinkles, and the like of the electrode plate formed on the edge side of the end portion of the electrode plate from the cross-section changing portion in the winding axis direction from extending beyond the cross-section changing portion. Therefore, the occurrence of wrinkles, creases, and the like in the electrode plate is suppressed by a simple configuration using the cross-section changing portion that forms the convex portion or the concave portion.

断面変化部は、極板の帯状をした変形部分によって形成されてもよい。上述の構成によって、断面変化部の構成が簡易になる。さらに、変形部分は、極板の折り曲げ部分によって形成されてもよい。上述の構成によって、断面変化部の構成がさらに簡易になる。   The cross-section changing portion may be formed by a deformed portion having a strip shape of an electrode plate. With the above-described configuration, the configuration of the cross-section changing portion is simplified. Further, the deformed portion may be formed by a bent portion of the electrode plate. With the above-described configuration, the configuration of the cross-section changing portion is further simplified.

極板は、基材と、基材上に形成される活物質層とを有し、断面変化部は、基材の巻回軸方向の端部における活物質層の非形成部に位置してもよい。上述の構成において、活物質層に断面変化部を形成しないことによって、隣り合う活物質層の間隔を均一にすることができる。これにより、活物質層における電流の偏りが低減する。   The electrode plate has a base material and an active material layer formed on the base material, and the cross-section change portion is located at a non-formation portion of the active material layer at an end portion in the winding axis direction of the base material. Also good. In the above structure, the interval between the adjacent active material layers can be made uniform by not forming the cross-section changing portion in the active material layer. Thereby, current bias in the active material layer is reduced.

断面変化部は、極板の端部のうちの巻回の最外周の極板の端部に少なくとも配置されてもよい。上述の構成において、電極体以外のものと接触し変形する可能性が最も高い最外周の極板の端部に断面変化部を配置することによって、極板の端部における皺、折り目等の発生が効果的に抑制される。   The cross-section changing portion may be disposed at least at the end of the outermost electrode plate of the winding among the end portions of the electrode plate. In the configuration described above, wrinkles, folds, etc. are generated at the end of the electrode plate by arranging the cross-section change part at the end of the outermost electrode plate that is most likely to contact and deform other than the electrode body. Is effectively suppressed.

蓄電素子は、極板と共に巻回されており且つ巻回されて重なる極板の間に介在するセパレータをさらに備え、断面変化部は、セパレータの巻回軸方向の縁と極板の巻回軸方向の縁との間に配置されてもよい。上述の構成において、断面変化部がセパレータと接触し損傷させることが抑制される。   The power storage element is further provided with a separator that is wound together with the electrode plates and interposed between the electrode plates that are wound and overlapped, and the cross-sectional change portion includes an edge in the winding axis direction of the separator and a winding axis direction of the electrode plate. You may arrange | position between edges. In the above-described configuration, the cross-section changing portion is prevented from coming into contact with the separator and being damaged.

蓄電素子は、間隙を形成し且つ間隙内で電極体を狭持して電極体と接続される接続部を有する集電体をさらに備え、電極体は、巻回軸と交差する方向に幅狭になる変形を受けて間隙内に挿入されており、断面変化部が位置する極板の端部が、間隙内に位置してもよい。上述の構成において、断面変化部は、電極体における変形を受ける部位の極板における皺、折り目等の発生を抑制する。   The power storage element further includes a current collector that forms a gap and has a connection portion that is connected to the electrode body by sandwiching the electrode body in the gap, and the electrode body is narrow in a direction intersecting the winding axis. The end portion of the electrode plate that is inserted into the gap in response to the deformation and the cross-section changing portion is located may be located in the gap. In the above-described configuration, the cross-section changing portion suppresses the generation of wrinkles, folds, and the like in the electrode plate at the portion subjected to deformation in the electrode body.

上記蓄電素子の製造方法は、極板を巻回して電極体を作製する工程と、極板の巻回時又は極板の巻回後に、極板に断面変化部を形成する工程とを含む。   The method for manufacturing an electric storage element includes a step of winding an electrode plate to produce an electrode body, and a step of forming a cross-sectional change portion on the electrode plate when the electrode plate is wound or after the electrode plate is wound.

本発明における蓄電素子によれば、極板における皺等の発生を抑えるための構成を簡易にすることが可能になる。   According to the electricity storage device of the present invention, it is possible to simplify the configuration for suppressing the occurrence of wrinkles and the like on the electrode plate.

本発明の実施の形態に係る蓄電素子の外観を模式的に示す斜視図である。It is a perspective view which shows typically the external appearance of the electrical storage element which concerns on embodiment of this invention. 図1の蓄電素子の分解斜視図である。It is a disassembled perspective view of the electrical storage element of FIG. 図2の電極体の一部を展開した斜視図である。FIG. 3 is a perspective view in which a part of the electrode body of FIG. 2 is developed. 図3の電極体における正極未塗工部側の湾曲壁状部が幅方向に絞られた状態を示す電極体の側面図である。It is a side view of the electrode body which shows the state by which the curved wall-shaped part by the side of the positive electrode uncoated part in the electrode body of FIG. 3 was restrict | squeezed in the width direction. 図4の電極体が正極集電体に接合された状態を示す側面図である。FIG. 5 is a side view showing a state where the electrode body of FIG. 4 is joined to a positive electrode current collector. 図3の電極体における正極未塗工部側の湾曲壁状部付近の拡大斜視図である。FIG. 4 is an enlarged perspective view of the vicinity of a curved wall portion on the positive electrode uncoated portion side in the electrode body of FIG. 3. 図6の電極体に形成された断面変化部の別例を示す斜視図である。It is a perspective view which shows another example of the cross-section change part formed in the electrode body of FIG. 実施の形態に係る蓄電素子の変形例における電極体を、図6と同様に示す斜視図である。It is a perspective view which shows the electrode body in the modification of the electrical storage element which concerns on embodiment similarly to FIG.

以下、図面を参照しつつ、本発明の実施の形態に係る蓄電素子について説明する。なお、以下で説明する実施の形態は、いずれも包括的又は具体的な例を示すものである。以下の実施の形態で示される数値、形状、材料、構成要素、構成要素の配置位置及び接続形態などは、一例であり、本発明を限定する主旨ではない。また、以下の実施の形態における構成要素のうち、最上位概念を示す独立請求項に記載されていない構成要素については、任意の構成要素として説明される。   Hereinafter, a power storage device according to an embodiment of the present invention will be described with reference to the drawings. It should be noted that each of the embodiments described below shows a comprehensive or specific example. Numerical values, shapes, materials, constituent elements, arrangement positions and connection forms of constituent elements, and the like shown in the following embodiments are merely examples, and are not intended to limit the present invention. In addition, among the constituent elements in the following embodiments, constituent elements that are not described in the independent claims indicating the highest concept are described as optional constituent elements.

また、添付の図面における各図は、模式的な図であり、必ずしも厳密に図示されたものでない。さらに、各図において、同一又は同様な構成要素については同じ符号を付している。また、以下の実施の形態の説明において、略平行、略直交のような「略」を伴った表現が、用いられる場合がある。例えば、略平行とは、完全に平行であることを意味するだけでなく、実質的に平行である、すなわち、例えば数%程度の差異を含むことも意味する。他の「略」を伴った表現についても同様である。   Each figure in the accompanying drawings is a schematic diagram and is not necessarily illustrated strictly. Furthermore, in each figure, the same code | symbol is attached | subjected about the same or similar component. In the following description of the embodiments, expressions with “substantially” such as substantially parallel and substantially orthogonal may be used. For example, “substantially parallel” not only means completely parallel, but also means substantially parallel, that is, including a difference of, for example, several percent. The same applies to expressions involving other “abbreviations”.

[実施の形態]
実施の形態に係る蓄電素子100の構成を説明する。図1は、実施の形態に係る蓄電素子100の外観を模式的に示す斜視図である。図1に示されるように、蓄電素子100は、扁平な直方体状の外形を有している。蓄電素子100は、充放電可能な二次電池である。例えば、蓄電素子100は、リチウムイオン二次電池(リチウム電池とも呼ばれる)などの非水電解質二次電池である。しかしながら、蓄電素子100は、非水電解質二次電池に限定されず、非水電解質二次電池以外の二次電池であってもよく、キャパシタであってもよい。
[Embodiment]
The structure of the electrical storage element 100 which concerns on embodiment is demonstrated. FIG. 1 is a perspective view schematically showing an external appearance of a power storage device 100 according to the embodiment. As shown in FIG. 1, the power storage element 100 has a flat rectangular parallelepiped outer shape. The storage element 100 is a chargeable / dischargeable secondary battery. For example, the electricity storage element 100 is a nonaqueous electrolyte secondary battery such as a lithium ion secondary battery (also called a lithium battery). However, the storage element 100 is not limited to a non-aqueous electrolyte secondary battery, and may be a secondary battery other than the non-aqueous electrolyte secondary battery or a capacitor.

図1及び図2を参照すると、蓄電素子100は、扁平な直方体状の容器10と、容器10の中に含まれる電極体20と、正極端子30及び負極端子40とを備えている。容器10は、有底角筒状の容器本体11と、容器本体11の細長い矩形形状の開口部11aを閉鎖可能である細長い矩形板状の蓋体12とを有している。なお、図2は、図1の蓄電素子100の分解斜視図である。容器本体11は、扁平な直方体状の外形を有している。蓋体12の外面12a上に、正極端子30及び負極端子40が配置されている。容器10の内部には、電極体20と共に電解液(本実施の形態では、非水電解液)などの電解質が封入されるが、当該電解質の図示は省略する。容器10に封入される電解質としては、蓄電素子100の性能を損なうものでなければその種類に特に制限はなく様々なものを選択することができる。   Referring to FIGS. 1 and 2, the electric storage element 100 includes a flat rectangular parallelepiped container 10, an electrode body 20 included in the container 10, a positive electrode terminal 30, and a negative electrode terminal 40. The container 10 has a bottomed rectangular tube-shaped container body 11 and an elongated rectangular plate-like lid body 12 that can close the elongated rectangular opening 11 a of the container body 11. 2 is an exploded perspective view of the storage element 100 of FIG. The container body 11 has a flat rectangular parallelepiped outer shape. On the outer surface 12 a of the lid body 12, the positive terminal 30 and the negative terminal 40 are disposed. The container 10 is filled with an electrolyte such as an electrolytic solution (in this embodiment, a nonaqueous electrolytic solution) together with the electrode body 20, but the illustration of the electrolyte is omitted. As the electrolyte sealed in the container 10, there is no particular limitation on the type thereof as long as it does not impair the performance of the electricity storage device 100, and various types can be selected.

容器本体11と蓋体12とは、溶接等の接合方法によって、互いの接合部を気密な状態にして固定される。これにより、容器10は、内部に密閉された空間を形成する。限定するものではないが、容器本体11及び蓋体12は、例えばステンレス鋼、アルミニウム、アルミニウム合金等の溶接可能な金属から作製され得る。   The container body 11 and the lid body 12 are fixed with their joints in an airtight state by a joining method such as welding. Thereby, the container 10 forms the space sealed inside. Although it does not limit, the container main body 11 and the cover body 12 may be produced from weldable metals, such as stainless steel, aluminum, aluminum alloy, for example.

導電性を有する正極端子30及び負極端子40はそれぞれ、蓋体12を貫通して蓋体12の外面12aと反対側に延在し、上記反対側において、導電性を有する正極集電体50及び負極集電体60と接続される。正極集電体50及び負極集電体60はさらに、電極体20と接続される。   The positive electrode terminal 30 and the negative electrode terminal 40 having conductivity extend through the lid body 12 to the opposite side to the outer surface 12a of the lid body 12, and on the opposite side, the positive electrode current collector 50 having conductivity and Connected to the negative electrode current collector 60. The positive electrode current collector 50 and the negative electrode current collector 60 are further connected to the electrode body 20.

上部絶縁部材31が、正極端子30と蓋体12との間に設けられ、これらを互いに電気的に絶縁し、下部絶縁部材32が、蓋体12と正極集電体50との間に設けられ、これらを互いに電気的に絶縁する。上部絶縁部材41が、負極端子40と蓋体12との間に設けられ、これらを互いに電気的に絶縁し、下部絶縁部材42が、蓋体12と負極集電体60との間に設けられ、これらを互いに電気的に絶縁する。絶縁部材31、32、41及び42はいずれも、樹脂等の電気的な絶縁性を有する材料から形成され、例えば、パッキン、ガスケット等を構成する。電極体20は、正極集電体50及び負極集電体60を介して、蓋体12から吊り下げられるように設けられる。そして、電極体20は、正極集電体50及び負極集電体60と共に、容器本体11に収容される。電極体20と容器本体11との間を電気的に絶縁するために、電極体20が絶縁フィルムなどで覆われる場合もある。電極体20と容器本体11との間に、スペーサ等の緩衝材が設けられる場合もある。   An upper insulating member 31 is provided between the positive electrode terminal 30 and the lid body 12 to electrically insulate them from each other, and a lower insulating member 32 is provided between the lid body 12 and the positive electrode current collector 50. These are electrically insulated from each other. An upper insulating member 41 is provided between the negative electrode terminal 40 and the lid body 12 to electrically insulate them from each other, and a lower insulating member 42 is provided between the lid body 12 and the negative electrode current collector 60. These are electrically insulated from each other. The insulating members 31, 32, 41, and 42 are all formed from a material having electrical insulation properties such as resin, and constitute, for example, a packing, a gasket, and the like. The electrode body 20 is provided so as to be suspended from the lid body 12 via the positive electrode current collector 50 and the negative electrode current collector 60. The electrode body 20 is housed in the container body 11 together with the positive electrode current collector 50 and the negative electrode current collector 60. In order to electrically insulate between the electrode body 20 and the container body 11, the electrode body 20 may be covered with an insulating film or the like. A buffer material such as a spacer may be provided between the electrode body 20 and the container body 11.

図2及び図3を参照して、電極体20の構成を説明する。なお、図3は、図2の電極体20の一部を展開した斜視図である。電極体20は、電気を蓄積可能な発電要素である。電極体20は、長尺な矩形帯状の平面形状をしたシート状の正極板21と、長尺な矩形帯状の平面形状をしたシート状の負極板22と、長尺な矩形帯状の平面形状をしたシート状の2つのセパレータ23とを、層状に重ねるように含んでいる。ここで、正極板21及び負極板22は、極板の一例である。   With reference to FIG.2 and FIG.3, the structure of the electrode body 20 is demonstrated. FIG. 3 is a perspective view in which a part of the electrode body 20 of FIG. 2 is developed. The electrode body 20 is a power generation element capable of storing electricity. The electrode body 20 includes a sheet-like positive electrode plate 21 having a long rectangular belt-like planar shape, a sheet-like negative electrode plate 22 having a long rectangular belt-like planar shape, and a long rectangular belt-like planar shape. The sheet-like two separators 23 are included so as to be layered. Here, the positive electrode plate 21 and the negative electrode plate 22 are examples of electrode plates.

そして、電極体20は、層状に重ねられた正極板21、負極板22及びセパレータ23を一緒に、巻回軸Aを中心に巻回方向Bで渦巻き状に多重に巻回されることによって、形成される。巻回軸Aは、図2及び図3において一点鎖線で示される仮想の軸であり、電極体20は、巻回軸Aに関して略対称な構成を有している。限定されるものではないが、本実施の形態では、電極体20は、巻回軸Aに垂直な断面が扁平な長円形状である扁平な外形を有している。しかしながら、電極体20の断面形状は、長円形以外であってもよく、円形、楕円形、矩形、その他の多角形であってもよい。   Then, the electrode body 20 is wound in a spiral manner in the winding direction B around the winding axis A together with the positive electrode plate 21, the negative electrode plate 22 and the separator 23 stacked in layers, It is formed. The winding axis A is a virtual axis indicated by a one-dot chain line in FIGS. 2 and 3, and the electrode body 20 has a substantially symmetric configuration with respect to the winding axis A. Although not limited, in the present embodiment, the electrode body 20 has a flat outer shape having an oblong shape with a flat cross section perpendicular to the winding axis A. However, the cross-sectional shape of the electrode body 20 may be other than an oval shape, and may be a circle, an ellipse, a rectangle, or other polygons.

正極板21は、アルミニウム、アルミニウム合金等の金属からなる長尺な矩形帯状の金属箔である正極基材21aと、正極基材21aの両側の幅広な主面上の略全体に塗工等の方法で積層された正極活物質層21b(図3において斜線表示)とを含む。負極板22は、銅、銅合金等の金属からなる長尺な矩形帯状の金属箔である負極基材22aと、負極基材22aの両側の幅広な主面上の略全体に塗工等の方法で積層された負極活物質層22b(図3において斜線表示)とを含む。正極活物質層21bに用いられる正極活物質又は負極活物質層22bに用いられる負極活物質としては、リチウムイオンを吸蔵放出可能な正極活物質又は負極活物質であれば、適宜公知の材料を使用できる。セパレータ23は、樹脂等の電気的な絶縁性を有する材料からなる微多孔性のシートである。なお、本実施の形態では、正極活物質層21b及び負極活物質層22bはそれぞれ、正極基材21a及び負極基材22aの両側の主面上に形成されているが、片側の主面上のみに形成されてもよい。ここで、正極基材21a及び負極基材22aは、極板の基材の一例であり、正極活物質層21b及び負極活物質層22bは、極板の活物質層の一例である。   The positive electrode plate 21 includes a positive electrode base material 21a which is a long rectangular strip-shaped metal foil made of a metal such as aluminum or an aluminum alloy, and a coating or the like substantially over the wide main surface on both sides of the positive electrode base material 21a. And a positive electrode active material layer 21b (indicated by hatching in FIG. 3) stacked by the method. The negative electrode plate 22 includes a negative electrode base material 22a which is a long rectangular belt-shaped metal foil made of a metal such as copper or a copper alloy, and a coating or the like substantially over the wide main surface on both sides of the negative electrode base material 22a. And a negative electrode active material layer 22b (indicated by hatching in FIG. 3) stacked by the method. As a positive electrode active material used for the positive electrode active material layer 21b or a negative electrode active material used for the negative electrode active material layer 22b, a known material is appropriately used as long as it is a positive electrode active material or a negative electrode active material capable of occluding and releasing lithium ions. it can. The separator 23 is a microporous sheet made of a material having electrical insulation properties such as a resin. In the present embodiment, the positive electrode active material layer 21b and the negative electrode active material layer 22b are formed on the main surfaces on both sides of the positive electrode substrate 21a and the negative electrode substrate 22a, respectively, but only on one main surface. May be formed. Here, the positive electrode base material 21a and the negative electrode base material 22a are examples of the electrode plate base material, and the positive electrode active material layer 21b and the negative electrode active material layer 22b are examples of the electrode plate active material layer.

正極板21の長手方向に沿った2つの縁のうちの一方の縁の近傍の帯状領域では、正極基材21aのいずれの主面にも、正極活物質層21bが積層されていない。上記帯状領域を形成する正極板21の縁部分を正極未塗工部21cと呼ぶ。つまり、正極板21は、巻回軸Aに沿う方向である巻回軸A方向での2つの端部のうちの一方の端部21dに、正極未塗工部21cを有している。正極未塗工部21cは、露出した正極基材21aによって形成されており、正極板21の集電領域を形成している。   In the band-like region in the vicinity of one of the two edges along the longitudinal direction of the positive electrode plate 21, the positive electrode active material layer 21b is not laminated on any main surface of the positive electrode base material 21a. The edge portion of the positive electrode plate 21 that forms the band-like region is referred to as a positive electrode uncoated portion 21c. That is, the positive electrode plate 21 has a positive electrode uncoated portion 21 c at one end portion 21 d of two ends in the winding axis A direction that is a direction along the winding axis A. The positive electrode uncoated portion 21 c is formed by the exposed positive electrode base material 21 a and forms a current collecting region of the positive electrode plate 21.

さらに、負極板22の長手方向に沿った2つの縁のうちの一方の縁の近傍の帯状領域では、負極基材22aのいずれの主面にも、負極活物質層22bが積層されていない。上記帯状領域を形成する負極板22の縁部分を負極未塗工部22cと呼ぶ。つまり、負極板22は、巻回軸A方向での2つの端部のうちの一方の端部22dに、負極未塗工部22cを有している。負極未塗工部22cは、露出した負極基材22aによって形成されており、負極板22の集電領域を形成している。ここで、端部21d及び22dは、極板の端部の一例であり、正極未塗工部21c及び負極未塗工部22cは、活物質層の非形成部の一例である。   Furthermore, the negative electrode active material layer 22b is not laminated on any main surface of the negative electrode substrate 22a in the band-like region in the vicinity of one of the two edges along the longitudinal direction of the negative electrode plate 22. The edge portion of the negative electrode plate 22 that forms the belt-like region is referred to as a negative electrode uncoated portion 22c. That is, the negative electrode plate 22 has a negative electrode uncoated portion 22c at one end 22d of two ends in the winding axis A direction. The negative electrode uncoated portion 22 c is formed by the exposed negative electrode base material 22 a and forms a current collecting region of the negative electrode plate 22. Here, the end portions 21d and 22d are examples of end portions of the electrode plate, and the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c are examples of non-forming portions of the active material layer.

正極板21と負極板22とは、巻回のために、それぞれの長手方向を同方向にして、重ねられる。このとき、正極未塗工部21cと負極未塗工部22cとは、正極板21及び負極板22の重なり部分を挟んで互いに反対側に位置する。巻回軸A方向において、正極未塗工部21cの縁21caは、縁21caと上記重なり部分の同じ側に位置する負極板22の縁よりも突出する。負極未塗工部22cの縁22caは、縁22caと上記重なり部分の同じ側に位置する正極板21の縁よりも突出する。ここで、縁21ca及び22caは、極板の縁の一例である。   The positive electrode plate 21 and the negative electrode plate 22 are overlapped with each other in the same longitudinal direction for winding. At this time, the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c are positioned on opposite sides of the overlapping portion of the positive electrode plate 21 and the negative electrode plate 22. In the winding axis A direction, the edge 21ca of the positive electrode uncoated portion 21c protrudes beyond the edge of the negative electrode plate 22 located on the same side of the overlapping portion as the edge 21ca. The edge 22ca of the negative electrode uncoated portion 22c protrudes from the edge of the positive electrode plate 21 located on the same side of the overlapping portion with the edge 22ca. Here, the edges 21ca and 22ca are examples of edges of the electrode plate.

2つのセパレータ23が、1つの負極板22の両側の平坦な主面上にそれぞれ設けられる。このとき、負極未塗工部22cを除く負極板22全体が、セパレータ23によって覆われている。そして、負極未塗工部22cが、2つのセパレータ23の間を通ってセパレータ23よりも突出する。さらに、1つの正極板21が、巻回時に負極板22に内側で隣り合うセパレータ23のさらに内側に位置するように、セパレータ23上に重ねて設けられる。このとき、正極未塗工部21cを除く正極板21全体が、負極板22及びセパレータ23によって覆われており、負極板22に面している。そして、正極未塗工部21cが、2つのセパレータ23よりも突出している。   Two separators 23 are respectively provided on flat main surfaces on both sides of one negative electrode plate 22. At this time, the entire negative electrode plate 22 except the negative electrode uncoated portion 22 c is covered with the separator 23. Then, the negative electrode uncoated portion 22 c protrudes from the separator 23 through between the two separators 23. Furthermore, one positive electrode plate 21 is provided on the separator 23 so as to be positioned further inside the separator 23 adjacent to the negative electrode plate 22 on the inner side during winding. At this time, the entire positive electrode plate 21 excluding the positive electrode uncoated portion 21 c is covered with the negative electrode plate 22 and the separator 23 and faces the negative electrode plate 22. The positive electrode uncoated portion 21 c protrudes beyond the two separators 23.

上述のように積層された1つの正極板21と1つの負極板22と2つのセパレータ23とが重ね合わされた状態で、巻回軸Aを中心に、巻回方向Bで渦巻き状に巻回され、それにより、電極体20が形成される。巻回後の電極体20では、積層された正極未塗工部21cの縁21caが、面状に並び、電極体20の端部20aを形成している。また、積層された負極未塗工部22cの縁22caが、面状に並び、電極体20の端部20bを形成している。端部20a及び20bは、巻回軸Aに略垂直に延在している。   In the state where one positive electrode plate 21, one negative electrode plate 22, and two separators 23 laminated as described above are overlapped, the positive electrode plate 21 is wound in a spiral shape in the winding direction B around the winding axis A. Thereby, the electrode body 20 is formed. In the electrode body 20 after winding, the edges 21ca of the stacked positive electrode uncoated portions 21c are arranged in a planar shape to form an end portion 20a of the electrode body 20. Further, the edges 22ca of the laminated negative electrode uncoated portions 22c are arranged in a planar shape to form the end portion 20b of the electrode body 20. The ends 20a and 20b extend substantially perpendicular to the winding axis A.

さらに、巻回後の電極体20では、積層された正極板21、負極板22及びセパレータ23が、巻回方向Bに沿って延在する壁状体を形成している。具体的には、壁状体は、巻回軸Aを挟んで対向して位置し且つ幅広で平坦である2つの平坦壁状部20c及び20dと、巻回軸Aを挟んで対向して位置し且つ半円状に湾曲した2つの湾曲壁状部20e及び20fとから構成されている。平坦壁状部20c及び20dは、互いに略平行に延在している。湾曲壁状部20e及び20fはそれぞれ、平坦壁状部20cと平坦壁状部20dとを互いに両端で連結する。   Further, in the electrode body 20 after winding, the stacked positive electrode plate 21, negative electrode plate 22 and separator 23 form a wall-like body extending along the winding direction B. Specifically, the wall-like body is positioned opposite to the two flat wall-shaped portions 20c and 20d that are wide and flat while being opposed to each other with the winding axis A interposed therebetween. And two curved wall portions 20e and 20f that are curved in a semicircular shape. The flat wall portions 20c and 20d extend substantially parallel to each other. The curved wall portions 20e and 20f respectively connect the flat wall portion 20c and the flat wall portion 20d to each other at both ends.

図2〜図4を参照すると、電極体20の端部20aでは、平坦壁状部20cの複数層の正極未塗工部21cと、平坦壁状部20dの複数層の正極未塗工部21cとが、平坦壁状部20c及び20dの延在方向と略垂直な方向に分けられる。さらに、2つに分けられた正極未塗工部21cがそれぞれ、集束される。集束された正極未塗工部21cは、正極集電体50と接続される。なお、図4は、図3の電極体20における正極未塗工部21c側の湾曲壁状部20eが幅方向に絞られた状態を示す電極体20の側面図であり、電極体20を端部20a側から見た側面図である。湾曲壁状部20eの幅とは、平坦壁状部20cから平坦壁状部20dに向かう方向の幅のことである。   2 to 4, at the end 20a of the electrode body 20, a plurality of positive electrode uncoated portions 21c of the flat wall-shaped portion 20c and a plurality of positive electrode uncoated portions 21c of the flat wall-shaped portion 20d are formed. Are divided in a direction substantially perpendicular to the extending direction of the flat wall portions 20c and 20d. Furthermore, the positive electrode uncoated portion 21c divided into two parts is focused. The converged positive electrode uncoated portion 21 c is connected to the positive electrode current collector 50. 4 is a side view of the electrode body 20 showing a state in which the curved wall-shaped portion 20e on the positive electrode uncoated portion 21c side in the electrode body 20 of FIG. 3 is narrowed in the width direction. It is the side view seen from the part 20a side. The width of the curved wall portion 20e is a width in a direction from the flat wall portion 20c toward the flat wall portion 20d.

正極集電体50は、1つの板状の第一固定部50aと、2つの脚状の第二固定部50bとを一体に有し、電極体20の正極板21の正極基材21aと同様の材料から形成され得る。第一固定部50aは、蓋体12を貫通して延在する正極端子30の軸部30aと、かしめ接合、溶接等の種々の接続方法で接続される。2つの第二固定部50bはそれぞれ、平坦壁状部20c及び20dで集束された正極未塗工部21cと接続される。第二固定部50bは、当て板51と共に集束された正極未塗工部21cを挟み込み、超音波溶接、抵抗溶接などの溶接によって、当て板51と接合される。これにより、第二固定部50b、当て板51及び正極未塗工部21cが共に接合される。当て板51は、第二固定部50b及び正極未塗工部21cを共に両側から挟むクリップでもよい。ここで、第二固定部50bは、集電体の接続部の一例である。   The positive electrode current collector 50 integrally includes one plate-like first fixing portion 50a and two leg-like second fixing portions 50b, and is similar to the positive electrode substrate 21a of the positive electrode plate 21 of the electrode body 20. Can be formed from the following materials: The first fixing portion 50a is connected to the shaft portion 30a of the positive terminal 30 extending through the lid body 12 by various connection methods such as caulking and welding. The two second fixing portions 50b are respectively connected to the positive electrode uncoated portion 21c focused by the flat wall portions 20c and 20d. The second fixing portion 50b is sandwiched between the positive electrode uncoated portions 21c converged together with the contact plate 51, and is joined to the contact plate 51 by welding such as ultrasonic welding or resistance welding. Thereby, the 2nd fixing | fixed part 50b, the contact plate 51, and the positive electrode uncoated part 21c are joined together. The backing plate 51 may be a clip that sandwiches the second fixed portion 50b and the positive electrode uncoated portion 21c from both sides. Here, the 2nd fixing | fixed part 50b is an example of the connection part of a collector.

同様に、電極体20の端部20bでは、平坦壁状部20cの複数層の負極未塗工部22cと、平坦壁状部20dの複数層の負極未塗工部22cとが、平坦壁状部20c及び20dの延在方向と略垂直な方向に分けられて集束される。集束された負極未塗工部22cは、負極集電体60と接続される。   Similarly, at the end portion 20b of the electrode body 20, a plurality of negative electrode uncoated portions 22c of the flat wall-shaped portion 20c and a plurality of negative electrode uncoated portions 22c of the flat wall-shaped portion 20d are flat wall-shaped. The portions 20c and 20d are focused in a direction substantially perpendicular to the extending direction of the portions 20c and 20d. The converged negative electrode uncoated portion 22 c is connected to the negative electrode current collector 60.

負極集電体60は、1つの板状の第一固定部60aと、2つの脚状の第二固定部60bとを一体に有し、電極体20の負極板22の負極基材22aと同様の材料から形成され得る。第一固定部60aは、蓋体12を貫通して延在する負極端子40の軸部40aと、かしめ接合、溶接等の種々の接続方法で接続される。2つの第二固定部60bはそれぞれ、平坦壁状部20c及び20dで集束された負極未塗工部22cと接続される。第二固定部60bは、当て板61と共に集束された負極未塗工部22cを挟み込み、溶接によって当て板61と接合される。これにより、第二固定部60b、当て板61及び負極未塗工部22cが共に接合される。当て板61は、第二固定部60b及び負極未塗工部22cを共に両側から挟むクリップでもよい。ここで、第二固定部60bは、集電体の接続部の一例である。   The negative electrode current collector 60 has one plate-like first fixing part 60a and two leg-like second fixing parts 60b, and is the same as the negative electrode substrate 22a of the negative electrode plate 22 of the electrode body 20. Can be formed from the following materials: The first fixing portion 60a is connected to the shaft portion 40a of the negative electrode terminal 40 extending through the lid body 12 by various connection methods such as caulking and welding. The two second fixing portions 60b are respectively connected to the negative electrode uncoated portion 22c focused by the flat wall portions 20c and 20d. The second fixing portion 60b sandwiches the negative electrode uncoated portion 22c converged together with the contact plate 61, and is joined to the contact plate 61 by welding. Thereby, the 2nd fixing | fixed part 60b, the contact plate 61, and the negative electrode uncoated part 22c are joined together. The backing plate 61 may be a clip that sandwiches the second fixed portion 60b and the negative electrode uncoated portion 22c from both sides. Here, the 2nd fixing | fixed part 60b is an example of the connection part of an electrical power collector.

上述のように、正極集電体50及び負極集電体60それぞれを介して正極端子30及び負極端子40と電気的及び物理的に接続された電極体20は、その巻回軸Aを蓋体12に沿う方向にして蓋体12に固定される。上述のような電極体20は、縦巻き型の電極体と呼ばれる。   As described above, the electrode body 20 electrically and physically connected to the positive electrode terminal 30 and the negative electrode terminal 40 through the positive electrode current collector 50 and the negative electrode current collector 60 respectively has its winding axis A as a lid body. 12 is fixed to the lid 12 in a direction along the direction 12. The electrode body 20 as described above is called a vertically wound electrode body.

図3及び図5を参照すると、正極集電体50において、2つの第二固定部50bは、第一固定部50aを挟んで互いに対向する位置に位置して第一固定部50aから同方向に突出している。図5は、図4の電極体20が正極集電体50に接合された状態を示す側面図である。さらに、これに限定するものではないが、本実施の形態では、2つの第二固定部50bは、互いに略平行に延在している。2つの第二固定部50bの間の間隙Gの幅B1は、平坦壁状部20cから平坦壁状部20dに向かう方向での電極体20の幅B2よりも小さい。さらに、2つの第二固定部50bはそれぞれ、平坦壁状部20c及び20dの外面よりも電極体20の中心側つまり巻回軸A側に位置している。   Referring to FIGS. 3 and 5, in the positive electrode current collector 50, the two second fixing portions 50 b are located at positions facing each other across the first fixing portion 50 a and are in the same direction from the first fixing portion 50 a. It protrudes. FIG. 5 is a side view showing a state where the electrode body 20 of FIG. 4 is joined to the positive electrode current collector 50. Furthermore, although not limited to this, in the present embodiment, the two second fixing portions 50b extend substantially parallel to each other. The width B1 of the gap G between the two second fixed portions 50b is smaller than the width B2 of the electrode body 20 in the direction from the flat wall portion 20c toward the flat wall portion 20d. Further, the two second fixing portions 50b are located on the center side of the electrode body 20, that is, on the winding axis A side, from the outer surfaces of the flat wall portions 20c and 20d.

電極体20は、湾曲壁状部20eから平坦壁状部20c及び20dの一部にわたる正極未塗工部21cを、正極集電体50の2つの第二固定部50bの間の間隙Gに位置させて第二固定部50bによって外側から狭持されるようにし、第二固定部50bと接合される。   In the electrode body 20, the positive electrode uncoated portion 21 c extending from the curved wall portion 20 e to a part of the flat wall portions 20 c and 20 d is positioned in the gap G between the two second fixed portions 50 b of the positive electrode current collector 50. It is made to pinch from the outside by the 2nd fixing | fixed part 50b, and is joined with the 2nd fixing | fixed part 50b.

このため、図4〜図6に示すように、間隙G内に位置する湾曲壁状部20eから平坦壁状部20c及び20dにわたって、正極未塗工部21cの幅が、間隙Gの幅B1内に収まるように狭められる。なお、図6は、図3の電極体20における正極未塗工部21c側の湾曲壁状部20e付近の拡大斜視図である。そして、湾曲壁状部20eの正極未塗工部21cつまり湾曲正極未塗工部21ceの幅を狭めるために、湾曲正極未塗工部21ce又はその近傍で、正極未塗工部21cが、平坦壁状部20c及び平坦壁状部20dそれぞれの外方から平坦壁状部20c及び20dの内方である電極体20の中央に向かって押圧される。押圧する位置Pは、押圧により変形する湾曲正極未塗工部21ceが、その径を縮小するように全体幅を狭めることができるが、その湾曲形状の滑らかさ及び積層間隔等の積層状態を大きく崩すことを抑え、押圧解除後に幅を戻すように拡がることを抑えることができるような位置であることが望ましい。   For this reason, as shown in FIGS. 4 to 6, the width of the positive electrode uncoated portion 21 c extends from the curved wall portion 20 e located in the gap G to the flat wall portions 20 c and 20 d within the width B 1 of the gap G. It is narrowed to fit in. FIG. 6 is an enlarged perspective view of the vicinity of the curved wall-shaped portion 20e on the positive electrode uncoated portion 21c side in the electrode body 20 of FIG. Then, in order to narrow the width of the positive electrode uncoated portion 21c of the curved wall-shaped portion 20e, that is, the curved positive electrode uncoated portion 21ce, the positive electrode uncoated portion 21c is flat at or near the curved positive electrode uncoated portion 21ce. It is pressed toward the center of the electrode body 20 which is the inside of the flat wall-shaped portions 20c and 20d from the outside of the wall-shaped portion 20c and the flat wall-shaped portion 20d. The pressing position P can reduce the overall width of the curved positive electrode uncoated portion 21ce that is deformed by pressing so that the diameter thereof is reduced, but the curved shape is smooth and the stacking state such as the stacking interval is greatly increased. It is desirable that the position is such that it can be prevented from collapsing and can be prevented from expanding so as to return the width after releasing the pressure.

位置Pに対して平坦壁状部20c及び20dに略垂直な方向の押圧力が作用する場合、位置Pは、図6に示すように、平坦壁状部20c及び20dに略垂直な方向で、湾曲正極未塗工部21ceの最内周面21cebに対向する位置又はその近傍位置であることが望ましい。なお、最内周面21cebは、複数層の湾曲正極未塗工部21ceにおける最も内側に位置する湾曲正極未塗工部21ceを構成する正極基材21aの内周面である。さらに、位置Pは、平坦壁状部20c及び20dに略垂直な方向で、湾曲正極未塗工部21ceの最内周面21cebに対向する位置、又は最内周面21cebの近傍の平坦壁状部20c及び20dにおける正極未塗工部21cの最内周面に対向する位置であることがより望ましい。さらにまた、位置Pは、平坦壁状部20c及び20dに略垂直な方向で、最内周面21cebに対向する位置であることがよりさらに望ましい。   When a pressing force in a direction substantially perpendicular to the flat wall portions 20c and 20d acts on the position P, the position P is in a direction substantially perpendicular to the flat wall portions 20c and 20d, as shown in FIG. A position facing the innermost circumferential surface 21ceb of the curved positive electrode uncoated portion 21ce or a position in the vicinity thereof is desirable. The innermost peripheral surface 21ceb is the inner peripheral surface of the positive electrode base material 21a that constitutes the curved positive electrode uncoated portion 21ce located on the innermost side in the plurality of layers of the curved positive electrode uncoated portion 21ce. Further, the position P is a direction substantially perpendicular to the flat wall-shaped portions 20c and 20d and is opposed to the innermost peripheral surface 21ceb of the curved positive electrode uncoated portion 21ce, or a flat wall shape near the innermost peripheral surface 21ceb. It is more desirable that the position is opposite to the innermost peripheral surface of the positive electrode uncoated portion 21c in the portions 20c and 20d. Furthermore, the position P is more preferably a position facing the innermost peripheral surface 21ceb in a direction substantially perpendicular to the flat wall portions 20c and 20d.

例えば、位置Pが、平坦壁状部20c及び20dに略垂直な方向で最内周面21cebに対向する位置又はその近傍位置に対して、平坦壁状部20c及び20dと反対側つまり湾曲正極未塗工部21ceの突出側に位置する場合、湾曲正極未塗工部21ceは、位置P及びその近傍のみをその径方向内側に向かって窪ませるように部分的に変形する。この結果、所望とする湾曲正極未塗工部21ceの幅が得られない可能性が高くなる。また、位置Pが、平坦壁状部20c及び20dに略垂直な方向で最内周面21cebに対向する位置又はその近傍位置から離れて、平坦壁状部20c及び20d側に位置する場合、押圧力を受けて幅を狭めた電極体20は、押圧力の解除後、幅を元に戻すような挙動をする。   For example, the position P is opposite to the flat wall-shaped portions 20c and 20d, that is, the curved positive electrode is not positioned with respect to the position facing the innermost peripheral surface 21ceb in the direction substantially perpendicular to the flat wall-shaped portions 20c and 20d or the vicinity thereof. When located on the protruding side of the coating part 21ce, the curved positive electrode uncoated part 21ce is partially deformed so that only the position P and its vicinity are recessed toward the inside in the radial direction. As a result, there is a high possibility that the desired width of the curved positive electrode uncoated portion 21ce cannot be obtained. Further, when the position P is located on the side of the flat wall portions 20c and 20d, away from the position facing the innermost peripheral surface 21ceb or in the vicinity thereof in the direction substantially perpendicular to the flat wall portions 20c and 20d, The electrode body 20 whose width is narrowed by receiving pressure behaves such that the width is restored after the pressing force is released.

上述のような位置Pでの押圧を受けることによって、正極未塗工部21cは、正極集電体50の第二固定部50bの間隙Gに対応する部位で全体的に幅を狭め、湾曲正極未塗工部21ce又はその近傍で部分的に幅をさらに狭めるように絞られる形状を形成する。また、負極未塗工部22cも、正極未塗工部21cと同様に押圧を受けるように構成される。そして、負極未塗工部22cは、正極集電体50と同様の構成を有する負極集電体60の第二固定部60bの間隙Gに対応する部位で全体的に幅を狭め、その湾曲負極未塗工部22ce又はその近傍で部分的に幅をさらに狭めるように絞られる形状を形成する。   By receiving the pressure at the position P as described above, the positive electrode uncoated portion 21c is entirely reduced in width at a portion corresponding to the gap G of the second fixed portion 50b of the positive electrode current collector 50, and the curved positive electrode A shape that is narrowed so as to further narrow the width is formed at or near the uncoated portion 21ce. The negative electrode uncoated portion 22c is also configured to be pressed in the same manner as the positive electrode uncoated portion 21c. The negative electrode uncoated portion 22c is narrowed as a whole at a portion corresponding to the gap G of the second fixed portion 60b of the negative electrode current collector 60 having the same configuration as the positive electrode current collector 50, and the curved negative electrode A shape that is narrowed to further narrow the width is formed at or near the uncoated portion 22ce.

上述のように湾曲正極未塗工部21ce及び湾曲負極未塗工部22ceを変形させる場合、正極未塗工部21c及び負極未塗工部22cに折り目、皺等が発生する場合がある。また、電極体20の平坦壁状部20c及び20dの集束時、湾曲正極未塗工部21ce及び湾曲負極未塗工部22ceを中心とする正極未塗工部21c及び負極未塗工部22cに、折り目、皺等が発生する場合もある。   When the curved positive electrode uncoated portion 21ce and the curved negative electrode uncoated portion 22ce are deformed as described above, folds, wrinkles, and the like may occur in the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c. Further, when the flat wall-like portions 20c and 20d of the electrode body 20 are focused, the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c centered on the curved positive electrode uncoated portion 21ce and the curved negative electrode uncoated portion 22ce In some cases, creases, wrinkles, etc. may occur.

折り目、皺等を含む状態の湾曲正極未塗工部21ceが上述のような変形を受ける又は外力を受けると、折り目、皺等が、電極体20の巻回軸A方向に成長して伸び、正極板21における正極活物質層21bが形成されている部位又はセパレータ23と対向する部位にまで至る可能性がある。同様に、折り目、皺等を含む状態の湾曲負極未塗工部22ceが上述のような変形を受ける又は外力を受けると、折り目、皺等が、電極体20の巻回軸A方向に成長して伸び、負極板22における負極活物質層22bの形成部位又はセパレータ23との対向部位にまで至る可能性がある。正極活物質層21b及び負極活物質層22bにおける折り目、皺等を含む部位では、隣り合う負極板22及び正極板21との距離が不均一になり、電流の偏りが生じる可能性がある。また、成長した折り目、皺等が、鋭く突出するような形状を有すると、セパレータ23を突き破り、それにより、正極板21と負極板22とが短絡する可能性がある。   When the curved positive electrode uncoated portion 21ce in a state including a crease, a crease or the like is subjected to the above-described deformation or an external force, the crease, the crease or the like grows and extends in the winding axis A direction of the electrode body 20, There is a possibility that the positive electrode plate 21 may reach a portion where the positive electrode active material layer 21 b is formed or a portion facing the separator 23. Similarly, when the curved negative electrode uncoated portion 22ce including folds, wrinkles, etc. is subjected to the above-described deformation or external force, the folds, wrinkles, etc. grow in the direction of the winding axis A of the electrode body 20. May extend to the formation site of the negative electrode active material layer 22 b in the negative electrode plate 22 or the site facing the separator 23. In a portion including a fold, a crease or the like in the positive electrode active material layer 21b and the negative electrode active material layer 22b, the distance between the adjacent negative electrode plate 22 and the positive electrode plate 21 becomes non-uniform, and current bias may occur. Further, if the grown folds, wrinkles, etc. have a shape that protrudes sharply, the separator 23 may be pierced, thereby causing a short circuit between the positive electrode plate 21 and the negative electrode plate 22.

巻回軸A方向の折り目、皺等の伸長を抑制するために、図6に示すように、電極体20の湾曲正極未塗工部21ceには、電極体20の巻回方向Bである湾曲正極未塗工部21ceの周方向に沿って延在する帯状突起形状の断面変化部24が、形成されている。つまり、断面変化部24は、折り目、皺等の伸長方向と交差する方向に延在する。さらに、断面変化部24は、湾曲正極未塗工部21ce上において、セパレータ23における正極未塗工部21cに近位の縁23aと、湾曲正極未塗工部21ceの縁である正極未塗工部21cの縁21caとの間に位置する。そして、断面変化部24は、湾曲正極未塗工部21ceの上記変形前に形成される。ここで、断面変化部24は、凸部によって形成される断面変化部の一例である。   In order to suppress the expansion of folds, wrinkles and the like in the winding axis A direction, the curved positive electrode uncoated portion 21ce of the electrode body 20 is curved in the winding direction B of the electrode body 20, as shown in FIG. A cross-section changing portion 24 having a belt-like protrusion shape extending along the circumferential direction of the positive electrode uncoated portion 21ce is formed. That is, the cross-section changing part 24 extends in a direction intersecting with the extending direction of folds, wrinkles and the like. Further, the cross-section changing portion 24 is formed on the curved positive electrode uncoated portion 21ce, the edge 23a proximal to the positive electrode uncoated portion 21c in the separator 23, and the positive electrode uncoated which is the edge of the curved positive electrode uncoated portion 21ce. It is located between the edge 21ca of the part 21c. And the cross-section change part 24 is formed before the said deformation | transformation of the curved positive electrode uncoated part 21ce. Here, the cross-section changing portion 24 is an example of a cross-section changing portion formed by a convex portion.

本実施の形態では、断面変化部24は、正極未塗工部21cを変形させて、電極体20の内方から外方に向かってつまり径方向外側に向かって突出する凸部を形成するように形成された皺又は折り目によって、構成されている。断面変化部24は、巻回方向Bに沿って正極未塗工部21cを折りたたむことによって形成されてもよい。つまり、断面変化部24は、湾曲正極未塗工部21ceに巻回軸A方向に沿う折り目を形成するような巻回軸A周りの曲げ応力に対する湾曲正極未塗工部21ceの剛性を向上するように形成される。このような断面変化部24は、湾曲正極未塗工部21ceに生じた折り目、皺等が、セパレータ23の縁23aに向かう巻回軸A方向に断面変化部24を越えて伸長することを抑制する。   In the present embodiment, the cross-section changing portion 24 deforms the positive electrode uncoated portion 21c to form a convex portion that protrudes from the inside of the electrode body 20 to the outside, that is, radially outward. It is comprised by the crease | fold or crease | fold formed in this. The cross-section changing portion 24 may be formed by folding the positive electrode uncoated portion 21 c along the winding direction B. That is, the cross-section changing portion 24 improves the rigidity of the curved positive electrode uncoated portion 21ce with respect to bending stress around the winding axis A that forms a fold along the winding axis A direction in the curved positive electrode uncoated portion 21ce. Formed as follows. Such a cross-section changing portion 24 suppresses the creases, wrinkles, etc. generated in the curved positive electrode uncoated portion 21ce from extending beyond the cross-section changing portion 24 in the winding axis A direction toward the edge 23a of the separator 23. To do.

本実施の形態では、断面変化部24は、複数層の湾曲正極未塗工部21ceのうちの最外周に位置する最外湾曲正極未塗工部21ceaのみに形成される。しかしながら、断面変化部24は、最外湾曲正極未塗工部21ceaから径方向内側に向かって複数層の湾曲正極未塗工部21ceに形成されてもよく、最外湾曲正極未塗工部21cea以外の1層以上の湾曲正極未塗工部21ceに形成されてもよく、全ての層の湾曲正極未塗工部21ceに形成されてもよい。   In the present embodiment, the cross-section changing portion 24 is formed only in the outermost curved positive electrode uncoated portion 21cea located on the outermost periphery of the multiple layers of curved positive electrode uncoated portions 21ce. However, the cross-section changing portion 24 may be formed in a plurality of layers of the curved positive electrode uncoated portion 21ce in the radial direction from the outermost curved positive electrode uncoated portion 21cea, and the outermost curved positive electrode uncoated portion 21cea. It may be formed in one or more layers of the curved positive electrode uncoated portion 21ce, or may be formed in all layers of the curved positive electrode uncoated portion 21ce.

また、本実施の形態では、断面変化部24は、平坦壁状部20c及び20dに沿う方向で湾曲正極未塗工部21ceにおける最も突出する部位つまり巻回軸Aから最も離れた部位を含むように位置し、巻回方向Bに沿った湾曲正極未塗工部21ceの一部にわたって延在する。上記の湾曲正極未塗工部21ceにおける最も突出する部位では、位置Pで正極未塗工部21cが押圧されたときに、最も大きい曲げモーメントが作用する部位である。つまり、断面変化部24は、上述のような最も大きい曲げモーメントが作用する部位を含むように配置されることが、望ましい。   Further, in the present embodiment, the cross-section changing portion 24 includes the most protruding portion in the curved positive electrode uncoated portion 21ce in the direction along the flat wall portions 20c and 20d, that is, the portion farthest from the winding axis A. And extends over a portion of the curved positive electrode uncoated portion 21ce along the winding direction B. The most protruding portion of the curved positive electrode uncoated portion 21ce is a portion where the largest bending moment acts when the positive electrode uncoated portion 21c is pressed at the position P. That is, it is desirable that the cross-section changing portion 24 is arranged so as to include a portion where the largest bending moment acts as described above.

また、断面変化部24は、湾曲正極未塗工部21ceにおいて、位置Pに関して、平坦壁状部20c及び20dと反対側に配置されることが、望ましい。さらに、断面変化部24は、位置Pから離れていることが、望ましい。位置Pから離れた断面変化部24は、押圧時に押し潰されずに、皺、折り目等の伸長を抑制する機能を果たすことができる。位置Pに関して平坦壁状部20c及び20dと反対側に配置される断面変化部24は、湾曲正極未塗工部21ceにおいて押圧時に大きく変形する部位での皺、折り目等の伸長を効果的に抑制する。   In addition, it is desirable that the cross-section changing portion 24 be disposed on the opposite side of the curved positive electrode uncoated portion 21ce with respect to the position P from the flat wall portions 20c and 20d. Furthermore, it is desirable that the cross-section changing portion 24 is away from the position P. The cross-section changing portion 24 away from the position P can fulfill the function of suppressing the expansion of wrinkles, creases, etc. without being crushed when pressed. The cross-section changing portion 24 arranged on the opposite side of the flat wall-shaped portions 20c and 20d with respect to the position P effectively suppresses the expansion of wrinkles, creases, etc. at the portions that are largely deformed when pressed in the curved positive electrode uncoated portion 21ce. To do.

また、断面変化部24は、巻回軸A方向で湾曲正極未塗工部21ceの縁側よりも正極活物質層21b側に配置されることが、望ましい。これは、正極活物質層21b側での湾曲正極未塗工部21ceの変形量が、湾曲正極未塗工部21ceの縁側よりも小さいためである。   In addition, it is desirable that the cross-section changing portion 24 is disposed closer to the positive electrode active material layer 21b side than the edge side of the curved positive electrode uncoated portion 21ce in the winding axis A direction. This is because the deformation amount of the curved positive electrode uncoated portion 21ce on the positive electrode active material layer 21b side is smaller than the edge side of the curved positive electrode uncoated portion 21ce.

また、本実施の形態では、断面変化部24は、電極体20の巻回方向Bに沿って延在している、つまり、正極未塗工部21cの縁21ca及びセパレータ23の縁23aに沿って延在している。断面変化部24は、電極体20の巻回軸Aと単に交差する方向に延在してもよい。   Moreover, in this Embodiment, the cross-sectional change part 24 is extended along the winding direction B of the electrode body 20, ie, along the edge 21ca of the positive electrode uncoated part 21c, and the edge 23a of the separator 23. It is extended. The cross-section changing portion 24 may extend in a direction that simply intersects with the winding axis A of the electrode body 20.

電極体20の湾曲負極未塗工部22ceにおいても湾曲正極未塗工部21ceと同様に、湾曲負極未塗工部22ceの周方向に沿って延在する帯状突起形状の断面変化部24が、形成されている。負極板22上において、断面変化部24は、セパレータ23における縁23aと反対側の縁23bと、負極未塗工部22cの縁22caとの間に位置する。   In the curved negative electrode uncoated portion 22ce of the electrode body 20, similarly to the curved negative electrode uncoated portion 21ce, a belt-like protrusion-shaped cross-section changing portion 24 extending along the circumferential direction of the curved negative electrode uncoated portion 22ce is provided. Is formed. On the negative electrode plate 22, the cross-section changing part 24 is located between the edge 23b of the separator 23 opposite to the edge 23a and the edge 22ca of the negative electrode uncoated part 22c.

また、本実施の形態では、電極体20の巻回軸A方向において、1つの断面変化部24が、湾曲正極未塗工部21ce及び湾曲負極未塗工部22ceそれぞれに配置されている。さらに、電極体20の巻回方向Bにおいて、1つの断面変化部24が、湾曲正極未塗工部21ce及び湾曲負極未塗工部22ceそれぞれに配置されている。断面変化部24は、巻回軸A方向及び巻回方向Bのいずれにおいても、2つ以上配置されてもよい。   In the present embodiment, one cross-section changing portion 24 is disposed in each of the curved positive electrode uncoated portion 21ce and the curved negative electrode uncoated portion 22ce in the winding axis A direction of the electrode body 20. Furthermore, in the winding direction B of the electrode body 20, one cross-section changing portion 24 is disposed in each of the curved positive electrode uncoated portion 21ce and the curved negative electrode uncoated portion 22ce. Two or more cross-section changing portions 24 may be arranged in any of the winding axis A direction and the winding direction B.

また、断面変化部24は、電極体20の巻回方向Bで、湾曲正極未塗工部21ceの全体にわたって延在してよく、この場合、断面変化部24は、連続していても不連続であってもよい。さらに、図7に示すように、断面変化部24は、湾曲正極未塗工部21ceの全体にわたり且つ平坦壁状部20c及び20dの少なくとも一方の正極未塗工部21cに至っていてもよい。湾曲負極未塗工部22ceに形成される断面変化部24も、湾曲正極未塗工部21ceの断面変化部24の上記構成と同様の構成を有してもよい。   Further, the cross-section changing portion 24 may extend over the entire curved positive electrode uncoated portion 21ce in the winding direction B of the electrode body 20, and in this case, the cross-section changing portion 24 is discontinuous even if continuous. It may be. Further, as shown in FIG. 7, the cross-section changing portion 24 may extend over the entire curved positive electrode uncoated portion 21ce and to at least one positive electrode uncoated portion 21c of the flat wall portions 20c and 20d. The cross-section changing portion 24 formed in the curved negative electrode uncoated portion 22ce may also have the same configuration as that of the cross-section changing portion 24 of the curved positive electrode uncoated portion 21ce.

また、本実施の形態では、断面変化部24は、電極体20の巻回時に、ロールから引き出される正極板21及び負極板22のそれぞれの正極未塗工部21c及び負極未塗工部22cに形成されてよい。   Moreover, in this Embodiment, the cross-sectional change part 24 is each in the positive electrode uncoated part 21c and the negative electrode uncoated part 22c of the positive electrode plate 21 and the negative electrode plate 22 which are pulled out from a roll at the time of winding of the electrode body 20. May be formed.

上述したように、本実施の形態に係る蓄電素子100は、巻回された正極板21及び負極板22によって形成される電極体20を備える。正極板21及び負極板22は、正極板21及び負極板22の湾曲部分における正極板21及び負極板22の巻回軸A方向の端部21d及び22dに、正極板21及び負極板22の巻回方向Bに沿って延在する凸部によって形成される断面変化部24を有する。   As described above, the energy storage device 100 according to the present embodiment includes the electrode body 20 formed by the positive electrode plate 21 and the negative electrode plate 22 that are wound. The positive electrode plate 21 and the negative electrode plate 22 are wound around the end portions 21 d and 22 d in the winding axis A direction of the positive electrode plate 21 and the negative electrode plate 22 in the curved portions of the positive electrode plate 21 and the negative electrode plate 22. The cross-section changing portion 24 is formed by a convex portion extending along the turning direction B.

上述の構成において、巻回方向Bに沿って延在する凸部を形成する断面変化部24は、正極板21及び負極板22に巻回軸A方向に沿った折り目が入ることを抑制する。よって、断面変化部24は、巻回軸A方向で、断面変化部24よりも正極板21の端部21dの縁21ca側に形成された正極板21の折り目、皺等、及び断面変化部24よりも負極板22の端部22dの縁22ca側に形成された負極板22の折り目、皺等が、断面変化部24を越えて反対側に伸長することを抑制する。従って、凸部を形成する断面変化部24による簡易な構成によって、正極板21及び負極板22における皺、折り目等の発生が抑制される。   In the above-described configuration, the cross-section changing portion 24 that forms the convex portion extending along the winding direction B suppresses the folds along the winding axis A direction from entering the positive electrode plate 21 and the negative electrode plate 22. Therefore, the cross-section changing portion 24 is in the winding axis A direction, and the cross-section changing portion 24 has a fold, a crease, and the like of the positive electrode plate 21 formed on the edge 21ca side of the end 21d of the positive electrode plate 21 with respect to the cross-section changing portion 24. In addition, the folds, wrinkles, and the like of the negative electrode plate 22 formed on the edge 22ca side of the end 22d of the negative electrode plate 22 are prevented from extending beyond the cross-section changing portion 24 to the opposite side. Therefore, the occurrence of wrinkles, creases, and the like in the positive electrode plate 21 and the negative electrode plate 22 is suppressed by a simple configuration using the cross-sectional change portion 24 that forms the convex portion.

実施の形態に係る蓄電素子100において、断面変化部24は、正極板21及び負極板22の帯状をした変形部分によって形成される。さらに、上記変形部分によって形成される断面変化部24は、正極板21及び負極板22の折り曲げ部分によって形成される。上述の構成によって、断面変化部24の構成が簡易になる。   In power storage element 100 according to the embodiment, cross-section changing portion 24 is formed by a belt-like deformed portion of positive electrode plate 21 and negative electrode plate 22. Further, the cross-section changing portion 24 formed by the deformed portion is formed by a bent portion of the positive electrode plate 21 and the negative electrode plate 22. With the above-described configuration, the configuration of the cross-section changing unit 24 is simplified.

実施の形態に係る蓄電素子100において、正極板21及び負極板22はそれぞれ、正極基材21a及び負極基材22aと、正極基材21a及び負極基材22a上に形成される正極活物質層21b及び負極活物質層22bとを有する。断面変化部24は、正極基材21aの巻回軸A方向の端部21dにおける正極活物質層21bの非形成部である正極未塗工部21c、及び、負極基材22aの巻回軸A方向の端部22dにおける負極活物質層22bの非形成部である負極未塗工部22cに、位置する。上述の構成において、正極活物質層21b及び負極活物質層22bに断面変化部24が形成されないため、隣り合って積層する正極活物質層21b及び負極活物質層22bの間隔を均一にすることができる。これにより、正極活物質層21b及び負極活物質層22bにおける電流の偏りが低減する。   In the electricity storage device 100 according to the embodiment, the positive electrode plate 21 and the negative electrode plate 22 are respectively a positive electrode base material 21a and a negative electrode base material 22a, and a positive electrode active material layer 21b formed on the positive electrode base material 21a and the negative electrode base material 22a. And a negative electrode active material layer 22b. The cross-section changing portion 24 includes a positive electrode uncoated portion 21c that is a non-forming portion of the positive electrode active material layer 21b at the end portion 21d in the winding axis A direction of the positive electrode base material 21a, and a winding axis A of the negative electrode base material 22a. It is located in the negative electrode uncoated portion 22c which is a non-formation portion of the negative electrode active material layer 22b at the end 22d in the direction. In the above-described configuration, since the cross-sectional change portion 24 is not formed in the positive electrode active material layer 21b and the negative electrode active material layer 22b, the interval between the positive electrode active material layer 21b and the negative electrode active material layer 22b stacked adjacent to each other can be made uniform. it can. Thereby, current bias in the positive electrode active material layer 21b and the negative electrode active material layer 22b is reduced.

実施の形態に係る蓄電素子100において、断面変化部24は、正極板21の端部21dのうちの巻回の最外周の正極板21の端部21dに少なくとも配置される。また、断面変化部24は、負極板22の端部22dのうちの巻回の最外周の負極板22の端部22dに少なくとも配置される。上述の構成において、電極体20以外のものと接触し変形する可能性が最も高い最外周の正極板21及び負極板22の端部21d及び22dに断面変化部24を配置することによって、正極板21の端部21d及び負極板22の端部22dにおける皺、折り目等の発生が効果的に抑制される。   In the electricity storage device 100 according to the embodiment, the cross-section changing portion 24 is disposed at least at the end portion 21 d of the positive electrode plate 21 at the outermost periphery of the winding among the end portions 21 d of the positive electrode plate 21. Further, the cross-section changing portion 24 is disposed at least at the end portion 22d of the negative electrode plate 22 at the outermost periphery of the winding in the end portion 22d of the negative electrode plate 22. In the above-described configuration, the positive electrode plate is provided by disposing the cross-section changing portions 24 at the end portions 21d and 22d of the outermost positive electrode plate 21 and the negative electrode plate 22 that are most likely to come into contact with the electrode body 20 and deform. Occurrence of wrinkles, creases, etc. at the end 21d of 21 and the end 22d of the negative electrode plate 22 is effectively suppressed.

実施の形態に係る蓄電素子100は、正極板21及び負極板22と共に巻回されており且つ巻回されて重なる正極板21及び負極板22の間に介在するセパレータ23を備える。断面変化部24は、セパレータ23の巻回軸A方向の縁23a又は23bと正極板21の巻回軸A方向の縁21ca又は負極板22の巻回軸A方向の縁22caとの間に配置される。上述の構成において、断面変化部24がセパレータ23と接触し損傷させることが抑制される。   The power storage device 100 according to the embodiment includes a separator 23 that is wound together with the positive electrode plate 21 and the negative electrode plate 22 and interposed between the positive electrode plate 21 and the negative electrode plate 22 that are wound and overlapped. The cross-section changing portion 24 is disposed between the edge 23a or 23b of the separator 23 in the winding axis A direction and the edge 21ca of the positive electrode plate 21 in the winding axis A direction or the edge 22ca of the negative electrode plate 22 in the winding axis A direction. Is done. In the above-described configuration, the cross-section changing portion 24 is prevented from coming into contact with the separator 23 and being damaged.

実施の形態に係る蓄電素子100は、間隙Gを形成し且つ間隙G内で電極体20を狭持して電極体20と接続される第二固定部50b及び60bを有する正極集電体50及び負極集電体60を備える。電極体20は、巻回軸Aと交差する方向に幅狭になる変形を受けて間隙G内に挿入されており、断面変化部24が位置する正極板21及び負極板22の端部21d及び22dが、間隙G内に位置する。上述の構成において、断面変化部24は、電極体20における変形を受ける部位の正極板21及び負極板22における皺、折り目等の発生を抑制する。   The power storage device 100 according to the embodiment includes a positive electrode current collector 50 having second fixing portions 50b and 60b that form a gap G and sandwich the electrode body 20 in the gap G and are connected to the electrode body 20. A negative electrode current collector 60 is provided. The electrode body 20 is inserted into the gap G under deformation that becomes narrow in the direction crossing the winding axis A, and the positive electrode plate 21 where the cross-section changing portion 24 is located and the end portion 21d of the negative electrode plate 22 and 22d is located in the gap G. In the above-described configuration, the cross-section changing portion 24 suppresses the generation of wrinkles, creases, and the like in the positive electrode plate 21 and the negative electrode plate 22 at the portions that are subject to deformation in the electrode body 20.

実施の形態に係る蓄電素子100を製造する場合、その製造方法は、正極板21及び負極板22を巻回して電極体20を作製する工程と、正極板21及び負極板22の巻回時に、正極板21及び負極板22に断面変化部24を形成する工程とを含む。上述の構成によって、断面変化部24は、正極板21及び負極板22の任意の位置に効率的に形成されることができる。   When manufacturing the electricity storage device 100 according to the embodiment, the manufacturing method includes the steps of winding the positive electrode plate 21 and the negative electrode plate 22 to produce the electrode body 20, and winding the positive electrode plate 21 and the negative electrode plate 22. Forming the cross-section changing portion 24 in the positive electrode plate 21 and the negative electrode plate 22. With the above-described configuration, the cross-section changing portion 24 can be efficiently formed at an arbitrary position on the positive electrode plate 21 and the negative electrode plate 22.

[変形例]
また、実施の形態に係る蓄電素子100の変形例として、以下のような構成が挙げられる。具体的には、図8に示されるように、変形例に係る蓄電素子の電極体20では、帯状突起形状の断面変化部24の代わりに溝状の断面変化部25が形成されている。なお、図8は、実施の形態に係る蓄電素子の変形例における電極体20を、図6と同様に示す斜視図である。また、以下の変形例の説明において、前出した図における参照符号と同一の符号の構成要素は、同一又は同様な構成要素であるので、その詳細な説明は省略する。
[Modification]
Moreover, the following structures are mentioned as a modification of the electrical storage element 100 which concerns on embodiment. Specifically, as illustrated in FIG. 8, in the electrode body 20 of the electricity storage device according to the modification, a groove-shaped cross-section changing portion 25 is formed instead of the belt-like protrusion-shaped cross-section changing portion 24. FIG. 8 is a perspective view showing the electrode body 20 in a modification of the energy storage device according to the embodiment in the same manner as FIG. Further, in the following description of the modified examples, the constituent elements having the same reference numerals as the reference numerals in the previous drawings are the same or similar constituent elements, and thus detailed description thereof is omitted.

電極体20の正極板21の湾曲正極未塗工部21ceでは、電極体20の巻回方向Bに沿って延在し且つ溝状に窪んだ断面変化部25が、実施の形態に係る蓄電素子100における断面変化部24と同様の位置、形状及び寸法で、形成されているが、これに限定されるわけではない。本変形例では、断面変化部25は、湾曲正極未塗工部21ceに、電極体20の外方から内方に向かってつまり湾曲正極未塗工部21ceの径方向内側に向かって窪む凹部を形成するように形成された折り目によって、構成されている。断面変化部25は、巻回方向Bに沿って、正極未塗工部21cを電極体20の内方に向かって突出するように折りたたむことによって形成されてもよい。断面変化部25は、湾曲正極未塗工部21ceに巻回軸A方向に沿う折り目を形成するような巻回軸A周りの曲げ応力に対する湾曲正極未塗工部21ceの剛性を向上するように形成される。このような断面変化部25は、湾曲正極未塗工部21ceに生じた折り目、皺等が、巻回軸A方向に断面変化部25を越えて伸長することを抑制する。ここで、断面変化部25は、凹部によって形成される断面変化部の一例である。   In the curved positive electrode uncoated portion 21ce of the positive electrode plate 21 of the electrode body 20, the cross-section changing portion 25 extending along the winding direction B of the electrode body 20 and recessed in a groove shape is a power storage device according to the embodiment. Although it is formed with the same position, shape and dimensions as the cross-section changing portion 24 in 100, it is not limited to this. In this modification, the cross-section changing portion 25 is a concave portion that is recessed in the curved positive electrode uncoated portion 21ce from the outside of the electrode body 20 toward the inside, that is, inward in the radial direction of the curved positive electrode uncoated portion 21ce. It is comprised by the fold formed so that it may form. The cross-section changing portion 25 may be formed by folding the positive electrode uncoated portion 21 c along the winding direction B so as to protrude inward of the electrode body 20. The cross-section changing portion 25 improves the rigidity of the curved positive electrode uncoated portion 21ce with respect to bending stress around the winding axis A so as to form a fold along the winding axis A direction in the curved positive electrode uncoated portion 21ce. It is formed. Such a cross-sectional change part 25 suppresses that the crease | fold, wrinkle, etc. which arose in the curved positive electrode uncoated part 21ce extend beyond the cross-section change part 25 in the winding axis A direction. Here, the cross-section changing portion 25 is an example of a cross-section changing portion formed by a recess.

本変形例では、断面変化部25は、複数層の湾曲正極未塗工部21ceのうちの最外湾曲正極未塗工部21ceaのみに形成される。しかしながら、断面変化部25は、最外湾曲正極未塗工部21ceaから径方向内側に向かって複数層の湾曲正極未塗工部21ceに形成されてもよく、最外湾曲正極未塗工部21cea以外の1層以上の湾曲正極未塗工部21ceに形成されてもよく、全ての層の湾曲正極未塗工部21ceに形成されてもよい。   In the present modification, the cross-section changing portion 25 is formed only in the outermost curved positive electrode uncoated portion 21cea among the multiple layers of curved positive electrode uncoated portions 21ce. However, the cross-section changing portion 25 may be formed in the plurality of layers of the curved positive electrode uncoated portion 21ce in the radial direction from the outermost curved positive electrode uncoated portion 21cea, and the outermost curved positive electrode uncoated portion 21cea. It may be formed in one or more layers of the curved positive electrode uncoated portion 21ce, or may be formed in all layers of the curved positive electrode uncoated portion 21ce.

断面変化部25も、位置Pで電極体20の正極未塗工部21cが押圧されたときに、最も大きい曲げモーメントが作用する部位を含むように配置されることが、望ましい。そして、断面変化部25は、湾曲正極未塗工部21ceにおいて、位置Pに関して、平坦壁状部20c及び20dと反対側に配置され、さらに、位置Pから離れていることが、望ましい。断面変化部25はまた、巻回軸A方向で湾曲正極未塗工部21ceの縁側よりも正極活物質層21b側に配置されることが、望ましい。断面変化部25はまた、正極未塗工部21cの縁21caとセパレータ23の縁23aとの間に配置されることが、望ましい。断面変化部25は、正極未塗工部21cの縁21ca及びセパレータ23の縁23aに沿って延在しているが、電極体20の巻回軸Aと単に交差する方向に延在してもよい。   It is desirable that the cross-section changing portion 25 is also arranged to include a portion where the largest bending moment acts when the positive electrode uncoated portion 21c of the electrode body 20 is pressed at the position P. And it is desirable for the cross-sectional change part 25 to be arrange | positioned regarding the position P in the curved positive electrode uncoated part 21ce on the opposite side to the flat wall-shaped parts 20c and 20d, and to be further away from the position P. It is desirable that the cross-section changing portion 25 is also disposed closer to the positive electrode active material layer 21b side than the edge side of the curved positive electrode uncoated portion 21ce in the winding axis A direction. It is desirable that the cross-section changing portion 25 is also disposed between the edge 21ca of the positive electrode uncoated portion 21c and the edge 23a of the separator 23. Although the cross-section changing portion 25 extends along the edge 21ca of the positive electrode uncoated portion 21c and the edge 23a of the separator 23, the cross-section changing portion 25 may extend in a direction that simply intersects with the winding axis A of the electrode body 20. Good.

電極体20の湾曲負極未塗工部22ceにおいても湾曲正極未塗工部21ceと同様に、湾曲負極未塗工部22ceの周方向に沿って延在する溝状の断面変化部25が、形成されている。   Also in the curved negative electrode uncoated portion 22ce of the electrode body 20, the groove-shaped cross-section changing portion 25 extending along the circumferential direction of the curved negative electrode uncoated portion 22ce is formed, similarly to the curved positive electrode uncoated portion 21ce. Has been.

湾曲正極未塗工部21ce及び湾曲負極未塗工部22ceそれぞれに、1つの断面変化部25が配置されてもよく、2つ以上の断面変化部25が配置されてもよい。断面変化部25は、電極体20の巻回方向Bで、湾曲正極未塗工部21ce及び湾曲負極未塗工部22ceそれぞれの一部又は全体にわたって連続的又は不連続的に延在してよく、さらに、平坦壁状部20c及び20dの少なくとも一方にわたって延在してもよい。   One cross-section changing portion 25 may be arranged in each of the curved positive electrode uncoated portion 21ce and the curved negative electrode uncoated portion 22ce, or two or more cross-section changing portions 25 may be arranged. The cross-section changing portion 25 may extend continuously or discontinuously over part or all of the curved positive electrode uncoated portion 21ce and the curved negative electrode uncoated portion 22ce in the winding direction B of the electrode body 20. Furthermore, it may extend over at least one of the flat wall portions 20c and 20d.

本変形例の断面変化部25は、電極体20の巻回時に、ロールから引き出される正極板21及び負極板22のそれぞれの正極未塗工部21c及び負極未塗工部22cに形成され得る。又は、断面変化部25は、巻回後の電極体20において、正極未塗工部21c及び負極未塗工部22cをそれぞれ、電極体20の外方から内方に向かって線状に押圧することによって、形成され得る。このとき、一度の押圧によって、複数層の正極未塗工部21c又は負極未塗工部22cにわたって、断面変化部25が形成されることができる。例えば、巻回後の電極体20に断面変化部25が形成される場合、位置Pで電極体20の正極未塗工部21c及び負極未塗工部22cが押圧されるときと同時に断面変化部25が形成されてもよい。この場合、2つの位置Pで正極未塗工部21c又は負極未塗工部22cを押圧する治具が、湾曲正極未塗工部21ce又は湾曲負極未塗工部22ceを覆って押圧するように構成され、湾曲正極未塗工部21ce又は湾曲負極未塗工部22ceを押圧する治具の部分に、断面変化部25を形成する突起が形成されてもよい。   The cross-section changing portion 25 of the present modification can be formed on each of the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c of the positive electrode plate 21 and the negative electrode plate 22 drawn from the roll when the electrode body 20 is wound. Alternatively, the cross-section changing portion 25 presses the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c linearly from the outside of the electrode body 20 toward the inside thereof in the wound electrode body 20. Can be formed. At this time, the cross-sectional change part 25 can be formed over the positive electrode uncoated part 21c or the negative electrode uncoated part 22c of multiple layers by one press. For example, when the cross-section changing portion 25 is formed in the wound electrode body 20, the cross-section changing portion is simultaneously with the time when the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c of the electrode body 20 are pressed at the position P. 25 may be formed. In this case, the jig that presses the positive electrode uncoated portion 21c or the negative electrode uncoated portion 22c at the two positions P covers and presses the curved positive electrode uncoated portion 21ce or the curved negative electrode uncoated portion 22ce. The protrusion which comprises and forms the cross-sectional change part 25 may be formed in the part of the jig | tool which is comprised and presses the curved negative electrode uncoated part 21ce or the curved negative electrode uncoated part 22ce.

また、変形例に係る蓄電素子におけるその他の構成は、実施の形態に係る蓄電素子100と同様であるため、その説明を省略する。さらに、変形例に係る蓄電素子によると、実施の形態に係る蓄電素子100と同様の効果が得られる。   Other configurations of the power storage element according to the modification are the same as those of the power storage element 100 according to the embodiment, and thus the description thereof is omitted. Furthermore, according to the power storage device according to the modification, the same effect as that of power storage device 100 according to the embodiment can be obtained.

また、変形例に係る蓄電素子を製造する場合、その製造方法は、正極板21及び負極板22を巻回して電極体20を作製する工程と、正極板21及び負極板22の巻回時又は巻回後に、正極板21及び負極板22に断面変化部25を形成する工程とを含む。上述の構成において、断面変化部25は、正極板21及び負極板22の巻回時に形成される場合、正極板21及び負極板22の任意の位置に効率的に形成されることができる。また、断面変化部25は、正極板21及び負極板22の巻回後に形成される場合、例えば、巻回後の電極体20の外面を押圧することによって形成され得る。よって、断面変化部25を簡易な手段で形成することができる。   Moreover, when manufacturing the electrical storage element which concerns on a modification, the manufacturing method is the process of winding the positive electrode plate 21 and the negative electrode plate 22, and producing the electrode body 20, the winding of the positive electrode plate 21 and the negative electrode plate 22, or Forming a cross-section changing portion 25 on the positive electrode plate 21 and the negative electrode plate 22 after winding. In the above-described configuration, the cross-section changing portion 25 can be efficiently formed at an arbitrary position of the positive electrode plate 21 and the negative electrode plate 22 when it is formed when the positive electrode plate 21 and the negative electrode plate 22 are wound. In addition, when the cross-section changing portion 25 is formed after the positive electrode plate 21 and the negative electrode plate 22 are wound, for example, the cross-section changing portion 25 can be formed by pressing the outer surface of the electrode body 20 after the winding. Therefore, the cross-section changing portion 25 can be formed by simple means.

[その他の変形例]
以上、本発明の実施の形態及び変形例に係る蓄電素子について説明したが、本発明は、実施の形態及び変形例に限定されるものではない。つまり、今回開示された実施の形態及び変形例は全ての点で例示であって制限的なものではないと考えられるべきである。本発明の範囲は上述した説明ではなくて特許請求の範囲によって示され、特許請求の範囲と均等の意味及び範囲内での全ての変更が含まれることが意図される。
[Other variations]
The power storage device according to the embodiment and the modification of the present invention has been described above, but the present invention is not limited to the embodiment and the modification. That is, it should be considered that the embodiment and the modification disclosed this time are examples in all respects and are not restrictive. The scope of the present invention is defined by the terms of the claims, rather than the description above, and is intended to include any modifications within the scope and meaning equivalent to the terms of the claims.

実施の形態及び変形例に係る蓄電素子の電極体20では、断面変化部24は、電極体20の内方から外方に向かって突出していたが、電極体20の外方から内方に向かって突出してもよい。また、断面変化部25は、電極体20の外方から内方に向かって窪んでいたが、電極体20の内方から外方に向かって窪んでいてもよい。   In the electrode body 20 of the energy storage device according to the embodiment and the modification, the cross-section changing portion 24 protrudes from the inside of the electrode body 20 to the outside, but from the outside of the electrode body 20 to the inside. May protrude. In addition, the cross-section changing portion 25 is recessed from the outside of the electrode body 20 toward the inside, but may be recessed from the inside of the electrode body 20 toward the outside.

実施の形態に係る蓄電素子100の電極体20では、断面変化部24は、正極基材21a及び負極基材22aの折り曲げによって形成されていたが、これに限定されるものでない。断面変化部24は、正極基材21a及び負極基材22aを湾曲して形成されてもよく、正極基材21a及び負極基材22aに一体成形された突起又は突出部分によって形成されてもよく、正極基材21a及び負極基材22aに貼り付けられた別部材によって形成されてもよい。   In the electrode body 20 of the energy storage device 100 according to the embodiment, the cross-section changing portion 24 is formed by bending the positive electrode base material 21a and the negative electrode base material 22a, but is not limited thereto. The cross-section changing portion 24 may be formed by bending the positive electrode base material 21a and the negative electrode base material 22a, or may be formed by a protrusion or a protruding portion integrally formed with the positive electrode base material 21a and the negative electrode base material 22a. You may form by the separate member affixed on the positive electrode base material 21a and the negative electrode base material 22a.

変形例に係る蓄電素子の電極体20では、断面変化部25は、正極基材21a及び負極基材22aの折り曲げによって形成されていたが、これに限定されるものでない。断面変化部25は、正極基材21a及び負極基材22aを湾曲して形成されてもよく、正極基材21a及び負極基材22aに、一体成形によりそれぞれの一部として形つくられてもよい。   In the electrode body 20 of the electricity storage device according to the modification, the cross-section changing portion 25 is formed by bending the positive electrode base material 21a and the negative electrode base material 22a, but is not limited thereto. The cross-section changing portion 25 may be formed by bending the positive electrode base material 21a and the negative electrode base material 22a, or may be formed as a part of each of the positive electrode base material 21a and the negative electrode base material 22a by integral molding. .

実施の形態及び変形例に係る蓄電素子の電極体20では、断面変化部24及び25は、正極集電体50の第二固定部50bの間及び負極集電体60の第二固定部60bの間に位置する電極体20の湾曲壁状部20eに形成されていたが、反対側の湾曲壁状部20fに形成されてもよい。   In the electrode body 20 of the energy storage device according to the embodiment and the modification, the cross-section changing portions 24 and 25 are provided between the second fixing portion 50b of the positive electrode current collector 50 and the second fixing portion 60b of the negative electrode current collector 60. Although it was formed in the curved wall-shaped part 20e of the electrode body 20 located in between, it may be formed in the curved wall-shaped part 20f on the opposite side.

実施の形態及び変形例に係る蓄電素子の電極体20では、断面変化部24及び25は、正極未塗工部21c及び負極未塗工部22cに形成されていたが、正極板21及び負極板22におけるその他の位置に形成されてもよい。   In the electrode body 20 of the electricity storage device according to the embodiment and the modification, the cross-section changing portions 24 and 25 are formed in the positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c. It may be formed at other positions in 22.

実施の形態及び変形例に係る蓄電素子は、1つの電極体20を備えていた。しかしながら、蓄電素子は、2つ以上の電極体を備えるものであってもよい。   The power storage element according to the embodiment and the modification includes one electrode body 20. However, the power storage element may include two or more electrode bodies.

実施の形態及び変形例に係る蓄電素子では、電極体20は、帯状の正極未塗工部21c及び負極未塗工部22cがそれぞれ正極集電体50及び負極集電体60に接続される構成であったが、これに限定されるものでない。電極体は、正極未塗工部及び負極未塗工部の位置に、正極基材及び負極基材から一体的に突出し且つ正極活物質層及び負極活物質層が形成されていないタブを有する構成であってもよい。そして、正極集電体50及び負極集電体60が、タブに接続されてよい。このとき、断面変化部24及び25は、タブに形成されてもよく、正極板及び負極板におけるタブ以外の場所に形成されてもよい。   In the energy storage device according to the embodiment and the modification, the electrode body 20 has a configuration in which the strip-shaped positive electrode uncoated portion 21c and the negative electrode uncoated portion 22c are connected to the positive electrode current collector 50 and the negative electrode current collector 60, respectively. However, it is not limited to this. The electrode body has a tab that protrudes integrally from the positive electrode base material and the negative electrode base material and is not formed with the positive electrode active material layer and the negative electrode active material layer at the positions of the positive electrode uncoated part and the negative electrode uncoated part. It may be. The positive electrode current collector 50 and the negative electrode current collector 60 may be connected to the tab. At this time, the cross-sectional change parts 24 and 25 may be formed in a tab, and may be formed in places other than the tab in a positive electrode plate and a negative electrode plate.

実施の形態及び変形例に係る蓄電素子は、縦巻き型の電極体20を備える蓄電素子であったが、電極体の巻回軸A方向の端部を容器10の蓋体12に対向させる向きで電極体が配置される横巻き型の電極体を備える蓄電素子であってもよい。   The power storage device according to the embodiment and the modification is a power storage device including the vertically wound electrode body 20, but the direction in which the end of the electrode body in the winding axis A direction is opposed to the lid body 12 of the container 10. It may be a power storage element including a horizontally wound electrode body on which the electrode body is disposed.

また、実施の形態及び変形例を任意に組み合わせて構築される形態も、本発明の範囲内に含まれる。例えば、1つの電極体に、断面変化部24及び25が混在して形成されてもよい。   In addition, embodiments constructed by arbitrarily combining the embodiment and the modified examples are also included in the scope of the present invention. For example, the cross-section changing parts 24 and 25 may be formed in one electrode body.

また、本発明は、上述のような蓄電素子として実現することができるだけでなく、1つ以上の蓄電素子を備える蓄電装置においても実現することができる。例えば、本発明は、複数の蓄電素子100を備える蓄電装置として実現することができる。蓄電装置は、並べて配置された複数の蓄電ユニットを備え、各蓄電ユニットは、例えば一列に並べられ且つ互いに電気的に接続された複数の蓄電素子100によって、構成される。上述の構成によって、複数の蓄電素子100が、1ユニットとして使用され、蓄電装置に必要な電気容量、蓄電装置の形状及び寸法等に対応して、蓄電ユニットの数量及び配列が選択され得る。複数の蓄電素子100を備え且つ高出力である蓄電装置は、電気自動車(EV)、ハイブリッド自動車(HEV)、プラグインハイブリッド自動車(PHEV)等の自動車用電源として搭載することもできる。   In addition, the present invention can be realized not only as a power storage element as described above but also in a power storage device including one or more power storage elements. For example, the present invention can be realized as a power storage device including a plurality of power storage elements 100. The power storage device includes a plurality of power storage units arranged side by side, and each power storage unit includes, for example, a plurality of power storage elements 100 arranged in a line and electrically connected to each other. With the above-described configuration, the plurality of power storage elements 100 are used as one unit, and the quantity and arrangement of the power storage units can be selected in accordance with the electric capacity required for the power storage device, the shape and dimensions of the power storage device, and the like. A power storage device that includes a plurality of power storage elements 100 and has a high output can be mounted as a power source for a vehicle such as an electric vehicle (EV), a hybrid vehicle (HEV), and a plug-in hybrid vehicle (PHEV).

本発明は、リチウムイオン二次電池などの蓄電素子、蓄電ユニット、蓄電装置等に適用できる。   The present invention can be applied to power storage elements such as lithium ion secondary batteries, power storage units, power storage devices, and the like.

20 電極体
21 正極板(極板)
21a 正極基材(極板の基材)
21b 正極活物質層(極板の活物質層)
21c 正極未塗工部(活物質層の非形成部)
21ca,22ca 縁(極板の縁)
21d,22d 端部(極板の端部)
22 負極板(極板)
22a 負極基材(極板の基材)
22b 負極活物質層(極板の活物質層)
22c 負極未塗工部(活物質層の非形成部)
23 セパレータ
23a,23b 縁(セパレータの縁)
24,25 断面変化部
50 正極集電体
50b,60b 第二固定部50b(接続部)
60 負極集電体
100 蓄電素子
A 巻回軸
B 巻回方向
G 間隙
20 Electrode body 21 Positive electrode plate (electrode plate)
21a Positive electrode substrate (electrode plate substrate)
21b Positive electrode active material layer (active material layer of electrode plate)
21c Positive electrode uncoated part (active material layer non-formation part)
21ca, 22ca edge (edge of electrode plate)
21d, 22d end (end of electrode plate)
22 Negative electrode (electrode plate)
22a Negative electrode substrate (electrode plate substrate)
22b Negative electrode active material layer (active material layer of electrode plate)
22c Negative electrode uncoated part (active material layer non-formed part)
23 Separator 23a, 23b Edge (Separator edge)
24, 25 Cross-section change part 50 Positive electrode current collector 50b, 60b Second fixing part 50b (connection part)
60 Negative electrode current collector 100 Storage element A Winding axis B Winding direction G Gap

Claims (8)

巻回された極板によって形成される電極体を備える蓄電素子であって、
前記極板は、前記極板の湾曲部分における前記極板の巻回軸方向の端部に、前記極板の巻回方向に沿って延在する凸部又は凹部によって形成される断面変化部を有する
蓄電素子。
A power storage device comprising an electrode body formed by a wound electrode plate,
The electrode plate has a cross-section changing portion formed by a convex portion or a concave portion extending along the winding direction of the electrode plate at an end portion in the winding axis direction of the electrode plate in a curved portion of the electrode plate. Power storage element.
前記断面変化部は、前記極板の帯状をした変形部分によって形成される
請求項1に記載の蓄電素子。
The electricity storage device according to claim 1, wherein the cross-section changing portion is formed by a belt-like deformed portion of the electrode plate.
前記変形部分は、前記極板の折り曲げ部分によって形成される
請求項2に記載の蓄電素子。
The electric storage element according to claim 2, wherein the deformed portion is formed by a bent portion of the electrode plate.
前記極板は、基材と、前記基材上に形成される活物質層とを有し、
前記断面変化部は、前記基材の前記巻回軸方向の端部における前記活物質層の非形成部に位置する
請求項1〜3のいずれか一項に記載の蓄電素子。
The electrode plate has a base material and an active material layer formed on the base material,
The electric storage element according to any one of claims 1 to 3, wherein the cross-section changing portion is located in a portion where the active material layer is not formed at an end portion of the base material in the winding axis direction.
前記断面変化部は、前記極板の前記端部のうちの巻回の最外周の前記極板の前記端部に少なくとも配置される
請求項1〜4のいずれか一項に記載の蓄電素子。
The electric storage element according to any one of claims 1 to 4, wherein the cross-section changing portion is disposed at least at the end portion of the electrode plate on the outermost periphery of the winding among the end portions of the electrode plate.
前記極板と共に巻回されており且つ巻回されて重なる前記極板の間に介在するセパレータをさらに備え、
前記断面変化部は、前記セパレータの前記巻回軸方向の縁と前記極板の前記巻回軸方向の縁との間に配置される
請求項1〜5のいずれか一項に記載の蓄電素子。
A separator interposed between the electrode plates that are wound and overlapped with the electrode plates;
The power storage device according to claim 1, wherein the cross-section changing portion is disposed between an edge in the winding axis direction of the separator and an edge in the winding axis direction of the electrode plate. .
間隙を形成し且つ前記間隙内で前記電極体を狭持して前記電極体と接続される接続部を有する集電体をさらに備え、
前記電極体は、前記巻回軸と交差する方向に幅狭になる変形を受けて前記間隙内に挿入されており、
前記断面変化部が位置する前記極板の前記端部が、前記間隙内に位置する
請求項1〜6のいずれか一項に記載の蓄電素子。
And further comprising a current collector having a connection portion that forms a gap and is connected to the electrode body by sandwiching the electrode body in the gap,
The electrode body is inserted into the gap after undergoing deformation that becomes narrow in the direction intersecting the winding axis,
The electric storage element according to any one of claims 1 to 6, wherein the end portion of the electrode plate in which the cross-sectional change portion is located is located in the gap.
請求項1〜7のいずれか一項に記載の蓄電素子の製造方法であって、
前記極板を巻回して前記電極体を作製する工程と、
前記極板の巻回時又は前記極板の巻回後に、前記極板に前記断面変化部を形成する工程とを含む製造方法。
It is a manufacturing method of the electrical storage element according to any one of claims 1 to 7,
Winding the electrode plate to produce the electrode body;
Forming the cross-section changing portion on the electrode plate when the electrode plate is wound or after the electrode plate is wound.
JP2016024177A 2016-02-10 2016-02-10 Power storage element and manufacturing method therefor Pending JP2017143005A (en)

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Publication number Priority date Publication date Assignee Title
WO2019090476A1 (en) * 2017-11-07 2019-05-16 宁德新能源科技有限公司 Winding battery

Citations (1)

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Publication number Priority date Publication date Assignee Title
JP2013037816A (en) * 2011-08-04 2013-02-21 Toyota Motor Corp Battery and manufacturing method therefor

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013037816A (en) * 2011-08-04 2013-02-21 Toyota Motor Corp Battery and manufacturing method therefor

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019090476A1 (en) * 2017-11-07 2019-05-16 宁德新能源科技有限公司 Winding battery
US11329309B2 (en) 2017-11-07 2022-05-10 Ningde Amperex Technology Limited Wound electrode assembly with empty foil segment

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