JP2017118851A - Oil and fat composition for kneading confectionery production and breadmaking and method for producing burned product using the same - Google Patents

Oil and fat composition for kneading confectionery production and breadmaking and method for producing burned product using the same Download PDF

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JP2017118851A
JP2017118851A JP2015257421A JP2015257421A JP2017118851A JP 2017118851 A JP2017118851 A JP 2017118851A JP 2015257421 A JP2015257421 A JP 2015257421A JP 2015257421 A JP2015257421 A JP 2015257421A JP 2017118851 A JP2017118851 A JP 2017118851A
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JP6787666B2 (en
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晶 太田
Akira Ota
晶 太田
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Miyoshi Yushi KK
Miyoshi Oil and Fat Co Ltd
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Miyoshi Oil and Fat Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide an oil and fat composition for kneading confectionery production and breadmaking capable of obtaining confectionery and bread excellent in softness, melt in mouth, and texture with no contraction by kneaded in a dough as a plastic oil and fat, and to provide a method for producing a burned product using the same.SOLUTION: An oil and fat composition for kneading confectionery production and breadmaking contains only oil and fat having a content of tri-saturated triglyceride of which all of constituent fatty acids have 16 or more carbon atoms of 15 mass% or less, and satisfies the following (a) to (d) conditions: (a) a mass ratio (PPO/POP) of PPO and POP of the triglyceride is more than 1.0 and 2.2 or less (P represents palmitic acid, and O represents oleic acid); (b) a content of P2O (PPO and POP) is 6.5-15.5 mass% with respect to the total amount of the oil and fat; (c) a content of the tri-saturated triglyceride of which all of the constituent fatty acids have 16 or more carbon atoms is 0.1-7.5 mass% with respect to the total oil and fat; and (d) the amount of a lauric acid bonded at a 2-position of the triglyceride is 2.0-25 mass% with respect to the whole amount of the oil and fat.SELECTED DRAWING: None

Description

本発明は、焼成品の生地への練り込みに使用される製菓製パン練り込み用油脂組成物とそれを用いた焼成品の製造方法に関する。   The present invention relates to a confectionery bread kneading oil and fat composition used for kneading a baked product into a dough and a method for producing a baked product using the same.

従来、製パンにおけるソフトさ、口溶け、ヒキのない食感については長く検討されてきた。ソフトさを得るための技術としては、酵素、乳化剤、または食品素材を使用すること、あるいは油脂組成物の配合を調整することなどが行われている(特許文献1〜5)。   Conventionally, the softness, melting in the mouth, and the texture without cracks have been studied for a long time. As a technique for obtaining softness, use of an enzyme, an emulsifier, or a food material, or adjustment of the composition of an oil or fat composition is performed (Patent Documents 1 to 5).

特許文献1には、ソフトで団子にならず、喉ごしの良いパン等を得ることを目的として、油中水型乳化物の水相中にトレハロースを配合することが提案されている。しかし、トレハロースはイーストに分解されないため、特有の甘みがパン等に付加され、特に食パンに使用した場合には風味を損なうおそれがある。   Patent Document 1 proposes that trehalose is blended in the aqueous phase of a water-in-oil emulsion for the purpose of obtaining bread that is soft and does not become dumpling and has a good throat. However, since trehalose is not decomposed into yeast, a special sweetness is added to bread and the like, and when used in bread, the flavor may be impaired.

特許文献2には、製品のソフト化、老化防止に加えて食感面でのくちゃつきを改善することを目的として、グルコースオキシダーゼとαアミラーゼを含有する製パン改良剤が提案されている。しかし、くちゃつきは軽減できるが、ヒキのない食感については十分な改善効果がみられていない。   Patent Document 2 proposes a bread-improving agent containing glucose oxidase and α-amylase for the purpose of improving product fluffing in addition to softening and preventing aging. However, although it can reduce fluttering, it does not have a sufficient improvement effect on the texture without cracks.

特許文献1、2などに提案されている、酵素、乳化剤、または食品素材を使用した改良剤は、製品表示上の制約や、最終製品の味に影響を与える等の問題があった。   The improving agents using enzymes, emulsifiers, or food materials proposed in Patent Documents 1 and 2 have problems such as restrictions on product labeling and the taste of the final product.

特許文献3には、製パンの作業性、ソフトさ、歯切れを改善することを目的として、酵素、乳化剤、食品素材を使用せず、油脂配合のみの観点から、油脂の結晶を調整した油脂組成物が提案されている。しかし、構成脂肪酸の全てが炭素数16以上で構成される3飽和トリグリセリドの含有量については言及されておらず、ソフトさやヒキのない食感を得る技術には更なる改善の余地があった。   Patent Document 3 discloses a fat composition in which crystals of fats and oils are adjusted from the standpoint of blending fats and oils without using enzymes, emulsifiers, and food materials for the purpose of improving workability, softness, and crispness in breadmaking. Things have been proposed. However, there is no mention of the content of trisaturated triglycerides in which all of the constituent fatty acids are composed of 16 or more carbon atoms, and there is room for further improvement in the technology for obtaining a soft and free texture.

特許文献4には、生地に練り込む際の作業性、泡立ち、低温領域での可塑性などの改善を図ることを目的として、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドPPOと、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドPOPとの質量比(PPO/POP)、PPOおよびPOPの合計量であるP2Oの含有量などの油脂組成を特定範囲とすることが提案されている。しかし、PPO/POPの数値が低く、またはP2Oの量が少ないため、油脂組成全体を考慮すると結晶量が少ない配合となっている。そのため、パンが口中で団子になりやすく、くちゃつきのある食感となりやすい。   In Patent Document 4, for the purpose of improving workability when kneaded into a dough, foaming, plasticity in a low temperature region, etc., palmitic acid, 3rd position or 2nd position or 2nd position or 3rd position Mass ratio (PPO / POP) of triglyceride PPO with oleic acid bonded at position 1 to palmitic acid at positions 1 and 3 and triglyceride POP bonded with oleic acid at position 2, the total amount of PPO and POP It has been proposed that the oil and fat composition such as the content of a certain P2O be in a specific range. However, since the numerical value of PPO / POP is low or the amount of P2O is small, the amount of crystals is small when considering the entire oil and fat composition. For this reason, bread tends to be dumpling in the mouth, and it tends to have a texture with a flicker.

特許文献5には、クロワッサン、パイ、デニッシュなどのペストリー食品の製造に使用するのに適した広い温度域における可塑性、伸展性を有し、かつ、得られるペストリー食品の浮きが良好で、かつ口溶けなどの食感も良好な実質的にトランス酸を含有しないロールイン用可塑性油中水型乳化物を目的として、可塑性油中水型乳化物中、ラウリン系ハードバターを5〜50質量%、パーム油起源の非選択的エステル交換油脂3質量%以上、乳脂肪を1質量%以上含有し、油相のSFCが10℃で40%以上、35℃で10%以下であり実質的にトランス酸を含まないロールイン用可塑性油中水型乳化物が提案されている。しかし、PPO/POPの数値が高いため、他の油脂組成も併せて考慮すると、焼成品のソフトさに影響し、口溶け、すなわち口中でのダマになりやすさに問題がある。あるいは、実施例によってはP2Oの量が少ないため結晶量が少なく、パンがくちゃつきのある食感となりやすい。また、用途についても生地と重ねて層状に折り込むロールイン用で、生地中に練り込んで分散させる練り込み用途については記載されていない。   Patent Document 5 discloses that plasticity and extensibility in a wide temperature range suitable for use in the manufacture of pastry foods such as croissants, pies, and Danishes, and that the resulting pastry foods have good float and melt in the mouth. For the purpose of a water-in-plastic plastic oil-in-water emulsion for roll-in that does not substantially contain a trans acid having a good texture, such as 5 to 50% by weight of lauric hard butter in a plastic water-in-oil emulsion. Oil-derived non-selective transesterified fat 3% or more, milk fat 1% or more, SFC of the oil phase is 40% or more at 10 ° C, 10% or less at 35 ° C, substantially trans acid There has been proposed a water-in-plastic plastic emulsion for roll-in that does not contain. However, since the value of PPO / POP is high, when other oil composition is also taken into consideration, it affects the softness of the baked product, and there is a problem that it is likely to melt in the mouth, that is, to become lumps in the mouth. Alternatively, depending on the embodiment, since the amount of P2O is small, the amount of crystals is small, and the bread tends to have a texture with flickering. Further, the use is not described for the kneading use for kneading and dispersing in the dough for roll-in which is overlapped with the dough and folded into a layer.

特開2002−153208号公報JP 2002-153208 A 特開平9−135656号公報JP-A-9-135656 特開2003−210107公報JP 2003-210107 A 国際公開第2010/26928号International Publication No. 2010/26928 特開2008−193974号公報JP 2008-193974 A

特許文献3〜5に記載の技術は、油脂配合の観点からパンのソフトさなどの特性の改良を図るものであるが、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量などについては触れられておらず、またPPO/POPやP2Oなどの数値および油脂組成全体を併せて考慮すると、ソフトさ、口溶け、ヒキのない食感がいずれも良好な製菓製パンを得るには更なる改善の余地があった。   The techniques described in Patent Documents 3 to 5 are intended to improve characteristics such as softness of bread from the viewpoint of blending fats and oils, but the content of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms, etc. Is not mentioned, and considering the numerical values of PPO / POP, P2O, etc. and the entire fat and oil composition, it is necessary to obtain a confectionery bakery that is soft, melted, and has a good texture without cracks. There was room for improvement.

本発明は、以上の通りの事情に鑑みてなされたものであり、可塑性油脂として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる、製菓製パン練り込み用油脂組成物とそれを用いた焼成品の製造方法を提供することを課題としている。   The present invention was made in view of the circumstances as described above, and by kneading into a dough as a plastic fat, it is possible to obtain a confectionery bread excellent in softness, melting in the mouth, and texture without cracks, It is an object of the present invention to provide an oil and fat composition for confectionery bread kneading and a method for producing a baked product using the same.

上記の課題を解決するために、本発明の製菓製パン練り込み用油脂組成物は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有し、以下の(a)〜(d)の条件を満たすことを特徴としている:
(a)PPOとPOPとの質量比(PPO/POP)が1.0超2.2以下(PPOは、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドであり、POPは、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドであり、Pはパルミチン酸、Oはオレイン酸を示す。);
(b)P2Oの含有量が油脂全量に対して6.5〜15.5質量%(P2Oの含有量は、PPOおよびPOPの合計量である。);
(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が油脂全量に対して0.1〜7.5質量%;および、
(d)トリグリセリドの2位に結合されたラウリン酸量が油脂全量に対して2.0〜25質量%。
In order to solve the above-described problems, the confectionery bread kneading fat and oil composition of the present invention includes only fats and oils in which the content of trisaturated triglycerides having 16 or more carbon atoms is 15% by mass or less. And is characterized by satisfying the following conditions (a) to (d):
(A) The mass ratio of PPO to POP (PPO / POP) is more than 1.0 and 2.2 or less (PPO is palmitic acid at 1st and 2nd position or 2nd and 3rd position, and olein at 3rd or 1st position) An acid-bound triglyceride, POP is palmitic acid at positions 1 and 3 and oleic acid is bound at position 2, P is palmitic acid, and O is oleic acid);
(B) The content of P2O is 6.5 to 15.5% by mass with respect to the total amount of fats and oils (the content of P2O is the total amount of PPO and POP);
(C) the content of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms is 0.1 to 7.5% by mass with respect to the total amount of fats and oils; and
(D) The amount of lauric acid bonded to the 2-position of triglyceride is 2.0 to 25% by mass with respect to the total amount of fats and oils.

本発明の焼成品の製造方法は、前記製菓製パン練り込み用油脂組成物を含有する可塑性油脂を生地に練り込み、この生地を焼成することを特徴としている。   The method for producing a baked product according to the present invention is characterized in that a plastic fat containing the above-mentioned confectionery bread kneading fat composition is kneaded into a dough and the dough is baked.

本発明によれば、可塑性油脂として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。   ADVANTAGE OF THE INVENTION According to this invention, the confectionery bread | bread excellent in softness, the melt | dissolution in the mouth, and the food texture without a crack can be obtained by knead | mixing into dough as a plastic fat.

以下の記述において、P2Oは、PPOおよびPOPを示す。PPOは、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドを示し、POPは、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドを示し、Pはパルミチン酸、Oはオレイン酸を示す。LLLは、1位と2位と3位にラウリン酸が結合されたトリグリセリドを示し、MLLは、1位または3位にミリスチン酸、2位と3位または1位と2位にラウリン酸が結合されたトリグリセリドを示し、LMLは、1位と3位にラウリン酸、2位にミリスチン酸が結合されたトリグリセリドを示し、Lはラウリン酸、Mはミリスチン酸を示す。   In the following description, P2O indicates PPO and POP. PPO is a triglyceride with palmitic acid at the 1st and 2nd positions or 2nd and 3rd positions, and oleic acid at the 3rd or 1st position. POP is palmitic acid at the 1st and 3rd positions, and olein at the 2nd position. An acid-bound triglyceride is shown, P is palmitic acid, and O is oleic acid. LLL is a triglyceride with lauric acid bonded at the 1st, 2nd and 3rd positions, and MLL has myristic acid at the 1st or 3rd position, and lauric acid at the 2nd and 3rd positions or the 1st and 2nd positions. LML represents triglyceride in which lauric acid is bonded to the 1st and 3rd positions and myristic acid is bonded to the 2nd position, L represents lauric acid, and M represents myristic acid.

本明細書において「口溶け」とは、口中でのダマになりにくさを言う。「ヒキ」とは、焼成品を口中に含んだ際に、パン様の繋がりが残存する食感を言う。「パサつき」とは、パンを食べる際に、生地が乾燥してボソボソとしているように感じられ、咀嚼時に、飲み込みにくくなることを指す。   In the present specification, “melting in the mouth” refers to the difficulty of becoming lumps in the mouth. “Hiki” refers to a texture in which a bread-like connection remains when a baked product is included in the mouth. “Pasari” means that when bread is eaten, the dough feels dry and rough, making it difficult to swallow when chewing.

以下に、本発明を詳細に説明する。   The present invention is described in detail below.

本発明の製菓製パン練り込み用油脂組成物(A)は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有し、(a)PPO/POP、(b)P2Oの含有量、(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、(d)トリグリセリドの2位に結合されたラウリン酸量を特定範囲としたことを特徴としている。このような油脂組成としたことにより、低融点であり、口に入れると油脂が素早く溶解する特性を持ち、かつ結晶量が適度にあることから、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。   The confectionery bread kneading fat and oil composition (A) according to the present invention contains only fats and oils in which the content of trisaturated triglycerides having 16 or more carbon atoms is 15% by mass or less. PPO / POP, (b) P2O content, (c) Trisaturated triglyceride content in which all of the constituent fatty acids are 16 or more carbon atoms, (d) Amount of lauric acid bound to position 2 of triglyceride It is characterized by that. By having such an oil and fat composition, it has a low melting point, has characteristics that fats and oils dissolve quickly when put in the mouth, and has an appropriate amount of crystals, so it is kneaded into the dough as a plastic oil and fat (B). A confectionery bakery excellent in softness, melting in the mouth, and free of crinkles can be obtained.

また、このような特性を持つことから、本発明の製菓製パン練り込み用油脂組成物(A)を可塑性油脂(B)として生地に練り込んだ焼成品は、パサつき感がなく、トップのフレーバーリリースに優れている。また、本発明の製菓製パン練り込み用油脂組成物(A)を用いた可塑性油脂(B)は、10℃程度、例えば5〜10℃の低温における生地への分散性に優れている。   Moreover, since it has such characteristics, the fired product obtained by kneading the confectionery bread kneading fat and oil composition (A) of the present invention into a dough as a plastic fat and oil (B) does not have a feeling of dryness, and has the top Excellent flavor release. Moreover, the plastic fat (B) using the confectionery bread kneading fat and oil composition (A) of the present invention is excellent in dispersibility to the dough at a low temperature of about 10 ° C, for example, 5 to 10 ° C.

1.油脂
本発明において、油脂中のトリグリセリドとは、1分子のグリセロールに3分子の脂肪酸がエステル結合した構造を有するものである。トリグリセリドの1位、2位、3位とは、脂肪酸が結合した位置を表す。なお、トリグリセリドの構成脂肪酸の略称として、S:飽和脂肪酸、U:不飽和脂肪酸、を用いる。
1. Fat and oil In the present invention, triglyceride in fat and oil has a structure in which three molecules of fatty acid are ester-bonded to one molecule of glycerol. The 1st, 2nd and 3rd positions of triglyceride represent the positions where fatty acids are bonded. In addition, S: saturated fatty acid and U: unsaturated fatty acid are used as abbreviations of constituent fatty acids of triglyceride.

飽和脂肪酸Sは、油脂中に含まれるすべての飽和脂肪酸である。また、各トリグリセリド分子に結合している2つまたは3つの飽和脂肪酸Sは、同一の飽和脂肪酸であってもよいし、異なる飽和脂肪酸であってもよい。   Saturated fatty acid S is all saturated fatty acids contained in fats and oils. The two or three saturated fatty acids S bonded to each triglyceride molecule may be the same saturated fatty acid or different saturated fatty acids.

飽和脂肪酸Sとしては、特に限定されないが、例えば、酪酸(4)、カプロン酸(6)、カプリル酸(8)、カプリン酸(10)、ラウリン酸(12)、ミリスチン酸(14)、パルミチン酸(16)、ステアリン酸(18)、アラキジン酸(20)、ベヘン酸(22)、リグノセリン酸(24)などが挙げられる。なお、上記の数値表記は、脂肪酸の炭素数である。   Although it does not specifically limit as saturated fatty acid S, For example, butyric acid (4), caproic acid (6), caprylic acid (8), capric acid (10), lauric acid (12), myristic acid (14), palmitic acid (16), stearic acid (18), arachidic acid (20), behenic acid (22), lignoceric acid (24) and the like. In addition, said numerical description is carbon number of a fatty acid.

不飽和脂肪酸Uは、油脂中に含まれるすべての不飽和脂肪酸である。また、各トリグリセリド分子に結合している2つまたは3つの不飽和脂肪酸Uは、同一の不飽和脂肪酸であってもよいし、異なる不飽和脂肪酸であってもよい。   Unsaturated fatty acid U is all unsaturated fatty acids contained in fats and oils. Also, the two or three unsaturated fatty acids U bound to each triglyceride molecule may be the same unsaturated fatty acid or different unsaturated fatty acids.

不飽和脂肪酸Uとしては、特に限定されないが、例えば、ミリストレイン酸(14:1)、パルミトレイン酸(16:1)、ヒラゴン酸(16:3)、オレイン酸(18:1)、リノール酸(18:2)、リノレン酸(18:3)、エイコセン酸(20:1)、エルカ酸(22:1)、セラコレイン酸(24:1)などが挙げられる。なお、上記不飽和脂肪酸についての括弧内の数値表記は、左側が脂肪酸の炭素数であり、右側が二重結合数を意味する。   Although it does not specifically limit as unsaturated fatty acid U, For example, myristoleic acid (14: 1), palmitoleic acid (16: 1), hiragonic acid (16: 3), oleic acid (18: 1), linoleic acid ( 18: 2), linolenic acid (18: 3), eicosenoic acid (20: 1), erucic acid (22: 1), ceracoleic acid (24: 1) and the like. In the numerical notation in the parentheses for the unsaturated fatty acid, the left side is the number of carbon atoms of the fatty acid, and the right side is the number of double bonds.

本発明の製菓製パン練り込み用油脂組成物(A)に使用される油脂は、1位、2位、3位のすべてに飽和脂肪酸Sが結合した3飽和トリグリセリド(SSS)を含み、1分子のグリセロールに2分子の飽和脂肪酸Sと1分子の不飽和脂肪酸Uが結合した2飽和トリグリセリドとして、1位および3位に飽和脂肪酸Sが結合し、かつ2位に不飽和脂肪酸Uが結合した対称型トリグリセリド(SUS)と、1位と2位、または2位と3位に飽和脂肪酸Sが結合し、かつ3位または1位に不飽和脂肪酸Uが結合した非対称型トリグリセリド(SSU)とを含む。また、1分子のグリセロールに2分子の不飽和脂肪酸Uと1分子の飽和脂肪酸Sが結合した2不飽和トリグリセリド(UUS、USU)を含んでよく、1位、2位、3位のすべてに不飽和脂肪酸Uが結合した3不飽和トリグリセリド(UUU)を含んでよい。   The fats and oils used in the confectionery bread kneading fat and oil composition (A) of the present invention contains trisaturated triglycerides (SSS) in which saturated fatty acids S are bonded to all of the first, second, and third positions. As a disaturated triglyceride in which two molecules of saturated fatty acid S and one molecule of unsaturated fatty acid U are bound to glycerol, saturated fatty acid S is bound to the 1st and 3rd positions, and unsaturated fatty acid U is bound to the 2nd position. Type triglycerides (SUS) and asymmetric triglycerides (SSU) in which a saturated fatty acid S is bonded to positions 1 and 2 or 2 and 3 and an unsaturated fatty acid U is bonded to positions 3 and 1 . It may also contain diunsaturated triglycerides (UUS, USU) in which two molecules of unsaturated fatty acid U and one molecule of saturated fatty acid S are bound to one molecule of glycerol. Trisaturated triglycerides (UUU) to which saturated fatty acids U are bound may be included.

本発明の製菓製パン練り込み用油脂組成物(A)に使用される油脂としては、特に限定されないが、例えば、パーム油、パーム核油、ヤシ油、菜種油、大豆油、綿実油、ヒマワリ油、米油、サフラワー油、オリーブ油、ゴマ油、魚油、シア脂、サル脂、イリッペ脂、カカオ脂、豚脂(ラード)、牛脂、乳脂、それらの分別油またはそれらの加工油(硬化およびエステル交換反応のうち1つ以上の処理がなされたもの)などが挙げられる。本発明の製菓製パン練り込み用油脂組成物(A)における、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有すること、および(a)PPO/POP、(b)P2Oの含有量、(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、(d)トリグリセリドの2位に結合されたラウリン酸量を満たすために、これらの油脂は、2種以上を併用することが好ましい。   Fats and oils used in the confectionery bread kneading fat and oil composition (A) of the present invention are not particularly limited, but examples thereof include palm oil, palm kernel oil, coconut oil, rapeseed oil, soybean oil, cottonseed oil, sunflower oil, Rice oil, safflower oil, olive oil, sesame oil, fish oil, shea fat, monkey fat, iripe fat, cacao butter, lard, beef tallow, milk fat, fractionated oil or processed oil thereof (cured and transesterified) Of which one or more processing is performed). In the fat composition (A) for confectionery bread kneading of the present invention, all the constituent fatty acids contain only fats and oils whose content of 3 saturated triglycerides having 16 or more carbon atoms is 15% by mass or less, and ( a) the content of PPO / POP, (b) P2O, (c) the content of trisaturated triglycerides in which all of the constituent fatty acids are 16 or more carbon atoms, and (d) the amount of lauric acid bonded to the 2-position of the triglycerides. In order to satisfy, it is preferable to use two or more of these oils and fats in combination.

2.製菓製パン練り込み用油脂組成物(A)
本発明の製菓製パン練り込み用油脂組成物(A)は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有する。このような油脂のみを含有することで、低融点であり、口に入れると油脂が素早く溶解する特性を持ち、かつ結晶量が適度にあることから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂組成の条件(a)〜(d)と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。このような点を考慮すると、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が12質量%以下である油脂のみを含有することが好ましい。
2. Oil composition for kneading confectionery bread (A)
The confectionery bread kneading fat and oil composition (A) of the present invention contains only fats and oils in which the content of trisaturated triglycerides having 16 or more carbon atoms is 15% by mass or less. By containing only such fats and oils, it has a low melting point, has characteristics that fats and fats dissolve quickly when put in the mouth, and has an appropriate amount of crystals, the fat composition for kneading bread for confectionery of the present invention Combined with the conditions (a) to (d) of the oil and fat composition in the product (A), kneaded into the dough as a plastic fat and oil (B), making the confectionery excellent in softness, melting in the mouth and texture without cracks You can get bread. Considering such points, it is preferable to contain only fats and oils in which the content of trisaturated triglycerides having 16 or more carbon atoms is 12% by mass or less.

(a)本発明の製菓製パン練り込み用油脂組成物(A)は、PPOとPOPとの質量比(PPO/POP)が1.0超2.2以下である。この範囲内であると、トリグリセリドの対称性が良く、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができ、特に焼成品のソフトさが良好で、口溶けも良好である。   (A) The confectionery bread kneading fat and oil composition (A) of the present invention has a mass ratio of PPO to POP (PPO / POP) of more than 1.0 and 2.2 or less. Within this range, the triglyceride has good symmetry, and in combination with the oil and fat composition and oil and fat composition conditions in the confectionery bread kneading oil and fat composition (A) of the present invention, the dough can be used as a plastic oil and fat (B). By kneading into confectionery, a confectionery bakery excellent in softness, melting in the mouth, and free of texture can be obtained. Especially, the softness of the baked product is good and the melting in the mouth is also good.

(b)本発明の製菓製パン練り込み用油脂組成物(A)は、P2Oの含有量が油脂全量に対して6.5〜15.5質量%である。P2Oの含有量をこの範囲内とすることで、結晶量が適度なものとなり、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができ、特にヒキのない食感が良好である。   (B) The confectionery bread kneading fat and oil composition (A) of the present invention has a P2O content of 6.5 to 15.5% by mass based on the total fat and oil content. By making the content of P2O within this range, the amount of crystals becomes moderate, and in combination with the oil and fat composition and fat and oil composition conditions in the confectionery bread kneading fat and oil composition (A) of the present invention, By kneading into the dough as the plastic fat (B), a confectionery bakery excellent in softness, melting in the mouth, and a texture without cracks can be obtained, and the texture without cracks is particularly good.

(c)本発明の製菓製パン練り込み用油脂組成物(A)は、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が油脂全量に対して0.1〜7.5質量%である。この範囲内とすることで、低融点であり、口に入れると油脂が素早く溶解する特性を持ち、かつ結晶量が適度にあることから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。また、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量は、生地への分散性が向上する点から、油脂全量に対して1.0〜6.0質量%が好ましい。   (C) The fat and oil composition (A) for confectionery bread kneading of the present invention has a content of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms in a range of 0.1 to 7.5 with respect to the total amount of fat and oil. % By mass. By making it within this range, it has a low melting point, has characteristics that fats and oils dissolve quickly when put in the mouth, and has an appropriate amount of crystals. Therefore, the confectionery bread kneading fats and oils composition (A In combination with the fat and oil composition and the fat and oil composition conditions in (1), the confectionery bread having excellent softness, melting in the mouth and no texture can be obtained by kneading into the dough as the plastic fat (B). In addition, the content of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms is preferably 1.0 to 6.0% by mass with respect to the total amount of fats and oils from the viewpoint of improving dispersibility in the dough.

(d)本発明の製菓製パン練り込み用油脂組成物(A)は、トリグリセリドの2位に結合されたラウリン酸量が油脂全量に対して2.0〜25質量%である。2位にラウリン酸が結合されたトリグリセリドは、ラウリン酸の分子量が小さいことに起因し、分子運動がおこりやすい。そのため固化後に油脂中で、分子同士が離れやすい状態となり、その結果として、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、口溶け、ソフトさが良好となる。また、低温下での良好な物性を得ることができ、10℃程度の低温における生地への分散性に優れている。   (D) In the confectionery bread kneading oil and fat composition (A) of the present invention, the amount of lauric acid bonded to the 2-position of the triglyceride is 2.0 to 25% by mass with respect to the total amount of oil and fat. Triglycerides having lauric acid bonded to the 2-position are likely to undergo molecular motion due to the low molecular weight of lauric acid. Therefore, in the fats and oils after solidification, the molecules are easily separated from each other. As a result, in combination with the fat and oil composition and fat and oil composition conditions in the confectionery bread kneading fat and oil composition (A) of the present invention, By kneading into the dough as (B), the mouth melts and the softness becomes good. In addition, good physical properties at low temperatures can be obtained, and the dispersibility to the fabric at a low temperature of about 10 ° C. is excellent.

2位にラウリン酸が結合されたトリグリセリドの1、3位の構成脂肪酸は、飽和脂肪酸または不飽和脂肪酸のいずれであってもよい。2位がラウリン酸であるトリグリセリドとしては、例えば、SLS型トリグリセリド、SLU型トリグリセリド(位置異性体も含む)、ULU型トリグリセリドなどが挙げられるが、特に限定されない。なお、「L」とは、トリグリセリドの構成脂肪酸であるラウリン酸を意味する。本発明の効果を得る点から、2位にラウリン酸が結合されたトリグリセリドの1位または3位の構成脂肪酸が飽和脂肪酸である場合、炭素数4〜20の飽和脂肪酸であることが好ましい。2位にラウリン酸が結合されたトリグリセリドの1位または3位の構成脂肪酸が不飽和脂肪酸である場合、炭素数16〜18の不飽和脂肪酸(パルミトレイン酸、オレイン酸、リノール酸、リノレン酸など)であることが好ましい。2位にラウリン酸が結合されたトリグリセリドの1位または3位の構成脂肪酸が飽和脂肪酸と不飽和脂肪酸である場合、上述の飽和脂肪酸(炭素数4〜20の飽和脂肪酸)と不飽和脂肪酸(炭素数16〜18の不飽和脂肪酸)であることが好ましい。   The constituent fatty acids at the 1st and 3rd positions of the triglyceride having lauric acid bonded at the 2nd position may be either saturated fatty acids or unsaturated fatty acids. Examples of the triglyceride in which the 2-position is lauric acid include, but are not particularly limited to, SLS type triglyceride, SLU type triglyceride (including positional isomers), ULU type triglyceride and the like. “L” means lauric acid which is a constituent fatty acid of triglyceride. From the point of obtaining the effects of the present invention, when the constituent fatty acid at the 1st or 3rd position of the triglyceride having lauric acid bonded at the 2nd position is a saturated fatty acid, it is preferably a saturated fatty acid having 4 to 20 carbon atoms. When the constituent fatty acid at the 1st or 3rd position of the triglyceride having lauric acid bonded at the 2nd position is an unsaturated fatty acid, the unsaturated fatty acid having 16 to 18 carbon atoms (palmitoleic acid, oleic acid, linoleic acid, linolenic acid, etc.) It is preferable that When the constituent fatty acid at the 1st or 3rd position of the triglyceride having lauric acid bonded at the 2nd position is a saturated fatty acid and an unsaturated fatty acid, the saturated fatty acid (saturated fatty acid having 4 to 20 carbon atoms) and the unsaturated fatty acid (carbon) It is preferable that it is a unsaturated fatty acid of several 16-18.

本発明の製菓製パン練り込み用油脂組成物(A)は、LLL、MLL、およびLMLの合計量が油脂全量に対して1.5〜7質量%であることが好ましい。LLL、MLL、およびLMLの合計量をこの範囲内とすることで、口溶けとソフトさのバランスが良好となり、口溶けが良くかつソフトさが良好となる。すなわち、飽和脂肪酸の中でもLLLやMLL、LMLといったトリグリセリドを含有することで、口溶けとソフトさのバランスが取れ、従ってフレーバーリリースが良好な製菓製パンを得ることができる。   In the confectionery bread kneading fat and oil composition (A) of the present invention, the total amount of LLL, MLL and LML is preferably 1.5 to 7% by mass relative to the total amount of fat and oil. By making the total amount of LLL, MLL, and LML within this range, the balance between the melting of the mouth and the softness becomes good, the melting of the mouth becomes good and the softness becomes good. That is, by containing triglycerides such as LLL, MLL, and LML among saturated fatty acids, it is possible to obtain a confectionery bread having a good balance between melting and softness and thus good flavor release.

本発明の製菓製パン練り込み用油脂組成物(A)は、35℃における固体脂含量が8質量%以下の油脂のみを含有することが好ましい。このような油脂のみを含有することで、低融点であり、口に入れると油脂が素早く溶解する特性を持つことから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。特にヒキのない食感が良好となる。また、作業性の面では、10℃程度の低温における生地への分散性が良好となる。   The confectionery bread kneading fat and oil composition (A) of the present invention preferably contains only fats and oils having a solid fat content at 35 ° C. of 8% by mass or less. By containing only such fats and oils, it has a low melting point and has the property that fats and oils dissolve quickly when put in the mouth. Therefore, the fats and oils blended in the confectionery bread kneading fats and oils composition (A) of the present invention and Combined with the conditions of the oil / fat composition, kneading into the dough as a plastic oil / fat (B) makes it possible to obtain a confectionery bread excellent in softness, melting in the mouth, and having no texture. In particular, the texture without cracks is improved. Further, in terms of workability, the dispersibility to the fabric at a low temperature of about 10 ° C. is good.

本発明の製菓製パン練り込み用油脂組成物は、ヨウ素価が50〜60のエステル交換油脂を含有することが好ましい。このようなエステル交換油脂を含有することで、低融点であり、口に入れると油脂が素早く溶解する特性を持つことから、本発明の製菓製パン練り込み用油脂組成物(A)における油脂配合および油脂組成の条件と相俟って、後述の可塑性油脂(B)として生地に練り込むことで、ソフトさ、口溶け、ヒキのない食感に優れた製菓製パンを得ることができる。特にヒキのない食感が良好となる。   The confectionery bread kneading fat and oil composition of the present invention preferably contains a transesterified fat and oil having an iodine value of 50 to 60. By containing such a transesterified fat and oil, it has a low melting point and has a property that fat and oil dissolves quickly when put in the mouth. Therefore, the fat and oil blending in the confectionery bread kneading fat and oil composition (A) of the present invention Combined with the conditions of the oil and fat composition, kneading into the dough as the later-described plastic fat (B) can provide a confectionery bakery excellent in softness, melting in the mouth, and no texture. In particular, the texture without cracks is improved.

ヨウ素価が50〜60のエステル交換油脂としては、パーム系油脂を原料に含むエステル交換油脂が好ましい。パーム系油脂としては、例えば、パーム油、パーム分別油、これらの硬化油などが挙げられ、これらはエステル交換油脂の原料として1種単独で使用してもよく2種以上を併用してもよい。パーム分別油としては、硬質部、軟質部、中融点部などを用いることができる。   As the transesterified fat and oil having an iodine value of 50 to 60, a transesterified fat and oil containing palm-based fat and oil as a raw material is preferable. Examples of palm oils and fats include palm oil, palm fractionated oil, and hardened oils thereof. These may be used alone or in combination of two or more as a raw material for transesterified oils and fats. . As palm fractionation oil, a hard part, a soft part, a middle melting point part, etc. can be used.

上記エステル交換油脂のエステル交換反応には、エステル交換触媒として化学触媒や酵素触媒が用いられる。化学触媒としてはナトリウムメチラートや水酸化ナトリウムなどが用いられ、酵素触媒としてはリパーゼなどが用いられる。リパーゼとしてはアスペルギルス属、アルカリゲネス属などのリパーゼが挙げられ、イオン交換樹脂、ケイ藻土、セラミックなどの担体上に固定し固定化したものを用いても、粉末の形態として用いても良い。また位置選択性のあるリパーゼ、位置選択性のないリパーゼのいずれも用いることができるが、位置選択性のないリパーゼを用いることが好ましい。   In the transesterification reaction of the transesterified oil and fat, a chemical catalyst or an enzyme catalyst is used as a transesterification catalyst. Sodium methylate or sodium hydroxide is used as the chemical catalyst, and lipase or the like is used as the enzyme catalyst. Examples of the lipase include lipases of the genus Aspergillus and the genus Alkagenes, which may be fixed and immobilized on a carrier such as an ion exchange resin, diatomaceous earth, or ceramic, or may be used in the form of a powder. Either lipase with regioselectivity or lipase without regioselectivity can be used, but it is preferable to use a lipase without regioselectivity.

エステル交換反応に化学触媒を用いる場合、触媒を油脂質量の0.05〜0.15質量%添加し、減圧下で80〜120℃に加熱し、0.5〜1.0時間攪拌することでエステル交換反応が平衡状態となって完了し、エステル交換油脂を得ることができる。また酵素触媒を用いる場合、リパーゼなどの酵素触媒を油脂質量の0.01〜10質量%添加し、40〜80℃でエステル交換反応を行うことによりエステル交換反応が平衡状態となって完了し、エステル交換油脂を得ることができる。エステル交換反応はカラムによる連続反応、バッチ反応のいずれの方法で行うこともできる。エステル交換反応後、必要に応じて脱色、脱臭などの精製を行うことができる。   When using a chemical catalyst for the transesterification reaction, the catalyst is added at 0.05 to 0.15% by mass of the oil lipid amount, heated to 80 to 120 ° C. under reduced pressure, and stirred for 0.5 to 1.0 hour. The transesterification reaction is completed in an equilibrium state, and transesterified fats and oils can be obtained. When an enzyme catalyst is used, an enzyme catalyst such as lipase is added in an amount of 0.01 to 10% by mass of the oil lipid amount, and the ester exchange reaction is completed in an equilibrium state by carrying out the ester exchange reaction at 40 to 80 ° C. Transesterified fats and oils can be obtained. The transesterification reaction can be carried out by either a continuous reaction using a column or a batch reaction. After the transesterification reaction, purification such as decolorization and deodorization can be performed as necessary.

本発明の製菓製パン練り込み用油脂組成物(A)は、油脂の構成脂肪酸としてトランス酸を含んでもよく、含まなくてもよいが、トランス酸の摂取量が多くなると、人体に摂取された際のLDLコレステロールが増加しうる。よって、これを抑制しやすい点から、本発明においては、油脂の構成脂肪酸中のトランス酸の含有量は、油脂の構成脂肪酸全体の質量に対して10質量%未満であることが好ましく、5質量%未満であることがより好ましく、3質量%未満であることが最も好ましい。   The confectionery bread kneading fat and oil composition (A) of the present invention may or may not contain trans acid as a constituent fatty acid of the fat or oil, but when the intake of trans acid increases, it was ingested by the human body. LDL cholesterol can increase. Therefore, from the viewpoint of easily suppressing this, in the present invention, the content of trans acid in the constituent fatty acids of the fat is preferably less than 10% by mass with respect to the total mass of the constituent fatty acids of the fat. % Is more preferable, and it is most preferable that it is less than 3% by mass.

2.可塑性油脂(B)
本発明の製菓製パン練り込み用油脂組成物(A)は、油相中に本発明の製菓製パン練り込み用油脂組成物(A)を含有する可塑性油脂(B)を調製し、これを原材料とする生地を用いて焼成品を得ることができる。
2. Plastic oil (B)
The confectionery bread kneading fat and oil composition (A) of the present invention prepares a plastic fat and oil (B) containing the confectionery bread kneading fat and oil composition (A) of the present invention in the oil phase. A fired product can be obtained using the dough used as a raw material.

この可塑性油脂(B)は、油相中に本発明の製菓製パン練り込み用油脂組成物(A)を含有するものである。   This plastic fat (B) contains the fat composition (A) for confectionery bread kneading of the present invention in the oil phase.

可塑性油脂(B)における本発明の製菓製パン練り込み用油脂組成物(A)の含有量としては、好ましくは50〜100質量%、より好ましくは70〜100質量%である。   The content of the confectionery bread kneading fat and oil composition (A) of the present invention in the plastic fat and oil (B) is preferably 50 to 100% by mass, more preferably 70 to 100% by mass.

この可塑性油脂(B)は、水相を実質的に含有しない形態と、水相を含有する形態をとることができる。水相を含有する形態としては油中水型、水中油型、油中水中油型、水中油中水型が挙げられ、油相の含有量は、好ましくは60〜99.4質量%、より好ましくは65〜98質量%であり、水相の含有量は、好ましくは0.6〜40質量%、より好ましくは2〜35質量%である。水相を含有する形態としては油中水型が好ましく、例えばマーガリンが挙げられる。   This plastic fat (B) can take the form which does not contain an aqueous phase substantially, and the form which contains an aqueous phase. Water-in-oil type, oil-in-water type, oil-in-water-in-oil type, water-in-oil-in-water type are included as the form containing the water phase, and the content of the oil phase is preferably 60 to 99.4% by mass, more Preferably it is 65-98 mass%, Content of an aqueous phase becomes like this. Preferably it is 0.6-40 mass%, More preferably, it is 2-35 mass%. As a form containing an aqueous phase, a water-in-oil type is preferable, for example, margarine.

また水相を実質的に含有しない形態としてはショートニングが挙げられる。ここで「実質的に含有しない」とは日本農林規格のショートニングに該当する、水分(揮発分を含む。)の含有量が0.5質量%以下のことである。   Moreover, shortening is mentioned as a form which does not contain an aqueous phase substantially. Here, “substantially does not contain” means that the content of moisture (including volatile matter) is 0.5% by mass or less, corresponding to the shortening of the Japanese Agricultural Standard.

この可塑性油脂(B)には、水以外に、従来の公知の成分を含んでもよい。公知の成分としては、特に限定されないが、例えば、乳、乳製品、蛋白質、糖質、塩類、酸味料、pH調整剤、抗酸化剤、香辛料、着色成分、フレーバー、乳化剤、酒類、酵素、粉末油脂などが挙げられる。乳としては、牛乳などが挙げられる。乳製品としては、脱脂乳、生クリーム、チーズ(ナチュラルチーズ、プロセスチーズなど)、発酵乳、濃縮乳、脱脂濃縮乳、無糖れん乳、加糖れん乳、無糖脱脂れん乳、加糖脱脂れん乳、全脂粉乳、脱脂粉乳、クリームパウダー、ホエイパウダー、蛋白濃縮ホエイパウダー、ホエイ蛋白コンセントレート(WPC)、ホエイ蛋白アイソレート(WPI)、バターミルクパウダー、トータルミルクプロテイン、カゼインナトリウム、カゼインカリウムなどが挙げられる。蛋白質としては、大豆蛋白、エンドウ豆蛋白、小麦蛋白などの植物蛋白などが挙げられる。糖質としては、単糖(グルコース、フルクトース、ガラクトース、マンノースなど)、二糖類(ラクトース、スクロース、マルトース、トレハロースなど)、オリゴ糖、糖アルコール、ステビア、アスパルテームなどの甘味料、デンプン、デンプン分解物、多糖類などが挙げられる、抗酸化剤としては、L−アスコルビン酸、L−アスコルビン酸誘導体、トコフェロール、トコトリエノール、リグナン、ユビキノン類、キサンチン類、オリザノール、植物ステロール、カテキン類、ポリフェノール類、茶抽出物などが挙げられる。香辛料としては、カプサイシン、アネトール、オイゲノール、シネオール、ジンゲロンなどが挙げられる。着色成分としては、カロテン、アナトー、アスタキサンチンなどが挙げられる。フレーバーとしては、バターフレーバー、ミルクフレーバーなどが挙げられる。乳化剤としては、レシチン、グリセリン脂肪酸エステル、有機酸グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、プロピレングリコール脂肪酸エステル、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウム、ポリオキシエチレンソルビタン脂肪酸エステルなどが挙げられる。   This plastic fat (B) may contain conventional known components in addition to water. Known ingredients are not particularly limited, for example, milk, dairy products, proteins, sugars, salts, acidulants, pH adjusters, antioxidants, spices, coloring ingredients, flavors, emulsifiers, alcoholic beverages, enzymes, powders Examples include fats and oils. Examples of milk include milk. Dairy products include skim milk, fresh cream, cheese (natural cheese, processed cheese, etc.), fermented milk, concentrated milk, defatted concentrated milk, sugar-free milk, sweetened milk, sugar-free skimmed milk, sweetened skimmed milk , Whole milk powder, skim milk powder, cream powder, whey powder, protein concentrated whey powder, whey protein concentrate (WPC), whey protein isolate (WPI), buttermilk powder, total milk protein, casein sodium, casein potassium, etc. Can be mentioned. Examples of the protein include plant proteins such as soybean protein, pea protein, and wheat protein. Carbohydrates include monosaccharides (glucose, fructose, galactose, mannose, etc.), disaccharides (lactose, sucrose, maltose, trehalose, etc.), oligosaccharides, sweeteners such as sugar alcohol, stevia, aspartame, starch, starch degradation products Antioxidants include L-ascorbic acid, L-ascorbic acid derivatives, tocopherols, tocotrienols, lignans, ubiquinones, xanthines, oryzanols, plant sterols, catechins, polyphenols, tea extraction Such as things. Examples of spices include capsaicin, anethole, eugenol, cineol, gingerone and the like. Examples of the coloring component include carotene, anato, and astaxanthin. Examples of flavors include butter flavor and milk flavor. As an emulsifier, lecithin, glycerin fatty acid ester, organic acid glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, propylene glycol fatty acid ester, calcium stearoyl lactate, sodium stearoyl lactate, Examples include polyoxyethylene sorbitan fatty acid ester.

この可塑性油脂(B)は、公知の方法により製造することができる。例えば水相を含有する形態のものは、本発明の製菓製パン練り込み用油脂組成物(A)を含む油相と水相とを適宜に加熱し混合して乳化した後、コンビネーター、パーフェクター、ボテーター、ネクサスなどの冷却混合機により急冷捏和し得ることができる。水相を含有しない形態のものは、本発明の製菓製パン練り込み用油脂組成物(A)を含む油相を加熱した後、コンビネーター、パーフェクター、ボテーター、ネクサスなどの冷却混合機により急冷捏和し得ることができる。冷却混合機において、必要に応じて窒素ガスなどの不活性ガスを吹き込むこともできる。また急冷捏和後に熟成(テンパリング)してもよい。   This plastic fat (B) can be produced by a known method. For example, in a form containing an aqueous phase, an oil phase containing the confectionery bread kneading fat and oil composition (A) of the present invention and an aqueous phase are appropriately heated, mixed and emulsified, and then combined with a combinator, perfection Can be quenched and chilled with a cooling mixer such as a rotator, a botter, or a nexus. In a form not containing an aqueous phase, the oil phase containing the confectionery bread kneading fat and oil composition (A) of the present invention is heated, and then rapidly cooled by a cooling mixer such as a combinator, perfector, bottor, or nexus. Can be calmed down. In the cooling mixer, an inert gas such as nitrogen gas can be blown as necessary. Further, aging (tempering) may be performed after quenching.

3.生地および焼成品
本発明の製菓製パン練り込み用油脂組成物(A)は、可塑性油脂(B)としてパンや菓子などの焼成品の生地に練り込んで使用することができる。可塑性油脂(B)を含有する生地を焼成することによってパンや菓子などの焼成品が得られる。生地への可塑性油脂(B)の練り込みや、焼成は、例えば公知の条件および方法に従って行うことができる。
3. Dough and baked product The confectionery bread kneading oil / fat composition (A) of the present invention can be used as a plastic fat / oil (B) kneaded into a batter of baking products such as bread and confectionery. Baking products, such as bread and confectionery, are obtained by baking the dough containing the plastic fat (B). The kneading and baking of the plastic fat (B) into the dough can be performed, for example, according to known conditions and methods.

生地は穀粉を主成分とし、穀粉としては、通常、焼成品の生地に配合されるものであれば、特に限定されないが、例えば、小麦粉(強力粉、中力粉、薄力粉など)、大麦粉、米粉、とうもろこし粉、ライ麦粉、そば粉、大豆粉などが挙げられる。   The dough is mainly composed of flour, and the flour is not particularly limited as long as it is usually blended into a baked product dough. For example, wheat flour (strong flour, medium flour, thin flour, etc.), barley flour, rice flour Corn flour, rye flour, buckwheat flour, soybean flour and the like.

生地における可塑性油脂(B)の配合量は、焼成品の種類によっても異なり特に限定されないが、生地に配合される穀粉100質量部に対して、好ましくは2〜40質量部であり、より好ましくは2〜30質量部である。   The blending amount of the plastic fat (B) in the dough varies depending on the kind of the baked product and is not particularly limited, but is preferably 2 to 40 parts by weight, more preferably 100 parts by weight of flour blended in the dough. 2 to 30 parts by mass.

生地には、穀粉と可塑性油脂(B)以外にも、通常、焼成品の生地に配合されるものであれば、特に制限なく配合することができる。また、これらの配合量も、通常、焼成品の生地に配合される範囲を考慮して特に制限なく配合することができる。具体的には、例えば、水や、前述したような乳、乳製品、蛋白質、糖質の他、卵、卵加工品、澱粉、塩類、乳化剤、乳化起泡剤(乳化油脂)、イースト、イーストフード、カカオマス、ココアパウダー、チョコレート、コーヒー、紅茶、抹茶、野菜類、果物類、果実、果汁、ジャム、フルーツソース、肉類、魚介類、豆類、きな粉、豆腐、豆乳、大豆蛋白、膨張剤、甘味料、調味料、香辛料、着色料、フレーバー、酵素などが挙げられる。   In addition to the flour and the plastic fat (B), the dough can be blended without particular limitation as long as it is usually blended with the dough of the baked product. These blending amounts can also be blended without any particular limitation, usually considering the range blended in the baked product dough. Specifically, for example, water, milk, dairy products, proteins and sugars as described above, eggs, egg products, starches, salts, emulsifiers, emulsifying foaming agents (emulsified fats and oils), yeast, yeast Food, cacao mass, cocoa powder, chocolate, coffee, tea, matcha, vegetables, fruits, fruit, fruit juice, jam, fruit sauce, meat, seafood, legumes, kinakome, tofu, soymilk, soy protein, swelling agent, sweetness Seasonings, seasonings, spices, colorants, flavors, enzymes and the like.

可塑性油脂(B)を添加した生地を用いた焼成品のパンや菓子としては、例えば、食パン、テーブルロール、菓子パン、調理パン、フランスパン、ライブレッドなどのパン類、シュトーレン、パネトーネ、クグロフ、ブリオッシュ、ドーナツなどのイースト菓子、デニッシュ、クロワッサン、パイなどのペストリー、バターケーキ、パウンドケーキ、スポンジケーキ、ビスケット、クッキー、ドーナツ、ブッセ、ホットケーキ、ワッフルなどのケーキなどが挙げられる。   Examples of the baked goods bread and confectionery using the dough to which the plastic fat (B) is added include, for example, bread such as bread, table roll, confectionery bread, cooking bread, French bread, live red, stollen, panettone, kuguroff, brioche , Pastries such as donuts, croissants and pies, butter cakes, pound cakes, sponge cakes, biscuits, cookies, donuts, busses, hot cakes, waffles and other cakes.

以下に、実施例により本発明をさらに詳しく説明するが、本発明はこれらの実施例に何ら限定されるものではない。
(1)測定方法
油脂のヨウ素価は、基準油脂分析試験法(公益社団法人日本油化学会)の「2.3.4.1−2013ヨウ素価(ウィイス−シクロヘキサン法)」で測定した。
EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.
(1) Measuring method The iodine value of fats and oils was measured by "2.3.4.1-2013 iodine number (Wiis-cyclohexane method)" of the standard fats and oils analysis test method (Japan Oil Chemists' Society).

油脂の固体脂含量(SFC)は、基準油脂分析試験法(公益社団法人日本油化学会)の「2.2.9−2013 固体脂含量(NMR法)」で測定した。   The solid fat content (SFC) of fats and oils was measured by “2.2.9-2013 solid fat content (NMR method)” of the standard fat analysis method (Japan Oil Chemists' Society).

P2Oの含有量(PPOおよびPOPの合計量)、PPOとPOPとの質量比(PPO/POP)、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、LLL、MLL、およびLMLの合計量は、ガスクロマトグラフ法(基準油脂分析試験法(公益社団法人日本油化学会)の「2.4.2.2−2013 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「奨2−2013 2位脂肪酸組成」)で測定し、それぞれ脂肪酸量を用いて計算にて求めた。トリグリセリドの2位に結合されたラウリン酸量は、ガスクロマトグラフ法(基準油脂分析試験法(公益社団法人日本油化学会)の「2.4.2.2−2013 脂肪酸組成(FID昇温ガスクロマトグラフ法)」と「奨2−2013 2位脂肪酸組成」で測定した。なお、P2Oの含有量、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量、トリグリセリドの2位に結合されたラウリン酸量、LLL、MLL、およびLMLの合計量は、油脂全量を基準としている。   Content of P2O (total amount of PPO and POP), mass ratio of PPO and POP (PPO / POP), content of trisaturated triglycerides whose constituent fatty acids are all 16 or more, LLL, MLL, and LML The total amount of is determined by gas chromatographic method (“2.4.2.2-2013 fatty acid composition (FID temperature rising gas chromatographic method)” and “Recommendation 2- 2013 2nd-position fatty acid composition "), and calculated | required by calculation using the amount of fatty acids, respectively. The amount of lauric acid bonded to the 2-position of triglyceride was determined by the gas chromatographic method (standard oil analysis test method (Japan Oil Chemists' Society), "2.4.2.2-2013 fatty acid composition (FID temperature rising gas chromatograph). Method) ”and“ Recommendation 2-2013 2-position fatty acid composition. ”In addition, the content of P2O, the content of trisaturated triglycerides in which all of the constituent fatty acids are 16 or more carbon atoms, and the 2-position of triglycerides are combined. The total amount of lauric acid, LLL, MLL, and LML is based on the total amount of fats and oils.

(2)評価
<製菓製パン練り込み用油脂組成物(A)および可塑性油脂(B)の作製>
表1および表2に示す配合比にて各油脂を混合し、実施例および比較例の製菓製パン練り込み用油脂組成物(A)を得た。なお、各油脂の35℃における固体脂含量(%)、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量(質量%)は表3に示すとおりである。
(2) Evaluation <Production of Confectionery Bread Kneading Oil Composition (A) and Plastic Fat (B)>
Each fats and oils were mixed by the compounding ratio shown in Table 1 and Table 2, and the fat and oil composition (A) for confectionery bread kneading of an Example and a comparative example was obtained. The solid fat content (%) at 35 ° C. of each fat and oil and the content (mass%) of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms are as shown in Table 3.

製菓製パン練り込み用油脂組成物(A)81.2質量部を75℃に調温し、乳化剤0.2質量部を添加後、溶解させ油相とした。一方、水16.5質量部に脱脂粉乳1.0質量部および食塩1.0質量部を添加し、80℃で加熱殺菌して水相を得た。   81.2 parts by mass of an oil / fat composition for kneading confectionery bread (A) was adjusted to 75 ° C., 0.2 parts by mass of an emulsifier was added, and dissolved to obtain an oil phase. On the other hand, 1.0 part by mass of skim milk powder and 1.0 part by mass of sodium chloride were added to 16.5 parts by mass of water, and heat sterilized at 80 ° C. to obtain an aqueous phase.

次に、該油相に該水相を添加し、プロペラ攪拌機で撹拌して、油中水型に乳化した後、ミルクフレーバーを0.1質量部添加し、撹拌後、コンビネーターによって急冷捏和して、下記の配合割合のマーガリンを可塑性油脂(B)として得た。得られたマーガリンは熟成(テンパリング)後に5℃で保管した。
〈マーガリンの配合〉
製菓製パン練り込み用油脂組成物(A) 81.2質量部
乳化剤 0.2質量部
水 16.5質量部
脱脂粉乳 1.0質量部
食塩 1.0質量部
ミルクフレーバー 0.1質量部
Next, the aqueous phase is added to the oil phase, stirred with a propeller stirrer and emulsified into a water-in-oil type, and then 0.1 part by weight of milk flavor is added. After stirring, the mixture is quenched and kneaded with a combinator. And the margarine of the following mixture ratio was obtained as a plastic fat (B). The obtained margarine was stored at 5 ° C. after aging (tempering).
<Combination of margarine>
Oil and fat composition for confectionery bread kneading (A) 81.2 parts by weight Emulsifier 0.2 parts by weight Water 16.5 parts by weight Nonfat dry milk 1.0 part by weight Salt 1.0 part by weight Milk flavor 0.1 parts by weight

<食パンの作製>
イーストを分散させた水、イーストフード、および強力粉をミキサーボールに投入しフックを使用して、下記条件にてミキシング、発酵を行い、中種生地を得た。
<Preparation of bread>
Water in which yeast was dispersed, yeast food, and strong flour were put into a mixer bowl and mixed and fermented under the following conditions using a hook to obtain a medium seed dough.

その後、本捏配合のマーガリン以外の全材料および中種生地を添加し低速3分、中低速3分でミキシングした後、マーガリンを投入し、さらに低速3分、中低速4分でミキシングしパン生地を得た。捏上温度は28℃であった。   After that, add all ingredients other than margarine and medium-sized dough, mix at low speed 3 minutes, medium low speed 3 minutes, then add margarine, mix at low speed 3 minutes, medium low speed 4 minutes and mix bread dough Obtained. The soaking temperature was 28 ° C.

その後、20分のフロアータイムをとった後、生地を分割し、再度20分のベンチタイムをとった。生地の成型は、モルダーで伸展し、ロール型に成型後、ワンローフ型に入れ、38℃、湿度80%で45分間のホイロをとり、その後200℃で30分焼成した。
〈食パン配合〉
・中種配合
強力粉 70質量部
イースト 2.5質量部
イーストフード 0.1質量部
水 40質量部
・本捏配合
強力粉 30質量部
上白糖 6質量部
食塩 1.8質量部
脱脂粉乳 2質量部
マーガリン(可塑性油脂(B)) 5質量部
水 25質量部
Then, after taking a floor time of 20 minutes, the dough was divided and a bench time of 20 minutes was taken again. The dough was stretched with a molder, molded into a roll mold, put into a one loaf mold, proofed for 45 minutes at 38 ° C. and 80% humidity, and then baked at 200 ° C. for 30 minutes.
<With bread>
・ Mixed seed compounded powder 70 parts by weight Yeast 2.5 parts by weight Yeast food 0.1 part by weight Water 40 parts by weight / Main body blended Powerful powder 30 parts by weight Sucrose 6 parts by weight Salt 1.8 parts by weight Nonfat dry milk 2 parts by weight Margarine (Plastic oil (B)) 5 parts by mass Water 25 parts by mass

<評価>
以下の各評価において、パネルは、五味(甘味、酸味、塩味、苦味、うま味)の識別テスト、味の濃度差識別テスト、食品の味の識別テスト、基準嗅覚テストを実施し、その各々のテストで適合と判断された20〜40代の男性4名、女性6名を選抜した。
<Evaluation>
In each of the following evaluations, the panel conducted a distinction test for five tastes (sweet, sour, salty, bitter, umami), a taste concentration difference identification test, a food taste identification test, and a standard olfactory test. Four men and six women in their 20s to 40s who were judged to be suitable were selected.

[ヒキ]
焼成した食パンを放冷後、20℃で2日保存し、試食したときにヒキ(パン様の繋がりが残存する食感)を感じるかをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、ヒキがないと評価した。
○:パネル10名中5〜7名が、ヒキがないと評価した。
△:パネル10名中3〜4名が、ヒキがないと評価した。
×:パネル10名中ヒキがないと評価したのは2名以下であった。
[Hiki]
After allowing the baked bread to cool, it was stored at 20 ° C. for 2 days, and it was evaluated by 10 panelists according to the following criteria whether or not it would feel a hiki (a texture in which bread-like connections remain) when tasted.
Evaluation Criteria A : Eight or more of the 10 panelists evaluated that there were no cracks.
A: 5 to 7 out of 10 panelists evaluated that there was no crack.
Δ: 3 to 4 out of 10 panelists evaluated that there were no cracks.
X: Two or less persons evaluated that there was no crack in 10 panelists.

[口中でのダマになりやすさ]
焼成した食パンを放冷後、20℃で2日保存し、試食したときに口中でのダマになりやすさを感じるかをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、口中でダマになりにくいと評価した。
○:パネル10名中5〜7名が、口中でダマになりにくいと評価した。
△:パネル10名中3〜4名が、口中でダマになりにくいと評価した。
×:パネル10名中、口中でダマになりにくいと評価したのは2名以下であった。
[Easy to become a nuisance in the mouth]
After allowing the baked bread to cool, it was stored at 20 ° C. for 2 days, and it was evaluated by 10 panelists according to the following criteria whether or not it was likely to become lumps in the mouth when it was tasted.
Evaluation Criteria A : Eight or more out of 10 panelists evaluated that they were less likely to become lumps in the mouth.
A: 5 to 7 out of 10 panelists evaluated that they were less likely to become lumps in the mouth.
Δ: 3 to 4 out of 10 panelists evaluated that they were less likely to become lumps in the mouth.
X: Among 10 panelists, 2 or less evaluated that they were less likely to become lumps in the mouth.

[パサつき感]
焼成した食パンを放冷後、20℃で2日保存し、試食したときのパサつきをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、パサつきが無いと評価した。
○:パネル10名中5〜7名が、パサつきが無いと評価した。
△:パネル10名中3〜4名が、パサつきが無いと評価した。
×:パネル10名中パサつきが無いと評価したのは2名以下であった。
[Feeling dry]
The baked bread was allowed to cool and then stored at 20 ° C. for 2 days. The taste of the baked bread was evaluated by 10 panelists according to the following criteria.
Evaluation Criteria A : Eight or more out of 10 panelists evaluated that there was no patter.
◯: 5 to 7 out of 10 panelists evaluated that there was no fluffiness.
Δ: 3 to 4 out of 10 panelists evaluated that there was no padding.
X: It was less than 2 persons who evaluated that there was no passage in 10 panelists.

[口あたりのソフトさ]
焼成した食パンを放冷後、20℃で2日保存し、試食したときの口あたりのソフトさをパネル10名で以下の基準により評価した。
評価基準
◎:パネル10名中8名以上が、ソフトさがあると評価した。
○:パネル10名中5〜7名が、ソフトさがあると評価した。
△:パネル10名中3〜4名が、ソフトさがあると評価した。
×:パネル10名中ソフトさがあると評価したのは2名以下であった。
[Mouth softness]
The baked bread was allowed to cool and then stored at 20 ° C. for 2 days. The softness of the mouth when tasting was evaluated by the following 10 criteria using 10 panelists.
Evaluation Criteria A : Eight or more of 10 panelists evaluated that there was softness.
A: 5 to 7 out of 10 panelists evaluated that there was softness.
Δ: 3 to 4 out of 10 panelists evaluated that there was softness.
X: Two or less persons evaluated that there was softness in 10 panelists.

[トップのフレーバーリリース]
焼成した食パンを20℃で2日保存し、試食したときのトップのフレーバーリリースをパネル10名で以下の基準で評価し、その平均点により評価した。
評価基準
点数
4点:トップのフレーバーリリースが非常に速く、風味を強く感じる。
3点:トップのフレーバーリリースが速く、風味を強く感じる。
2点:トップのフレーバーリリースがやや遅く、風味が若干薄れる。
1点:トップのフレーバーリリースが遅く、風味が弱い。
平均点
◎:平均点が3.5以上
〇:平均点が3以上3.5未満
△:平均点が2以上3未満
×:平均点が2未満
[Top flavor release]
The baked bread was stored at 20 ° C. for 2 days, and the top flavor release at the time of tasting was evaluated according to the following criteria by 10 panels, and the average score was evaluated.
Evaluation criteria Score 4 points: The top flavor release is very fast and the flavor is strong.
3 points: The top flavor release is fast and the flavor is strong.
2 points: The flavor release at the top is slightly slow and the flavor is slightly diminished.
1 point: The top flavor release is slow and the flavor is weak.
Average point ◎: Average point is 3.5 or more ○: Average point is 3 or more and less than 3.5 △: Average point is 2 or more and less than 3 ×: Average point is less than 2

[10℃での生地への分散性]
食パン作製時に10℃でマーガリンを生地に添加したときのマーガリンの塊がなくなる時間を目視により評価した。
評価基準
◎:1分超〜1分45秒以内で分散した。
○:1分45秒超〜2分30秒以内で分散した。
△:2分30秒超〜3分30秒以内で分散した。
×:3分30秒超で分散した。
[Dispersibility in dough at 10 ° C]
When margarine was added to the dough at 10 ° C. at the time of preparing bread, the time when the margarine lump disappeared was visually evaluated.
Evaluation criteria A : Dispersed within 1 minute to 1 minute 45 seconds.
○: Dispersed within 1 minute 45 seconds to 2 minutes 30 seconds.
Δ: Dispersed within 2 minutes 30 seconds to 3 minutes 30 seconds.
X: Dispersed in over 3 minutes 30 seconds.

上記の評価結果を表1および表2に示す。また製菓製パン用油脂組成物(A)の組成等も併せてこれらの表に示し、各油脂の35℃における固体脂含量(%)、構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量(質量%)は表3に示した。   The above evaluation results are shown in Tables 1 and 2. In addition, the composition of the confectionery bakery fat composition (A) is also shown in these tables, and the solid fat content (%) of each fat and oil at 35 ° C. and all the constituent fatty acids are trisaturated triglycerides having 16 or more carbon atoms. The content (mass%) of is shown in Table 3.

Figure 2017118851
Figure 2017118851

Figure 2017118851
Figure 2017118851

Figure 2017118851
Figure 2017118851

Claims (6)

構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が15質量%以下である油脂のみを含有し、以下の(a)〜(d)の条件を満たす製菓製パン練り込み用油脂組成物:
(a)PPOとPOPとの質量比(PPO/POP)が1.0超2.2以下(PPOは、1位と2位または2位と3位にパルミチン酸、3位または1位にオレイン酸が結合されたトリグリセリドであり、POPは、1位と3位にパルミチン酸、2位にオレイン酸が結合されたトリグリセリドであり、Pはパルミチン酸、Oはオレイン酸を示す。);
(b)P2Oの含有量が油脂全量に対して6.5〜15.5質量%(P2Oの含有量は、PPOおよびPOPの合計量である。);
(c)構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が油脂全量に対して0.1〜7.5質量%;および、
(d)トリグリセリドの2位に結合されたラウリン酸量が油脂全量に対して2.0〜25質量%。
Fats and oils for kneading confectionery bread containing only fats and oils containing 15% by mass or less of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms and satisfy the following conditions (a) to (d) Composition:
(A) The mass ratio of PPO to POP (PPO / POP) is more than 1.0 and 2.2 or less (PPO is palmitic acid at 1st and 2nd position or 2nd and 3rd position, and olein at 3rd or 1st position) An acid-bound triglyceride, POP is palmitic acid at positions 1 and 3 and oleic acid is bound at position 2, P is palmitic acid, and O is oleic acid);
(B) The content of P2O is 6.5 to 15.5% by mass with respect to the total amount of fats and oils (the content of P2O is the total amount of PPO and POP);
(C) the content of trisaturated triglycerides in which all of the constituent fatty acids have 16 or more carbon atoms is 0.1 to 7.5% by mass with respect to the total amount of fats and oils; and
(D) The amount of lauric acid bonded to the 2-position of triglyceride is 2.0 to 25% by mass with respect to the total amount of fats and oils.
LLL、MLL、およびLMLの合計量が油脂全量に対して1.5〜7質量%である、請求項1に記載の製菓製パン練り込み用油脂組成物(LLLは、1位と2位と3位にラウリン酸が結合されたトリグリセリドであり、MLLは、1位または3位にミリスチン酸、2位と3位または1位と2位にラウリン酸が結合されたトリグリセリドであり、LMLは、1位と3位にラウリン酸、2位にミリスチン酸が結合されたトリグリセリドであり、Lはラウリン酸、Mはミリスチン酸を示す。)。   The fat and oil composition for confectionery bread kneading according to claim 1, wherein the total amount of LLL, MLL and LML is 1.5 to 7% by mass with respect to the total amount of fats and oils (LLL is first and second) MLL is a triglyceride having lauric acid bonded to the 3rd position, and MLL is a triglyceride having myristic acid bonded to the 1st or 3rd position and lauric acid bonded to the 2nd and 3rd positions or the 1st and 2nd positions. This is a triglyceride in which lauric acid is bonded to the 1st and 3rd positions and myristic acid is bonded to the 2nd position, L is lauric acid, and M is myristic acid. 35℃における固体脂含量が8質量%以下の油脂のみを含有する、請求項1または2に記載の製菓製パン練り込み用油脂組成物。   The fat and oil composition for kneading confectionery bread according to claim 1 or 2, containing only fats and oils having a solid fat content at 35 ° C of 8% by mass or less. 構成脂肪酸の全てが炭素数16以上である3飽和トリグリセリドの含有量が12質量%以下である油脂のみを含有する、請求項1から3のいずれかに記載の製菓製パン練り込み油脂組成物。   The confectionery bread kneading fats and oils composition according to any one of claims 1 to 3 containing only fats and oils whose content of 3 saturated triglycerides whose constituent fatty acids are 16 or more carbon atoms is 12 mass% or less. ヨウ素価が50〜60のエステル交換油脂を含有する、請求項1から4のいずれかに記載の製菓製パン練り込み用油脂組成物。   The fat and oil composition for kneading confectionery bread according to any one of claims 1 to 4, comprising a transesterified fat and oil having an iodine value of 50 to 60. 請求項1から5のいずれかに記載の製菓製パン練り込み用油脂組成物を含有する可塑性油脂を生地に練り込み、この生地を焼成する焼成品の製造方法。
The manufacturing method of the baked product which knead | mixes the plastic fat and oil containing the fat and oil composition for confectionery bread kneading | mixing in any one of Claim 1 to 5 to baking dough.
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WO2020026996A1 (en) * 2018-08-03 2020-02-06 株式会社J-オイルミルズ Sponge cake improver
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